Safety Data Sheet Material Name: Antimony Pentafluoride SDS ID: 0595P

Total Page:16

File Type:pdf, Size:1020Kb

Safety Data Sheet Material Name: Antimony Pentafluoride SDS ID: 0595P Safety Data Sheet Material Name: Antimony pentafluoride SDS ID: 0595P Section 1 - PRODUCT AND COMPANY IDENTIFICATION Material Name Antimony pentafluoride Product Use semiconductor manufacture Restrictions on Use None known. Details of the supplier of the safety data sheet Entegris, Inc. 129 Concord Road Building 2 Billerica, MA 01821 USA Telephone Number: +1-952-556-4181 Telephone Number: +1-800-394-4083 (toll free within North America) Emergency Telephone Number: CHEMTREC - U.S. - 1-800-424-9300 CHEMTREC - Intl. - 1-703-527-3887 E-mail: [email protected] Section 2 - HAZARDS IDENTIFICATION Classification in accordance with paragraph (d) of 29 CFR 1910.1200. Corrosive to Metals - Category 1 Acute Toxicity - Oral - Category 4 Acute Toxicity - Inhalation - Vapor - Category 1 Skin Corrosion/Irritation - Category 1 Serious Eye Damage/Eye Irritation - Category 1 Carcinogenicity - Category 2 Specific Target Organ Toxicity - Single Exposure - Category 1 ( respiratory system , cardiovascular system , liver , kidneys ) Hazardous to the Aquatic Environment - Acute - Category 2 Hazardous to the Aquatic Environment - Chronic - Category 2 GHS Label Elements Symbol(s) Signal Word Danger Hazard Statement(s) ____________________________________________________________ Page 1 of 10 Issue date: 2018-12-20 Revision 1.0 Print date: 2018-12-20 Safety Data Sheet Material Name: Antimony pentafluoride SDS ID: 0595P May be corrosive to metals. Fatal if inhaled. Harmful if swallowed. Causes severe skin burns and eye damage. Suspected of causing cancer. Causes damage to organs. (respiratory system , cardiovascular system , liver , kidneys ) Toxic to aquatic life with long lasting effects. Precautionary Statement(s) Prevention Keep only in original container. Do not breathe vapor or mist. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid release to the environment. Response Absorb spillage to prevent material damage. If exposed: Call a POISON CENTER or doctor/physician. Immediately call a POISON CENTER or doctor/physician. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Specific treatment is urgent, see first aid section of Safety Data Sheet. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Collect spillage. Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Store in corrosive resistant container with a resistant inner liner. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Other Hazards Contact with water or moist air may form hydrogen fluoride. Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS CAS Component Name Percent 7783-70-2 Antimony pentafluoride 100 Section 4 - FIRST AID MEASURES ____________________________________________________________ Page 2 of 10 Issue date: 2018-12-20 Revision 1.0 Print date: 2018-12-20 Safety Data Sheet Material Name: Antimony pentafluoride SDS ID: 0595P Inhalation If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. Skin Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes. Eyes Immediately flush eyes with plenty of water for at least 60 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Then get immediate medical attention. Ingestion If swallowed, do NOT induce vomiting. Rinse mouth. Get immediate medical attention. Most Important Symptoms/Effects Acute Fatal if inhaled, Harmful if swallowed, respiratory tract burns, skin burns, eye burns, mucous membrane burns, respiratory system damage, cardiovascular system damage, liver damage, kidney damage Delayed cancer Indication of any immediate medical attention and special treatment needed For inhalation, consider oxygen. Avoid gastric lavage or emesis. Section 5 - FIRE FIGHTING MEASURES Extinguishing Media Suitable Extinguishing Media carbon dioxide, dry chemical, dry sand, alcohol-resistant foam. Large fires: water spray or fog, alcohol- resistant foam. Unsuitable Extinguishing Media high-pressure water streams Special Hazards Arising from the Chemical Negligible fire hazard. May ignite or explode on contact with combustible materials. Hazardous Combustion Products Material is non-flammable, however, it may increase fire severity upon contact with combustible materials; oxides of antimony, hydrogen fluoride Advice for firefighters Negligible fire hazard. May ignite or explode on contact with combustible materials. Fire Fighting Measures Move container from fire area if it can be done without risk. Do not scatter spilled material with high- pressure water streams. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Do not get water inside container. Cool containers with water spray until well after the fire is out. