Manuscript Click here to download Manuscript: Paint It Black Radivojevic Rehren REVISION December 2014.docx 1 2 3 4 5 6 Paint It Black: the rise of metallurgy in the Balkans 7 8 9 10 11 12 Miljana Radivojević1 and Thilo Rehren2 13 1 14 Institute of Archaeology, University College London, 31-34 Gordon Square, WC1H 0PY London, UK; 15 email:
[email protected], phone: +44 207 679 4936; fax 0207 679 1043 16 2 17 UCL Qatar, Georgetown Building, PO Box 25256, Education City, Doha, UK; email: 18
[email protected] 19 20 21 22 Abstract 23 24 This paper integrates archaeological, material, microstructural and compositional data of c. 7000 years 25 old metallurgical production evidence with the aim to address the knowledge of the world’s earliest 26 metalworkers. The main focus is placed on copper minerals, ores, slags, slagged sherds and metal 27 droplets coming from four Vinča culture settlements in Serbia and Bosnia and Herzegovina: Belovode, 28 29 Pločnik, Vinča and Gornja Tuzla, all dated between c. 5400 – 4400 BC. Chemical study of copper 30 minerals throughout all sites points at striking uniformity in selecting black and green minerals from the 31 early days of the settlements’ occupation, some of which predate the metal smelting events. 32 33 Microstructural examination of metal production debris showed convincing technological similarity 34 throughout c. six centuries of copper making in the studied sites, as well as a consistent choice of black 35 and green ores for metal extraction. We argue that black and green ores were intentionally selected as 36 ingredients for the metal smelting ‘recipe’ in the early stages of Balkan metallurgy based on the 37 38 knowledge related to their characteristic visual aspects.