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Principles of Extractive Metallurgy Lectures Note
PRINCIPLES OF EXTRACTIVE METALLURGY B.TECH, 3RD SEMESTER LECTURES NOTE BY SAGAR NAYAK DR. KALI CHARAN SABAT DEPARTMENT OF METALLURGICAL AND MATERIALS ENGINEERING PARALA MAHARAJA ENGINEERING COLLEGE, BERHAMPUR DISCLAIMER This document does not claim any originality and cannot be used as a substitute for prescribed textbooks. The information presented here is merely a collection by the author for their respective teaching assignments as an additional tool for the teaching-learning process. Various sources as mentioned at the reference of the document as well as freely available material from internet were consulted for preparing this document. The ownership of the information lies with the respective author or institutions. Further, this document is not intended to be used for commercial purpose and the faculty is not accountable for any issues, legal or otherwise, arising out of use of this document. The committee faculty members make no representations or warranties with respect to the accuracy or completeness of the contents of this document and specifically disclaim any implied warranties of merchantability or fitness for a particular purpose. BPUT SYLLABUS PRINCIPLES OF EXTRACTIVE METALLURGY (3-1-0) MODULE I (14 HOURS) Unit processes in Pyro metallurgy: Calcination and roasting, sintering, smelting, converting, reduction, smelting-reduction, Metallothermic and hydrogen reduction; distillation and other physical and chemical refining methods: Fire refining, Zone refining, Liquation and Cupellation. Small problems related to pyro metallurgy. MODULE II (14 HOURS) Unit processes in Hydrometallurgy: Leaching practice: In situ leaching, Dump and heap leaching, Percolation leaching, Agitation leaching, Purification of leach liquor, Kinetics of Leaching; Bio- leaching: Recovery of metals from Leach liquor by Solvent Extraction, Ion exchange , Precipitation and Cementation process. -
An Analysis of the Metal Finds from the Ninth-Century Metalworking
Western Michigan University ScholarWorks at WMU Master's Theses Graduate College 8-2017 An Analysis of the Metal Finds from the Ninth-Century Metalworking Site at Bamburgh Castle in the Context of Ferrous and Non-Ferrous Metalworking in Middle- and Late-Saxon England Julie Polcrack Follow this and additional works at: https://scholarworks.wmich.edu/masters_theses Part of the Medieval History Commons Recommended Citation Polcrack, Julie, "An Analysis of the Metal Finds from the Ninth-Century Metalworking Site at Bamburgh Castle in the Context of Ferrous and Non-Ferrous Metalworking in Middle- and Late-Saxon England" (2017). Master's Theses. 1510. https://scholarworks.wmich.edu/masters_theses/1510 This Masters Thesis-Open Access is brought to you for free and open access by the Graduate College at ScholarWorks at WMU. It has been accepted for inclusion in Master's Theses by an authorized administrator of ScholarWorks at WMU. For more information, please contact [email protected]. AN ANALYSIS OF THE METAL FINDS FROM THE NINTH-CENTURY METALWORKING SITE AT BAMBURGH CASTLE IN THE CONTEXT OF FERROUS AND NON-FERROUS METALWORKING IN MIDDLE- AND LATE-SAXON ENGLAND by Julie Polcrack A thesis submitted to the Graduate College in partial fulfillment of the requirements for the degree of Master of Arts The Medieval Institute Western Michigan University August 2017 Thesis Committee: Jana Schulman, Ph.D., Chair Robert Berkhofer, Ph.D. Graeme Young, B.Sc. AN ANALYSIS OF THE METAL FINDS FROM THE NINTH-CENTURY METALWORKING SITE AT BAMBURGH CASTLE IN THE CONTEXT OF FERROUS AND NON-FERROUS METALWORKING IN MIDDLE- AND LATE-SAXON ENGLAND Julie Polcrack, M.A. -
Iron Production in Iceland
