34 (Data in Thousand Metric Tons of Boric Oxide (B O ), Unless Otherwise
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
Salt Crystallization Temperatures in Searles Lake, California!
Mineral. Soc. Amer. Spec. Pap. 3, 257-259 (1970). SALT CRYSTALLIZATION TEMPERATURES IN SEARLES LAKE, CALIFORNIA! GEORGE 1. SMITH, U.S. Geological Survey, Menlo Park, California 94025 2 IRVING FRIEDMAN, AND SADAO MATSU0 , U.S. Geological Survey, Denver, Colorado ABSTRACT The DIH ratios in natural samples of borax, gaylussite, nahcolite and trona were compared with minerals synthesized in the laboratory to deduce temperatures of crystallization in Searles Lake. During most of the Early Holocene, trona in the Upper Salt was deposited during warm summers, average 32°C, similar to the present. Crystallization temperatures of the Middle Wisconsin Lower Salt inferred from DIH ratios are in the range _12° to +8°C; by consideration of phase rela- tions these are assigned to winter crystallization. Winter temperatures much colder than those of the present are inferred for the upper and lower thirds of this Lower Salt unit; summer temperatures for these units inferred from mineral as- semblages are also lower than those of the present. A more complete description of the method, data and results will be published elsewhere. INTRODUCTION are therefore considered to have crystallized well above Searles Lake, which is dry today, was one of a chain of 20°C, and assemblages lacking burkeite are considered to large lakes that formed in the Great Basin segment of have formed at lower temperature. Similarly, assemblages southeast California during pluvial periods of late Quater- that contain nahcolite, borax, thenardite, and mirabilite, nary time (Gale, 1914; Flint and Gale, 1958; Smith, 1968). whose solubilities are also greatly affected by temperature, The number of lakes in the chain, and the size of the last are used to estimate crystallization temperatures. -
Origin of the Kramer Borax Deposit, Boron, CA
A 50 year retrospective 1 OUTLINE 1. A brief history of borax 2. Kramer borax deposit a) Setting and Discovery b) Mineralogy of sedimentary borates c) Stratigraphy and Lithology d) Petrography and implications for geologic setting e) Solubility studies and modeling lake characteristics f) Comparable modern analogues 3. New evidence a) Turkish and Argentinian deposits b) Boron isotopic studies 4. Broader questions – Source water controls (thermal springs), B-As-Sb association, igneous-metamorphic controls on boron in thermal waters 2 Why give this talk? 1. Old (but rusty) material to me, new to most of you 2. Desire to see if ideas have changed in the past 50+ years. 3. Citation of my work even today suggests I did something right. 4. Wish to compare Kramer work with evidence from newer borate deposits in Turkey and South America 5. A wish to evaluate these ideas in light of new evidence using tools that weren’t available in 1964 6. A chance to ponder broader questions about boron’s geochemical cycle. 7. Work done so long ago that if you ask penetrating questions I can always plead a “senior moment” 3 What was unique about my research on the Kramer deposits? • Used a combination of geological tools (Field AND lab work – rare in 1964) • Stratigraphy, Petrography, and XRD based mineralogy • Experimental solubility studies of effects of other salts on Na-borate solubilities • Field studies of other possible borate environments (Borax Lake, Teels and Columbus Marsh, NV, Death Valley, Searles Lake) • Benefits of discussions with an all-star support team with similar interests (Mary Clark, Blair Jones, G.I. -
The Grystal Structure of Hanksite
American Mineralogist, Volume 58,pages 799-801,1973 The GrystalStructure of Hanksite Tnrlnlnu ARAKr,l,lNn Tlson Tntrx Departmentof Geologyand Geophysics,Uniuersity of Minnesota, Minneapolis, Minnesota 554 5 5 Abstract Hanksite, NaaK(COg)r(SOn)"C1, from Searles Lake, California, gave the space group P6s/m and the unit cell constants a - 10.465 and c - 21,191 A. Its structure was solved by three-dimensional Patterson synthesis and subsequent Fourier methods. The atomic co- ordinates and isotropic temperature factors were refined by full-matrix least-squares to R = 6.45 percentfor 1159reflections. The structure is characterized by chains of Na and K octahedra running