Effects of Conservation Practices on Mitigation of Pesticide Loss And
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Restricted Use Product Summary Report
Page 1 of 17 Restricted Use Product Summary Report (January 19, 2016) Percent Active Registration # Name Company # Company Name Active Ingredient(s) Ingredient 4‐152 BONIDE ORCHARD MOUSE BAIT 4 BONIDE PRODUCTS, INC. 2 Zinc phosphide (Zn3P2) 70‐223 RIGO EXOTHERM TERMIL 70 VALUE GARDENS SUPPLY, LLC 20 Chlorothalonil 100‐497 AATREX 4L HERBICIDE 100 SYNGENTA CROP PROTECTION, LLC 42.6 Atrazine 100‐585 AATREX NINE‐O HERBICIDE 100 SYNGENTA CROP PROTECTION, LLC 88.2 Atrazine 100‐669 CURACRON 8E INSECTICIDE‐MITICIDE 100 SYNGENTA CROP PROTECTION, LLC 73 Profenofos 100‐817 BICEP II MAGNUM HERBICIDE 100 SYNGENTA CROP PROTECTION, LLC 33; 26.1 Atrazine; S‐Metolachlor 100‐827 BICEP LITE II MAGNUM HERBICIDE 100 SYNGENTA CROP PROTECTION, LLC 28.1; 35.8 Atrazine; S‐Metolachlor 100‐886 BICEP MAGNUM 100 SYNGENTA CROP PROTECTION, LLC 33.7; 26.1 Atrazine; S‐Metolachlor 100‐898 AGRI‐MEK 0.15 EC MITICIDE/INSECTICIDE 100 SYNGENTA CROP PROTECTION, LLC 2 Abamectin 100‐903 DENIM INSECTICIDE 100 SYNGENTA CROP PROTECTION, LLC 2.15 Emamectin benzoate 100‐904 PROCLAIM INSECTICIDE 100 SYNGENTA CROP PROTECTION, LLC 5 Emamectin benzoate 100‐998 KARATE 1EC 100 SYNGENTA CROP PROTECTION, LLC 13.1 lambda‐Cyhalothrin 100‐1075 FORCE 3G INSECTICIDE 100 SYNGENTA CROP PROTECTION, LLC 3 Tefluthrin Acetochlor; Carbamothioic acid, dipropyl‐ 100‐1083 DOUBLEPLAY SELECTIVE HERBICIDE 100 SYNGENTA CROP PROTECTION, LLC 16.9; 67.8 , S‐ethyl ester 100‐1086 KARATE EC‐W INSECTICIDE 100 SYNGENTA CROP PROTECTION, LLC 13.1 lambda‐Cyhalothrin 100‐1088 SCIMITAR GC INSECTICIDE 100 SYNGENTA CROP PROTECTION, -
2,4-Dichlorophenoxyacetic Acid
2,4-Dichlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid IUPAC (2,4-dichlorophenoxy)acetic acid name 2,4-D Other hedonal names trinoxol Identifiers CAS [94-75-7] number SMILES OC(COC1=CC=C(Cl)C=C1Cl)=O ChemSpider 1441 ID Properties Molecular C H Cl O formula 8 6 2 3 Molar mass 221.04 g mol−1 Appearance white to yellow powder Melting point 140.5 °C (413.5 K) Boiling 160 °C (0.4 mm Hg) point Solubility in 900 mg/L (25 °C) water Related compounds Related 2,4,5-T, Dichlorprop compounds Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) 2,4-Dichlorophenoxyacetic acid (2,4-D) is a common systemic herbicide used in the control of broadleaf weeds. It is the most widely used herbicide in the world, and the third most commonly used in North America.[1] 2,4-D is also an important synthetic auxin, often used in laboratories for plant research and as a supplement in plant cell culture media such as MS medium. History 2,4-D was developed during World War II by a British team at Rothamsted Experimental Station, under the leadership of Judah Hirsch Quastel, aiming to increase crop yields for a nation at war.[citation needed] When it was commercially released in 1946, it became the first successful selective herbicide and allowed for greatly enhanced weed control in wheat, maize (corn), rice, and similar cereal grass crop, because it only kills dicots, leaving behind monocots. Mechanism of herbicide action 2,4-D is a synthetic auxin, which is a class of plant growth regulators. -
Corn and Soybean Mode of Action Herbicide Chart
