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Transport of Dangerous Goods
ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions. -
Supported Metal Hydroxides As Efficient Heterogeneous Catalysts for Green Functional Group Transformations
Journal of the Japan Petroleum Institute, 57, (6), 251-260 (2014) 251 [Review Paper] Supported Metal Hydroxides as Efficient Heterogeneous Catalysts for Green Functional Group Transformations Kazuya YAMAGUCHI and Noritaka MIZUNO* Dept. of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, JAPAN (Received August 23, 2014) This review article mainly describes our research on the development of highly active heterogeneous catalysts based on the properties of metal hydroxides and efficient green functional group transformations using these cata- lysts. Metal hydroxide species have both Lewis acid (metal center) and Brønsted base (hydroxy group) sites on the same metal sites. Combined action of the Lewis acid and Brønsted base paired sites can activate various types of organic substrates; for example, alcohols→alkoxides, amines→ amides, nitriles→η2-amidates, and terminal alkynes→acetylides. In the presence of supported ruthenium hydroxide catalyst (Ru(OH)x/Al2O3), oxidative dehydrogenation of alcohols and amines efficiently proceeds, forming the corresponding carbonyl compounds (aldehydes and ketones) and nitriles, respectively. Ru(OH)x /Al2O3 can also catalyze hydration of nitriles to pri- mary amides, ammoxidation of primary alcohols to nitriles, and formal α-oxygenation of primary amines to pri- mary amides. In addition, oxidative alkyne homocoupling and 1,3-dipolar cycloaddition efficiently proceed in the presence of supported copper hydroxide catalysts (Cu(OH)x /OMS-2 for homocoupling, Cu(OH)x/TiO2 and Cu(OH)x/Al2O3 for cycloaddition; where OMS-2 is manganese oxide-based octahedral molecular sieve, KMn8O16). The catalytic processes for these transformations are heterogeneous, and the catalysts can be reused several times with maintained high catalytic activity. -
Catalysis Science & Technology
Catalysis Science & Technology Accepted Manuscript This is an Accepted Manuscript, which has been through the Royal Society of Chemistry peer review process and has been accepted for publication. Accepted Manuscripts are published online shortly after acceptance, before technical editing, formatting and proof reading. Using this free service, authors can make their results available to the community, in citable form, before we publish the edited article. We will replace this Accepted Manuscript with the edited and formatted Advance Article as soon as it is available. You can find more information about Accepted Manuscripts in the Information for Authors. Please note that technical editing may introduce minor changes to the text and/or graphics, which may alter content. The journal’s standard Terms & Conditions and the Ethical guidelines still apply. In no event shall the Royal Society of Chemistry be held responsible for any errors or omissions in this Accepted Manuscript or any consequences arising from the use of any information it contains. www.rsc.org/catalysis Page 1 of 10 Catalysis Science & Technology Journal Name RSC Publishing ARTICLE Scheelite: A Versatile Structural Template for Selective Alkene Oxidation Catalysts Cite this: DOI: 10.1039/x0xx00000x J. F. Brazdil , Manuscript Received 00th January 2012, The scheelite (CaWO4) structure type serves as the framework for a wide variety of metal Accepted 00th January 2012 oxide catalysts used for the selective oxidation and ammoxidation of alkenes. Among the industrially important processes where these catalysts find application are propylene oxidation DOI: 10.1039/x0xx00000x to acrolein, propylene ammoxidation to acrylonitrile and butene oxidative dehydrogenation to www.rsc.org/ butadiene. -
02/06/2019 12:05 PM Appendix 3745-21-09 Appendix A
