FIREDOC Vocabulary List, 3Rd Edition
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Safety Data Sheet
Coghlan’s Magnesium Fire Starter #7870 SAFETY DATA SHEET This Safety Data Sheet complies with the Canadian Hazardous Product Regulations, the United States Occupational Safety and Health Administration (OSHA) Hazard Communication Standard, 29 CFR 1910 (OSHA HCS), and the European Union Directives. 1. Product and Supplier Identification 1.1 Product: Magnesium Fire Starter 1.2 Other Means of Identification: Coghlan’s #7870 1.3 Product Use: Fire starter 1.4 Restrictions on Use: None known 1.5 Producer: Coghlan’s Ltd., 121 Irene Street, Winnipeg, Manitoba Canada, R3T 4C7 Telephone: +1(204) 284-9550 Facsimile: +1(204) 475-4127 Email: [email protected] Supplier: As above 1.6 Emergencies: +1(877) 264-4526 2. Hazards Identification 2.1 Classification of product or mixture This product is an untested preparation. GHS classification for this preparation is based upon its use as a fire starter by making shavings and small particulate from the metal block. As shipped in mass form, this preparation is not considered to be a hazardous product and is not classifiable under the requirements of GHS. GHS Classification: Flammable Solids, Category 1 2.2 GHS Label Elements, including precautionary statements Pictogram: Signal Word: Danger Page 1 of 11 October 18, 2016 Coghlan’s Magnesium Fire Starter #7870 GHS Hazard Statements: H228: Flammable Solid GHS Precautionary Statements: Prevention: P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280: Wear protective gloves, eye and face protection Response: P370+P378: In case of fire use water as first choice. Sand, earth, dry chemical, foam or CO2 may be used to extinguish. -
Hot Surface Ignition Temperature of Dust Layers with and Without Combustible Additives
HOT SURFACE IGNITION TEMPERATURE OF DUST LAYERS WITH AND WITHOUT COMBUSTIBLE ADDITIVES by Haejun Park A Thesis Submitted to the Faculty of the WORCESTER POLYTECHNIC INSTITUTE in partial fulfillment of the requirements for the Degree of Master of Science in Fire Protection Engineering May 2006 APPROVED: Professor Robert G. Zalosh, Advisor Joseph A. Senecal, Kiddie-Fenwal, Inc., Co-advisor Professor Kathy A. Notarianni, Head of Department Abstract An accumulated combustible dust layer on some hot process equipment such as dryers or hot bearings can be ignited and result in fires when the hot surface temperature is sufficiently high. The ASTM E 2021 test procedure is often used to determine the Hot Surface Minimum Ignition Temperature for a half inch deep layer of a particular dust material. This test procedure was used in this thesis to study possible effects of combustible liquid (such as lubricating oil) and powder additives in the dust layer as well as air flow effects. The following combustible dusts were used: paper dust from a printing press, Arabic gum powder, Pittsburgh seam coal, and brass powder. To develop an improved understanding of the heat transfer, and oxygen mass transfer phenomena occurring in the dust layer, additional instrumentation such as a second thermocouple in the dust layer, an oxygen analyzer and gas sampling line, and an air velocity probe were used in at least some tests. Hot Surface Minimum Ignition temperatures were 220oC for Pittsburgh seam coal, 360oC for paper dust, 270℃ for Arabic gum powder, and > 400oC for brass powder. The addition of 5-10 weight percent stearic acid powder resulted in significantly lower ignition temperature of brass powder. -
Copyrighted Material