By Premix Corn and Soybean This chart lists premix herbicides alphabetically by their trade names so you can identify the premix’s component herbicides and their respective site of action groups. Refer Herbicide Chart to the Mode of Action chart for more information. Component Repeated use of herbicides with the same Site of Premix Trade Active Action site of action can result in the development of Trade Name ® Name ® Ingredient Group* herbicide-resistant weed populations. Authority First ............... Spartan sulfentrazone 14 FirstRate cloransulam 2 Axiom ........................... Define flufenacet 15 This publication was designed for commercial printing, color shifts may occur on other printers and on-screeen. Sencor metribuzin 5 Basis . ........................... Resolve rimsulfuron 2 Harmony GT thifensulfuron 2 By Mode of Action (effect on plant growth) Bicep II Magnum .......... Dual II Magnum s-metolachlor 15 AAtrex atrazine 5 This chart groups herbicides by their modes of action to assist Bicep Lite II Magnum .... Dual II Magnum s-metolachlor 15 AAtrex atrazine 5 you in selecting herbicides 1) to maintain greater diversity in Boundary ...................... Dual Magnum s-metolachlor 15 herbicide use and 2) to rotate among herbicides with different Sencor metribuzin 5 Breakfree ATZ ............... Breakfree acetochlor 15 sites of action to delay the development of herbicide resistance. atrazine atrazine 5 Breakfree ATZ Lite ........ Breakfree acetochlor 15 Number of atrazine atrazine 5 resistant weed Buctril + Atrazine ......... Buctril bromoxynil 6 atrazine atrazine 5 species in U.S. Bullet ............................ Micro-Tech alachlor 15 Site of Chemical Active atrazine atrazine 5 Action Product Examples Camix ........................... Callisto mesotrione 28 Group* Site of Action Family Ingredient (Trade Name ®) Dual II Magnum s-metolachlor 15 Lipid Canopy DF .................. -
Exposure to Herbicides in House Dust and Risk of Childhood Acute Lymphoblastic Leukemia
Journal of Exposure Science and Environmental Epidemiology (2013) 23, 363–370 & 2013 Nature America, Inc. All rights reserved 1559-0631/13 www.nature.com/jes ORIGINAL ARTICLE Exposure to herbicides in house dust and risk of childhood acute lymphoblastic leukemia Catherine Metayer1, Joanne S. Colt2, Patricia A. Buffler1, Helen D. Reed3, Steve Selvin1, Vonda Crouse4 and Mary H. Ward2 We examine the association between exposure to herbicides and childhood acute lymphoblastic leukemia (ALL). Dust samples were collected from homes of 269 ALL cases and 333 healthy controls (o8 years of age at diagnosis/reference date and residing in same home since diagnosis/reference date) in California, using a high-volume surface sampler or household vacuum bags. Amounts of agricultural or professional herbicides (alachlor, metolachlor, bromoxynil, bromoxynil octanoate, pebulate, butylate, prometryn, simazine, ethalfluralin, and pendimethalin) and residential herbicides (cyanazine, trifluralin, 2-methyl-4- chlorophenoxyacetic acid (MCPA), mecoprop, 2,4-dichlorophenoxyacetic acid (2,4-D), chlorthal, and dicamba) were measured. Odds ratios (OR) and 95% confidence intervals (CI) were estimated by logistic regression. Models included the herbicide of interest, age, sex, race/ethnicity, household income, year and season of dust sampling, neighborhood type, and residence type. The risk of childhood ALL was associated with dust levels of chlorthal; compared to homes with no detections, ORs for the first, second, and third tertiles were 1.49 (95% CI: 0.82–2.72), 1.49 (95% CI: 0.83–2.67), and 1.57 (95% CI: 0.90–2.73), respectively (P-value for linear trend ¼ 0.05). The magnitude of this association appeared to be higher in the presence of alachlor. -
40 CFR Ch. I (7–1–18 Edition) § 455.61
