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Ministère des Richesses Naturelles, Quebec SEWCE DE LA DOCUMENTATION TECHNIQUE
Date: No ~?. -,376
GEOLOGY AND HYDROCARBON POTENTIAL OF THE BERRY MOUNTAIN SYNCLINE, CENTRAL GASPE (MATANE, MATAPEDIA, GASPE W. AND BONAVENTURE COUNTIES), QUEBEC
A. HAKIM SIKANDER MAY, 1975 ii
ABSTRACT
The Berry Mountain Syncline consists of a wide oval shaped asymmetric structure, the northern limb of which is gently dipping, and the southern limb steep to upright. The central portion of the Syncline is underlain by the Lower-Middle Devonian Gaspé Sandstone series.
The Gaspé Sandstone, conformably overlying the Lower Devonian Gaspé Limestone series, is divided into: The 2,000 to over 6,000 foot thick, marine, York River formation (Emsian, Lower Devonian) consisting of greenish grey, fine to very fine grained, poorly sorted, grey, felds- pathic, and muddy sandstone with intervening shale and siltstone. A 0-5,000 foot thick middle unit, the Lake Branch formation, of deltaic interface facies, consisting of red silty shale, with minor fine grained but relatively high energy sands (late Emsian?, Lower Devonian). And the 8,000-10,000 foot thick, alluvial Battery Point formation (extending into Eifelian, Middle Devonian), consisting mainly of greenish grey, fine to medium grained, highly cross-stratified, (pink) feldspar-rich sandstone, and a red sandstone and shale.
Although detailed correlation of the Gaspé Sandstone horizons across the Syncline is difficult, the 5,000 foot thick Lake Branch interval consisting of shale with minor sand, is absent in the southern limb sections: Also, the York River Formation contains more shale interbeds in the southern sections than to the north. Thus, stratigra- phic trap possibilities are envisaged, especially on the gently dipping northern limb. Prospective structural traps consist of normal faults on the northern flank.
Owing to a lack of organic matter, the York River is consid- ered a,shaving poor source-rock potential. Maturation studies, (vitri- nite reflectance and organic matter carbonization) suggest that the York River, and the Lake Branch formations are situated at a favourable level of organic metamorphism for oil and gas generation; the western 111 part of the area having a greater possibility for oil than the eastern part; the latter attaining a higher regional metamorphism due to the presence of a great thickness of volcanics, and intrusives. The meta- morphic effects along the volcanic and the sedimentary rock contacts are of an extremely local nature.
The field work did not reveal the presence of sandstones with interesting reservoir possibilities. The low porosity development in the Lower Devonian sandstones is attributed to the presence of illite, chlorite, rare kaolinite, altered feldspars, and occasional calcite and silica cement. The effect of surface weathering, and the formation of authigenic illite and chlorite on the potential reservoir sand is not clear.
