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Safety Data Sheet CS: 1.7.2

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Safety Data Sheet CS: 1.7.2 Safety Data Sheet CS: 1.7.2 Page : 1 of 5 Infosafe No ™ 1CHBK Issue Date : November 2016 RE-ISSUED by CHEMSUPP Product Name : SODIUM BISULFATE Anhydrous Classified as hazardous 1. Identification GHS Product SODIUM BISULFATE Anhydrous Identifier Company Name CHEM-SUPPLY PTY LTD (ABN 19 008 264 211) Address 38 - 50 Bedford Street GILLMAN SA 5013 Australia Telephone/Fax Tel: (08) 8440-2000 Number Fax: (08) 8440-2001 Recommended use Flux for decomposing minerals ; substitute for sulfuric acid in dyeing ; disinfectant ; liberating CO2 in of the chemical and carbonic acid baths, in thermophores ; carbonizing wool ; to reduce alkalinity and pH in swimming pools ; restrictions on use manufacture of magnesia cements, paper, soap, perfumes, industrial and household cleaners, foods, silver and metal pickling compounds, sodium hydrosulfide, sodium sulfate and soda alum and laboratory reagent. Other Names Name Product Code SODIUM BISULFATE LR SL010 Sodium hydrogen sulfate, Sodium pyrosulfate, Sodium acid sulfate Other Information EMERGENCY CONTACT NUMBER: +61 08 8440 2000 Business hours: 8:30am to 5:00pm, Monday to Friday. Chem-Supply Pty Ltd does not warrant that this product is suitable for any use or purpose. The user must ascertain the suitability of the product before use or application intended purpose. Preliminary testing of the product before use or application is recommended. Any reliance or purported reliance upon Chem-Supply Pty Ltd with respect to any skill or judgement or advice in relation to the suitability of this product of any purpose is disclaimed. Except to the extent prohibited at law, any condition implied by any statute as to the merchantable quality of this product or fitness for any purpose is hereby excluded. This product is not sold by description. Where the provisions of Part V, Division 2 of the Trade Practices Act apply, the liability of Chem-Supply Pty Ltd is limited to the replacement of supply of equivalent goods or payment of the cost of replacing the goods or acquiring equivalent goods. 2. Hazard Identification GHS classification Eye Damage/Irritation: Category 1 of the substance/mixture Signal Word (s) DANGER Hazard Statement H318 Causes serious eye damage. (s) Pictogram (s) Corrosion Precautionary P280 Wear protective gloves/protective clothing/eye protection/face protection. statement – Prevention Precautionary P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses , statement – if present and easy to do. Continue rinsing. Response P310 Immediately call a POISON CENTER or doctor/physician. 3. Composition/information on ingredients Chemical Solid Characterization Ingredients Name CAS Proportion Hazard Symbol Risk Phrase Sodium bisulfate 7681-38-1 95-100 % 4. First-aid measures Inhalation If inhaled, remove from contaminated area to fresh air immediately. Apply artificial respiration if not breathing. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear. Print Date: 8/05/2018 CS: 1.7.2 Safety Data Sheet CS: 1.7.2 Page : 2 of 5 Infosafe No ™ 1CHBK Issue Date : November 2016 RE-ISSUED by CHEMSUPP Product Name : SODIUM BISULFATE Anhydrous Classified as hazardous Ingestion Rinse mouth thoroughly with water immediately, repeat until all traces of product have been removed. DO NOT INDUCE VOMITING. Seek medical advice if effects persist. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. If rapid recovery does not occur, obtain medical attention Eye contact Immediately irrigate with copious quantity of water for at least 15 minutes. Eyelids to be held open. Seek medical attention. First Aid Facilities Maintain eyewash fountain and safety shower in work area. Advice to Doctor Treat symptomatically based on judgement of doctor and individual reactions of the patient. Protection for First No action shall be taken involving any personal risk or without suitable training. If it is suspected that Aiders fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing or wear gloves. Other Information For advice, contact a Poisons Information Centre (Phone eg Australia 13 1126 ; New Zealand 0800 764 766) or a doctor. 