003984Cob Salt & Vinegar Seasoning

Home , Sodium diacetate

003984COB SALT & VINEGAR SEASONING W W The Product Makers (Australia) Pty Ltd Chemwatch Hazard Alert Code: 3 Version No: 2.2 Issue Date: 24/10/2019 Safety Data Sheet according to WHS and ADG requirements Print Date: 24/10/2019 S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier Product name : 003984COB SALT & VINEGAR SEASONING W W Other means of identification : Not Available

Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses : Use according to manufacturer's directions.

Details of the supplier of the safety data sheet Emergency telephone number

Registered company name The Product Makers (Australia) Pty Ltd Association / Organisation The Product Makers (Australia) Pty Ltd Address 50 - 60 Popes Road Keysborough 3173 Australia Emergency telephone numbers 61 3 9771 0300 Telephone 61 3 9771 0300 Other emergency telephone numbers Not Available Fax 61 3 9771 0301 Website www.theproductmakers.com Email Not Available

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.

ChemWatch Hazard Ratings Flammability 0 Toxicity 0 0 = Minimum 1 = Low Body Contact 3 2 = Moderate Reactivity 0 3 = High Chronic 0 4 = Extreme

Poisons Schedule Not Applicable

Classification [1] Serious Eye Damage Category 1, Specific target organ toxicity - single exposure Category 3 (respiratory tract irritation), Skin Corrosion/Irritation Category 2 Legend: 1. Classified by Chemwatch; 2. Classification drawn from HCIS; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI

Label elements Hazard pictogram(s)

SIGNAL WORD : DANGER

Hazard statement(s) H318 : Causes serious eye damage. H335 : May cause respiratory irritation. H315 : Causes skin irritation.

Precautionary statement(s) Prevention P271 : Use only outdoors or in a well-ventilated area. P280 : Wear protective gloves/protective clothing/eye protection/face protection. P261 : Avoid breathing dust/fumes.

Precautionary statement(s) Response P305+P351+P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Continued... Version No: 2.2 Page 2 of 10 Issue Date: 24/10/2019 003984COB SALT & VINEGAR SEASONING W W Print Date: 24/10/2019

P310 : Immediately call a POISON CENTER or doctor/physician. P321 : Specific treatment (see advice on this label). P362 : Take off contaminated clothing and wash before reuse. P302+P352 : IF ON SKIN: Wash with plenty of water. P304+P340 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P332+P313 : If skin irritation occurs: Get medical advice/attention.

Precautionary statement(s) Storage P405 : Store locked up. P403+P233 : Store in a well-ventilated place. Keep container tightly closed.

Precautionary statement(s) Disposal P501 : Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances See section below for composition of Mixtures

Mixtures

CAS No %[weight] Name 126-96-5 30 sodium diacetate 7647-14-5 16 sodium chloride 7447-40-7 9 potassium chloride 77-92-9 5 citric acid 57-50-1 2 sucrose 20510-56-9 0.2 sodium chloride-37Cl 100209-45-8 1.8 vegetable protein, hydrolysed 8001-21-6 1 sunflower oil 64-19-7 0.5 acetic acid glacial 7631-86-9 0.5 silica amorphous Not Available 21.25 MERIZET 116 CORNSTARCH Not Available 12.75 RICE FLOUR FINE 584 LOW BAC

SECTION 4 FIRST AID MEASURES

Description of first aid measures Eye Contact

If this product comes in contact with the eyes: - Immediately hold eyelids apart and flush the eye continuously with running water. - Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. - Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. - Transport to hospital or doctor without delay. - Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact

If skin or hair contact occurs: - Immediately flush body and clothes with large amounts of water, using safety shower if available. - Quickly remove all contaminated clothing, including footwear. - Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre. - Transport to hospital, or doctor.

Inhalation

- If fumes or combustion products are inhaled remove from contaminated area. - Lay patient down. Keep warm and rested. - Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. - Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. - Transport to hospital, or doctor, without delay.