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. ALWAYS stay away from tanks engulfed in fire. Avoid inhalation of material or combustion by-products. Dike for later disposal. Special Protective Equipment and Precautions for Firefighters Wear full protective fire fighting gear including self contained breathing apparatus (SCBA) for protection against possible exposure. ____________________________________________________________ Page 3 of 10 Issue date: 2018-12-20 Revision 1.0 Print date: 2018-12-20 Safety Data Sheet Material Name: Antimony pentafluoride SDS ID: 0595P Section 6 - ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures Wear personal protective clothing and equipment. Methods and Materials for Containment and Cleaning Up Eliminate all ignition sources if safe to do so. All equipment used when handling the product must be grounded. Stop leak if possible without personal risk. Do not touch spilled material. A vapor suppressing foam may be used to reduce vapors. Prevent entry into waterways, sewers, basements, or confined areas. Do not get water inside container. Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. Absorb spill with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Keep unnecessary people away, isolate hazard area and deny entry. Environmental Precautions Avoid release to the environment. Collect spillage. Section 7 - HANDLING AND STORAGE Precautions for Safe Handling Keep only in original container. Do not breathe vapor or mist. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. Use only outdoors or in a well-ventilated area. Do not eat, drink or smoke when using this product. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Conditions for Safe Storage, Including any Incompatibilities Store in a well-ventilated place. Keep container tightly closed. Store locked up. Store in corrosive resistant container with a resistant inner liner. Store in accordance with all current regulations and standards. Keep separated from incompatible substances. Incompatible Materials combustible materials, metals, reducing agents, water Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION Component Exposure Limits Antimony pentafluoride 7783-70-2 ACGIH: 0.5 mg/m3 TWA as Sb (related to Antimony compounds) NIOSH: 0.5 mg/m3 TWA as Sb (related to Antimony compounds) 50 mg/m3 IDLH as Sb (related to Antimony compounds) OSHA (US): 0.5 mg/m3 TWA as Sb (related to Antimony compounds) Mexico: 0.5 mg/m3 TWA [VLE-PPT ] as Sb (related to Antimony compounds) ACGIH - Threshold Limit Values - Biological Exposure Indices (BEI) Antimony pentafluoride (7783-70-2) 2 mg/l Medium: urine Time: prior to shift Parameter: Fluoride (background, nonspecific ); 3 mg/l Medium: urine Time: end of shift Parameter: Fluoride (background, nonspecific ) (related to Fluorides) Engineering Controls ____________________________________________________________ Page 4 of 10 Issue date: 2018-12-20 Revision 1.0 Print date: 2018-12-20 Safety Data Sheet Material Name: Antimony pentafluoride SDS ID: 0595P Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits. Individual Protection Measures, such as Personal Protective Equipment Eye/face protection Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Skin Protection Wear appropriate chemical resistant clothing. Respiratory Protection Respirators depend on exposure level. SCBA with full face piece recommended during change outs and available
Recommended publications
  • UNITED STATES PATENT OFFICE 2,499,833 METEOD of MARING FLUORNATED ORGANIC COMPOUNDS Melvin A
    Patented Mar. 7, 1950 2,499,833 UNITED STATES PATENT OFFICE 2,499,833 METEOD OF MARING FLUORNATED ORGANIC COMPOUNDS Melvin A. Perkins, Wilmington, Del, assignor to the United States of America as represented by the United States Atomic Energy Commission No Drawing. Application July 2, 1944, Serial No. 546,916 3 Claims. (C. 260-648) 2 This invention relates to new halogen com silver difluoride to replace hydrogen and saturate pounds and to methods for their production. any residual double bonds. It is an object of the invention to provide prod The products have densities in the neighbor lucts of high thermal stability and inertness to hood of 1.8 and refractive indices of about 1.3 chemical reagents, particularly oxidizing agents, s (sodium-D-line) at 23° C. They are usually ob acids, bases and metals. A further object is the tained in the crude state as mixtures of compounds provision of products suitable for use as heat of the molecular formulae CaF16, CaClF15, CaCl2F14 transfer media, lubricants and Sealants. Further and other chloro-fluorocarbons, from which the objects will appear from the following detailed individual constituents may be obtained by frac description of the invention. tional distillation. The products possess a high In my United States patent application Serial degree of stability to oxidizing agents, acids, bases Number 546,915 entitled "Halogenated organic and metals, and the stability increases with the compounds and method of making,' filed on the degree of fluorination. Thus the compound CaF16 Same date herewith, which became U. S. Patent is the most stable compound of the group and the No.