§ 455.61 40 CFR Ch. I (7–1–18 Edition) from: the operation of employee show- § 455.64 Effluent limitations guidelines ers and laundry facilities; the testing representing the degree of effluent of fire protection equipment; the test- reduction attainable by the applica- ing and emergency operation of safety tion of the best available tech- showers and eye washes; or storm nology economically achievable water. (BAT). (d) The provisions of this subpart do Except as provided in 40 CFR 125.30 not apply to wastewater discharges through 125.32, any existing point from the repackaging of microorga- source subject to this subpart must nisms or Group 1 Mixtures, as defined achieve effluent limitations rep- under § 455.10, or non-agricultural pes- resenting the degree of effluent reduc- ticide products. tion attainable by the application of the best available technology economi- § 455.61 Special definitions. cally achievable: There shall be no dis- Process wastewater, for this subpart, charge of process wastewater pollut- means all wastewater except for sani- ants. tary water and those wastewaters ex- § 455.65 New source performance cluded from the applicability of the standards (NSPS). rule in § 455.60. Any new source subject to this sub- § 455.62 Effluent limitations guidelines part which discharges process waste- representing the degree of effluent water pollutants must meet the fol- reduction attainable by the applica- lowing standards: There shall be no dis- tion of the best practicable pollut- charge of process wastewater pollut- ant control technology (BPT). ants. Except as provided in 40 CFR 125.30 through 125.32, any existing point § 455.66 Pretreatment standards for existing sources (PSES). -
Reduction of Nitroaromatic Pesticides with Zero-Valent Iron
Chemosphere 54 (2004) 255–263 www.elsevier.com/locate/chemosphere Reduction of nitroaromatic pesticides with zero-valent iron Young-Soo Keum, Qing X. Li * Department of Molecular Biosciences and Bioengineering, University of Hawaii, 1955 East-West Road, Ag Sci 218, Honolulu, HI 96822, USA Received 5 February 2003; received in revised form 4 June 2003; accepted 4 August 2003 Abstract Reduction of eleven nitroaromatic pesticides was studied with zero-valent iron powder. Average half-lives ranged from 2.8 to 6.3 h and the parent compounds were completely reduced after 48–96 h. The di-nitro groups of the 2,6- dinitroaniline herbicides were rapidly reduced to the corresponding diamines, with a negligible amount of partially reduced monoamino or nitroso products. Low levels of de-alkylated products were observed after 10 days. The nitro group of the organophosphorus insecticides was reduced dominantly to the monoamines but in a slower rate than the 2,6-dinitroanilines. A trace amount of oxon products was found. Reduction of nitro to amino was also the predominant reaction for the diphenyl ether herbicides. Aromatic de-chlorination and de-alkylation were minor reactions. These amine products were more stable than the parent compounds and 60% or more of the amines were detected after two weeks. Humic acid decreased the reduction rates of pendimethalin, and dichlone (a known quinone redox mediator) counteracted the effect of humic acid on the reactivity. Storage of iron powder under air decreased the reactivity very rapidly due to iron oxidation. Repeated use of iron powder also showed similar results. The reduced activity of air- oxidized iron was recovered by purging with hydrogen, but not nitrogen. -
U.S. Geological Survey National Water-Quality Assessment Program
