109 Part 116—Designation of Hazardous Substances
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
United States Patent Office Patented Sept
3,000,702 United States Patent Office Patented Sept. 19, 196 2 since potassium fluoride is very soluble. In this case, a 3,000,702 MANUEFACTURE OF SODIUM FLUOR DE double or complex salt is formed in the melt between George L. Cunningham, Burtonsville, Md., assignor to potassium fluoride and the calcium salt and that is slowly W. R. Grace & Co., New York, N.Y., a corporation extracted with water in spite of the great solubility of of Connecticut potassium fluoride in water. The corrosion of the molten No Drawing. Filed May 23, 1958, Ser. No. 737,196 melt is also a considerable problem although suitable 4. Claims. (CI. 23-88) ceramic materials have been discovered for constructing the fusion vessel. This invention relates to a process for the manufac Processes have been devised for the production of so ture of sodium fluoride relatively low in silica content. 10 dium fluoride based on the thermal decomposition of More particularly, this invention relates to a cyclic proc sodium silicofluoride to sodium fluoride and silicon tetra ess whereby sodium fluoride, relatively low in silica con fluoride (U.S. 1,896,697, U.S. 2,588,786, 1,730,915, tent and ammonium chloride, may be manufactured from 2,602,726, and U.S. 1,664,348). These processes are cheap and readily available raw materials. faulty in that relatively high temperatures are required to As manufactured at the present time, technical sodium 15 decompose the sodium silicofluoride and thus it is very fluoride contains 94% to 97% NaF and 1.5% to 5.0% difficult to carry the reaction to completion. -
Chemicals Used for Chemical Manufacturing Page 1 of 2
Chemicals used for Chemical Manufacturing Page 1 of 2 Acetic Acid (Glacial, 56%) Glycol Ether PMA Acetone Glycol Ether PNB Acrylic Acid Glycol Ether PNP Activated Carbon Glycol Ether TPM Adipic Acid Glycols Aloe Vera Grease Aluminum Stearate Gum Arabic Aluminum Sulfate Heat Transfer Fluids Amino Acid Heptane Ammonium Acetate Hexane Ammonium Bicarbonate Hydrazine Hydrate Ammonium Bifluoride Hydrochloric Acid (Muriatic) Ammonium Chloride Hydrogen Peroxide Ammonium Citrate Hydroquinone Ammonium Hydroxide Hydroxylamine Sulfate Ammonium Laureth Sulfate Ice Melter Ammonium Lauryl Sulfate Imidazole Ammonium Nitrate Isobutyl Acetate Ammonium Persulfate Isobutyl Alcohol Ammonium Silicofluoride Calcium Stearate Dipropylene Glycol Isopropanolamine Ammonium Sulfate Carboxymethylcellulose Disodium Phosphate Isopropyl Acetate Antifoams Caustic Potash D'Limonene Isopropyl Alcohol Antifreeze Caustic Soda (All Grades) Dodecylbenzene Sulfonic Acid Isopropyl Myristate Antimicrobials Caustic Soda (Beads, Prills) (DDBSA) Isopropyl Palmitate Antimony Oxide Cetyl Alcohol Dowfrost Itaconic Acid Aqua Ammonia Cetyl Palmitate Dowfrost HD Jojoba Oil Ascorbic Acid Chlorine, Granular Dowtherm SR-1 Keratin Barium Carbonate Chloroform Dowtherm 4000 Lactic Acid Barium Chloride Chromic Acid EDTA Lanolin Beeswax Citric Acid (Dry and Liquid) EDTA Plus Lauric Acid Bentonite Coal Epsom Salt Lauryl Alcohol Benzaldehyde Cocamide DEA Ethyl Acetate Lecithin Benzoic Acid Copper Nitrate Ethyl Alcohol (Denatured) Lime Benzyl Alcohol Copper Sulfate Ethylene Glycol Linoleic Acid Bicarbonate -
Inventory Size (Ml Or G) 103220 Dimethyl Sulfate 77-78-1 500 Ml
