Fact Sheet Series Fact Sheet 2

Nitrogen Basics – The Cycle

Nitrogen, Crops and the Environment available N. , volatilization, Nitrogen (N) is essential for the development of immobilization, and result in permanent or field crops. When N is deficient, root systems and temporary N losses from the root zone. Read on for plant growth are stunted, older leaves turn yellow specifics about each of the N cycle processes. and the crop is low in crude . Too much N can delay maturity and cause excessive vegetative Fixation refers to the conversion of atmospheric N growth at the expense of grain yield. Nitrogen to a plant available form. This occurs either through is expensive and losses can be detrimental an industrial process, as in the production of to the environment. Efficient use of N by meeting commercial , or a biological process, as crop needs while avoiding excessive applications of with such as and . Nitrogen N is an important goal. This fact sheet provides a fixation requires energy, and minerals, so brief overview of the important components of the if a plant available form of N is present, the crop will N cycle to aid in reaching that goal. use it instead of fixing it from the air.

Nitrogen Cycle N2 Æ NH3 Æ R-NH2 The N cycle illustrates how N from , nitrogen organic N fertilizers and moves through the to crops, and the air. Understanding the N cycle ƒ When legumes are tilled into the soil, the N will help you make the best use of manure and stored in their roots is released and made fertilizers to meet crop needs while safeguarding available to the next crop or lost to the the environment. In general, the N cycle processes environment, depending on management. of fixation, mineralization and increase ƒ In mixed -grass stands, the grass can utilize N fixed by the legumes. If the stand has The 25% or more legume, no additional N is needed. Mineralization is the process by which microbes decompose organic N from manure, and crop residues to . Because it is a biological process, rates of mineralization vary with soil temperature, moisture and the amount of in the soil (aeration).

+ R-NH2 Æ NH3 Æ NH4 organic N ammonia ammonium

ƒ Mineralization readily occurs in warm (68-95°F), well-aerated and moist . ƒ In New York State, approximately 60—80 lbs of N per acre is mineralized on average from each year.

Nitrification is the process by which convert ammonium to to obtain energy. Nitrate is the most plant available form of N, but is also highly susceptible to leaching losses.

+ - - NH4 Æ NO2 Æ NO3 ammonium nitrate

ƒ Nitrification is most rapid when soil is warm (67- 86°F), moist and well-aerated, but is virtually halted below 41°F and above 122°F.

Department of Crop and Soil Sciences 1 College of and Sciences Denitrification occurs when N is lost through the high N inputs (especially outside of the growing conversion of nitrate to gaseous forms of N, such as season) and high rainfall are all conditions that nitric , and dinitrogen gas. This increase the potential for nitrate leaching. occurs when the soil is saturated and the use nitrate as an oxygen source. Crop Uptake is the prime goal of N management

- - on farms. The greatest efficiency occurs when NO3 Æ NO2 Æ NO Æ N2O Æ N2 adequate N is applied at a time when the crop is nitrate nitrite nitric nitrous dinitrogen actively taking it up. Efficient N use also depends on oxide oxide gas a number of other factors including temperature, ƒ De-nitrification is common in poorly drained soils. soil moisture, pest pressure, and soil compaction. ƒ In the moist Northeast climate, nitrate remaining Volatilization is the loss of N through the in the soil after the growing season will be lost to conversion of ammonium to ammonia gas, which is leaching or denitrification between crop harvest released to the . The volatilization losses and the next planting season. increase at higher soil pH and conditions that favor ƒ Efficient N use during the growing season and the (e.g. hot and windy). use of cover crops can minimize such losses.

Summary The ultimate goal of N management is to + H2N-C-NH2 Æ NH4 Æ NH3 maximize N efficiency by increasing crop uptake and ammonium ammonia minimizing N losses to the environment. Crop N

needs can be met through existing N sources (e.g. ƒ Volatilization losses are higher for and from soil organic matter, past sods and previously urea fertilizers that are surface applied and not applied manure) and supplementary applications of incorporated (by tillage or by rain) into the soil. N through manure and fertilizers. To make the most ƒ Manure contains N in two primary forms: of existing N sources and purchased fertilizers, ammonium and organic N. If manure is consider the N cycle facts, below: incorporated within one day, 65% of the ƒ N released from killed sods, via mineralization ammonium N is retained; when incorporated after and nitrification, can supply enough N for most, if 5 days the ammonium N will have been lost not all, of the N needs of the following corn crop. through volatilization. Organic N in manure is not ƒ The timing and method of manure and fertilizer lost through volatilization, but it takes time to applications determine the availability of nitrogen mineralize and become plant available. to the crop, but also the potential for loss. Spring

applications with immediate incorporation will Immobilization is the reverse of mineralization. All conserve ammonium from volatilization losses. living things require N; therefore microorganisms in ƒ Fall cover crops act as a “ savings the soil compete with crops for N. Immobilization account” by taking up residual N from the refers to the process in which nitrate and growing season or fall manure applications and, ammonium are taken up by soil organisms and thereby, reducing leaching losses. The therefore become unavailable to crops. in the become available for the next + - crop (by mineralization) after the sod is rotated. NH4 and/or NO3 Æ R-NH2 organic N For more information about N management in field ƒ Incorporation of materials with a high to crops (N guidelines, N calculators, etc.), see the nitrogen ratio (e.g. sawdust, straw, etc.), will “Nutrient Guidelines” section of the Nutrient increase biological activity and cause a greater Management Spear Program web site, below, or demand for N, and thus result in N immobilization contact your local Cornell Cooperative Extension ƒ Immobilization only temporarily locks up N. When field crop educator. the microorganisms die, the organic N contained For more information in their cells is converted by mineralization and nitrification to plant available nitrate.

Leaching is a pathway of N loss of a high concern to water quality. Soil particles do not retain nitrate very well because both are negatively charged. As a result, nitrate easily moves with water in the soil. The rate of leaching depends on soil drainage, rainfall, amount of nitrate present in the soil, and Spear Program http://nmsp.css.cornell.edu crop uptake. ƒ The EPA has set the maximum contaminant level Authors Courtney Johnson, Greg Albrecht, Quirine Ketterings, for at 10 ppm N as nitrate. Jen Beckman, and Kristen Stockin ƒ Well-drained soils, unexpected low crop yield, 2005

Department of Crop and Soil Sciences 2 College of Agriculture and Life Sciences