    [Show full text]
  • Chemical Name Federal P Code CAS Registry Number Acutely
    Acutely / Extremely Hazardous Waste List Federal P CAS Registry Acutely / Extremely Chemical Name Code Number Hazardous 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro- P059 76-44-8 Acutely Hazardous 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide P050 115-29-7 Acutely Hazardous Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- P197 17702-57-7 Acutely Hazardous 1-(o-Chlorophenyl)thiourea P026 5344-82-1 Acutely Hazardous 1-(o-Chlorophenyl)thiourea 5344-82-1 Extremely Hazardous 1,1,1-Trichloro-2, -bis(p-methoxyphenyl)ethane Extremely Hazardous 1,1a,2,2,3,3a,4,5,5,5a,5b,6-Dodecachlorooctahydro-1,3,4-metheno-1H-cyclobuta (cd) pentalene, Dechlorane Extremely Hazardous 1,1a,3,3a,4,5,5,5a,5b,6-Decachloro--octahydro-1,2,4-metheno-2H-cyclobuta (cd) pentalen-2- one, chlorecone Extremely Hazardous 1,1-Dimethylhydrazine 57-14-7 Extremely Hazardous 1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4,4a,5,6,7,8,8a-octahydro-1,4-endo-endo-5,8- dimethanonaph-thalene Extremely Hazardous 1,2,3-Propanetriol, trinitrate P081 55-63-0 Acutely Hazardous 1,2,3-Propanetriol, trinitrate 55-63-0 Extremely Hazardous 1,2,4,5,6,7,8,8-Octachloro-4,7-methano-3a,4,7,7a-tetra- hydro- indane Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]- 51-43-4 Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, P042 51-43-4 Acutely Hazardous 1,2-Dibromo-3-chloropropane 96-12-8 Extremely Hazardous 1,2-Propylenimine P067 75-55-8 Acutely Hazardous 1,2-Propylenimine 75-55-8 Extremely Hazardous 1,3,4,5,6,7,8,8-Octachloro-1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime 26419-73-8 Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime.
