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Acetic Acid, Specific Heat Capacities (Vapor Phase) 88 Carbon Dioxide 88

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Acetic Acid, Specific Heat Capacities (Vapor Phase) 88 Carbon Dioxide 88 Index Acetic acid, specific heat capacities (vapor hydrogen bonds 201 phase) 88 water molecules 198 carbon dioxide 88 Carboxylic acids, dimerization 87 cyclohexane 88 mixtures 86 Acetonitrile 147 Carnahan–Starling equation 111, 114 3-Acetoxy-1,3-diphenylprop-1-ene/dimethyl Cavity-correlation function (CCF) 112 malonate 171 C–C/C–O cleavage reactions 167 Adipic acid, solubility 93 Cell dynamics system method (CDS) 110, 122 Adsorption configurations, tail/loop/train 137 Chain-like molecules 134 Alcohols, bubble-point pressures 84 Chemical potential 43 vapor pressures 119 Chloroaluminate ILs 177 1-Alkyl-3-methylimidazolium 146 Choline acesulfamate ILs 179 N-Alkylpyridinium 146 Choline saccharinate ILs 179 Aluminophosphates 173 Closures 33 Amino acids, solubility 93 CO2/methane in CNT, competition adsorption 1-Aminoethyl-3-methylimidazolium 217 hexafluorophosphate 151 Co-AlPOs 174 1-Aminopropyl-3-butylimidazolium tetrafluo- Colloidal stability 57 roborate 151 Compressibility factor 107, 113, 123 Aqueous electrolyte solutions, high tempera- Conducting polymers 179 ture/pressure, thermodynamic properties Contact value theorem 55 217 Correlation functions 24 Association contribution 79, 106 Coulomb interactions 69 Counter-intuitive electrostatic phenomena 69 Bisphenol A (BPA)/phenol/water 95 Cryptomelane 173 BMCSL, bulk hard-sphere fluids 63 Cyclohexane/acetic acid 89 Bubble-point pressures, alcohols 84 Cyclopentadiene/methylvinyl ketone 168 Bulk fluid, radial distribution function 25 Butyl methacrylate (BMA) 100 Decanoic acid 86 Butyronitrile/n-heptane 81 Density 108 Density distribution 24 Cahn–Hilliard theory 8 Density fluctuations 26 Carbapalladacycle catalyst 169 Density functional theory (DFT) vii, 1, 15, 17, Carbon dioxide, cycloaddition to epoxide 171 61, 109 Carbon nanotubes (CNT) 198 Density profile 18 CO2/methane, competition adsorption Density–density correlation 26 217 Depletion potential 60 271 272 Index Designer solvents 144 Helmholtz energy, association contribution 106 Dialkylimidazolium tetrafluoroborate 138 dipolar interactions 106 Diblock copolymer melts 124 dispersion contribution 105 Dichloromethane 147 Helmholtz energy functionals, excess 61 Dilead pentaoxochromate 174 intrinsic 44 Dimethylformamide/1-butene 81 Heteroazeotropic behavior 84 Dipole/polarizability contribution 80 Heterogeneous fluids, density functional Dispersion contribution 79 theory 130 Dissipative particle dynamics method (DPD) Hexyl acetate 147 110, 122 Hohenberg–Kohn theorem 20 Dynamic density functional theory (DDFT) Hybrid density functional theory (HDFT) 136 109, 110, 122 Hydration factor 218 ionic hydration 218 Electrochemical sensors 178 Hydration free energy 221 Electrodeposition 177 Hydrogen bonding 68 Electrolytes 193 Hydrogenation catalysts, ILs 165 Electrons, ground-state energy 21 Hydrostatics equation 52 Electropolishing 177 Electrostatics 69 Ideal gas, intrinsic Helmholtz energy Electrosynthesis 177 functional 61 EOS-based DDFT 111 ILs see Ionic liquids Ethanol, carbon nanotubes 211 Imidazolium 150 Ethanol sensor 178 Integral equation theories 31 Ethanol–water, vapor–liquid equilibria 119 Internal energy 38 Ethyl acetate/furfural 85 Intrinsic Helmholtz energy functional 44 Ethyl cinnamyl carbonate/ethyl acetoacetate Ionic liquids viii, 143 171 applications 160 Ethylammonium nitrate 144 catalytic reactions 160 Euler–Lagrange equation 23, 132 eco-design 183 Excess Helmholtz energy functionals 61 electrochemistry 176 Excluded-volume effect 62 fixation of CO2 161 metabolites 183 First-order mean-spherical approximation molecular simulations 149 (FMSA) 66 one-pot synthesis 148 Fluid mixtures, equation of state 116 phosphonium-amino acid 164 Fluids, inhomogeneous, thermodynamic polymer electrolyte composites 176 properties 44 structures/properties 149 uniform, thermodynamic sulfonate 