1 Historical Milieu 1.1 Organophosphorus Nerve Agents 2 1.2 Blister Agents 5 1.3 Sternutator Agents 11 1.4 Chemical Weapons Convention (CWC) 13 1.4.1 Schedule of Chemicals 14 1.4.2 Destruction of Chemical Weapons 14 References 16 COPYRIGHTED MATERIAL Analysis of Chemical Warfare Degradation Products, First Edition. Karolin K. Kroening, Renee N. Easter, Douglas D. Richardson, Stuart A. Willison and Joseph A. Caruso. © 2011 John Wiley & Sons, Ltd. Published 2011 by John Wiley & Sons, Ltd. 2 ANALYSIS OF CHEMICAL WARFARE DEGRADATION PRODUCTS 1.1 ORGANOPHOSPHORUS NERVE AGENTS Organophosphorus (OP) type compounds, that is, deriva- tives containing the P=O moiety, were first discovered in the 1800s when researchers were investigating useful applica- tions for insecticides/rodenticides. There are many derivatives of organophosphorus compounds, however, the OP deriva- tives that are typically known as ‘nerve agents’ were discov- ered accidentally in Germany in 1936 by a research team led by Dr. Gerhard Schrader at IG Farben [1–4]. Schrader had noticed the effects and lethality of these organophosphorus compounds towards insects and began developing a new class of insecticides. While working towards the goal of an improved insecticide, Schrader experimented with numerous phosphorus-containing compounds, leading to the discovery of the first nerve agent, Tabun (or GA) (Figure 1.1). The potency of these insecticides towards humans was not realized until there was yet another accident, which involved a Tabun spill. Schrader and coworkers began experiencing symptoms, such as miosis (constriction of the pupils of the eyes), dizziness and severe shortness of breath, with numerous effects lasting several weeks [1, 4, 5]. -
Fire Hazard Analysis Techniques Chapter Contents Performing a Fire Morgan J
SECTION 3 Chapter 7 Fire Hazard Analysis Techniques Chapter Contents Performing a Fire Morgan J. Hurley Richard W. Bukowski Hazard Analysis Developing Fire Scenarios and Design Fire Scenarios vailable methods to estimate the potential impact of fire can be divided into two categories: Quantification of Design risk-based and hazard-based. Both types of methods estimate the potential consequences of Fire Scenarios A Prediction of Hazards possible events. Risk-based methods also analyze the likelihood of scenarios occurring, whereas hazard-based methods do not. Fire risk analysis is described more fully in Section 3, Chapter 8, “Fire Risk Analysis.” Section 3, Chapter 9, “Closed Form Enclosure Fire Calculations,” provides Key Terms simple fire growth calculation methods. bounding condition, design The goal of a fire hazards analysis (FHA) is to determine the expected outcome of a specific fire curve, design fire set of conditions called a fire scenario. The scenario includes details of the room dimensions, con- scenario, fire hazard tents, and materials of construction; arrangement of rooms in the building; sources of combustion analysis, fire model, fire air; position of doors; numbers, locations, and characteristics of occupants; and any other details scenario, performance- that have an effect on the outcome of interest. This outcome determination can be made by expert based design, t-squared fire judgment, by probabilistic methods using data from past incidents, or by deterministic means such as fire models. “Fire models” include empirical correlations, computer programs, full-scale and reduced-scale models, and other physical models. The trend today is to use models whenever pos- sible, supplemented if necessary by expert judgment. -
A Toxicological Review of the Products of Combustion
HPA-CHaPD-004 A Toxicological Review of the Products of Combustion J C Wakefield ABSTRACT The Chemical Hazards and Poisons Division (CHaPD) is frequently required to advise on the health effects arising from incidents due to fires. The purpose of this review is to consider the toxicity of combustion products. Following smoke inhalation, toxicity may result either from thermal injury, or from the toxic effects of substances present. This review considers only the latter, and not thermal injury, and aims to identify generalisations which may be made regarding the toxicity of common products present in fire smoke, with respect to the combustion conditions (temperature, oxygen availability, etc.), focusing largely on the adverse health effects to humans following acute exposure to these chemicals in smoke. The prediction of toxic combustion products is a complex area and there is the potential for generation of a huge range of pyrolysis products depending on the nature of the fire and the conditions of burning. Although each fire will have individual characteristics and will ultimately need to be considered on a case by case basis there