HASA DRY ACID Safety Data Sheet (SDS No. 207)

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Safety DataSheet :

4 661.259.1538 661.259.1538 661.259.5848 661.259.5848

 

Hasa Hasa Inc. 802736 O. P.Box Santa 91355 CA Clarita, 1-800-424-9300 (24 Hour Emergency Telephone) (24Emergency Hour 1-800-424-9300 HASA DRY ACID DRY HASA 7681-38-1 VZ1860000 231-665-7 bisulfate NaHSO salt Inorganic acid Sulfate, Sodium Hydrogen , Acid Sodium Pyrosulfate. for theto pH water lower of primarily It is used pools swimming chlorination, including effective and spas. CHEMTREC 661-259-5848 / PST – PDT) 5 (8 PM AM

CHEMTREC 800.424.9300 CHEMTREC P. O. Box 802736 O. P.Box Santa 91355 CA Clarita, Telephone Fax

:

(Supersedes previous revisions) Assistance

(EuropeanInventory of

(Registryof Toxic Effects :

: (ChemicalAbstract Service)

: ofChemical Substances) EINECS Chemical Name: : Chemical Family: Synonym: Product Name: # CAS RTECS ExistingCommercial Substances) Emergency

-

Emergency Emergency Assistance: Non Recommended Recommended Uses: Identification: Company 1.1.4 1.1.5 1.1.6 1.1.7 1.1.8 Product Identification: Product 1.1.1 1.1.2 1.1.3 SECTION 1:SECTION CHEMICAL PRODUCT ANDCOMPANYIDENTIFICA

Emergency 24 Hour Telephone: Telephone: Emergency 24 Hour Corporate Headquarters: Corporate Headquarters: Hasa Inc. RevisionDate: 01/01/2015

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HASA DRY ACID

HASA DRY ACID Safety Data Sheet (SDS No. 207)

r r

or. inated clothing inated ontinue rinsing. ontinue cal, regional,

ection/face ection/face Page of 2 9

Category 1 Category 4 Category 4 Category

Storage Disposal DANGER Response Prevention Take off immediately all contaminated contaminated all Take off immediately

Rinse mouth. Do NOT induce vomiting. Call a vomiting. Call induce Do NOT mouth. Rinse : Remove person to fresh air and keep comfortable fo keep comfortable and fresh to personair Remove Rinse cautiously with water for several minutes. for minutes. water several with cautiously Rinse breathing. Immediately call a POISON CENTER or doct a call POISON CENTER breathing. Immediately national, international regulations as specified. as specified. regulations national, international Store locked up. Storeup. locked lo with in accordance container/contents ofDispose IF SWALLOWED Causes severe skin burns and eye damage. damage. and burns eye Causes skin severe Harmful if inhaled. Harmful if swallowed. mists. Do dusts or not breathe after handling. Washthoroughly hands prot clothing/eye gloves/protective Wear protective Skin corrosion / irritation: irritation: / Skin corrosion (oral): Toxicity Acute (inhalation): Toxicity Acute protection. area. well-ventilated outdoors in a or Use only usingthis product. when smoke or Do notdrink eat, poison center or doctor if you feel unwell. feel unwell. you if center poison doctor or (or hair): ONIF SKIN Wash contam water/shower. with clothing. skin Rinse before reuse. INHALED: IF IF IN IF EYES: C do. to if easy present and contact Remove lenses, (Supersedes previous revisions)

SECTION 2:SECTION HAZARD(S) IDENTIFICATION

Sodium Sulfate Sodium Sulfate 7757-82-6 7% Sodium Bisulfate 7681-38-1 93%

SECTION 3:SECTION COMPOSITION INFORMATION ON INGREDIENTS rd Statements RevisionDate: 01/01/2015

3.1 3.2 Ingredient No. CAS Wt.% Approx.

