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IR-3 Elements and Groups of Elements (March 04)
1 IR-3 Elements and Groups of Elements (March 04) CONTENTS IR-3.1 Names and symbols of atoms IR-3.1.1 Systematic nomenclature and symbols for new elements IR-3.2 Indication of mass, charge and atomic number using indexes (subscripts and superscripts) IR-3.3 Isotopes IR-3.3.1 Isotopes of an element IR-3.3.2 Isotopes of hydrogen IR-3.4 Elements (or elementary substances) IR-3.4.1 Name of an element of infinite or indefinite molecular formula or structure IR-3.4.2 Name of allotropes of definite molecular formula IR-3.5 Allotropic modifications IR-3.5.1 Allotropes IR-3.5.2 Allotropic modifications constituted of discrete molecules IR-3.5.3 Crystalline allotropic modifications of an element IR-3.5.4 Solid amorphous modifications and commonly recognized allotropes of indefinite structure IR-3.6 Groups of elements IR-3.6.1 Groups of elements in the Periodic Table and their subdivisions IR-3.6.2 Collective names of groups of like elements IR-3.7 References IR-3.1 NAMES AND SYMBOLS OF ATOMS The origins of the names of some chemical elements, for example antimony, are lost in antiquity. Other elements recognised (or discovered) during the past three centuries were named according to various associations of origin, physical or chemical properties, etc., and more recently to commemorate the names of eminent scientists. In the past, some elements were given two names because two groups claimed to have discovered them. To avoid such confusion it was decided in 1947 that after the existence of a new element had been proved beyond reasonable doubt, discoverers had the right to IUPACsuggest a nameProvisional to IUPAC, but that only Recommendations the Commission on Nomenclature of Inorganic Chemistry (CNIC) could make a recommendation to the IUPAC Council to make the final Page 1 of 9 DRAFT 2 April 2004 2 decision. -
Which Pnictogen Is Best?† Cite This: New J
NJC PAPER Pnictogen bonding with alkoxide cages: which pnictogen is best?† Cite this: New J. Chem., 2019, 43,14305 Henry J. Trubenstein, ‡ Shiva Moaven, ‡ Maythe Vega, Daniel K. Unruh and Anthony F. Cozzolino * Pnictogen bonding is beginning to emerge as a useful supramolecular interaction. The design strategies for these systems are still in the early stages of development and much attention has been focused on the lighter pnictogens. Pnictogen bond donors can have up to three independent sites for binding which can result in triple pnictogen bonding. This has been observed in the self-assembly of antimony alkoxide cages, but not with the lighter congeners. This work reports structural characterization of an analogous arsenic alkoxide cage that engages in a single pnictogen bond and synthetic explorations of Received 14th July 2019, the bismuth congener. DFT calculations are used to evaluate the differences between the structures. Accepted 13th August 2019 Ultimately the partial charge on the pnictogen and the energy of the pnictogen lone pair dictate the DOI: 10.1039/c9nj03648b strength, orientation and number of pnictogen bonds that these cages form. Antimony cages strike the best balance between strength and directionality, allowing them to achieve triple pnictogen bonding rsc.li/njc where the other congeners do not. Introduction or bismuth.15–23 Recently, antimony centred PnBs have been purposefully designed into molecules to actively direct the self- A pnictogen bond (PnB), in analogy to a halogen or chalcogen assembly of reversed bilayer vesicles,24 enable anion binding bond (XB/HaB or ChB), is ‘‘the net attractive interaction between with applications in sensing and transport,25–28 self-assembly an electrophilic region associated with a [pnictogen] atom in a complex architectures through triple pnictogen bonding29 and molecular entity [the PnB donor] and a nucleophilic region in allow for supramolecular catalysis.30 These applications rely on another, or the same, molecular entity [the PnB acceptor].’’1 the predictable formation of PnBs. -
Of the Periodic Table
