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Oct. 14, 1958 J. M. CARTER ET AL 2,856,263 PROCESS for the RECOVERY and PURIFICATION of URANIUM DEPOSITS Original Filed April 21, 1944 ‘7 Sheets-Sheet 1
Oct. 14, 1958 J. M. CARTER ET AL 2,856,263 PROCESS FOR THE RECOVERY AND PURIFICATION OF URANIUM DEPOSITS Original Filed April 21, 1944 ‘7 Sheets-Sheet 1 IN VEN TORS James M Car/‘er Mar?n D. ?ame/7 BY ATTORNEY Oct. 14, 1958 J. M. CARTER ET AL 2,856,263 PROCESS FOR THE RECOVERY AND PURIFICATION OF URANIUM DEPOSITS Original Filed April 21, 1944 7 Sheets-Sheet 55 QQOUMM,vRMmG w.9386mmE IN VEN TORS James M. Car fer By Marfin 0 Home/7 W4 W ATTORNEY Oct. 14,1958 J. M. CARTER ET AL 2,856,263 PROCESS FOR THE RECOVERY AND PURIFICATION _ OF URANIUM DEPOSITS Origlnal Filed April 21, 1944 7 Sheets-Sheet 4 SCRUBBYING. AND WASHING PARTS OF CALUTRON ' WITH HOT WATER Lf- WASH WATER :FCONDENSATE ' \WATERANDMAKE UP snevmc SOL/D IMPUR/ TIES — WASH WA TER -—p>- CONDENSING To DISCARD I OXIDIZING ORSALVAGE SOLUTION U02” Cu?! Few’! Cr!!! Ni“ FILTERING‘ - '3 PREC/P/TATE 0* |——‘———/ F/LTRA TE _ U024!- TO DISCARD __ EVAPORATING gel”,++ OR SALVAGE PRECIPITATING Z/VH OH AND F'LTER'NG gFlLTRA TE TO FURTHER T REATMENT Fig. 4 I INVENTORS ‘James M Cor fer, BY Mar/7'0 D. Kama/7 ' @ M A TTORNEY Oct. 14,1958 J. M. CARTER ET AL . 2,356,263 PROCESS FOR THE RECOVERY AND PURIFICATION 0F URANIUM DEPOSITS Original Filed April 21, 1944 7 Sheets-Sheet s DISSOLVING URANIUM METAL DEPOSITED ON COPPER COLLECTOR IN COLD HNo3 (8N) CONDENSATE I AND MAKE UP SOLUTION HNO3 U02" ' Cu ** 7—>— CONDENSING ' HN03 . EVAPORATI NG CONCENTRA TED \ soburj'o/v _ F/LTRA TE C35 cu {NHJLF H PRECIPITATING ‘ -[—-~’—NH4OH A ND F ILTERING ' f/RECIP/ TA TES *Cu/‘OHZH4 :0 01 ORTO SALVAGEDISCARD *Trace T__>_ DISSOLVING HN 0 3 ' - SOLUTION U02 +4 *cuvf *Tme F/LTRA TE PRECIPITATING _l—_'_NH OH AND FILTERING 4 { PREClP/TATE NH U 0 TO DISCARD ( ‘)2 2 ’ OR SALVAGE , r---‘“—? TO FURTHER TREATMENT 5 I N V EN TORS' James M Car/‘er ' Mar/"in D. -
ORGANOMETAT,T,TC CHEMISTRY of URANIUM a Thesis Submitted By
ORGANOMETAT,T,TC CHEMISTRY OF URANIUM A thesis submitted by R1TN R. SIGURDSON, B.Sc. for the DEGREE of DOCTOR of PHILOSOPHY of the UNIVERSITY of LONDON Royal College of Science Imperial College of Science and Technology London, SW7 ?AY August 1976 TO MY PARENTS 3 ACKNOWLEDGEMENTS I would like to express my gratitude to Professor Geoffrey Wilkinson, F.R.S. for his guidance and enthusiastic support throughout the course of this work. Many thanks are also extended to Drs. Dick Andersen, Ernesto Carmona-Guzman and David Cole-Hamilton for their suggestionS, encouragement and advice, and to Dr. Kostas Mertis for his patient help during the first months. I am indebted to the Canadian Research Council of Canada for financial support during the past three years. 4 CONTENTS ABSTRACT 6 INTRODUCTION I. The Chemistry of Uranium(IV) 8 .II. The Chemistry of Uranium(V) 15 III. The Chemistry of Uranium(VI) 16 CHAPTER I. DILITHIUMHEXAALKYLURANATE(IV) COMPLEXES I. Introduction 19 II. Results and Discussion 27 III. Experimental 35 CHAPTER II. TRILITHIUMOCTAALKYLURANATE(V) COMPLEXES I. Introduction 54 II. Results and Discussion 55 III. Experimental 60 CHAPTER III. ADDITION COMPOUNDS OF URANIUM(VI) HEXAISO-PROPDXIDE WITH LITHIUM, MAGNESIUM AND ALUMINIUM ALKYLS I. Introduction 70 II. Results and Discussion 71 III. Experimental 77 CHAPTER IV. ORGANOMETALLIC CHEMISTRY OF ADAMANTANE I. Introduction 84 II. Results and Discussion 85 III. Experimental 87 REFERENCES 92 5 ABBREVIATIONS Me - methyl Et - ethyl Prn- normal-propyl Pri- iso-propyl Bun- normal-butyl But- iso-butyl But- tertiary-butyl Ph - phenyl CP cyclopentadienyl DME - dimethoxyethane tmed - N,N,NI,N'-tetramethylethylenediamine pmdt - N,N,Nt,N",N"-pentamethyldiethylenetriamine g.l.c. -
1214 Final Report SF 10 03 06-CS
