Recommendations for Occupational Safety and Health
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Chemical Hygiene Plan Manual
CHEMICAL HYGIENE PLAN AND HAZARDOUS MATERIALS SAFETY MANUAL FOR LABORATORIES This is the Chemical Hygiene Plan specific to the following areas: Laboratory name or room number(s): ___________________________________ Building: __________________________________________________________ Supervisor: _______________________________________________________ Department: _______________________________________________________ Telephone numbers 911 for Emergency and urgent consultation 48221 Police business line 46919 Fire Dept business line 46371 Radiological and Environmental Management Revisied on: Enter a revision date here. All laboratory chemical use areas must maintain a work-area specific Chemical Hygiene Plan which conforms to the requirements of the OSHA Laboraotry Standard 29 CFR 19190.1450. Purdue University laboratories may use this document as a starting point for creating their work area specific CHP. Minimally this cover page is to be edited for work area specificity (non-West Lafayette laboratories are to place their own emergency, fire, and police telephone numbers in the space above) AND appendix K must be completed. This instruction and information box should remain. This model CHP is version 2010A; updates are to be found at www.purdue.edu/rem This page intentionally blank. PURDUE CHEMICAL HYGIENE PLAN AWARENESS CERTIFICATION For CHP of: ______________________________ Professor, building, rooms The Occupational Safety and Health Administration (OSHA) requires that laboratory employees be made aware of the Chemical Hygiene Plan at their place of employment (29 CFR 1910.1450). The Purdue University Chemical Hygiene Plan and Hazardous Materials Safety Manual serves as the written Chemical Hygiene Plan (CHP) for laboratories using chemicals at Purdue University. The CHP is a regular, continuing effort, not a standby or short term activity. Departments, divisions, sections, or other work units engaged in laboratory work whose hazards are not sufficiently covered in this written manual must customize it by adding their own sections as appropriate (e.g. -
Sodium Diacetate
Technical Data Sheet Ref.: 2019_12v09 Sodium Diacetate Stability Description SodiumDiacetate is stable for 3 years from Sodium Diacetate is available as a free date of production. Physical stability and flowing white crystal, containing appearance may change before the end of approximately equimolar amounts of shelf-life if not stored single-stacked in Sodium Acetate and acetic acid. closed original packaging, dry and at room temperature. PRODUCT PROPERTIES Handling Product is classified as irritant. Always Product name Sodium Diacetate check the Safety Data Sheet and label Formula CH3COONaCH3COOH before using the product. Molecular weight 142.08 g/mol CAS No. 126-96-5 Packaging EINECS No. 2048149 Sodium Diacetate crystal is packed in 900 kg big bags. HS code US 2915.29.5000 HS code EU 2915.29.00 Safety precautions Please see the Safety Data Sheet before handling the material. Product grades Sodium Diacetate has a free acetic acid content of 40% - 43%. Application Sodium Diacetate is used in haemodialysis. The product is also used in other applications where it is advantageous to use a solid source of free acetic acid, e.g. for safer handling and reduced transportation costs. Warranty. This information herein is offered as a guide and is believed to be accurate and reliable as of the date of the printing. The values given are not to be considered as a warranty and they are subject to change without prior notice. For additional information regarding our products or for information concerning current specifications, please contact our Technical Service. Niacet Corporation www.niacet.com Niacet b.v. 400, 47th Street P.O. -
Effects of Sodium Citrate Plus Sodium Diacetate and Buffered Vinegar on Escherichia Coli O157:H7 and Psychrotrophic Bacteria in Brine-Injected Beef