are commonalities, particularly with regard to the most important components relating to toxicity. © Health Protection Agency Approval: February 2010 Centre for Radiation, Chemical and Environmental Hazards Publication: February 2010 Chemical Hazards and Poisons Division £15.00 Chilton, Didcot, Oxfordshire OX11 0RQ ISBN 978-0-85951- 663-1 This report from HPA Chemical Hazards and Poisons Division reflects understanding and evaluation of the current scientific evidence as presented and referenced in this document. EXECUTIVE SUMMARY The Chemical Hazards and Poisons Division (CHaPD) is frequently required to advise on the health effects arising from incidents due to fires. -
Argonne Report.Pdf
CONTENTS NOTATION ........................................................................................................................... xi ABSTRACT ........................................................................................................................... 1 1 INTRODUCTION ........................................................................................................... 5 1.1 Overview of the Emergency Response Guidebook ................................................ 5 1.2 Organization of this Report ..................................................................................... 7 2 GENERAL METHODOLOGY ....................................................................................... 9 2.1 TIH List ................................................................................................................... 10 2.1.1 Background ................................................................................................. 10 2.1.2 Changes in the TIH List for the ERG2012 ................................................. 11 2.2 Shipment and Release Scenarios ............................................................................ 11 2.2.1 Shipment Profiles ........................................................................................ 12 2.2.2 Treatment of Chemical Agents ................................................................... 14 2.3 Generics, Mixtures, and Solutions .......................................................................... 17 2.4 Analysis of Water-Reactive -
Health Aspects of Biological and Chemical Weapons
[cover] WHO guidance SECOND EDITION WORLD HEALTH ORGANIZATION GENEVA DRAFT MAY 2003 [inside cover] PUBLIC HEALTH RESPONSE TO BIOLOGICAL AND CHEMICAL WEAPONS DRAFT MAY 2003 [Title page] WHO guidance SECOND EDITION Second edition of Health aspects of chemical and biological weapons: report of a WHO Group of Consultants, Geneva, World Health Organization, 1970 WORLD HEALTH ORGANIZATION GENEVA 2003 DRAFT MAY 2003 [Copyright, CIP data and ISBN/verso] WHO Library Cataloguing-in-Publication Data ISBN xxxxx First edition, 1970 Second edition, 2003 © World Health Organization 1970, 2003 All rights reserved. The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the World Health Organization concerning the legal status of any country, territory, city or area or of its authorities, or concerning the delimitation of its frontiers or boundaries. Dotted lines on maps represent approximate border lines for which there may not yet be full agreement. The mention of specific companies or of certain manufacturers’ products does not imply that they are endorsed or recommended by the World Health Organization in preference to others of a similar nature that are not mentioned. Errors and omissions excepted, the names of proprietary products are distinguished by initial capital letters. The World Health Organization does not warrant that the information contained in this publication is complete and correct and shall not be liable for any damages incurred as a result of its use. Publications of the World Health Organization can be obtained from Marketing and Dissemination, World Health Organization, 20 Avenue Appia, 1211 Geneva 27, Switzerland (tel: +41 22 791 2476; fax: +41 22 791 4857; email: [email protected]). -
Medical Aspects of Chemical Warfare
