Glossary of Semiconductor Terminology A
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10-1 CHAPTER 10 DEFORMATION 10.1 Stress-Strain Diagrams And
EN380 Naval Materials Science and Engineering Course Notes, U.S. Naval Academy CHAPTER 10 DEFORMATION 10.1 Stress-Strain Diagrams and Material Behavior 10.2 Material Characteristics 10.3 Elastic-Plastic Response of Metals 10.4 True stress and strain measures 10.5 Yielding of a Ductile Metal under a General Stress State - Mises Yield Condition. 10.6 Maximum shear stress condition 10.7 Creep Consider the bar in figure 1 subjected to a simple tension loading F. Figure 1: Bar in Tension Engineering Stress () is the quotient of load (F) and area (A). The units of stress are normally pounds per square inch (psi). = F A where: is the stress (psi) F is the force that is loading the object (lb) A is the cross sectional area of the object (in2) When stress is applied to a material, the material will deform. Elongation is defined as the difference between loaded and unloaded length ∆푙 = L - Lo where: ∆푙 is the elongation (ft) L is the loaded length of the cable (ft) Lo is the unloaded (original) length of the cable (ft) 10-1 EN380 Naval Materials Science and Engineering Course Notes, U.S. Naval Academy Strain is the concept used to compare the elongation of a material to its original, undeformed length. Strain () is the quotient of elongation (e) and original length (L0). Engineering Strain has no units but is often given the units of in/in or ft/ft. ∆푙 휀 = 퐿 where: is the strain in the cable (ft/ft) ∆푙 is the elongation (ft) Lo is the unloaded (original) length of the cable (ft) Example Find the strain in a 75 foot cable experiencing an elongation of one inch. -
(Oxy)Hydroxide Electrocatalysts for Water Oxidation Bryan R
www.acsami.org Research Article Effect of Selenium Content on Nickel Sulfoselenide-Derived Nickel (Oxy)hydroxide Electrocatalysts for Water Oxidation Bryan R. Wygant, Anna H. Poterek, James N. Burrow, and C. Buddie Mullins* Cite This: ACS Appl. Mater. Interfaces 2020, 12, 20366−20375 Read Online ACCESS Metrics & More Article Recommendations *sı Supporting Information ABSTRACT: An efficient and inexpensive electrocatalyst for the oxygen evolution reaction (OER) must be found in order to improve the viability of hydrogen fuel production via water electrolysis. Recent work has indicated that nickel chalcogenide materials show promise as electrocatalysts for this reaction and that their performance can be further enhanced with the generation of ternary, bimetallic chalcogenides (i.e., Ni1−aMaX2); however, relatively few studies have investigated ternary chalcogenides created through the addition of a second chalcogen (i.e., NiX2−aYa). To address this, we fi studied a series of Se-modi ed Ni3S2 composites for use as OER electrocatalysts in alkaline solution. We found that the addition of Se results in the creation of Ni3S2/NiSe composites composed of cross-doped metal chalcogenides and show that the addition of 10% Se reduces the overpotential required to reach a current density of 10 mA/cm2 by 40 mV versus a pure nickel sulfide material. Chemical analysis of the composites’ surfaces shows a reduction in the amount of nickel oxide species with Se incorporation, which is supported by transmission electron microscopy; this reduction is correlated with a decrease in the OER overpotentials measured for these samples. Together, our results suggest that the incorporation of Se into Ni3S2 creates a more conductive material with a less-oxidized surface that is more electrocatalytically active and resistant to further oxidation. -
The Effect of Yield Strength on Inelastic Buckling of Reinforcing
