DEVCON R-Flex Curing Agent

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DEVCON R-Flex Curing Agent ITW POLYMERS AND FLUIDS Chemwatch: 5147-12 Issue Date: 21/07/2014 Version No: 2.1.1.1 Print Date: 23/07/2014 Safety Data Sheet according to WHS and ADG requirements Initial Date: Not Available S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier

Product name DEVCON R-Flex Curing Agent Chemical Name Not Applicable Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains diethyltoluenediamine) Chemical formula Not Applicable Other means of identification Not Available CAS number Not Applicable

Relevant identified uses of the substance or mixture and uses advised against

Use according to manufacturer's directions. The use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritating atmosphere developing. Relevant identified uses Before starting consider control of exposure by mechanical ventilation. Hardener.

Details of the manufacturer/importer

Registered company name ITW POLYMERS AND FLUIDS 100 Hassall Street Wetherill Park NSW 2164 Address Australia Telephone +61 2 9757 8800 Fax +61 2 9757 3855 Website www.itwpf.com.au Email Not Available

Emergency telephone number

Association / Organisation Not Available Emergency telephone numbers 1800 039 008 Other emergency telephone numbers +61 3 9573 3112

CHEMWATCH EMERGENCY RESPONSE

Primary Number Alternative Number 1 Alternative Number 2 1800 039 008 +612 9186 1132 Not Available

Once connected and if the message is not in your prefered language then please dial 01

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.

Poisons Schedule S5

GHS Classification [1] Acute Toxicity (Oral) Category 4, Acute Toxicity (Dermal) Category 4, Eye Irrit. 2, STOT - RE Category 2, Chronic Aquatic Hazard Category 1 Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI

Label elements

GHS label elements

SIGNAL WORD WARNING

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Hazard statement(s)

H302 Harmful if swallowed H312 Harmful in contact with skin H319 Causes serious eye irritation H373 May cause damage to organs through prolonged or repeated exposure H410 Very toxic to aquatic life with long lasting effects

Precautionary statement(s): Prevention

P260 Do not breathe dust/fume/gas/mist/vapours/spray. P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary statement(s): Response

P321 Specific treatment (see advice on this label). P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P314 Get medical advice/attention if you feel unwell. P337+P313 If eye irritation persists: Get medical advice/attention.

Precautionary statement(s): Storage Not Applicable

Precautionary statement(s): Disposal

P501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances See section below for composition of Mixtures Mixtures

CAS No %[weight] Name 68479-98-1 >60 diethyltoluenediamine 112-80-1 10-30 oleic acid 1333-86-4 0.1-1 carbon black 8013-07-8 1-5 soybean oil, epoxidised 60-33-3 1-5 linoleic acid Not Available 1-5 C14-C17 saturated carboxylic acids

SECTION 4 FIRST AID MEASURES

Description of first aid measures

If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper Eye Contact and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin contact occurs: Immediately remove all contaminated clothing, including footwear. Skin Contact Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Inhalation Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Ingestion Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice.

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Indication of any immediate medical attention and special treatment needed

The material may induce methaemoglobinaemia following exposure. Initial attention should be directed at oxygen delivery and assisted ventilation if necessary. Hyperbaric oxygen has not demonstrated substantial benefits. Hypotension should respond to Trendelenburg's position and intravenous fluids; otherwise dopamine may be needed. Symptomatic patients with methaemoglobin levels over 30% should receive methylene blue. (Cyanosis, alone, is not an indication for treatment). The usual dose is 1-2 mg/kg of a 1% solution (10 mg/ml) IV over 50 minutes; repeat, using the same dose, if symptoms of hypoxia fail to subside within 1 hour. Thorough cleansing of the entire contaminated area of the body, including the scalp and nails, is of utmost importance. BIOLOGICAL EXPOSURE INDEX - BEI These represent the determinants observed in specimens collected from a healthy worker exposed at the Exposure Standard (ES or TLV):

Determinant Index Sampling Time Comment 1. Methaemoglobin in blood 1.5% of haemoglobin During or end of shift B, NS, SQ

B: Background levels occur in specimens collected from subjects NOT exposed NS: Non-specific determinant; also observed after exposure to other materials SQ: Semi-quantitative determinant - Interpretation may be ambiguous; should be used as a screening test or confirmatory test.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media

Foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide.

Special hazards arising from the substrate or mixture

Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Fire Fighting Prevent, by any means available, spillage from entering drains or water course. Use water delivered as a fine spray to control fire and cool adjacent area. Combustible. Slight fire hazard when exposed to heat or flame. Fire/Explosion Hazard Heating may cause expansion or decomposition leading to violent rupture of containers. On combustion, may emit toxic fumes of carbon monoxide (CO).

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Environmental hazard - contain spillage. Clean up all spills immediately. Minor Spills Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Environmental hazard - contain spillage. Moderate hazard. Major Spills Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard.

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

DO NOT USE brass or copper containers / stirrers DO NOT allow clothing wet with material to stay in contact with skin Avoid all personal contact, including inhalation. Safe handling Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. Store in original containers. Keep containers securely sealed. Other information Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers.

Conditions for safe storage, including any incompatibilities

DO NOT use aluminium, galvanised or tin-plated containers Suitable container Metal can or drum Packaging as recommended by manufacturer.

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Check all containers are clearly labelled and free from leaks. Many arylamines (aromatic amines such as aniline, N-ethylaniline, o-toluidine, xylidine etc. and their mixtures) are hypergolic (ignite Storage incompatibility spontaneously) with red fuming nitric acid. When the amines are dissolved in triethylamine, ignition occurs at -60 deg. C. or less. Various metal oxides and their salts may promote ignition of amine-red fuming nitric acid systems.

PACKAGE MATERIAL INCOMPATIBILITIES Not Available

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA Source Ingredient Material name TWA STEL Peak Notes Australia Exposure Standards carbon black Carbon black 3 mg/m3 Not Available Not Available Not Available

EMERGENCY LIMITS Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3 oleic acid 0.015 ppm 0.05 ppm 0.4 ppm 500 ppm carbon black 3.5 ppm 10.5 ppm 17.5 ppm 500 ppm

Ingredient Original IDLH Revised IDLH diethyltoluenediamine Not Available Not Available oleic acid Not Available Not Available carbon black N.E. mg/m3N.E. ppm 1,750 mg/m3 soybean oil, epoxidised Not Available Not Available linoleic acid Not Available Not Available C14-C17 saturated carboxylic acids Not Available Not Available

Exposure controls

Use in a well-ventilated area General exhaust is adequate under normal operating conditions. Appropriate engineering controls Refer also to protective measures for the other component used with the product. Read both MSDS before using; store and attach MSDS together.

Personal protection

Safety glasses with side shields. Chemical goggles. Eye and face protection Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. Skin protection See Hand protection below Wear chemical protective gloves, e.g. PVC. Hands/feet protection Wear safety footwear or safety gumboots, e.g. Rubber Body protection See Other protection below Overalls. Other protection P.V.C. apron. Barrier cream. Thermal hazards Not Available

Recommended material(s) Respiratory protection GLOVE SELECTION INDEX Type AK-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Glove selection is based on a modified presentation of the: Z88 or national equivalent) "Forsberg Clothing Performance Index". Where the concentration of gas/particulates in the breathing zone, The effect(s) of the following substance(s) are taken into account in the computer- generated selection: approaches or exceeds the "Exposure Standard" (or ES), respiratory DEVCON R-Flex Curing Agent Not Available protection is required. Degree of protection varies with both face-piece and Class of filter; Material CPI the nature of protection varies with Type of filter. * CPI - Chemwatch Performance Index A: Best Selection Required B: Satisfactory; may degrade after 4 hours continuous immersion Minimum Half-Face Full-Face Powered Air C: Poor to Dangerous Choice for other than short term immersion Protection Respirator Respirator Respirator NOTE: As a series of factors will influence the actual performance of the glove, a final Continued... Chemwatch: 5147-12 Page 5 of 9 Issue Date: 21/07/2014 Version No: 2.1.1.1 DEVCON R-Flex Curing Agent Print Date: 23/07/2014

selection must be based on detailed observation. - Factor * Where the glove is to be used on a short term, casual or infrequent basis, factors such as "feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise AK-PAPR-AUS / up to 10 x ES AK-AUS P3 - be unsuitable following long-term or frequent use. A qualified practitioner should be consulted. Class 1 P3 AK-AUS / up to 50 x ES - - Class 1 P3 up to 100 x ES - AK-2 P3 AK-PAPR-2 P3 ^

^ - Full-face A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Black mobile liquid with a mild ammonia like odour; slightly soluble in water.

Physical state Liquid Relative density (Water = 1) 1.05 Odour Not Available Partition coefficient n-octanol / water Not Available Odour threshold Not Available Auto-ignition temperature (°C) Not Available pH (as supplied) Not Available Decomposition temperature Not Available Melting point / freezing point (°C) Not Available Viscosity (cSt) Not Available Initial boiling point and boiling range >100 Molecular weight (g/mol) Not Applicable (°C) Flash point (°C) >135 (TCC) Taste Not Available Evaporation rate <<1 BuAC = 1 Explosive properties Not Available Flammability Not Applicable Oxidising properties Not Available Upper Explosive Limit (%) Not Available Surface Tension (dyn/cm or mN/m) Not Available Lower Explosive Limit (%) Not Available Volatile Component (%vol) VOC 0 g/L Vapour pressure (kPa) Not Available Gas group Not Available Solubility in water (g/L) Partly Miscible pH as a solution(1%) >7 (5% solution) Vapour density (Air = 1) >1 VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7 Unstable in the presence of incompatible materials. Chemical stability Product is considered stable. Hazardous polymerisation will not occur. Possibility of hazardous reactions See section 7 Conditions to avoid See section 7 Incompatible materials See section 7 Hazardous decomposition products See section 5

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Limited evidence or practical experience suggests that the material may produce irritation of the respiratory system, in a significant number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to a chemical insult by first removing or neutralising the irritant and then repairing the damage. The repair process, which initially evolved to protect mammalian lungs from foreign matter and antigens, Inhaled may however, produce further lung damage resulting in the impairment of gas exchange, the primary function of the lungs. Respiratory tract irritation often results in an inflammatory response involving the recruitment and activation of many cell types, mainly derived from the vascular system. Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be fatal or may produce serious damage to the health of the individual. Ingestion of amine epoxy-curing agents (hardeners) may cause severe abdominal pain, nausea, vomiting or diarrhoea. The vomitus may contain Ingestion blood and mucous. If death does not occur within 24 hours there may be an improvement in the patients condition for 2-4 days only to be followed by the sudden onset of abdominal pain, board-like abdominal rigidity or hypo-tension; this indicates that delayed gastric or oesophageal corrosive damage has occurred.

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Skin contact with the material may be harmful; systemic effects may result following absorption.