of the Periodic Table teacher notes Give your students a visual introduction to the families of the periodic table! This product includes eight mini- posters, one for each of the element families on the main group of the periodic table: Alkali Metals, Alkaline Earth Metals, Boron/Aluminum Group (Icosagens), Carbon Group (Crystallogens), Nitrogen Group (Pnictogens), Oxygen Group (Chalcogens), Halogens, and Noble Gases. The mini-posters give overview information about the family as well as a visual of where on the periodic table the family is located and a diagram of an atom of that family highlighting the number of valence electrons. Also included is the student packet, which is broken into the eight families and asks for specific information that students will find on the mini-posters. The students are also directed to color each family with a specific color on the blank graphic organizer at the end of their packet and they go to the fantastic interactive table at www.periodictable.com to learn even more about the elements in each family. Furthermore, there is a section for students to conduct their own research on the element of hydrogen, which does not belong to a family. When I use this activity, I print two of each mini-poster in color (pages 8 through 15 of this file), laminate them, and lay them on a big table. I have students work in partners to read about each family, one at a time, and complete that section of the student packet (pages 16 through 21 of this file). When they finish, they bring the mini-poster back to the table for another group to use. -
Chemical Nomenclature
Chemical Nomenclature Many everyday and historically important chemical compounds have common names. For example, water is the common name for H2O, baking soda is the common name for NaHCO3 and KNO3, an important component of gunpowder, is known as saltpeter. However, since there are over 50 million known chemical compounds, learning a common name for each one would be very difficult. Chemical nomenclature is a systematic method of naming chemical compounds. Having a system for naming means that we don’t have to learn 50 million names, we only have to learn the rules for naming. It also allows scientists who speak different languages to communicate effectively. The rules for chemical nomenclature come from the International Union for Pure and Applied Chemistry (IUPAC), a group made up of chemists from all over the world. In this exercise you will learn rules for naming ionic and covalent compounds and learn to predict the ratios that chemicals combine in based on their ionic charge. A. Naming Type I Binary Ionic Compounds Type I binary ionic compounds are made of (1) a metal that can only have one possible charge and (2) a nonmetal. The metal is the cation, or positively charged ion and the nonmetal is the anion, or negatively charged ion. In the chemical formula, the cation is always written first and the anion is written second. Cations that fall under Type I naming include Group 1A alkali metals, which always form 1+ cations and Group 2A alkaline earth metals which always form 2+ cations. Most transition metals fall under Type II naming, discussed below, but the exceptions are silver (Ag), which always forms 1+ cations and zinc (Zn) and cadmium (Cd), which always form 2+ cations. -
Chemical Nomenclature for an Introductory Chemistry Course: a Tutorial Rules & Drills with Answers
Chemical Nomenclature for an Introductory Chemistry Course: A Tutorial Rules & Drills with Answers Table of Contents Unit I: Chemical Symbols of Some Common Elements (Drill A)…………………… 2 Unit II: Nomenclature of Pure Elements (Drill B)…………………………………… 4 Unit III: Nomenclature of Monatomic Ions (Simple Ions) ………………………….. 5 Unit IIIA: Nomenclature of Monatomic Anions ………………………………….. 5 Unit IIIB: Nomenclature of Monatomic Cations of Fixed Charges ………………. 6 Unit IIIC: Nomenclature of Monatomic Cations of Variable Charges (Drill C)….. 6 Unit IV: Nomenclature of Ionic Compounds of Monatomic Ions …………………... 7 Unit IVA: Writing Formulas from a Given Name (Drill D)………………………. 8 Unit IVB: Writing Names from a Given Formula (Drills E thru H)………………. 9 Unit V: Nomenclature of Polyatomic Ions …………………………………………... 11 Unit VA: The "Basic Eight" Polyatomic Ions (Drills I-1 thru I-4)………………... 11 Unit VB: Polyatomic Ions with "- ite" Ending ……………………………………. 14 Unit VC: Nomenclature of "- ate" and "- ite" Compounds (Drill I-5)……………... 