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(12) United States Patent (10) Patent No.: US 8,186,995 B2 Putrello, Jr
US008186995B2 (12) United States Patent (10) Patent No.: US 8,186,995 B2 Putrello, Jr. (45) Date of Patent: May 29, 2012 (54) SURVIVAL TOOL FIRE STARTER WITH 148/404; 44/507,506, 508; 280/87.042: MISCHMETAL FLINTROD 126/25 B; 149/38, 41,42; 7/158 See application file for complete search history. (76) Inventor: Andrew C. Putrello, Jr., Utica, NY (US) (56) References Cited (*) Notice: Subject to any disclaimer, the term of this U.S. PATENT DOCUMENTS patent is extended or adjusted under 35 2,908,071 A * 10/1959 Bungardt ...................... 428,585 U.S.C. 154(b) by 765 days. 3,275,484. A * 9, 1966 Foote et al. ..................... 149,38 3.278,009 A * 10/1966 Crump, Jr. .................... 206,121 4,089,706 A 5/1978 Zeiringer (21) Appl. No.: 12/392,535 4,698,068 A * 10/1987 Jensen ............................ 44,507 6,782.576 B1 8, 2004 Valencic et al. (22) Filed: Feb. 25, 2009 2005/O127630 A1* 6/2005 Kuhlman et al. ........ 280/87.042 (65) Prior Publication Data * cited by examiner US 2009/0214996 A1 Aug. 27, 2009 Primary Examiner — Steven B McAllister Assistant Examiner — Avinash Savani Related U.S. Application Data (74) Attorney, Agent, or Firm — Hiscock & Barclay, LLP (63) Continuation-in-part of application No. 12/070,741, (57) ABSTRACT filed on Feb. 22, 2008. A fire-starter device for Survival or emergency use has a (51) Int. C. handle portion and case portion that twist together, to sheath a mischmetal flint rod inside the case, and a seal ring protects F23O I/02 (2006.01) the flint rod from environmental moisture. -
Historical Development of the Periodic Classification of the Chemical Elements
THE HISTORICAL DEVELOPMENT OF THE PERIODIC CLASSIFICATION OF THE CHEMICAL ELEMENTS by RONALD LEE FFISTER B. S., Kansas State University, 1962 A MASTER'S REPORT submitted in partial fulfillment of the requirements for the degree FASTER OF SCIENCE Department of Physical Science KANSAS STATE UNIVERSITY Manhattan, Kansas 196A Approved by: Major PrafeLoor ii |c/ TABLE OF CONTENTS t<y THE PROBLEM AND DEFINITION 0? TEH-IS USED 1 The Problem 1 Statement of the Problem 1 Importance of the Study 1 Definition of Terms Used 2 Atomic Number 2 Atomic Weight 2 Element 2 Periodic Classification 2 Periodic Lav • • 3 BRIEF RtiVJiM OF THE LITERATURE 3 Books .3 Other References. .A BACKGROUND HISTORY A Purpose A Early Attempts at Classification A Early "Elements" A Attempts by Aristotle 6 Other Attempts 7 DOBEREBIER'S TRIADS AND SUBSEQUENT INVESTIGATIONS. 8 The Triad Theory of Dobereiner 10 Investigations by Others. ... .10 Dumas 10 Pettehkofer 10 Odling 11 iii TEE TELLURIC EELIX OF DE CHANCOURTOIS H Development of the Telluric Helix 11 Acceptance of the Helix 12 NEWLANDS' LAW OF THE OCTAVES 12 Newlands' Chemical Background 12 The Law of the Octaves. .........' 13 Acceptance and Significance of Newlands' Work 15 THE CONTRIBUTIONS OF LOTHAR MEYER ' 16 Chemical Background of Meyer 16 Lothar Meyer's Arrangement of the Elements. 17 THE WORK OF MENDELEEV AND ITS CONSEQUENCES 19 Mendeleev's Scientific Background .19 Development of the Periodic Law . .19 Significance of Mendeleev's Table 21 Atomic Weight Corrections. 21 Prediction of Hew Elements . .22 Influence -
The Rare Earths II
Redis co very of the Elements The Ra re Earth s–The Con fusing Years I A gallery of rare earth scientists and a timeline of their research I I James L. Marshall, Beta Eta 1971 , and Virginia R. Marshall, Beta Eta 2003 , Department of Chemistry, University of North Texas, Denton, TX 76203-5070, [email protected] The rare earths after Mosander. In the pre - vi ou s HEXAGON “Rediscovery” article, 1p we were introduced to the 17 rare earths, found in the f-block and the Group III chemical family of Figure 1. Important scientists dealing with rare earths through the nineteenth century. Johan Gadolin the Periodic Table. Because of a common (1760 –1852) 1g —discovered yttrium (1794). Jöns Jacob Berzelius (1779 –1848) and Martin Heinrich valence electron configuration, the rare earths Klaproth (1743 –1817) 1d —discovered cerium (1803). Carl Gustaf Mosander (1787 –1858) 1p —discovered have similar chemical properties, and their lanthanum (1839), didymium (1840), terbium, and erbium (1843). Jean-Charles deGalissard Marignac chemical separation from one another can be (1817 –1894) 1o —discovered ytterbium (1878) and gadolinium (1880). Per Teodor Cleve (1840 –1905) 1n — difficult. From preparations of the first two rare discovered holmium and thulium (1879). Lars Fredrik Nilson (1840 –1899) 1n —discovered scandium earth element s—yttrium and ceriu m—the (1879). Paul-Émile Lecoq de Boisbaudran (1838 –1912) —discovered samarium (1879) and dysprosium Swedish chemist Carl Gustaf Mosander (Figure (1886). 1b Carl Auer von Welsbach (1858 –1929) 1c —discovered praseodymium and neodymium (1885); 1, 2) was able to separate four additional ele - co-discovered lutetium (1907). -
