Hindawi Publishing Corporation Journal of Nanomaterials Volume 2011, Article ID 781935, 5 pages doi:10.1155/2011/781935 Research Article Effect of Nitrogen Pressure on the Structure of Cr-N, Ta-N, Mo-N, and W-N Nanocrystals Synthesized by Arc Discharge Longhai Shen and Nan Wang School of Science, Shenyang Ligong University, Shenyang 110159, China Correspondence should be addressed to Longhai Shen,
[email protected] Received 28 March 2011; Revised 10 June 2011; Accepted 5 July 2011 Academic Editor: Theodorian Borca-Tasciuc Copyright © 2011 L. Shen and N. Wang. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The effect of nitrogen pressure on the structure of Ta-N, Cr-N, Mo-N, and W-N nanocrystals formed in arc discharge process was investigated. At the nitrogen pressure of 5 ∼ 20 kPa, the pure cubic-phase TaN and CrN nanocrystals were formed, whereas pure cubic phase of Mo2N and W2N cannot be obtained. A little of metal Mo and a mass of metal W were mixed with the products of Mo2N and W2N, respectively. At the nitrogen pressure of 30 ∼ 50 kPa, subnitride Ta2NandCr2N and metal Cr were gradually formed in the product; furthermore, the proportion of metal Mo and W increased in the product of Mo2N and W2N, respectively. It indicated that the low nitrogen pressure makes cubic mononitride formation favorable. We explain this experimental observation in terms of the evaporation rate of anode metal and the ionization of nitrogen.