14 Unit VD: Nomenclature of Oxohaloanions (Drills J & K)………………………… 15 Unit VI: Nomenclature of Acids (Drill L)……………………………………………. 17 Unit VII: Nomenclature of Acid Anions (Drill M)…………………………………… 20 Unit VIII: Nomenclature of Molecular Binary Compounds (Drill N & O)……….…. 22 Unit IX: Nomenclature of Hydrates (Drill P)……………………………………….... 23 Answers to Drill A…………………………………………………………………. 25 Answers to Drill B…………………………………………………………………. 25 Answers to Drill C…………………………………………………………………. 25 Answers to Drill D………………………………………………………………… 26 Answers to Drill E…………………………………………………………………. 26 Answers to Drill F…………………………………………………………………. 26 Answers to Drill G…………………………………………………………………. 27 Answers to Drill H………………………………………………………………… 27 Answers to Drill I-1, I-2, I-3………………………………………………………. 28 Answers to Drill I-4, I-5…………………………………………………………… 29 Answers to Drill J………………………………………………………………….. 30 Answers to Drill K………………………………………………………………… 30 Answers to Drill L……………………………………………………………….... -
Chem T2, U5 Covalent Bonds and Nomenclature
Chem T2, U5 Covalent Bonds and Nomenclature Chemistry: Term 2: Unit 5 Topic: Covalent Bonds and Nomenclature Duration: Traditional (50 minute periods) : 11-13 days (adjust to student needs using professional discretion) Block Schedule (90 minute periods) : 5-7 days (adjust to student needs using professional discretion) Eligible Content This is what the State of Pennsylvania wants your students to know and be able to do by the end of the unit. CHEM.A.1.2.5 Describe how chemical bonding can affect whether a substance dissolves in a given liquid. CHEM.B.1.4.2 Utilize Lewis dot structures to predict the structure and bonding in simple compounds. CHEM.B.1.4.2 Utilize Lewis dot structures to predict the structure and bonding in simple compounds. BIO.A.2.2.1 Explain how carbon is uniquely suited to form biological macromolecules. Performance Objectives These are examples, created by SDP teachers, of how you may translate the eligible content into learning goals for your classroom. -
A Book Collector's View of the Periodic Table: Key Documents
Firenze University Press www.fupress.com/substantia A Book Collector’s View of the Periodic Table: Key Documents before Mendeleev’s Citation: G. S. Girolami (2019) A Book Collector’s View of the Periodic Table: Contributions of 1869 Key Documents before Mendeleev’s Contributions of 1869. Substantia 3(2) Suppl. 5: 109-124. doi: 10.13128/Sub- stantia-592 Gregory S. Girolami Copyright: © 2019 G. S. Girolami. School of Chemical Sciences, 600 S. Mathews Ave., University of Illinois at Urbana- This is an open access, peer-reviewed Champaign, Urbana, 61801, US article published by Firenze University E-mail: [email protected] Press (http://www.fupress.com/substan- tia) and distributed under the terms of the Creative Commons Attribution Abstract. The present article identifies and discusses some of the books and scientif- License, which permits unrestricted ic articles that played important roles in the development of the periodic law, before use, distribution, and reproduction Mendeleev published his Periodic System in 1869. For each book, information is giv- in any medium, provided the original en about the edition in which the discovery was made, and for each scientific article, author and source are credited. information is given about the form in which it was issued, such as whether offprints Data Availability Statement: All rel- were printed in addition to the journal appearance. Some observations of interest to evant data are within the paper and its book collectors are included, such as assessments of the availability of these documents Supporting Information files. on the rare book market. This paper may also be of use to those who wish to learn about (or to teach) the history of the periodic law from the original documents that Competing Interests: The Author(s) first announced important advances toward its creation. -
Techniques of Preparation and Crystal Chemistry of Transuranic Chalcogenides and Pnictides D