U.S. Geological Survey National Water-Quality Assessment Program Stream water-quality analytes Major ions and trace elementsschedule 998 (20 constituents) Pesticides schedule 2437 (229 compounds) Alkalinity 1H1,2,4Triazole Arsenic 2,3,3Trichloro2propene1sulfonic acid (TCPSA) Boron 2,4D Calcium 2(1Hydroxyethyl)6methylaniline Chloride 2[(2Ethyl6methylphenyl)amino]1propanol Fluoride 2AminoNisopropylbenzamide Iron 2Aminobenzimidazole Lithium 2Chloro2',6'diethylacetanilide 2Chloro4,6diaminostriazine {CAAT} Magnesium (Didealkylatrazine) pH 2Chloro4isopropylamino6aminostriazine Potassium 2Chloro6ethylamino4aminostriazine {CEAT} Total dissolved solids 2ChloroN(2ethyl6methylphenyl)acetamide Selenium 2Hydroxy4isopropylamino6aminostriazine 2Hydroxy4isopropylamino6ethylaminostriazin Silica e {OIET} Sodium 2Hydroxy6ethylamino4aminostriazine Specific conductance 2Isopropyl6methyl4pyrimidinol Strontium 3,4Dichlorophenylurea Sulfate 3Hydroxycarbofuran Turbidity 3Phenoxybenzoic acid Vanadium 4(Hydroxymethyl)pendimethalin 4Chlorobenzylmethyl sulfoxide Suspended sediment 4Hydroxy molinate 4Hydroxychlorothalonil Nutrientsschedule 2430 (18 constituents) 4Hydroxyhexazinone A Inorganic carbon, suspended Acephate Dissolved inorganic carbon Acetochlor ammonia + organic nitrogen (unfilteredKjeldahl) Acetochlor oxanilic acid ammonia + organic nitrogen (filteredKjeldahl) Acetochlor sulfonic acid Ammonia as N, filtered Acetochlor sulfynilacetic acid nitrite, filtered Alachlor -
Efficacy of Imazapic/Imazapyr and Other Herbicides in Mixtures for The
Efficacy of imazapic/imazapyr and other herbicides in mixtures for the control of Digitaria insularis prior to soybean sowing Efectividad de imazapic/imazapyr y otros herbicidas en mezclas para el control de Digitaria insularis en pre-siembra de soya Alfredo Junior Paiola Albrecht1, Leandro Paiola Albrecht1, André Felipe Moreira Silva²*, Romulo Augusto Ramos³, Everson Pedro Zeny³, Juliano Bortoluzzi Lorenzetti4, Maikon Tiago Yamada Danilussi4, and Arthur Arrobas Martins Barroso4 ABSTRACT RESUMEN Herbicide mixtures, use of multiple sites of action, and other Las mezclas entre herbicidas, el uso de múltiples sitios de acción weed management practices are necessary to avoid cases of y otras prácticas de manejo de malezas son necesarias para biotype resistance. The aim of this study was to evaluate the evitar otros casos de resistencia de biotipos. El objetivo de este efficiency of imazapic/imazapyr and other herbicides in mix- estudio fue evaluar la eficiencia de imazapic/imazapyr y otros tures to control Digitaria insularis at burndown before soybean herbicidas en mezclas para controlar Digitaria insularis en la sowing. This field research was conducted in Umuarama, State desecación antes de la siembra de soya. Esta investigación de of Parana (PR), Brazil, in the 2018/19 soybean season. The ex- campo se realizó en Umuarama, Estado de Paraná (PR), Brasil, periment was conducted in a randomized block experimental en la cosecha de soya de 2018/19. El experimento se realizó en design with four replicates and 11 treatments composed of the un diseño experimental de bloques al azar, con cuatro repe- application of glyphosate, clethodim, haloxyfop, imazapic/ ticiones y 11 tratamientos, compuestos por la aplicación de imazapyr, glufosinate, 2,4-dichlorophenoxyacetic acid (2,4-D), glifosato, cletodim, haloxifop, imazapic/imazapir, glufosinato, dicamba, triclopyr, and saflufenacil, in mixtures. -
PUBLIC WATER SUPPLY SAMPLING PLAN for Contaminants with a Vermont Health Advisory – May 2020