Rounding up Lutetium
Rounding up lutetium Downloaded from: https://research.chalmers.se, 2019-05-11 19:07 UTC Citation for the original published paper (version of record): Öhrström, L. (2018) Rounding up lutetium Nature Chemistry, 10(3): 372- http://dx.doi.org/10.1038/nchem.2938 N.B. When citing this work, cite the original published paper. research.chalmers.se offers the possibility of retrieving research publications produced at Chalmers University of Technology. It covers all kind of research output: articles, dissertations, conference papers, reports etc. since 2004. research.chalmers.se is administrated and maintained by Chalmers Library (article starts on next page) in your element Rounding up lutetium Lars Öhrström suspects that as time goes by, we may see more of lutetium — the last of the lanthanoids. e’ll always have Paris” Rick says motexafn (based on the ‘texaphyrins’), a “ to Ilsa in their fnal goodbye on sub-class of porphyrin-like macrocycles Wthe foggy airstrip of Casablanca with fve instead of four nitrogen atoms in in the eponymous flm. However, the an approximately planar ring. Motexafn question among chemists about the element lutetium, which features Lu3+ and two lutetium, named afer Lutetia, as the French acetate counter-ions coordinated on either capital was known in Roman times, is not so side of the macrocycle, is potentially a good much about having it (it is more abundant photosensitizer in dynamic phototherapy than silver in the Earth’s crust), but rather and has been going through phase I trials where to place it on the map. against prostate cancer2. With its valence electron confguration Uses of the naturally occurring element [Xe]4f 146s25d1, element 71 seems to belong are otherwise scarce, but its isotope Lu-177 is to group 3, but we ofen see it placed at successfully used in experimental and clinical BRITTA LANGEN, LANGEN, BRITTA SWEDEN UNIVERSITY OF GOTHENBURG, the very end of the lanthanoid series. -
Preliminary Estimates of the Quantities of Rare-Earth Elements Contained in Selected Products and in Imports of Semimanufactured Products to the United States, 2010
Preliminary Estimates of the Quantities of Rare-Earth Elements Contained in Selected Products and in Imports of Semimanufactured Products to the United States, 2010 By Donald I. Bleiwas and Joseph Gambogi Open-File Report 2013–1072 U.S. Department of the Interior U.S. Geological Survey U.S. Department of the Interior KEN SALAZAR, Secretary U.S. Geological Survey Suzette M. Kimball, Acting Director U.S. Geological Survey, Reston, Virginia: 2013 For more information on the USGS—the Federal source for science about the Earth, its natural and living resources, natural hazards, and the environment—visit http://www.usgs.gov or call 1–888–ASK–USGS For an overview of USGS information products, including maps, imagery, and publications, visit http://www.usgs.gov/pubprod To order other USGS information products, visit http://store.usgs.gov Suggested citation: Bleiwas, D.I., and Gambogi, Joseph, 2013, Preliminary estimates of the quantities of rare-earth elements contained in selected products and in imports of semimanufactured products to the United States, 2010: U.S. Geological Survey Open–File Report 2013–1072, 14 p., http://pubs.usgs.gov/of/2013/1072/. Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government. Although this information product, for the most part, is in the public domain, it also may contain copyrighted materials as noted in the text. Permission to reproduce copyrighted items must be secured from the copyright owner. Cover. Left: Aerial photograph of Molycorp, Inc.’s Mountain Pass rare-earth oxide mining and processing facilities in Mountain Pass, California. -
