Interview with Leon T. Silver
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Health Concerns of Heavy Metals (Pb; Cd; Hg) and Metalloids (As)
Health concerns of the heavy metals and metalloids Chris Cooksey • Toxicity - acute and chronic • Arsenic • Mercury • Lead • Cadmium Toxicity - acute and chronic Acute - LD50 Trevan, J. W., 'The error of determination of toxicity', Proc. Royal Soc., 1927, 101B, 483-514 LD50 (rat, oral) mg/kg CdS 7080 NaCl 3000 As 763 HgCl 210 NaF 52 Tl2SO4 16 NaCN 6.4 HgCl2 1 Hodge and Sterner Scale (1943) Toxicity Commonly used term LD50 (rat, oral) Rating 1 Extremely Toxic <=1 2 Highly Toxic 1 - 50 3 Moderately Toxic 50 - 500 4 Slightly Toxic 500 - 5000 5 Practically Non-toxic 5000 - 15000 6 Relatively Harmless >15000 GHS - CLP LD50 Category <=5 1 Danger 5 - 50 2 Danger 50 - 300 3 Danger 300 - 2000 4 Warning Globally Harmonised System of Classification and Labelling and Packaging of Chemicals CLP-Regulation (EC) No 1272/2008 Toxicity - acute and chronic Chronic The long-term effect of sub-lethal exposure • Toxicity - acute and chronic • Arsenic • Mercury • Lead • Cadmium Arsenic • Pesticide o Inheritance powder • Taxidermy • Herbicide o Agent Blue • Pigments • Therapeutic uses Inorganic arsenic poisoning kills by allosteric inhibition of essential metabolic enzymes, leading to death from multi- system organ failure. Arsenicosis - chronic arsenic poisoning. Arsenic LD50 rat oral mg/kg 10000 1000 LD50 100 10 1 Arsine Arsenic acid Trimethylarsine Emerald green ArsenicArsenious trisulfide oxideSodium arsenite MethanearsonicDimethylarsinic acid acid Arsenic poisoning by volatile arsenic compounds from mouldy wall paper in damp rooms • Gmelin (1839) toxic mould gas • Selmi (1874) AsH3 • Basedow (1846) cacodyl oxide • Gosio (1893) alkyl arsine • Biginelli (1893) Et2AsH • Klason (1914) Et2AsO • Challenger (1933) Me3As • McBride & Wolfe (1971) Me2AsH or is it really true ? William R. -
Historical Group
Historical Group NEWSLETTER and SUMMARY OF PAPERS No. 61 Winter 2012 Registered Charity No. 207890 COMMITTEE Chairman: Prof A T Dronsfield, School of Education, | Prof J Betteridge (Twickenham, Middlesex) Health and Sciences, University of Derby, | Dr N G Coley (Open University) Derby, DE22 1GB [e-mail [email protected]] | Dr C J Cooksey (Watford, Hertfordshire) Secretary: | Prof E Homburg (University of Maastricht) Prof W P Griffith, Department of Chemistry, | Prof F James (Royal Institution) Imperial College, South Kensington, London, | Dr D Leaback (Biolink Technology) SW7 2AZ [e-mail [email protected]] | Dr P J T Morris (Science Museum) Treasurer; Membership Secretary: | Prof. J. W. Nicholson (University of Greenwich) Dr J A Hudson, Graythwaite, Loweswater, | Mr P N Reed (Steensbridge, Herefordshire) Cockermouth, Cumbria, CA13 0SU | Dr V Quirke (Oxford Brookes University) [e-mail [email protected]] | Dr S Robinson (Ham, Surrey) Newsletter Editor: | Prof. H. Rzepa (Imperial College) Dr A Simmons, Epsom Lodge, | Dr. A Sella (University College) La Grande Route de St Jean,St John, Jersey, JE3 4FL [e-mail [email protected]] Newsletter Production: Dr G P Moss, School of Biological and Chemical, Sciences Queen Mary University of London, Mile End Road, London E1 4NS [e-mail [email protected]] http://www.chem.qmul.ac.uk/rschg/ http://www.rsc.org/membership/networking/interestgroups/historical/index.asp Contents From the Editor 2 RSC Historical Group News - Bill Griffith 3 Identification Query - W. H. Brock 4 Members’ Publications 5 NEWS AND UPDATES 6 USEFUL WEBSITES AND ADDRESSES 7 SHORT ESSAYS 9 The Copperas Works at Tankerton - Chris Cooksey 9 Mauveine - the final word? (3) - Chris Cooksey and H. -
Yale Law School 2007-2008
bulletin of yale university bulletin of yale Series 1o3 8 Number 10, 2007 August 2007–2008 Yale Law School Yale bulletin of yale university August 10, 2007 Yale Law School Periodicals postage paid Periodicals Connecticut Haven, New 06520-8227 CT New Haven Haven New bulletin of yale university bulletin of yale Bulletin of Yale University The University is committed to basing judgments concerning the admission, education, and employment of individuals upon their qualifications and abilities and a∞rmatively Postmaster: Send address changes to Bulletin of Yale University, seeks to attract to its faculty, sta≠, and student body qualified persons of diverse back- PO Box 208227, New Haven CT 06520-8227 grounds. In accordance with this policy and as delineated by federal and Connecticut law, Yale does not discriminate in admissions, educational programs, or employment PO Box 208230, New Haven CT 06520-8230 against any individual on account of that individual’s sex, race, color, religion, age, Periodicals postage paid at New Haven, Connecticut disability, status as a special disabled veteran, veteran of the Vietnam era, or other covered veteran, or national or ethnic origin; nor does Yale discriminate on the basis of Issued seventeen times a year: one time a year in May, November, and December; sexual orientation or gender identity or expression. two times a year in June; three times a year in July and September; six times a year University policy is committed to a∞rmative action under law in employment of in August women, minority group members, individuals with disabilities, special disabled veterans, veterans of the Vietnam era, and other covered veterans. -