AN ASSESSMENT OF SOURCES, PATHWAYS, MECHANISMS AND RISKS OF CURRENT AND POTENTIAL FUTURE POLLUTION OF WATER AND SEDIMENTS IN GOLD-MINING AREAS OF THE WONDERFONTEINSPRUIT CATCHMENT Report to the WATER RESEARCH COMMISSION Compiled by Henk Coetzee Council for Geosience Reference to the whole of the publication should read: Coetzee, H. (compiler) 2004: An assessment of sources, pathways, mechanisms and risks of current and potential future pollution of water and sediments in gold-mining areas of the Wonderfonteinspruit catchment WRC Report No 1214/1/06, Pretoria, 266 pp. Reference to chapters/sections within the publication should read (example): Wade, P., Winde, F., Coetzee, H. (2004): Risk assessment. In: Coetzee, H (compiler): An assessment of sources, pathways, mechanisms and risks of current and potential future pollution of water and sediments in gold-mining areas of the Wonderfonteinspruit catchment. WRC Report No 1214/1/06, pp 119-165 WRC Report No 1214/1/06 ISBN No 1-77005-419-7 MARCH 2006 Executive summary 1. Introduction and historical background The eastern catchment of the Mooi River, also known as the Wonderfonteinspruit, has been identified in a number of studies as the site of significant radioactive and other pollution, generally attributed to the mining and processing of uraniferous gold ores in the area. With the establishment of West Rand Consolidated in 1887 gold mining reached the Wonderfonteinspruit catchment only one year after the discovery of gold on the Witwatersrand. By 1895 five more gold mines had started operations in the (non-dolomitic) headwater region of the Wonderfonteinspruit as the westernmost part of the West Rand goldfield. -
Personnel Monitoring
RADIOLOGICAL MONITORING, METHOD, INSTRUMENTATION AND TECHNIQUES: PERSONNEL MONITORING Agensi Nuklear Malaysia Contents Introduction Objective of Personnel Monitoring Personnel Monitoring Instrument for External Radiation Personnel Monitoring Instrument for Internal radiation Calibration and Quality Control Introduction Atomic Energy Licensing Regulations (BSS) 2010 (Act 304) require monitoring to be carried out on all personnel who work in controlled areas (and selectively in supervised areas). Occupational exposure can be delivered to personnel either by sources outside the body in the form of external radiation or by intake of radioactive contaminants. Atomic Energy Licensing Regulations (BSS) 2010 (Act 304) require the radiation exposures both from external and internal sources be evaluated to represent an individual dose in a year. A devices that is accepted by the AELB are required by all personnel to measure the radiation dose received while working with radiation sources or working in classified areas. Objective of Personnel Monitoring To provide information on radiation dose received by workers. To observe the trends of exposure histories of individuals or groups of workers in order to assess the need for improved standards of radiation protection. To provide information in the event of accidental over exposure. To provide information about the condition of radiation level at workplace. To improve the workers attitudes toward radiation protection in order to reduce future exposures as a results of information given to them. To demonstrate the adequacy of supervision, training and engineering standards. To provide a record of information which may be needed for legal or epidemiological purposes. Personal monitoring External monitoring Internal monitoring (the measurement of dose due to (the measurement of dose due to sources outside the body) sources inside the body) Whole body Partial body monitoring (extremity) 1. -
Matls Licensing Package for Amend 9 to License 34-25957-01 For
- k y$$f,$$$? u c A 2 1 1 eg 4 W 808 License number MATERIALS LICENSE j SUPPLEMENTARY SHEET 30 3073 I ( < Amendment No. 09 f>( l-i ' i M |4 (i Victoreen, Inc. (Delaware) j 6000 Cochran Road I q Solon, OH 44139-3395 In accordance with letter dated May 17, 1993,, license Number 34-25957-01 is amended as | Fj je follows: , ; [ [ t - - 4 y, ; . - i1" Conditions ll.C and 24. are amended *to read: k k(t , i < ~ ss j 11. C. The Radiation Saf(t) Officer for this license is B'arbara M. Kapsar. y C ~',f , , i |$ 24. Except as specifical.ly provided otherwise in this license, the licensee shall 4 conduct its program 5in accordance with the statementsr representations, and d procedures contain$d in the ddcu'ments, including ag 'ni;enclosuges,, listed below. The d U.S. Nuclear Regulatory Commission's regulatio'ns4 hall govern unless the statements, f representations,1and procedure's in'the' licensee q more restrictive than the regulations.'eJ. uj)ts:[ application'"and{ correspondence are A .. .x's e. N 4 A. Applications idated Jiarch 6,T.1985,1 Novemberf l6,1987, Augdit 3,1988 (with ,4 attachments),' August 331,1990;4Eeb'ruar' L6','1991'.