GLOBAL RARE-EARTH PRODUCTION: HISTORY and OUTLOOK History – the Discovery
Center for Strategic and International Studies Rare Earth Elements: Geology, Geography, and Geopolitics James B. Hedrick Hedrick Consultants, Inc. U.S. Rare Earths, Inc. Burke, Virginia December 15, 2010 Washington, DC GLOBAL RARE-EARTH PRODUCTION: HISTORY AND OUTLOOK History – The Discovery . The rare earths were discovered in 1787 by Swedish Army Lieutenant Carl Axel Arrhenius . Carl, an amateur mineralogist collected the black mineral ytterbite, later renamed gadolinite, from a small feldspar and quartz mine at Ytterby, Sweden . With similar chemical structures the rare earths proved difficult to separate . It was not until 1794 that Finnish chemist Johann Gadolin separated the first impure yttrium oxide from the mineral ytterbite History – The Discovery History – The Commercialization . The rare earths were commercialized when the incandescent lamp mantle industry was established in 1884 with mantles of zirconium, lanthanum, and yttrium oxides with later improvements requiring only the oxides of thorium and cerium. The lamp mantle was discovered by Baron Carl Auer von Welsbach . The mantles also used small amounts of neodymium and praseodymium as an indelible brand name Welsbach label History – The Early Mining . Rare earths were first produced commercially in the 1880s with the mining in Sweden and Norway of the rare-earth thorium phosphate mineral monazite . Foreign Production Brazil produced monazite as early as 1887 India produced monazite starting in 1911 . Domestic Production Monazite production in the United States was first recorded in 1893 in North Carolina - a small tonnage of monazite was reportedly mined in 1887 Monazite mining in South Carolina began in 1903 History – The Processing . Three main methods for separating and refining the rare- earth elements since they were discovered . -
Transmittal of Draft EIR for Molycorp Mountain Pass Mine Expansion, for Review and Comment
COUNTY OF SAN BERNARDINO PLANNING DEPARTMENT I,regular-! I PUBLIC WORKS GROUP -- W&- Sw1. NENNO lorth Arrowhead Avenue * San Bernardino, CA 924154182 * (909) 3874131 VALERY PILMER Director of Planning December 9, 1996No. 909) 3873223 IY RESPONSIBLE AND TRUSTEE AGENCIES INTERESTED ORGANIZATIONS AND INDIVIDUALS RE: NOTICE OF AVAILABILITY FOR THE DRAFT EIR ON THE MOLYCORP MOUNTAIN PASS MINE EXPANSION Dear Reader/Reviewer: Enclosed for your review and comment is the Draft EIR for the Molycorp Mountain Pass Mine Expansion. The purpose of the document is to identify and describe the probable environmental impacts that would result from the proposed expansion of Molycorp's existing mine and processing plant complex located at Mountain Pass, California. Mountain Pass is within the unincorporated portion San Bernardino County along Interstate 15 approximately 30 miles northeast of Baker and approximately 14 miles southwest of the Nevada stateline. The proposed quarry and waste rock areas would add 696 acres of disturbance to the existing mine site, resulting in a total disturbed area of approximately 1,044 acres. sag_> This document has been prepared to meet the State requirements of the California Environmental Quality Act. The Draft EIR has been prepared under the supervision of the County of San Bernardino Planning Department. The public comment period will end on January 27, 1997. Written comments should be addressed to: County of San Bemnardino- Planning Dgparnn 385 N. Arrowhead Avenue, Third Floor San Bernardino, CA 92415-0182 Attn: Randy Scott Sincerely, Randy Scottjlanning Manager, San Berardo County Planning Department ~-! - nLA ,;;K Scr.'Eperviscs .,* 1:,. 3 - -, I- . 1 12 4~ ..!A','V34-' TUrCCI Vi~i D;s~ri:n, BARBA~RA CPANM FURtOPAN . -
Critical Materials and US Import Reliance