Limited evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a substantial number of Skin Contact individuals following direct contact, and/or produces significant inflammation when applied to the healthy intact skin of animals, for up to four hours, such inflammation being present twenty-four hours or more after the end of the exposure period. Skin irritation may also be present after prolonged or repeated exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and thickening of the epidermis. Evidence exists, or practical experience predicts, that the material may cause severe eye irritation in a substantial number of individuals and/or may produce significant ocular lesions which are present twenty-four hours or more after instillation into the eye(s) of experimental animals. Eye Eye contact may cause significant inflammation with pain. Corneal injury may occur; permanent impairment of vision may result unless treatment is prompt and adequate. Repeated or prolonged exposure to irritants may cause inflammation characterised by a temporary redness (similar to windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur. Harmful: danger of serious damage to health by prolonged exposure if swallowed. Serious damage (clear functional disturbance or morphological change which may have toxicological significance) is likely to be caused by Chronic repeated or prolonged exposure. As a rule the material produces, or contains a substance which produces severe lesions. Such damage may become apparent following direct application in subchronic (90 day) toxicity studies or following sub-acute (28 day) or chronic (two-year) toxicity tests.

TOXICITY IRRITATION DEVCON R-Flex Curing Agent Not Available Not Available

TOXICITY IRRITATION

Dermal (rabbit) LD50: >700 mg/kg [Manufacturer] diethyltoluenediamine Inhalation (rats) LD50: >2.45 mg/l Eye (rabbit): moderate-SEVERE Oral (rat) LD50: 470-540 mg/kg Skin (rabbit): slight Not Available Not Available

TOXICITY IRRITATION

Oral (rat) LD50: 74000 mg/kg Skin (human):15 mg/3d-I- moderate oleic acid Skin (rabbit):500 mg mild Not Available Not Available

TOXICITY IRRITATION

carbon black Dermal (rabbit) LD50: >3000 mg/kg Not Available Not Available

TOXICITY IRRITATION

Oral (rat) LD50: 40000 mg/kg [KIRK-OTHMER] soybean oil, epoxidised Oral (rat) LD50: 6000 mg/kg Skin (rabbit): non-irritating Not Available Not Available

TOXICITY IRRITATION

Intraperitoneal (Mouse) LD50: 280 mg/kg Skin (human):75 mg/3d-I- moderate linoleic acid Intraperitoneal (Rat) LD50: >50000 mg/kg Oral (Mouse) LD50: >50000 mg/kg Not Available Not Available

Not available. Refer to individual constituents.

The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may DIETHYLTOLUENEDIAMINE produce conjunctivitis. p-Phenylenediamines are oxidised by the liver microsomal enzymes (S9). Pure p-phenylenediamine is non-mutagenic in but becomes mutagenic after it is oxidized.

The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. OLEIC ACID The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of dermatitis is often characterised by skin redness (erythema) and swelling the epidermis.

No significant acute toxicological data identified in literature search. CARBON BLACK WARNING: This substance has been classified by the IARC as Group 2B: Possibly Carcinogenic to Humans. Inhalation (rat) TCLo: 50 mg/m3/6h/90D-I Nil reported

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For epoxidised oils and their derivatives (EOD): Epoxidised Oils and Derivatives are epoxidised fatty acid esters. The oils from which these products are derived are naturally occurring long SOYBEAN OIL, EPOXIDISED chain fatty acid sources, and there is considerable overlap in the composition of the fatty acid portion of these products. They are primarily the C18 acids: oleic, linoleic, and linolenic acid. The alcohols are primary alcohols, diols or triols. .

Acute Toxicity Carcinogenicity Skin Irritation/Corrosion Reproductivity Serious Eye Damage/Irritation STOT - Single Exposure Respiratory or Skin sensitisation STOT - Repeated Exposure Mutagenicity Aspiration Hazard

CMR STATUS Not Applicable

SECTION 12 ECOLOGICAL INFORMATION

Toxicity Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air Not Available Not Available Not Available

Bioaccumulative potential

Ingredient Bioaccumulation Not Available Not Available

Mobility in soil

Ingredient Mobility Not Available Not Available

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Recycle wherever possible or consult manufacturer for recycling options. Consult State Land Waste Management Authority for disposal. Product / Packaging disposal Material may be disposed of by controlled burning in an approved incinerator or buried in an approved landfill. Prior to disposal in a landfill the material should be mixed with the other component and reacted to render the material inert.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant

HAZCHEM •3Z

Land transport (ADG)

UN number 3082

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Packing group III UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains diethyltoluenediamine) Environmental hazard No relevant data

Class 9 Transport hazard class(es) Subrisk Not Applicable

Special provisions 179 274 331 335 AU01 Special precautions for user Limited quantity 5 L

Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082 are not subject to this Code when transported by road or rail in; (a) packagings; (b) IBCs; or (c) any other receptacle not exceeding 500 kg(L). - Australian Special Provisions (SP AU01) - ADG Code 7th Ed. Air transport (ICAO-IATA / DGR)

UN number 3082 Packing group III UN proper shipping name Environmentally hazardous substance, liquid, n.o.s. * (contains diethyltoluenediamine) Environmental hazard No relevant data

ICAO/IATA Class 9 Transport hazard class(es) ICAO / IATA Subrisk Not Applicable ERG Code 9L

Special provisions A97A158 Cargo Only Packing Instructions 964 Cargo Only Maximum Qty / Pack 450 L Special precautions for user Passenger and Cargo Packing Instructions 964 Passenger and Cargo Maximum Qty / Pack 450 L Passenger and Cargo Limited Quantity Packing Instructions Y964 Passenger and Cargo Limited Maximum Qty / Pack 30 kg G

Sea transport (IMDG-Code / GGVSee)

UN number 3082 Packing group III UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains diethyltoluenediamine) Environmental hazard No relevant data

IMDG Class 9 Transport hazard class(es) IMDG Subrisk Not Applicable

EMS Number F-A , S-F Special precautions for user Special provisions 274 335 Limited Quantities 5 L

Transport in bulk according to Annex II of MARPOL 73 / 78 and the IBC code

Source Ingredient Pollution Category Residual Concentration - Outside Special Area (% w/w) Residual Concentration IMO MARPOL 73/78 (Annex II) - List of oleic acid Y Not Available Not Available Noxious Liquid Substances Carried in Bulk

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

"International Maritime Dangerous Goods Requirements (IMDG Code)","International Maritime Dangerous Goods Requirements (IMDG Code) - Substance Index","Australia Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (English)","OECD List of High Production Volume (HPV) Chemicals","Australia Inventory of Chemical Substances (AICS)","Belgium Federal Public Service Mobility and Transport, Regulations diethyltoluenediamine(68479-98-1) is concerning the International Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013 (Dutch)","Australia National found on the following regulatory lists Pollutant Inventory","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Spanish)","Australia Dangerous Goods Code (ADG Code) - Dangerous Goods List","International Air Transport Association (IATA) Dangerous Goods Regulations","Australia Hazardous Substances Information System - Consolidated Lists","Australia - New South Wales Protection of the

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Environment Operations (Waste) Regulation 2005 - Characteristics of trackable wastes" "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","International Council of Chemical Associations (ICCA) - High Production Volume List","IOFI Global Reference List of Chemically Defined Substances","IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk","FisherTransport Information","Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions","OECD List of High Production Volume (HPV) Chemicals","Australia oleic acid(112-80-1) is found on the Inventory of Chemical Substances (AICS)","Joint FAO/WHO Expert Committee on Food Additives (JECFA) - Specifications for following regulatory lists Flavourings","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix B (Part 3)","IMO Provisional Categorization of Liquid Substances - List 1: Pure or technically pure products","Sigma-AldrichTransport Information","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","GESAMP/EHS Composite List - GESAMP Hazard Profiles","International Fragrance Association (IFRA) Survey: Transparency List","IMO IBC Code Chapter 17: Summary of minimum requirements" "International Council of Chemical Associations (ICCA) - High Production Volume List","Australia Exposure Standards","OECD List of High Production Volume (HPV) Chemicals","Australia Inventory of Chemical Substances (AICS)","International Numbering System for Food carbon black(1333-86-4) is found on the Additives","Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be Transported","OECD Existing Chemicals following regulatory lists Database","Sigma-AldrichTransport Information","Australia High Volume Industrial Chemical List (HVICL)","Australia Hazardous Substances Information System - Consolidated Lists","Acros Transport Information" soybean oil, epoxidised(8013-07-8) is "International Council of Chemical Associations (ICCA) - High Production Volume List","OECD List of High Production Volume (HPV) found on the following regulatory lists Chemicals","Australia Inventory of Chemical Substances (AICS)","OECD Existing Chemicals Database","Sigma-AldrichTransport Information" "IOFI Global Reference List of Chemically Defined Substances","International Council of Chemical Associations (ICCA) - High Production Volume List","WHO Food Additives Series - Flavouring agents considered for specifications only","FisherTransport Information","OECD List of linoleic acid(60-33-3) is found on the High Production Volume (HPV) Chemicals","Australia Inventory of Chemical Substances (AICS)","Joint FAO/WHO Expert Committee on Food following regulatory lists Additives (JECFA) - Specifications for Flavourings","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix B (Part 3)","International Numbering System for Food Additives","Sigma-AldrichTransport Information","International Fragrance Association (IFRA) Survey: Transparency List","IMO IBC Code Chapter 17: Summary of minimum requirements"

SECTION 16 OTHER INFORMATION

Other information Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references

The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.

end of SDS DEVCON R-Flex Resin

ITW (ITW Polymers & Fluids) Chemwatch Hazard Alert Code: 3 Chemwatch: 5147-11 Issue Date: 24/02/2016 Version No: 3.1.1.1 Print Date: 25/02/2016 Safety Data Sheet according to WHS and ADG requirements Initial Date: Not Available S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier

Product name DEVCON R-Flex Resin Synonyms Not Available Proper shipping name TOXIC LIQUID, ORGANIC, N.O.S. (see 3.2.5 for relevant [AUST.] entries) (contains methylene bis(4-cyclohexylisocyanate)) Other means of Not Available identification

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses Use according to manufacturer's directions.

Details of the supplier of the safety data sheet

Registered company name ITW (ITW Polymers & Fluids) Address 100 Hassall Street Wetherill Park 2164 NSW Australia Telephone +61 2 9757 8800 Fax +61 2 9757 3855 Website https://www.itwpf.com.au/ Email Not Available

Emergency telephone number

Association / Organisation Not Available Emergency telephone 1800 039 008 (24 hours) numbers Other emergency telephone +61 3 9573 3112 numbers

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.

Poisons Schedule S6 Acute Toxicity (Inhalation) Category 2, Skin Corrosion/Irritation Category 2, Eye Irritation Category 2A, Respiratory Sensitizer Category 1, Skin Sensitizer Classification [1] Category 1, Specific target organ toxicity - single exposure Category 3 (respiratory tract irritation) Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI

Label elements

GHS label elements

SIGNAL WORD DANGER

Hazard statement(s)

H331 Toxic if inhaled H315 Causes skin irritation H319 Causes serious eye irritation H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H317 May cause an allergic skin reaction H335 May cause respiratory irritation

Precautionary statement(s) Prevention

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

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P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P284 Wear respiratory protection. P272 Contaminated work clothing should not be allowed out of the workplace.