    [Show full text]
  • The List of Extremely Hazardous Substances)
    APPENDIX A (THE LIST OF EXTREMELY HAZARDOUS SUBSTANCES) THRESHOLD REPORTABLE INVENTORY RELEASE QUANTITY QUANTITY CAS NUMBER CHEMICAL NAME (POUNDS) (POUNDS) 75-86-5 ACETONE CYANOHYDRIN 500 10 1752-30-3 ACETONE THIOSEMICARBAZIDE 500/500 1,000 107-02-8 ACROLEIN 500 1 79-06-1 ACRYLAMIDE 500/500 5,000 107-13-1 ACRYLONITRILE 500 100 814-68-6 ACRYLYL CHLORIDE 100 100 111-69-3 ADIPONITRILE 500 1,000 116-06-3 ALDICARB 100/500 1 309-00-2 ALDRIN 500/500 1 107-18-6 ALLYL ALCOHOL 500 100 107-11-9 ALLYLAMINE 500 500 20859-73-8 ALUMINUM PHOSPHIDE 500 100 54-62-6 AMINOPTERIN 500/500 500 78-53-5 AMITON 500 500 3734-97-2 AMITON OXALATE 100/500 100 7664-41-7 AMMONIA 500 100 300-62-9 AMPHETAMINE 500 1,000 62-53-3 ANILINE 500 5,000 88-05-1 ANILINE,2,4,6-TRIMETHYL- 500 500 7783-70-2 ANTIMONY PENTAFLUORIDE 500 500 1397-94-0 ANTIMYCIN A 500/500 1,000 86-88-4 ANTU 500/500 100 1303-28-2 ARSENIC PENTOXIDE 100/500 1 THRESHOLD REPORTABLE INVENTORY RELEASE QUANTITY QUANTITY CAS NUMBER CHEMICAL NAME (POUNDS) (POUNDS) 1327-53-3 ARSENOUS OXIDE 100/500 1 7784-34-1 ARSENOUS TRICHLORIDE 500 1 7784-42-1 ARSINE 100 100 2642-71-9 AZINPHOS-ETHYL 100/500 100 86-50-0 AZINPHOS-METHYL 10/500 1 98-87-3 BENZAL CHLORIDE 500 5,000 98-16-8 BENZENAMINE, 3-(TRIFLUOROMETHYL)- 500 500 100-14-1 BENZENE, 1-(CHLOROMETHYL)-4-NITRO- 500/500 500 98-05-5 BENZENEARSONIC ACID 10/500 10 3615-21-2 BENZIMIDAZOLE, 4,5-DICHLORO-2-(TRI- 500/500 500 FLUOROMETHYL)- 98-07-7 BENZOTRICHLORIDE 100 10 100-44-7 BENZYL CHLORIDE 500 100 140-29-4 BENZYL CYANIDE 500 500 15271-41-7 BICYCLO[2.2.1]HEPTANE-2-CARBONITRILE,5-
    [Show full text]
  • United States Patent Office Patented Sept
    2,904,588 United States Patent Office Patented Sept. 15, 1959 - 2 m Three grams of the product prepared as described above was placed in a polyethylene bottle and 6 g. of water 2,904,588 was added. After the initial exothermic reaction had FLUOROPHOSPHORANES AND THEIR subsided and the solution had cooled, a white crystalline PREPARATION solid separated. This solid was recrystallized twice from water. After drying, the product melted at 159 to 161 William C. Smith, Wilmington, Del, assignor to E. I. du C. The melting point of benzenephosphonic acid is 159 Pont de Nemours and Company, Wilmington, Del., a to 161° C., and this is the product expected from the com corporation of Delaware plete hydrolysis of phenyltetrafluorophosphorane. No Drawing. Application March 26, 1956 O Nuclear magnetic resonance examination of the phenyl Serial No. 573,659 tetrafluorophosphorane showed it to have four equiv alent fluorine atoms bound to phosphorus, which indi 15 Claims. (C. 260-543) cated a square pyramidal structure. This invention relates to new compositions of matter 5 EXAMPLE II and to their preparation. Example I was repeated, using a charge consisting Organic fluorine compounds have attained considerable of 53.7 g (0.3 mole) of phenylphosphonous dichloride importance in recent years and simple and economic in the reaction flask and 65.1 g (0.3 mole) of antimony methods for their preparation are greatly desired. pentafluoride in the dropping funnel. The antimony This invention has as an object the preparation of new 20 pentafluoride was added to the phenylphosphonous di fluorophosphoranes. A further object is the provision of chloride at such a rate that the temperature of the reac a new process for their preparation.