Medical Diagnostics Chapter 22 MEDICAL DIAGNOSTICS † ‡ § BENEDICT R. CAPACIO, PHD*; J. RICHARD SMITH ; RICHARD K. GORDON, PHD ; JULIAN R. HAIGH, PHD ; JOHN ¥ ¶ R. BARR, PHD ; AND GENNADY E. PLATOFF JR, PHD INTRODUCTION NERVE AGENTS SULFUR MUSTARD LEWISITE CYANIDE PHOSGENE 3-QUINUCLIDINYL BENZILATE SAMPLE CONSIDERATIONS Summary * Chief, Medical Diagnostic and Chemical Branch, Analytical Toxicology Division, US Army Medical Research Institute of Chemical Defense, 3100 Rickets Point Road, Aberdeen Proving Ground, Maryland 21010-5400 † Chemist, Medical Diagnostic and Chemical Branch, Analytical Toxicology Division, US Army Medical Research Institute of Chemical Defense, 3100 Rickets Point Road, Aberdeen Proving Ground, Maryland 21010-5400 ‡ Chief, Department of Biochemical Pharmacology, Biochemistry Division, Walter Reed Army Institute of Research, 503 Robert Grant Road, Silver Spring, Maryland 20910-7500 § Research Scientist, Department of Biochemical Pharmacology, Biochemistry Division, Walter Reed Army Institute of Research, 503 Robert Grant Road, Silver Spring, Maryland 20910-7500 ¥ Lead Research Chemist, Centers for Disease Control and Prevention, 4770 Buford Highway, Mailstop F47, Atlanta, Georgia 30341 ¶ Colonel, US Army (Retired); Scientific Advisor, Office of Biodefense Research, National Institute of Allergies and Infectious Disease, National Institutes of Health, 6610 Rockledge Drive, Room 4069, Bethesda, Maryland 20892-6612 691 Medical Aspects of Chemical Warfare INTRODUCTION In the past, issues associated with chemical war- an -
Particularly Hazardous Substances
Particularly Hazardous Substances In its Laboratory Standard, OSHA requires the establishment of additional protections for persons working with "Particularly Hazardous Substances" (PHS). OSHA defines these materials as "select" carcinogens, reproductive toxins and acutely toxic materials. Should you wish to add: explosive, violently reactive, pyrophoric and water-reactve materials to this category, the information is included. Carbon nanotubes have also been added due to their suspected carcinogenic properties. This table is designed to assist the laboratory in the identification of PHS, although it is not definitively conclusive or entirely comprehensive. *Notes on the proper use of this table appear on page 12. 1 6 5 2 3 4 Substance CAS National Toxicity National Program Carcinogen Toxin Acute Regulated OSHA Carcinogen Group IARC Carcinogen Toxin Reproductive Violently Reactive/ Explosive/Peroxide Forming/Pyrophoric A-a-C(2-Amino-9H-pyrido[2,3,b]indole) 2648-68-5 2B Acetal 105-57-7 yes Acetaldehyde 75-07-0 NTP AT 2B Acrolein (2-Propenal) 107-02-8 AT Acetamide 126850-14-4 2B 2-Acetylaminofluorene 53-96-3 NTP ORC Acrylamide 79-06-6 NTP 2B Acrylyl Chloride 814-68-6 AT Acrylonitrile 107-13-1 NTP ORC 2B Adriamycin 23214-92-8 NTP 2A Aflatoxins 1402-68-2 NTP 1 Allylamine 107-11-9 AT Alkylaluminums varies AT Allyl Chloride 107-05-1 AT ortho-Aminoazotoluene 97-56-3 NTP 2B para-aminoazobenzene 60-09-3 2B 4-Aminobiphenyl 92-67-1 NTP ORC 1 1-Amino-2-Methylanthraquinone 82-28-0 NTP (2-Amino-6-methyldipyrido[1,2-a:3’,2’-d]imidazole) 67730-11-4 2B -
Ghs Reference Materials Health Hazard Criteria
APPENDIX F: GHS REFERENCE MATERIALS This appendix provides both an overview of GHS highly toxic hazard classification. A listing of Particularly Hazardous Substances that Carnegie Mellon University has published with their Chemical Hygiene plan is also provided as general reference. The list is useful cross check with GHS listings to determine which materials require prior approval for use BUT NO LIST IS COMPLETE you must check the SDS for possible additional chemicals rated as highly toxic. This appendix also provides the GHS (global harmonization system) for chemical hazard classification under the Hazard Communication Standard for highly toxic materials. This section provides overall information about categories under the classification of acute toxicity, mutagens’, reproductive and carcinogen hazards. When chemicals are rated on the GHS – Safety Data Sheet (SDS) as the following hazards then the PRIOR APPROVAL PROCESS WITH CHEMICAL HYGIENE OFFICER/COMMITTEE must be used: Acute toxicity category 1 and 2, Germ cell mutagenicity