Ingestion

- For advice, contact a Poisons Information Centre or a doctor at once. - Urgent hospital treatment is likely to be needed. - If swallowed do NOT induce vomiting. - If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. - Observe the patient carefully. - Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. - Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. - Transport to hospital or doctor without delay.

Indication of any immediate medical attention and special treatment needed Treat symptomatically.

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For acute or short term repeated exposures to strong acids: - Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially. - Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling - Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise. - Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicating action of the acid on proteins in specific tissues. INGESTION: - Immediate dilution (milk or water) within 30 minutes post ingestion is recommended. - DO NOT attempt to neutralise the acid since exothermic reaction may extend the corrosive injury. - Be careful to avoid further vomit since re-exposure of the mucosa to the acid is harmful. Limit fluids to one or two glasses in an adult. - Charcoal has no place in acid management. - Some authors suggest the use of lavage within 1 hour of ingestion. SKIN: - Skin lesions require copious saline irrigation. Treat chemical burns as thermal burns with non-adherent gauze and wrapping. - Deep second-degree burns may benefit from topical silver sulfadiazine. EYE: - Eye injuries require retraction of the eyelids to ensure thorough irrigation of the conjuctival cul-de-sacs. Irrigation should last at least 20-30 minutes. DO NOT use neutralising agents or any other additives. Several litres of saline are required. - Cycloplegic drops, (1% cyclopentolate for short-term use or 5% homatropine for longer term use) antibiotic drops, vasoconstrictive agents or artificial tears may be indicated dependent on the severity of the injury. - Steroid eye drops should only be administered with the approval of a consulting ophthalmologist).

[Ellenhorn and Barceloux: Medical Toxicology]

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media - Foam.

Special hazards arising from the substrate or mixture Fire Incompatibility

- Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters Fire Fighting

- Alert Fire Brigade and tell them location and nature of hazard.

Fire/Explosion Hazard

- Combustible. Combustion products include: carbon monoxide (CO) carbon dioxide (CO2) hydrogen chloride phosgene other pyrolysis products typical of burning organic material. May emit poisonous fumes. May emit corrosive fumes.

HAZCHEM Not Applicable

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures See section 8

Environmental precautions See section 12

Methods and material for containment and cleaning up Minor Spills

- Clean up all spills immediately.

Major Spills

Moderate hazard.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling Safe handling

- Avoid all personal contact, including inhalation. - Organic powders when finely divided over a range of concentrations regardless of particulate size or shape and suspended in air or some other oxidizing medium may form explosive dust-air mixtures and result in a fire or dust explosion (including secondary explosions) - Minimise airborne dust and eliminate all ignition sources.

Other information

- Store in original containers. - Shelf Life : 6 months

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Conditions for safe storage, including any incompatibilities Suitable container

- Lined metal can, lined metal pail/ can.

Storage incompatibility

Acetic acid: - vapours forms explosive mixtures with air (above 39 C.) - reacts violently with bases such as carbonates and hydroxides (giving off large quantities of heat), oxidisers, organic amines, acetaldehyde, potassium tert-butoxide - reacts (sometimes violently), with strong acids, aliphatic amines, alkanolamines, alkylene oxides, epichlorohydrin, acetic anhydride, 2-aminoethanol, ammonia, ammonium nitrate, bromine pentafluoride, chlorosulfonic acid, chromic acid, chromium trioxide, ethylenediamine, ethyleneimine, hydrogen peroxide, isocyanates, oleum, perchloric acid, permanganates, phosphorus isocyanate, phosphorus trichloride, sodium peroxide, xylene - attacks cast iron, stainless steel and other metals, forming flammable hydrogen gas - attacks many forms of rubber, plastics and coatings - Avoid strong bases. - Avoid reaction with oxidising agents