359 Journal of Food Protection, Vol. 74, No. 3, 2011, Pages 359–364 doi:10.4315/0362-028X.JFP-10-294 Copyright G, International Association for Food Protection Effects of Sodium Citrate plus Sodium Diacetate and Buffered Vinegar on Escherichia coli O157:H7 and Psychrotrophic Bacteria in Brine-Injected Beef AMUDHAN PONRAJAN,1,2 MARK A. HARRISON,1 JACOB R. SEGERS,2 BRADLEY K. LOWE,2 RUSSELL O. MCKEITH,2 T. DEAN PRINGLE,2 KARINA G. MARTINO,1 JAKE H. MULLIGAN,1 AND ALEXANDER M. STELZLENI2* Downloaded from http://meridian.allenpress.com/jfp/article-pdf/74/3/359/1685103/0362-028x_jfp-10-294.pdf by guest on 01 October 2021 1Department of Food Science and Technology and 2Department of Animal and Dairy Sciences, University of Georgia, Athens, Georgia 30602, USA MS 10-294: Received 15 July 2010/Accepted 4 December 2010 ABSTRACT The objective of this research was to examine the effects of sodium citrate plus sodium diacetate or buffered vinegar on Escherichia coli O157:H7 and psychrotrophic bacteria when incorporated in brine solutions for injected beef. Two experiments were conducted in which 30 top rounds and 30 top sirloins were injected (110%) to contain (i) 0.5% sodium chloride and 0.4% sodium tripolyphosphate as the control (CNT); (ii) CNT with a 1% solution of 80% sodium citrate plus 20% sodium diacetate (SCzD); or (iii) CNT with 2% buffered vinegar (VIN) in the final product. For the E. coli challenge, muscles were surface inoculated to target 6 log CFU/cm2. After injection and 10 days of storage in a vacuum package (4uC), one half of each muscle was sampled raw and the other half was cooked to an internal temperature of 60uC with a 12-min hold. -
Safety Data Sheet Flammable Storage Code Red
SDS No.: DD0032 SAFETY DATA SHEET FLAMMABLE STORAGE CODE RED Section 1 Identifi cation Page E1 of E2 CHEMTREC 24 Hour Emergency ® Phone Number (800) 424-9300 Innovating Science by Aldon Corporation 221 Rochester Street For laboratory and industrial use only. Avon, NY 14414-9409 Not for drug, food or household use. “cutting edge science for the classroom” (585) 226-6177 Product 1,2-DICHLOROETHANE Synonyms Ethylene Dichloride ; Ethylene Chloride ; EDC ; Dichloroethane Section 2 Hazards identifi cation Signal word: DANGER Precautionary statement: Pictograms: GHS02 / GHS07 / GHS08 P201: Obtain special instructions before use. Target organs: Liver, Kidneys P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat/sparks/open fl ames/hot surfaces. No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P242: Use only non-sparking tools. GHS Classifi cation: P243: Take precautionary measures against static discharge. Flammable liquid (Category 2) P261: Avoid breathing mist/vapours/spray. Acute toxicity, oral (Category 4) P264: Wash hands thoroughly after handling. Skin irritation (Category 2) P270: Do not eat, drink or smoke when using this product. Eye irritation (Category 2A) P271: Use only outdoors or in a well-ventilated area. STOT-SE (Category 3) P280: Wear protective gloves/protective clothing/eye protection/face protection. Carcinogenicity (Category 1B) P301+P330+P312: IF SWALLOWED: Rinse mouth. Call a POISON CENTER or doctor if you feel unwell. GHS Label information: Hazard statement: P302+P352: IF ON SKIN: Wash with plenty of water and soap. H225: Highly fl ammable liquid and vapour. -
Pds Sodium Polysulfide 35 Percent
Nouryon Functional Chemicals GmbH Product Data Sheet Sodium Polysulfide 35% - Na2S4 Formula: Na2S4 Chemical Name: Disodium Tetrasulfide (hydrate) Concentration: 35 % Molecular weight: 174.24 g/mol CAS-No.: 1344-08-7 EC-No.: 215-689-9 Properties: Relative Density (20 °C): 1.33 g/ml pH-value 10 to 11 Specification: Appearance: Orange to light brown solution Na2Sx Content: Min. 34 % Na2S2O3 (Sodium Thiosulfate): Max. 4.0 % Na2CO3 (Sodium Carbonate): Max. 0.4 % Iron (Fe): Max. 10 ppm Analytical methods are available on request. Major Applications: Process aid for leather and tanning applications, auxiliary in cellulose production, coloration of textiles, flocculent for waste water treatment, reduction of NOx in off-gases. Storage: Store in a dry and dark location, avoid exposure to direct sun light. Max. storage temperature 40°C. When stored under these recommended storage conditions, Sodium Polysulfide (>35wt%) will remain within the Nouryon specifications for a period of at least six months after delivery. Packaging and Transport: Sodium Sulfide is delivered in: IBCs 1200-1300 kg net Hazard Identification No.: 80 UN-No.: 1760 (CORROSIVE