Minerals and Rocks Their Properties and Uses
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Midterm 2 Examination Key
GLY4200C Name 90 points October 26, 2011 16 took exam - Numbers to the left of the question number in red are the number of incorrect responses. Instructor comments are in blue. Florida Atlantic University MINERALOGY -- MIDTERM 2 EXAMINATION KEY True-False - Print the letter T or F in the blank to indicate if each of the following statements is true or false. Illegible answers are wrong. (1 point each) 0 T 1. All mathematical groups, including crystallographic point and space groups, must contain an identity operation. 2 F 2. All pyramidal forms are closed. 11 F 3. As nuclei grow, their surface area/volume ratio increases. 1 F 4. Growth twins are always penetration twins. 2 T 5. Low-spin Fe3+ is smaller than high-spin Fe3+. 0 T 6.As pressure increases, minerals transform to denser structures, with atoms packed more closely together 1 T 7. Although silicon normally has CN = IV, in the lower mantle the pressures are so great that the CN of silicon is VI. 2 F 8. If two ions have the same charge, the larger ion will enter a crystal structure preferentially. 2 T 9. Crystal classes are defined by the thirty-two possible point groups. 11 F 10. Possible symmetry operations include rotation axes, mirror planes, and an inversion center. What is wrong with this statement? 0 T 11. Faces composed of all anions or all cations are very high energy. They attract ions of opposite sign, grow rapidly, and may grow themselves out of existence. 1 T 12. The calculation of the zone axis is done using the same method as a vector cross- product. -
Syntectonic Mobility of Supergene Nickel Ores of New Caledonia (Southwest Pacific)
Syntectonic mobility of supergene nickel ores of New Caledonia (Southwest Pacific). Evidence from faulted regolith and garnierite veins. Dominique Cluzel, Benoit Vigier To cite this version: Dominique Cluzel, Benoit Vigier. Syntectonic mobility of supergene nickel ores of New Caledonia (Southwest Pacific). Evidence from faulted regolith and garnierite veins.. Resource Geology, Wiley- Blackwell publishing, 2008, 58 (2), pp.161 - 170. 10.1111/j.1751-3928.2008.00053.x. hal-00161201 HAL Id: hal-00161201 https://hal.archives-ouvertes.fr/hal-00161201 Submitted on 10 Jul 2007 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Syntectonic mobility of supergene nickel ores of New Caledonia (Southwest Pacific). Evidence from faulted regolith and garnierite veins. Dominique CLUZEL and Benoit VIGIER Institut des Sciences de la Terre d'Orléans, ISTO, UMR 6113, University of Orleans, BP 6759, 45067 Orléans Cedex 2, France. [email protected] Running title: Syntectonic mobility of supergene nickel ores Abstract Supergene nickel deposits of New Caledonia that have been formed in the Neogene by weathering of obducted ultramafic rocks are tightly controlled by fracture development. The relationship of tropical weathering and tectonic structures, faults and tension gashes, have been investigated in order to determine whether fractures have play a passive role only, as previously thought; or alternatively, if brittle tectonics was acting together with alteration. -
Rocks and Minerals in This Station-Based Event
Gary Vorwald NYS Rock & Mineral Supervisor Paul J. Gelinas JHS [email protected] Event Description Participants will demonstrate their knowledge of rocks and minerals in this station-based event. A team of up to 2 Approximate time: 40 – 50 Minutes Event Parameters Each team may bring: one magnifying glass One 3-ring binder (1 inch) containing information in any form from any source Materials MUST be 3-hole punched and inserted into the rings (sheet protectors allowed) The Competition Station Event: 15-24 stations with samples & questions Equal time intervals will be allotted for each station. When the signal is given, participants will begin work at their initial station. Participants may not move to the next station until prompted to do so, may not skip stations, nor return to any previously-visited station Mineral and Rock Stations The Competition HCl will not be provided, nor may it be brought to, or be used during the competition. Written descriptions as to how a specimen might react were it to be tested with HCl may be provided. The Competition Identification will be limited to specimens appearing on the Official Science Olympiad Rock and Mineral List (see www.soinc.org) Other rocks or minerals may be used to illustrate key concepts. Tournament Directors may include up to five additional specimens important to their own state. If additional specimens are to be included, all teams must be notified no later than 3 weeks prior to the competition. 