Mechanics and Mechanical Engineering Vol. 14, No. 2 (2010) 247{255 ⃝c Technical University of Lodz The Effect of Yield Strength on Inelastic Buckling of Reinforcing Bars Jacek Korentz Institute of Civil Engineering University of Zielona G´ora Licealna 9, 65{417 Zielona G´ora, Poland Received (13 June 2010) Revised (15 July 2010) Accepted (25 July 2010) The paper presents the results of numerical analyses of inelastic buckling of reinforcing bars of various geometrical parameters, made of steel of various values of yield strength. The results of the calculations demonstrate that the yield strength of the steel the bars are made of influences considerably the equilibrium path of the compressed bars within the range of postyielding deformations Comparative diagrams of structural behaviour (loading paths) of thin{walled sec- tions under investigation for different strain rates are presented. Some conclusions and remarks concerning the strain rate influence are derived. Keywords: Reinforcing bars, inelastic buckling, yield strength, tensil strength 1. Introduction The impact of some exceptional loads, e.g. seismic loads, on a structure may re- sult in the occurrence of post{critical states. Therefore the National Standards regulations for designing reinforced structures on seismically active areas e.g. EC8 [15] require the ductility of a structure to be examined on a cross{sectional level, and additionally, the structures should demonstrate a suitable level of global duc- tility. The results of the examinations of members of reinforced concrete structures show that inelastic buckling of longitudinal reinforcement bars occurs in the state of post{critical deformations, [1, 2, 4, 7], and in some cases it occurs yet within the range of elastic deformations [8]. -
Effect of Nitrogen Pressure on the Structure of Cr-N, Ta-N, Mo-N, and WN Nanocrystals Synthesized by Arc Discharge
Hindawi Publishing Corporation Journal of Nanomaterials Volume 2011, Article ID 781935, 5 pages doi:10.1155/2011/781935 Research Article Effect of Nitrogen Pressure on the Structure of Cr-N, Ta-N, Mo-N, and W-N Nanocrystals Synthesized by Arc Discharge Longhai Shen and Nan Wang School of Science, Shenyang Ligong University, Shenyang 110159, China Correspondence should be addressed to Longhai Shen, [email protected] Received 28 March 2011; Revised 10 June 2011; Accepted 5 July 2011 Academic Editor: Theodorian Borca-Tasciuc Copyright © 2011 L. Shen and N. Wang. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The effect of nitrogen pressure on the structure of Ta-N, Cr-N, Mo-N, and W-N nanocrystals formed in arc discharge process was investigated. At the nitrogen pressure of 5 ∼ 20 kPa, the pure cubic-phase TaN and CrN nanocrystals were formed, whereas pure cubic phase of Mo2N and W2N cannot be obtained. A little of metal Mo and a mass of metal W were mixed with the products of Mo2N and W2N, respectively. At the nitrogen pressure of 30 ∼ 50 kPa, subnitride Ta2NandCr2N and metal Cr were gradually formed in the product; furthermore, the proportion of metal Mo and W increased in the product of Mo2N and W2N, respectively. It indicated that the low nitrogen pressure makes cubic mononitride formation favorable. We explain this experimental observation in terms of the evaporation rate of anode metal and the ionization of nitrogen. -
2.1.5 Stress-Strain Relation for Anisotropic Materials
,/... + -:\ 2.1.5Stress-strain Relation for AnisotropicMaterials The generalizedHook's law relatingthe stressesto strainscan be writtenin the form U2, 13,30-32]: o,=C,,€, (i,i =1,2,.........,6) Where: o, - Stress('ompttnents C,, - Elasticity matrix e,-Straincomponents The material properties (elasticity matrix, Cr) has thirty-six constants,stress-strain relations in the materialcoordinates are: [30] O1 LI CT6 a, l O2 03_ a, -t ....(2-6) T23 1/ )1 T32 1/1l 'Vt) Tt2 C16 c66 I The relations in equation (3-6) are referred to as characterizing anisotropicmaterials since there are no planes of symmetry for the materialproperties. An alternativename for suchanisotropic material is a triclinic material. If there is one plane of material property symmetry,the stress- strainrelations reduce to: -'+1-/ ) o1 c| ct2 ct3 0 0 crc €l o2 c12 c22 c23 0 0 c26 a: ct3 C23 ci3 0 0 c36 o-\ o3 ....(2-7) 723 000cqqc450 y)1 T3l 000c4sc5s0 Y3l T1a ct6 c26 c36 0 0 c66 1/t) Where the plane of symmetryis z:0. Such a material is termed monoclinicwhich containstfirfen independentelastic constants. If there are two brthogonalplanes of material property symmetry for a material,symmetry will existrelative to a third mutuallyorthogonal plane. The stress-strainrelations in coordinatesaligned with principal material directionswhich are parallel to the intersectionsof the three orthogonalplanes of materialsymmetry, are'. Ol ctl ct2ctl000 tl O2 Ct2 c22c23000 a./ o3 ct3 c23c33000 * o-\ ....(2-8) T23 0 00c4400 y)1 yll 731 0 000css0 712 0 0000cr'e 1/1) 'lt"' -' , :t i' ,/ Suchmaterial is calledorthotropic material.,There is no interaction betweennormal StreSSeS ot r 02, 03) andanisotropic materials. -