LIQUID, N.O.S. (Sodium Polysulphides) Safety advice: SODIUM POLYSULFIDE (>35wt%) is classified as a dangerous product. It is corrosive to metals and contact with the skin and eyes can cause burns. It is toxic if swallowed and is very toxic to aquatic life. Contact with acids must be avoided. In contact with acids, the toxic gas Hydrogen Sulfide (H2S) can be released. For more information regarding handling, transport and first aid please refer to our Material Safety Data Sheet (MSDS). All information concerning this product and/or suggestions for handling and use contained herein are offered in good faith and are believed to be reliable. -
Chemical Hygiene Plan 2016
Chemical Hygiene Plan 2016 Table of Contents 1.0 INTRODUCTION AND SCOPE ...................................................... 8 1.1 Assignment of Responsibility ........................................................................... 8 1.1.1 Environmental Health & Safety (EH&S) ................................................ 8 1.1.2 Laboratory Staff ........................................................................................ 9 1.1.3 Principal Investigator ............................................................................... 9 1.1.4 Research Departments ............................................................................ 10 1.1.5 Northern Arizona University ................................................................. 10 1.2 Availability ....................................................................................................... 10 1.3 Annual Review ................................................................................................. 10 1.4 Employee Information and Training ............................................................. 10 1.4.1 Information .............................................................................................. 10 1.4.2 Training .................................................................................................... 11 1.5 Record Keeping ............................................................................................... 12 2.0 HAZARD DEFINITIONS AND ASSESSMENT .......................... 12 2.1 Hazardous Chemical Definitions -
Shale Gas and Groundwater Quality
Shale Gas and Groundwater Quality A literature review on fate and effects of added chemicals Alette Langenhoff 1202141-008 © Deltares, 2011 1202141-008-ZWS-0001, 28 December 2011, final Contents 1 Introduction 1 2 The process of fracturing or fracking 5 3 The use of chemicals 7 4 Polyacrylamide 8 4.1 Aerobic degradation of polyacrylamide 8 4.2 Anaerobic degradation 10 4.3 Chemical or physical removal 10 4.4 Conclusion on removal of polyacrylamide 10 5 Glutaraldehyde 12 5.1 Biocide 12 5.2 Biodegradation 12 5.3 Chemical inactivation of glutaraldehyde 13 6 Conclusions 14 7 References 15 Appendices 17 Appendices A Chemicals identified in hydraulic fracturing fluid and flowback/produced water (EPA, 2011). A-1 B Fracturing fluid ingredients and common uses (Europe Unconventional Gas 2011) B-1 C Properties of Polyacrylamide (source: Wikipedia) C-1 D Properties of Glutaraldehyde (source: Wikipedia) D-1 Shale Gas and Groundwater Quality i 1202141-008-ZWS-0001, 28 December 2011, final 1 Introduction Shale gas is a so-called unconventional sources of natural gas, and is one of the most rapidly expanding trends in onshore domestic oil and gas exploration and production today (Fig. 1 and 2). Shale gas is present in hydrocarbon rich shale formations. Shallow gas is commonly defined as gas occurrences in unconsolidated sediments of Tertiary age (often down to depths of 1000 m below surface). The occurrences are positively associated with thick Neogene sediments and are often trapped in anticlinal structures associated with rising salt domes (Muntendam-Bos et al, 2009). Shale has low matrix permeability, so gas production in commercial quantities requires fractures to provide permeability. -
Gasket Chemical Services Guide