2017 Rock & Mineral List Available at: https://www. soinc.org Students should place list in front of notebook Minerals are organized by mineral family Consists of: 59 Minerals 7 Metamorphic Rocks 10 Igneous Rocks 17 Sedimentary Rocks (or varieties) Minerals Native Elements 31. -
Thermal Annealing and Phase Transformation of Serpentine-Like Garnierite
minerals Article Thermal Annealing and Phase Transformation of Serpentine-Like Garnierite Arun Kumar 1,2 , Michele Cassetta 1, Marco Giarola 3, Marco Zanatta 4 , Monique Le Guen 5, Gian Domenico Soraru 6 and Gino Mariotto 1,* 1 Department of Computer Science, University of Verona, 37134 Verona, Italy; [email protected] (A.K.); [email protected] (M.C.) 2 CNR-Institute for Microelectronics and Microsystems, Agrate Brianza, 20864 Agrate, Italy 3 Centro Piattaforme Tecnologiche (CPT), University of Verona, 37134 Verona, Italy; [email protected] 4 Department of Physics, University of Trento, 38123 Povo, Italy; [email protected] 5 Innovation Technology Direction, ERAMET IDEAS, 78190 Trappes, France; [email protected] 6 Department of Industrial Engineering, University of Trento, 38123 Povo, Italy; [email protected] * Correspondence: [email protected] Abstract: This study is focused on the vibrational and microstructural aspects of the thermally induced transformation of serpentine-like garnierite into quartz, forsterite, and enstatite occur- ring at about 620 ◦C. Powder specimens of garnierite were annealed in static air between room temperature and 1000 ◦C. The kinetic of the transformation was investigated by means of thermo- gravimetric and differential thermal analysis, and the final product was extensively characterized via micro-Raman spectroscopy and X-ray diffraction. Our study shows that serpentine-like garnierite consists of a mixture of different mineral species. Furthermore, these garnierites and their compo- sition can provide details based on the mineralogy and the crystalline phases resulting from the thermal treatment. Citation: Kumar, A.; Cassetta, M.; Giarola, M.; Zanatta, M.; Le Guen, M.; Keywords: garnierite; phase transformation; TGA/DSC; XRD; micro-Raman spectroscopy Soraru, G.D.; Mariotto, G. -
Thermal and Infrared Studies of Garnierite from the Soroako Nickeliferous Laterite Deposit, Sulawesi, Indonesia
Indonesian Journal of Geology, Vol. 7 No. 2 June 2012: 77-85 Thermal and Infrared Studies of Garnierite from the Soroako Nickeliferous Laterite Deposit, Sulawesi, Indonesia Analisis Termal dan Inframerah Garnierit dari Endapan Laterit Nikel Saroako, Sulawesi, Indonesia SUFRIADIN1,3*, A. IDRUS1, S. PRAMUMIJOYO1, I W. WARMADA1, I. NUR1,3, A. IMAI2, A.M. IMRAN3, and KAHARUDDIN3 1Department of Geological Engineering, Gadjah Mada University, Yogyakarta 55281, Indonesia 2Department of Earth Science and Technology, Akita University, Akita 010-8512, Japan 3Department of Geological Engineering, Hasanuddin University, Makassar 90245, Indonesia ABSTRACT Mineralogical characterization of some garnierite samples from Soroako have been conducted using X-ray diffraction, thermal analysis, and infrared spectroscopy methods. XRD patterns reveal the samples mainly containing the mixture of kerolite (talc-like phase) and serpentine with minor smectite, sepiolite, and silica. Thermal analyses of garnierite samples indicated by DTA curves are in good agreement with patterns that have been reported in literature. Three endothermic peaks normally occur in the ranges between 58º C and <800º C illustrating three steps of weight losses: adsorbed, bound, and hydroxyl/crystal water. One additional weight loss in low temperature region of sepiolite is corresponding to the lost of zeolitic water. Infrared spectra appeared in 3800 - 3200 cm-1 region generally exhibit broad absorption bands, indicating low crystallinities of studied samples and can be assigned to the presence of hydroxyl group bonded to octahedral coordina- tion mainly Mg atom. The bands observed at 1660 cm-1, 1639 cm-1, 1637 cm-1, and 1633 cm-1 in all samples indicate water molecules. FTIR spectra displaying the strong bands at 1045 cm-1, 1038 cm-1, and 1036 cm-1 could be related to the presence of Si-O-Si bonds linking to tetrahedral coordination. -