Háskóli Íslands Hugvísindasvið Fornleifafræði Iron Production in Iceland A reexamination of old sources Ritgerð til B.A. prófs í fornelifafræði Florencia Bugallo Dukelsky Kt.: 0102934489 Leiðbeinandi: Orri Vésteinsson Abstract There is good evidence for iron smelting and production in medieval Iceland. However the nature and scale of this prodction and the reasons for its demise are poorly understood. The objective of this essay is to analyse and review already existing evidence for iron production and iron working sites in Iceland, and to assses how the available data can answer questions regarding iron production in the Viking and medieval times Útdráttur Góðar heimildir eru um rauðablástur og framleiðslu járns á Íslandi á miðöldum. Mikið skortir hins vegar upp á skilning á skipulagi og umfangi þessarar framleiðslu og skiptar skoðanir eru um hvers vegna hún leið undir lok. Markmið þessarar ritgerðar er að draga saman og greina fyrirliggjandi heimildir um rauðablástursstaði á Íslandi og leggja mat á hvernig þær heimildir geta varpað ljósi á álitamál um járnframleiðslu á víkingaöld og miðöldum. 2 Table of Contents Háskóli Íslands ............................................................................................................. 1 Hugvísindasvið ............................................................................................................. 1 Ritgerð til B.A. prófs í fornelifafræði ........................................................................ 1 Introduction ................................................................................................................... -
The Early Medieval Cutting Edge Of
University of Bradford eThesis This thesis is hosted in Bradford Scholars – The University of Bradford Open Access repository. Visit the repository for full metadata or to contact the repository team © University of Bradford. This work is licenced for reuse under a Creative Commons Licence. The Early Medieval Cutting Edge of Technology: An archaeometallurgical, technological and social study of the manufacture and use of Anglo-Saxon and Viking iron knives, and their contribution to the early medieval iron economy Volume 1 Eleanor Susan BLAKELOCK BSc, MSc Submitted for the degree of Doctor of Philosophy Division of Archaeological, Geographical and Environmental Sciences University of Bradford 2012 Abstract The Early Medieval Cutting Edge of Technology: An archaeometallurgical, technological and social study of the manufacture and use of Anglo-Saxon and Viking iron knives, and their contribution to the early medieval iron economy Eleanor Susan Blakelock A review of archaeometallurgical studies carried out in the 1980s and 1990s of early medieval (c. AD410-1100) iron knives revealed several patterns (Blakelock & McDonnell 2007). Clear differences in knife manufacturing techniques were present in rural cemeteries and later urban settlements. The main aim of this research is to investigate these patterns and to gain an overall understanding of the early medieval iron industry. This study has increased the number of knives analysed from a wide spectrum of sites across England, Scotland and Ireland. Knives were selected for analysis based on x-radiographs and contextual details. Sections were removed for more detailed archaeometallurgical analysis. The analysis revealed a clear change through time, with a standardisation in manufacturing techniques in the 7th century, and differences between the quality of urban and rural knives. -
Experimental Design for Copper Cementation Process in Fixed Bed
Arabian Journal of Chemistry (2010) 3, 187–190 King Saud University Arabian Journal of Chemistry www.ksu.edu.sa www.sciencedirect.com ORIGINAL ARTICLE Experimental design for copper cementation process in fixed bed reactor using two-level factorial design I. Yahiaoui *, F. Aissani-Benissad Laboratoire de Ge´nie de l’Environnement (LGE), De´partement de Ge´nie des Proce´de´s, Faculte´ de la Technologie, Universite´ A.MIRA de Bejaia 06000, Algeria Received 20 July 2009; accepted 20 December 2009 Available online 18 April 2010 KEYWORDS Abstract This work deals with cementation of copper onto iron grid in a fixed bed reactor. The 2+ Copper; influence of several parameters is studied, namely: initial concentration of copper [Cu ]0, temper- Iron; ature and flow rate. Moreover, their influence on the copper cementation reaction is investigated Fixed bed reactor; statistically by the experimental design in view of industrial application. The estimation and the Factorial design comparison of the parameter’s effects are realized by using two-level factorial design. The analysis of these effects permits to state that the most influential factor is initial concentration of copper 2+ [Cu ]0 with an effect of (+2.4566), the second in the order is the temperature with an effect of (+0.18959), the third is the flow rate of the electrolytic solution with an effect of (À0.4226). The significance interactions found by the design of experiments are between initial concentrations of copper ions–flow rate (x1x3) with an effect (b13 = +0.6965). ª 2010 King Saud University. All rights reserved. 1. Introduction Ultimately, this wastewater is discharged in permitted concen- trations of suspended solids and dissolved salts. -