Gasket Chemical Services Guide Revision: GSG-100 6490 Rev.(AA) • The information contained herein is general in nature and recommendations are valid only for Victaulic compounds. • Gasket compatibility is dependent upon a number of factors. Suitability for a particular application must be determined by a competent individual familiar with system-specific conditions. • Victaulic offers no warranties, expressed or implied, of a product in any application. Contact your Victaulic sales representative to ensure the best gasket is selected for a particular service. Failure to follow these instructions could cause system failure, resulting in serious personal injury and property damage. Rating Code Key 1 Most Applications 2 Limited Applications 3 Restricted Applications (Nitrile) (EPDM) Grade E (Silicone) GRADE L GRADE T GRADE A GRADE V GRADE O GRADE M (Neoprene) GRADE M2 --- Insufficient Data (White Nitrile) GRADE CHP-2 (Epichlorohydrin) (Fluoroelastomer) (Fluoroelastomer) (Halogenated Butyl) (Hydrogenated Nitrile) Chemical GRADE ST / H Abietic Acid --- --- --- --- --- --- --- --- --- --- Acetaldehyde 2 3 3 3 3 --- --- 2 --- 3 Acetamide 1 1 1 1 2 --- --- 2 --- 3 Acetanilide 1 3 3 3 1 --- --- 2 --- 3 Acetic Acid, 30% 1 2 2 2 1 --- 2 1 2 3 Acetic Acid, 5% 1 2 2 2 1 --- 2 1 1 3 Acetic Acid, Glacial 1 3 3 3 3 --- 3 2 3 3 Acetic Acid, Hot, High Pressure 3 3 3 3 3 --- 3 3 3 3 Acetic Anhydride 2 3 3 3 2 --- 3 3 --- 3 Acetoacetic Acid 1 3 3 3 1 --- --- 2 --- 3 Acetone 1 3 3 3 3 --- 3 3 3 3 Acetone Cyanohydrin 1 3 3 3 1 --- --- 2 --- 3 Acetonitrile 1 3 3 3 1 --- --- --- --- 3 Acetophenetidine 3 2 2 2 3 --- --- --- --- 1 Acetophenone 1 3 3 3 3 --- 3 3 --- 3 Acetotoluidide 3 2 2 2 3 --- --- --- --- 1 Acetyl Acetone 1 3 3 3 3 --- 3 3 --- 3 The data and recommendations presented are based upon the best information available resulting from a combination of Victaulic's field experience, laboratory testing and recommendations supplied by prime producers of basic copolymer materials. -
IODINE Its Properties and Technical Applications
IODINE Its Properties and Technical Applications CHILEAN IODINE EDUCATIONAL BUREAU, INC. 120 Broadway, New York 5, New York IODINE Its Properties and Technical Applications ¡¡iiHiüíiüüiütitittüHiiUitítHiiiittiíU CHILEAN IODINE EDUCATIONAL BUREAU, INC. 120 Broadway, New York 5, New York 1951 Copyright, 1951, by Chilean Iodine Educational Bureau, Inc. Printed in U.S.A. Contents Page Foreword v I—Chemistry of Iodine and Its Compounds 1 A Short History of Iodine 1 The Occurrence and Production of Iodine ....... 3 The Properties of Iodine 4 Solid Iodine 4 Liquid Iodine 5 Iodine Vapor and Gas 6 Chemical Properties 6 Inorganic Compounds of Iodine 8 Compounds of Electropositive Iodine 8 Compounds with Other Halogens 8 The Polyhalides 9 Hydrogen Iodide 1,0 Inorganic Iodides 10 Physical Properties 10 Chemical Properties 12 Complex Iodides .13 The Oxides of Iodine . 14 Iodic Acid and the Iodates 15 Periodic Acid and the Periodates 15 Reactions of Iodine and Its Inorganic Compounds With Organic Compounds 17 Iodine . 17 Iodine Halides 18 Hydrogen Iodide 19 Inorganic Iodides 19 Periodic and Iodic Acids 21 The Organic Iodo Compounds 22 Organic Compounds of Polyvalent Iodine 25 The lodoso Compounds 25 The Iodoxy Compounds 26 The Iodyl Compounds 26 The Iodonium Salts 27 Heterocyclic Iodine Compounds 30 Bibliography 31 II—Applications of Iodine and Its Compounds 35 Iodine in Organic Chemistry 35 Iodine and Its Compounds at Catalysts 35 Exchange Catalysis 35 Halogenation 38 Isomerization 38 Dehydration 39 III Page Acylation 41 Carbón Monoxide (and Nitric Oxide) Additions ... 42 Reactions with Oxygen 42 Homogeneous Pyrolysis 43 Iodine as an Inhibitor 44 Other Applications 44 Iodine and Its Compounds as Process Reagents ... -
WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C12N 15/10 (2006.01) kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, (21) International Application Number: BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, PCT/DK20 15/050343 DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (22) International Filing Date: HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, 11 November 2015 ( 11. 1 1.2015) KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, (25) Filing Language: English PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, (26) Publication Language: English SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: PA 2014 00655 11 November 2014 ( 11. 1 1.2014) DK (84) Designated States (unless otherwise indicated, for every 62/077,933 11 November 2014 ( 11. 11.2014) US kind of regional protection available): ARIPO (BW, GH, 62/202,3 18 7 August 2015 (07.08.2015) US GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, (71) Applicant: LUNDORF PEDERSEN MATERIALS APS TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, [DK/DK]; Nordvej 16 B, Himmelev, DK-4000 Roskilde DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, (DK). -