Precautionary statement(s) Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P310 Immediately call a POISON CENTER or doctor/physician. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P362 Take off contaminated clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention.

Precautionary statement(s) Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Precautionary statement(s) Disposal

P501 Dispose of contents/container in accordance with local regulations.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances See section below for composition of Mixtures

Mixtures

CAS No %[weight] Name 25322-69-4 10-30 polypropylene glycol 5124-30-1 10-30 methylene bis(4-cyclohexylisocyanate) 25190-06-1 10-30 tetrahydrofuran homopolymer Not Available 10-30 polyurethane prepolymer 78-93-3 5-10 methyl ethyl ketone

SECTION 4 FIRST AID MEASURES

Description of first aid measures

If this product comes in contact with the eyes: Wash out immediately with fresh running water. Eye Contact Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin contact occurs: Immediately remove all contaminated clothing, including footwear. Skin Contact Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if Inhalation necessary. Transport to hospital, or doctor, without delay. Following uptake by inhalation, move person to an area free from risk of further exposure. Oxygen or artificial respiration should be administered as needed. Asthmatic-type symptoms may develop and may be immediate or delayed up to several hours. Treatment is essentially symptomatic. A physician should be consulted. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Ingestion Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice.

Indication of any immediate medical attention and special treatment needed For sub-chronic and chronic exposures to isocyanates: This material may be a potent pulmonary sensitiser which causes bronchospasm even in patients without prior airway hyperreactivity. Clinical symptoms of exposure involve mucosal irritation of respiratory and gastrointestinal tracts. Conjunctival irritation, skin inflammation (erythema, pain vesiculation) and gastrointestinal disturbances occur soon after exposure.

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Pulmonary symptoms include cough, burning, substernal pain and dyspnoea. Some cross-sensitivity occurs between different isocyanates. Noncardiogenic pulmonary oedema and bronchospasm are the most serious consequences of exposure. Markedly symptomatic patients should receive oxygen, ventilatory support and an intravenous line. Treatment for asthma includes inhaled sympathomimetics (epinephrine [adrenalin], terbutaline) and steroids. Activated charcoal (1 g/kg) and a cathartic (sorbitol, magnesium citrate) may be useful for ingestion. Mydriatics, systemic analgesics and topical antibiotics (Sulamyd) may be used for corneal abrasions. There is no effective therapy for sensitised workers. [Ellenhorn and Barceloux; Medical Toxicology] NOTE: Isocyanates cause airway restriction in naive individuals with the degree of response dependant on the concentration and duration of exposure. They induce smooth muscle contraction which leads to bronchoconstrictive episodes. Acute changes in lung function, such as decreased FEV1, may not represent sensitivity. [Karol & Jin, Frontiers in Molecular Toxicology, pp 56-61, 1992] Personnel who work with isocyanates, isocyanate prepolymers or polyisocyanates should have a pre-placement medical examination and periodic examinations thereafter, including a pulmonary function test. Anyone with a medical history of chronic respiratory disease, asthmatic or bronchial attacks, indications of allergic responses, recurrent eczema or sensitisation conditions of the skin should not handle or work with isocyanates. Anyone who develops chronic respiratory distress when working with isocyanates should be removed from exposure and examined by a physician. Further exposure must be avoided if a sensitivity to isocyanates or polyisocyanates has developed.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media Foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide. Water spray or fog - Large fires only.

Special hazards arising from the substrate or mixture

Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. Use water delivered as a fine spray to control fire and cool adjacent area. Fire Fighting Avoid spraying water onto liquid pools. Do not approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. Combustible. Moderate fire hazard when exposed to heat or flame. When heated to high temperatures decomposes rapidly generating vapour which pressures and may then rupture containers with release of flammable and highly toxic isocyanate vapour. Fire/Explosion Hazard Burns with acrid black smoke and poisonous fumes. Combustion yields traces of highly toxic hydrogen cyanide HCN, plus toxic nitrogen oxides NOx and carbon monoxide. Combustion products include:, carbon dioxide (CO2), isocyanates, and minor amounts of, hydrogen cyanide, nitrogen oxides (NOx), other pyrolysis products typical of burning organic material May emit corrosive fumes.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Remove all ignition sources. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Minor Spills Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up. Place in a suitable, labelled container for waste disposal. Liquid Isocyanates and high isocyanate vapour concentrations will penetrate seals on self contained breathing apparatus - SCBA should be used inside encapsulating suit where this exposure may occur. For isocyanate spills of less than 40 litres (2 m2): Evacuate area from everybody not dealing with the emergency, keep them upwind and prevent further access, remove ignition sources and, if inside building, ventilate area as well as possible. Notify supervision and others as necessary. Put on personal protective equipment (suitable respiratory protection, face and eye protection, protective suit, gloves and impermeable boots). Control source of leakage (where applicable). Dike the spill to prevent spreading and to contain additions of decontaminating solution. Prevent the material from entering drains. Estimate spill pool volume or area. Absorb and decontaminate. - Completely cover the spill with wet sand, wet earth, vermiculite or other similar absorbent. - Add neutraliser (for suitable Major Spills formulations: see below) to the adsorbent materials (equal to that of estimated spill pool volume). Intensify contact between spill, absorbent and neutraliser by carefully mixing with a rake and allow to react for 15 minutes Shovel absorbent/decontaminant solution mixture into a steel drum. Decontaminate surface. - Pour an equal amount of neutraliser solution over contaminated surface. - Scrub area with a stiff bristle brush, using moderate pressure. - Completely cover decontaminant with vermiculite or other similar absorbent. - After 5 minutes, shovel absorbent/decontamination solution mixture into the same steel drum used above. Monitor for residual isocyanate. If surface is decontaminated, proceed to next step. If contamination persists, repeat decontaminate procedure immediately above Place loosely covered drum (release of carbon dioxide) outside for at least 72 hours. Label waste-containing drum appropriately. Remove waste materials for incineration. Decontaminate and remove personal protective equipment. Return to normal operation.

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Conduct accident investigation and consider measures to prevent reoccurrence.

Decontamination: Treat isocyanate spills with sufficient amounts of isocyanate decontaminant preparation ("neutralising fluid"). Isocyanates and polyisocyanates are generally not miscible with water. Liquid surfactants are necessary to allow better dispersion of isocyanate and neutralising fluids/ preparations. Alkaline neutralisers react faster than water/surfactant mixtures alone. Typically, such a preparation may consist of: Sawdust: 20 parts by weight Kieselguhr 40 parts by weight plus a mixture of {ammonia (s.g. 0.880) 8% v/v non-ionic surfactant 2% v/v water 90% v/v}. Let stand for 24 hours Three commonly used neutralising fluids each exhibit advantages in different situations. Formulation A : liquid surfactant 0.2-2% sodium carbonate 5-10% water to 100% Formulation B liquid surfactant 0.2-2% concentrated ammonia 3-8% water to 100% Formulation C ethanol, isopropanol or butanol 50% concentrated ammonia 5% water to 100%

After application of any of these formulae, let stand for 24 hours.

Formulation B reacts faster than Formulation A. However, ammonia-based neutralisers should be used only under well-ventilated conditions to avoid overexposure to ammonia or if members of the emergency team wear suitable respiratory protection. Formulation C is especially suitable for cleaning of equipment from unreacted isocyanate and neutralizing under freezing conditions. Regard has to be taken to the flammability of the alcoholic solution. Avoid contamination with water, alkalies and detergent solutions. Material reacts with water and generates gas, pressurises containers with even drum rupture resulting. DO NOT reseal container if contamination is suspected. Open all containers with care. Moderate hazard. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. No smoking, naked lights or ignition sources. Increase ventilation. Stop leak if safe to do so. Contain spill with sand, earth or vermiculite. Collect recoverable product into labelled containers for recycling. Absorb remaining product with sand, earth or vermiculite. Collect solid residues and seal in labelled drums for disposal. Wash area and prevent runoff into drains. If contamination of drains or waterways occurs, advise emergency services.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

DO NOT allow clothing wet with material to stay in contact with skin Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. Avoid smoking, naked lights or ignition sources. Avoid contact with incompatible materials. Safe handling When handling, DO NOT eat, drink or smoke. Keep containers securely sealed when not in use. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions. Store in original containers. Keep containers securely sealed. No smoking, naked lights or ignition sources. Other information Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers. Protect containers against physical damage and check regularly for leaks. Observe manufacturer's storage and handling recommendations contained within this SDS.

Conditions for safe storage, including any incompatibilities

Metal can or drum Suitable container Packaging as recommended by manufacturer. Check all containers are clearly labelled and free from leaks. Avoid reaction with water, alcohols and detergent solutions. Isocyanates and thioisocyanates are incompatible with many classes of compounds, reacting exothermically to release toxic gases. Reactions with amines, Storage incompatibility strong bases, aldehydes, alcohols, alkali metals, ketones, mercaptans, strong oxidisers, hydrides, phenols, and peroxides can cause vigorous releases of heat. Acids and bases initiate polymerisation reactions in these materials.

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Isocyanates easily form adducts with carbodiimides, isothiocyanates, ketenes, or with substrates containing activated CC or CN bonds. Some isocyanates react with water to form amines and liberate carbon dioxide. This reaction may also generate large volumes of foam and heat. Foaming in confined spaces may produce pressure in confined spaces or containers. Gas generation may pressurise drums to the point of rupture. Do NOT reseal container if contamination is expected Open all containers with care Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence, Isocyanates will attack and embrittle some plastics and rubbers. Keep dry NOTE: May develop pressure in containers; open carefully. Vent periodically.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA Source Ingredient Material name TWA STEL Peak Notes methylene bis(4- Methylene bis(4-cyclo- Not Not Australia Exposure Standards Not Available Not Available cyclohexylisocyanate) hexylisocyanate) Available Available 445 mg/m3 / 150 890 mg/m3 / 300 Not Not Australia Exposure Standards methyl ethyl ketone Methyl ethyl ketone (MEK) ppm ppm Available Available

EMERGENCY LIMITS Ingredient Material name TEEL-1 TEEL-2 TEEL-3 polypropylene glycol Polypropylene glycols 30 mg/m3 80 mg/m3 480 mg/m3 methylene bis(4- Methylene bis(4-isocyanatocyclohexane), 1,1'- 0.005 ppm 0.01 ppm 0.13 ppm cyclohexylisocyanate) methyl ethyl ketone Butanone, 2-; (Methyl ethyl ketone; MEK) Not Available Not Available Not Available

Ingredient Original IDLH Revised IDLH polypropylene glycol Not Available Not Available methylene bis(4- Not Available Not Available cyclohexylisocyanate) tetrahydrofuran homopolymer Not Available Not Available polyurethane prepolymer Not Available Not Available methyl ethyl ketone 3,000 ppm 3,000 [Unch] ppm

Exposure controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use. Employers may need to use multiple types of controls to prevent employee overexposure. Spraying of material or material in admixture with other components must be carried out in conditions conforming to local state regulations (AS/NZS 4114, UNI EN 12215:2010, ANSI/AIHA Z9.3–2007 or national equivalent). Local exhaust ventilation with full face positive-pressure air supplied breathing apparatus (hood or helmet type) is required. Spraying should be performed in a spray booth fitted with an effective exhaust system which complies with local environmental legislation. The spray booth area must be isolated from unprotected personnel whilst spraying is in progress and until all spraying mist has cleared. NOTE: Isocyanate vapours will not be adequately absorbed by organic vapour respirators. Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to effectively remove the contaminant.