ACTION: Final EXISTING DATE: 02/06/2019 12:05 PM Appendix 3745-21-09 Appendix A List of Organic Chemicals for which Paragraphs (DD) and (EE) of Rule 3745-21-09 of the Administrative Code are Applicable Organic Chemical Organic Chemical Acetal Benzaldehyde Acetaldehyde Benzamide Acetaldol Benzene Acetamide Benzenedisulfonic acid Acetanilide Benzenesulfonic acid Acetic acid Benzil Acetic Anhydride Benzilic acid Acetone Benzoic acid Acetone cyanohydrin Benzoin Acetonitrile Benzonitrile Acetophenone Benzophenone Acetyl chloride Benzotrichloride Acetylene Benzoyl chloride Acrolein Benzyl alcohol Acrylamide Benzylamine Acrylic acid Benzyl benzoate Acrylonitrile Benzyl chloride Adipic acid Benzyl dichloride Adiponitrile Biphenyl Alkyl naphthalenes Bisphenol A Allyl alcohol Bromobenzene Allyl chloride Bromonaphthalene Aminobenzoic acid Butadiene Aminoethylethanolamine 1-butene p-aminophenol n-butyl acetate Amyl acetates n-butyl acrylate Amyl alcohols n-butyl alcohol Amyl amine s-butyl alcohol Amyl chloride t-butyl alcohol Amyl mercaptans n-butylamine Amyl phenol s-butylamine Aniline t-butylamine Aniline hydrochloride p-tertbutyl benzoic acid Anisidine 1,3-butylene glycol Anisole n-butyraldehyde Anthranilic acid Butyric acid Anthraquinone Butyric anhydride Butyronitrile Caprolactam APPENDIX p(183930) pa(324943) d: (715700) ra(553210) print date: 02/06/2019 12:05 PM 3745-21-09, Appendix A 2 Carbon disulfide Cyclohexene Carbon tetrabromide Cyclohexylamine Carbon tetrachloride Cyclooctadiene Cellulose acetate Decanol Chloroacetic acid Diacetone alcohol -
Ammoxidation Reactions 1 1.2 (Potential) Applications of Nitriles 3 1.3 Aromatic Nitriles As Intermediates in Selective Oxidation Reactions 5 2
Catalytic conversion of alkylaromatics to aromatic nitriles Citation for published version (APA): Stobbelaar, P. J. (2000). Catalytic conversion of alkylaromatics to aromatic nitriles. Technische Universiteit Eindhoven. https://doi.org/10.6100/IR538872 DOI: 10.6100/IR538872 Document status and date: Published: 01/01/2000 Document Version: Publisher’s PDF, also known as Version of Record (includes final page, issue and volume numbers) Please check the document version of this publication: • A submitted manuscript is the version of the article upon submission and before peer-review. There can be important differences between the submitted version and the official published version of record. People interested in the research are advised to contact the author for the final version of the publication, or visit the DOI to the publisher's website. • The final author version and the galley proof are versions of the publication after peer review. • The final published version features the final layout of the paper including the volume, issue and page numbers. Link to publication General rights Copyright and moral rights for the publications made accessible in the public portal are retained by the authors and/or other copyright owners and it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights. • Users may download and print one copy of any publication from the public portal for the purpose of private study or research. • You may not further distribute the material or use it for any profit-making activity or commercial gain • You may freely distribute the URL identifying the publication in the public portal. -
UNITED STATES PATENT OFFICE PROCESS of PREPARING 2,2-DIPHENYL-3- TRILEMETHYL-4-Dimethylamino-BUTYRONI Earl M
Patented Aug. 19, 1952 2,607,794 UNITED STATES PATENT OFFICE PROCESS OF PREPARING 2,2-DIPHENYL-3- TRILEMETHYL-4-DIMETHYLAMINo-BUTYRONI Earl M. Chamberlin, Rahway, and Max Tishler, Westfield, N.J., assignors to Merck & Co., Inc., Rahway, N.J., a corporation of New Jersey No Drawing. Application April 9, 1949, Seria No. 86,596 6 Claims. (CL 260-465) . 2 This invention relates to the manufacture of dimethylamino-butyronitrile (compound 5). Compounds possessing analgesic and anesthetic These reactions may be chemically represented action. In particular, it is concerned with an as follows: improved synthetic method for preparing 2,2-di phenyl 3-methyl-4-dimethylamino - butyronia CH3CHOHCHCl + RSO: C1 - cHipHCHCI trile and With novel chemical compounds useful Öso, R. as intermediates in the preparation of this come (1) (2) (3) pound. , 2,2-diphenyl-3-methyl - 4-dimethylami (C6H5)2CHCN no-butyronitrile is itself an important interne NaNH diate in the Synthesis of isoamidone, 1-dimethyl O amino-2-methyl-3,3-diphenylhexanone - 4 and (CH3)NH SaltS thereof. ISOamidone and its salts possess (C.H.)