parallel to the c-axis. These chains are connected by carbon and sulfur coordination groups, Introduction cell dimensionsare in good agreementwith those ( The mineralogy and the conditions of occurrence first reportedby Ramsdell 1939). of hanksite,NazsK(COe)2(SO4)ecl, at SearlesLake, Three-dimensionalintensities were collectedby a California, and the system Na-Cl-SOa-COs-H2O, generalinclination (Santoro and Zocchi, 1966) dif- which includeshanksite, have been extensivelystud- fractometerusing CuKc radiationon a crystalfrag- ied by severalauthors (Eugster and Smith, 1965; ment mountedfor a-axis rotation. All 1268 reflec- = Hardie and Eugster, l97O; Smith, Friedman, and tions were measuredup to sin 0 O.9245and were Matsuo, 1970). The possiblecrystal structure of correctedfor absorptionusing the methodintroduced hanksite, however, posed interesting questionsdue by Burnham (1966). The spacegroup of P6s/m to the unusual cation ratios in its chemicalcomposi- was concludedfrom the systematicabsences in the tion and the identity of its morphology and space 00t reflections,from the inequalities between hkl group with that of apatite. -
Potash and Borax Industry
Registry No. 1218-8-03 NATIONAL RECOVERY ADMINISTRATION PROPOSED CODE OF FAIR COMPETITION FOR THE POTASH AND BORAX INDUSTRY AS SUBMITTED ON AUGUST 31, 1933 R MEMBER U.S. WE D0 OUR PART The Code for the Potash and Borax Industry in its present form merely reflects the proposal of the above-mentioned industry, and none of the provisions contained therein are to be regarded as having received the approval of the National Recovery Administration as applying to this industry UNITED STATES GOVERNMENT PRINTING OFFICE WASHINGTON: 1933 For sale by the Superintendent of Documents, Washington, D.C. ---- ----- Price 5 cents SUBMITTED BY NATIONAL POTASh PROiUI CLRS ASsOCIATJON AND NATIONAL BORAX PRODUCRS ASSOCIATION PROPOSED CODE OF FAIR COMPETITION FOR THE POTASH AND BORAX INDUSTRIES To effectuate the policy of Title I of the National IndiustriAl Recovery Act, to reduce and relieve unemployment, to maintain adequate scales of wages and hours of labor consistent with American standards of living, to eliminate unfair competitive practices, to promote the fullest possible utilization of the present productive capacity of the industries, to encourage increased domestic production and consumption, to conserve natural resources, and in other respects to rehabilitate and to protect the Potash and Borax industries; the following provisions are established as a code of fair competition for the Potash and Borax industries: I This code is filed by the National Potash Producers Association, a voluntary association representing practically one hundred percent of the miners and/or manufacturers of Potash in the United States, and by the National Borax Producers Association, a voluntary asso- ciation representing miners and/or manufacturers producinig 95% of the borax in the United States. -
Warren, J. K., 2010, Evaporites Through Time: Tectonic, Climatic And
Earth-Science Reviews 98 (2010) 217–268 Contents lists available at ScienceDirect Earth-Science Reviews journal homepage: www.elsevier.com/locate/earscirev Evaporites through time: Tectonic, climatic and eustatic controls in marine and nonmarine deposits John K. Warren Petroleum Geoscience Program, Department of Geology, Chulalongkorn University, 254 Phayathai Road, Pathumwan, Bangkok 10330, Thailand article info abstract Article history: Throughout geological time, evaporite sediments form by solar-driven concentration of a surface or Received 25 February 2009 nearsurface brine. Large, thick and extensive deposits dominated by rock-salt (mega-halite) or anhydrite Accepted 10 November 2009 (mega-sulfate) deposits tend to be marine evaporites and can be associated with extensive deposits of Available online 22 November 2009 potash salts (mega-potash). Ancient marine evaporite deposition required particular climatic, eustatic or tectonic juxtapositions that have occurred a number of times in the past and will so again in the future. Keywords: Ancient marine evaporites typically have poorly developed Quaternary counterparts in scale, thickness, evaporite deposition tectonics and hydrology. When mega-evaporite settings were active within appropriate arid climatic and marine hydrological settings then