Statements Precautionary Haza SignalWord Symbol Hazard Category

HASA DRY ACID Safety Data Sheet (SDS No. 207) ith

own own g fire. al. ther ther erial erial itself ible, sweep ible, sweep ng and and ng rson. rson. er for er 15-20 Page of 3 9 oison control oison control fortreatment -20 minutes. minutes. -20 ce, then give give thence, w. nt advice. advice. nt nt advice. advice. nt 5 minutes, then then minutes, 5 f possible. possible. f treatment advice. treatment advice.

of gastric lavage. gastric lavage. of -9300 for emergency medical treatment medical for emergency -9300 alling a poison control center or doctor, or or center doctor, or control poison alling a

Sweep up or vacuum. Place in plastic bag for for dispos bag up orin plastic Place vacuum. Sweep If possible place in pool or spa water. If poss ornot water. spa If place in pool possible for disposal. plastic up,bag place in Not applicable. Not applicable. Not applicable. Not applicable. or allow water to get inside container. container. getto inside orwater allow Water may be used to cool containers and to knock d knock to and containers cool to may be used Water mat on Do notwater use fire in a vapors situation. Use any means suitable for extinguishing surroundin for extinguishing suitable means Use any Not applicable. Not applicable. Nonflammable. Nonflammable. Not explosive. Not explosive. Not applicable. Not applicable. In the event of a fire, wear full protective clothi full protective fire, wear a theIn of event o or pressure the demand facepiece in full operated pressure mode. positive NIOSH-approved self-contained breathing apparatus w apparatus breathing self-contained NIOSH-approved Decomposition product may include sulfur oxides. oxides. sulfur may include Decomposition product HOT LINE NUMBER HOT LINE NUMBER

NOTE NOTE TO PHYSICIAN

artificial respiration, preferably mouth-to-mouth i preferably artificial respiration, advice. minutes. minutes. continue rinsing eye. continue rinsing eye. center or center doctor.or for of 15 with plenty water skin immediately Rinse an or ambulan 911 call If is breathing, not person clothing. Take off contaminated freshperson to air. Move doctor or immediately a center control poison Call wat gently with and slowly open and eye rinse Hold swallo to glass of able person if water sip Have a firstthe if after present, contact Remove lenses, for treatme doctor or a center control poison Call for treatme doctor or a center control poison Call further for doctor or a center control poison Call a p by to so told do unless vomiting Do not induce pe mouth an to by unconscious give Do anything not • • • • • • • • • • • • •

Media:

SECTION 4:SECTION FIRST AID MEASURES

(Supersedes previous revisions) : SECTION 5:SECTION FIRE FIGHTING MEASURES

Temperature:

SECTION 6:SECTION ACCIDENTAL RELEASE MEASURES

Ignition - Extinguishing Extinguishing Small Spill: Large Spill: Explosion Hazards: Fire Special Remarks Auto Flash Point: Limits: Flammable Hazardous Decomposition Products: Fire Hazards: Flammability: IF SWALLOWED CLOTHING INHALED IF IF INIF EYES OR ONIF SKIN

information. information. Probable mucosal damage may contraindicate the use the may contraindicate damage mucosal Probable Have the product container or label with you when c you with label or thecontainer product Have 1-800-424 may also contact You for goingtreatment. RevisionDate: 01/01/2015

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HASA DRY ACID Safety Data Sheet (SDS No. 207) ved ved F. o

close inants inants

nd face face nd ndard ndard eating, eating, l. Wash l.

e e dust. Do dust. Do s, s, ld where ld where use to ) . Wear . sture. neering neering e, toe, imit imit C/120 o Page of 4 9 nt?p_table=standards&p_id=9992 n Table Z-1 Limits for Air Contaminants. for Table Limits Air Z-1 Contaminants. n limit, which is the same as the asis same the which limit, l, inorganic, or organic, not listed not organic, or l, inorganic,

total dust, total dust total 3 3 respirable fraction for nuisance dusts. fordusts. fraction nuisance respirable 3 10 10 mg/m Material is hygroscopic and will readily absorb moi readily is will hygroscopic and Material 49 above store Do not place. dry Storea cool in 5 5 mg/m dust respirator. respirator. dust In dusty atmospheres (>10 mg/m³), use a NIOSH-appro a use (>10 mg/m³), atmospheres In dusty Rubber gloves. Rubber 15 15 mg/m Ensure that eyewash stations and safety showers are showers stationssafety and that eyewash Ensure before chemical products, handling after thoroughly to the workstation location. Wash forearms a hands, location. theto workstation th and end the at of the lavatory using smoking and working period. controls to keep worker exposure to airborne contam toexposure keepairborne to controls worker Use only with adequate ventilation. Use process ventilation. with adequate Use only other or engi ventilation exhaust local enclosures, limits. statutory or recommended any below fountain and quick-drench facilities in work area. facilities area. in work quick-drench fountain and Use chemical safety goggles and/or a full face full shie goggles a and/or Use chemical safety eye wash Maintain is dusting possible. splashing or Wear impervious protective clothing, including boot protective Wear impervious appropriat as coveralls, or apron gloves, coat, lab prevent skin contact. Keep container tightly closed & upright when not in not closed when & upright tightly Keep container prevent leakage. not get in eyes, on skin or clothing. Wear OSHA Sta skin clothing. or on getnot in eyes, materia this to footwear impervious gloves, & apron Use only with adequate ventilation. Do not breathe breathe Do not ventilation. with adequate Use only Supplier Safety Equipment face full shield. Consult reuse. clothing before Contains no substances with occupational exposure l exposure occupational with no substances Contains