--HCH.N(CH), --- (CH)--HCH.Cl analgesic action and may be used as substitutes CE CH: for morphine. - N N 2,2-diphenyl-3-methyl - 4 - dimethylamino 5 (5) (4) butyronitrile has been prepared previously by The organic Sulfonyl chloride employed in the reacting 1-dimethylamino-2-chloropropane with foregoing reaction can be either an aromatic diphenylacetonitrile as described by Schultz et al. Sulfonyl chloride such as p-toluene sulfonyl chlo (J. A. C. S. 69, 188-189, Jan. 1947). As pointed ride, benzene Sulfonyl chloride and the like, or out by these workers, however, when 2,2-di 20 an aliphatic Sulfonyl chloride such as methane phenyl - 3 - methyl - 4-dimethlamino-butyroni Sulfonyl chloride. -
Synchronous Fluorescence Spectroscopic Study Of
Spectrochimica Acta Part A 79 (2011) 1034–1041 Contents lists available at ScienceDirect Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy jou rnal homepage: www.elsevier.com/locate/saa Synchronous fluorescence spectroscopic study of solvatochromic curcumin dye ∗ Digambara Patra , Christelle Barakat Department of Chemistry, Faculty of Arts and Sciences, American University of Beirut, P.O. Box 11-0236, Riad El Solh, Beirut 1107-2020, Lebanon a r t i c l e i n f o a b s t r a c t Article history: Curcumin, the main yellow bioactive component of turmeric, has recently acquired attention by chemists Received 1 July 2010 due its wide range of potential biological applications as an antioxidant, an anti-inflammatory, and an Accepted 13 April 2011 anti-carcinogenic agent. This molecule fluoresces weakly and poorly soluble in water. In this detailed study of curcumin in thirteen different solvents, both the absorption and fluorescence spectra of curcumin Keywords: was found to be broad, however, a narrower and simple synchronous fluorescence spectrum of curcumin Curcumin was obtained at = 10–20 nm. Lippert–Mataga plot of curcumin in different solvents illustrated two Solvent polarity E sets of linearity which is consistent with the plot of Stokes’ shift vs. the 30. When Stokes’s shift in SFS T wavenumber scale was replaced by synchronous fluorescence maximum in nanometer scale, the solvent max E polarity dependency measured by SFS vs. Lippert–Mataga plot or T30 values offered similar trends as max measured via Stokes’ shift for protic and aprotic solvents for curcumin. Better linear correlation of SFS vs. -
Itll Lawrence Berkeley Laboratory Iii:~ UNIVERSITY of CALIFORNIA APPLIED SCIENCE
LBL-24543 C'_~ ITll Lawrence Berkeley Laboratory iii:~ UNIVERSITY OF CALIFORNIA APPLIED SCIENCE -. ~ ., .. I DIVISION. •-, l:: '-' 1:: v L _ LAWRENCE EJr.:ov~L''"V_, .nc: c' LABORATORY APR 1 9 1988 LIBRARY AND The Use of Basic Polymer Sorbents DOCUMENTS SECTION for the Recovery of Acetic Acid from Dilute Aqueous Solution A.A. Garcia and C.J. King January 1988 '· . J I • .I APPLIED SCIENCE DIVISION Prepared for the U.S. Department of Energy under Contract DE-AC03-76SF00098 DISCLAIMER This document was prepared as an account of work sponsored by the United States Government. While this document is believed to contain correct information, neither the United States Government nor any agency thereof, nor the Regents of the University of California, nor any of their employees, makes any warranty, express or implied, or assumes any legal responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by its trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof, or the Regents of the University of Califomia. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof or the Regents of the University of California. LBL-24543 The Use of Basic Polymer Sorbents For The Recovery of Acetic Acid From Dilute Aqueous Solution Antonio Agustin Garcia and C. -