huge volumes of seawater were drawn into the subsealevel evaporitic nonmarine depressions. These systems were typical of regions where the evaporation rates of ocean waters were at plate tectonics their maximum, and so were centred on the past latitudinal equivalents of today's horse latitudes. But, like economic geology today's nonmarine evaporites, the location of marine Phanerozoic evaporites in zones of appropriate classification adiabatic aridity and continentality extended well into the equatorial belts. Exploited deposits of borate, sodium carbonate (soda-ash) and sodium sulfate (salt-cake) salts, along with evaporitic sediments hosting lithium-rich brines require continental–meteoric not marine-fed hydrologies. -
Pink Halite (With Nahcolite) from Searles Lake (Actual Size 13.0 X 11.4Cm) the Holiday Party at the Pierce's on Sat. 12/05
DELVINGS __________________________________________________________ Volume LXVIII Number 12 December 2015 Pink Halite (with Nahcolite) from Searles Lake (actual size 13.0 x 11.4cm) Photo from Wikimedia Commons courtesy Rob Lavinsky/iRocks.com The holiday party at the Pierce’s on Sat. 12/05 is our December meeting Shopping opportunity at the Jewel Tunnel Imports warehouse – Sat 12/05: 10-4 ©Delvers Gem & Mineral Society, Inc.- a 501 (c)(3) organization- 1001 West Lambert Rd. #18, La Habra, CA 90631-1378 Saturday, December 5th – the Delvers Holiday Party, and Installation of Officers 1318 North Kroeger Ave., Fullerton 4:30 to 5:30 Hors d'oeuvre and crafts; 5:30 Sit-down Dinner Chuck Pierce: 714-595-3862, [email protected] We will have an ugly ornament exchange this year. To participate, bring a wrapped ugly ornament. One approach from the 91 Frwy is to take Raymond Avenue north. Turn left onto Melody Lane, after 0.2 miles turn right onto Kroeger Ave Jewel Tunnel Wholesale Warehouse Saturday December 5 th, 10 AM – 4 PM Members and friends of the Delvers Gem and Mineral Society are invited to attend an open-house at Jewel Tunnel Imports on Saturday December 5th, 2015. Starving students and others will be fed. Unattended children will be sold as slaves. Jewel Tunnel Imports is a leading wholesale distributor of mineral specimens, crystals, fossils, tumbled stones and many different kinds of lapidary items like balls, eggs, jewelry etc. made from different minerals. We have a warehouse in excess of 10,000 sq. feet full of mineral related natural history items, perhaps the largest of its kind in the United States. -
Character and Distribution of Nonclastic Minerals in the Searles Lake Evaporite Deposit California
Character and Distribution of Nonclastic Minerals in the Searles Lake Evaporite Deposit California By GEORGE I. SMITH and DAVID V. HAINES I CONTRIBUTIONS TO GENERAL GEOLOGY GEOLOGICAL SURVEY BULLETIN 1181-P Prepared in cooperation with the State of California, Resources Agency, ' Department of Conservation, Division of Mines and Geology -A UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1964 UNITED STATES DEPARTMENT OF THE INTERIOR STEWART L. UDALL, Secretary GEOLOGICAL SURVEY Thomas B. Nolan, Director The U.S. Geological Survey Library catalog card for this publication appears after page P58. For sale by the Superintendent of Documents, U.S. Government Printing Office Washington, D.C. 20402 CONTENTS Page Abstract..---.---------------------------------------------------- PI Introduction-____________-___-___----_--_-______-____--_______-___ 3 Acknowledgments ____-_____---_-__--__--_----__-_______---____..__- 4 Mineralogy __________-_---_---------_-_--_----_-------_--__-_-____ 6 , Minerals associated with saline layers____________________________ 8 Aphthitalite.. __-____---_----_---_--___---_---__-_________ 8 Borax-----.--------------------------------------.------- 10 Burkeite__.______--____-_.._-___-._-__.____..._..______ 12 Halite ------------------------------------------------- 14 Hanksite.-_------------_-----_-------__----------_----__- 16 Nahcolite__-___-_---_-_______-___-___---_____-___-_-____ 18 ^ Sulfohalite-.--------------------------------------------- 19 Teepleite._-----------------_----_------_-------_---_-.-.- 20 ,- -
8.12 Sodium Carbonate 8.12.1 General Sodium Carbonate (Na CO ), Commonly Referred to As Soda Ash, Is One of the Largest-Volume M