(Supersedes previous revisions)

SECTION 7:SECTION HANDLING AND STORAGE Protection

easures

M

Protection Skin Protection Hand Limit Value (TLV) (TLV) Limit Value Protection Eye Respiratory OSHA PNOR OSHA Threshold ACGIH

SECTION 8:SECTION EXPOSURE CONTROLS / PERSONAL PROTECTION http://www.osha.gov/pls/oshaweb/owadisp.show_docume CFR 1910.1000.CFR values. All inert or nuisance dusts, whether minera whether dusts, inert All nuisance or values. this by by covered are name substance specifically (PNOR) limit i Regulated Otherwise Not Particulates 8.4.3 8.4.4 Personal Protection 8.4.1 8.4.2 ( 8.3.1 8.3.2 Airborne Exposure Limits: Airborne Engineering Controls Engineering Hygiene Handling: Storage: RevisionDate: 01/01/2015

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HASA DRY ACID Safety Data Sheet (SDS No. 207)

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) 3

83 83 lb/ft (

3

Stable under normal use and storage conditions. conditions. and storage use normal Stable under No information available. No information available. Strong bases, calcium hypochlorite, chlorinated chlorinated hypochlorite, calcium Strong bases, NOT DO carbonate. sodium isocyanurates, and solutions chlorine of concentrated MIX or dry products. cleansers similar or bleach, ammonia Not sensitive. Not sensitive. DO NOT store dry product where exposed to exposed product dry where DO store NOT moist conditions. Not sensitive. Will not occur. Will occur. not Corrosive to metals. metals. toCorrosive 120.06 g/mole (anhydrous) (anhydrous) g/mole 120.06 No information available. Dry crystalline solid spherical shape beads. spherical shape solid beads. crystalline Dry toFresh pungent. toFresh pungent. [Conc. <1 (% w/w):5%] (350.6°F) 177°C No information available. No information available. Not pertinent. hazard. fire No specific explosion or No information available. No information available. water soluble: 67g/100g Partially No information available. (350.6°F) 177°C at Decomposes No specific fire or explosion hazard. hazard. fire No specific explosion or g/cm 1.28 No information available.

: /

: :

:

: octanol

)

- : n (

Specific Specific (Supersedes previous revisions) emperature:

lammability or lammability T :

emperature

F :

T & Boiling Range Boiling & SECTION 10:SECTION STABILITY AND REACTIVITY

:

Polymerization: : le Materials le oefficient: oefficient:

C ower ower

ressure L oint

/ P SECTION 9:SECTION PHYSICAL AND CHEMICAL PROPERTIES P

ignition itions of itions Instability: of -

ensitivity to Mechanical Impact Mechanical to ensitivity reezing point reezing S toDischarge Static Sensitivity Hazardous Incompatib Corrosivity: Stability: Temperature: Instability Cond water): Auto Decomposition Weight: Molecular Viscosity: Vapor Vapor Vapor Density: ( Relative Density Gravity): Water: in Solubility Partition Boiling Boiling Point Flash Rate: Evaporation (solid, gas Flammability Upper Limits: Explosive Appearance Odor: Odor Threshold: pH: : F

RevisionDate: 01/01/2015

10.8 10.5 10.6 10.7 10.3 10.4 10.1 10.2 9.20 9.17 9.18 9.19 9.15 9.16 9.13 9.14 9.11 9.12 9.8 9.8 9.9 9.10 9.5 9.5 9.6 9.7 9.2 9.2 9.3 9.4 9.1 9.1

HASA DRY ACID Safety Data Sheet (SDS No. 207)

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: This product readily dissolves formtoin water dissolves readily This product greater (by or A 0.05% solution. a weak acid be likely product will this of weight) solution life. harmful aquatic to acutely No No information available. No No information available. No information available. No information available.