Techniques of preparation and crystal chemistry of transuranic chalcogenides and pnictides D. Damien, R. Haire, J. Peterson To cite this version: D. Damien, R. Haire, J. Peterson. Techniques of preparation and crystal chemistry of transuranic chalcogenides and pnictides. Journal de Physique Colloques, 1979, 40 (C4), pp.C4-95-C4-100. 10.1051/jphyscol:1979430. jpa-00218826 HAL Id: jpa-00218826 https://hal.archives-ouvertes.fr/jpa-00218826 Submitted on 1 Jan 1979 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. JOURNAL DE PHYSIQUE Colloque C4, supplément au n° 4, Tome 40, avril 1979, page C4-95 Techniques of preparation and crystal chemistry of transuranic chalcogenides and pnictides (*) D. A. Damien (**), R. G. Haire and J. R. Peterson (t) Transuranium Research Laboratory, Oak Ridge National Laboratory, Oak Ridge, TN 37830, U.S.A. Résumé. — La cristallochimie d'un certain nombre de chalcogénures et pnictures d'éléments transuraniens a été étudiée en utilisant les isotopes Am, Cm, Bk et Cf. Les composés ont été préparés par réaction directe du métal avec l'élément chalcogène ou pnictogène à température élevée. Les chalcogénures supérieurs ont été dissociés thermiquement pour donner des composés à stœchiométrie plus basse dont les sesquichalco- génures constituent la limite. -
Organometallic Pnictogen Chemistry
Institut für Anorganische Chemie 2014 Fakultät für Chemie und Pharmazie | Sabine Reisinger aus Regensburg, geb. Scheuermayer am 15.07.1983 Studium: Chemie, Universität Regensburg Abschluss: Diplom Promotion: Prof. Dr. Manfred Scheer, Institut für Anorganische Chemie Sabine Reisinger Die vorliegende Arbeit enthält drei Kapitel zu unterschiedlichen Aspekten der metallorganischen Phosphor- und Arsen-Chemie. Zunächst werden Beiträge zur supramolekularen Chemie mit 5 Pn-Ligandkomplexen basierend auf [Cp*Fe(η -P5)] und 5 i [Cp*Fe(η - Pr3C3P2)] gezeigt, gefolgt von der Eisen-vermittelten Organometallic Pnictogen Aktivierung von P4, die zu einer selektiven C–P-Bindungsknüpfung führt, während das dritte Kapitel die Verwendung von Phosphor Chemistry – Three Aspects und Arsen als Donoratome in mehrkernigen Komplexen mit paramagnetischen Metallionen behandelt. Sabine Reisinger 2014 Alumniverein Chemie der Universität Regensburg E.V. [email protected] http://www.alumnichemie-uniregensburg.de Aspects Three – Chemistry Pnictogen Organometallic Fakultät für Chemie und Pharmazie ISBN 978-3-86845-118-4 Universität Regensburg Universitätsstraße 31 93053 Regensburg www.uni-regensburg.de 9 783868 451184 4 Sabine Reisinger Organometallic Pnictogen Chemistry – Three Aspects Organometallic Pnictogen Chemistry – Three Aspects Dissertation zur Erlangung des Doktorgrades der Naturwissenschaften (Dr. rer. nat.) der Fakultät für Chemie und Pharmazie der Universität Regensburg vorgelegt von Sabine Reisinger, geb. Scheuermayer Regensburg 2014 Die Arbeit wurde von Prof. Dr. Manfred Scheer angeleitet. Das Promotionsgesuch wurde am 20.06.2014 eingereicht. Das Kolloquium fand am 11.07.2014 statt. Prüfungsausschuss: Vorsitzender: Prof. Dr. Helmut Motschmann 1. Gutachter: Prof. Dr. Manfred Scheer 2. Gutachter: Prof. Dr. Henri Brunner weiterer Prüfer: Prof. Dr. Bernhard Dick Dissertationsreihe der Fakultät für Chemie und Pharmazie der Universität Regensburg, Band 4 Herausgegeben vom Alumniverein Chemie der Universität Regensburg e.V. -
Chapter 10. Chemical Nomenclature
Chapter 10. Chemical Nomenclature 10.1. Chemical Language Each society of people has its own language, and it is necessary to learn the language of the society to communicate effectively with it. Imagine, for example, what a foreigner might envision the first time theyheard a sports announcer on a radio use terminology like‘‘steal- ing’’, ‘‘sacrifice’’, and ‘‘high fly’’. The subjects of naming chemical substances, or chemical nomenclature,and writing chemical ‘‘equations’’are basic to communication in the society of chemists. Language communicates information and the language of chemistry has ev olved and improvedwith the understanding of chemical principles. Forthis reason, an understanding of chemical language in not only useful for communicating, but reflects an underlying understanding of the concepts of chemistry. Unfortunately,partly due to historical precedent and partly due to conceptual limita- tions, there is no ultimate chemical language which describes uniquely everything known about a material, including molecular structure and chemical properties, and it may be assumed that chemical concepts yet to be discovered will lead to newways of describing that knowledge.1 Forthis reason, several