8.12 Sodium Carbonate 8.12.1 General1-3 Sodium carbonate (Na2CO3), commonly referred to as soda ash, is one of the largest-volume mineral products in the U. S., with 1991 production of over 9 million megagrams (Mg) (10.2 million tons). Over 85 percent of this soda ash originates in Wyoming, with the remainder coming from Searles Valley, California. Soda ash is used mostly in the production of glass, chemicals, soaps, and detergents, and by consumers. Demand depends to great extent upon the price of, and environmental issues surrounding, caustic soda, which is interchangeable with soda ash in many uses and is widely coproduced with chlorine (see Section 8.11, "Chlor-Alkali"). 8.12.2 Process Description4-7 Soda ash may be manufactured synthetically or from naturally occurring raw materials such as ore. Only 1 U. S. facility recovers small quantities of Na2CO3 synthetically as a byproduct of cresylic acid production. Other synthetic processes include the Solvay process, which involves saturation of brine with ammonia (NH3) and carbon dioxide (CO2) gas, and the Japanese ammonium chloride (NH4Cl) coproduction process. Both of these synthetic processes generate ammonia emissions. Natural processes include the calcination of sodium bicarbonate (NaHCO3), or nahcolite, a naturally occurring ore found in vast quantities in Colorado. The 2 processes currently used to produce natural soda ash differ only in the recovery stage in primary treatment of the raw material used. The raw material for Wyoming soda ash is mined trona ore, while California soda ash comes from sodium carbonate-rich brine extracted from Searles Lake. There are 4 distinct methods used to mine the Wyoming trona ore: (1) solution mining, (2) room-and-pillar, (3) longwall, and (4) shortwall. -
Hains Tech Report for Lithium Project
HAINS ENGINEERING COMPANY LIMITED TECHNICAL REPORT ON THE PANAMINT VALLEY LITHIUM PROJECT, PANAMINT VALLEY, CALIFORNIA Prepared for BATTERY MINERAL RESOURCES LIMITED Report for NI 43-101 Effective Date: November 16, 2017 Qualified Person: Donald H. Hains, P.Geo. March 25, 2018 Hains Engineering Company Limited Report Control Form Document Title Technical Report on the Panamint Valley Lithium Project, Panamint Valley, California Client Name & Address Battery Mineral Resources Limited Level 36, Governor Philip Tower, 1 Farrar Place Sydney NSW 2000, Australia Document Reference Status & Project #17-011 Issue No. Version 2 Issue Date March 25, 2018 Lead Author Don Hains (name) (signature & date) Peer Reviewer (name) (signature & date) Project Manager Approval (name) (signature & date) Project Director Approval (name) (signature & date) Report Distribution Name No. of Copies Client 1 pdf Hains Engineering Filing 1 (project box) Hains Engineering Company Limited 2275 lakeshore Blvd. West, Suite 515 Toronto, Ontario M8V 3Y3 Canada Tel: +1 416 971-9783 Fax: +1 416 971-9812 [email protected] HAINS ENGINEERING COMPANY LIMITED TABLE OF CONTENTS Page 1 EXECUTIVE SUMMARY ........................................................................................... 1-1 1.1 Introduction .................................................................................................. 1-1 1.2 Conclusions ............................................................................................................... 1-2 1.3 Recommendations .................................................................................................... -
Historical and Technical Developments of Potassium Resources
Historical and technical developments of potassium resources The MIT Faculty has made this article openly available. Please share how this access benefits you. Your story matters. Citation Ciceri, Davide, David A.C. Manning, and Antoine Allanore. “Historical and Technical Developments of Potassium Resources.” Science of The Total Environment 502 (January 2015): 590–601. As Published http://dx.doi.org/10.1016/j.scitotenv.2014.09.013 Publisher Elsevier B.V. Version Author's final manuscript Citable link http://hdl.handle.net/1721.1/106614 Terms of Use Creative Commons Attribution-NonCommercial-NoDerivs License Detailed Terms http://creativecommons.org/licenses/by-nc-nd/4.0/ 1 Historical and technical developments of potassium resources 2 3 Davide Ciceria, David A.C. Manningb and Antoine Allanorec 4 5 a Department of Materials Science & Engineering. Room 13-5066 Massachusetts Institute of Technology. 