Inventory Bottle Size Number Name CAS# (mL or g) Room # Location 103220 Dimethyl sulfate 77-78-1 500 ml 3222 A-1 Benzonitrile 100-47-0 100ml 3222 A-1 Tin(IV)chloride 1.0 M in DCM 7676-78-8 100ml 3222 A-1 103713 Acetic Anhydride 108-24-7 500ml 3222 A2 103714 Sulfuric acid, fuming 9014-95-7 500g 3222 A2 103723 Phosphorus tribromide 7789-60-8 100g 3222 A2 103724 Trifluoroacetic acid 76-05-1 100g 3222 A2 101342 Succinyl chloride 543-20-4 3222 A2 100069 Chloroacetyl chloride 79-04-9 100ml 3222 A2 10002 Chloroacetyl chloride 79-04-9 100ml 3222 A2 101134 Acetyl chloride 75-36-5 500g 3222 A2 103721 Ethyl chlorooxoacetate 4755-77-5 100g 3222 A2 100423 Titanium(IV) chloride solution 7550-45-0 100ml 3222 A2 103877 Acetic Anhydride 108-24-7 1L 3222 A3 103874 Polyphosphoric acid 8017-16-1 1kg 3222 A3 103695 Chlorosulfonic acid 7790-94-5 100g 3222 A3 103694 Chlorosulfonic acid 7790-94-5 100g 3222 A3 103880 Methanesulfonic acid 75-75-2 500ml 3222 A3 103883 Oxalyl chloride 79-37-8 100ml 3222 A3 103889 Thiodiglycolic acid 123-93-3 500g 3222 A3 103888 Tetrafluoroboric acid 50% 16872-11-0 1L 3222 A3 103886 Tetrafluoroboric acid 50% 16872-11-0 1L 3222 A3 102969 sulfuric acid 7664-93-9 500 mL 2428 A7 102970 hydrochloric acid (37%) 7647-01-0 500 mL 2428 A7 102971 hydrochloric acid (37%) 7647-01-0 500 mL 2428 A7 102973 formic acid (88%) 64-18-6 500 mL 2428 A7 102974 hydrofloric acid (49%) 7664-39-3 500 mL 2428 A7 103320 Ammonium Hydroxide conc. -
Inventory Stock Status by Item September 1 - 7, 2017 on Hand
10:14 AM MSU Chem Stores 09/07/17 Inventory Stock Status by Item September 1 - 7, 2017 On Hand Inventory 1-Propanol 1L (1-Propanol 1L) 2.00 1butanolt1L (tert-Butanol 1L Ea) 0.00 aceticacidgla (Acetic acid glacial 99.7% 2.5L Ea) 1.00 aceticanhyd (Acetic anhydride 500ml Ea) 0.00 aceton4Lchrom (Acetone chromAR for HPLC use) 0.00 acetone1L (Acetone HPLC 1L Ea) 0.00 acetone4L (Acetone HPLC 4L Ea) 1.00 acetonebulk (Acetone 345 lb/Drum (ACS) Bulk Lb) 720.63 Acetonit500ml (Acetonitrile 500ml ACS) 0.00 acetonitril4L (Acetonitrile HPLC 4L Ea 99.9%) 4.00 acetonitril4LHPLC99.9% (Acetonitril 4L HPLC 99.9% Gold Optima) -2.00 alconox (Alconox 4 Lb Carton Ea) 0.00 alcotabs (Alcotabs Bottle/100 Ea) 11.00 alumnitrate500 (Aluminum Nitrate 9 hydrate 500 g) 1.00 ammbicarb250 (Ammonium bicarbonate 250 gramEa) 0.00 ammcarbonaACS (Ammonium carbonate ACS 500g Ea) 1.00 ammchlori500g (Ammonium chloride 500g Ea) 0.00 ammfluoride (Ammonium fluoride 100g Ea) 0.00 ammhydroxide (Ammonium hydroxide 28-30% 2.5L Ea) 5.00 ammoniumnitrate2500 (Ammonium Nitrate Crystal 2500g) 8.00 ammoniumnitrate500 (Ammonium Nitrate Crystal 500g) 4.00 Ammoxal500g (Ammonium Oxalate 500G-Lab Grade) 0.00 amylalcmix8pt (Amyl alcohol (mixed isomers) 8pt (3.8L) Ea) 1.00 applicator (Applicators cotton-tipped Pk100) 77.00 aprondisp (Apron Tyvec 27x36" Ea) 1.00 ascorbicacid100g (L-ascorbic acid cry acs 100 grams) 0.00 aspiratorpoly (Aspirator poly Ea) 17.00 bags10x18 (Bags poly 10x18 Belart Ea) 90.00 bags12x20 (Bags poly 12x20 Belart Ea) 53.00 bagsbiohaz24x30 (Bags Biohazard 24"x30" 1.5mil per) 0.00 -
A Study on Physical Chemistry of Solid a Mmonium Materials for Nox Reduction of Diesel Engine Emissions
A Study on Physical Chemistry of Solid A mmonium Materials for NOx Reduction of Diesel Engine Emissions Cheon Seog (Steve) Yoon and Jong Kook Shin Hannam University, Daejeon, KOREA Hoyeol Lee and Hongsuk Kim Korea Institute of Machinery & Materials, Daejeon, KOREA 2014 DOE CLEERS Workshop University of Michigan, Dearborn, MI, USA 1 Table of Contents • Introduction of Solid SCR System • Ammonium Salts • Chemical Reactions, Decomposition Chemistry • Chemical Kinetic Parameters by TGA, DTA and DSC • Decomposition Rate from Hot Plate Test and Chemical Kinetic Parameters • Simple Reactor with Visible Window • Equilibrium Vapor Pressure Curve for Ammonium Carbonate • Acquisition of Re-solidified Materials from Ammonium Carbonate • Analytical Study of Re-solidified Materials from Ammonium Carbonate by XRD, FT-IR, and EA • Concluding Remarks • Acknowledgement • Reference 2 Solid SCR System • NOx purification technology by using NH3, which is generated from solid ammonium. • Ammonium carbonate, (NH4)2CO3 , is solid at room temperature, and it decomposes into NH3, H2O & CO2 above temperature of 60℃. 3 Material Properties of Ammonium Salts Solid urea Ammonium carbonate Ammonium cabarmate Molecular formula (NH2)2CO (NH4)2CO3 NH2COONH4 Molecular weight 60.07 96.09 78.07 3 Density, g/cm 1.33 1.5 1.6 Mols NH3 per Mol 2 2 2 Mols NH3 per kg 33.3 20.8 25.6 Decomposition temp., ℃ 140 58 60 NH2CONH2↔ NH3+HNCO Reaction mechanism (NH4)2CO3↔2NH3+CO2+H2O NH4COONH2 ↔ 2NH3 + CO2 HNCO +H2O ↔ NH3 + CO2 Cost cheap cheap moderate * HNCO: Isocyanic Acid [ref] G. Fulks, -