Type of Contaminant: Air Speed: Appropriate engineering direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active generation into 1-2.5 m/s (200-500 controls zone of rapid air motion) f/min.)

Within each range the appropriate value depends on:

Lower end of the range Upper end of the range 1: Room air currents minimal or favourable to capture 1: Disturbing room air currents 2: Contaminants of low toxicity or of nuisance value only 2: Contaminants of high toxicity 3: Intermittent, low production. 3: High production, heavy use 4: Large hood or large air mass in motion 4: Small hood-local control only

Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreases with the square of distance from the extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of 4-10 m/s (800-2000 f/min.) for extraction of solvents generated by spraying at a point 2 meters distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are installed or used. Refer also to protective measures for the other component used with the product. Read both SDS before using; store and attach SDS together.

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Personal protection

Safety glasses with side shields. Chemical goggles. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of Eye and face protection chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent] Skin protection See Hand protection below NOTE: The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective equipment, to avoid all possible skin contact. Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed. The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has to be observed when making a final choice. Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: frequency and duration of contact, chemical resistance of glove material, glove thickness and Hands/feet protection dexterity Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent). When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended. When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended. Some glove polymer types are less affected by movement and this should be taken into account when considering gloves for long-term use. Contaminated gloves should be replaced. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended. Isocyanate resistant materials include Teflon, Viton, nitrile rubber and some PVA gloves. Protective gloves and overalls should be worn as specified in the appropriate national standard. Contaminated garments should be removed promptly and should not be re-used until they have been decontaminated. NOTE: Natural rubber, neoprene, PVC can be affected by isocyanates Body protection See Other protection below Overalls. P.V.C. apron. Other protection Barrier cream. Skin cleansing cream. Eye wash unit. Thermal hazards Not Available

Respiratory protection Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Clear liquid with a faint odour; reacts with water.

Physical state Liquid Relative density (Water = 1) 1.03 Partition coefficient Odour Not Available Not Available n-octanol / water Auto-ignition temperature Odour threshold Not Available Not Available (°C) Decomposition pH (as supplied) Not Available Not Available temperature Melting point / freezing Not Available Viscosity (cSt) Not Available point (°C) Initial boiling point and >148.8 Molecular weight (g/mol) Not Applicable boiling range (°C) Flash point (°C) >204.4 (TCC) Taste Not Available Evaporation rate Not Available Explosive properties Not Available Flammability Not Applicable Oxidising properties Not Available Surface Tension (dyn/cm or Upper Explosive Limit (%) Not Available Not Available mN/m) Lower Explosive Limit (%) Not Available Volatile Component (%vol) VOC 0 g/L Vapour pressure (kPa) Not Available Gas group Not Available

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Solubility in water (g/L) Reacts pH as a solution (1%) 7.0 (5% solution) Vapour density (Air = 1) Not Available VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7 Unstable in the presence of incompatible materials. Chemical stability Product is considered stable. Hazardous polymerisation will not occur. Possibility of hazardous See section 7 reactions Conditions to avoid See section 7 Incompatible materials See section 7 Hazardous decomposition See section 5 products

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

The vapour/mist may be highly irritating to the upper respiratory tract and lungs; the response may be severe enough to produce bronchitis and pulmonary oedema. Possible neurological symptoms arising from isocyanate exposure include headache, insomnia, euphoria, ataxia, anxiety neurosis, depression and paranoia. Gastrointestinal disturbances are characterised by nausea and vomiting. Pulmonary sensitisation may produce asthmatic reactions ranging from Inhaled minor breathing difficulties to severe allergic attacks; this may occur following a single acute exposure or may develop without warning for several hours after exposure. Sensitized people can react to very low doses, and should not be allowed to work in situations allowing exposure to this material. Continued exposure of sensitised persons may lead to possible long term respiratory impairment. Inhalation hazard is increased at higher temperatures. Accidental ingestion of the material may be damaging to the health of the individual. Ingestion Adverse effects associated with the administration of central nervous system stimulants include labored breathing, coughing, narrowed airways, chest tightness, and throat spasm. Muscular involvement may produce contraction of small localised muscle fibres (visible through the skin) or seizures. The material may cause moderate inflammation of the skin either following direct contact or after a delay of some time. Repeated exposure can cause contact dermatitis which is characterised by redness, swelling and blistering. Skin Contact Open cuts, abraded or irritated skin should not be exposed to this material Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected. Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial number of individuals. Prolonged eye contact may Eye cause inflammation characterised by a temporary redness of the conjunctiva (similar to windburn). Irritation of the eyes may produce a heavy secretion of tears (lachrymation). Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and related systemic problems. Inhaling this product is more likely to cause a sensitisation reaction in some persons compared to the general population. Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population. Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure. Chronic Persons with a history of asthma or other respiratory problems or are known to be sensitised, should not be engaged in any work involving the handling of isocyanates. [CCTRADE-Bayer, APMF] Isocyanate vapours are irritating to the airways and can cause their inflammation, with wheezing, gasping, severe distress, even loss of consciousness and fluid in the lungs. Nervous system symptoms that may occur include headache, sleep disturbance, euphoria, inco-ordination, anxiety, depression and paranoia. Sensitisation may give severe responses to very low levels of exposure, i.e. hypersensitivity.

TOXICITY IRRITATION DEVCON R-Flex Resin Not Available Not Available

TOXICITY IRRITATION

Dermal (rabbit) LD50: >20000 mg/kg[2] Skin (rabbit): 500 mg mild polypropylene glycol Inhalation (rat) LC50: >0.17 mg/l1 h[1]

Oral (rat) LD50: >2000 mg/kg[1]

TOXICITY IRRITATION

dermal (rat) LD50: >7000 mg/kg[1] *[Bayer] methylene bis(4- Inhalation (rat) LC50: 0.295 mg/L/4h *[2] Eye (rabbit): slight irritant* cyclohexylisocyanate) Inhalation (rat) LC50: 0.307 mg/L/4h *[2] Skin (guinea pig): sensitiser*

Oral (rat) LD50: 18020 mg/kg[1]

tetrahydrofuran TOXICITY IRRITATION homopolymer Not Available Not Available

TOXICITY IRRITATION

Dermal (rabbit) LD50: >8100 mg/kg[1] - mild methyl ethyl ketone Inhalation (rat) LC50: 23.5 mg/L/8H[2] Eye (human): 350 ppm -irritant

Inhalation (rat) LC50: 50.1 mg/L/8 hr[2] Eye (rabbit): 80 mg - irritant

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Oral (rat) LD50: 3474.9 mg/kg[1] Skin (rabbit): 402 mg/24 hr - mild Skin (rabbit):13.78mg/24 hr open

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, POLYPROPYLENE GLYCOL scaling and thickening of the skin. ** Rohm and Haas Paraplex WP-1 MSDS The following information refers to contact allergens as a group and may not be specific to this product. Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g. contact urticaria, involve antibody-mediated immune reactions. The significance of the contact allergen is not simply determined by its sensitisation potential: the distribution of the substance and the opportunities for contact with it are equally important. A weakly sensitising substance which is widely distributed can be a more important allergen than one with stronger sensitising potential with which few individuals come into contact. From a clinical point of view, substances are noteworthy if they produce an allergic test reaction in more than 1% of the persons tested.

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an infrequent disorder with rates related to the concentration of and duration of exposure to METHYLENE BIS(4- the irritating substance. Industrial bronchitis, on the other hand, is a disorder that occurs as result of exposure due to high concentrations of irritating CYCLOHEXYLISOCYANATE) substance (often particulate in nature) and is completely reversible after exposure ceases. The disorder is characterised by dyspnea, cough and mucus production. Allergic reactions involving the respiratory tract are usually due to interactions between IgE antibodies and allergens and occur rapidly. Allergic potential of the allergen and period of exposure often determine the severity of symptoms. Some people may be genetically more prone than others, and exposure to other irritants may aggravate symptoms. Allergy causing activity is due to interactions with proteins. Attention should be paid to atopic diathesis, characterised by increased susceptibility to nasal inflammation, asthma and eczema. Exogenous allergic alveolitis is induced essentially by allergen specific immune-complexes of the IgG type; cell-mediated reactions (T lymphocytes) may be involved. Such allergy is of the delayed type with onset up to four hours following exposure. Isocyanate vapours are irritating to the airways and can cause their inflammation, with wheezing, gasping, severe distress, even loss of consciousness and fluid in the lungs. Nervous system symptoms that may occur include headache, sleep disturbance, euphoria, inco-ordination, anxiety, depression and paranoia. The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. Aromatic and aliphatic diisocyanates may cause airway toxicity and skin sensitization. Monomers and prepolymers exhibit similar respiratory effect. Of the several members of diisocyanates tested on experimental animals by inhalation and oral exposure, some caused cancer while others produced a harmless outcome. This group of compounds has therefore been classified as cancer-causing. Inhalation (Rat, adult female) LC50: 307 mg/m3/4h * Inhalation (Rat, adult male) LC50: 295 mg/m3/4h * * Vendor MSDS

Acute Toxicity Carcinogenicity Skin Irritation/Corrosion Reproductivity Serious Eye STOT - Single Exposure Damage/Irritation Respiratory or Skin STOT - Repeated Exposure sensitisation Mutagenicity Aspiration Hazard Legend: – Data available but does not fill the criteria for classification – Data required to make classification available – Data Not Available to make classification