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

Occupational Exposure Limits (OEL) INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes Australia Not (a) This value is for inhalable dust containing no Exposure sucrose Sucrose 10 mg/m3 Not Available Available asbestos and < 1% crystalline silica. Standards Australia acetic acid 10 ppm / 25 37 mg/m3 / Not Exposure Acetic acid Not Available glacial mg/m3 15 ppm Available Standards Australia silica Not Exposure Fumed silica (respirable dust) 2 mg/m3 Not Available See Silica -Amorphous amorphous Available Standards Australia Silica - Amorphous: Fume silica Not (e) Containing no asbestos and < 1% crystalline Exposure (thermally generated)(respirable 2 mg/m3 Not Available amorphous Available silica. Standards dust) Australia silica Silica - Amorphous: Fumed silica Not Exposure 2 mg/m3 Not Available Not Available amorphous (respirable dust) Available Standards Australia silica Silica - Amorphous: Diatomaceous Not (a) This value is for inhalable dust containing no Exposure 10 mg/m3 Not Available amorphous earth (uncalcined) Available asbestos and < 1% crystalline silica. Standards Australia silica Not (a) This value is for inhalable dust containing no Exposure Silica - Amorphous: Silica gel 10 mg/m3 Not Available amorphous Available asbestos and < 1% crystalline silica. Standards Australia See Silica -Amorphous; (a) This value is for silica Not Exposure Diatomaceous earth (uncalcined) 10 mg/m3 Not Available inhalable dust containing no asbestos and < 1% amorphous Available Standards crystalline silica. Australia See Silica -Amorphous; (a) This value is for silica Not Exposure Silica gel 10 mg/m3 Not Available inhalable dust containing no asbestos and < 1% amorphous Available Standards crystalline silica. Australia See Silica -Amorphous; (a) This value is for silica Not Exposure Precipitated silica 10 mg/m3 Not Available inhalable dust containing no asbestos and < 1% amorphous Available Standards crystalline silica. Australia silica Silica - Amorphous: Precipitated Not (a) This value is for inhalable dust containing no Exposure 10 mg/m3 Not Available amorphous silica Available asbestos and < 1% crystalline silica. Standards

Occupational Exposure Banding

Ingredient Occupational Exposure Band Rating Occupational Exposure Band Limit sodium E ≤ 0.01 mg/m³ diacetate sodium E ≤ 0.01 mg/m³ chloride citric acid E ≤ 0.01 mg/m³ sunflower oil E ≤ 0.1 ppm Occupational exposure banding is a process of assigning chemicals into specific categories or bands based on a chemical's potency and the adverse health Notes: outcomes associated with exposure. The output of this process is an occupational exposure band (OEB), which corresponds to a range of exposure concentrations that are expected to protect worker health.

Exposure controls Appropriate engineering controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard.

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Personal protection

Eye and face protection

- Chemical goggles.

Skin protection See Hand protection below

Hands/feet protection

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Experience indicates that the following polymers are suitable as glove materials for protection against undissolved, dry solids, where abrasive particles are not present.

Body protection See Other protection below

Other protection

- Overalls.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties Appearance : White coloured free flowing powder

Physical state Solid Relative density (Water = 1) Not Available

Odour Not Available Partition coefficient n-octanol / water Not Available

Odour threshold Characteristic of salt and vinegar Auto-ignition temperature (°C) Not Available pH (as supplied) Not Available Decomposition temperature Not Available Melting point / freezing point (°C) Not Available Viscosity (cSt) Not Available Initial boiling point and boiling range (°C) Not Available Molecular weight (g/mol) Not Available

Flash point (°C) Not Available Taste Not Available

Evaporation rate Not Available Explosive properties Not Available Flammability Not Available Oxidising properties Not Available Upper Explosive Limit (%) Not Available Surface Tension (dyn/cm or mN/m) Not Applicable Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available Vapour pressure (kPa) Not Available Gas group Not Available Solubility in water Not Available pH as a solution (1%) Not Available Vapour density (Air = 1) Not Available VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity : See section 7 Chemical stability : - Unstable in the presence of incompatible materials. Possibility of hazardous reactions : See section 7 Conditions to avoid : See section 7 Incompatible materials : See section 7 Hazardous decomposition products : See section 5

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects Inhaled

The material can cause respiratory irritation in some persons. Persons with impaired respiratory function, airway diseases and conditions such as emphysema or chronic bronchitis, may incur further disability if excessive concentrations of particulate are inhaled. Corrosive acids can cause irritation of the respiratory tract, with coughing, choking and mucous membrane damage.

