Minerals Named in Honour of the Collaborators of the A.E
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Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
1469 Vol 43#5 Art 03.Indd
1469 The Canadian Mineralogist Vol. 43, pp. 1469-1487 (2005) BORATE MINERALS OF THE PENOBSQUIS AND MILLSTREAM DEPOSITS, SOUTHERN NEW BRUNSWICK, CANADA JOEL D. GRICE§, ROBERT A. GAULT AND JERRY VAN VELTHUIZEN† Research Division, Canadian Museum of Nature, P.O. Box 3443, Station D, Ottawa, Ontario K1P 6P4, Canada ABSTRACT The borate minerals found in two potash deposits, at Penobsquis and Millstream, Kings County, New Brunswick, are described in detail. These deposits are located in the Moncton Subbasin, which forms the eastern portion of the extensive Maritimes Basin. These marine evaporites consist of an early carbonate unit, followed by a sulfate, and fi nally, a salt unit. The borate assemblages occur in specifi c beds of halite and sylvite that were the last units to form in the evaporite sequence. Species identifi ed from drill-core sections include: boracite, brianroulstonite, chambersite, colemanite, congolite, danburite, hilgardite, howlite, hydroboracite, kurgantaite, penobsquisite, pringleite, ruitenbergite, strontioginorite, szaibélyite, trembathite, veatchite, volkovskite and walkerite. In addition, 41 non-borate species have been identifi ed, including magnesite, monohydrocalcite, sellaite, kieserite and fl uorite. The borate assemblages in the two deposits differ, and in each deposit, they vary stratigraphically. At Millstream, boracite is the most common borate in the sylvite + carnallite beds, with hilgardite in the lower halite strata. At Penobsquis, there is an upper unit of hilgardite + volkovskite + trembathite in halite and a lower unit of hydroboracite + volkov- skite + trembathite–congolite in halite–sylvite. At both deposits, values of the ratio of B isotopes [␦11B] range from 21.5 to 37.8‰ [21 analyses] and are consistent with a seawater source, without any need for a more exotic interpretation. -
Thirty-Fourth List of New Mineral Names
MINERALOGICAL MAGAZINE, DECEMBER 1986, VOL. 50, PP. 741-61 Thirty-fourth list of new mineral names E. E. FEJER Department of Mineralogy, British Museum (Natural History), Cromwell Road, London SW7 5BD THE present list contains 181 entries. Of these 148 are Alacranite. V. I. Popova, V. A. Popov, A. Clark, valid species, most of which have been approved by the V. O. Polyakov, and S. E. Borisovskii, 1986. Zap. IMA Commission on New Minerals and Mineral Names, 115, 360. First found at Alacran, Pampa Larga, 17 are misspellings or erroneous transliterations, 9 are Chile by A. H. Clark in 1970 (rejected by IMA names published without IMA approval, 4 are variety because of insufficient data), then in 1980 at the names, 2 are spelling corrections, and one is a name applied to gem material. As in previous lists, contractions caldera of Uzon volcano, Kamchatka, USSR, as are used for the names of frequently cited journals and yellowish orange equant crystals up to 0.5 ram, other publications are abbreviated in italic. sometimes flattened on {100} with {100}, {111}, {ill}, and {110} faces, adamantine to greasy Abhurite. J. J. Matzko, H. T. Evans Jr., M. E. Mrose, lustre, poor {100} cleavage, brittle, H 1 Mono- and P. Aruscavage, 1985. C.M. 23, 233. At a clinic, P2/c, a 9.89(2), b 9.73(2), c 9.13(1) A, depth c.35 m, in an arm of the Red Sea, known as fl 101.84(5) ~ Z = 2; Dobs. 3.43(5), D~alr 3.43; Sharm Abhur, c.30 km north of Jiddah, Saudi reflectances and microhardness given. -
Yuksporite (K; Ba)(Na; Sr)Ca2(Si; Ti)4O11(F; OH) ² H2O C 2001 Mineral Data Publishing, Version 1.2 ° Crystal Data: Orthorhombic