SULLIVAN-THESIS-2017.Pdf (2.553Mb)
APPLICATIONS OF THE OSMIUM ISOTOPIC SYSTEM AND RHENIUM- PLATINUM GROUP ELEMENT CONCENTRATIONS IN ORGANIC-RICH MUD ROCKS FROM THE EAGLE FORD FORMATION, TEXAS: A GEOCHEMISTRY AND REDOX STUDY A Thesis Presented to the Faculty of the Department of Earth and Atmospheric Sciences University of Houston ________________________________________ In Partial Fulfillment of the Requirements for the Degree Master of Science _________________________________________ By Daniel Louis Sullivan May 2017 APPLICATIONS OF THE OSMIUM ISOTOPIC SYSTEM AND RHENIUM- PLATINUM GROUP ELEMENT CONCENTRATIONS IN ORGANIC-RICH MUD ROCKS FROM THE EAGLE FORD FORMATION, TEXAS: A GEOCHEMISTRY AND REDOX STUDY _______________________________________ Dan Sullivan APPROVED: _______________________________________ Dr. Alan Brandon, Chairman _______________________________________ Dr. Qi Fu _______________________________________ Dr. Steven Bergman _______________________________________ Dean, College of Natural Sciences and Mathematics ii “True scientific discovery renders the brain incapable at such moments of shouting vigorously to the world ‘Look at what I’ve done! Now I will reap the benefits of recognition and wealth.’ Instead such discovery instinctively forces the brain to thunder ‘We did it’ in a voice no one else can hear, within its sacred, but lonely, chapel of scientific thought. — Clair Cameron Patterson, reacting to being the first person to discover the age of the earth. “I believe in intuition and inspiration. Imagination is more important than knowledge. For knowledge -
Catherine A. Wright
In the Darkness Grows the Green: The Promise of a New Cosmological Horizon of Meaning Within a Critical Inquiry of Human Suffering and the Cross by Catherine A. Wright A Thesis submitted to the Faculty of Regis College and the Theology Department of the Toronto School of Theology in partial fulfilment of the requirements for the degree of Doctor of Philosophy in Theology awarded by the University of St. Michael's College © Copyright by Catherine A. Wright 2015 In The Darkness Grows the Green: The Promise of a New Cosmological Horizon of Meaning Within a Critical Inquiry of Human Suffering and the Cross Catherine A. Wright Doctor of Philosophy in Theology Regis College and the University of St. Michael’s College 2015 Abstract Humans have been called “mud of the earth,”i organic stardust animated by the Ruah of our Creator,ii and microcosms of the macrocosm.iii Since we now understand in captivating detail how humanity has emerged from the cosmos, then we must awaken to how humanity is “of the earth” in all the magnificence and brokenness that this entails. This thesis will demonstrate that there are no easy answers nor complete theological systems to derive satisfying answers to the mystery of human suffering. Rather, this thesis will uncover aspects of sacred revelation offered in and through creation that could mould distinct biospiritual human imaginations and cultivate the Earth literacy required to construct an ecological theological anthropology (ETA). It is this ecocentric interpretive framework that could serve as vital sustenance and a vision of hope for transformation when suffering befalls us. -
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Pb) and Clinical Disparities in Pre- and Post-Katrina New Orleans
Int. J. Environ. Res. Public Health 2014, 11, 7482-7491; doi:10.3390/ijerph110707482 OPEN ACCESS International Journal of Environmental Research and Public Health ISSN 1660-4601 www.mdpi.com/journal/ijerph Review Evolving from Reactive to Proactive Medicine: Community Lead (Pb) and Clinical Disparities in Pre- and Post-Katrina New Orleans Howard W. Mielke 1,*, Christopher Gonzales 2,†, Eric Powell 2 and Paul W. Mielke 3,† 1 Department of Pharmacology, Tulane University School of Medicine, New Orleans, LA 70112, USA 2 Lead Lab, Inc., New Orleans, LA 70119, USA; E-Mails: [email protected] (C.G.); [email protected] (E.P.) 3 Department of Statistics, Colorado State University, Fort Collins, CO 80523, USA; E-Mail: [email protected] † These authors contributed equally to this work. * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel.: +1-504-988-3889; Fax: +1-504-988-6428. Received: 16 December 2013; in revised form: 12 March 2014 / Accepted: 13 March 2014 / Published: 21 July 2014 Abstract: In 2012 the U.S. Centers for Disease Control (CDC) set the blood Pb reference value at ≥5 µg/dL. Clinical analysis of children’s blood Pb levels is the common way to diagnose environmental Pb contamination, and intervention ensues with education and household dust cleanup. Recent review indicates that education and household dust cleanup are not effective at reducing children’s Pb exposure. Here we review mapping environmental Pb and children’s blood Pb response as an alternative approach for proactive Pb dust intervention. New Orleans was divided into a high (≥100 mg/kg) and low (<100 mg/kg) soil Pb communities. -