Removal of Copper Ions from Aqueous Solutions by a Steel-Making By-Product F.A
ARTICLE IN PRESS Water Research 37 (2003) 3883–3890 Removal of copper ions from aqueous solutions by a steel-making by-product F.A. Lopez*,! M.I. Mart!ın, C. Perez,! A. Lopez-Delgado,! F.J. Alguacil Department of Primary Metallurgy and Materials Recycling, National Centre for Metallurgical Research (CENIM), CSIC, Avda. Gregorio del Amo, 8, 28040 Madrid, Spain Received 11 October 2002; received in revised form 10 April 2003; accepted 14 April 2003 Abstract A study is made of the use of a steel-making by-product (rolling mill scale) as a material for removing Cu2+ ions from aqueous solutions. The influence of contact time, initial copper ion concentration and temperature on removal capability is considered. The removal of Cu2+ ions from an aqueous solution involves two processes: on the one hand, the adsorption of Cu2+ ions on the surface of mill scale due to the iron oxides present in the latter; and on the other hand, the cementation of Cu2+ onto metallic iron contained in the mill scale. Rolling mill scale is seen to be an effective material for the removal of copper ions from aqueous solutions. r 2003 Elsevier Ltd. All rights reserved. Keywords: Copper; Steel-making by-product; Rolling mill scale; Cementation; Adsorption 1. Introduction membrane processing and electrolytic methods, etc. [3–10,24–26]. The effluents generated by modern industries (petro- Rolling mill scale is a steel-making by-product from steel leum refineries, non-ferrous metal works, motor vehicles, hot rolling processes and is basically composed of iron aircraft plating and finishing, etc.) generally have a oxides and metallic iron with variable oil and grease complex composition which includes metals (ions or contents [11,12]. -
Through in Situ Carburization of Refractory High Entropy Alloys Yuanlin Ai National University of Defense Technology, [email protected]
Engineering Conferences International ECI Digital Archives Ultra-High Temperature Ceramics: Materials for Proceedings Extreme Environment Applications IV 9-18-2017 Feasibility research of gaining “refractory high entropy carbides” through in situ carburization of refractory high entropy alloys Yuanlin Ai National University of Defense Technology, [email protected] Shuxin Bai National University of Defense Technology Li’an Zhu National University of Defense Technology Yicong Ye National University of Defense Technology Follow this and additional works at: http://dc.engconfintl.org/uhtc_iv Part of the Engineering Commons Recommended Citation Yuanlin Ai, Shuxin Bai, Li’an Zhu, and Yicong Ye, "Feasibility research of gaining “refractory high entropy carbides” through in situ carburization of refractory high entropy alloys" in "Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications IV", Jon Binner, The nivU ersity of Birmingham, Edgbaston, United Kingdom Bill Lee, Imperial College, London, United Kingdom Eds, ECI Symposium Series, (2017). http://dc.engconfintl.org/uhtc_iv/53 This Abstract and Presentation is brought to you for free and open access by the Proceedings at ECI Digital Archives. It has been accepted for inclusion in Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications IV by an authorized administrator of ECI Digital Archives. For more information, please contact [email protected]. Feasibility Research of Gaining “Refractory High Entropy Carbides” Through In Situ Carburization of Refractory High Entropy Alloys Lian Zhu, Yuanlin Ai, Shuxin Bai National University of Defense Technology, China Outline 31 Introduction 32 Experimental 3 Results and discussion 43 Conclusions 2 1. Introduction High-entropy alloys (HEAs) – First proposed by Yeh in 2004 – Excellent comprehensive properties – 4 core effects Sluggish diffusion High- entropy Severe lattice- distortion Cocktail Gludovatz, B. -
Ironworks and Iron Monuments Forges Et
