Age of the Earth
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Health Concerns of Heavy Metals (Pb; Cd; Hg) and Metalloids (As)
Health concerns of the heavy metals and metalloids Chris Cooksey • Toxicity - acute and chronic • Arsenic • Mercury • Lead • Cadmium Toxicity - acute and chronic Acute - LD50 Trevan, J. W., 'The error of determination of toxicity', Proc. Royal Soc., 1927, 101B, 483-514 LD50 (rat, oral) mg/kg CdS 7080 NaCl 3000 As 763 HgCl 210 NaF 52 Tl2SO4 16 NaCN 6.4 HgCl2 1 Hodge and Sterner Scale (1943) Toxicity Commonly used term LD50 (rat, oral) Rating 1 Extremely Toxic <=1 2 Highly Toxic 1 - 50 3 Moderately Toxic 50 - 500 4 Slightly Toxic 500 - 5000 5 Practically Non-toxic 5000 - 15000 6 Relatively Harmless >15000 GHS - CLP LD50 Category <=5 1 Danger 5 - 50 2 Danger 50 - 300 3 Danger 300 - 2000 4 Warning Globally Harmonised System of Classification and Labelling and Packaging of Chemicals CLP-Regulation (EC) No 1272/2008 Toxicity - acute and chronic Chronic The long-term effect of sub-lethal exposure • Toxicity - acute and chronic • Arsenic • Mercury • Lead • Cadmium Arsenic • Pesticide o Inheritance powder • Taxidermy • Herbicide o Agent Blue • Pigments • Therapeutic uses Inorganic arsenic poisoning kills by allosteric inhibition of essential metabolic enzymes, leading to death from multi- system organ failure. Arsenicosis - chronic arsenic poisoning. Arsenic LD50 rat oral mg/kg 10000 1000 LD50 100 10 1 Arsine Arsenic acid Trimethylarsine Emerald green ArsenicArsenious trisulfide oxideSodium arsenite MethanearsonicDimethylarsinic acid acid Arsenic poisoning by volatile arsenic compounds from mouldy wall paper in damp rooms • Gmelin (1839) toxic mould gas • Selmi (1874) AsH3 • Basedow (1846) cacodyl oxide • Gosio (1893) alkyl arsine • Biginelli (1893) Et2AsH • Klason (1914) Et2AsO • Challenger (1933) Me3As • McBride & Wolfe (1971) Me2AsH or is it really true ? William R. -
Historical Group
Historical Group NEWSLETTER and SUMMARY OF PAPERS No. 61 Winter 2012 Registered Charity No. 207890 COMMITTEE Chairman: Prof A T Dronsfield, School of Education, | Prof J Betteridge (Twickenham, Middlesex) Health and Sciences, University of Derby, | Dr N G Coley (Open University) Derby, DE22 1GB [e-mail [email protected]] | Dr C J Cooksey (Watford, Hertfordshire) Secretary: | Prof E Homburg (University of Maastricht) Prof W P Griffith, Department of Chemistry, | Prof F James (Royal Institution) Imperial College, South Kensington, London, | Dr D Leaback (Biolink Technology) SW7 2AZ [e-mail [email protected]] | Dr P J T Morris (Science Museum) Treasurer; Membership Secretary: | Prof. J. W. Nicholson (University of Greenwich) Dr J A Hudson, Graythwaite, Loweswater, | Mr P N Reed (Steensbridge, Herefordshire) Cockermouth, Cumbria, CA13 0SU | Dr V Quirke (Oxford Brookes University) [e-mail [email protected]] | Dr S Robinson (Ham, Surrey) Newsletter Editor: | Prof. H. Rzepa (Imperial College) Dr A Simmons, Epsom Lodge, | Dr. A Sella (University College) La Grande Route de St Jean,St John, Jersey, JE3 4FL [e-mail [email protected]] Newsletter Production: Dr G P Moss, School of Biological and Chemical, Sciences Queen Mary University of London, Mile End Road, London E1 4NS [e-mail [email protected]] http://www.chem.qmul.ac.uk/rschg/ http://www.rsc.org/membership/networking/interestgroups/historical/index.asp Contents From the Editor 2 RSC Historical Group News - Bill Griffith 3 Identification Query - W. H. Brock 4 Members’ Publications 5 NEWS AND UPDATES 6 USEFUL WEBSITES AND ADDRESSES 7 SHORT ESSAYS 9 The Copperas Works at Tankerton - Chris Cooksey 9 Mauveine - the final word? (3) - Chris Cooksey and H. -
SULLIVAN-THESIS-2017.Pdf (2.553Mb)