Judging from the poor source rock, reservoir and trapping pos- sibilities, and a favourable level of organic metamorphism, the hydro- carbon potential of the area, as evaluated from the surface collected samples, is rated as poor to fair. It is the qualified opinion of the author that the rock exposure in the area is too poor to make a categoric judgement on the potential parameters, such as source and reservoir. Furthermore, owing to an absence of wells in the area, a correspondance of the surface data with those of the subsurface is not clear. iv
CONTENTS
Page
1. GENERAL DESCRIPTION 1
1.1 INTRODUCTION AND PURPOSE OF STUDY 1 1.2 ACKNOWLEDGEMENTS 2 1.3 PREVIOUS WORK 2 1.4 METHOD OF STUDY 6 1.5 ACCESS AND EXPOSURE 7 1.6 TOPOGRAPHY AND DRAINAGE 8
2. GEOLOGICAL DESCRIPTION 12
2.1 CAP BON AMI FORMATION 13 2.1.1 DISTRIBUTION 13 2.1.2 DESCRIPTION 14 2.1.3 CONCLUSIONS 16
2.2 GRANDE GREVE FORMATION 16 2.2.1 DISTRIBUTION 17 2.2.2 DESCRIPTION 17 2.2.2.1 North Brandy Brook 18 2.2.2.2 Cascapedia Salmon Branch 18 2.2.2.3 Cascapedia Lake Branch 19 2.2.2.4 West Lake Branch 20 2.2.2.5 Nouvelle River 21 2.2.3 CONCLUSIONS 21
2.3 YORK LAKE FACIES 22 2.3.1 DISTRIBUTION 23 2.3.2 DESCRIPTION 23 2.3.2.1 Brandy Brook 24 2.3.2.2 Cascapedia Salmon Branch 24 2.3.2.3 Go-Ashore Brook 24 2.3.2.4 Cascapedia Lake Branch 25 2.3.2.5 West Lake Branch 25 2.3.2.6 Nouvelle Road South 25
v
Page
2.3.3 CONCLUSIONS 26
2.4 YORK RIVER 26 2.4.1 DISTRIBUTION 28 2.4.2 DESCRIPTION 28 2.4.2.1 Northern Area 29 2.4.2.1.1 Brandy Brook 29 2.4.2.1.2 Cascapedia Salmon Branch 29 2.4.2.1.3 Cascapedia Lake Branch 31 2.4.2.1.4 West Lake Branch 32 2.4.2.2 Southern Area 34 2.4.2.2.1 Caron Brook 34 2.4.2.2.2 Marcil West Brook 35 2.4.2.2.3 Charles Valley 37 2.4.2.2.4 Nouvelle South 39 2.4.3 CONCLUSIONS 40
2.5 LAKE BRANCH FORMATION 41 2.5.1 DISTRIBUTION 41 2.5.2 DESCRIPTION 42 2.5.2.1 Nouvelle South 42 2.5.3 CONCLUSIONS 44
2.6 BATTERY POINT FORMATION 45 2.6.1 DISTRIBUTION 46 2.6.2 DESCRIPTION 46 2.6.3 CONCLUSIONS 49
3. CORRELATION AND. ENVIRONMENTAL PALEONTOLOGY 51
4. PALEOGEOGRAPHY 54.
4.1 INTRODUCTION 54 4.2 DEPOSITIONAL ENVIRONMENT 55 4.2.1 YORK RIVER FORMATION 56 4.2.2 LAKE BRANCH FORMATION 57 4.2.3 BATTERY POINT FORMATION 57 4.3 CURRENT DIRECTIONS 58 4.4 CONCLUSIONS 60
5. VOLCANIC AND GRANITIC ROCKS 62
5.1 VOLCANIC ROCKS 62 5.2 DEVONIAN GRANITIC ROCKS 65 5.3 DIABASE INTRUSIVE 66
6. STRUCTURE 67 vi
Paae
7. ECONOMIC POSSIBILITIES 71
7.1 HYDROCARBONS 71 7.1.1 SOURCE ROCK POTENTIAL 73 7.1.2 MATURATION POTENTIAL 74 7.1.2.1 Clay Composition and Crystallinity 74 7.1.2.2 Vitrinite Reflectance 76 7.1.2.3 Organic Matter Colouration 79 7.1.3 RESERVOIR POTENTIAL 79 7.1.4 TRAPPING POTENTIAL 82 7.1.5 SUMMARY 83 7.2 MINERALS 84
8. REFERENCES 86
9. APPENDICES 92
9.1 FOSSIL IDENTIFICATION 93 9.2 PALYNOSTRATIGRAPHY 95 9.3 FIELD PHOTOGRAPHS 104 vii
LIST OF ILLUSTRATIONS
ENCLOSURES
1. Compilation geological map.
2. Stratigraphic section, northern limb of the Berry Mountain Syncline.
3. Stratigraphic section, southern limb of the Berry Mountain Syncline.
4. Structural sections A-A' and B-B,.
5. Important geological columns.
FIGURES
1. Previous studies.
2. Correlation of Lower-Middle Devonian formations by previous workers in the Gaspé Peninsula.
3. Transportation and general situation map.
4. Generalized topographic map.
5. Table of formations.,
6a. Northeast-Southwest diagrammatic section illustrating regional correlation.
b. North-South diagrammatic section illustrating regional correlation.