Yuksporite (K; Ba)(Na; Sr)Ca2(Si; Ti)4O11(F; OH) ² H2O c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Orthorhombic. Point Group: n.d. Fibrous, scaly, or lamellar; in irregular aggregates, to 10 cm. Physical Properties: Hardness = 5 D(meas.) = 3.05(3) D(calc.) = [2.98] Optical Properties: Semitransparent. Color: Rose-red to straw-yellow. Optical Class: Biaxial (+). Pleochroism: Marked; X = pale rose-yellow; Y = Z = rose-yellow. ® = 1.644(2) ¯ = n.d. ° = 1.660(2) 2V(meas.) = 46±{76± Cell Data: Space Group: n.d. a = 24.869(8) b = 16.756(6) c = 7.057(3) Z = 10 X-ray Powder Pattern: Khibiny massif, Russia. 2.778 (10), 3.00 (9), 1.786 (9), 3.10 (8), 3.05 (8), 1.888 (7), 2.92 (6) Chemistry: (1) (2) (1) (2) SiO2 40.92 38.40 BaO 8.60 TiO2 11.00 Na2O 7.94 3.84 Al2O3 0.07 K2O 12.57 6.15 Fe2O3 9.10 0.75 F 3.05 MnO 0.91 0.29 Cl 0.80 + MgO 0.42 H2O 2.20 CaO 20.56 18.90 H2O 8.52 SrO 5.87 O = (F; Cl) 1.46 ¡ 2 Total 100.94 [98.46] (1) Khibiny massif, Russia. (2) Murun massif, Russia; original total given as 99.07%, 3+ corresponds to (K0:70Ba0:30)§=1:00(Na0:66Sr0:30)§=0:96(Ca1:80Ti0:19Fe0:06Mn0:02)§=2:07 (Si3:42Ti0:57Al0:01)§=4:00O11[F0:86Cl0:12(OH)0:02]§=1:00 ² 0:6H2O: Occurrence: In veins in nepheline syenite in a di®erentiated alkalic massif (Khibiny massif, Russia). -
New Minerals Approved Bythe Ima Commission on New
NEW MINERALS APPROVED BY THE IMA COMMISSION ON NEW MINERALS AND MINERAL NAMES ALLABOGDANITE, (Fe,Ni)l Allabogdanite, a mineral dimorphous with barringerite, was discovered in the Onello iron meteorite (Ni-rich ataxite) found in 1997 in the alluvium of the Bol'shoy Dolguchan River, a tributary of the Onello River, Aldan River basin, South Yakutia (Republic of Sakha- Yakutia), Russia. The mineral occurs as light straw-yellow, with strong metallic luster, lamellar crystals up to 0.0 I x 0.1 x 0.4 rnrn, typically twinned, in plessite. Associated minerals are nickel phosphide, schreibersite, awaruite and graphite (Britvin e.a., 2002b). Name: in honour of Alia Nikolaevna BOG DAN OVA (1947-2004), Russian crys- tallographer, for her contribution to the study of new minerals; Geological Institute of Kola Science Center of Russian Academy of Sciences, Apatity. fMA No.: 2000-038. TS: PU 1/18632. ALLOCHALCOSELITE, Cu+Cu~+PbOZ(Se03)P5 Allochalcoselite was found in the fumarole products of the Second cinder cone, Northern Breakthrought of the Tolbachik Main Fracture Eruption (1975-1976), Tolbachik Volcano, Kamchatka, Russia. It occurs as transparent dark brown pris- matic crystals up to 0.1 mm long. Associated minerals are cotunnite, sofiite, ilin- skite, georgbokiite and burn site (Vergasova e.a., 2005). Name: for the chemical composition: presence of selenium and different oxidation states of copper, from the Greek aA.Ao~(different) and xaAxo~ (copper). fMA No.: 2004-025. TS: no reliable information. ALSAKHAROVITE-Zn, NaSrKZn(Ti,Nb)JSi401ZJz(0,OH)4·7HzO photo 1 Labuntsovite group Alsakharovite-Zn was discovered in the Pegmatite #45, Lepkhe-Nel'm MI. -
L'leve~Th List of New Mineral Na~Es. ~
556 L'leve~th list of new mineral na~es. ~ By L. J. SPENCER, M.A., Sc.D., F.R.S. Keeper of Minerals ia the British Museum (Natural History). [Communicated June 12~ 1928.] Ajkaite. (L. Zeehmeister, Math. Termdszettud. ~:rtesitS, Badapest, 1926, vol. 43, p. 332 (ajkait); L. Zechmeister and V. Vrab~ly, Per. Deutsch. Chem. Gesell., 1926, vol. 59, Abt. B, p. 1426). The same as ajkite (Bull. Soc. Min. France, 1878, vol. 1, p. 126 ; abstract from... ?). A fossil resin containing 1-5 ~ sulphur and no succinic acid, from Ajka, com. Veszpr~m, Hungary. [M.A. 3-362.] Albiclase. A. N. Winchell, 1925. Journ. Geol. Chicago, vol. 83, p. 726 ; Elements of optical mineralogy, 2nd edit., 1927, pt. 2, p. 319. P. Niggli, Lehrbuch Min., 1926, vol. 2, p. 536 (Albiklas). A contrac- tion of albite-oligoclase for felspars of the plagioclase series