Testimony Critical Materials and U.S. Import Reliance Recent Developments and Recommended Actions Richard Silberglitt CT-485 Testimony presented before House Natural Resources Committee, Subcommittee on Energy and Mineral Resources on December 12, 2017. For more information on this publication, visit www.rand.org/pubs/testimonies/CT485.html Testimonies RAND testimonies record testimony presented or submitted by RAND associates to federal, state, or local legislative committees; government-appointed commissions and panels; and private review and oversight bodies. Published by the RAND Corporation, Santa Monica, Calif. © Copyright 2017 RAND Corporation is a registered trademark. Limited Print and Electronic Distribution Rights This document and trademark(s) contained herein are protected by law. This representation of RAND intellectual property is provided for noncommercial use only. Unauthorized posting of this publication online is prohibited. Permission is given to duplicate this document for personal use only, as long as it is unaltered and complete. Permission is required from RAND to reproduce, or reuse in another form, any of its research documents for commercial use. For information on reprint and linking permissions, please visit www.rand.org/pubs/permissions.html. www.rand.org Critical Materials and U.S. Import Reliance: Recent Developments and Recommended Actions Testimony of Richard Silberglitt1 The RAND Corporation2 Before the Committee on Natural Resources Subcommittee on Energy and Mineral Resources United States House of Representatives December 12, 2017 hank you Chairman Gosar, Ranking Member Lowenthal, and distinguished members of the Subcommittee for inviting me to testify today. My testimony is based on the results of a 2013 study conducted by the RAND Corporation at the request of the National T 3 Intelligence Council, taking into account relevant developments and data since the publication of that report. -
Rounding up Lutetium Lars Öhrström Suspects That As Time Goes By, We May See More of Lutetium — the Last of the Lanthanoids
in your element Rounding up lutetium Lars Öhrström suspects that as time goes by, we may see more of lutetium — the last of the lanthanoids. e’ll always have Paris” Rick says motexafin (based on the ‘texaphyrins’), a “ to Ilsa in their final goodbye on sub-class of porphyrin-like macrocycles Wthe foggy airstrip of Casablanca with five instead of four nitrogen atoms in in the eponymous film. However, the an approximately planar ring. Motexafin question among chemists about the element lutetium, which features Lu3+ and two lutetium, named after Lutetia, as the French acetate counter-ions coordinated on either capital was known in Roman times, is not so side of the macrocycle, is potentially a good much about having it (it is more abundant photosensitizer in dynamic phototherapy than silver in the Earth’s crust), but rather and has been going through phase I trials where to place it on the map. against prostate cancer2. With its valence electron configuration Uses of the naturally occurring element [Xe]4f 146s25d1, element 71 seems to belong are otherwise scarce, but its isotope Lu-177 is to group 3, but we often see it placed at successfully used in experimental and clinical BRITTA LANGEN, BRITTA SWEDEN UNIVERSITY OF GOTHENBURG, the very end of the lanthanoid series. Its treatments against some severe cancers by downstairs neighbour lawrencium, for which Illustration of a radiolabelled somatostatin hooking it up to a tetraazacyclododecane- experimental data are much more difficult to analogue built using PyMOL (https://pymol.org) tetraacetate (DOTA) ligand grafted to obtain, is in the same ambiguous situation. -
RBRC-32 BNL-6835.4 PARITY ODD BUBBLES in HOT QCD D. KHARZEEV in This ~A~Er We Give a Pedawwicalintroduction~0 Recent Work Of
RBRC-32 BNL-6835.4 PARITY ODD BUBBLES IN HOT QCD D. KHARZEEV RIKEN BNL Research Center, Br$ookhauenNational Laboratory, . Upton, New York 11973-5000, USA R.D. PISARSKI Department of Physics, Brookhaven National Laboratoy, Upton, New York 11973-5000, USA M.H.G. TYTGAT Seruice de Physique Th&orique, (7P 225, Uniuersitc4Libre de Bruzelles, B[ud. du !t%iomphe, 1050 Bruxelles, Belgium We consider the topological susceptibility for an SU(N) gauge theory in the limit of a large number of colors, N + m. At nonzero temperature, the behavior of the topological susceptibility depends upon the order of the reconfining phrrse transition. The meet interesting possibility is if the reconfining transition, at T = Td, is of second order. Then we argue that Witten’s relation implies that the topological suscepti~lfity vanishes in a calculable fdion at Td. Ae noted by Witten, this implies that for sufficiently light quark messes, metaetable etates which act like regions of nonzero O — parity odd bubbles — can arise at temperatures just below Td. Experimentally, parity odd bubbles have dramatic signature% the rI’ meson, and especially the q meson, become light, and are copiously produced. Further, in parity odd bubbles, processes which are normally forbidden, such as q + rr”ro, are allowed. The most direct way to detect parity violation is by measuring a parity odd global seymmetry for charged pions, which we define. 