Leaded Avgas Safety Data Sheet According to Federal Register / Vol
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Leaded Avgas Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision Date : 01/22/2014 Version : 1.0 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY 1.1. Product Identifier Product Form: Mixture Product Name: Leaded Avgas Synonyms: Avgas; Avgas100LL; Aviation Gasoline; Avgas 100LL; DOT - Gasoline, 3, II Product Group: Commercial product 1.2. Intended Use of the Product Use of the Substance/Mixture: Aviation fuel. For professional use only. 1.3. Name, Address, and Telephone of the Responsible Party Customer EPIC Aviation, LLC P.O. Box 12249 Salem, OR 97309 T 866-501-3742 www.EPICaviationllc.com 1.4. Emergency Telephone Number Emergency Number : Within USA and Canada: 800-424-9300 Outside USA and Canada: +1 703-527-3887 (Collect Calls Accepted) For Chemical Emergency, Spill, Leak, Fire, Exposure, or Accident, call CHEMTREC – Day or Night SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flam. Liq. 1 H224 Skin Irrit. 2 H315 Eye Irrit. 2A H319 Muta. 1B H340 Carc. 1A H350 Repr. 1A H360 STOT SE 3 H336 STOT RE 1 H372 Asp. Tox. 1 H304 Aquatic Acute 2 H401 Aquatic Chronic 2 H411 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) : GHS02 GHS07 GHS08 GHS09 Signal Word (GHS-US) : Danger Hazard Statements (GHS-US) : H224 - Extremely flammable liquid and vapor H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness H340 - May cause genetic defects H350 - May cause cancer H360 - May damage fertility or the unborn child 01/22/2014 EN (English US) 1/21 Leaded Avgas Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations H372 - Causes damage to organs (lung/respiratory system) through prolonged or repeated exposure H401 - Toxic to aquatic life H411 - Toxic to aquatic life with long lasting effects Precautionary Statements (GHS-US) : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical, lighting, ventilating equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P260 - Do not breathe fume, mist, spray, vapors. P264 - Wash hands and forearms thoroughly after handling. P270 - Do no eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P280 – Wear protective gloves, protective clothing, eye protection, face protection, respiratory protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P302+P352 - IF ON SKIN: Wash with plenty of soap and water P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - If exposed or concerned: Get medical advice/attention P312 - Call a POISON CENTER or doctor if you feel unwell P314 - Get medical advice and attention if you feel unwell P321 - Specific treatment (see section 4) P331 - If swallowed, do NOT induce vomiting P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362 - Take off contaminated clothing P370+P378 - In case of fire: Use Dry chemical, water spray, regular foam for extinction P391 - Collect spillage P403+P233 - Store in a well-ventilated place. Keep container tightly closed P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P501 - Dispose of contents/container to local, regional, national, and international regulations 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Flammable vapors can accumulate in head space of closed systems. Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. 2.4. Unknown Acute Toxicity (GHS-US) No data available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Not applicable 3.2. Mixtures Name Product Identifier % Classification (GHS-US) Naphtha, petroleum, full-range (CAS No) 68527-27-5 70 - 100 Flam. Liq. 1, H224 alkylate, butane-containing Skin Irrit. 2, H315 01/22/2014 EN (English US) 2/21 Leaded Avgas Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Muta. 1B, H340 Carc. 1B, H350 Repr. 2, H361 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Acute 2, H401 Aquatic Chronic 2, H411 Toluene (CAS No) 108-88-3 0 - 20 Flam. Liq. 2, H225 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Repr. 2, H361 STOT SE 3, H336 STOT RE 2, H373 Asp. Tox. 1, H304 Aquatic Acute 2, H401 Hexane (CAS No) 110-54-3 0 - 1 Flam. Liq. 2, H225 Skin Irrit. 2, H315 Repr. 2, H361 STOT SE 3, H336 STOT RE 2, H373 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 Benzene (CAS No) 71-43-2 0 - 1 Flam. Liq. 2, H225 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Muta. 1B, H340 Carc. 1A, H350 STOT RE 1, H372 Asp. Tox. 1, H304 Aquatic Acute 2, H401 Tetraethyllead (CAS No) 78-00-2 < 0.1 Acute Tox. 1 (Oral), H300 Acute Tox. 1 (Dermal), H310 Acute Tox. 1 (Inhalation), H330 Acute Tox. 1 (Inhalation:vapour), H330 Carc. Not classified Repr. 1A, H360 STOT RE 2, H373 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 1,2-Dibromoethane (CAS No) 106-93-4 0 - 0.04 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation:dust,mist), H331 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Carc. 1B, H350 STOT SE 3, H335 Aquatic Acute 2, H401 Full text of H-phrases: see section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General : If medical advice is needed, have product container or label at hand. First-aid Measures After Inhalation : If inhaled, remove to fresh air and keep at rest in a position comfortable for breathing. If not breathing, give artificial respiration. Obtain medical attention if breathing difficulty persists. 01/22/2014 EN (English US) 3/21 Leaded Avgas Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations First-aid Measures After Skin Contact : Wash immediately with plenty of soap and water. Seek medical attention if ill effect or irritation develops. In case of contact, remove contaminated clothing and shoes. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact : Immediately rinse with water for a prolonged period while holding the eyelids wide open. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice and attention. First-aid Measures After Ingestion : If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Irritation to eyes, skin and respiratory tract. Vapors may cause drowsiness and dizziness. May be fatal if swallowed and enters airways. May cause cancer. May damage fertility. May damage the unborn child. May cause heritable genetic damage. Causes damage to organs through prolonged or repeated exposure. Symptoms/Injuries After Inhalation: Overexposure may be irritating to the respiratory system. High concentration of vapours may induce: headache, dizziness, drowsiness, nausea and vomiting. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes eye irritation. Symptoms/Injuries After Ingestion: Abdominal pain. Diarrhea. Vomiting. Nausea. May be fatal if swallowed and enters airways. Chronic Symptoms: May cause damage to central nervous sysyem and respiratory system. May cause cancer. Suspected of damaging fertility. Suspected of damaging the unborn child. Chronic exposure causes liver and kidney damages. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Dry chemical, carbon dioxide, or regular foam. Water spray. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Vapours are heavier than air and may travel considerable distance to an ignition source and flash back to source of vapours. Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or below ground level. Exposed to ignition source, vapours can burn in open / explode if confined. Under conditions of fire this material may produce: Carbon monoxide. Carbon dioxide (CO2). Low molecular weight hydrocarbon fragments. Smoke. Extremely flammable liquid and vapor. Explosion Hazard: Exposed to ignition source, vapours can burn in open / explode if confined. Reactivity: Stable at ambient temperature and under normal conditions of use. 5.3. Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Use water spray or fog for cooling exposed containers. In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Other information: Do not allow the product to be released into the environment.