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Ingestion

The material can produce chemical burns within the oral cavity and gastrointestinal tract following ingestion. The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". Ingestion of acidic corrosives may produce burns around and in the mouth, the throat and oesophagus.

Skin Contact

The material can produce chemical burns following direct contact with the skin. Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce health damage following entry through wounds, lesions or abrasions. Skin contact with acidic corrosives may result in pain and burns; these may be deep with distinct edges and may heal slowly with the formation of scar tissue. Open cuts, abraded or irritated skin should not be exposed to this material Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. The material may cause moderate inflammation of the skin either following direct contact or after a delay of some time.

Eye

The material can produce chemical burns to the eye following direct contact. If applied to the eyes, this material causes severe eye damage. Irritation of the eyes may produce a heavy secretion of tears (lachrymation). Direct eye contact with acid corrosives may produce pain, tears, sensitivity to light and burns.

Chronic

Long-term exposure to respiratory irritants may result in airways disease, involving difficulty breathing and related whole-body problems. Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure. Repeated or prolonged exposure to acids may result in the erosion of teeth, swelling and/or ulceration of mouth lining.

TOXICITY IRRITATION 003984COB SALT & VINEGAR SEASONING W W Not Available Not Available

TOXICITY IRRITATION sodium diacetate Not Available Not Available

TOXICITY IRRITATION

Oral (rat) LD50: 3000 mg/kg [2] Eye (rabbit): 10 mg - moderate sodium chloride Eye (rabbit):100 mg/24h - moderate Skin (rabbit): 500 mg/24h - mild

TOXICITY IRRITATION potassium chloride Oral (rat) LD50: 2600 mg/kg [2] Eye (rabbit): 500 mg/24h - mild

TOXICITY IRRITATION

citric acid dermal (rat) LD50: >2000 mg/kg [1] Eye (rabbit): 0.75 mg/24h-SEVERE

Oral (rat) LD50: 3000 mg/kg [2] Skin (rabbit): 500 mg/24h - mild

TOXICITY IRRITATION sucrose Oral (rat) LD50: 29700 mg/kg [2] Not Available

TOXICITY IRRITATION sodium chloride-37Cl Not Available Not Available

TOXICITY IRRITATION

vegetable protein, hydrolysed Oral (rat) LD50: >2000 mg/kg [2] Eye (rabbit): not irritating * Skin (rabbit): not irritating *

TOXICITY IRRITATION sunflower oil Not Available Not Available

TOXICITY IRRITATION

Dermal (rabbit) LD50: 1060 mg/kg [2] Eye (rabbit): 0.05mg (open)-SEVERE acetic acid glacial Inhalation (rat) LC50: 11 mg/l/4H [2] Skin (human):50mg/24hr - mild

Oral (rat) LD50: 3310 mg/kg [2] Skin (rabbit):525mg (open)-SEVERE

TOXICITY IRRITATION

Dermal (rabbit) LD50: >5000 mg/kg [2] Eye (rabbit): non-irritating *

silica amorphous Inhalation (rat) LC50: >0.139 mg/l/14h**[Grace] [2] Eye: no adverse effect observed (not irritating) [1]

Oral (rat) LD50: 3160 mg/kg [2] Skin (rabbit): non-irritating *

Skin: no adverse effect observed (not irritating) [1]

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Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

SODIUM DIACETATE The material may produce respiratory tract irritation, and result in damage to the lung including reduced lung function.

POTASSIUM CHLORIDE The material may be irritating to the eye, with prolonged contact causing inflammation.