Pharmacy and Poisons (Third and Fourth Schedule Amendment) Order 2017
Q UO N T FA R U T A F E BERMUDA PHARMACY AND POISONS (THIRD AND FOURTH SCHEDULE AMENDMENT) ORDER 2017 BR 111 / 2017 The Minister responsible for health, in exercise of the power conferred by section 48A(1) of the Pharmacy and Poisons Act 1979, makes the following Order: Citation 1 This Order may be cited as the Pharmacy and Poisons (Third and Fourth Schedule Amendment) Order 2017. Repeals and replaces the Third and Fourth Schedule of the Pharmacy and Poisons Act 1979 2 The Third and Fourth Schedules to the Pharmacy and Poisons Act 1979 are repealed and replaced with— “THIRD SCHEDULE (Sections 25(6); 27(1))) DRUGS OBTAINABLE ONLY ON PRESCRIPTION EXCEPT WHERE SPECIFIED IN THE FOURTH SCHEDULE (PART I AND PART II) Note: The following annotations used in this Schedule have the following meanings: md (maximum dose) i.e. the maximum quantity of the substance contained in the amount of a medicinal product which is recommended to be taken or administered at any one time. 1 PHARMACY AND POISONS (THIRD AND FOURTH SCHEDULE AMENDMENT) ORDER 2017 mdd (maximum daily dose) i.e. the maximum quantity of the substance that is contained in the amount of a medicinal product which is recommended to be taken or administered in any period of 24 hours. mg milligram ms (maximum strength) i.e. either or, if so specified, both of the following: (a) the maximum quantity of the substance by weight or volume that is contained in the dosage unit of a medicinal product; or (b) the maximum percentage of the substance contained in a medicinal product calculated in terms of w/w, w/v, v/w, or v/v, as appropriate. -
Ammonium Bifluoride CAS No
Product Safety Summary Ammonium Bifluoride CAS No. 1341-49-7 This Product Safety Summary is intended to provide a general overview of the chemical substance. The information on the summary is basic information and is not intended to provide emergency response information, medical information or treatment information. The summary should not be used to provide in-depth safety and health information. In-depth safety and health information can be found in the Safety Data Sheet (SDS) for the chemical substance. Names • Ammonium bifluoride (ABF) • Ammonium difluoride • Ammonium acid fluoride • Ammonium hydrogen difluoride • Ammonium fluoride compound with hydrogen fluoride (1:1) Product Overview Solvay Fluorides, LLC does not sell ammonium bifluoride directly to consumers. Ammonium bifluoride is used in industrial applications and in other processes where workplace exposures can occur. Ammonium bifluoride (ABF) is used for cleaning and etching of metals before they are further processed. It is used as an oil well acidifier and in the etching of glass or cleaning of brick and ceramics. It may also be used for pH adjustment in industrial textile processing or laundries. ABF is available as a solid or liquid solution (in water). Ammonium bifluoride is a corrosive chemical and contact can severely irritate and burn the skin and eyes causing possible permanent eye damage. Breathing ammonium bifluoride can severely irritate and burn the nose, throat, and lungs, causing nosebleeds, cough, wheezing and shortness of breath. On contact with water or moist skin, ABF can release hydrofluoric acid, a very dangerous acid. Inhalation or ingestion of large amounts of ammonium bifluoride can cause nausea, vomiting and loss of appetite. -
1 Abietic Acid R Abrasive Silica for Polishing DR Acenaphthene M (LC
