Diagenetic Formation of Uranium-Silica Polymers in Lake Sediments Over 3,300 Years
Diagenetic formation of uranium-silica polymers in lake sediments over 3,300 years Pierre Lefebvrea,1, Alkiviadis Gourgiotisb, Arnaud Mangeretb, Pierre Sabatierc, Pierre Le Papea, Olivier Diezb, Pascale Louvatd, Nicolas Menguya, Pauline Merrota,2, Camille Bayaa, Mathilde Zebrackib, Pascale Blanchartb, Emmanuel Maletc, Didier Jézéqueld,e, Jean-Louis Reyssc, John R. Bargarf, Jérôme Gaillardetd, Charlotte Cazalab, and Guillaume Morina aInstitut de Minéralogie, de Physique des Matériaux et de Cosmochimie, UMR 7590 Sorbonne Université-CNRS-MNHN-IRD (Museum National d’Histoire Naturelle-Institut de Recherche pour le Développement), 75005 Paris, France; bInstitut de Radioprotection et de Sûreté Nucléaire, PSE-ENV SEDRE, 92260 Fontenay-aux-Roses, France; cUMR 5204, Université Grenoble Alpes-Université Savoie Mont Blanc-CNRS-EDYTEM (Environnements DYnamiques et TErritoires de la Montagne), 73370 Le Bourget-Du-Lac, France; dUMR 7154, Université de Paris-Institut de Physique du Globe de Paris-CNRS, 75005 Paris, France; eINRAE-Université Savoie Mont Blanc, UMR CARRTEL (Centre Alpin de Recherche sur les Réseaux Trophiques et Ecosystèmes Limniques), 74200 Thonon-les-Bains, France; and fStanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, CA 94025 Edited by François M. M. Morel, Princeton University, Princeton, NJ, and approved December 16, 2020 (received for review October 27, 2020) The long-term fate of uranium-contaminated sediments, especially have been recognized as a major U pool in reduced contami- downstream former mining areas, is a widespread environmental nated soils and sediments over the last decade (6, 7, 19–25) and challenge. Essential for their management is the proper under- are known to be sensitive to reoxidation by natural oxidants such standing of uranium (U) immobilization mechanisms in reducing as oxygen or nitrate (26 and references therein).
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