CITRIC ACID For citric acid (and its inorganic citrate salts) Based on extensive animal testing data and on human experience, citric acid ahs low acute toxicity.

SUCROSE Oral (Human) TDLo: 9.6E-5 mg/kg

SUNFLOWER OIL 551omega6 551liper For aliphatic fatty acids (and salts) Acute oral (gavage) toxicity: The acute oral LD50 values in rats for both were greater than >2000 mg/kg bw Clinical signs were generally associated with poor condition following administration of high doses (salivation, diarrhoea, staining, piloerection and lethargy).There were no adverse effects on body weight in any study In some studies, excess test substance and/or irritation in the gastrointestinal tract was observed at necropsy. Epoxidation of double bonds is a common bioactivation pathway for alkenes. For group E aliphatic esters (polyol esters): The polyol esters, including trimethylolpropane (TMP). Oxidative stress in cells and tissues produces free radical and singlet oxygen oxidations of linoleic acid to generate 13-HpODEs, 9-HpODEs, 13-HODEs, and 9-HODEs; these non-enzymatic reactions produce or are suspected but not proven to produce approximately equal amounts of their S and R stereoisomers. For polyunsaturated fatty acids and oils (triglycerides): Animal studies have shown a link between polyunsaturated fat and the incidence of tumours, which increased with increasing intake of polyunsaturated fats.

ACETIC ACID GLACIAL The material may produce severe irritation to the eye causing pronounced inflammation. The material may cause severe skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin. Prolonged or repeated exposure to acetic acid may produce irritation and/ or corrosion at the site of contact as well as systemic toxicity.

SILICA AMORPHOUS Reports indicate high/prolonged exposures to amorphous silicas induced lung fibrosis in experimental animals; in some experiments these effects were reversible. For silica amorphous: When experimental animals inhale synthetic amorphous silica (SAS) dust, it dissolves in the lung fluid and is rapidly eliminated. The substance is classified by IARC as Group 3: NOT classifiable as to its carcinogenicity to humans.

003984COB SALT & VINEGAR SEASONING W W & SODIUM DIACETATE & SODIUM CHLORIDE & CITRIC ACID & SODIUM CHLORIDE-37CL & SUNFLOWER OIL & ACETIC ACID GLACIAL Asthma-like symptoms may continue for months or even years after exposure to the material ends.

003984COB SALT & VINEGAR SEASONING W W & ACETIC ACID GLACIAL For acid mists, aerosols, vapours Test results suggest that eukaryotic cells are susceptible to genetic damage when the pH falls to about 6.5.

SODIUM DIACETATE & SODIUM CHLORIDE & SODIUM CHLORIDE-37CL The material may produce moderate eye irritation leading to inflammation.

SODIUM DIACETATE & SODIUM CHLORIDE & CITRIC ACID & SODIUM CHLORIDE-37CL & SUNFLOWER OIL The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin.

SODIUM CHLORIDE-37CL & SUNFLOWER OIL No significant acute toxicological data identified in literature search.

Acute Toxicity Carcinogenicity Skin Irritation/Corrosion Reproductivity Legend: Serious Eye Damage/Irritation STOT - Single Exposure – Data either not available or does not fill the criteria for classification Respiratory or Skin sensitisation STOT - Repeated Exposure – Data available to make classification Mutagenicity Aspiration Hazard

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE 003984COB SALT & VINEGAR SEASONING W W Not Available Not Available Not Available Not Available Not Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE LC50 96 Fish 10-mg/L 2

sodium diacetate EC50 48 Crustacea >1-mg/L 2 EC50 72 Algae or other aquatic plants >1-mg/L 2 NOEC 72 Algae or other aquatic plants 1-mg/L 2

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE sodium chloride LC50 96 Fish 5-840mg/L 2

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EC50 48 Crustacea 402.6mg/L 4 EC50 96 Algae or other aquatic plants 2430mg/L 4 NOEC 6 Fish 0.001mg/L 4