APPLICATIONS OF THE OSMIUM ISOTOPIC SYSTEM AND RHENIUM- PLATINUM GROUP ELEMENT CONCENTRATIONS IN ORGANIC-RICH MUD ROCKS FROM THE EAGLE FORD FORMATION, TEXAS: A GEOCHEMISTRY AND REDOX STUDY A Thesis Presented to the Faculty of the Department of Earth and Atmospheric Sciences University of Houston ________________________________________ In Partial Fulfillment of the Requirements for the Degree Master of Science _________________________________________ By Daniel Louis Sullivan May 2017 APPLICATIONS OF THE OSMIUM ISOTOPIC SYSTEM AND RHENIUM- PLATINUM GROUP ELEMENT CONCENTRATIONS IN ORGANIC-RICH MUD ROCKS FROM THE EAGLE FORD FORMATION, TEXAS: A GEOCHEMISTRY AND REDOX STUDY _______________________________________ Dan Sullivan APPROVED: _______________________________________ Dr. Alan Brandon, Chairman _______________________________________ Dr. Qi Fu _______________________________________ Dr. Steven Bergman _______________________________________ Dean, College of Natural Sciences and Mathematics ii “True scientific discovery renders the brain incapable at such moments of shouting vigorously to the world ‘Look at what I’ve done! Now I will reap the benefits of recognition and wealth.’ Instead such discovery instinctively forces the brain to thunder ‘We did it’ in a voice no one else can hear, within its sacred, but lonely, chapel of scientific thought. — Clair Cameron Patterson, reacting to being the first person to discover the age of the earth. “I believe in intuition and inspiration. Imagination is more important than knowledge. For knowledge -
Isochron Dating Paul Giem
Isochron Dating Paul Giem Abstract The isochron method of dating is used in multiple radiometric dating systems. An explanation of the method and its rationale are given. Mixing lines, an alternative explanation for apparent isochron lines are explained. Mixing lines do not require significant amounts of time to form. Possible ways of distinguishing mixing lines from isochron lines are explored, including believability, concordance with the geological time scale or other radiometric dates, the presence or absence of mixing hyperbolae, and the believability of daughter and reference isotope homogenization. A model for flattening of “isochron” lines utilizing fractional separation and partial mixing is developed, and its application to the problem of reducing the slope of “isochron” lines without significant time is outlined. It is concluded that there is at present a potentially viable explanation for isochron “ages” that does not require significant amounts of time that may be superior to the standard long-age explanation, and that short-age creationists need not uncritically accept the standard long-age interpretation of radiometric dates. Page 1 of 21 Isochron dating Paul Giem Isochron Dating Paul Giem This paper attempts to accomplish two objectives: First, to explain what isochron dating is and how it is done, and second, to provide an analysis of how reliable it is. In this kind of evaluation, it is important to avoid both over- and underestimates of its reliability. While I will offer tentative conclusions, substantive challenges to those conclusions are welcomed. Unfortunately, there is no way to deal with the subject without at least mentioning mathematics. This means that math phobics cannot be completely accommodated; they will at least have to see equations. -
106 Radiometric Dating
Smoky Mountain Bible Institute Biology, Radiometric Dating 106 Welcome back to the lab. Time, time and more time—we will continue our short detour from the topic of biology and touch on chemistry and geology for the next couple of lessons relating to time. There is a large number of dating methods, and they produce greatly varying dates. We will discuss one more radiometric dating method, and then move on to some dating methods that provide much younger earth results before concluding our detour on time. To perform radiometric dating, a rock is crushed to a fine powder and the minerals are separated. Each mineral has different ratios between its parent and daughter concentrations. This topic is much too complicated to be dealt with in a single lesson, not to mention it carries great potential for painful boredom. I will therefore try to condense this into one lesson that describes the concepts without becoming too scientific and complicated. Isochron dating is a common radiometric dating technique applied to date natural events like the crystallization of minerals as they cool, changes in rocks by metamorphism, or what are essentially naturally occurring shock events like meteor strikes. Minerals present in these events contain various radioactive elements which decay, and the resulting daughter elements can then be used to deduce the age of the mineral through an isochron. So, what is an isochron? In the mathematical theory of dynamic systems, an isochron is a set of initial conditions for the system that all lead to the same long-term behavior. Translation: a mathematical method of determining the initial condition of something based on its current composition. -