7. Geographic distribution, Cap Bon Ami formation.
8. Geographic distribution, Grande Grève formation.
9. Geographic distribution, York Lake facies.
10. Geographic distribution, York River formation.
11. Geographic distribution, Lake Branch formation.
12. Geographic distribution, Battery Point formation.
13. Compilation of environment models for clastic sedimentation viii
14. Frequency listing of lithological and sedimentary features, Gaspé Sandstone.
15. Isopach map, paleo-current directions, York River formation.
16. Thickness estimates, paleo-current directions, Battery Point formation.
17. Illustrative diagrams envisaging sedimentary environment for the lithological units of the Gaspé Sandstone.
13a. General scheme of hydrocarbon generation.
b. Principal steps of kerogen evolution and hydrocarbon formation.
c. Examples of kerogen evolution paths.
19. Some scales of organic metamorphism after Hood and Castano (1974), and Hood et al (1975).
20. Vitrinite reflectance, index for level of organic metamorphism, York River formation.
21. Table of porosity and permeability analyses.
22. Summary of hydrocarbon potential, Berry Mountain Syncline.
I-1. Fossil locations, Berry Mountain Syncline. GENERAL DESCRIPTION
INTRODUCTION AND PURPOSE OF STUDY
The Berry Mountain Syncline area designates an area of approxi- mately 900 square miles (33 x 27) situated in central Gaspé between lati- tudes 48°26'-48°52' N and longitudes 65°54'-66°38' W, located midway between the St. Lawrence River to the north, and Chaleurs Bay to the south. The central part of the area is situated some 50 miles from the village of Ste-Anne-des-Monts.
Broadly speaking, the area consists of a gently dipping northern limb which exposes the Silurian and lower Devonian rocks, and a steeply dipping southern limb. The axial area is occupied by a thick sandstone sequence of Lower to Middle Devonian age. A major facies change occurs across the syncline axis: A several thousand foot thick sand interval shales out along the northern limb.
The Devonian granitic intrusives are restricted to the northern part (Barren Mountain), and to the north of the area in the Hog's Back Mountain. Volcanic lava flows, both acidic and basic, and pyroclastic rocks are present in the lower Devonian, at various horizons. The con- tact metamorphic effects of these lava flows, appear to be limited in both horizontal and vertical extent.
Hydrothermal activity, north and east of the area, causes a widespread sulphide mineralisation, along anticlinal structures which usually expose the Gaspé Limestone, especially the Grande Grève formation.
No wells have yet been drilled for hydrocarbons in the area.
The purpose of the study is to: 1. Build several geological columns, in order to establish 2
lithological sub-divisions within the Gaspé Sandstone series, and investigate the possibility of reservoir sand in the sequence. 2. Investigate sedimentological aspects and the depositional envi- ronment of each lithological subdivision. 3. Using geochemical techniques define the hydrocarbon potential for the Gaspé Sandstone series in central Gaspé. 4. Improve the over-all geological knowledge of the Berry Mountain Syncline area.
ACKNOWLEDGEMENTS
I am indebted to Michel Leduc for continued assistance in the field. Richard Theroux worked in the field as senior geological assis- tant, and later helped construct the geological sections; his help was invaluable throughout the writing phase. I also acknowledge the close communication that was maintained with the INRS-Pétrole laboratories of the Université de Quebec.
Finally, I am indebted to Dr. J.A. Boucot, who identified the brachiopods collected in the field.
PREVIOUS WORK
Important previous studies in central Gaspé are shown in figure 1.
The first geological description of the area was included in the Geology of Canada (Logan, 1863). Logan described the sequence south of the Quebec Group outcrop area as consisting of sandstone followed upwards into low dipping fossiliferous limestone, which he tentatively, correlated with the "Anticosti Group".