Economic Diversification Plan for East Kern County
FEBRUARY 2017 ECONOMIC DIVERSIFICATION PLAN EAST KERN COUNTY, CA KERN COUNTY ACKNOWLEDGEMENTS TIP Strategies would like to thank the many individuals who participated in the creation of this Economic Diversification Plan. We are especially grateful to the members of the East Kern Economic Alliance who contributed their time and input throughout this planning process. Their expertise helped us gain a deep understanding of the region’s range of assets and opportunities. We are also thankful for the US Department of Defense Office of Economic Adjustment for their visionary investments and support which helped make this project a reality. We also want to thank the leadership and staff of Kern County and the Kern EDC for their essential support, guidance, and feedback during the development of this plan. EAST KERN ECONOMIC ALLIANCE KEY STAKEHOLDERS Richard Chapman, President & CEO Jennifer Wood, Mayor Gary Parsons, Economic Kern Economic Development California City Development Manager Corporation City of Ridgecrest Karina Drees, CEO and General Bill Deaver, Michelle Vance, Economic Manager Edwards Community Alliance Development Coordinator Mojave Air & Spaceport City of Tehachapi Kimberly Maevers, President Kelly Bearden, Director Ryan Rush, Field Representative Greater Antelope Valley Economic CSU-Bakersfield SBDC Kern County Board of Supervisors, Alliance 2nd District KERN COUNTY PROJECT TEAM Supervisor Zach Scrivner, Chairman of the Kern County Board of Supervisors & 2nd District Supervisor Teresa Hitchcock, Assistant County Administrative -
Swelling Capacity of Mixed Talc-Like/Stevensite Layers in White/Green Clay
This is a preprint, the final version is subject to change, of the American Mineralogist (MSA) Cite as Authors (Year) Title. American Mineralogist, in press. DOI: https://doi.org/10.2138/am-2020-6984 1 1 Plagcheck: no concerns 2 Tables?: 3 small 3 Word Count: ~9,100 4 Prod notes: make sure tables in file before RE 5 6 7 8 Swelling capacity of mixed talc-like/stevensite layers in white/green clay 9 infillings (‘deweylite’/‘garnierite’) from serpentine veins of faulted 10 peridotites, New Caledonia 11 REVISION 2 12 Lionel FONTENEAU 1, Laurent CANER 2*, Sabine PETIT 2, Farid JUILLOT 3, Florian 13 PLOQUIN 3, Emmanuel FRITSCH 3 14 15 1Corescan Pty Ltd, 1/127 Grandstand Road, 6104 Ascot, WA, Australia 16 2 Université de Poitiers, Institut de Chimie des Milieux et Matériaux de Poitiers, IC2MP UMR 17 7285 CNRS, 5 rue Albert Turpain, TSA51106, 86073 Poitiers cedex 9, France 18 * Corresponding author, e-mail: [email protected] 19 3 Institut de Minéralogie, de Physique des Matériaux et de Cosmochimie (IMPMC), Sorbonne 20 Universités – Université Pierre et Marie Curie UPMC, UMR CNRS 7590, Museum National 21 d’Histoire Naturelle, UMR IRD 206, 101 Promenade Roger Laroque, Anse Vata, 98848, 22 Nouméa, New Caledonia 23 24 25 Abstract: White (Mg-rich) and green (Ni-rich) clay infillings (‘deweylite’/‘garnierite’) found 26 in serpentine veins of faulted peridotite formations from New Caledonia consist of an intimate 27 mixture of fine-grained and poorly ordered 1:1 and 2:1 layer silicates, commonly referred to 28 as non-expandable serpentine-like (SL) and talc-like (TL) minerals. -
Inyoite Cab3o3(OH)5 • 4H2O C 2001-2005 Mineral Data Publishing, Version 1