Catherine A. Wright
In the Darkness Grows the Green: The Promise of a New Cosmological Horizon of Meaning Within a Critical Inquiry of Human Suffering and the Cross by Catherine A. Wright A Thesis submitted to the Faculty of Regis College and the Theology Department of the Toronto School of Theology in partial fulfilment of the requirements for the degree of Doctor of Philosophy in Theology awarded by the University of St. Michael's College © Copyright by Catherine A. Wright 2015 In The Darkness Grows the Green: The Promise of a New Cosmological Horizon of Meaning Within a Critical Inquiry of Human Suffering and the Cross Catherine A. Wright Doctor of Philosophy in Theology Regis College and the University of St. Michael’s College 2015 Abstract Humans have been called “mud of the earth,”i organic stardust animated by the Ruah of our Creator,ii and microcosms of the macrocosm.iii Since we now understand in captivating detail how humanity has emerged from the cosmos, then we must awaken to how humanity is “of the earth” in all the magnificence and brokenness that this entails. This thesis will demonstrate that there are no easy answers nor complete theological systems to derive satisfying answers to the mystery of human suffering. Rather, this thesis will uncover aspects of sacred revelation offered in and through creation that could mould distinct biospiritual human imaginations and cultivate the Earth literacy required to construct an ecological theological anthropology (ETA). It is this ecocentric interpretive framework that could serve as vital sustenance and a vision of hope for transformation when suffering befalls us. -
1 a Users Guide to Neoproterozoic Geochronology 1 2 Daniel J
1 A users guide to Neoproterozoic geochronology 2 3 Daniel J. Condon1 and Samuel A. Bowring2 4 1. NERC Isotope Geoscience Laboratories, British Geological Survey, Keyworth, 5 NG12 5GS, UK 6 2. Department of Earth, Atmospheric and Planetary Sciences, Massachusetts Institute 7 of Technology, Cambridge, Ma 02139, USA 8 Email – [email protected] 9 10 Chapter summary 11 Radio-isotopic dating techniques provide temporal constraints for Neoproterozoic 12 stratigraphy. Here we review the different types of materials (rocks and minerals) that 13 can be (and have been) used to yield geochronological constraints on 14 [Neoproterozoic] sedimentary successions, as well as review the different analytical 15 methodologies employed. The uncertainties associated with a date are often ignored 16 but are crucial when attempting to synthesise all existing data that are of variable 17 quality. In this contribution we outline the major sources of uncertainty, their 18 magnitude and the assumptions that often underpin them. 1 19 1. Introduction 20 Key to understanding the nature and causes of Neoproterozoic climate fluctuations 21 and links with biological evolution is our ability to precisely correlate and sequence 22 disparate stratigraphic sections. Relative ages of events can be established within 23 single sections or by regional correlation using litho-, chemo- and/or biostratigraphy. 24 However, relative chronologies do not allow testing of the synchroneity of events, the 25 validity of correlations or determining rates of change/duration of events. At present, 26 the major limitation to our understanding of the Neoproterozoic Earth System is the 27 dearth of high-precision, high-accuracy, radio-isotopic dates. -
Isotopegeochemistry Chapter2.Pdf