The limestones, according to Logan, are overlain by grey, fine- grained sandstones, and red sandstones containing mud-cracks and ripple-
4rsoN LEGEF;OE-LEGEND
GEYONIEN-GEVONIAN A / ~/ J Grcoite et feisite Granite and felsite Yattinson, 1964 , Alcock, 19Z6 6 /i ~ . j n"3 ~:~~.~' kicGerrlgle, 1954 -11 1 ~..e.~~•$ :~, _/ ~~~ d. ~ /b// s Pcdesite Andesite 4 ~ /. 7 1= Î Battery Point Battery Point / \ - i + 1J ~~ J/ Facies de 'Squire Forks' Square Forks facies ~~~~ i 1 1 ~qt,,,,,/ Bcttery Point typique Typical Battery Point ~. ,~ ;-~ ~ ' ~~~ i t t k, g. jr.Ch Lake Branch /1./4 6~\ 4/\^~
Y'ori. R.iY2r York Pi ver ,t~?ti I t(o1c&,,ioues, rLyolite, Volcanics, rhyolite, X2 basalte, ardesite E_: basalt, ande,itc >tI r-7-1 Groupe de f% York ',eke York Lake Fortin / f~ I'1 -' ~ /~i <1_,:.. //- Sranda_9 '0ri!!ve ; •, __J Grande Greve ~/(/~ ✓ i .,, ~I Cal Bor Am; r•77-`i Cn^ Bon :01",:01", ~/` 7 `.t, l_ J ~r ~. %~ï Y SIL'JRIEN DEVCNIEN-SILURIAN DEVONIAN Carbonneau, 1559 8 ~ .a s0' St. Leon (2a, .,,;r de Caldwin (2a; ü%.'dvin mbr. , +7 CAM3nD-ORuDVICIO ,-C.1M;C-ORCN IC!Av f 7 ,~ ` ` t Gro,;-_ d- Sr;i_xsncck i' r-/--1 Sh'ckshock Group '— ~ 2Q J• htasdic.entalres, mkta- C--- J Mctasediments, neta- ))) 7 / ~ SAREP, 1971 vol:an,Ç,ies YOlcdnici ~a ~j~7/ !'' 1_ 1 7 ~ , ti ras ~o u es° os°ssrv Faille Fault
Axcs de plis i' Fold aces —t— Contact g4ologi;ue FIGURE 1: ETUDES ANTERIEURES, SYNCLINAL 0E Geological contact BERRY MOUNTAIN, QUEBEC. PREVIOUS STUDIES, BERRY MOUNTAIN SYNCLINE, QUEBEC. Milles 0 4 g Miles
Kil,mêtres 10 4 Kilometres ECHELLE-SCALE 3 marks (p. 412). Although Logan's lithological descriptions are excellent, his thickness estimates are too low.
Ells, in 1883, did a reconnaissance along the Lake Branch and Salmon Branch, the two important tributaries of the Cascapedia river (Ells, 1885). The same year, Low ascended the Ste-Anne river to Lake Ste-Anne. He crossed over to the head waters of the west Branch of the Little Cascapedia river, and descended to the south shore of Gaspé.
Lead and zinc-bearing veins were discovered in Lemieux township in 1919, and Mailhiot mapped an area around the Federal zinc and lead mine.
In 1918-19, Coleman investigated the Berry Mountain area in a glacial and physiographic study of the Gaspé peninsula.
Alcock (1926) mapped the Mount Albert area, a part of which overlaps the northern area of the present study. Alcock's observations on the Gaspé Sandstone appear to be limited: However, he considered the lower part of the Gaspé Sandstone to be marine, and the upper as conti- nental (deltaic and fluvial).
Jones (1930) investigated the central Gaspé area: he divided the sequence into a lower, basic volcanics; and an upper, Gaspé Sandstone division. He subdivided the Gaspé Sandstone into a lower unit ("Lower to Middle Devonian"), which resembles the York River; a middle unit, predominantly consiting of red shales; and an upper unit consisting of highly cross-bedded, grey, hard sandstones.
Jones attributed a total thickness of 7,700 feet to the Gaspé Sandstone (the name originally used by Logan in 1863 for the rocks found along the eastern Gaspé coast). A large part of the sequence was con- sidered to be deposited under terrestial conditions as deltas. Owing to marine biota (p. 22), the basal part was considered to be marine. 4
Alcock (1945) reported the presence of solid bitumen in the amygdules, up to 2 inch in diameter, in basic volcanic rocks (within what is now known as the Lower Devonian York Lake), 1 mile west of Squaw Cap Mountain, along a tributary of the Salmon Branch (approx. loc. lat. 48°48'48", long. 66°18'30"). The bitumen saturation presumably took place before the precipitation of secondary calcite and quartz.
