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EUCO TREMIE GROUT Material: 088R 50 Version: 6.0 Revision Date: 01/03/2020 SAFETY DATA SHEET 1. Identification Material name: EUCO TREMIE GROUT Material: 088R 50 Recommended use and restriction on use Recommended use : Cement, Portland, chemicals Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information EUCLID CHEMICAL COMPANY 19218 REDWOOD ROAD CLEVELAND OH 44110 US Contact person : EH&S Department Telephone : 216-531-9222 Emergency telephone number : 1-800 -424 -9300 (US); 1 -613 -996 -6666 (Canada) 2. Hazard(s) identification Hazard Classification Health Hazards Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 1 Skin sensitizer Category 1 Carcinogenicity Category 1A Specific Target Organ Toxicity - Category 3 1. Single Exposure Specific Target Organ Toxicity - Category 1 2. Repeated Exposure Target Organs 1. Respiratory tract irritation. 2. Lung Unknown toxicity - Health Acute toxicity, oral 93.65 % Acute toxicity, dermal 94.82 % Acute toxicity, inhalation, vapor 99.96 % Acute toxicity, inhalation, dust 52.49 % or mist Label Elements Hazard Symbol : 1/20 800000050750 Version: 6.0 Revision Date: 01/03/2020 Signal Word: Danger Hazard Statement: Causes skin irritation. Causes serious eye damage. May cause an allergic skin reaction. May cause cancer. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure. Precautionary Statements Prevention: Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Contaminated work clothing should not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Use only outdoors or in a well-ventilated area. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Response : IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Wash with plenty of water/D If s)in irritation or rash occurs: et medical advice/attention. Immediately call a POI2ON CENTER/doctor. 2pecific treatment 6see on this label7. 0ash contaminated clothing before reuse. Storage : 2tore loc)ed up. 2tore in a well5ventilated place. Ceep container tightly closed. Disposal : Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Hazard(s) not otherwise None. classified (HNOC): 3. Composition/information on ingredients Mixtures Chemical Identity CAS number Content in percent (%) E 2/20 800000050750 Version: 6.0 Revision Date: 01/03/2020 Crystalline 2ilica 6Fuartz7/ 1180856057 20 5 G50% 2ilica 2and Portland cement 6599751551 20 5 G50% 2ilica, fused 6067658650 10 5 G20% Fumed silica 6901256152 1 5 G5% Calcium oxide 130557858 0.1 5 G1% Aluminum oxide 131152851 0.1 5 G1% Iron oxide 130953751 0.1 5 G1% E All concentrations are percent by weight unless ingredient is a gas. as concentrations are in percent by volume. 4. First -aid measures Description of necessary first -aid measures Inhalation : Move to fresh air. Skin Contact : et medical attention. Destroy or thoroughly clean contaminated shoes. Immediately remove contaminated clothing and shoes and wash s)in with soap and plenty of water. If s)in irritation or an allergic s)in reaction develops, get medical attention. Eye contact : Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Call a physician or poison control center immediately. Ingestion : Call a POI2ON CENTER/doctor if you feel unwell. Rinse mouth. Personal Protection for First - 2elf5contained breathing apparatus and full protective clothing must aid Responders: be worn in case of fire. Most important symptoms/effects, acute and delayed Symptoms : Prolonged or repeated contact with s)in may cause redness, itching, irritation and eczema/chapping. Extreme irritation of eyes and mucous membranes, including burning and tearing. Respiratory tract irritation. Hazards : No data available. Indication of immediate medical attention and special treatment needed Treatment : 2ymptoms may be delayed. 5. Fire -fighting measures General Fire Hazards : No unusual fire or explosion hazards noted. Suitable (and unsuitable) extinguishing media Suitable extinguishing Use fire5extinguishing media appropriate for surrounding materials. media: Unsuitable extinguishing Do not use water Het as an extinguisher, as this will spread the fire. media: 3/20 800000050750 Version: 6.0 Revision Date: 01/03/2020 Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical: Special protective equipment and precautions for firefighters Special fire fighting No data available. procedures: Special protective equipment 2elf5contained breathing apparatus and full protective clothing must be for fire-fighters: worn in case of fire. 6. Accidental release measures Personal precautions, 2ee 2ection 8 of the 2D2 for Personal Protective