Nose and eyes. Unlikely ingested. ingested. Unlikely Nose and eyes. Not Listed. Not Listed. Not Listed. Not Listed. 2,800 mg/kg (rat) mg/kg 2,800(rat) irritation. eye Causes serious skin irritation. may cause exposure Prolonged pain, watering may include symptoms Adverse and redness. tract respiratory may include symptoms Adverse irritationcoughing. and No specific data. No specific data. Not Listed. Small amounts (tablespoonful) swallowed are not (tablespoonful) swallowed amounts Small large swallowing however, toinjury; likely cause tract. digestive may irritate burn or amounts May cause erosion of teeth. teeth. cause erosion of May Inhalation of dust may irritate nose, throat and/or throat may irritate nose, Inhalation dust of lungs.

): 50

the Products of of Products the (LD

(Supersedes previous revisions)

AnnualReport on

: th Effects (Human Risk (Human Effects Risk

(AmericanConference of

SECTION 12:SECTION ECOLOGICAL INFORMATION (OccupationalSafety &

(International Agency for

(NationalToxicological SECTION 11:SECTION TOXICOLOGICAL INFORMATION : emarks on emarks Health Health Program6 GovernmentalIndustrial Hygienists): ACGIH ACGIH OSHA Skin: NTP IARC Eyes: Inhalation: Ingestion: Ingestion Skin: Eyes: Inhalation: Researchon Cancer Monographs, 1-100): V. Health Administration): Carcinogens): exposure exposure signs/symptoms

- Special R Biodegradation: BOD and COD: BOD and COD: Products Biodegradation: of ofof the Products Toxicity Biodegradation: Ecotoxicity 11.6.3 11.6.4 11.5.4 Potential] Information [Cancer Carcinogenic 11.6.1 11.6.2 Over 11.5.1 11.5.2 11.5.3 11.3.3 11.3.4 Chronic Assessment): Routes of Routes Entry: of Oral Acute Toxicity Health Acute Effects: 11.3.1 11.3.2

RevisionDate: 01/01/2015

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HASA DRY ACID Safety Data Sheet (SDS No. 207)

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zed wherever possible. This material and its and Thismaterial its possible. zed wherever pty containers or liners may retain some retain some may liners or containers pty able products via a licensed waste disposal products able disposal a waste licensed via gional, national and local laws and regulations. laws and gional,local national

disposal of spilled material and runoff and and and runoff material spilled of disposal Not regulated. Not regulated. Not regulated. Not regulated. Not regulated.

) (Supersedes previous revisions)

SECTION 14:SECTION TRANSPORT INFORMATION (Transportationof SECTION 13:SECTION DISPOSAL CONSIDERATIONS :

(InternationalCivil Aviation Code: Code: (International MaritimeDangerous

: (International MaritimeOrganization DangerousGoods) Organization): Goods) ICAO IMO IMDG US D.O.T. US TDG Canada

RevisionDate: 01/01/2015

14.3 14.4 14.1 14.2

The generation of waste should be avoided minimi or be should avoided generation waste of The

container must be disposed of in a safe way. Avoid way. safe in a of disposed must containerbe Em sewers. drains and soil, waterways, contact with product residues. Dispose of surplus and non-recycl surplus of product Dispose residues. contractor. re applicable be should with in accordance Disposal HASA DRY ACID Safety Data Sheet (SDS No. 207)

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This product is not subject to to subject Thisis not product

Acute: Yes Acute: Chronic:Yes Fire: No Pressure: No No Reactivity: This material is considered IRRITANT under IRRITANT under is Thismaterial considered 1910.1200) CFR (29 Standard the HAZCOM No results for this product search in WHMIS forin search this No product results Classifications. Oninventory orin compliance with inventory. Oninventory orin compliance with inventory. Registration No: 10897-50010-AA Registration 10897-50010-AA No: Not regulated. components All of this product are on the DSL. R34(causes burns) R41(risk of serious eye damage); S24/25: Avoidcontact with skinand eyes. S26:case In ofcontact witheyesrinse immediately plenty with of water and seek medicaladvice. S36/37/39:Wear suitable protective clothing, gloves, and eye/faceprotection. Oninventory orin compliance with inventory. Oninventory orin compliance with inventory. Oninventory orin compliance with inventory. Not regulated under FIFRA standard. standard. FIFRA Not under regulated Not regulated. 68.130) CFR (40 Not regulated. Not listed. Not regulated under PSM Standard CFR (29 PSM Not under regulated 1910.119) All components are listed or exempted. exempted. or components listed are All TSCA 12(b): export notification. export notification.