SECTION 12 ECOLOGICAL INFORMATION

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Toxicity

Ingredient Endpoint Test Duration (hr) Species Value Source polypropylene glycol LC50 96 Fish >100mg/L 2 polypropylene glycol EC50 48 Crustacea >100mg/L 2 polypropylene glycol NOEC 504 Crustacea >=10mg/L 2 polypropylene glycol EC50 72 Algae or other aquatic plants >100mg/L 2 methylene bis(4- LC50 96 Fish 0.69mg/L 1 cyclohexylisocyanate) methylene bis(4- EC50 72 Algae or other aquatic plants >5mg/L 2 cyclohexylisocyanate) methylene bis(4- NOEC 72 Algae or other aquatic plants 0.31mg/L 2 cyclohexylisocyanate) tetrahydrofuran EC50 384 Crustacea 145.625mg/L 3 homopolymer tetrahydrofuran EC50 96 Algae or other aquatic plants 4126.070mg/L 3 homopolymer tetrahydrofuran LC50 96 Fish 638.905mg/L 3 homopolymer methyl ethyl ketone EC50 384 Crustacea 52.575mg/L 3 methyl ethyl ketone LC50 96 Fish 228.130mg/L 3 methyl ethyl ketone EC50 96 Algae or other aquatic plants >500mg/L 4 methyl ethyl ketone EC50 48 Crustacea 308mg/L 2 methyl ethyl ketone NOEC 48 Crustacea 68mg/L 2 Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 - Legend: Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

for methylene bis(4-cyclohexylisocyanate): Fish toxicity: Acute (Brachydanio rerio) LC0: 0.69 mg/l/96h* Acute (Brachydanio rerio) LC50: 1.20 mg/l/96h* Acute (Brachydanio rerio) LC100: 2.76 mg/l96h* Bacterial toxicity: Acute EC50: 19mg/L* - The product reacts with water at the interface forming CO2 and a solid insoluble product with high melting point (polyurea). This reaction is accelerated by surfactants (eg. detergents) or by water soluble solvents.* *[Bayer] Persistence: does not meet the P criterion for aquatic environment due to a fast hydrolysis. The expected hydrolysis product under environmental conditions is 4,4�-diaminodicyclohexylmethane (CAS 1761-71-3). This substance is not considered inherently biodegradable and it is therefore considered fulfilling the screening P/vP criteria. Bioaccumulation: The substance fulfils due to the high logKow (6.11) the screening B criterion but no further testing is necessary due to the overall conclusion and due to the fast hydrolysis of the substance. For the environmentally relevant hydrolysis product 4,4�-diaminodicyclohexylmethane log Kow �values of 2.03 and 3.26 are available. It is concluded, that the hydrolysis product does not fulfill the screening B criterion. This substance fulfils the P/vP criteria based on screening data, but it does not fulfill the screening B criterion.

DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air methylene bis(4- HIGH HIGH cyclohexylisocyanate) tetrahydrofuran homopolymer LOW LOW methyl ethyl ketone LOW (Half-life = 14 days) LOW (Half-life = 26.75 days)

Bioaccumulative potential

Ingredient Bioaccumulation methylene bis(4- HIGH (LogKOW = 6.1145) cyclohexylisocyanate) tetrahydrofuran homopolymer LOW (LogKOW = -0.2174) methyl ethyl ketone LOW (LogKOW = 0.29)

Mobility in soil

Ingredient Mobility methylene bis(4- LOW (KOC = 376200) cyclohexylisocyanate) tetrahydrofuran homopolymer HIGH (KOC = 1) methyl ethyl ketone MEDIUM (KOC = 3.827)

SECTION 13 DISPOSAL CONSIDERATIONS

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Waste treatment methods

Recycle wherever possible or consult manufacturer for recycling options. Consult State Land Waste Management Authority for disposal. Product / Packaging Material may be disposed of by controlled burning in an approved incinerator or buried in an approved landfill. disposal Prior to disposal in a landfill the material should be mixed with the other component and reacted to render the material inert. Extreme caution should be taken when heating the resin/curing agent mix. Recycle containers where possible, or dispose of in an authorised landfill.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant NO HAZCHEM 2X

Land transport (ADG)

UN number 2810 Packing group III UN proper shipping name TOXIC LIQUID, ORGANIC, N.O.S. (see 3.2.5 for relevant [AUST.] entries) (contains methylene bis(4-cyclohexylisocyanate)) Environmental hazard Not Applicable

Class 6.1 Transport hazard class(es) Subrisk Not Applicable

Special provisions 223 274 Special precautions for user Limited quantity 5 L

Air transport (ICAO-IATA / DGR)

UN number 2810 Packing group III UN proper shipping name Toxic liquid, organic, n.o.s. * (contains methylene bis(4-cyclohexylisocyanate)) Environmental hazard Not Applicable

ICAO/IATA Class 6.1 Transport hazard class(es) ICAO / IATA Subrisk Not Applicable ERG Code 6L

Special provisions A3A4A137 Cargo Only Packing Instructions 663 Cargo Only Maximum Qty / Pack 220 L Special precautions for user Passenger and Cargo Packing Instructions 655 Passenger and Cargo Maximum Qty / Pack 60 L Passenger and Cargo Limited Quantity Packing Instructions Y642 Passenger and Cargo Limited Maximum Qty / Pack 2 L

Sea transport (IMDG-Code / GGVSee)

UN number 2810 Packing group III UN proper shipping name TOXIC LIQUID, ORGANIC, N.O.S. (contains methylene bis(4-cyclohexylisocyanate)) Environmental hazard Not Applicable

IMDG Class 6.1 Transport hazard class(es) IMDG Subrisk Not Applicable

EMS Number F-A, S-A Special precautions for user Special provisions 223 274 Limited Quantities 5 L

Transport in bulk according to Annex II of MARPOL and the IBC code

Source Ingredient Pollution Category

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IMO MARPOL (Annex II) - List of Noxious Liquid Substances polypropylene glycol Z Carried in Bulk IMO MARPOL (Annex II) - List of Noxious Liquid Substances methyl ethyl ketone Z Carried in Bulk

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

POLYPROPYLENE GLYCOL(25322-69-4) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Inventory of Chemical Substances (AICS)

METHYLENE BIS(4-CYCLOHEXYLISOCYANATE)(5124-30-1) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Exposure Standards Australia Inventory of Chemical Substances (AICS) Australia Hazardous Substances Information System - Consolidated Lists

TETRAHYDROFURAN HOMOPOLYMER(25190-06-1) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Inventory of Chemical Substances (AICS)

METHYL ETHYL KETONE(78-93-3) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Exposure Standards Australia Inventory of Chemical Substances (AICS) Australia Hazardous Substances Information System - Consolidated Lists

National Inventory Status Australia - AICS Y Canada - DSL Y Canada - NDSL N (polypropylene glycol; tetrahydrofuran homopolymer; methyl ethyl ketone) China - IECSC Y Europe - EINEC / ELINCS / N (tetrahydrofuran homopolymer) NLP Japan - ENCS Y Korea - KECI Y New Zealand - NZIoC Y Philippines - PICCS Y USA - TSCA Y Y = All ingredients are on the inventory Legend: N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)

SECTION 16 OTHER INFORMATION

Other information

Ingredients with multiple cas numbers

Name CAS No polypropylene glycol 25322-69-4, 29434-03-5 methylene bis(4- 103072-21-5, 107314-16-9, 123773-48-8, 135822-12-7, 13622-90-7, 190601-97-9, 201536-77-8, 5124-30-1, 68966-63-2, 73156-15-7, 88504-76-1 cyclohexylisocyanate) tetrahydrofuran homopolymer 24979-97-3, 25190-06-1

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. A list of reference resources used to assist the committee may be found at: www.chemwatch.net

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

end of SDS DEVCON R-Flex Surface Conditioner ITW POLYMERS AND FLUIDS Chemwatch: 5147-14 Issue Date: 21/07/2014 Version No: 2.1.1.1 Print Date: 24/07/2014 Safety Data Sheet according to WHS and ADG requirements Initial Date: Not Available S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier

Product name DEVCON R-Flex Surface Conditioner Chemical Name ACETONE Proper shipping name ACETONE Chemical formula Not Applicable Other means of identification Not Available CAS number Not Applicable

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses Surface conditioner.

Details of the manufacturer/importer

Registered company name ITW POLYMERS AND FLUIDS 100 Hassall Street Wetherill Park NSW 2164 Address Australia Telephone +61 2 9757 8800 Fax +61 2 9757 3855 Website www.itwpf.com.au Email Not Available

Emergency telephone number

Association / Organisation Not Available Emergency telephone numbers 1800 039 008 Other emergency telephone numbers +61 3 9573 3112

CHEMWATCH EMERGENCY RESPONSE

Primary Number Alternative Number 1 Alternative Number 2 1800 039 008 +612 9186 1132 Not Available

Once connected and if the message is not in your prefered language then please dial 01

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.

Poisons Schedule S5

GHS Classification [1] Flammable Liquid Category 2, Eye Irrit. 2, STOT - SE (Narcosis) Category 3 Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI

Label elements

GHS label elements

SIGNAL WORD DANGER

Hazard statement(s)

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H225 Highly flammable liquid and vapour H319 Causes serious eye irritation H336 May cause drowsiness or dizziness AUH066 Repeated exposure may cause skin dryness and cracking

Precautionary statement(s): Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P271 Use only outdoors or in a well-ventilated area. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary statement(s): Response

P370+P378 In case of fire: Use… to extinguish. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell. P337+P313 If eye irritation persists: Get medical advice/attention.

Precautionary statement(s): Storage

P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Precautionary statement(s): Disposal

P501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances See section below for composition of Mixtures Mixtures

CAS No %[weight] Name 67-64-1 60-100 acetone

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Indication of any immediate medical attention and special treatment needed

For acute or short term repeated exposures to acetone: Symptoms of acetone exposure approximate ethanol intoxication. About 20% is expired by the lungs and the rest is metabolised. Alveolar air half-life is about 4 hours following two hour inhalation at levels near the Exposure Standard; in overdose, saturable metabolism and limited clearance, prolong the elimination half-life to 25-30 hours. There are no known antidotes and treatment should involve the usual methods of decontamination followed by supportive care.

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[Ellenhorn and Barceloux: Medical Toxicology] Management: Measurement of serum and urine acetone concentrations may be useful to monitor the severity of ingestion or inhalation. Inhalation Management: Maintain a clear airway, give humidified oxygen and ventilate if necessary. If respiratory irritation occurs, assess respiratory function and, if necessary, perform chest X-rays to check for chemical pneumonitis. Consider the use of steroids to reduce the inflammatory response. Treat pulmonary oedema with PEEP or CPAP ventilation. Dermal Management: Remove any remaining contaminated clothing, place in double sealed, clear bags, label and store in secure area away from patients and staff. Irrigate with copious amounts of water. An emollient may be required. Eye Management: Irrigate thoroughly with running water or saline for 15 minutes. Stain with fluorescein and refer to an ophthalmologist if there is any uptake of the stain. Oral Management: No GASTRIC LAVAGE OR EMETIC Encourage oral fluids. Systemic Management: Monitor blood glucose and arterial pH. Ventilate if respiratory depression occurs. If patient unconscious, monitor renal function. Symptomatic and supportive care. The Chemical Incident Management Handbook: Guy's and St. Thomas' Hospital Trust, 2000 BIOLOGICAL EXPOSURE INDEX These represent the determinants observed in specimens collected from a healthy worker exposed at the Exposure Standard (ES or TLV):

Determinant Sampling Time Index Comments Acetone in urine End of shift 50 mg/L NS

NS: Non-specific determinant; also observed after exposure to other material

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media

Alcohol stable foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide.