Inyoite CaB3O3(OH)5 • 4H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Typically as crystals, short prismatic along [001], tabular on {001}, exhibiting prominent {110} and {001} and a dozen other minor forms, to 2.5 cm; in cockscomb aggregates of pseudorhombohedral crystals; also coarse spherulitic, granular. Physical Properties: Cleavage: {001}, good; {010}, distinct. Fracture: Irregular. Tenacity: Brittle. Hardness = 2 D(meas.) = 1.875 D(calc.) = 1.87 Soluble in H2O. Optical Properties: Transparent, translucent on dehydration. Color: Colorless, white on dehydration. Luster: Vitreous. Optical Class: Biaxial (–). Orientation: Y = b; X ∧ c =37◦; Z ∧ c = –53◦. Dispersion: r< v, slight. α = 1.490–1.495 β = 1.501–1.505 γ = 1.516–1.520 2V(meas.) = 70◦–86◦ Cell Data: Space Group: P 21/a. a = 10.621(1)) b = 12.066(1) c = 8.408(1) β = 114◦1.2◦ Z=4 X-ray Powder Pattern: Monte Azul mine, Argentina. 7.67 (100), 2.526 (25), 3.368 (22), 1.968 (22), 2.547 (21), 3.450 (20), 2.799 (19) Chemistry: (1) (2) B2O3 37.44 37.62 CaO 20.42 20.20 + H2O 9.46 − H2O 32.46 H2O 42.18 rem. 0.55 Total 100.33 100.00 • (1) Hillsborough, Canada; remnant is gypsum. (2) CaB3O3(OH)5 4H2O. Occurrence: Along fractures and nodular in sedimentary borate deposits; may be authigenic in playa sediments. Association: Meyerhofferite, colemanite, priceite, hydroboracite, ulexite, gypsum. Distribution: In the USA, in California, from an adit on Mount Blanco, Furnace Creek district, Death Valley, Inyo Co., and in the Kramer borate deposit, Boron, Kern Co. -
Ulexite Nacab5o6(OH)6 • 5H2O C 2001-2005 Mineral Data Publishing, Version 1 Crystal Data: Triclinic
Ulexite NaCaB5O6(OH)6 • 5H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Triclinic. Point Group: 1. Rare as measurable crystals, which may have many forms; typically elongated to acicular along [001], to 5 cm, then forming fibrous cottonball-like masses; in compact parallel fibrous veins, and radiating and compact nodular groups. Twinning: Polysynthetic on {010} and {100}; possibly also on {340}, {230}, and others. Physical Properties: Cleavage: On {010}, perfect; on {110}, good; on {110}, poor. Fracture: Uneven across fiber groups. Tenacity: Brittle. Hardness = 2.5 D(meas.) = 1.955 D(calc.) = 1.955 Slightly soluble in H2O; parallel fibrous masses can act as fiber optical light pipes; may fluoresce yellow, greenish yellow, cream, white under SW and LW UV. Optical Properties: Transparent to opaque. Color: Colorless; white in aggregates, gray if included with clays. Luster: Vitreous; silky or satiny in fibrous aggregates. Optical Class: Biaxial (+). Orientation: X (11.5◦,81◦); Y (100◦,21.5◦); Z (107◦,70◦) [with c (0◦,0◦) and b∗ (0◦,90◦) using (φ,ρ)]. α = 1.491–1.496 β = 1.504–1.506 γ = 1.519–1.520 2V(meas.) = 73◦–78◦ Cell Data: Space Group: P 1. a = 8.816(3) b = 12.870(7) c = 6.678(1) α =90.36(2)◦ β = 109.05(2)◦ γ = 104.98(4)◦ Z=2 X-ray Powder Pattern: Jenifer mine, Boron, California, USA. 12.2 (100), 7.75 (80), 6.00 (30), 4.16 (30), 8.03 (15), 4.33 (15), 3.10 (15b) Chemistry: (1) (2) B2O3 43.07 42.95 CaO 13.92 13.84 Na2O 7.78 7.65 H2O 35.34 35.56 Total 100.11 100.00 • (1) Suckow mine, Boron, California, USA. -
THE MAIN-GROUP ELEMENTS Atomic Properties
THE MAIN-GROUP ELEMENTS Atomic Properties Properties of elements is based valence-shell electron configurations. Five atomic properties: 1. atomic radius 2. ionization energy 3. electron affinity 4. electronegativity 5. polarizability Atomic Size Adding more valence levels increases the distance from the electrons to the nucleus, it also decrease the effect the nucleus has on the outer electrons. decreases across a period Effective Nuclear Force increases down a group Valence levels Ionization Energy Ionization energy: the energy required to remove the most loosely held electron from an atom in the gaseous state. Size of Atom Ionization Energy Smaller size Higher ionization energy Electron Affinity The electron affinity is a release of energy to form an anion. Ionization Energy Electron Affinity Atoms with higher effective nuclear charges release more energy. Electronegativity Electronegativity is the tendency of an atom to attract electrons to itself. Ionization Energy Electronegativity Atoms with a greater effective nuclear charge have a stronger pull on bonding electrons. Large differences in electronegativity typically form ionic bonds and small differences from covalent bonds. Polarizability Polarizability is the ease an atoms electron cloud can be distorted. Size of Atom Polarizability Electron-rich, heavier atoms are easily polarized. High polarizing power atom-are small sized, highly charged atoms. Bonding Trends Elements in period 2 strictly follow the octet rule; carbon forms four bonds. Elements in Period 3 and higher periods exceed the octet. They reach higher oxidation states because they can access empty d-orbitals. Also, larger atoms can simply make more bonds to more neighbors . Group 1A: Alkali Metals The chemical properties of alkali metals are striking similar. -