(with attschments) and y ~ ,2; f October 8, 1991s (with" attachments)'; [inds , ,. .. D . ' h !q B. Letters dated 'J nuary 28,11983, Dec' W r -embe 16 ?)984, Mar'c5 6, 1985, May 31, 1985,. 4 March 12, 1986,-June 8, 1987, Decemberc9,*1987, January 13, 1988, March 11, k ~1988, March 28,1988, April 11, '1988,' -July 7,' 1988? August 3,1988, jj September 8,1988, Tune 9,1989, March 26,1996G{ebruary 25, 1991, May 17, g ! 1993 and June 15, 1993. -
1968 Technical Highlights of the National Bureau of Standards
TECHNICAL HIGHLIGHTS 196B U.S. DEPARTMENT OF COMMERCE / National Bureau of Standards UNITED STATES DEPARTMENT OF COMMERCE C. R. Smith, Secretary John F. Kincaid, Assistant Secretary for Science and Technology NATIONAL BUREAU OF STANDARDS A. V. Astin, Director 1968 Technical Highlights of the National Bureau of Standards Institute for Basic Standards Institute for Materials Research Institute for Applied Technology Center for Radiation Research Annual Report, Fiscal Year 1968 For sale by the Superintendent of Documents, U.S. Government Printing Office Washington, D.G. 20402 - Price $1 Library of Congress Catalog Card Number: 6-23979 CONTENTS INTRODUCTION 1 Management Progress 1 Center for Radiation Research Created. Reorganization of Boulder Laboratories. New Institute Directors Named. Special Programs 3 Research Associate Program. Foreign Scientist Visitation Program. Utilization of Federal Laboratories 5 Legislative Report 6 Flammable Fabrics Act. Fire Research and Safety Act. Standard Reference Data Act. TWO KEY STANDARDS PROGRAMS 9 The National Standard Reference Data System 9 History of the Program 10 Responsibilities of NBS. Operation of the System. General Status of the Program. The Standard Reference Data Act. International Cooperation. Current Data Project Activity 19 Nuclear Properties. Atomic and Molecular Properties. Thermodynamic and Transport Properties. Solid State Properties. Chemical Kinetics. Colloid and Surface Properties. Data Systems Design and Development 24 Information Services 25 The Standard Reference Materials Program 26 History of the Program 26 Current Activity 33 INSTITUTE FOR BASIC STANDARDS 39 Physical Quantities 39 International Base Units 40 Length. Time and Frequency. Temperature. Electric Cur- rent. Fundamental Physical Constants. Mechanical Quantities 47 Electrical Quantities—D.C and Low Frequency 49 Electrical Quantities—Radio Frequency 51 High Frequency Region. -
Química (2016) 27, 240---248
Educación Química (2016) 27, 240---248 educación Química www.educacionquimica.info REFLECTION Henry Enfield Roscoe Jaime Wisniak Department of Chemical Engineering, Ben-Gurion University of the Negev, Beer-Sheva 84105, Israel Received 14 July 2015; accepted 15 September 2015 Available online 1 June 2016 KEYWORDS Abstract Henry Enfield Roscoe (1833---1915), together with Robert Bunsen, his mentor, carried Photochemistry; on fundamental research in photochemistry, determining its laws and quantitative effects. His Vanadium; most important studies were on the chemistry of vanadium, uranium, tungsten, and molyb- Tungsten; denum, their oxides and oxychlorides, carrying on, for the first time, their synthesis and Niobium; separation. He also did important studies on public heath. His academic activities transformed Owens College (Victoria University) into the leading chemistry school in Britain. Public health; Education All Rights Reserved © 2016 Universidad Nacional Autónoma de México, Facultad de Química. This is an open access item distributed under the Creative Commons CC License BY-NC-ND 4.0. PALABRAS CLAVE Henry Enfield Roscoe Fotoquímica; Vanadio; Resumen Henry Enfield Roscoe (1833-1915), con la colaboración de Robert Bunsen, su men- Tungsten; tor, realizó estudios fundamentales sobre fotoquímica, fijando sus leyes, y la determinación Niobio; cuantitativa de sus efectos. Sus trabajos mas importantes fueron sobre la química del vanadio, uranio, tungsteno, y molibdeno, sus óxidos y oxicloruros, realizando, por primera vez, su sínte- Salud pública; Educación sis y separación. Asimismo, efectuó estudios importantes sobre salud pública. Sus actividades pedagógicas transformaron a Owens College (Victoria University) en la escuela líder de química en Inglaterra. Derechos Reservados © 2016 Universidad Nacional Autónoma de México, Facultad de Química. -