Special hazards arising from the substrate or mixture

Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Fire Fighting Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water course. Liquid and vapour are highly flammable. Severe fire hazard when exposed to heat, flame and/or oxidisers. Fire/Explosion Hazard Vapour may travel a considerable distance to source of ignition. Heating may cause expansion or decomposition leading to violent rupture of containers.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Remove all ignition sources. Clean up all spills immediately. Minor Spills Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Major Spills May be violently or explosively reactive. Wear breathing apparatus plus protective gloves.

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling Avoid all personal contact, including inhalation. Continued... Chemwatch: 5147-14 Page 4 of 8 Issue Date: 21/07/2014 Version No: 2.1.1.1 DEVCON R-Flex Surface Conditioner Print Date: 24/07/2014

Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. Store in original containers in approved flame-proof area. No smoking, naked lights, heat or ignition sources. Other information DO NOT store in pits, depressions, basements or areas where vapours may be trapped. Keep containers securely sealed.

Conditions for safe storage, including any incompatibilities

Packing as supplied by manufacturer. Suitable container Plastic containers may only be used if approved for flammable liquid. Check that containers are clearly labelled and free from leaks. Avoid reaction with oxidising agents Acetone: may react violently with chloroform, activated charcoal, aliphatic amines, bromine, bromine trifluoride, chlorotriazine, chromic(IV) acid, chromic(VI) acid, chromium trioxide, chromyl chloride, hexachloromelamine, iodine heptafluoride, iodoform, liquid oxygen, nitrosyl chloride, nitrosyl perchlorate, nitryl perchlorate, perchloromelamine, peroxomonosulfuric acid, platinum, potassium tert-butoxide, strong acids, sulfur dichloride, trichloromelamine, xenon tetrafluoride Storage incompatibility reacts violently with bromoform and chloroform in the presence of alkalies or in contact with alkaline surfaces. may form unstable and explosive peroxides in contact with strong oxidisers, fluorine, hydrogen peroxide (90%), sodium perchlorate, 2-methyl-1,3-butadiene can increase the explosive sensitivity of nitromethane on contact flow or agitation may generate electrostatic charges due to low conductivity dissolves or attacks most rubber, resins, and plastics (polyethylenes, polyester, vinyl ester, PVC, Neoprene, Viton)

PACKAGE MATERIAL INCOMPATIBILITIES Not Available

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA Source Ingredient Material name TWA STEL Peak Notes Australia Exposure Standards acetone Acetone 1185 mg/m3 / 500 ppm 2375 mg/m3 / 1000 ppm Not Available Not Available

EMERGENCY LIMITS Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3 acetone 200 ppm 200 ppm 3200 ppm 5700 ppm

Ingredient Original IDLH Revised IDLH acetone 20,000 ppm 2,500 [LEL] ppm

Exposure controls

Personal protection

Safety glasses with side shields. Chemical goggles. Eye and face protection Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. Skin protection See Hand protection below Wear chemical protective gloves, e.g. PVC. Hands/feet protection Wear safety footwear or safety gumboots, e.g. Rubber Body protection See Other protection below Overalls. PVC Apron. Other protection PVC protective suit may be required if exposure severe. Eyewash unit. Thermal hazards Not Available

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Recommended material(s) Respiratory protection GLOVE SELECTION INDEX Type AX Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Glove selection is based on a modified presentation of the: Z88 or national equivalent) "Forsberg Clothing Performance Index". Where the concentration of gas/particulates in the breathing zone, The effect(s) of the following substance(s) are taken into account in the computer- generated selection: approaches or exceeds the "Exposure Standard" (or ES), respiratory DEVCON R-Flex Surface Conditioner protection is required. Degree of protection varies with both face-piece and Class of filter; Material CPI the nature of protection varies with Type of filter. BUTYL A BUTYL/NEOPRENE A Required Minimum Half-Face Full-Face Powered Air PE/EVAL/PE A Protection Respirator Respirator Respirator PVDC/PE/PVDC A Factor SARANEX-23 2-PLY B up to 5 x ES Air-line* AX-2 AX-PAPR-2 ^ TEFLON B up to 10 x ES - AX-3 - * CPI - Chemwatch Performance Index 10+ x ES - Air-line** - A: Best Selection B: Satisfactory; may degrade after 4 hours continuous immersion * - Continuous Flow; ** - Continuous-flow or positive pressure C: Poor to Dangerous Choice for other than short term immersion NOTE: As a series of factors will influence the actual performance of the glove, a final demand selection must be based on detailed observation. - ^ - Full-face * Where the glove is to be used on a short term, casual or infrequent basis, factors such as A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = "feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen be unsuitable following long-term or frequent use. A qualified practitioner should be consulted. cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Clear to amber, highly volatile, highly flammable liquid with sweet solvent odour; mixes with water.

Physical state Liquid Relative density (Water = 1) 0.887 Odour Not Available Partition coefficient n-octanol / water Not Available Odour threshold Not Available Auto-ignition temperature (°C) 465 pH (as supplied) Not Applicable Decomposition temperature Not Available Melting point / freezing point (°C) Not Available Viscosity (cSt) Not Available Initial boiling point and boiling range 55.5 Molecular weight (g/mol) Not Applicable (°C) Flash point (°C) -20 (TCC) Taste Not Available Evaporation rate <1 Ether = 1 Explosive properties Not Available Flammability Flammable. Oxidising properties Not Available Upper Explosive Limit (%) 12.8 Surface Tension (dyn/cm or mN/m) Not Available Lower Explosive Limit (%) 0.6 Volatile Component (%vol) 97.25 Vapour pressure (kPa) 24 @ 20 C Gas group Not Available Solubility in water (g/L) Miscible pH as a solution(1%) Not Available Vapour density (Air = 1) 2.0 VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7 Product is considered stable under normal handling conditions. Chemical stability Stable under normal storage conditions. Hazardous polymerization will not occur. Possibility of hazardous reactions See section 7 Conditions to avoid See section 7 Incompatible materials See section 7 Hazardous decomposition products See section 5

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

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Systemic effects of acetone inhalation exposure include central nervous system depression, light-headedness, incoherent speech, ataxia, stupor, hypotension, tachycardia, metabolic acidosis, hyperglycaemia and ketosis. Rarely, convulsions and tubular necrosis may be evident. Other Inhaled symptoms of exposure may include restlessness, headache, vomiting, low blood-pressure and rapid and irregular pulse, eye and throat irritation, weakness of the legs and dizziness. Inhalation of high concentrations may produce dryness of the mouth and throat, nausea, uncoordinated movement, loss of coordinated speech, drowsiness and, in severe cases, coma. Accidental ingestion of the material may be damaging to the health of the individual. Ingestion |Large ingestions may produce coma, respiratory depression, and rarely, convulsions. Skin contact with the material may damage the health of the individual; systemic effects may result following absorption. The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of Skin Contact dermatitis is often characterised by skin redness (erythema) and swelling epidermis. Histologically there may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the epidermis. Evidence exists, or practical experience predicts, that the material may cause severe eye irritation in a substantial number of individuals and/or may produce significant ocular lesions which are present twenty-four hours or more after instillation into the eye(s) of experimental animals. Eye Eye contact may cause significant inflammation with pain. Corneal injury may occur; permanent impairment of vision may result unless treatment is prompt and adequate. Repeated or prolonged exposure to irritants may cause inflammation characterised by a temporary redness (similar to windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur. Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or biochemical systems. Chronic Workers exposed to 700 ppm acetone for 3 hours/day for 7-15 years showed inflammation of the respiratory tract, stomach and duodenum, attacks of giddiness and loss of strength. Exposure to acetone may enhance liver toxicity of chlorinated solvents.

TOXICITY IRRITATION DEVCON R-Flex Surface Conditioner Not Available Not Available

TOXICITY IRRITATION

Dermal (rabbit) LD50: 20000 mg/kg Eye (human): 500 ppm - irritant Inhalation (rat) LC50: 50100 mg/m3/8 hr Eye (rabbit): 20mg/24hr -moderate acetone Oral (rat) LD50: 5800 mg/kg Eye (rabbit): 3.95 mg - SEVERE Skin (rabbit): 500 mg/24hr - mild Skin (rabbit):395mg (open) - mild Not Available Not Available

Not available. Refer to individual constituents.

The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of dermatitis is often characterised by skin redness (erythema) and swelling epidermis. Histologically there may be intercellular oedema of the ACETONE spongy layer (spongiosis) and intracellular oedema of the epidermis. for acetone: The acute toxicity of acetone is low.

CMR STATUS Not Applicable

SECTION 12 ECOLOGICAL INFORMATION

Toxicity DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air Not Available Not Available Not Available

Bioaccumulative potential

Ingredient Bioaccumulation Not Available Not Available

Mobility in soil

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Ingredient Mobility Not Available Not Available

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified. Product / Packaging disposal Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or Incineration in a licenced apparatus (after admixture with suitable combustible material). Decontaminate empty containers.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant NO

HAZCHEM •2YE

Land transport (ADG)

UN number 1090 Packing group II UN proper shipping name ACETONE Environmental hazard No relevant data

Class 3 Transport hazard class(es) Subrisk Not Applicable

Special provisions Not Applicable Special precautions for user Limited quantity 1 L

Air transport (ICAO-IATA / DGR)

UN number 1090 Packing group II UN proper shipping name Acetone Environmental hazard No relevant data

ICAO/IATA Class 3 Transport hazard class(es) ICAO / IATA Subrisk Not Applicable ERG Code 3H

Special provisions Not Applicable Cargo Only Packing Instructions 364 Cargo Only Maximum Qty / Pack 60 L Special precautions for user Passenger and Cargo Packing Instructions 353 Passenger and Cargo Maximum Qty / Pack 5 L Passenger and Cargo Limited Quantity Packing Instructions Y341 Passenger and Cargo Limited Maximum Qty / Pack 1 L

Sea transport (IMDG-Code / GGVSee)

UN number 1090 Packing group II UN proper shipping name ACETONE Environmental hazard No relevant data

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IMDG Class 3 Transport hazard class(es) IMDG Subrisk Not Applicable

EMS Number F-E , S-D Special precautions for user Special provisions Not Applicable Limited Quantities 1 L