Determination of Focal Length of a Converging Lens and Mirror
Physics 41- Lab 5 Determination of Focal Length of A Converging Lens and Mirror Objective: Apply the thin-lens equation and the mirror equation to determine the focal length of a converging (biconvex) lens and mirror. Apparatus: Biconvex glass lens, spherical concave mirror, meter ruler, optical bench, lens holder, self-illuminated object (generally a vertical arrow), screen. Background In class you have studied the physics of thin lenses and spherical mirrors. In today's lab, we will analyze several physical configurations using both biconvex lenses and concave mirrors. The components of the experiment, that is, the optics device (lens or mirror), object and image screen, will be placed on a meter stick and may be repositioned easily. The meter stick is used to determine the position of each component. For our object, we will make use of a light source with some distinguishing marking, such as an arrow or visible filament. Light from the object passes through the lens and the resulting image is focused onto a white screen. One characteristic feature of all thin lenses and concave mirrors is the focal length, f, and is defined as the image distance of an object that is positioned infinitely far way. The focal lengths of a biconvex lens and a concave mirror are shown in Figures 1 and 2, respectively. Notice the incoming light rays from the object are parallel, indicating the object is very far away. The point, C, in Figure 2 marks the center of curvature of the mirror. The distance from C to any point on the mirror is known as the radius of curvature, R. -
Chapter1: Semiconductor Diode
Chapter1: Semiconductor Diode. Electronics I Discussion Eng.Abdo Salah Theoretical Background: • The semiconductor diode is formed by doping P-type impurity in one side and N-type of impurity in another side of the semiconductor crystal forming a p-n junction as shown in the following figure. At the junction initially free charge carriers from both side recombine forming negatively c harged ions in P side of junction(an atom in P -side accept electron and be comes negatively c harged ion) and po sitive ly c harged ion on n side (an atom in n-side accepts hole i.e. donates electron and becomes positively charged ion)region. This region deplete of any type of free charge carrier is called as depletion region. Further recombination of free carrier on both side is prevented because of the depletion voltage generated due to charge carriers kept at distance by depletion (acts as a sort of insulation) layer as shown dotted in the above figure. Working principle: When voltage is not app lied acros s the diode , de pletion region for ms as shown in the above figure. When the voltage is applied be tween the two terminals of the diode (anode and cathode) two possibilities arises depending o n polarity of DC supply. [1] Forward-Bias Condition: When the +Ve terminal of the battery is connected to P-type material & -Ve terminal to N-type terminal as shown in the circuit diagram, the diode is said to be forward biased. The application of forward bias voltage will force electrons in N-type and holes in P -type material to recombine with the ions near boundary and to flow crossing junction. -
The Influence of Sodium Hydroxide Concentration on the Phase, Morphology and Agglomeration of Cobalt Oxide Nanoparticles and Application As Fenton Catalyst