Identification of Potential Waste Processing and Waste Form Options for Molten Salt Reactors
Identification of Potential Waste Processing and Waste Form Options for Molten Salt Reactors Prepared for U.S. Department of Energy MSR Campaign B.J. Riley,(a) J. McFarlane,(b) G.D. DelCul,(b) J.D. Vienna,(a) C.I. Contescu,(b) L.M. Hay,(a) A.V. Savino,(a) H.E. Adkins,(a) (a)Pacific Northwest National Laboratory (b)Oak Ridge National Laboratory August 15, 2018 NTRD-MSR-2018-000379, PNNL-27723 Approved for public release. Distribution is unlimited. DISCLAIMER This information was prepared as an account of work sponsored by an agency of the U.S. Government. Neither the U.S. Government nor any agency thereof, nor any of their employees, makes any warranty, expressed or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness, of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. References herein to any specific commercial product, process, or service by trade name, trade mark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the U.S. Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the U.S. Government or any agency thereof. Identification of Potential Waste Processing and Waste Form Options for Molten Salt Reactors iv August 15, 2018 SUMMARY The overall summary of the waste management envelope discussed in this report is represented by the diagram shown in Figure S1. The -
Radiation Measurements and Dosimetry – ASP 2021
Radiation dosimetry, radiation protection and measurements Marco Silari CERN, Geneva, Switzerland [email protected] M. Silari – Radiation Measurements and Dosimetry – ASP 2021 1 Outline of the lecture ─ A very brief historical introduction ─ Directly and indirectly ionizing radiation ─ Radioactivity ─ Natural exposures ─ The effects of ionizing radiation ─ Deterministic and stochastic effects ─ Radiological quantities and units ─ physical, protection and operational quantities ─ Principles of radiation protection ─ Justification, optimization and dose limitation ─ The ALARA principle ─ Protection means ─ Instrumentation for measuring ionizing radiation M. Silari – Radiation Measurements and Dosimetry – ASP 2021 2 Outline of the lecture ─ A very brief historical introduction ─ Directly and indirectly ionizing radiation ─ Radioactivity ─ Natural exposures ─ The effects of ionizing radiation ─ Deterministic and stochastic effects ─ Radiological quantities and units ─ physical, protection and operational quantities ─ Principles of radiation protection ─ Justification, optimization and dose limitation ─ The ALARA principle ─ Protection means ─ Instrumentation for measuring ionizing radiation M. Silari – Radiation Measurements and Dosimetry – ASP 2021 3 The discovery of radiation 1895 Discovery of X rays Wilhelm C. Röntgen 1897 First treatment of tissue with X rays Leopold Freund J.J. Thompson 1897 “Discovery” of the electron M. Silari – Radiation Measurements and Dosimetry – ASP 2021 4 The discovery of radiation Henri Becquerel (1852-1908) -
Lawrence Berkeley National Laboratory Recent Work