1 abietic acid R abrasive silica for polishing DR acenaphthene M (LC) acenaphthene quinone R acenaphthylene R acetal (see 1,1-diethoxyethane) acetaldehyde M (FC) acetaldehyde-d (CH3CDO) R acetaldehyde dimethyl acetal CH acetaldoxime R acetamide M (LC) acetamidinium chloride R acetamidoacrylic acid 2- NB acetamidobenzaldehyde p- R acetamidobenzenesulfonyl chloride 4- R acetamidodeoxythioglucopyranose triacetate 2- -2- -1- -β-D- 3,4,6- AB acetamidomethylthiazole 2- -4- PB acetanilide M (LC) acetazolamide R acetdimethylamide see dimethylacetamide, N,N- acethydrazide R acetic acid M (solv) acetic anhydride M (FC) acetmethylamide see methylacetamide, N- acetoacetamide R acetoacetanilide R acetoacetic acid, lithium salt R acetobromoglucose -α-D- NB acetohydroxamic acid R acetoin R acetol (hydroxyacetone) R acetonaphthalide (α)R acetone M (solv) acetone ,A.R. M (solv) acetone-d6 RM acetone cyanohydrin R acetonedicarboxylic acid ,dimethyl ester R acetonedicarboxylic acid -1,3- R acetone dimethyl acetal see dimethoxypropane 2,2- acetonitrile M (solv) acetonitrile-d3 RM acetonylacetone see hexanedione 2,5- acetonylbenzylhydroxycoumarin (3-(α- -4- R acetophenone M (LC) acetophenone oxime R acetophenone trimethylsilyl enol ether see phenyltrimethylsilyl... acetoxyacetone (oxopropyl acetate 2-) R acetoxybenzoic acid 4- DS acetoxynaphthoic acid 6- -2- R 2 acetylacetaldehyde dimethylacetal R acetylacetone (pentanedione -2,4-) M (C) acetylbenzonitrile p- R acetylbiphenyl 4- see phenylacetophenone, p- acetyl bromide M (FC) acetylbromothiophene 2- -5- -
Action of Ammonium Chloride Upon Silicates
Bulletin No. 207 Series E, Chemistry and Physics, 36 DEPARTMENT OF TEiE INTERIOR UNITED STATES GEOLOGICAL SURVEY CHARLES D. WALCOTT, DIRECTOR THE ACTION OF AMMONIUM CHLORIDE UPON SILICATES BY AND GKKOKG-IE Srj::ir, WASHINGTON GOVERNMEN.T PllINTING OFFICE 1902 CONTENTS. Page. Introductory statement......--..-..---.--.------.--.-..--.-.-----------. 7 Analcite-.....-.-.-.--.-.....-.--.'--------....--.-.--..._.-.---.-...---.--. 8 Leucite .....................'.................-....................^-..... 16 The constitution of analcite and leucite.........-..--.-..--...--.---------. 17 Pollucite---. ............................................................ 21 Natrolite--------------------------..-..-----------------.------ --------- 22 Scolecite ................,.:............-.....-.................--.--.... 24 Prehnite .....--.-............--.------------------------------ --------- 25 The trisilicic acids-.--.-.--..---..........-._-----...-.........-...----.- 26 Stilbite.............-..................-....-.-.-----...--.---.......... 29 Henlandite .......... .......................---.-..-.-..-...-----.--..--.. 81 Chabazite............................................................... 32 Thoinsonite...-.-.-..-...._.................---...-.-.-.----..-----..--.. 34 Lanmontite -.-.------.-..-------------.-..-.-..-.-------.-.-----........ 35 Pectolite ......:......... ......................................'.......;.., 36 Wollastonite ....'............................ ................:........... 39 Apophyllite. _.--._..._-....__.....:......___-------------....----..-...._ -
Environmental Protection Agency § 117.3
Environmental Protection Agency § 117.3 (4) Applicability date. This paragraph TABLE 117.3—REPORTABLE QUANTITIES OF (i) is applicable beginning on February HAZARDOUS SUBSTANCES DESIGNATED PUR- 6, 2020. SUANT TO SECTION 311 OF THE CLEAN (j) Process waste water means any WATER ACT—Continued water which, during manufacturing or Cat- RQ in pounds processing, comes into direct contact Material egory (kilograms) with or results from the production or use of any raw material, intermediate Ammonium benzoate ...................... D ...... 5,000 (2,270) Ammonium bicarbonate .................. D ...... 5,000 (2,270) product, finished product, byproduct, Ammonium bichromate ................... A ....... 10 (4.54) or waste product. Ammonium bifluoride ...................... B ....... 100 (45.4) Ammonium bisulfite ......................... D ...... 