Digest Journal of Nanomaterials and Biostructures Vol.14, No.4, October-December 2019, p. 1131-1137 THE INFLUENCE OF SODIUM HYDROXIDE CONCENTRATION ON THE PHASE, MORPHOLOGY AND AGGLOMERATION OF COBALT OXIDE NANOPARTICLES AND APPLICATION AS FENTON CATALYST E. L. VILJOENa,*, P. M. THABEDEa, M. J. MOLOTOa, K. P. MUBIAYIb, B. W. DIKIZAa aDepartment of Chemistry, Vaal University of Technology Private, Bag X021, Vanderbijlpark 1900, South Africa bSchool of Chemistry, University of the Witwatersrand, 1 Jan Smuts Avenue, Braamfontein Johannesburg 2000, South Africa The concentration of NaOH was varied from 0.2 M to 0.7 M during the preparation of the cobalt oxide/cobalt oxide hydroxide nanoparticles by precipitation and air oxidation. Cubic shaped and less well defined Co3O4 nanoparticles formed at 0.2 M NaOH. An increase in the NaOH concentration increased the number of well-defined cubic shaped nanoparticles. Agglomerated CoO(OH) particles with different shapes formed at the highest NaOH concentration. The cubic shaped Co3O4 nanoparticles were subsequently used as catalyst for the Fenton degradation of methylene blue and it was found that the least agglomerated nanoparticles were the most catalytically active. (Received June 25, 2019; Accepted December 6, 2019) Keywords: Cobalt oxide, Nanoparticles, Precipitation, pH, Fenton reaction 1. Introduction Controlling the size and the shape of nanoparticles using simple, inexpensive precipitation methods without sophisticated capping molecules, remains a challenge. Literature has indicated that the concentration of the base (pH) is an important parameter to control the size, shape and phase of metal oxide nanoparticles. Obodo et al.[1] used chemical bath deposition at atmospheric pressure and 70 °C to precipitate Co3O4 crystallites on a glass substrate and they showed that the crystallite sizes were larger at a higher pH of 12 in comparison to when a pH of 10 was used. -
How Does the Light Adjustable Lens Work? What Should I Expect in The
How does the Light Adjustable Lens work? The unique feature of the Light Adjustable Lens is that the shape and focusing characteristics can be changed after implantation in the eye using an office-based UV light source called a Light Delivery Device or LDD. The Light Adjustable Lens itself has special particles (called macromers), which are distributed throughout the lens. When ultraviolet (UV) light from the LDD is directed to a specific area of the lens, the particles in the path of the light connect with other particles (forming polymers). The remaining unconnected particles then move to the exposed area. This movement causes a highly predictable change in the curvature of the lens. The new shape of the lens will match the prescription you selected during your eye exam. What should I expect in the period after cataract surgery? Please follow all instructions provided to you by your eye doctor and staff, including wearing of the UV-blocking glasses that will be provided to you. As with any cataract surgery, your vision may not be perfect after surgery. While your eye doctor selected the lens he or she anticipated would give you the best possible vision, it was only an estimate. Fortunately, you have selected the Light Adjustable Lens! In the next weeks, you and your eye doctor will work together to optimize your vision. Please make sure to pay close attention to your vision and be prepared to discuss preferences with your eye doctor. Why do I have to wear UV-blocking glasses? The UV-blocking glasses you are provided with protect the Light Adjustable Lens from UV light sources other than the LDD that your doctor will use to optimize your vision. -
Exploring Density
Exploring Density Students investigate the densities of different liquids and solids and understand how density may help identify a substance. Suggested Grade Range: 6-8 Approximate Time: 1 hour Relevant National Content Standards: Next Generation Science Standards Science and Engineering Practices: Developing and using Models Modeling in 6–8 builds on K–5 experiences and progresses to developing, using, and revising models to describe, test, and predict more abstract phenomena and design systems. • Develop and use a model to describe phenomena. Science and Engineering Practices: Analyzing and Interpreting Data Analyzing data in 6-8 builds on K-5 and progresses