The Phase Diversity of Nickel Phyllosilicates from New Caledonia: an Investigation Using Transmission Electron Microscopy (TEM) STUDENT: Brittany A
THE PHASE DIVERSITY OF NICKEL PHYLLOSILICATES FROM NEW CALEDONIA: AN INVESTIGATION USING TRANSMISSION ELECTRON MICROSCOPY (TEM) A THESIS SUBMITTED TO THE GRADUATE SCHOOL IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE MASTER OF SCIENCE BY BRITTANY CYMES DR. KIRSTEN NICHOLSON – ADVISOR BALL STATE UNIVERSITY MUNCIE, INDIANA MAY 2016 ABSTRACT THESIS: The Phase Diversity of Nickel Phyllosilicates from New Caledonia: An Investigation Using Transmission Electron Microscopy (TEM) STUDENT: Brittany A. Cymes DEGREE: Master of Science COLLEGE: Sciences and Humanities DATE: May, 2016 PAGES: 136 New Caledonia is a French territorial island in the Southwest Pacific with an economy heavily dependent upon nickel-mining, being the 5th largest producer worldwide. The nickel deposits result from tropical lateritic weathering of ophiolite units that were emplaced during the late Eocene. The ultramafic units weathered and continue to weather into bright green Ni-rich phyllosilicates colloquially referred to as „garnierite‟. Detailed investigations of „garnierite‟ using transmission electron microscopy (TEM) have been carried out in other locations to characterize important nanoscale features; however, none have been undertaken in New Caledonia. In this investigation, ten samples of „garnierite‟ from New Caledonia were examined with powder X-ray diffraction (XRD) and TEM with energy dispersive spectrometry (EDS). The XRD results show the phyllosilicate material to be comprised of highly disordered talc- and serpentine-like minerals with minor chlorite indicated by significantly broad reflections and two- i dimensional diffraction bands, consistent with published data. TEM analysis, however, revealed new information. Talc-like minerals occur as fluffy aggregates of crystals with lattices with approximately 10 Å d-spacing and significant crystallographic disorder and also as aggregates of larger crystals with more orderly lattices; these two varieties represent the kerolite-pimelite series and the talc- willemseite series, respectively. -
Talc- and Serpentine-Like “Garnierites” from Falcondo Ni
macla nº 15 . septiembre 2011 revista de la sociedad española de mineralogía 197 Talc- and Serpentine-like “Garnierites” from Falcondo Ni-laterite Deposit (Dominican Republic): a HRTEM approach / CRISTINA VILLANOVA-DE-BENAVENT (1,*), FERNANDO NIETO (2), JOAQUÍN A. PROENZA (1), SALVADOR GALÍ (1) (1) Departament de Cristal·lografia, Mineralogia i Dipòsits Minerals. Facultat de Geologia. Universitat de Barcelona. C/ Martí i Franquès s/n. 08028 Barcelona, Catalunya (España) (2) Departamento de Mineralogía y Petrología e Instituto Andaluz de Ciencias de la Tierra. Universidad de Granada-CSIC. Campus de • Fuerteventura s/n. 18002 Granada (España) INTRODUCTION. from Falcondo Ni-laterite deposit. These “garnierites” mainly occur as mm-cm results are compared to those previously vein fillings in fractures, but also as “Garnierites” represent significant Ni ore obtained through powder XRD and EMP coatings, boxworks and different kinds minerals in the lower horizons of many (CCiT, Universitat de Barcelona). of breccias, within the saprolite horizon Ni-laterite deposits worldwide (e.g. or near the unweathered peridotite, Freyssinet et al., 2005). They consist of Preliminary data allows to classify the close to the base of the lateritic profile. a green, fine-grained mixture of hydrous sampled “garnierites” into two groups, Ni-bearing magnesium phyllosilicates, which display two well distinguishable METHODOLOGY. including serpentine, talc, sepiolite, greenish colours in hand specimen: smectite and chlorite (e.g. Brindley and A representative sample, containing Hang, 1973; Springer, 1974; Brindley et • Bluish bright-green “garnierites” strongly serpentinized peridotite al., 1979). Thus, “garnierite” is a general display colloform textures under the (saprolite) cross-cut by talc-like and descriptive term and is not recognized optical microscope.