    [Show full text]
  • Acutely / Extremely Hazardous Waste List
    Acutely / Extremely Hazardous Waste List Federal P CAS Registry Acutely / Extremely Chemical Name Code Number Hazardous 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro- P059 76-44-8 Acutely Hazardous 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide P050 115-29-7 Acutely Hazardous Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- P197 17702-57-7 Acutely Hazardous 1-(o-Chlorophenyl)thiourea P026 5344-82-1 Acutely Hazardous 1-(o-Chlorophenyl)thiourea 5344-82-1 Extemely Hazardous 1,1,1-Trichloro-2, -bis(p-methoxyphenyl)ethane Extemely Hazardous 1,1a,2,2,3,3a,4,5,5,5a,5b,6-Dodecachlorooctahydro-1,3,4-metheno-1H-cyclobuta (cd) pentalene, Dechlorane Extemely Hazardous 1,1a,3,3a,4,5,5,5a,5b,6-Decachloro--octahydro-1,2,4-metheno-2H-cyclobuta (cd) pentalen-2- one, chlorecone Extemely Hazardous 1,1-Dimethylhydrazine 57-14-7 Extemely Hazardous 1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4,4a,5,6,7,8,8a-octahydro-1,4-endo-endo-5,8- dimethanonaph-thalene Extemely Hazardous 1,2,3-Propanetriol, trinitrate P081 55-63-0 Acutely Hazardous 1,2,3-Propanetriol, trinitrate 55-63-0 Extemely Hazardous 1,2,4,5,6,7,8,8-Octachloro-4,7-methano-3a,4,7,7a-tetra- hydro- indane Extemely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]- 51-43-4 Extemely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, P042 51-43-4 Acutely Hazardous 1,2-Dibromo-3-chloropropane 96-12-8 Extemely Hazardous 1,2-Propylenimine P067 75-55-8 Acutely Hazardous 1,2-Propylenimine 75-55-8 Extemely Hazardous 1,3,4,5,6,7,8,8-Octachloro-1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran Extemely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime 26419-73-8 Extemely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime.
    [Show full text]
  • List of Lists
    United States Office of Solid Waste EPA 550-B-10-001 Environmental Protection and Emergency Response May 2010 Agency www.epa.gov/emergencies LIST OF LISTS Consolidated List of Chemicals Subject to the Emergency Planning and Community Right- To-Know Act (EPCRA), Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and Section 112(r) of the Clean Air Act • EPCRA Section 302 Extremely Hazardous Substances • CERCLA Hazardous Substances • EPCRA Section 313 Toxic Chemicals • CAA 112(r) Regulated Chemicals For Accidental Release Prevention Office of Emergency Management This page intentionally left blank. TABLE OF CONTENTS Page Introduction................................................................................................................................................ i List of Lists – Conslidated List of Chemicals (by CAS #) Subject to the Emergency Planning and Community Right-to-Know Act (EPCRA), Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and Section 112(r) of the Clean Air Act ................................................. 1 Appendix A: Alphabetical Listing of Consolidated List ..................................................................... A-1 Appendix B: Radionuclides Listed Under CERCLA .......................................................................... B-1 Appendix C: RCRA Waste Streams and Unlisted Hazardous Wastes................................................ C-1 This page intentionally left blank. LIST OF LISTS Consolidated List of Chemicals
    [Show full text]
  • 2020 Emergency Response Guidebook
    2020 A guidebook intended for use by first responders A guidebook intended for use by first responders during the initial phase of a transportation incident during the initial phase of a transportation incident involving hazardous materials/dangerous goods involving hazardous materials/dangerous goods EMERGENCY RESPONSE GUIDEBOOK THIS DOCUMENT SHOULD NOT BE USED TO DETERMINE COMPLIANCE WITH THE HAZARDOUS MATERIALS/ DANGEROUS GOODS REGULATIONS OR 2020 TO CREATE WORKER SAFETY DOCUMENTS EMERGENCY RESPONSE FOR SPECIFIC CHEMICALS GUIDEBOOK NOT FOR SALE This document is intended for distribution free of charge to Public Safety Organizations by the US Department of Transportation and Transport Canada. This copy may not be resold by commercial distributors. https://www.phmsa.dot.gov/hazmat https://www.tc.gc.ca/TDG http://www.sct.gob.mx SHIPPING PAPERS (DOCUMENTS) 24-HOUR EMERGENCY RESPONSE TELEPHONE NUMBERS For the purpose of this guidebook, shipping documents and shipping papers are synonymous. CANADA Shipping papers provide vital information regarding the hazardous materials/dangerous goods to 1. CANUTEC initiate protective actions. A consolidated version of the information found on shipping papers may 1-888-CANUTEC (226-8832) or 613-996-6666 * be found as follows: *666 (STAR 666) cellular (in Canada only) • Road – kept in the cab of a motor vehicle • Rail – kept in possession of a crew member UNITED STATES • Aviation – kept in possession of the pilot or aircraft employees • Marine – kept in a holder on the bridge of a vessel 1. CHEMTREC 1-800-424-9300 Information provided: (in the U.S., Canada and the U.S. Virgin Islands) • 4-digit identification number, UN or NA (go to yellow pages) For calls originating elsewhere: 703-527-3887 * • Proper shipping name (go to blue pages) • Hazard class or division number of material 2.