Alcock recommended a stratigraphic drilling program to inves- tigate the presence of petroleum in local structures; but he noted a general absence of oil shows in the area.
McGerrigle (1946) found a contradiction in the paleontological age of the lower 3,000 feet of the Gaspé Sandstone series in eastern Gaspé. The brachiopods in the interval suggest Oriskany, while the molluscs, particularly the pelecypods, suggest a Middle Devonian Hamilton age.
Kindle (1938) postulated that the Gaspé Sandstone series should be divided into York River and Peninsula subdivisions. The York River being marine, and the Peninsula, non-marine; the two being essentially contemporaneous. However, McGerrigle (1946) suggested that although this may be valid to some extent, the presence of 4,000-5,000 feet of York River under 7,000 feet of Peninsula (Battery Point) makes this con- cept difficult to understand.
Using the paleontological data of Cooper (1942), and Kindle (1938), and judging from structural and geographic positions, McGerrigle (1946) suggested that the Heppel Sandstone, in the Matapedia Valley in western Gaspé, and the Gaspé Sandstone, in eastern Gaspé, are identical in age.
Carbonneau (1953, 1959) adopted the name "Big Berry Mountains" for the main topographic feature east and west of the Cascapedia River as indicated on the topographic maps of the topographic division of the Department of Mines and Technical Surveys, Ottawa. He systematically 5 mapped the Big Berry Mountain area. His study consists of an excellent work on the Gaspé Sandstone in which he extended McGerrigle's (1950) observations in eastern Gaspé, to central Gaspé.
Carbonneau (1959) subdivided the Devonian sequence into a Cape Bon Ami - Grande Grève limestone unit, a transitional limestone-sandstone interbedding called York Lake facies; grading upward, through a volcanic sequence, into the Gaspé Sandstone. He divided the Gaspé Sandstone into the York River, Lake Branch and Battery Point formations. A volcanic sequence preceded the Battery Point. The Devonian formations, according to him, range in age from middle Lower Devonian to lower Middle Devonian.
He concluded that the Lake Branch was a facies equivalent of the marine York River formation.
A re-study of the Gaspé Sandstone fauna in eastern and western Gaspé by Boucot et al (1967) revealed that at least the lower 2,000 feet of the strata are Lower Devonian in age. In eastern Gaspé, the York River is to Etymothyris zone age, and in western Gaspé it is of Etymothy- ris and Amphigenia age. Other brachiopod genera suggest an equivalence of the upper part of the Lower Devonian. Gastropods (Nylanderina n. genus) from the Gaspé Sandstone suggest a Lower Devonian age. They also indicate that the Lake Branch formation in western Gaspé (upper Heppel) is equivalent to the Battery Point of eastern Gaspé. The base of the York River formation in the west, according to the workers, is older than its equivalent in eastern Gaspé.
Figure 2 shows the published opinions of various recent workers regarding correlation and age of the Gaspé Limestone and the Gaspé Sand- stone series in the Gaspé Peninsula.
McGerrigle (1954) mapped the Tourelle-Courcelette areas, which form the northern part of the present study area. His maps are used in the present study. Figure 2: Correlation of Lower-Middle Devonian formations by previous workers in the Gaspé Peninsula, Quebec.
Region Western Gaspé Central Gaspé Eastern Gaspé
Author Boucot et a1,1967 Carbonneau,1959 Present Study McGerrigle,1950 Boucot et a1,1967 McGregor,1973
Battery Point le
1, d v - fp S Battery Point Battery Point ------d Lake Branch York River Mi Battery Point LE.ke Branch
• York River_ York Lake'
ONIAN Lake Branch York River G 7 T N Battery Point
r ~(erk Lake DEV we 'York Lake ' York River
Lo Fortin Series York River •