to extending quantitative analysis to investigations, distinguishing between correlation and causation, and basic statistical techniques of data and error analysis. • Analyze and interpret data to determine similarities and differences in findings. Disciplinary Core Ideas: PS1.A Structure and Properties of Matter Each pure substance has characteristic physical and chemical properties (for any bulk quantity under given conditions) that can be used to identify it. Common Core State Standard: 7NS 2. Apply and extend previous understanding of multiplication and division and of fractions to multiply and divide rational numbers. 3. Solve real-world and mathematical problems involving the four operations with rational numbers. Common Core State Standard: 7EE Solve real-life and mathematical problems using numerical and algebraic expressions and equations. 4. Use variables to represent -
Answer Key Chapter 16: Standard Review Worksheet – + 1
Answer Key Chapter 16: Standard Review Worksheet – + 1. H3PO4(aq) + H2O(l) H2PO4 (aq) + H3O (aq) + + NH4 (aq) + H2O(l) NH3(aq) + H3O (aq) 2. When we say that acetic acid is a weak acid, we can take either of two points of view. Usually we say that acetic acid is a weak acid because it doesn’t ionize very much when dissolved in water. We say that not very many acetic acid molecules dissociate. However, we can describe this situation from another point of view. We could say that the reason acetic acid doesn’t dissociate much when we dissolve it in water is because the acetate ion (the conjugate base of acetic acid) is extremely effective at holding onto protons and specifically is better at holding onto protons than water is in attracting them. + – HC2H3O2 + H2O H3O + C2H3O2 Now what would happen if we had a source of free acetate ions (for example, sodium acetate) and placed them into water? Since acetate ion is better at attracting protons than is water, the acetate ions would pull protons out of water molecules, leaving hydroxide ions. That is, – – C2H3O2 + H2O HC2H3O2 + OH Since an increase in hydroxide ion concentration would take place in the solution, the solution would be basic. Because acetic acid is a weak acid, the acetate ion is a base in aqueous solution. – – 3. Since HCl, HNO3, and HClO4 are all strong acids, we know that their anions (Cl , NO3 , – and ClO4 ) must be very weak bases and that solutions of the sodium salts of these anions would not be basic. -
Effect of Enzyme/Substrate Ratio on the Antioxidant Properties of Hydrolysed African Yam Bean
African Journal of Biotechnology Vol. 11(50), pp. 11086-11091, 21 June, 2012 Available online at http://www.academicjournals.org/AJB DOI: 10.5897/AJB11.2271 ISSN 1684–5315 ©2012 Academic Journals Full Length Research Paper Effect of enzyme/substrate ratio on the antioxidant properties of hydrolysed African yam bean Fasasi Olufunmilayo*, Oyebode Esther and Fagbamila Oluwatoyin Department of Food Science and Technology, P. M. B. 704, Federal University of Technology, Akure, Nigeria. Accepted 8 June, 2012 The use of natural antioxidant as compared with synthetic antioxidant in food processing is a growing trend as consumers prefer natural to synthetic antioxidant mainly on emotional ground. This study investigates the antioxidant activity of hydrolysed African yam bean (Sphenostylis sternocarpa) which is regarded as one of the neglected underutilized species (NUS) of crop in Africa and Nigeria especially to improve food security and boost the economic importance of the crop. The antioxidant properties of African yam bean hydrolysates (AYH) produced at different enzyme to substrate (E/S) ratios of 1: 100 and 3: 100 (W/V) using pepsin (pH 2.0, 37°C) were studied. 2, 2-Diphenyl-1-picryl-hydrazyl (DPPH) radical scavenging activity of the hydrolysates was significantly influenced by the E\S ratio as DPPH radical scavenging activity ranged from 56.1 to 75.8% in AYH (1: 100) and 33.3 to 58.8% in AYH (3:100) with 1000 µg/ml having the highest DPPH radical scavenging activity. AYH (1:100) and AYH (3:100) had higher reducing activities of 0.42 and 0.23, respectively at a concentration of 1000 µg/ml.