ranging in composition from Ab~Anlo to AbsoAn~o. Allite. tL Harrassowitz, 1926. Laterit, Material und Versuch erdgesehichtlicher Auswertung, Berlin 1926, p. 255 (Allit, plur. Allite). A rock-name to include both bauxite and laterite. Later (Metall und Erz, Halle, ]927, vol. 24, p. 589) bauxite with A1208. H~O is distinguished as monohydrallite (Monohydrallit) and laterite with Al~0s.3H20 as trihydrallite (Trihydrallit). These, although suggestive of mineral- names (and given so i~ error in Chem. Zentr., 1926, vol. 1, p. 671), are proposed as rock-names ; from aluminium and M~o~. Similarly, siallites (1926, p. 252, Siallit, from Si, A1, M0o~), to include kaolinite and allo- phanite, are rocks composed of the aluminium silicates kaolin and allophane. -
Design Rules for Discovering 2D Materials from 3D Crystals
Design Rules for Discovering 2D Materials from 3D Crystals by Eleanor Lyons Brightbill Collaborators: Tyler W. Farnsworth, Adam H. Woomer, Patrick C. O'Brien, Kaci L. Kuntz Senior Honors Thesis Chemistry University of North Carolina at Chapel Hill April 7th, 2016 Approved: ___________________________ Dr Scott Warren, Thesis Advisor Dr Wei You, Reader Dr. Todd Austell, Reader Abstract Two-dimensional (2D) materials are championed as potential components for novel technologies due to the extreme change in properties that often accompanies a transition from the bulk to a quantum-confined state. While the incredible properties of existing 2D materials have been investigated for numerous applications, the current library of stable 2D materials is limited to a relatively small number of material systems, and attempts to identify novel 2D materials have found only a small subset of potential 2D material precursors. Here I present a rigorous, yet simple, set of criteria to identify 3D crystals that may be exfoliated into stable 2D sheets and apply these criteria to a database of naturally occurring layered minerals. These design rules harness two fundamental properties of crystals—Mohs hardness and melting point—to enable a rapid and effective approach to identify candidates for exfoliation. It is shown that, in layered systems, Mohs hardness is a predictor of inter-layer (out-of-plane) bond strength while melting point is a measure of intra-layer (in-plane) bond strength. This concept is demonstrated by using liquid exfoliation to produce novel 2D materials from layered minerals that have a Mohs hardness less than 3, with relative success of exfoliation (such as yield and flake size) dependent on melting point. -
Glossary of Obsolete Mineral Names
Uaranpecherz = uraninite, László 282 (1995). überbasisches Cuprinitrat = gerhardtite, Hintze I.3, 2741 (1916). überbrannter Amethyst = heated 560ºC red-brown Fe-rich quartz, László 11 (1995). Überschwefelblei = galena + anglesite + sulphur-α, Chudoba RI, 67 (1939); [I.3,3980]. uchucchacuaïte = uchucchacuaite, MR 39, 134 (2008). uddervallite = pseudorutile, Hey 88 (1963). uddevallite = pseudorutile, Dana 6th, 218 (1892). uddewallite = pseudorutile, Des Cloizeaux II, 224 (1893). udokanite = antlerite, AM 56, 2156 (1971); MM 43, 1055 (1980). uduminelite (questionable) = Ca-Al-P-O-H, AM 58, 806 (1973). Ueberschwefelblei = galena + anglesite + sulphur-α, Egleston 132 (1892). Uekfildit = wakefieldite-(Y), Chudoba EIV, 100 (1974). ufalit = upalite, László 280 (1995). uferite = davidite-(La), AM 42, 307 (1957). ufertite = davidite-(La), AM 49, 447 (1964); 50, 1142 (1965). U-free thorite = huttonite, Clark 303 (1993). U-galena = U-rich galena, AM 20, 443 (1935). ugandite = bismutotantalite, MM 22, 187 (1929). ughvarite = nontronite ± opal-C, MAC catalog 10 (1998). ugol = coal, Thrush 1179 (1968). ugrandite subgroup = uvarovite + grossular + andradite ± goldmanite ± katoite ± kimzeyite ± schorlomite, MM 21, 579 (1928). uhel = coal, Thrush 1179 (1968). Uhligit (Cornu) = colloidal variscite or wavellite, MM 18, 388 (1919). Uhligit (Hauser) = perovskite or zirkelite, CM 44, 1560 (2006). U-hyalite = U-rich opal, MA 15, 460 (1962). Uickenbergit = wickenburgite, Chudoba EIV, 100 (1974). uigite = thomsonite-Ca + gyrolite, MM 32, 340 (1959); AM 49, 223 (1964). Uillemseit = willemseite, Chudoba EIV, 100 (1974). uingvárite = green Ni-rich opal-CT, Bukanov 151 (2006). uintahite = hard bitumen, Dana 6th, 1020 (1892). uintaite = hard bitumen, Dana 6th, 1132 (1892). újjade = antigorite, László 117 (1995). újkrizotil = chrysotile-2Mcl + lizardite, Papp 37 (2004). új-zéalandijade = actinolite, László 117 (1995). -
New Mineral Names*
American Mineralogist, Volume 62, pages 1259-1262, 1977 NewMineral Names* MtcHe.rr-Flrlscsnn, Lours J. CesRrAND ADoLF Pe.ssr Franzinite* Six microprobe analyses gave (range and av.): AsrOu 44.96-45.68,45.36; CuO 16.84-20.22,18.81; ZnO 16.78-18.57, Stefano Merlino and Paolo Orlandi (1977)Franzinite, a new min- 17.90;CdO l3 58-14.93,14.08; CaO 0.41-l.ll' 0.80; PbO 0.14- eral phase from Pitigliano,ltaly. Neues Jahrb. Mineral. Mon- 1.42,0.63: MnO 0.'79-1.27,1.07; sum 97 8l-99 54' 98.65 percent, atsh., 163-167. corresponding to (Cu,Zn,Cd).(AsOa), with Cu:Zn:Cd : 1.19: Microchemical analysis gave SiO, 32.44, Al2Os 25.21, Fe"O" Lll:0.55. The mineral is readily dissolvedby concentratedacids 0.04,MgO 0.14,CaO 12.08,Na,O 11.50,K,O 4.24,SOa 10.65, CO, X-ray study showsthe mineral to be monoclinic,space group 12' 154, Cl 036,H,O 1.88,sum 100.08- (O:Cl,) 0.08 : 100.00 Im. or 12/m, a ll.65, b 12.68,c 6.87(all + 0.01A)' B 98 95 + 0.05'' percent. "SiO, and AlrO, were determined by X-ray fluorescence, Z = 6, G calc 4.95 The strongest X-ray lines (46 given) are 6.41 (vvs) account being taken of the proper correction factor for S and Cl (MS) (020, l0T), 3.29 (vSXll2), 2.876 (vSX400), 2.79s and assuming that the weight percentages sum up to 100 0." (222, 321, 240), 1.644(MS). -
Paula Celeste Da Novel Microporous Silicates and Mesoporous MCM Silva Ferreira Materials Derivatised with Inorganic and Organometallic Complexes
Universidade de Aveiro Departamento de Quimica 0 @ 2000 qso 5a"s Paula Celeste da Novel microporous silicates and mesoporous MCM Silva Ferreira materials derivatised with inorganic and organometallic complexes Dissertação apresentada à Universidade de Aveiro para cumprimento dos requisitos necessários a obtenção do grau de Doutor em Quirnica, realizada sob orientação científica do Doutor João Carlos Matias Celestino Gomes da Rocha, Professor CatedrBtico do Departamento de Quirnica da Universidade de Aveiro. o Júri Presidente: Doutor Casimiro Adrião Pio Professor Catedrático da Universidade de Aveiro Vogais: Doutor Carlos José Rodrigues Crispim Romão Professor Catedrático do Instituto de Tecnologia Química e Biológica da Universidade Nova de Lisboa Doutor João Carlos Matias Celestino Gomes da Rocha Professor Catedrático da Universidade de Aveiro Doutora Maria Filipa Gomes Ribeiro Professora Associada do Departamento de Engenharia Química do Instituto Superior Técnico, da Universidade Técnica de Lisboa Doutora Ana Maria Vieira Silva Viana Cavaleiro Professora Associada da Universidade de Aveiro Doutora Isabel Maria de Sousa Gonçalves Professora Auxiliar da Universidade de Aveiro Doutor Michael William Anderson Full Professor, Department of Chemistry, Institute of Science and Technology, University of Manchester acknowledgements I would like to express my sincere gratitude to my supervisor Prof. Dr. João Rocha for giving me the opportunity to work with him and for sharing with me some of his knowledge. I also acknowledge his continuous help, specially, in the solid state NMR experiments and in the correction of this thesis. I would like to thank Prof. Dr. Isabel Gonçalves for her indispensable help, advice and guidance in the derivatisation of mesoporous MCM rnaterials with organometallic and inorganic complexes. -