Lawrence Berkeley National Laboratory Recent Work Title THE KINETICS OF THE CHLORINATION OF UC14 BY Cl2 Permalink https://escholarship.org/uc/item/28x84687 Author Camahort, Jose Luis Publication Date 1965-05-20 eScholarship.org Powered by the California Digital Library University of California UCRL-11986 University of California Ernest 0. lawrence Radiation Laboratory THE KINETICS OF THE CHLORINATION OF UC1 BY C12 - TWO-WEEK LOAN COPY This is a library Circulating Copy which may be borrowed for two weeks. For a personal retention copy, call Tech. Info. Dioision, Ext. 5545 Berkeley, California DISCLAIMER This document was prepared as an account of work sponsored by the United States Government. While this document is believed to contain correct information, neither the United States Government nor any agency thereof, nor the Regents of the University of California, nor any of their employees, makes any warranty, express or implied, or assumes any legal responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by its trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof, or the Regents of the University of California. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof or the Regents of the University of California. DCl\L-llSJ36 UNIVERSITY OF CALIFORNIA Lal·rrence Radiation Laboratory Berkeley} California AEC Contract No. -
16004479.Pdf
LIST OF MILITARY AND CIVIL DEFENSE RADIAC DEVICES 1969 AUGUST 1969 "Each transmittal of this report outside the agencies of the U. S. Government must have prior approval of the Director, Defense Atomic Support Agency, Washington, D. C. 20305." Prepared * by Research and Development Liaison Directorate Field Command, Defense Atomic Support Agency Sandia Base, New Mexico 87l15 i ABSTRACT A compilation of radiac dwices currently available to the Department of Defense is presented. The list is separated into rate meters, dosimeters, miscellaneous radiac equipment for calibration and special purposes, and major research and devel- opment items. Each item includes nomenclature. classification, federal stock number, cost, sponsoring agency and a description of the item. ii Letter of Promulgation This "List of Military and Civil Defense Radiac Devices" is a compilation of information on radisc devices currently available to the Department of Defense. Information on major research and development items currently under investigation is also included. The radiac information included herein has been furnished * by the agencies sponsoring the various devices. It is intended for use as a convenient reference document for agencies associared with radiac developments. [ Brigadier (isnorel, USAP Deputy Mrector (Ops & Admin) iii -.., .. iv TABLE OF CONTENTS SECTION A - RATE METERS -PAGE A-1 Low Range Survey Meters A-2 High Range Survey Meters A-3 Alpha Detectors A-4 Neutron Detectors A-5 Special Purpose Rate Meters A-6 Training Devices SECTION B - DOSIMETERS -
Chem 481 Lecture Material 3/13/09
Chem 481 Lecture Material 3/13/09 Radiation Detection and Measurement When radiation interacts with matter electronic excitation and ionization occur. When de-excitation results in the emission of photons these can be detected by suitable light- sensitive devices. When charge carriers (ion pairs, electron/hole pairs) are produced these can be collected to generate an electrical signal. The dead time of a detector is the length of time between the formation of an output signal (pulse) and when the detector conditions are able to produce another output signal (see figure below). Initially this second output is insufficient in size to be recognized by the counting electronics (less than the discriminator level). The resolving time is the interval between the initial pulse and the formation of a detectable pulse (see figure below). The recovery time is the interval between two full-size pulses. Events that occur during the resolving time will not be recorded and are known as coincidence losses. Gas Ionization Detectors Imagine a gas-filled container with 2 electrodes of opposite charge (see figure below). As radiation enters the gas filling and ionizes the gas (creates primary cation-electron pairs), the cations will drift toward the negatively-charged electrode and the electrons Radiation Detection and Measurement 3/13/09 page 2 will be collected at the positive anode resulting in a current that can be measured. Some cations and electrons may recombine. As the electric potential across the electrodes is increased a voltage is reached where the electrode attraction is greater than the attraction between cations and electrons and all primary ion pairs are collected.