Tungstovanadate Heteropoly Complexes. 11. Products of Acidification of V2w&Lg4
TUNGSTOVANADATEHETEROPOLY COMPLEXES Inorganic Chemistry, Vol. 10, No. 12, 1971 2745 Then, assuming that the difference is also reflected in line widths were somewhat broader than those of the Tze,much broader epr lines are expected for the mono- VO(H20)42+spectrum. That observation is compatible chloro species, which would be difficult to detect in the with a decreased re relative to that of the aquo complex, presence of the sharper spectrum of VO(H20)2C12. but a much more detailed investigation of the relaxa- The liquid solution epr spectra for a number of tion processes would be necessary for quantitative HC1 concentrations were also observed in this labora- comparison. tory. The intensity of the spectrum attributed to VO (H~0)4~+appeared to follow qualitatively the rela- Acknowledgments.-We are indebted to Dr. W. tive concentrations indicated in Tables I1 and I11 and Burton Lewis and others for helpful comments during Figure 4. However, no attempt was made to do an discussions of the work reported here. We also wish absolute spin count. In 12 M HC1 solution the (g) to thank Dr. B. B. McInteer and Mr. R. M. Potter of and (A) values obtained corresponded well with the Los Alamos Scientific Laboratory for supplying those reported by Kon and Sharpless and the observed the enriched "'0. CONTRIBUTIONFROM THE DEPARTMENTOF CHEMISTRY, GEORGETOWNUNIVERSITY, WASHINGTON, D. C. 20007 Tungstovanadate Heteropoly Complexes. 11. Products of Acidification of v2w&lg4- BY C. M. FLY", JR., AND M. T. POPE* Receiz'ed April 30, 1971 Acidification of solutions of VzW40104- is an efficient means of preparing the red complex V~WQO~O~-,isolated as K, "4, Na, N(CH3)4, C(NHZ)~,and C~H~(NH~)Zsalts. -
Alfa Laval Black and Grey List, Rev 14.Pdf 2021-02-17 1678 Kb
Alfa Laval Group Black and Grey List M-0710-075E (Revision 14) Black and Grey list – Chemical substances which are subject to restrictions First edition date. 2007-10-29 Revision date 2021-02-10 1. Introduction The Alfa Laval Black and Grey List is divided into three different categories: Banned, Restricted and Substances of Concern. It provides information about restrictions on the use of Chemical substances in Alfa Laval Group’s production processes, materials and parts of our products as well as packaging. Unless stated otherwise, the restrictions on a substance in this list affect the use of the substance in pure form, mixtures and purchased articles. - Banned substances are substances which are prohibited1. - Restricted substances are prohibited in certain applications relevant to the Alfa Laval group. A restricted substance may be used if the application is unmistakably outside the scope of the legislation in question. - Substances of Concern are substances of which the use shall be monitored. This includes substances currently being evaluated for regulations applicable to the Banned or Restricted categories, or substances with legal demands for monitoring. Product owners shall be aware of the risks associated with the continued use of a Substance of Concern. 2. Legislation in the Black and Grey List Alfa Laval Group’s Black and Grey list is based on EU legislations and global agreements. The black and grey list does not correspond to national laws. For more information about chemical regulation please visit: • REACH Candidate list, Substances of Very High Concern (SVHC) • REACH Authorisation list, SVHCs subject to authorization • Protocol on persistent organic pollutants (POPs) o Aarhus protocol o Stockholm convention • Euratom • IMO adopted 2015 GUIDELINES FOR THE DEVELOPMENT OF THE INVENTORY OF HAZARDOUS MATERIALS” (MEPC 269 (68)) • The Hong Kong Convention • Conflict minerals: Dodd-Frank Act 1 Prohibited to use, or put on the market, regardless of application.