as a category 1A Substances known to induce heritable mutations in germ cells of humans and Category 1B: Substances which should be regarded as if they induce heritable mutations in the germ cells of humans, Reproductive Hazard as a category 1: Known or presumed human reproductive toxicants and Category 2; suspected human reproductive toxicant. Carcinogen as a Category 1 (includes 1A and 1B): Known or presumed human carcinogens, Category 2: Suspected human carcinogens. The Campus Chemical Hygiene Committee (Officer) must conduct a prior approval process. Appendix C Chemical Prior Approval Form on procedure for conducing prior approval. The following is from OSHA standard on the chemicals classifications that PCC Laboratory instructional operations shall use for defining the prior approval hazards. -
Safety Data Sheet
SAFETY DATA SHEET Creation Date 18-Apr-2011 Revision Date 19-Mar-2018 Revision Number 1 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identification Product Description: Misch metal Cat No. : 45589 Synonyms Misch metal cerium CAS-No 62379-61-7 Molecular Formula Ce Reach Registration Number - 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. Uses advised against No Information available 1.3. Details of the supplier of the safety data sheet Company Alfa Aesar . Avocado Research Chemicals, Ltd. Shore Road Port of Heysham Industrial Park Heysham, Lancashire LA3 2XY United Kingdom Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608 E-mail address [email protected] www.alfa.com Product Safety Department 1.4. Emergency telephone number Call Carechem 24 at +44 (0) 1865 407333 (English only); +44 (0) 1235 239670 (Multi-language) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture CLP Classification - Regulation (EC) No 1272/2008 Physical hazards Flammable solids Category 2 (H228) Substances/mixtures which, in contact with water, emit flammable gases Category 3 (H261) Health hazards Based on available data, the classification criteria are not met Environmental hazards Based on available data, the classification criteria are not met ______________________________________________________________________________________________ ALFAA45589 Page 1 / 9 SAFETY DATA SHEET Misch metal Revision Date 19-Mar-2018 ______________________________________________________________________________________________ 2.2. Label elements Signal Word Warning Hazard Statements H228 - Flammable solid H261 - In contact with water releases flammable gases May form combustible dust concentrations in air Precautionary Statements P231 + P232 - Handle under inert gas. -
United States Patent Office Patented Mar
3,171,249 United States Patent Office Patented Mar. 2, 1965 i 2 fuel rocket engine. The above and other objects of this 3,171,249 PROPELLANT AND Rick |PROPULSSON METH invention will become apparent from the discussion OXD EMPLOYANG EYERAZINE WITH AMSNO which follows. TETRAZOLES The objects of this invention are accomplished by the Ronald E. Be, Canoga Park, Calif., assigner to use of compounds having the general formula: North American Aviatiosa, Bac. No Drawing. Fied Nov. 29, 1961, Ser. No. 155,803 NH2. (R) 8 Clains. (C. 60-35.4) N This invention relates to a novel rocket propellant. YS More particularly, this invention relates to a novel in 10 N--H proved rocket propellant and a method of operating a wherein x varies from 0 to 1 and R is selected from the rocket engine. class consisting of HCl, H2O, HNO3, and HCIO, as addi The criterion by which rocket propellants are classi tives to a hydrazine-based rocket fuel in an amount suffi fied is specific impulse, Is, defined as thrust in pounds 5 cient to depress the freezing point at least 40° C. while divided by the total mass flow of fuel and oxidizer in retaining about the same density impulse and specific pounds per second. Specific impulse is thus given in impulse. Hence, an embodiment of this invention com units of "seconds.” Oxidizer-fuel propulsion system prises a method of operating a rocket engine comprising compositions with a relatively high specific impulse are ejecting from the reaction chamber of the engine a gaseous known in the art.