House Fly Attractants and Arrestante: Screening of Chemicals Possessing Cyanide, Thiocyanate, Or Isothiocyanate Radicals
House Fly Attractants and Arrestante: Screening of Chemicals Possessing Cyanide, Thiocyanate, or Isothiocyanate Radicals Agriculture Handbook No. 403 Agricultural Research Service UNITED STATES DEPARTMENT OF AGRICULTURE Contents Page Methods 1 Results and discussion 3 Thiocyanic acid esters 8 Straight-chain nitriles 10 Propionitrile derivatives 10 Conclusions 24 Summary 25 Literature cited 26 This publication reports research involving pesticides. It does not contain recommendations for their use, nor does it imply that the uses discussed here have been registered. All uses of pesticides must be registered by appropriate State and Federal agencies before they can be recommended. CAUTION: Pesticides can be injurious to humans, domestic animals, desirable plants, and fish or other wildlife—if they are not handled or applied properly. Use all pesticides selectively and carefully. Follow recommended practices for the disposal of surplus pesticides and pesticide containers. ¿/áepé4áaUÁí^a¡eé —' ■ -"" TMK LABIL Mention of a proprietary product in this publication does not constitute a guarantee or warranty by the U.S. Department of Agriculture over other products not mentioned. Washington, D.C. Issued July 1971 For sale by the Superintendent of Documents, U.S. Government Printing Office Washington, D.C. 20402 - Price 25 cents House Fly Attractants and Arrestants: Screening of Chemicals Possessing Cyanide, Thiocyanate, or Isothiocyanate Radicals BY M. S. MAYER, Entomology Research Division, Agricultural Research Service ^ Few chemicals possessing cyanide (-CN), thio- cyanate was slightly attractive to Musca domes- eyanate (-SCN), or isothiocyanate (~NCS) radi- tica, but it was considered to be one of the better cals have been tested as attractants for the house repellents for Phormia regina (Meigen). -
Designing Multifunctionality Into Single Phase and Multiphase Metal-Oxide-Selective Propylene Ammoxidation Catalysts
catalysts Review Designing Multifunctionality into Single Phase and Multiphase Metal-Oxide-Selective Propylene Ammoxidation Catalysts James F. Brazdil Archer Daniels Midland Company, James R. Randall Research Center, Decatur, IL 62521, USA; [email protected]; Tel.: +1-217-451-2870 Received: 5 February 2018; Accepted: 26 February 2018; Published: 2 March 2018 Abstract: Multifunctionality is the hallmark of most modern commercial heterogeneous catalyst systems in use today, including those used for the selective ammoxidation of propylene to acrylonitrile. It is the quintessential principle underlying commercial catalyst design efforts since petrochemical process development is invariably driven by the need to reduce manufacturing costs. This is in large part achieved through new and improved catalysts that increase selectivity and productivity. In addition, the future feedstocks for chemical processes will be invariably more refractory than those currently in use (e.g., replacing alkenes with alkanes or using CO2), thus requiring a disparate combination of chemical functions in order to effect multiple chemical transformations with the fewest separate process steps. This review summarizes the key chemical phenomena behind achieving the successful integration of multiple functions into a mixed-metal-oxide-selective ammoxidation catalyst. An experiential and functional catalyst design model is presented that consists of one or both of the following components: (1) a mixed-metal-oxide–solid solution where the individual metal components serve separate and necessary functions in the reaction mechanism through their atomic level interaction in the context of a single crystallographic structure; (2) the required elemental components and their catalytic function existing in separate phases, where these phases are able to interact for the purposes of electron and lattice oxygen transfer through the formation of a structurally coherent interface (i.e., epitaxy) between the separate crystal structures. -