IRONWORKS AND IRON MONUMENTS FORGES ET MONUMENTS EN FER I( ICCROM i ~ IRONWORKS AND IRON MONUMENTS study, conservation and adaptive use etude, conservation et reutilisation de FORGES ET MONUMENTS EN FER Symposium lronbridge, 23-25 • X •1984 ICCROM rome 1985 Editing: Cynthia Rockwell 'Monica Garcia Layout: Azar Soheil Jokilehto Organization and coordination: Giorgio Torraca Daniela Ferragni Jef Malliet © ICCROM 1985 Via di San Michele 13 00153 Rome RM, Italy Printed in Italy Sintesi Informazione S.r.l. CONTENTS page Introduction CROSSLEY David W. The conservation of monuments connected with the iron and steel industry in the Sheffield region. 1 PETRIE Angus J. The No.1 Smithery, Chatham Dockyard, 1805-1984 : 'Let your eye be your guide and your money the last thing you part with'. 15 BJORKENSTAM Nils The Swedish iron industry and its industrial heritage. 37 MAGNUSSON Gert The medieval blast furnace at Lapphyttan. 51 NISSER Marie Documentation and preservation of Swedish historic ironworks. 67 HAMON Francoise Les monuments historiques et la politique de protection des anciennes forges. 89 BELHOSTE Jean Francois L'inventaire des forges francaises et ses applications. 95 LECHERBONNIER Yannick Les forges de Basse Normandie : Conservation et reutilisation. A propos de deux exemples. 111 RIGNAULT Bernard Forges et hauts fourneaux en Bourgogne du Nord : un patrimoine au service de l'identite regionale. 123 LAMY Yvon Approche ethnologique et technologique d'un site siderurgique : La forge de Savignac-Ledrier (Dordogne). 149 BALL Norman R. A Canadian perspective on archives and industrial archaeology. 169 DE VRIES Dirk J. Iron making in the Netherlands. 177 iii page FERRAGNI Daniela, MALLIET Jef, TORRACA Giorgio The blast furnaces of Capalbio and Canino in the Italian Maremma. -
Calculation of Carbon Diffusion Forcementation of Gear Wheels
components (eg gears, shafts) made of steel to provide CALCULATION OF CARBON hardness and strength while maintaining a tough core. The tough core provides low carbon steel to about 0.2%. DIFFUSION However, the steel containing 0.2% C is not a guarantee to get the necessary amount of martensite. The theoretical amount of carbon for steel quenching (hardening) is 0.3%. FORCEMENTATION OF More favorable for quenching (hardening) is the carbon content - about 0.7 to 0.8%. Therefore, the surface of the GEAR WHEELS steel structural component must be saturated with carbon - cementing. However, the cementation would not produce JIRI MACHUTA, IVA NOVA, PAVEL SEVCIK the desired result without subsequent heat treatment, so Technical University of Liberec called quenching. E.g. thepresent thermal treatment of Department of Engineering Technology gears is accomplished by cementation in batch furnaces or Liberec, Czech Republic in vacuum, followed by martensitic hardening and low DOI: 10.17973/MMSJ.2018_10_201826 temperature tempering. The martensitic structure in the e-mail: [email protected] surface layer of the gear wheel increases the hardness and abrasion resistance of the surface. The paper deals with the determination of the precise calculation of carbon diffusion and carbon prediction in the Subsequently, attention is paid directly to carbon steeping, production of gear wheels cementation from steel by Czech i.e cementation, and subsequent heat treatment. The standard (steel CSN 14220, or ASTMA 506). In the research components must be quenched after carbon saturation part of the paper, considerable attention is paid to the itself to obtain a hard surface layer and a tough core, and determination of the necessary data for calculating the subsequently lowered to lower the residual austenite to cementation, especially the mass- the carbon-binding reduce internal stresses. -
Beyond Wayland – Thoughts on Early Medi- Eval Metal Workshops in Scandinavia
Beyond Wayland – thoughts on early medi- eval metal workshops in Scandinavia Ny Björn Gustafsson ABSTRACT: This paper reflects on and summarises the current state of research on early medieval (750-1100 AD) metal workshops in Scandinavia by way of examples from workshops and metalworking sites recovered via archaeological excavations and surveys over the last 30 years. A critique is presented of a number of features which occur perennially in Scandinavian archaeometallurgical presentations, such as the tendency to overemphasise the importance of written accounts and the common habit of over-interpreting archaeometallurgical finds. Introduction The use of metals in past ages is a subject of seemingly endless possibilities in terms of research and publica- tions – Scandinavia is no exception. It is explicitly or implicitly included in most