PROPOSED PUBLIC WATER SUPPLY SAMPLING PLAN For Contaminants with a Vermont Health Advisory – May 2020 Vermont Department of Environmental Conservation Drinking Water & Groundwater Protection Division A Plan to Sample for Chemicals with a Vermont Health Advisory As required by Act 21 (2019), Section 10(b), the Secretary of the Agency of Natural Resources, on or before January 1, 2020, must publish for public review and comment a plan to collect data for contaminants in drinking water from public community water systems and all non-transient non-community water systems, for which a health advisory has been established, but no Maximum Contaminant Level has been adopted. These health advisories are referred to as Vermont Health Advisories (VHAs) in this document. 1 | P a g e TABLE OF CONTENTS I. Executive Summary …………………………………………………………………………………………..Page 3 II. Background ……………………………………………………………………………………………………… Page 4 III. Determining the VHA contaminants for sampling at public water systems ………..Page 6 IV. Sampling Considerations …..…………………………………………………………………………….. Page 10 V. Proposed Sampling Plan ………………………………………………………………………….………..Page 12 Attachments Table 1 Complete List of Vermont Health Advisories (VHAs) …………………………………………..Page 13 Table 2 Proposed List of VHAs with Potential Concern ……………………………………………………Page 18 2 | P a g e I. Executive Summary The Secretary of the Agency of Natural Resources was tasked with developing a sampling plan for public review, for certain drinking water contaminants that have an established health advisory, also known as the Vermont Health Advisory (VHA) but have no Maximum Contaminant Level (MCL). This Sampling Plan (Plan) is targeted to public community and public non- transient non-community water systems. To provide context for public water system regulation, and standards that apply, a discussion of how VHAs and MCLs are determined is given. -
Weed Management with Diclosulam in Peanut (Arachis Hypogaea)1
Weed Technology. 2002. Volume 16:724–730 Weed Management with Diclosulam in Peanut (Arachis hypogaea)1 ANDREW J. PRICE, JOHN W. WILCUT, and CHARLES W. SWANN2 Abstract: Field experiments were conducted at three locations in North Carolina in 1998 and 1999 and one location in Virginia in 1998 to evaluate weed management systems in peanut. Treatments consisted of diclosulam alone preemergence (PRE), or diclosulam plus metolachlor PRE alone or followed by (fb) bentazon plus acifluorfen postemergence (POST). These systems were also com pared with commercial standards of metolachlor PRE fb bentazon plus acifluorfen POST or imazapic POST. Our data indicate that diclosulam PRE plus metolachlor PRE in conventional tillage peanut production usually controlled common lambsquarters, common ragweed, prickly sida, and entireleaf morningglory. But control of spurred anoda, goosegrass, ivyleaf morningglory, large crabgrass, and pitted morningglory by this system was inconsistent and may require additional POST herbicide treatments. Systems that included diclosulam plus metolachlor PRE consistently provided high yields and net returns. Nomenclature: Acifluorfen, bentazon, diclosulam, imazapic, metolachlor; common lambsquarters, Chenopodium album L. #3 CHEAL; common ragweed, Ambrosia artemisiifolia L. # AMBEL; enti releaf morningglory, Ipomoea hederacea var. integruiscula Grey # IPOHG; goosegrass, Eleusine indica (L.) Gaertn. # ELEIN; ivyleaf morningglory, Ipomoea hederacea (L.) Jacq # IPOHE; large crabgrass, Digitaria sanguinalis L. Scop. # DIGSA; pitted morningglory, Ipomoea lacunosa L. # IPOLA; prickly sida, Sida spinosa L. # SIDSP; spurred anoda, Anoda cristata L. # ANVCR; peanut, Arachis hypogaea L. ‘NC 10C’, ‘NC 12C’. Additional index words: Economic analysis. Abbreviations: fb, followed by; POST, postemergence; PPI, preplant incorporated; PRE, preemer gence. INTRODUCTION Wilcut and Swann 1990; Wilcut et al. -