different systems of terminology areinuse today,each with advantages and disadvantages. It is assumed that somewhere along the career of the chemist, mentioning something likehydrogen sulfide will conjure up memories of rotten eggs and bent bonds the way the mention of the word water connotes a cool liquid that satisfies thirst and the symbols H2O. The best we can do here is to introduce a fewcommunication methods students are likely to encounter in introductory courses. Chemical language is similar to other human languages, with element symbols forming the alphabet, chemical formulas the words, chemical equations the sentences and multistep chemical processes the paragraphs. -
Chemical Nomenclature
Chemistry HS/Science Unit: 05 Lesson: 01 Suggested Duration: 12 days Chemical Nomenclature Lesson Synopsis: In this lesson, students will discover the importance of having a common and consistent system of rules for writing formulas and naming chemical compounds. The lesson will focus upon developing an understanding of how to write formulas and name compounds appropriately. Models will be used to aid students’ understanding and application of the International Union of Pure and Applied Chemistry (IUPAC) rules for chemical nomenclature. TEKS: C.7 Science concept. The student knows how atoms form ionic, metallic, and covalent bonds. The student is expected to: C.7A Name ionic compounds containing main group or transition metals, covalent compounds, acids, and bases, using International Union of Pure and Applied Chemistry (IUPAC) nomenclature rules. Readiness Standard C.7B Write the chemical formulas of common polyatomic ions, ionic compounds containing main group or transition metals, covalent compounds, acids, and bases. Readiness Standard Scientific Process TEKS: C.2 Scientific processes. The student uses scientific methods to solve investigative questions. The student is expected to: C.2D Distinguish between scientific hypotheses and scientific theories. C.2E Plan and implement investigative procedures, including asking questions, formulating testable hypotheses, and selecting equipment and technology, including graphing calculators, computers and probes, sufficient scientific glassware such as beakers, Erlenmeyer flasks, pipettes, graduated cylinders, volumetric flasks, safety goggles, and burettes, electronic balances, and an adequate supply of consumable chemicals. C.2F Collect data and make measurements with accuracy and precision. C.2H Organize, analyze, evaluate, make inferences, and predict trends from data. C.2I Communicate valid conclusions supported by the data through methods such as lab reports, labeled drawings, graphs, journals, summaries, oral reports, and technology-based reports. -
Nomenclature Notes
Rules of Nomenclature for Binary Compounds There are three types of binary compounds: Type I. A metal of fixed charge and a nonmetal; Type II. A metal of variable charge and a nonmetal; and Type III. Two nonmetals Metals of ‘variable charge’ tend to be transition elements with some exceptions; metals of fixed charge tend to be the alkali metals and the alkaline earths, along with zinc, cadmium and silver. Nonmetals are those compounds to the right of the bold zig-zag line (see Periodic Table attached) The rules for naming binary compounds are then as follows: • Rule 1. When writing a formula or naming a compound: a). For Type I and Type II compounds, first list the metal then the nonmetal; b) For Type III compounds always list the electropositive species first (the element furthest left in the periodic table) and then the electronegative species. Type III species tend to be exclusively covalently bound compounds. NOTE: It becomes very important that you KNOW YOUR IONS AND THEIR CHARGES (especially the anions, since any given element anion does not have varying charges)!!! • Rule 2. All compound must be neutral UNLESS indicated otherwise. • Rule 3. When naming binary compounds: a). For compounds of Type I and Type II, always use the FULL name of the metal and add the suffix -ide to the root name of the nonmetal (i.e. Metal Nonmetide); b). Type II compounds are handled the same as Type I except the charge on the metal is indicated by using a roman numeral in parentheses immediately following the metal (i.e.