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard Facilities (And Their Threshold Quantity) Table 2","IOFI Global Reference List of Chemically Defined Substances","Australia Illicit Drug Reagents/Essential Chemicals - Category III","International Maritime Dangerous Goods Requirements (IMDG Code)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","Australia Customs (Prohibited Exports) Regulations 1958 - Schedule 9 Precursor substances - Part 2","United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances - Table II","International Maritime Dangerous Goods Requirements (IMDG Code) - Substance Index","Australia FAISD Handbook - Safety Directions","Australia Crimes (Traffic in Narcotic Drugs and Psychotropic Substances) Act - Schedule 1 - United Nations Convention Against Illicit Traffic In Narcotic Drugs And Psychotropic Substances - Table II","Australia Exposure Standards","Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions","FisherTransport Information","IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances","Australia Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","United Nations Consolidated List of Products Whose Consumption and/or Sale Have Been Banned, Withdrawn, Severely Restricted or Not Approved by Governments","United Nations Recommendations on the Transport of acetone(67-64-1) is found on the Dangerous Goods Model Regulations (English)","OECD List of High Production Volume (HPV) Chemicals","Australia Inventory of Chemical following regulatory lists Substances (AICS)","Joint FAO/WHO Expert Committee on Food Additives (JECFA) - Specifications for Flavourings","OSPAR National List of Candidates for Substitution – Norway","Belgium Federal Public Service Mobility and Transport, Regulations concerning the International Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013 (Dutch)","IMO IBC Code Chapter 18: List of products to which the Code does not apply","Australia National Pollutant Inventory","UNECE - Kiev Protocol on Pollutant Release and Transfer Registers - Annex II","OECD Existing Chemicals Database","Sigma-AldrichTransport Information","Australia High Volume Industrial Chemical List (HVICL)","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Spanish)","Australia Dangerous Goods Code (ADG Code) - Dangerous Goods List","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","FEMA Generally Recognized as Safe (GRAS) Flavoring Substances 23 - Examples of FEMA GRAS Substances with Non-Flavor Functions","GESAMP/EHS Composite List - GESAMP Hazard Profiles","International Air Transport Association (IATA) Dangerous Goods Regulations","Australia Hazardous Substances Information System - Consolidated Lists","International Fragrance Association (IFRA) Survey: Transparency List","IMO IBC Code Chapter 17: Summary of minimum requirements","United Nations List of Precursors and Chemicals Frequently used in the Illicit Manufacture of Narcotic Drugs and Psychotropic Substances Under International Control (Red List) - Table II"

SECTION 16 OTHER INFORMATION

end of SDS DEVCON R-Flex Surface Conditioner Powder Premix ITW POLYMERS AND FLUIDS Chemwatch: 5147-13 Issue Date: 21/07/2014 Version No: 2.1.1.1 Print Date: 24/07/2014 Safety Data Sheet according to WHS and ADG requirements Initial Date: Not Available S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier

Product name DEVCON R-Flex Surface Conditioner Powder Premix Chemical Name Not Applicable Proper shipping name TRICHLOROISOCYANURIC ACID, DRY Chemical formula Not Applicable Other means of identification Not Available CAS number Not Applicable

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses Use according to manufacturer's directions.

Details of the manufacturer/importer

Registered company name ITW POLYMERS AND FLUIDS 100 Hassall Street Wetherill Park NSW 2164 Address Australia Telephone +61 2 9757 8800 Fax +61 2 9757 3855 Website www.itwpf.com.au Email Not Available

Emergency telephone number

Association / Organisation Not Available Emergency telephone numbers 1800 039 008 Other emergency telephone numbers +61 3 9573 3112

CHEMWATCH EMERGENCY RESPONSE

Primary Number Alternative Number 1 Alternative Number 2 1800 039 008 +612 9186 1132 Not Available

Once connected and if the message is not in your prefered language then please dial 01

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.

Poisons Schedule S6 Oxidizing Solid Category 3, Acute Toxicity (Oral) Category 4, Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 2, Eye GHS Classification [1] Irrit. 2, STOT - SE (Resp. Irr.) Category 3, Chronic Aquatic Hazard Category 1, Hazardous to the Ozone Layer Category 1 Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI

Label elements

GHS label elements

SIGNAL WORD WARNING

Hazard statement(s)

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H272 May intensify fire; oxidizer H302 Harmful if swallowed H332 Harmful if inhaled H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation H410 Very toxic to aquatic life with long lasting effects H420 Harms public health and the environment by destroying ozone in the upper atmosphere AUH031 Contact with acid liberates toxic gas

Precautionary statement(s): Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P221 Take any precaution to avoid mixing with combustibles/organic material P271 Use only outdoors or in a well-ventilated area. P220 Keep/Store away from clothing/organic material/combustible materials.

Precautionary statement(s): Response

P321 Specific treatment (see advice on this label). P370+P378 In case of fire: Use… to extinguish. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention.

Precautionary statement(s): Storage

P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Precautionary statement(s): Disposal

P501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration P502 Refer to manufacturer/supplier for information on recovery/recycling

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances See section below for composition of Mixtures Mixtures

CAS No %[weight] Name 87-90-1 >60 N',N',N'- trichloroisocyanuric acid Not Available 10-30 ingredients determined not to be hazardous NotSpec. Decomposes in water and produces toxic fumes of 7782-50-5 >2 chlorine

SECTION 4 FIRST AID MEASURES

Description of first aid measures

If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper Eye Contact and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin contact occurs: Immediately remove all contaminated clothing, including footwear. Skin Contact Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Inhalation Transport to hospital, or doctor, without delay. Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema. Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs). As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semi-recumbent posture) and must be kept under medical observation even if no symptoms are (yet) manifested.

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Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivative may be considered. This must definitely be left to a doctor or person authorised by him/her. (ICSC13719) If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Ingestion Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice.

Indication of any immediate medical attention and special treatment needed

Excellent warning properties force rapid escape of personnel from chlorine vapour thus most inhalations are mild to moderate. If escape is not possible, exposure to high concentrations for a very short time can result in dyspnea, haemophysis and cyanosis with later complications being tracheobroncho-pneumonitis and pulmonary oedema. Oxygen, intermittent positive pressure breathing apparatus and aerosolysed bronchodilators are of therapeutic value where chlorine inhalation has been light to moderate. Severe inhalation should result in hospitalisation and treatment for a respiratory emergency. Any chlorine inhalation in an individual with compromised pulmonary function (COPD) should be regarded as a severe inhalation and a respiratory emergency. [CCINFO, Dow 1988] Effects from exposure to chlorine gas include pulmonary oedema which may be delayed. Observation in hospital for 48 hours is recommended Diagnosed asthmatics and those people suffering from certain types of chronic bronchitis should receive medical approval before being employed in occupations involving chlorine exposure. If burn is present, treat as any thermal burn, after decontamination. Depending on the degree of exposure, periodic medical examination is indicated. The symptoms of lung oedema often do not manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation is therefore essential. Immediate administration of an appropriate spray, by a doctor or a person authorised by him/her should be considered. (ICSC24419/24421

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media

FOR SMALL FIRE: USE FLOODING QUANTITIES OF WATER. DO NOT use dry chemical, CO2, foam or halogenated-type extinguishers. FOR LARGE FIRE Flood fire area with water from a protected position

Special hazards arising from the substrate or mixture

Avoid storage with reducing agents. Fire Incompatibility Avoid any contamination of this material as it is very reactive and any contamination is potentially hazardous

Advice for firefighters

Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Fire Fighting Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water courses. Will not burn but increases intensity of fire. Heating may cause expansion or decomposition leading to violent rupture of containers. Fire/Explosion Hazard Heat affected containers remain hazardous. Contact with combustibles such as wood, paper, oil or finely divided metal may produce spontaneous combustion or violent decomposition.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Environmental hazard - contain spillage. Clean up all spills immediately. Minor Spills No smoking, naked lights, ignition sources. Avoid all contact with any organic matter including fuel, solvents, sawdust, paper or cloth and other incompatible materials, as ignition may result. Environmental hazard - contain spillage. Clear area of personnel and move upwind. Major Spills Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive.

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Avoid personal contact and inhalation of dust, mist or vapours. Safe handling Provide adequate ventilation. Always wear protective equipment and wash off any spillage from clothing.

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Keep material away from light, heat, flammables or combustibles. Store in original containers. Keep containers securely sealed as supplied. Other information Store in a cool, well ventilated area. Keep dry.

Conditions for safe storage, including any incompatibilities

DO NOT repack. Use containers supplied by manufacturer only. For low viscosity materials Suitable container Drums and jerricans must be of the non-removable head type. Where a can is to be used as an inner package, the can must have a screwed enclosure. Contact with acids produces toxic fumes Trichloroisocyanuric acid: is a powerful oxidiser and reacts violently with reducing agents reacts with acrolein, antimony trisulfide, antimony tritelluride, arsenic pentasulfide, calcium hypochlorite and other bleaching agents, 1,1-dichloro-1-nitroethane, 1,3-dichloropropene, diethylamine, mineral oils and other combustible substance, s-trioxane is incompatible with m-bis(trichloromethyl)benzene reacts with nitrogen-containing compounds such as ammonia, amines, urea, forming the unstable explosive nitrogen trichloride Storage incompatibility may ignite combustible materials on contact

NOTE: If mixed with a small amount of water, the concentrated solution (with pH around 2) may explode, owning to the evolution of nitrogen trichloride. It is thought that hydrolysis leads to the formation of hypochlorous acid and dichloro-s-triazinetrione, and the protonated acid then attacks the C=N bonds in the triazine ring lading to the formation of chloramine and nitrogen trichloride. The dichloro compound is stable to acid in the absence of hypochlorous acid Avoid any contamination of this material as it is very reactive and any contamination is potentially hazardous

PACKAGE MATERIAL INCOMPATIBILITIES Not Available

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA Source Ingredient Material name TWA STEL Peak Notes Australia Exposure Standards chlorine Chlorine Not Available Not Available 3 mg/m3 / 1 ppm Not Available

EMERGENCY LIMITS Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3 chlorine 0.5 ppm 0.5 ppm 2 ppm 20 ppm

Ingredient Original IDLH Revised IDLH N',N',N'- trichloroisocyanuric acid Not Available Not Available ingredients determined not to be hazardous Not Available Not Available chlorine 30 ppm 10 ppm

Exposure controls

Use in a well-ventilated area Appropriate engineering controls General exhaust is adequate under normal operating conditions.

Personal protection

Chemical goggles. Full face shield may be required for supplementary but never for primary protection of eyes. Eye and face protection Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. Skin protection See Hand protection below Wear chemical protective gloves, e.g. PVC. Wear safety footwear or safety gumboots, e.g. Rubber The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to Hands/feet protection manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has to be observed when making a final choice. Body protection See Other protection below

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Overalls. PVC Apron. Other protection PVC protective suit may be required if exposure severe. Eyewash unit. Thermal hazards Not Available

Recommended material(s) Respiratory protection GLOVE SELECTION INDEX Type AB-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Glove selection is based on a modified presentation of the: Z88 or national equivalent) "Forsberg Clothing Performance Index". Where the concentration of gas/particulates in the breathing zone, The effect(s) of the following substance(s) are taken into account in the computer- generated selection: approaches or exceeds the "Exposure Standard" (or ES), respiratory DEVCON R-Flex Surface Conditioner Powder Premix Not Available protection is required. Degree of protection varies with both face-piece and Class of filter; Material CPI the nature of protection varies with Type of filter. * CPI - Chemwatch Performance Index A: Best Selection Required B: Satisfactory; may degrade after 4 hours continuous immersion Minimum Half-Face Full-Face Powered Air C: Poor to Dangerous Choice for other than short term immersion Protection Respirator Respirator Respirator NOTE: As a series of factors will influence the actual performance of the glove, a final Factor selection must be based on detailed observation. - AB-PAPR-AUS / * Where the glove is to be used on a short term, casual or infrequent basis, factors such as up to 10 x ES AB-AUS P2 - "feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise Class 1 P2 be unsuitable following long-term or frequent use. A qualified practitioner should be consulted. AB-AUS / up to 50 x ES - - Class 1 P2 up to 100 x ES - AB-2 P2 AB-PAPR-2 P2 ^

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Amber powder with a slight chlorine odour; partly soluble in water. Oxidising agent.