5. Fire-fighting measures Hazards from Sulfur oxides (SO2, SO3, etc.), sulfuric acid, sodium oxides and suffocating and toxic fumes. Reacts with Combustion most metals in the presence of moisture, liberating extremely flammable hydrogen gas. Products Specific Methods Use extinguishing media most appropriate for the surrounding fire. No limitations to the type of extinguishing media. Small fire: Use dry chemical, CO2 or water spray. If safe to do so, move undamaged containers from fire area. Large fire: Use dry chemical, CO2, foam or water spray - Do not use water jets. Cool containers with flooding quantities of water until well after fire is out. Avoid getting water inside containers. Hazchem Code 2X Precautions in Wear SCBA and chemical splash suit. Fully-encapsulating, gas-tight suits should be worn for maximum connection with Fire protection. Structural firefighter's uniform is NOT effective for these materials. 6. Accidental release measures Personal Avoid substance contact. Avoid generation of dusts: do not inhale dusts. Ensure supply of fresh air in Precautions enclosed rooms. Personal Protection Wear protective clothing specified for normal operations (see Section 8) Clean-up Methods - Sweep up (avoid generating dust) and using clean non-sparking tools transfer to a clean, suitable, Small Spillages clearly labelled container for disposal in accordance with local regulations. 7. Handling and storage Precautions for Safe Avoid ingestion or inhalation of dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or Handling repeated exposure. Avoid generating dust. Keep container tightly closed. Use only with adequate ventilation. Operations should be carried out in an efficient fume hood or equivalent system. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Wear appropriate protective equipment to prevent inhalation, skin and eye contact. Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Discard contaminated shoes. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Ensure a high level of personal hygiene is maintained when using this product. That is ; always wash hands before eating , drinking, smoking or using the toilet. Keep locked up. Never add water to this product. Keep away from incompatibles such as oxidizing agents, alkalis. Chemicals should be used only by those trained in handling potentially hazardous materials. Conditions for safe Store in tightly sealed containers, in a cool, dry, well-ventilated area, out of direct sunlight and moisture. storage, including Store in labelled containers. Keep container tightly closed when not in use. Product reacts with water. any Moisture sensitive. Prevent contact with atmospheric moisture. Store away from water and incompatible incompatabilities materials. Corrosiveness Corrosive to aluminium in aqueous solution. Corrosive to most metals (carbon steel, copper, copper alloys, zinc or nickel) in the presence of moisture, liberating extremely flammable hydrogen gas. Storage Regulations Refer Australian Standard AS 3780-1994 'The storage and handling of corrosive substances'. Unsuitable Materials Aqueous solutions cannot be stored in aluminium, carbon steel, copper, copper alloys, zinc or nickel containers. Print Date: 8/05/2018 CS: 1.7.2 Safety Data Sheet CS: 1.7.2 Page : 3 of 5 Infosafe No ™ 1CHBK Issue Date : November 2016 RE-ISSUED by CHEMSUPP Product Name : SODIUM BISULFATE Anhydrous Classified as hazardous 8. Exposure controls/personal protection Other Exposure A time weighted average (TWA) concentration for an 8 hour day, and 5 day week has not been Information established by Safe Work Australia for this product. There is a blanket limit of 10 mg/m³ for dusts when limits have not otherwise been established. Appropriate In industrial situations maintain the concentrations values below the TWA. This may be achieved by engineering controls process modification, use of local exhaust ventilation, capturing substances at the source, or other methods. Respiratory Where ventilation is not adequate, respiratory protection may be required. Avoid breathing dust, vapours Protection or mists. Respiratory protection should comply with AS 1716 - Respiratory Protective Devices and be selected in accordance with AS 1715 - Selection, Use and Maintenance of Respiratory Protective Devices. Filter capacity and respirator type depends on exposure levels. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection. Eye Protection The use of a face shield, chemical goggles or safety glasses with side shield protection as appropriate. Must comply with Australian Standards AS 1337 and be selected and used in accordance with AS 1336. Hand Protection Hand protection should comply with AS 2161, Occupational protective gloves - Selection, use and
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