Title III: III: Title

(Hazard

(Comprehensive

(ProcessSafety

(FederalInsecticide, (SuperfundAmendments (ToxicSubstance Control

(Supersedes previous revisions) (RiskManagement Plan)

(SafeDrinking Water and Toxic (CaliforniaAccidental Release (WorkplaceHazardous Materials

(PhilippineInventory of (Inventory ofExisting Chemical (New Zealand (New Inventory of HAZCOM PSM (CaliforniaDepartment of SECTION 15:SECTION REGULATORY INFORMATION

(Korean ExistingChemicals (AustralianInventory of Chemical : FIFRA FIFRA (DomesticSubstances List) )

ARP Fungicideand Rodenticide Act) and Reauthorization and Act) Chemicals and ChemicalSubstances) Substancesin China) Act) EnvironmentalResponse, Compensation, and Liability Act) Chemicals) EnforcementAct of 1986) KECI KECI PICCS IECSC NZIoC AICS AICS Risk Phrase: Phrases: Safety Cal WHMIS DSL EPA RMP EPA Prop 65 CDPR EPA SARA SARA EPA EPA TSCA TSCA EPA CERCLA EPA OSHA OSHA OSHA EPA Inventory) PreventionProgram) Management) Information System) Communication) Pesticide Regulation) Substances) Section 311/312

tate of California Regulations: tate California of 15.5.2 15.5.3 15.5.4 15.5.5 International Inventory: International 15.5.1 DSCL (EEC DSCL 15.4.1 15.4.2 15.2.3 Regulations Canada 15.3.1 15.3.2 15.1.7 S 15.2.1 15.2.2 15.1.6 15.1.4 15.1.5 U.S. Regulations: 15.1.1 15.1.2 15.1.3

RevisionDate: 01/01/2015

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15.4 15.3 15.2

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HASA DRY ACID Safety Data Sheet (SDS No. 207)

. .

2004 2006

– – erformance, erformance, Page of 9 9

ANSI Z400.1 ANSI Z129.1 ANSI

n n 8

1 0 0 1 0 0 Sectio Complies with with Complies with Complies

Irritant.

uaranteed, was prepared by competent was by prepared uaranteed, best of our knowledge and belief. NO NO and belief. our of best knowledge patents or violate any Federal, State, and/or State, Federal, any violate or patents will be happy to respond to questions questions to be to happy respond will

may involve additional safety and/or may involve responsibility of the customer. No suggestions suggestions No customer. theof responsibility

ation available in the public domain. domain. in the public ation available nd use procedures. The safe handling, storage, Thestorage, safe handling, nd use procedures. by been prepared has Sheet ThisData tc. Safety

- - ntended as or to be construed as construed be to or as ntended ): use, handling, transportation, and storage. storage. and transportation, handling, use,

express or implied, is made regarding the product the p regarding made implied, is or express

SECTION 16:SECTION OTHER INFORMATION (Supersedes previous revisions)

(NationalFire Protection Association):

(HazardousMaterials Identification System): Hazardous Industrial Chemicals Chemicals Hazardous Industrial MSDS-Preparation: Chemicals Hazardous Industrial Precautionary Labeling: HEALTH FLAMMABILITY REACTIVITY SPECIAL HEALTH FLAMMABILITY HAZARD PHYSICAL PROTECTION: PERSONAL AmericanNational StandardsInstitute III (

Building Code [1997 edition]: [1997 edition]: Building Code ANSI ANSI 16.3.1 16.3.2 International / Code International Fire NFPA 704 NFPA 16.2.1 16.2.2 16.2.3 16.2.4 HMIS 16.1.1 16.1.2 16.1.3 16.1.4

RevisionDate: 01/01/2015

product stability, or as to any otherof any condition to as product or stability,

Customer use, handling, transportation, and and storage transportation, Customer handling, use, personnel Our technical performance considerations. Note: The information contained herein, while g not herein, contained Note:information The

16.4 theto accurate true and is and technical personnel GUARANTEE, OR WARRANTY a transportation, storage, regarding handling, safe the sole remain procedures and use transportation, use i are transportation, or for storage, handling, existing any may infringe on which recommendations e standard, ordinance, and/or regulation, law local reportsother inform test and from Inc. HASA, staff

16.3 16.2

16.1