Dear Friends
Department of Earth and Planetary Sciences University of Tennessee, Knoxville 2005 Annual Newsletter 2005 Newsletter Department of Earth and Planetary Sciences University of Tennessee, Knoxville Editors: Larry McKay and Bill Deane Cover photos: Top Right: Geology 586 – Field and Lab Methods in Hydrogeology – goes caving. Photo courtesy of Larry McKay. Top Left: This specimen measuring 40 mm is Pentremites robustus from the Sloan's Valley Member of the Pennington Formation, Upper Mississippian from near Berea, Kentucky. Photo courtesy of Colin Sumrall. Bottom: No, this is not the Vol Navy! Larry McKay and Vijay Vulava are preparing to collect sediments from Chattanooga Creek. Photo courtesy of Larry McKay. The University of Tennessee does not discriminate on the basis of race, sex, religion, national origin, age, disability, or veteran status in provision of educational programs and services or employment opportunities and benefits. This policy extends to both employment and admission to the University. The University does not discriminate on the basis of race, sex or disability in the educational programs and activities pursuant to the requirements of the Title VI of the Civil Rights Act of 1964, Title IX of the Educational Amendments of 1972, Section 504 of the Rehabilitation Act of 1973, and the Americans with Disabilities Act (ADA) of 1990. Inquiries and charges of violation concerning Title VI, Title IX, Section 504, ADA or the Age Discrimination in Employment Act (ADEA) or any of the other above referenced policies should be directed to the Office of Equity and Diversity (OED), 1840 Melrose Avenue, Knoxville, TN 37996-3560, telephone (865) 974- 2498 (V/TTY available) or 974-2440. -
Charles G. Dawes Archive
Charles Deering McCormick Library of Special Collections Northwestern University Library, Evanston, Illinois 60208-2300 Charles G. Dawes Archive Biography: Charles Gates Dawes (1865-1951), prominent in U.S. politics and business, served as Comptroller of the Currency (1898-1901), director of the Military Board of Allied Supply (1918-1919), and first director of the Bureau of the Budget (1921). He received a Nobel Peace Prize as chairman of the Reparations Commission which restructured Germany's economy and devised a repayment plan (1924). He was elected Vice-President (1925- 1929), and appointed ambassador to England (1929-1931) and chairman of the Reconstruction Finance Corporation (1932). Charles and his brothers founded Dawes Brothers Incorporated. Dawes formed the Central Trust Co. in Chicago (1902), guided its successor banks, and was influential in Chicago business, politics, and philanthropy until his death. Charles Gates Dawes was born and educated in Ohio. He married Caro Blymyer in 1889, practiced law, and incorporated a real estate business in Lincoln, Nebraska, before moving to Evanston, Illinois in 1895. He acquired utility companies and real estate in northern Illinois and Wisconsin; and in 1908, with his brothers Henry, Rufus, and Beman, formed Dawes Brothers Incorporated, to invest assets in banks, oil companies and real estate throughout the country. Various acquaintances who were prominent in political and industrial affairs trusted them to manage their investments as well. Other companies in which Charles Dawes and his brothers played leading roles included Chicago's Central Trust Co. and its successor banks and Pure Oil Company of Ohio. Dawes made significant philanthropic contributions to the Chicago metropolitan community. -
Albert Francis Birch 3 by Thomas J
http://www.nap.edu/catalog/6201.html We ship printed books within 1 business day; personal PDFs are available immediately. Biographical Memoirs V.74 Office of the Home Secretary, National Academy of Sciences ISBN: 0-309-59186-4, 398 pages, 6 x 9, (1998) This PDF is available from the National Academies Press at: http://www.nap.edu/catalog/6201.html Visit the National Academies Press online, the authoritative source for all books from the National Academy of Sciences, the National Academy of Engineering, the Institute of Medicine, and the National Research Council: • Download hundreds of free books in PDF • Read thousands of books online for free • Explore our innovative research tools – try the “Research Dashboard” now! • Sign up to be