    [Show full text]
  • Antimony Pentafluoride Apf
    ANTIMONY PENTAFLUORIDE APF CAUTIONARY RESPONSE INFORMATION 4. FIRE HAZARDS 7. SHIPPING INFORMATION 4.1 Flash Point: 7.1 Grades of Purity: Commercial Common Synonyms Liquid Colorless Sharp odor Not flammable 7.2 Storage Temperature: Ambient 4.2 Flammable Limits in Air: Not flammable 7.3 Inert Atmosphere: No requirement 4.3 Fire Extinguishing Agents: Not pertinent Reacts violently with water. Poisonous gas is produced on contact 7.4 Venting: Pressure-vacuum with water. Freezing point is 45°F. 4.4 Fire Extinguishing Agents Not to Be Used: Do not use water or foam on 7.5 IMO Pollution Category: Currently not available AVOID CONTACT WITH LIQUID AND VAPOR. KEEP PEOPLE AWAY. adjacent fires. 7.6 Ship Type: Currently not available Wear goggles and self-contained breathing apparatus. 4.5 Special Hazards of Combustion 7.7 Barge Hull Type: Currently not available Stop discharge if possible. Products: Not pertinent Call fire department. 4.6 Behavior in Fire: Gives off toxic hydrogen Evacuate. 8. HAZARD CLASSIFICATIONS fluoride fumes when water is used to Isolate and remove discharged material. extinguish adjacent fire. 8.1 49 CFR Category: Corrosive material Notify local health and pollution control agencies. Protect water intakes. 4.7 Auto Ignition Temperature: Not pertinent 8.2 49 CFR Class: 8 4.8 Electrical Hazards: Not pertinent 8.3 49 CFR Package Group: II Not flammable. 4.9 Burning Rate: Not pertinent 8.4 Marine Pollutant: No Fire May cause fire on contact with combustibles. 4.10 Adiabatic Flame Temperature: Not 8.5 NFPA Hazard Classification: POISONOUS GASES ARE PRODUCED WHEN HEATED.