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE LC50 96 Fish 2-10mg/L 2

potassium chloride EC50 48 Crustacea 83mg/L 4 EC50 72 Algae or other aquatic plants 2-500mg/L 2 NOEC 72 Algae or other aquatic plants >=100mg/L 2

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE LC50 96 Fish 1-516mg/L 2 EC50 48 Crustacea >50mg/L 2 citric acid EC50 72 Algae or other aquatic plants 990mg/L 2 EC0 72 Crustacea <80mg/L 1 NOEC 16 Crustacea 153mg/L 4

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE sucrose LC50 96 Fish 2200000mg/L 3 EC50 96 Algae or other aquatic plants 60200000mg/L 3

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE sodium chloride-37Cl Not Available Not Available Not Available Not Available Not Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE vegetable protein, hydrolysed Not Available Not Available Not Available Not Available Not Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE sunflower oil Not Available Not Available Not Available Not Available Not Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE LC50 96 Fish >1-mg/L 2

acetic acid glacial EC50 48 Crustacea >1-mg/L 2 EC50 72 Algae or other aquatic plants >1-mg/L 2 NOEC 72 Algae or other aquatic plants 1-mg/L 2

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE LC50 96 Fish 1-289.09mg/L 2

silica amorphous EC50 48 Crustacea ca.7600mg/L 1 EC50 72 Algae or other aquatic plants 440mg/L 1 NOEC 720 Crustacea 34.223mg/L 2

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data Ecotoxicity: The tolerance of water organisms towards pH margin and variation is diverse. For Acetic Acid: Acetic acid and its salts (the acetates) can be grouped together because of their close structural relationships, their natural occurrence in plants and animals, and their fundamental role in cell metabolism. DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air sodium diacetate LOW LOW sodium chloride LOW LOW potassium chloride HIGH HIGH citric acid LOW LOW sucrose LOW LOW acetic acid glacial LOW LOW silica amorphous LOW LOW

Bioaccumulative potential

Ingredient Bioaccumulation sodium diacetate LOW (LogKOW = 0.0868)

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sodium chloride LOW (LogKOW = 0.5392) potassium chloride LOW (LogKOW = -0.4608) citric acid LOW (LogKOW = -1.64) sucrose LOW (LogKOW = -3.7) acetic acid glacial LOW (LogKOW = -0.17) silica amorphous LOW (LogKOW = 0.5294)

Mobility in soil

Ingredient Mobility sodium diacetate HIGH (KOC = 1) sodium chloride LOW (KOC = 14.3) potassium chloride LOW (KOC = 14.3) citric acid LOW (KOC = 10) sucrose LOW (KOC = 10) acetic acid glacial HIGH (KOC = 1) silica amorphous LOW (KOC = 23.74)

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods Product / Packaging disposal

- DO NOT allow wash water from cleaning or process equipment to enter drains.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant NO

HAZCHEM Not Applicable

Land transport (ADG): NOT Air transport (ICAO-IATA / DGR): NOT Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF REGULATED FOR TRANSPORT OF REGULATED FOR TRANSPORT OF DANGEROUS GOODS DANGEROUS GOODS DANGEROUS GOODS UN number: Not Applicable UN proper shipping name: Not Applicable Transport hazard class(es): Not Applicable Subrisk: Not Applicable Packing group: Not Applicable

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

sodium diacetate is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS) - Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5

sodium chloride is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS) - IMO Provisional Categorization of Liquid Substances - List 3: (Trade-named) mixtures containing at least 99% by weight of components already assessed by IMO, presenting safety hazards

potassium chloride is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS) - IMO IBC Code Chapter 17: Summary of minimum requirements - Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - - IMO IBC Code Chapter 18: List of products to which the Code does not apply Schedule 4 - IMO MARPOL (Annex II) - List of Noxious Liquid Substances Carried in Bulk - GESAMP/EHS Composite List - GESAMP Hazard Profiles

citric acid is found on the following regulatory lists - Australia Hazardous Chemical Information System (HCIS) - Hazardous Chemicals - IMO IBC Code Chapter 17: Summary of minimum requirements - Australia Inventory of Chemical Substances (AICS) - IMO MARPOL (Annex II) - List of Noxious Liquid Substances Carried in Bulk - GESAMP/EHS Composite List - GESAMP Hazard Profiles