163 properties 38 synthesis 146 Formic acid 86 toxicity 179 Fugacity coefficients 91, 108 two-step synthesis 146 Fundamental-measure theory Iridium (Ir) nanoparticles 174 (FMT) 63, 71 Irving–Kirkwood equation 53 Furfural 85 Latex particles, ζ -potential 69 Gibbs inequality 21 LDPE/ethene 96 Lennard-Jones fluid 12 Haloalkanes 147 Lennard-Jones potential 66 Hard chain 79 Liquid–liquid equilibria (LLE) 111 reference term, Helmholtz energy 104 Lithium batteries 178 Hard spheres 19, 35, 59, 76, 116 Local density approximations (LDA) 17, 65 Hard-sphere chains 133 Low-density polyethylene (LDPE) 96 fluids (HSCFs) 135 Low-molecular-weight systems, Hard wall 56, 68 modeling 80 Index 273 Mean force 57 Polymer systems 96 Metal organic frameworks (MOFs) 173 equation of state 111 Metal oxalatophosphonates 173, 174 microphase separation, DDF theory, Metal-organic frameworks, ionothermal equations of state 121 synthesis 175 Polystyrene-polybutadiene 127 Methanol/water, monohydrate Potential distribution theorem 59 formation 95 Pressure 107 Methionine, solubility 94 Pressure equations 40 1-Methyl-2,3-dihydrobenzo[b]furan 166 Pressure tensor 47 1-Methyl-3-ethylimidazoliumc chloride 167 Proton donor/acceptor 83 Methyl methacrylate (MMA)/water 84 PS/PBD 127 Microphase separation 109 liquid–liquid equilibria 120 Microstructure, quantum chemistry calcula- Pure fluids, equation of state 113 tions 222 Pyridinium aluminium tetrachloride 144 Mixtures, polar/associating fluids 83 strongly polar/nonpolar fluids 81 Reference-interaction-site model (RISM) 130 MOFs 173, 175 Repulsion, short-range 62 Molecular sieves, ionothermal synthesis 174 Molecular thermodynamics 109 SAFT, perturbed-chain 77 perturbed-chain polar (PCP-SAFT) 77 Nanoclusters 173 Scaled-particle theory 63 Nanoconfinement, fluids 196 Self-consistent-field theory (SCFT) 110, 122 Nanoneedles (γ-MnO2) 173 Nanorods (CoPt, cryptomelane) 173 Semiconductors 173 Nanosheets 173 Solidate (SOD) structure 174 Nanowires 173 Solid–liquid equilibria (SLE) 91, 111 Non-uniform fluid 109 Solubility 57 Solvation force 57 One-body density profile 24 Square-gradient theory 8 One-body potential 21 Square-well chains 135 Order–disorder transition (ODT) 124 Square-well perturbation 111 Order–order transition (OOT) 125 Stainless steel, electropolishing 177 Ornstein–Zernike Equation 31 Static structure factor 28 Oxalatophosphonate, ionothermal synthesis Statistical associating fluid theory 175 (SAFT) 68 Sticky-point model 112 Pair correlation function 25 Supported IL catalysts (SILCAs) 165 Palladium(II) imidazole complexes 169 Surface tension 54 Paracetamol, solubility 91 Suzuki coupling reactions, ILs 169 Pattern transfer parameter (PTP) 134 PC-SAFT equation of state 78 Tetraalkylammonium 146 Percus–Yevick (PY) theory 63 Tetraalkylphosphonium 146 Perturbed-chain polar SAFT Tetrabutylphosphonium amino acids 152 (PCP-SAFT) 77 Tetrabutylphosphonium hydroxide 164 Perturbed-chain SAFT (PC-SAFT) 77 Tetramethylguanidinium perchlorate (TMGP) Phase equilibria 75 152 Poisson–Boltzmann (PB) equation 69, 72 Tetramethylguanidium lactate (TMGL) 164 Poly(ethylene-co-ethyl acrylate) 98, 102 Thermodynamic modeling 75 Poly(ethylene-co-methacrylic acid) 99 Thermodynamic perturbation theory, Poly(sulfone), pVT 120 Wertheim’s first-order (TPT1) 80 Poly[(N-vinyl-2-pyrrolidone)-co-(1-vinyl- Tildesley–Streett equation 113 3-butylimidazolium chloride)] 165 Time-dependent density functional theory Polyethylene 98 (TDDFT) 72 274 Index Time-dependent Ginzburg–Landau equation Water, radial distribution function 28 (TDGL) 110, 122 ethyl acetate 85 Trost-Tsuji C-C coupling 171 furfural 85 Two-body density distribution 24 methanol/methyl methacrylate 85 methyl methacrylate 84 Uniform fluids, thermodynamic properties 38 Weighted density approximation (WDA) 111, 123, 130 Van der Waals attraction 65 Wertheim’s first-order thermodynamic Vapor–liquid equilibria (VLE) 111 perturbation theory (TPT1) 80 Variational principle of equilibrium 6 Volatile organic compounds (VOC) 145 Yukawa chain fluids 119.
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