    [Show full text]
  • Hazardous Materials Descriptions and Codes
    2012 Commodity Flow Survey Hazardous Materials Descriptions and Codes Hazardous Materials Descriptions and Proper Shipping Names UN or NA Code Accellerene, see p-Nitrosodimethylaniline Accumulators, electric, see Batteries, wet etc Accumulators, pressurized, pneumatic or hydraulic (containing non-flammable gas), see Articles pressurized, pneumatic or hydraulic (containing non-flammable gas) Acetal 1088 Acetaldehyde 1089 Acetaldehyde ammonia 1841 Acetaldehyde oxime 2332 Acetic acid, glacial or Acetic acid solution, with more than 80 percent acid, by mass 2789 Acetic acid solution, not less than 50 percent but not more than 80 percent acid, by 2790 mass Acetic acid solution, with more than 10 percent and less than 50 percent acid, by mass 2790 Acetic anhydride 1715 Acetone 1090 Acetone cyanohydrin, stabilized 1541 Acetone oils 1091 Acetonitrile 1648 Acetyl bromide 1716 Acetyl chloride 1717 Acetyl iodide 1898 Acetyl methyl carbinol 2621 Acetylene, dissolved 1001 Acetylene tetrabromide, see Tetrabromoethane Acid butyl phosphate, see Butyl acid phosphate Acid, sludge, see Sludge acid Acridine 2713 Acrolein dimer, stabilized 2607 Acrolein, stabilized 1092 Acrylamide, solid 2074 Acrylamide solution 3426 Acrylic acid, stabilized 2218 Acrylonitrile, stabilized 1093 Actuating cartridge, explosive, see Cartridges, power device Adhesives, containing a flammable liquid 1133 Adiponitrile 2205 Aerosols, poison, Packing Group III (each not exceeding 1 L capacity) 1950 Aerosols, flammable, (each not exceeding 1 L capacity) 1950 Source: Electronic Code of Federal Regulations http://ecfr.gpoaccess.gov/cgi/t/text/text- idx?c=ecfr&sid=dfec99df9f21ef29b59a8565433a56cd&rgn=div6&view=text&node=49:2.1.1.3.8.2&idno=49 1 Hazardous Materials Descriptions and Proper Shipping Names UN or NA Code Aerosols, flammable, n.o.s.
    [Show full text]
  • Emergency Planning and Community Right-To-Know
    Emergency Planning and Community Right-to-Know Facility Reporting Compliance Manual Ohio Revised Code Chapter 3750 State Emergency Response Commission January 2021 This program may apply to your facility if it is subject to the OSHA Hazard Communication Standard, and 1) Stores or uses a hazardous chemical in quantities of 10,000 pounds or more, or 2) Stores or uses one or more extremely hazardous substance in quantities of 500 pounds or less. Electronic Reporting Now Available The State Emergency Response Commission incorporates a non-web based reporting software tool to implement an electronic means of reporting in Ohio. Regulated facilities may elect to either submit electronically generated reports using the guidance stated below or may continue to report via the hard copy format as instructed within this compliance manual. The Ohio SERC continues to endorse the U.S. EPA Tier 2 Submit software program. The software can be downloaded directly onto your computer by visiting www.epa.gov/epcra/tier2-submit-software or www.epa.gov/epcra ALL TIER 2 SUBMIT SOFTWARE ASSISTANCE AND/OR QUESTIONS ARE DIRECTED TO THE U.S. EPA RMP REPORTING CENTER AT (703) Important 2020 Users!!! 227-7650 OR VIA EMAIL AT [email protected]. The SERC will rely DO NOT DELETE your 2020 Tier2 Submit after on the U.S. EPA’s webpage as the primary mechanism for you are done. Save it in a file for next year. distributing the reporting software and instructions to all users. Next year you can export/import 2020 Tier2 Ohio EPA will not mass produce or distribute the software or Submit into the updated 2021 Tier2 Submit instructions.