Isotope Geochemistry W. M. White Chapter 2 DECAY SYSTEMS & GEOCHRONOLOGY I 2.1 BASICS OF RADIOACTIVE ISOTOPE GEOCHEMISTRY 2.1.1 Introduction We can broadly define two principal applications of radiogenic isotope geochemistry. The first is geo- chronology. Geochronology makes use of the constancy of the rate of radioactive decay to measure time. Since a radioactive nuclide decays to its daughter at a rate independent of everything, we can deter- mine a time simply by determining how much of the nuclide has decayed. We will discuss the signifi- cance of this time at a later point. Geochronology is fundamental to our understanding of nature and its results pervade many fields of science. Through it, we know the age of the Sun, the Earth, and our solar system, which provides a calibration point for stellar evolution and cosmology. Geochronology also al- lows to us to trace the origins of culture, agriculture, and civilization back beyond the 5000 years of re- corded history, to date the origin of our species to some 200,000 years, the origins of our genus to nearly 2 million years, and the origin of life to at least 3.5 billion years. Most other methods of determining time, such as so-called molecular clocks, are valid only because they have been calibrated against ra- diometric ages. The history of geochronology begins with Yale University chemist Bertram Boltwood. In collabora- tion of Ernest Rutherford (a New Zealander working at Cambridge University), Boltwood had deduced that lead was the ultimate decay product of uranium. In 1907, he analyzed a series of uranium-rich minerals, determining their U and Pb contents. -
Pb) and Clinical Disparities in Pre- and Post-Katrina New Orleans
Int. J. Environ. Res. Public Health 2014, 11, 7482-7491; doi:10.3390/ijerph110707482 OPEN ACCESS International Journal of Environmental Research and Public Health ISSN 1660-4601 www.mdpi.com/journal/ijerph Review Evolving from Reactive to Proactive Medicine: Community Lead (Pb) and Clinical Disparities in Pre- and Post-Katrina New Orleans Howard W. Mielke 1,*, Christopher Gonzales 2,†, Eric Powell 2 and Paul W. Mielke 3,† 1 Department of Pharmacology, Tulane University School of Medicine, New Orleans, LA 70112, USA 2 Lead Lab, Inc., New Orleans, LA 70119, USA; E-Mails: [email protected] (C.G.); [email protected] (E.P.) 3 Department of Statistics, Colorado State University, Fort Collins, CO 80523, USA; E-Mail: [email protected] † These authors contributed equally to this work. * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel.: +1-504-988-3889; Fax: +1-504-988-6428. Received: 16 December 2013; in revised form: 12 March 2014 / Accepted: 13 March 2014 / Published: 21 July 2014 Abstract: In 2012 the U.S. Centers for Disease Control (CDC) set the blood Pb reference value at ≥5 µg/dL. Clinical analysis of children’s blood Pb levels is the common way to diagnose environmental Pb contamination, and intervention ensues with education and household dust cleanup. Recent review indicates that education and household dust cleanup are not effective at reducing children’s Pb exposure. Here we review mapping environmental Pb and children’s blood Pb response as an alternative approach for proactive Pb dust intervention. New Orleans was divided into a high (≥100 mg/kg) and low (<100 mg/kg) soil Pb communities. -
Isochron Discordances and the Role of Inheritance and Mixing of Radioisotopes in the Mantle and Crust
Chapter 6 Isochron Discordances and the Role of Inheritance and Mixing of Radioisotopes in the Mantle and Crust Andrew A. Snelling, Ph.D.* Abstract. New radioisotope data were obtained for ten rock units spanning the geologic record from the recent to the early Precambrian, five of these rock units being in the Grand Canyon area. All but one of these rock units were derived from basaltic magmas generated in the mantle. The objective was to test the reliability of the model and isochron “age” dating methods using the K-Ar, Rb-Sr, Sm-Nd, and Pb-Pb radioisotope systems. The isochron “ages” for these rock units consistently indicated that the α-decaying radioisotopes (238U, 235U, and 147Sm) yield older “ages” than the β-decaying radioisotopes (40K, 87Rb). Marked discordances were found among the isochron “ages” yielded by these radioisotope systems, particularly for the seven Precambrian rock units studied. Also, the longer the half-life of the α- or β-decaying radioisotope, and/or the heavier the atomic weight of the parent radioisotope, the greater was the isochron “age” it yielded relative to the other α- or β-decaying radioisotopes respectively. It was concluded that because each of these radioisotope systems was dating the same geologic event for each rock unit, the only way this systematic isochron discordance could be reconciled would be if the decay of the parent radioisotopes had been accelerated at different rates at some time or times in the past, the α-decayers having been accelerated more than the β-decayers. However, a further complication to this pattern is that the radioisotope endowments of the mantle sources of basaltic magmas can sometimes be inherited by the magmas without resetting of the radioisotope * Geology Department, Institute for Creation Research, Santee, California 394 A. -