notified when new books are published • Purchase printed books and selected PDF files Thank you for downloading this PDF. If you have comments, questions or just want more information about the books published by the National Academies Press, you may contact our customer service department toll- free at 888-624-8373, visit us online, or send an email to [email protected]. This book plus thousands more are available at http://www.nap.edu. Copyright © National Academy of Sciences. All rights reserved. Unless otherwise indicated, all materials in this PDF File are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited without written permission of the National Academies Press. Request reprint permission for this book. i ined, a he original t be ret Biographical Memoirs ion. om r f ibut r t cannot not r at o f book, however, version ng, i t at ive NATIONAL ACADEMY OF SCIENCES at rm riginal paper it o f c hor i f he o t om r he aut f ng-speci http://www.nap.edu/catalog/6201.html Biographical MemoirsV.74 as t ed i t ion peset y iles creat L f her t M is publicat h X t of om and ot r f yles, version posed Copyright © National Academy ofSciences. -
Department of Geological Sciences Newsletter No. 20, September 1971
Department of Geological Sciences Newsletter THE UNIVERSITY OF TEXAS AT AUSTIN NO. 20, September1971 FredBullard Honored at Dinner On the evening of May 9 about 200 friends and former Azores, the Philippines,New Guinea, Slovakia,and of course, students gathered to pay tribute to Fred Bullard at a dinner Italy. Out of this have come uncounted fascinating lectures at the Villa Capri in Austin. Fred has reached the age of and a book on volcanoes so popular that it is in its fourth mandatory retirement from full-time teaching, and in spite printingandbeingrevisedcurrentlybyFred. of his continued ability andyouthful appearance,he is bring- Fred Bullard was Chairman of the Department of Geology ing his record performance as a professor to a close. His for eight years (1929-1937), and for many years he taught charm and talent as alecturer are truly superb, as everyone the courses in mineralogy, petrography, field geology and learned again that evening. several other subjects as needed. His lectures in freshmen Fred has been in the teachingprofession for 47 years, and geology were always popular but he never made the course he hasprobably taught elementary geology to morethousands easy, as many will recall. Fred helped create and sustain a of students than any other professor in the world. In recent great tradition in this department: senior professors and years he has grown accustomed to discovering the children permanent staff members do nearly all the lecturing to fresh- of his former students attending his current classes, and one men, and they take pride in the task. As Professor Emeritus, young student at the dinner, Carolyn Keyser, was preceded Fred will no longer lecture to large freshman classes, but he by both her mother, Jean Funkhouser, and her grandfather, can probably be persuaded to teach a graduate class in vol- Ernest Funkhouser,inFred'sclasses. -
Transcribed Excerpts from Clair Cameron Patterson's Biography
Transcribed Excerpt from Biography of Clair Cameron Patterson, 1998 Claire Patterson was an energetic, innovative, determined scientist whose pioneering work stretched across an unusual number of sub-disciplines, including archeology, meteorology, oceanography, and environmental science—besides chemistry and geology. He is best known for his determination of the age of the Earth. That was possible only after he had spent some five years establishing methods for the separation and isotopic analysis of lead at microgram and sub-microgram levels. His techniques opened a new field in lead isotope geochemistry for terrestrial as well as for planetary studies. Whereas terrestrial lead isotope data had been based entirely on galena ore samples, isotopes could finally be measured on ordinary igneous rocks and sediments, greatly expanding the utility of the technique. While subsequently applying the methodology to ocean sediments, he came to the conclusion that the input of lead into the oceans was much greater than the removal of lead to sediments, because human activities were polluting the environment with unprecedented, possibly dangerous, levels of lead. Then followed years of study and debate involving him and other investigators and politicians over control of lead in the environment. In the end, his basic views prevailed, resulting in drastic reductions in the amount of lead entering the environment. Thus, in addition to measuring the age of the Earth and significantly expanding the field of lead isotope geochemistry, Patterson applied his scientific expertise to create a healthier environment for society. IOWA DEPARTMENT OF CULTURAL AFFAIRS 600 E. LOCUST ST. DES MOINES, IA 50319 IOWACULTURE.GOV .