academic works within the fields of Iron Age and early medieval studies, but as with so many other important and fundamental cultural features, it is more or less taken for granted – as if the extraction and working of metals took place almost on its own. The situation was of course much more complex than that, and this paper aims to highlight some aspects of one of the fundamental prerequisites for metalwork- ing – the workshop. The workshops and production sites listed below have mainly been found within the bound- aries of modern day Sweden, but some important sites in Denmark, Norway, Finland and Estonia have been included (Fig 1). The timeframe is that of c750-1100 AD, often referred to as the Viking Period. The ever-productive forge of myth and legend In many studies of early medieval Scandinavia, the working of metals is mainly presented as taking place under the ever-watchful eyes of masterful smiths. -
Removal of Copper from Wastewater by Cementation from Simulated Leach Liquors Ehssan Nassef1* , Yehia A
ineering ng & E P l r a o c i c e m s e s Journal of h T C e f c h o Nassef and El-Taweel, J Chem Eng Process Technol 2015, 6:1 l ISSN: 2157-7048 n a o n l o r g u y o J Chemical Engineering & Process Technology DOI: 10.4172/2157-7048.1000214 Research Article Article OpenOpen Access Access Removal of Copper From Wastewater By Cementation From Simulated Leach Liquors Ehssan Nassef1* , Yehia A. El-Taweel2 1Department of Petrochemical Engineering, Faculty of Engineering, Pharos University, Smouha, suburb, Canal El Mahmoudia Street, Alexandria, Egypt 2Department of Chemical Engineering, Faculty of Engineering Alexandria University, Lotfy El-Sied st. off Gamal Abd El-Naser, Alexandria, Egypt Abstract Every year, tons of precious and/or toxic metals are thrown away in industrial liquid effluents and most frequently directly in natural environment. The recovery of those metals in dilute solutions is an everyday problem associating both ecology and economy. Copper is among the most prevalent and valuable metal used by industry. Cementation is one of the most effective and economic techniques for recovering toxic and or valuable metals from industrial waste solution and from leach liquors obtained by leaching low grade copper ore. The present study was carried out to investigate the removal of copper metal ions from synthetic waste water by cementation using a rotating iron cylinder. The study covered the effect of different parameters in batch mode which are: Initial copper concentrations, pH values, rotational speed, and reaction temperature on the rate of cementation. -
United States Patent [191 [111 3,734,582 Beauchet [451 May22,1973
United States Patent [191 [111 3,734,582 Beauchet [451 May22,1973 [54] COMBINATION BEARING MATERIALS Primary Examiner-Charles J. Myhre Assistant Examiner-Frank Susko [75] Inventor: Jean Beauchet, Annecy (Haute Attorney-Stevens, Davis, Miller & Mosher Savoie ), France [73] Assignee: Societe Nouvelle De Roulements, An [57] ABSTRACT necy (Haute Savoie), France This invention relates to the manufacture of rolling [22] Filed: ' Oct. 29, 1971 contact bearings wherein the outer and inner races or rings were hitherto made of the same steel grade and [21] Appl. No.: 194,069 subjected to a heat treatment with or without a Related US. Application Data preliminary cementation. [63] Continuation of Ser. No. 4,729, Jan. 21, 1970, aban According to this invention, the inner races of the doned. bearings are made of cementation steel and the outer races as well as the rolling-contact members, such as [52] U.S. Cl ................................................. ..308/l73 balls and rollers from core-hardened alloy steel. The [51] Int. Cl. ...................................................... ..F16c treatment consists of a case-hardening or cementation [58] Field of Search .................... ..308/8, 2, 241, 237, applied to the inner races and of a hardening process 7 308/177 applied to the outer races and rolling bodies. [56] References Cited 2 Claims, 2 Drawing Figures UNITED STATES PATENTS 3,275,389 9/1966 Neilson et a1 ........................ _.308/8.2 3,734,582 1 2 COMBINATION BEARING MATERIALS creased fragility but also by a distortion of the treated parts, as a consequence of the above-described stress This is a continuation of application Ser. No. 4,729, effects, this distortion being frequently too important ?led Jan.