Environmental Protection Agency § 52.741
Environmental Protection Agency § 52.741 (z) Rules stayed. Not withstanding OCPDB Chemical any other provision of this subpart, the No.1 effectiveness of the following rules is 185 ........ Adiponitrile. stayed as indicated below. 190 ........ Alkyl naphthalenes. (1) [Reserved] 200 ........ Allyl alcohol. 210 ........ Allyl chloride. (2) Compliance with all of 40 CFR 220 ........ Aminobenzoic acid. 52.741 is stayed for 60 days (July 1, 1991, 230 ........ Aminoethylethanolamine. until August 30, 1991) as it pertains to 235 ........ p-aminophenol. the following parties: The Illinois En- 240 ........ Amyl acetates. 250 ........ Amyl alcohols. vironmental Regulatory Group includ- 260 ........ Amyl amine. ing its approximately 40 member firms; 270 ........ Amyl chloride. Allsteel, Incorporated; Riverside Lab- 280 ........ Amyl mercaptans. 290 ........ Amyl phenol. oratories, Incorporated; the Printing 300 ........ Aniline. Industry of Illinois/Indiana Association 310 ........ Aniline hydrochloride. including its member firms, and R.R. 320 ........ Anisidine. Donnelley & Sons Company; the rules 330 ........ Anisole. 340 ........ Anthranilic acid. applicable to General Motors Corpora- 350 ........ Anthraquinone. tion; Reynolds Metals Company; 360 ........ Benzaldehyde. Stepan Company; and Duo-Fast Cor- 370 ........ Benzamide. 380 ........ Benzene. poration. Final compliance for these 390 ........ Benzenedisulfonic acid. parties is extended 60 days from July 1, 400 ........ Benzene-sulfonic acid. 1991 until August 30, 1991. 410 ........ Benzil. (3) The following rules are stayed 420 ........ Benzilic acid. 430 ........ Benzoic acid. from July 23, 1991, until USEPA com- 440 ........ Benzoin. pletes its reconsideration as indicated: 450 ........ Bennzonitrile. (i) 40 CFR 52.741(e) only as it applies 460 ........ Benzophenone. 480 ........ Benzotrichloride. to Duo-Fast Corporation's Franklin 490 ........ Benzoyl chloride. Park, Illinois ``power-driven metal fas- 500 ........ Benzyl chalcohol. tener'' manufacturing facility, and 510 ....... -
2020 Emergency Response Guidebook
2020 A guidebook intended for use by first responders A guidebook intended for use by first responders during the initial phase of a transportation incident during the initial phase of a transportation incident involving hazardous materials/dangerous goods involving hazardous materials/dangerous goods EMERGENCY RESPONSE GUIDEBOOK THIS DOCUMENT SHOULD NOT BE USED TO DETERMINE COMPLIANCE WITH THE HAZARDOUS MATERIALS/ DANGEROUS GOODS REGULATIONS OR 2020 TO CREATE WORKER SAFETY DOCUMENTS EMERGENCY RESPONSE FOR SPECIFIC CHEMICALS GUIDEBOOK NOT FOR SALE This document is intended for distribution free of charge to Public Safety Organizations by the US Department of Transportation and Transport Canada. This copy may not be resold by commercial distributors. https://www.phmsa.dot.gov/hazmat https://www.tc.gc.ca/TDG http://www.sct.gob.mx SHIPPING PAPERS (DOCUMENTS) 24-HOUR EMERGENCY RESPONSE TELEPHONE NUMBERS For the purpose of this guidebook, shipping documents and shipping papers are synonymous. CANADA Shipping papers provide vital information regarding the hazardous materials/dangerous goods to 1. CANUTEC initiate protective actions. A consolidated version of the information found on shipping papers may 1-888-CANUTEC (226-8832) or 613-996-6666 * be found as follows: *666 (STAR 666) cellular (in Canada only) • Road – kept in the cab of a motor vehicle • Rail – kept in possession of a crew member UNITED STATES • Aviation – kept in possession of the pilot or aircraft employees • Marine – kept in a holder on the bridge of a vessel 1. CHEMTREC 1-800-424-9300 Information provided: (in the U.S., Canada and the U.S. Virgin Islands) • 4-digit identification number, UN or NA (go to yellow pages) For calls originating elsewhere: 703-527-3887 * • Proper shipping name (go to blue pages) • Hazard class or division number of material 2.