INDEX to PESTICIDE TYPES and FAMILIES and PART 180 TOLERANCE INFORMATION of PESTICIDE CHEMICALS in FOOD and FEED COMMODITIES
US Environmental Protection Agency Office of Pesticide Programs INDEX to PESTICIDE TYPES and FAMILIES and PART 180 TOLERANCE INFORMATION of PESTICIDE CHEMICALS in FOOD and FEED COMMODITIES Note: Pesticide tolerance information is updated in the Code of Federal Regulations on a weekly basis. EPA plans to update these indexes biannually. These indexes are current as of the date indicated in the pdf file. For the latest information on pesticide tolerances, please check the electronic Code of Federal Regulations (eCFR) at http://www.access.gpo.gov/nara/cfr/waisidx_07/40cfrv23_07.html 1 40 CFR Type Family Common name CAS Number PC code 180.163 Acaricide bridged diphenyl Dicofol (1,1-Bis(chlorophenyl)-2,2,2-trichloroethanol) 115-32-2 10501 180.198 Acaricide phosphonate Trichlorfon 52-68-6 57901 180.259 Acaricide sulfite ester Propargite 2312-35-8 97601 180.446 Acaricide tetrazine Clofentezine 74115-24-5 125501 180.448 Acaricide thiazolidine Hexythiazox 78587-05-0 128849 180.517 Acaricide phenylpyrazole Fipronil 120068-37-3 129121 180.566 Acaricide pyrazole Fenpyroximate 134098-61-6 129131 180.572 Acaricide carbazate Bifenazate 149877-41-8 586 180.593 Acaricide unclassified Etoxazole 153233-91-1 107091 180.599 Acaricide unclassified Acequinocyl 57960-19-7 6329 180.341 Acaricide, fungicide dinitrophenol Dinocap (2, 4-Dinitro-6-octylphenyl crotonate and 2,6-dinitro-4- 39300-45-3 36001 octylphenyl crotonate} 180.111 Acaricide, insecticide organophosphorus Malathion 121-75-5 57701 180.182 Acaricide, insecticide cyclodiene Endosulfan 115-29-7 79401 -
Weed Management—Major Crops
Weed Technology 2010 24:1–5 Weed Management—Major Crops Annual Grass Control in Strip-Tillage Peanut Production with Delayed Applications of Pendimethalin W. Carroll Johnson, III, Eric P. Prostko, and Benjamin G. Mullinix, Jr.* In strip-tillage peanut production, situations occur when dinitroaniline herbicides are not applied in a timely manner. In these cases, dinitroaniline herbicides would be applied days or weeks after seeding. However, there is no information that documents the effects of delayed applications on weed control. Trials were conducted in 2004, 2005, and 2007 in Georgia to determine the weed control efficacy of delayed applications of pendimethalin in strip-tillage peanut production. Treatments included seven timings of pendimethalin application and three pendimethalin-containing herbicide combinations. Timings of application were immediately after seeding (PRE), vegetative emergence of peanut (VE), 1 wk after VE (VE+1wk), VE+2wk, VE+3wk, VE+4wk, and a nontreated control. Pendimethalin containing herbicide programs included pendimethalin plus paraquat, pendimethalin plus imazapic, and pendimethalin alone. Among the possible treatment combinations was a current producer standard timing for nonpendimethalin weed control programs in peanut, which was either imazapic or paraquat alone applied VE+3wk. Pendimethalin alone did not effectively control Texas millet regardless of time of application (69 to 77%), whereas southern crabgrass was controlled by pendimethalin alone PRE (87%). Delayed applications of pendimethalin controlled Texas millet and southern crabgrass when combined with either paraquat or imazapic, with imazapic being the preferred combination due to better efficacy on southern crabgrass than paraquat at most delayed applications. Peanut yield was improved when any of the herbicide combinations were applied PRE compared to later applications.