Geological Time (Geochronology) Summary of Materials Relating to Course ESS 461 ”Geological Time” Taught at the University of Washington, Winter 2010, by John O
Geological Time (Geochronology) Summary of materials relating to course ESS 461 ”Geological Time” taught at the University of Washington, Winter 2010, by John O. Stone PhD Prepared by Michael McGoodwin (MCM), Winter 2010 Table of Contents Introduction ...................................................................................................................................................................................... 1 Age of the Earth: Early Estimates ....................................................................................................................................................... 4 Biblical chronology (Ussher, Lightfoot) .............................................................................................................................................. 4 Estimate by sedimentation rates (Benoît de Maillet) ........................................................................................................................ 5 Astronomical estimate of the age of Earth (George Darwin) ............................................................................................................ 5 Ocean salinity estimate of the age of Earth (John Joly) ..................................................................................................................... 5 Earliest radiometric estimates of the age of Earth (Rutherford, Boltwood) ...................................................................................... 5 Modern Radiometric and Other Dating Techniques.......................................................................................................................... -
Transcribed Excerpts from Clair Cameron Patterson's Biography
Transcribed Excerpt from Biography of Clair Cameron Patterson, 1998 Claire Patterson was an energetic, innovative, determined scientist whose pioneering work stretched across an unusual number of sub-disciplines, including archeology, meteorology, oceanography, and environmental science—besides chemistry and geology. He is best known for his determination of the age of the Earth. That was possible only after he had spent some five years establishing methods for the separation and isotopic analysis of lead at microgram and sub-microgram levels. His techniques opened a new field in lead isotope geochemistry for terrestrial as well as for planetary studies. Whereas terrestrial lead isotope data had been based entirely on galena ore samples, isotopes could finally be measured on ordinary igneous rocks and sediments, greatly expanding the utility of the technique. While subsequently applying the methodology to ocean sediments, he came to the conclusion that the input of lead into the oceans was much greater than the removal of lead to sediments, because human activities were polluting the environment with unprecedented, possibly dangerous, levels of lead. Then followed years of study and debate involving him and other investigators and politicians over control of lead in the environment. In the end, his basic views prevailed, resulting in drastic reductions in the amount of lead entering the environment. Thus, in addition to measuring the age of the Earth and significantly expanding the field of lead isotope geochemistry, Patterson applied his scientific expertise to create a healthier environment for society. IOWA DEPARTMENT OF CULTURAL AFFAIRS 600 E. LOCUST ST. DES MOINES, IA 50319 IOWACULTURE.GOV .