New Mineral Names*
American Mineralogist, Volume 69, pages 210-215, 1984 NEW MINERAL NAMES* Pere J. DuNu, Jonr D. Gruce, Mrcneer FLerscHen, AND ADoLF Pessr Chromdravite* Lithosite* E. V. Rumantseva(1983) Chromdravite, a new mineral.Zapiski A. P. Khomyakov, N. M. Chernitsova, and N. L Chistyakova Vses. Mineralog.Obsh., 112,222-226(in Russian). (19E3)Lithosite, KcALSisOzs.2H2O, a new mineral.Zapiski Vses.Mineralog. Obsh., ll2,218-222 (in Russian). Analysis by K. K. Gunbar after correction for 65Va impurity of chromian phengite(analyzed) gave SiO2 30.75, TiO, 0.13, Microprobe analyses of the mineral gave SiO2 50.0, 49.6; Al2O32.92, Cr2O3 3 I.60, V 2Or1.46, F e2O3 7.65, MnO 0. 19,MgO A12O320.7,20.4;K2O28.4,28.0;H2O (loss on ignition)2.34, sum 9.05,CaO 0.16,Na2O 2.66,820,3 9.00, loss on ignition4.43, sum of averages 100.94Vo,corresponding to K5.saAl3grSis oe 1W.00%.Microprobe analysis gave SiO2 37.9, Al2O35.1, Cr2O3 O2s' 2.53H2O.Easily decomposedby cold,lO% HCl. The infra- 30.|, V2O30.5, Fe2O38.E, MnO 0.7, MgO 6.5%. The correcred red spectrum indicates the presenceof molecular water. chemical analysis gives the formula (Na6 s;Mnoor X-ray study shows it to be monoclinic, pseudo-orthorhombic, "7Caa.s3)(Mgz vo 22Alo 16Tiq.62)3.0o (cra_zr FeISe Ab zr)666 (82 e1Ale se)goo Sis ar a= 15.197,b=10.233, c: E.435A,9:XJ.2t",Z=2,D(calc.) Ab re)6.0oo27(Oo.zrOHrrz)+ oo. This is, therefore, unlike chromian : 2'54, (meas.): 2.51.The strongestX-ray lines(47 given) are varieties previously described, a new member of the tourmaline 3.46 (84)(2r2,4or); 3.26(84)(122,03r) ; 3.07 (r0o)(3 0,a2Q ; group with Mg dominant in the Y position, Cr in the Z position. -
Synthesis and Adsorption Behavior of Microporous Iron-Doped Sodium Zirconosilicate with the Structure of Elpidite
Article Synthesis and Adsorption Behavior of Microporous Iron-Doped Sodium Zirconosilicate with the Structure of Elpidite Emad Elshehy Nuclear Materials Authority, P.O. Box 530, El-Maadi, Cairo 11728, Egypt; [email protected]; Tel.: +20-10-0819-7997 Abstract: Decontamination of water from radionuclides contaminants is a key priority in environ- mental cleanup and requires intensive effort to be cleared. In this paper, a microporous iron-doped zeolite-like sodium zirconosilicate (F@SZS) was designed through hydrothermal synthesis with various Si/Zr ratios of 5, 10, and 20, respectively. The synthesized materials of F@SZS materials were well characterized by various techniques such as XRD, SEM, TEM, and N2 adsorption–desorption measurements. Furthermore, the F@SZS-5 and F@SZS-10 samples had a crystalline structure re- lated to the Zr–O–Si bond, unlike the F@SZS-20 which had an overall amorphous structure. The fabricated F@SZS-5 nanocomposite showed a superb capability to remove cesium ions from ultra- dilute concentrations, and the maximum adsorption capacity was 21.5 mg g–1 at natural pH values through an ion exchange mechanism. The results of cesium ions adsorption were found to follow the pseudo-first-order kinetics and the Langmuir isotherm model. The microporous iron-doped sodium zirconosilicate is described as an adsorbent candidate for the removal of ultra-traces concentrations of Cs(I) ions. Keywords: zirconosilicates; zeolite structure; microporous materials; nanocomposite; cesium removal Citation: Elshehy, E. Synthesis and Adsorption Behavior of Microporous 1. Introduction Iron-Doped Sodium Zirconosilicate with the Structure of Elpidite. Surfaces Zeolites are finding increasing interest in technological applications due primarily 2021, 4, 41–53.