1 Introduction In this .-~a~er we give a Pedawwicalintroduction~0 recent work of ours? We I consider an SU(IV) gau”ge t~e~ry in the limit of a large number of colors, N + co, This is, of course, a familiar limit? We use the large N expansion I to investigate the behavior of the theory at nonzero temperature, especially for the topological susceptibility. -
Shark Deterrent and Incidental Capture Workshop April 10–11, 2008
NOAA Technical Memorandum NMFS-PIFSC-16 November 2008 Shark Deterrent and Incidental Capture Workshop April 10–11, 2008 Compiled and Edited by Yonat Swimmer, John H. Wang, and Lianne McNaughton Pacific Islands Fisheries Science Center National Marine Fisheries Service National Oceanic and Atmospheric Administration U.S. Department of Commerce About this document The mission of the National Oceanic and Atmospheric Administration (NOAA) is to understand and predict changes in the Earth=s environment and to conserve and manage coastal and oceanic marine resources and habitats to help meet our Nation=s economic, social, and environmental needs. As a branch of NOAA, the National Marine Fisheries Service (NMFS) conducts or sponsors research and monitoring programs to improve the scientific basis for conservation and management decisions. NMFS strives to make information about the purpose, methods, and results of its scientific studies widely available. NMFS= Pacific Islands Fisheries Science Center (PIFSC) uses the NOAA Technical Memorandum NMFS series to achieve timely dissemination of scientific and technical information that is of high quality but inappropriate for publication in the formal peer- reviewed literature. The contents are of broad scope, including technical workshop proceedings, large data compilations, status reports and reviews, lengthy scientific or statistical monographs, and more. NOAA Technical Memoranda published by the PIFSC, although informal, are subjected to extensive review and editing and reflect sound professional work. Accordingly, they may be referenced in the formal scientific and technical literature. A NOAA Technical Memorandum NMFS issued by the PIFSC may be cited using the following format: Swimmer, Y, J. H. Wang, and L. McNaughton. -
Rare Earth Elements Deposits of the United States—A Summary of Domestic Deposits and a Global Perspective
The Principal Rare Earth Elements Deposits of the United States—A Summary of Domestic Deposits and a Global Perspective Gd Pr Ce Sm La Nd Scientific Investigations Report 2010–5220 U.S. Department of the Interior U.S. Geological Survey Cover photo: Powders of six rare earth elements oxides. Photograph by Peggy Greb, Agricultural Research Center of United States Department of Agriculture. The Principal Rare Earth Elements Deposits of the United States—A Summary of Domestic Deposits and a Global Perspective By Keith R. Long, Bradley S. Van Gosen, Nora K. Foley, and Daniel Cordier Scientific Investigations Report 2010–5220 U.S. Department of the Interior U.S. Geological Survey U.S. Department of the Interior KEN SALAZAR, Secretary U.S. Geological Survey Marcia K. McNutt, Director U.S. Geological Survey, Reston, Virginia: 2010 For product and ordering information: World Wide Web: http://www.usgs.gov/pubprod Telephone: 1-888-ASK-USGS For more information on the USGS—the Federal source for science about the Earth, its natural and living resources, natural hazards, and the environment: World Wide Web: http://www.usgs.gov Telephone: 1-888-ASK-USGS Any use of trade, product, or firm names is for descriptive purposes only and does not imply endorsement by the U.S. Government. This report has not been reviewed for stratigraphic nomenclature. Although this report is in the public domain, permission must be secured from the individual copyright owners to reproduce any copyrighted material contained within this report. Suggested citation: Long, K.R., Van Gosen, B.S., Foley, N.K., and Cordier, Daniel, 2010, The principal rare earth elements deposits of the United States—A summary of domestic deposits and a global perspective: U.S.