    [Show full text]
  • The Chemical List of Interest
    List of Toxic and Pyrophoric Gases that require preappro val from MSU EHS BEFORE purc hase Chemical MSDS CAS # Health Fire Reactive 1,3-BUTADIENE 1,3-BUTADIENE 106-99-0 2d 4 0 2-METHYL-1,3-BUTADIENE 2-METHYL-1,3-BUTADIENE 78-79-5 1i 4 0 ACETYL FLUORIDE ACETYL FLUORIDE 557-99-3 3 0 0 AMMONIA AMMONIA 7664-41-7 3 1 0 ANTIMONY PENTAFLUORIDE ANTIMONY PENTAFLUORIDE 7783-70-2 4 0 1 ARSENIC PENTAFLUORIDE ARSENIC PENTAFLUORIDE 7784-36-3 3 1 0 ARSENIC TRIFLUORIDE ARSENIC TRIFLUORIDE 7784-35-2 3 0 1 ARSINE ARSINE 7784-42-1 4 4 2 BIS(TRIFLUOROMETHYL)PEROXIDE BIS(TRIFLUOROMETHYL)PEROXIDE 927-84-4 a, j a, j a, j BORON TRIBROMIDE BORON TRIBROMIDE 10294-33-4 4 2 0 BORON TRICHLORIDE BORON TRICHLORIDE 10294-34-5 3 0 1 BORON TRIFLUORIDE BORON TRIFLUORIDE 7637-07-2 4 0 1 BROMINE BROMINE 7726-95-6 3 0 0 BROMINE CHLORIDE BROMINE CHLORIDE 13863-41-7 3 0 1 BROMINE PENTAFLUORIDE BROMINE PENTAFLUORIDE 7789-30-2 3 0 3 BROMINE TRIFLUORIDE BROMINE TRIFLUORIDE 7787-71-5 3 0 3 BROMOETHENE BROMOETHENE 593-60-2 2d 4 1 BROMOMETHANE BROMOMETHANE 74-83-9 3 1 0 CARBON DISULFIDE CARBON DISULFIDE 75-15-0 3 4 0 CARBON MONOXIDE CARBON MONOXIDE 630-08-0 2e 4 0 CARBONYL FLUORIDE CARBONYL FLUORIDE 353-50-4 4 0 1 CARBONYL SULFIDE CARBONYL SULFIDE 463-58-1 3 4 1 CHLORINE CHLORINE 7782-50-5 4 0 0 CHLORINE DIOXIDE CHLORINE DIOXIDE 10049-04-4 3 0 4 CHLORINE MONOXIDE CHLORINE MONOXIDE 12301-79-0 a a a CHLORINE PENTAFLUORIDE CHLORINE PENTAFLUORIDE 13637-63-3 3 0 3 CHLORINE TRIFLUORIDE CHLORINE TRIFLUORIDE 7790-91-2 4 0 3 CHLOROTRIFLUOROETHYLENE CHLOROTRIFLUOROETHYLENE 79-38-9 3 4 3 CARBON
    [Show full text]
  • Antimony Pentafluoride Hazard Summary
    Common Name: ANTIMONY PENTAFLUORIDE CAS Number: 7783-70-2 RTK Substance number: 0144 DOT Number: UN 1732 Date: February 1998 Revision: June 2004 --------------------------------------------------------------------------- --------------------------------------------------------------------------- HAZARD SUMMARY * Antimony Pentafluoride can affect you when breathed in * Exposure to hazardous substances should be routinely and may be absorbed through the skin. evaluated. This may include collecting personal and area * Antimony Pentafluoride is a CORROSIVE CHEMICAL air samples. You can obtain copies of sampling results and contact can severely irritate and burn the skin and eyes from your employer. You have a legal right to this with possible eye damage. information under OSHA 1910.1020. * Exposure to Antimony Pentafluoride can irritate the * If you think you are experiencing any work-related health nose, mouth, throat and lungs causing coughing, wheezing problems, see a doctor trained to recognize occupational and/or shortness of breath. diseases. Take this Fact Sheet with you. * Antimony Pentafluoride can cause headaches, nausea, vomiting and loss of appetite. WORKPLACE EXPOSURE LIMITS * Very high exposure can cause Fluoride poisoning with The following exposure limits are recommended for Antimony stomach pain, weakness, convulsions, collapse and death. and compounds (measured as Antimony): * Prolonged or repeated exposure can cause ulcers and sores OSHA: The legal airborne permissible exposure limit in the nose. (PEL) is 0.5 mg/m3 averaged over an 8-hour * Repeated exposure may affect the lungs and cause an workshift. abnormal chest x-ray to develop. NIOSH: The recommended airborne exposure limit is * Antimony Pentafluoride may damage the kidneys, liver 0.5 mg/m3 averaged over a 10-hour workshift. and heart. ACGIH: The recommended airborne exposure limit is * Repeated high exposure can cause deposits of Fluorides in 0.5 mg/m3 averaged over an 8-hour workshift.
    [Show full text]