Iterations of Ytterbium Alasdair Skelton and Brett F
Total Page：16
File Type：pdf, Size：1020Kb
in your element Iterations of ytterbium Alasdair Skelton and Brett F. Thornton examine the twisting path through the several discoveries of ytterbium, from the eighteenth century to the present. lthough ytterbium was named by the the Latin name for Paris — with atomic Swiss chemist Jean de Marignac in weights of approximately 170 and 174 g mol–1, A1878, his ‘element’ was subsequently respectively. Urbain claimed that Welsbach split into two in 1905: ytterbium and lutetium. had no more than rediscovered these elements, The atomic weight of the ‘new’ ytterbium referring to Welsbach’s 1905 discovery as was later published in 1907 — so when was non-quantitative and lacking proof. In 1909, ytterbium actually discovered? The story the International Committee on Atomic begins on 13 June 1726, more than 150 years Weights — which included Urbain — favoured before it first received its name. On that date Urbain’s nomenclature, listing7 neo-ytterbium an agreement was signed allowing the Dutch and lutetium with atomic weights of 172 and tin-glazed imitation of porcelain (faience) 174 g mol–1, respectively. The neo-ytterbium to be produced in Sweden, which led to name was short-lived, however, and Marignac’s German alchemist, Johann Wolff, establishing original ‘ytterbium’ was soon reinstated. a ‘porcelain’ factory in Rörstrand Castle in Considering that Welsbach had earlier turned Stockholm. In the late 1700s, the factory one element discovery into two (neodymium began producing flintware (an improved and praesodymium) by renaming the major product invented by Josiah Wedgwood), component of didymium ‘neodymium’, it must leading to a need for feldspar. Rörstrand Ytterby mine minerals. Bottom-left: rare earth have been frustrating for Urbain that he was purchased a quartz and feldspar mine located containing black biotite veins in quartz. prevented from doing the same. 20 km away in Ytterby, a village probably Bottom-right, 20 cm orange feldspar crystal. Like many lanthanides, ytterbium is a named for its location on the seaward Photographs courtesy of Emma Sofia Karlsson. relatively lesser-studied element. It is used as (den yttre) side of Resarö, a small island in a strengthening agent in stainless steel; and Stockholm’s archipelago. because it becomes semi-conductive at high In 1788, Reinhold Geijer: chemist, Yttersten, or gadolinite, is now known to have pressure, ytterbium has been used to make mineralogist and then owner of Rörstrand the general formula FeBe2Y2Si2O10, though the stress gauges. Also, its radioactive isotope porcelain factory published a letter1 describing ‘Y’ would prove to be quite complex. (169Yb) is used in portable X-ray machines. A a black non-magnetic mineral with a specific In the decades that followed it became more recent application is in atomic clocks, gravity of 4.223, which had been found in clear that yttria was much more than an where using ultra-cold 174Yb promises an the Ytterby mine by an amateur geologist, oxide of yttrium. In 1843 it was found to accuracy exceeding one second in 50 billion Carl Axel Arrhenius. Arrhenius had also sent contain oxides of erbium and terbium too. years8 — over ten times the age of the Earth. a sample of this mineral to Johan Gadolin, Then, in 1878, Marignac isolated ytterbia Thus, Marignac’s ytterbium from Ekeberg’s professor at Åbo Akademi in Finland. Gadolin from yttria4, which he claimed to be the oxide yttria may find its way into global navigation performed a series of experiments on this of a new trivalent element, ytterbium, with and communication systems, and might mineral and found that it contained 31 parts an atomic weight of 172 g mol–1. However, ultimately aid in redefining the SI second8. ❐ silica, 19 parts alumina (in reality beryllia), in Austria in 1899, Franz Exner and 12 parts iron oxide and 38 parts of an Eduard Haschek presented spectroscopic ALASDAIR SKELTON and unknown earth (or oxide, in modern terms)2. evidence suggesting that ytterbium was not BRETT F. THORNTON are in In 1797, Anders Gustaf Ekeberg, a one substance. Six years later, also in Austria, the Department of Geological Sciences, chemist from Uppsala, re-analysed a purer Carl Auer von Welsbach used fractional Stockholm University, 106 91 sample and showed that Gadolin had crystallization to split Marignac’s ytterbium Stockholm, Sweden. overestimated the silica and alumina content into two elements, which he distinguished e-mail: [email protected]; and underestimated the proportion of new on the basis of emission spectra and called [email protected] earth, of which he found 47.5 parts — he also aldebaranium and cassiopeium. He published5 noted its disgusting taste3! He proposed the atomic weights of 172.90 and 174.23 g mol–1 References name yttersten (ytter-rock) for the mineral, for these elements in December 1907. 1. Geijer, B. R. Crells Ann. 229–230 (1788). 2. Gadolin, J. K. Vet. Akad. Handl. 15, 137–155 (1794). and the Swedish and Latin names ytterjord Forty-four days before Welsbach published 3. Ekeberg, A. G. K. Vet. Akad. Handl. 18, 156–164 (1797). (ytter-earth) and yttria for the new earth. his finding, Georges Urbain announced6 to 4. de Marignac J.‑C. G. Arch. Sci. Phys. Nat. 64, 97–107 (1878). the Paris Academy that he had separated 5. Welsbach, C. Monatsh. Chem. 29, 181–225 (1908). 6. Urbain, G. C. R. Acad. Sci. 145, 759–762 (1907). ytterbium into two elements, which he called 7. Clarke, F. W. et al. J. Am. Chem. Soc. 31, 1–6 (1909). neo-ytterbium, and lutecium — after Lutetia, 8. Hinkley, N. et al. Science 341, 1215–1218 (2013). Ho Er Tm Yb Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr 402 NATURE CHEMISTRY | VOL 9 | APRIL 2017 | www.nature.com/naturechemistry ©2017 Mac millan Publishers Li mited, part of Spri nger Nature. All ri ghts reserved. .