5,000 (2,270) [44 FR 50776, Aug. 29, 1979, as amended at 58 Ammonium carbamate .................... D ...... 5,000 (2,270) FR 45039, Aug. 25, 1993; 65 FR 30904, May 15, Ammonium carbonate ..................... D ...... 5,000 (2,270) 2000; 80 FR 37112, June 29, 2015; 83 FR 5208, Ammonium chloride ........................ D ...... 5,000 (2,270) Feb. 6, 2018] Ammonium chromate ...................... A ....... 10 (4.54) Ammonium citrate dibasic ............... D ...... 5,000 (2,270) Ammonium fluoborate ..................... D ...... 5,000 (2,270) § 117.2 Abbreviations. Ammonium fluoride ......................... B ....... 100 (45.4) NPDES equals National Pollutant Ammonium hydroxide ..................... C -
Alphabetical Index of Substances and Articles
ALPHABETICAL INDEX OF SUBSTANCES AND ARTICLES - 355 - NOTES TO THE INDEX 1. This index is an alphabetical list of the substances and articles which are listed in numerical order in the Dangerous Goods List in Chapter 3.2. 2. For the purpose of determining the alphabetical order the following information has been ignored even when it forms part of the proper shipping name: numbers; Greek letters; the abbreviations “sec” and “tert”; and the letters “N” (nitrogen), “n” (normal), “o” (ortho) “m” (meta), “p” (para) and “N.O.S.” (not otherwise specified). 3. The name of a substance or article in block capital letters indicates a proper shipping name. 4. The name of a substance or article in block capital letters followed by the word “see” indicates an alternative proper shipping name or part of a proper shipping name (except for PCBs). 5. An entry in lower case letters followed by the word “see” indicates that the entry is not a proper shipping name; it is a synonym. 6. Where an entry is partly in block capital letters and partly in lower case letters, the latter part is considered not to be part of the proper shipping name. 7. A proper shipping name may be used in the singular or plural, as appropriate, for the purposes of documentation and package marking. - 356 - INDEX Name and description Class UN No. Name and description Class UN No. Accumulators, electric, see 4.3 3292 Acid mixture, nitrating acid, see 8 1796 8 2794 8 2795 Acid mixture, spent, nitrating acid, see 8 1826 8 2800 8 3028 Acraldehyde, inhibited, see 6.1 1092 ACETAL 3 1088 -
Used at Rocky Flats
. TASK 1 REPORT (Rl) IDENTIFICATION OF CHEMICALS AND RADIONUCLIDES USED AT ROCKY FLATS I PROJECT BACKGROUND ChemRisk is conducting a Rocky Flats Toxicologic Review and Dose Reconstruction study for The Colorado Department of Health. The two year study will be completed by the fall of 1992. The ChemRisk study is composed of twelve tasks that represent the first phase of an independent investigation of off-site health risks associated with the operation of the Rocky Flats nuclear weapons plant northwest of Denver. The first eight tasks address the collection of historic information on operations and releases and a detailed dose reconstruction analysis. Tasks 9 through 12 address the compilation of information and communication of the results of the study. Task 1 will involve the creation of an inventory of chemicals and radionuclides that have been present at Rocky Flats. Using this inventory, chemicals and radionuclides of concern will be selected under Task 2, based on such factors as the relative toxicity of the materials, quantities used, how the materials might have been released into the environment, and the likelihood for transport of the materials off-site. An historical activities profile of the plant will be constructed under Task 3. Tasks 4, 5, and 6 will address the identification of where in the facility activities took place, how much of the materials of concern were released to the environment, and where these materials went after the releases. Task 7 addresses historic land-use in the vicinity of the plant and the location of off-site populations potentially affected by releases from Rocky Flats.