Physical state Divided Solid Relative density (Water = 1) 1.16-1.90 Odour Not Available Partition coefficient n-octanol / water Not Available Odour threshold Not Available Auto-ignition temperature (°C) Not Applicable pH (as supplied) Not Applicable Decomposition temperature Not Available Melting point / freezing point (°C) Not Available Viscosity (cSt) Not Applicable Initial boiling point and boiling range Not Applicable Molecular weight (g/mol) Not Applicable (°C) Flash point (°C) Not Applicable Taste Not Available Evaporation rate Not Applicable Explosive properties Not Available Flammability Not Applicable Oxidising properties Not Available Upper Explosive Limit (%) Not Applicable Surface Tension (dyn/cm or mN/m) Not Applicable Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) Negligible Vapour pressure (kPa) Negligible Gas group Not Available Solubility in water (g/L) Miscible pH as a solution(1%) Not Available Vapour density (Air = 1) Not Applicable VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7 Unstable in the presence of incompatible materials. Product is considered stable under normal handling conditions. Chemical stability Prolonged exposure to heat. Hazardous polymerisation will not occur. Possibility of hazardous reactions See section 7 Conditions to avoid See section 7

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Incompatible materials See section 7 Hazardous decomposition products See section 5

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Inhalation of dusts, generated by the material, during the course of normal handling, may be harmful. Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in a substantial number of Inhaled individuals, following inhalation. In contrast to most organs, the lung is able to respond to a chemical insult by first removing or neutralising the irritant and then repairing the damage. The repair process, which initially evolved to protect mammalian lungs from foreign matter and antigens, may however, produce further lung damage resulting in the impairment of gas exchange, the primary function of the lungs. Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be fatal or may produce Ingestion serious damage to the health of the individual. The material produces moderate skin irritation; evidence exists, or practical experience predicts, that the material either produces moderate inflammation of the skin in a substantial number of individuals following direct contact, and/or produces significant, but moderate, inflammation when applied to the healthy intact skin of animals (for up to four hours), such inflammation being present twenty-four hours or more after the end of the exposure period. Skin Contact Skin irritation may also be present after prolonged or repeated exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and thickening of the epidermis. At the microscopic level there may be intercellular oedema of the spongy layer of the skin (spongiosis) and intracellular oedema of the epidermis. Evidence exists, or practical experience predicts, that the material may cause severe eye irritation in a substantial number of individuals and/or may produce significant ocular lesions which are present twenty-four hours or more after instillation into the eye(s) of experimental animals. Eye Eye contact may cause significant inflammation with pain. Corneal injury may occur; permanent impairment of vision may result unless treatment is prompt and adequate. Repeated or prolonged exposure to irritants may cause inflammation characterised by a temporary redness (similar to windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur. Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and related systemic problems. Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or biochemical systems. Chronic Long term exposure to high dust concentrations may cause changes in lung function (i.e. pneumoconiosis) caused by particles less than 0.5 micron penetrating and remaining in the lung. A prime symptom is breathlessness.

DEVCON R-Flex Surface Conditioner TOXICITY IRRITATION Powder Premix Not Available Not Available

TOXICITY IRRITATION

Oral (rat) LD50: 406 mg/kg Eye (rabbit): 3125 mg - moderate Eye (rabbit): 50 ug/24h SEVERE N',N',N'- trichloroisocyanuric acid Skin (rabbit): 500 mg - SEVERE Skin (rabbit): 500 mg/24h-moderate Not Available Not Available

TOXICITY IRRITATION

chlorine Inhalation (rat) LC50: 293 ppm/1 hour Not Available Not Available

Not available. Refer to individual constituents.

CMR STATUS Not Applicable

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SECTION 12 ECOLOGICAL INFORMATION

Toxicity Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air Not Available Not Available Not Available

Bioaccumulative potential

Ingredient Bioaccumulation Not Available Not Available

Mobility in soil

Ingredient Mobility Not Available Not Available

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

For small quantities of oxidising agent: Cautiously acidify a 3% solution to pH 2 with sulfuric acid. Product / Packaging disposal Gradually add a 50% excess of sodium bisulfite solution with stirring. Add a further 10% sodium bisulfite. If no further reaction occurs (as indicated by a rise in temperature) cautiously add more acid.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant

HAZCHEM 1W

Land transport (ADG)

UN number 2468 Packing group II UN proper shipping name TRICHLOROISOCYANURIC ACID, DRY Environmental hazard No relevant data

Class 5.1 Transport hazard class(es) Subrisk Not Applicable

Special provisions Not Applicable Special precautions for user Limited quantity 1 kg

Air transport (ICAO-IATA / DGR)

UN number 2468 Packing group II UN proper shipping name Trichloroisocyanuric acid, dry Environmental hazard No relevant data

ICAO/IATA Class 5.1 Transport hazard class(es) ICAO / IATA Subrisk Not Applicable ERG Code 5L

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Sea transport (IMDG-Code / GGVSee)

UN number 2468 Packing group II UN proper shipping name TRICHLOROISOCYANURIC ACID, DRY Environmental hazard No relevant data

IMDG Class 5.1 Transport hazard class(es) IMDG Subrisk Not Applicable

EMS Number F-A , S-Q Special precautions for user Special provisions Not Applicable Limited Quantities 1 kg

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","International Council of Chemical Associations (ICCA) - High Production Volume List","International Maritime Dangerous Goods Requirements (IMDG Code)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","Australia - Queensland Health (Drugs and Poisons) Regulation 1996 - Appendix 7: Regulated poisons","International Maritime Dangerous Goods Requirements (IMDG Code) - Substance Index","Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic water supply - disinfection by-products)","Australia FAISD Handbook - Safety Directions","Australia Exposure Standards","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix J (Part 2)","Australia - Tasmania - Work Health and Safety Regulations 2012 - Hazardous Chemicals at Major Hazard Facilities (and their Threshold Quantity) - Table 15.1","Australia Council of Australian Governments (COAG) Chemicals of Security Concern","Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions","FisherTransport Information","Australia Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (English)","OECD List of High Production Volume (HPV) Chemicals","Australia Inventory of Chemical Substances (AICS)","Australia Drinking Water Guideline Values For Physical and Chemical Characteristics","WHO Model List of Essential Medicines - Adults","Belgium Federal Public Service Mobility and Transport, Regulations N',N',N'- trichloroisocyanuric concerning the International Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013 (Dutch)","International acid(87-90-1) is found on the following Numbering System for Food Additives","Australia - Australian Capital Territory - Environment Protection Regulation: Pollutants entering regulatory lists waterways taken to cause environmental harm (Aquatic habitat)","Australia National Pollutant Inventory","OECD Existing Chemicals Database","Australia - Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm - Domestic water supply quality","Sigma-AldrichTransport Information","WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in drinking-water","Australia High Volume Industrial Chemical List (HVICL)","Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (AQUA/1 to 6 - inorganic chemicals)","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Spanish)","Australia Work Health and Safety Regulations 2011 - Hazardous chemicals at major hazard facilities and their threshold quantity","Australia Dangerous Goods Code (ADG Code) - Dangerous Goods List","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","International Air Transport Association (IATA) Dangerous Goods Regulations","Australia Hazardous Substances Information System - Consolidated Lists","Australia - Queensland Work Health and Safety Regulation - Hazardous chemicals at major hazard facilities (and their threshold quantity)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix G","Acros Transport Information","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 7" "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","International Council of Chemical Associations (ICCA) - High Production Volume List","International Maritime Dangerous Goods Requirements (IMDG Code)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard Facilities (And Their Threshold Quantity) Table 1","International Maritime Dangerous Goods Requirements (IMDG Code) - Substance Index","Australia - Queensland Health (Drugs and Poisons) Regulation 1996 - Appendix 7: Regulated poisons","Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic water supply - disinfection by-products)","International Maritime Dangerous Goods Requirements (IMDG Code) - Marine Pollutants","Australia Exposure Standards","Australia - Tasmania - Work Health and Safety Regulations 2012 - Hazardous Chemicals at Major Hazard Facilities (and their Threshold Quantity) - Table 15.1","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix J (Part 2)","Australia - New South Wales - Work Health and Safety Regulation 2011 - Hazardous chemicals at major hazard facilities (and their threshold quantity) - Table 15.1","Australia - South Australia - Work Health and Safety Regulations 2012 - Schedule 15—Hazardous chemicals at major hazard facilities (and their threshold quantity) Table 15.1","Australia Council of Australian Governments (COAG) Chemicals of Security Concern","Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions","Australia Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (English)","OECD List of High Production Volume (HPV) Chemicals","Australia Inventory of Chemical Substances (AICS)","Australia Drinking Water Guideline Values For Physical and Chemical Characteristics","WHO Model List of chlorine(7782-50-5) is found on the Essential Medicines - Adults","Belgium Federal Public Service Mobility and Transport, Regulations concerning the International Carriage of following regulatory lists Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013 (Dutch)","International Numbering System for Food Additives","Australia - Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm (Aquatic habitat)","International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited List Passenger and Cargo Aircraft","Australia Dangerous Goods Code (ADG Code) - Packing Instruction - Liquefied and Dissolved Gases","Australia National Pollutant Inventory","UNECE - Kiev Protocol on Pollutant Release and Transfer Registers - Annex II","OECD Existing Chemicals Database","Australia - Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm - Domestic water supply quality","WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in drinking-water","Sigma-AldrichTransport Information","Australia High Volume Industrial Chemical List (HVICL)","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Spanish)","Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (AQUA/1 to 6 - inorganic chemicals)","Australia Work Health and Safety Regulations 2011 - Hazardous chemicals at major hazard facilities and their threshold quantity","Australia Dangerous Goods Code (ADG Code) - Dangerous Goods List","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","International Air Transport Association (IATA) Dangerous Goods Regulations","Australia Hazardous Substances Information System - Consolidated Lists","Australia - Queensland Work Health and Safety Regulation - Hazardous chemicals at major hazard facilities (and their threshold quantity)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix G","Acros Transport Information","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6","Australia Standard for the

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Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 7"

SECTION 16 OTHER INFORMATION

end of SDS