77 6 Massachusetts Avenue, Cambridge, MA 02139-4307, USA. Email: [email protected] 7 8 b School of Civil Engineering and Geosciences Room 3.01 Drummond Building. Newcastle University. Newcastle 9 upon Tyne NE1 7RU, UK. Email: [email protected] 10 11 c Corresponding author: Department of Materials Science & Engineering. Room 13-5066 Massachusetts Institute 12 of Technology. 77 Massachusetts Avenue, Cambridge, MA 02139-4307, USA. Email: [email protected] 13 1 1 ABSTRACT 2 3 The mining of soluble potassium salts (potash) is essential for manufacturing fertilizers required to ensure 4 continuous production of crops and hence global food security. As of 2014, potash is mined predominantly in the 5 northern hemisphere, where large deposits occur. Production tonnage and prices do not take into account the 6 needs of the farmers of the poorest countries. -
Rrelative Salt in Panamint Valley
Mineral. Soc. Amer. Spec. Pap. 3,307-319 (1970). BROMIDE GEOCHEMISTRY OF SOME NON-MARINE SALT DEPOSITS IN THE SOUTHERN GREAT BASIN WILLIAM T. HOLSER Chevron Oil Field Research Company, La Habra, California 90631 ABSTRACT The Wisconsin Upper Salt and Lower Salt in Searles Lake regularly contain about 50 ppm Br, compared to a mean of 20 ppm in the Early to Late Pleistocene Mixed Layer in Searles and the correlative salt in Panamint Valley. At least one period of dessication is suggested by high bromide in unit C of the Mixed Layer. Bromide in both the Pliocene Virgin Valley and Avawatz Mountain salt rocks is 6 to 10 ppm. This low range is consistent with derivation from older marine salt rocks eroded from the Colorado Plateau by an ancestral Colorado River. The Wisconsin salts at Searles accumulated at a rate possibly consistent with the recent flux of chloride in the Owens River, but these rates are several times the present input of chloride into the entire Owens drainage, including atmospheric precipitation and a small contribution from thermal springs. The halides may have been held over in Pliocene sediments such as the Waucobi-Coso lake beds. Various lines of evidence about Pliocene geography of this area admit the possi- bility that the Waucobi-Coso sediments may also have received some of their halides from an eastern source of marine evaporites either by a westward-flowing river or by westward-moving weather systems. INTRODUCTION MULTICYCLE FRESH- WATER 2nd- The general geochemical evolution of lake waters in the CYCLE EVAPORITES BRINE Great Basin was first developed by Hutchinson (1957), and ( with more detailed evidence by Jones (1966). -
Aluminum Bronze Hanger Bearings for Searles Valley Minerals
Aluminum Bronze Hanger Bearings for Searles Valley Minerals General Description of the Application Searles Valley Minerals in Trona, CA processes brine solutions from Searles Lake to produce boric acid, sodium carbonate, sodium sulfate, several specialty forms of borax and salt. Bulk materials produced by Searles Valley Minerals are used to create products such as window glass and windshields. Soda ash is one of the ten highest volume minerals produced in North America and constitutes nearly 25-percent of every pound of glass manufactured. Screw conveyors are used extensively in the soda ash manufacturing process at Searles Valley Miner- als. These screw conveyors must run 24 hours per day and 7 days per week. Downtime can be very costly. Preventive maintenance is performed on a regular basis to prevent equipment failures. The screw conveyors utilized bronze internal hanger bearings that required constant replacement. Maintenance personnel needed a hanger bearing that would last much longer than the bronze bearings currently in use. KWS worked with Searles Valley Minerals to nd the right solution. Design Parameters of Application Bulk Material: Soda Ash Material Density: 55 to 60 Lbs. per Cubic Foot Abrasiveness: Moderately Abrasive Conveyor Capacity: 100 to 200 Tons per Hour Duty: 24 Hours per Day, 7 Days per Week Advantages Provided by KWS Searles Valley Minerals contacted KWS to discuss their application and possible solutions. A replace- ment for bronze was needed that could stand up to the abrasion caused by conveying soda ash. After researching several dierent bearing materials, it was determined that aluminum bronze was superior to bronze for the hanger bearing application.