EAuipment. Do not touch protective equipment and damaged containers or spilled material unless wearing appropriate emergency procedures: protective clothing. Ceep unauthorized personnel away. Accidental release measures : In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Methods and material for Collect spillage in containers, seal securely and deliver for disposal containment and cleaning according to local regulations. up: Environmental Precautions : Do not contaminate water sources or sewer. Prevent further lea)age or spillage if safe to do so. 7. Handling and storage Handling Technical measures (e.g. Local Mechanical ventilation or local exhaust ventilation may be reAuired. and general ventilation): Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the ris) of inhalation of dust. Safe handling advice: Ventilate well, avoid breathing vapors. Use approved respirator if air contamination is above accepted level. Use mechanical ventilation in case of handling which causes formation of dust.Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Use personal protective eAuipment as reAuired. Do not get in eyes. 0ash hands thoroughly after handling. Avoid contact with s)in. Avoid contact with eyes, s)in, and clothing. Contact avoidance measures: No data available. Hygiene measures: Observe good industrial hygiene practices. 0ash hands before brea)s and immediately after handling the product. Do not get in eyes. 0ash contaminated clothing before reuse. Avoid contact with s)in. Contaminated wor) clothing should not be allowed out of the wor)place. Storage Safe storage conditions: 2tore loc)ed up. Safe packaging materials: No data available. 1/20 800000050750 Version: 6.0 Revision Date: 01/03/2020 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits Chemical Identity Type Exposure Limit Values Source Crystalline 2ilica 6Fuartz7/ T0A 0.025 mg/m3 U2. AC I, Threshold Limit Values, as 2ilica 2and 5 Respirable amended 620117 fraction. Crystalline 2ilica 6Fuartz7/ T0A 0.05 mg/m3 U2. O2,A 2pecifically Regulated 2ubstances 2ilica 2and 5 Respirable dust. 629 CFR 1910.1001510537, as amended 603 20167 O2,A_AC 0.025 mg/m3 U2. O2,A 2pecifically Regulated 2ubstances T 629 CFR 1910.1001510537, as amended 603 20167 Crystalline 2ilica 6Fuartz7/ PEL 0.05 mg/m3 U2. O2,A Table J51 Limits for Air 2ilica 2and 5 Respirable dust. Contaminants 629 CFR 1910.10007, as amended 603 20167 Crystalline 2ilica 6Fuartz7/ T0A 2.1 millions U2. O2,A Table J53 629 CFR 1910.10007, as 2ilica 2and 5 Respirable. of particles amended 620007 per cubic foot of air T0A 0.1 mg/m3 U2. O2,A Table J53 629 CFR 1910.10007, as amended 620007 Portland cement 5 Respirable T0A 1 mg/m3 U2. AC I, Threshold Limit Values, as fraction. amended 620117 Portland cement 5 Total dust. PEL 15 mg/m3 U2. O2,A Table J51 Limits for Air Contaminants 629 CFR 1910.10007, as amended 602 20067 Portland cement 5 Respirable PEL 5 mg/m3 U2. O2,A Table J51 Limits for Air fraction. Contaminants 629 CFR 1910.10007, as amended 602 20067 Portland cement T0A 50 millions of U2. O2,A Table J53 629 CFR 1910.10007, as particles per amended 620007 cubic foot of air 2ilica, fused T0A 20 millions of U2. O2,A Table J53 629 CFR 1910.10007, as particles per amended 620007 cubic foot of air T0A 0.8 mg/m3 U2. O2,A Table J53 629 CFR 1910.10007, as amended 620007 Fumed silica T0A 20 millions of U2. O2,A Table J53 629 CFR 1910.10007, as particles per amended 620007 cubic foot of air T0A 0.8 mg/m3 U2. O2,A Table J53 629 CFR 1910.10007, as amended 620007 Calcium oxide T0A 2 mg/m3 U2. AC I, Threshold Limit Values, as amended 620117 PEL 5 mg/m3 U2. O2,A Table J51 Limits for Air Contaminants 629 CFR 1910.10007, as amended 602 20067 Aluminum oxide 5 Respirable T0A 1 mg/m3 U2. AC I, Threshold Limit Values, as fraction. amended 620117 PEL 5 mg/m3 U2. O2,A Table J51 Limits for Air Contaminants 629 CFR 1910.10007, as amended 602 20067 Aluminum oxide 5 Total dust. PEL 15 mg/m3 U2. O2,A Table J51 Limits for Air Contaminants 629 CFR 1910.10007, as amended 602 20067 T0A 50 millions of U2. O2,A Table J53 629 CFR 1910.10007, as particles per amended 603 20167 cubic foot of air 5/20 800000050750 Version: 6.0 Revision Date: 01/03/2020 Aluminum oxide 5 Respirable T0A 15 millions of U2. O2,A Table J53 629 CFR 1910.10007, as fraction. particles per amended 603 20167 cubic foot of air T0A 5 mg/m3 U2. O2,A Table J53 629 CFR 1910.10007, as amended 603 20167 Aluminum oxide 5 Total dust. T0A 15 mg/m3 U2. O2,A Table J53 629 CFR 1910.10007, as amended 603 20167 Iron oxide 5 Respirable T0A 5 mg/m3 U2.
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