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sucrose is found on the following regulatory lists - Australia Exposure Standards - Australia Inventory of Chemical Substances (AICS)

sodium chloride-37Cl is found on the following regulatory lists - Not Applicable

vegetable protein, hydrolysed is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS) - IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances

sunflower oil is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS) - IMO IBC Code Chapter 17: Summary of minimum requirements - GESAMP/EHS Composite List - GESAMP Hazard Profiles - IMO MARPOL (Annex II) - List of Noxious Liquid Substances Carried in Bulk

acetic acid glacial is found on the following regulatory lists - Australia Dangerous Goods Code (ADG Code) - Dangerous Goods List - Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - - Australia Dangerous Goods Code (ADG Code) - List of Emergency Action Codes Schedule 6 - Australia Exposure Standards - GESAMP/EHS Composite List - GESAMP Hazard Profiles - Australia Hazardous Chemical Information System (HCIS) - Hazardous Chemicals - IMO IBC Code Chapter 17: Summary of minimum requirements - Australia Inventory of Chemical Substances (AICS) - IMO MARPOL (Annex II) - List of Noxious Liquid Substances Carried in Bulk - Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - - IMO Provisional Categorization of Liquid Substances - List 3: (Trade-named) mixtures Schedule 2 containing at least 99% by weight of components already assessed by IMO, presenting - Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - safety hazards Schedule 4 - International Air Transport Association (IATA) Dangerous Goods Regulations - Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - - International Maritime Dangerous Goods Requirements (IMDG Code) Schedule 5 - United Nations Recommendations on the Transport of Dangerous Goods Model Regulations

silica amorphous is found on the following regulatory lists - Australia Exposure Standards - Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - - Australia Hazardous Chemical Information System (HCIS) - Hazardous Chemicals Schedule 4 - Australia Inventory of Chemical Substances (AICS) - GESAMP/EHS Composite List - GESAMP Hazard Profiles - - International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs - International WHO List of Proposed Occupational Exposure Limit (OEL) Values for Manufactured Nanomaterials (MNMS)

National Inventory Status

National Inventory Status Australia - AICS No (sodium chloride-37Cl) Canada - DSL No (sodium chloride-37Cl) No (sucrose; potassium chloride; citric acid; sodium chloride-37Cl; acetic acid glacial; vegetable protein, hydrolysed; sunflower oil; sodium chloride; Canada - NDSL sodium diacetate) China - IECSC No (sodium chloride-37Cl) Europe - EINEC / ELINCS / No (sodium chloride-37Cl) NLP Japan - ENCS No (sucrose; sodium chloride-37Cl; vegetable protein, hydrolysed; sunflower oil) Korea - KECI No (sodium chloride-37Cl; vegetable protein, hydrolysed) New Zealand - NZIoC No (sodium chloride-37Cl) Philippines - PICCS No (sodium chloride-37Cl) USA - TSCA No (sodium chloride-37Cl; vegetable protein, hydrolysed) Taiwan - TCSI No (sodium chloride-37Cl) Mexico - INSQ No (sodium chloride-37Cl; vegetable protein, hydrolysed; sunflower oil) Vietnam - NCI No (sodium chloride-37Cl; sodium diacetate) Russia - ARIPS No (sodium chloride-37Cl; vegetable protein, hydrolysed; sodium diacetate) Yes = All CAS declared ingredients are on the inventory Legend: No = One or more of the CAS listed ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)

SECTION 16 OTHER INFORMATION

Revision Date : 24/10/2019 Initial Date : 03/10/2019

Other information Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment.

end of SDS