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Safety Data Sheet SAFETY DATA SHEET Creation Date 27-Aug-2013 Revision Date 13-Mar-2018 Revision Number 1 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identification Product Description: Cadmium bromide hydrate Cat No. : 44498 CAS-No 7789-72-6 EC-No. 232-165-1 Molecular Formula Br2 Cd Reach Registration Number - 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. Uses advised against No Information available 1.3. Details of the supplier of the safety data sheet Company Alfa Aesar . Avocado Research Chemicals, Ltd. Shore Road Port of Heysham Industrial Park Heysham, Lancashire LA3 2XY United Kingdom Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608 E-mail address [email protected] www.alfa.com Product Safety Department 1.4. Emergency telephone number Call Carechem 24 at +44 (0) 1865 407333 (English only); +44 (0) 1235 239670 (Multi-language) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture CLP Classification - Regulation (EC) No 1272/2008 Physical hazards Based on available data, the classification criteria are not met Health hazards Acute oral toxicity Category 4 (H302) Acute dermal toxicity Category 4 (H312) Acute Inhalation Toxicity - Dusts and Mists Category 4 (H332) ______________________________________________________________________________________________ ALFAA44498 Page 1 / 10 SAFETY DATA SHEET Cadmium bromide hydrate Revision Date 13-Mar-2018 ______________________________________________________________________________________________ Environmental hazards Acute aquatic toxicity Category 1 (H400) Chronic aquatic toxicity Category 1 (H410) 2.2. Label elements Signal Word Warning Hazard Statements H302 - Harmful if swallowed H312 - Harmful in contact with skin H332 - Harmful if inhaled H410 - Very toxic to aquatic life with long lasting effects Precautionary Statements P280 - Wear protective gloves/ protective clothing P261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray P304 + P340 - IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing P273 - Avoid release to the environment 2.3. Other hazards No information available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Component CAS-No EC-No. Weight % CLP Classification - Regulation (EC) No 1272/2008 Cadmium bromide 7789-42-6 EEC No. 232-165-1 >95 Acute Tox. 4 (H302) Acute Tox. 4 (H312) Acute Tox. 4 (H332) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410) Reach Registration Number - Full text of Hazard Statements: see section 16 SECTION 4: FIRST AID MEASURES ______________________________________________________________________________________________ ALFAA44498 Page 2 / 10 SAFETY DATA SHEET Cadmium bromide hydrate Revision Date 13-Mar-2018 ______________________________________________________________________________________________ 4.1. Description of first aid measures General Advice If symptoms persist, call a physician. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Obtain medical attention. Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur. Inhalation Move to fresh air. Obtain medical attention. If not breathing, give artificial respiration. Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. 4.2. Most important symptoms and effects, both acute and delayed None reasonably foreseeable. 4.3. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Extinguishing media which must not be used for safety reasons No information available. 5.2. Special hazards arising from the substance or mixture Do not allow run-off from fire fighting to enter drains or water courses. Hazardous Combustion Products Hydrogen bromide, Cadmium oxide. 5.3. Advice for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Use personal protective equipment. Avoid dust formation. 6.2. Environmental precautions Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. Should not be ______________________________________________________________________________________________ ALFAA44498 Page 3 / 10 SAFETY DATA SHEET Cadmium bromide hydrate Revision Date 13-Mar-2018 ______________________________________________________________________________________________ released into the environment. 6.3. Methods and material for containment and cleaning up Sweep up or vacuum up spillage and collect in suitable container for disposal. Keep in suitable, closed containers for disposal. 6.4. Reference to other sections Refer to protective measures listed in Sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Wear personal protective equipment. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. 7.2. Conditions for safe storage, including any incompatibilities Keep containers tightly closed in a dry, cool and well-ventilated place. 7.3. Specific end use(s) Use in laboratories SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Exposure limits List source(s): UK - EH40/2005 Containing the workplace exposure limits (WELs) for use with the Control of Substances Hazardous to Health Regulations (COSHH) 2002 (as amended). Updated by September 2006 official press release and October 2007 Supplement. Component The United Kingdom European Union Ireland Cadmium bromide STEL: 0.075 mg/m3 15 min TWA: 0.025 mg/m3 8 hr Biological limit values This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust MDHS10/2 Cadmium and inorganic compounds of cadmium in air Laboratory method using flame atomic absorption spectrometry or electrothermal atomic absorption spectrometry Derived No Effect Level (DNEL) No information available ______________________________________________________________________________________________ ALFAA44498 Page 4 / 10 SAFETY DATA SHEET Cadmium bromide hydrate Revision Date 13-Mar-2018 ______________________________________________________________________________________________ Route of exposure Acute effects (local) Acute effects Chronic effects Chronic effects (systemic) (local) (systemic) Oral Dermal Inhalation Predicted No Effect Concentration No information available. (PNEC) 8.2. Exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source Personal protective equipment Eye Protection Safety glasses with side-shields (European standard - EN 166) Hand Protection Protective gloves Glove material Breakthrough time Glove thickness EU standard Glove comments Natural rubber See manufacturers - EN 374 (minimum requirement) Nitrile rubber recommendations Neoprene PVC Skin and body protection Long sleeved clothing Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination. Respiratory Protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced Recommended Filter type: Particulates filter conforming to EN 143 Small scale/Laboratory use Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator
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