NJ. Department of Environmental Protectipn
Worker and Community Right to Know
Basis and Background
with Environmental Hazardous Substance List
Glossary References
April 1984 BASIS AND BACKGROUND DOCUMENT FOR N.J.A.C. 7:1G-1, et seq. DEVELOPED PURSUANT TO THE NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW ACT . (P.L. 1983, C.315, C.34:5A-1 et seq.)
March 1984
N.J. Department of Environmental Protection - Office of Science & Research Worker and Community Right to Know Act
Proposed Designation of Environmental Hazardous Subst.ances and Hazardous Materials
Prop'osed Environmental Survey and Emergency Services Information Survey
Basis and Background Document
New Jersey Eiepartment of Environmental Protection
March 1984 TABLE OF CONTENTS
INTRODUCTION
RIGHT TO KNOW PROPOSAL NOTICE
APPENDICES
I. Summary of the Act
II. Description of Standard Industrial Classifications (SIC) Codes for Employees Covered by the Act
III. Development of the Environmental Hazardous Substance List
IV. The Environmental Hazardous Substance List:
A Breakdown by Chemical Category of Usage, Health Effects, Environmental Parameters, and Regulations
V. Diagram of the Selection Process Used in Developing the Environmental Hazardous Substance List
VI. The Environmental Survey - Part I and Instructions
VII. The Emergency Services Information (ESI) Survey Form
VIII. The Environmental Survey - Part II
I.. The United States Department of Transportation Optional Materials Table
.. Sections of the Worker and Community Right to Know Act Pertaining to the Department of Environmental Protection INTRODUCTION
The New Jersey Department of Environmental Protection (The Department) is proposing to adopt a new rule, N.J.A.C. 7:1G, by which it will carry out its responsibilities under the Worker and Community Right to Know Act, P.L. 1983 c.315, N.J.S.A. 34:5A-1 et seq. Specifically, the Department is proposing to designate an Environmental Hazardous Substance List for use in completing the Environmental Survey required by the Act, designate a Hazardous Materials List: for the reporting of substances which can become safety hazards in an emergency, and establish requirements for the completion of an Emergency Survey Information (ESI) Survey for the reporting of substances on the Hazardous Materials List.
Detailed information concerning the development of N.J.A.C. 7:1G is contained in the Notice of Proposal which appears in the New Jersey Register (April 2, 1984). The Notice of Proposal includes a copy of the proposed new rule; advance notice of the procedure the Department intends to follow concerning distribution of the Environmental Survey and the Emergency docu mented scientific evidence gathered during the development of the Environmental Hazardous Substance List.
Public Hearings on the proposed new rule will be held. The times and locations are listed in the Right To Know Proposal Notice which follows.
Interested persons may submit, in writing, data, views, or arguments relevant to the proposed new rule on or before May 9, 1984. These submissions and inquiries about submissions and responses, should be addressed to:
Dr. Judith Louis N.J. Department of Environmental Protection Office of Science and Research CN 402 Trenton, New Jersey 08625 ENVIRONMENTAL PROTECTION PROPOSALS
At the close of the period for comments, the Department of Environmental Protection may adopt this proposal, with any minor changes not in violation of the rulemaking procedures at N.J.A.C. 1:30-3.5. Upon adoption of these rules, a notice of the adoption shall be published in the Register. The adopted rules shall become effective upon publication of that notice of adoption in the Register. Copies of this notice and background material and refer ence sources, may be obtained from the Department and will be available for inspection until May 3, 1984, during regular operating hours at: State Library Reference Department New Jersey State Library 185 West State Street Trenton, New Jersey 08625
(a) County Libraries OFFICE OF SCIENCE AND RESEARCH County Municipality Burlington Mount Holly Camden Echelon Urban Worker and Community Right to Know Act Complex, Voorhees Environmental Hazardous Substance List Cape May Cape May Court House Cumberland Bridgeton Hunterdon Flemington Proposed New Rule: N.J.A.C. 7:lG-l,-2,-3, Monmouth Freehold and -4 and -5 Morris Whippany Ocean Toms River Authorized by: Robert E. Hughey, Commissioner, De Somerset Somerville partment of Environmental Protection. Sussex Newton Authority: N.J.S.A. 34:5A-1 et seq. and N.J.S.A. Public Libraries 13-.1D-9. Bloomfield, Cherry Hill, East Brunswick, East Orange, DEP Docket Number: 012-84-03. Elizabeth, Hackensack, Jersey City, Linden, New Brunswick, Newark, Paterson, Phillipsburg, Plainfield, Ridgewood, Sa Public hearings concerning this proposed new rule will be lem, Trenton, Wayne, Woodbridge, and Woodbury. held at the following times and locations: This proposal is known as PRN 1984-180. . April 30, 1984 2:00 to 5:00 P.M. and 7:00 P.M. until The agency proposal follows: the closing of testimony Summary Labor Education Center By this notice, the Department of Environmental Protec Cook Campus tion (hereinafter referred to as "Department", as appropri Rutgers, The State University ate), is proposing several actions pursuant to the Worker and Ryder Lane Community Right to Know Act, P.L. 1983 c.315, N.J.S.A. New Brunswick, New Jersey 34:5A-1 et seq. (hereinafter referred to as the "Act"): May 2, 1984 1. The Department is proposing for adoption a new rule, 2:00 to 5:00 P.M. and 7:00 until the N.J.A.C. 7:1G, by which it would designate an "Environ closing of testimony mental Hazardous Substance List" for use in completing the The Theatre in the Fine Arts Building Environmental Survey, designate a "Hazardous Materials College of Arts and Sciences List", and establish requirements for the completion of an Rutgers, The State University "Emergency Services Information (ESI) Survey" about Haz Fourth and Linden Streets ardous Materials present at specified facilities in the State; Camden, New Jersey 2. The Department is providing the public with advance notice of the procedure it intends to follow concerning distri Interested persons may submit in writing, data, views, or bution of the "Environmental Survey" about "Environmen arguments relevant to the proposed new rule on or before tal Hazardous Substances" and the ESI Survey; and May 9, 1984. These submissions and inquiries about submis 3. The Department is providing the public with informa sions and responses, should be addressed to: tion concerning the documented scientific evidence gathered Dr. Judith Louis during the development of the Environmental Hazardous New Jersey Department of Environmental Substance List. Protection Materials available for inspection at the above locations Office of Science and Research include copies of the Act and survey forms, additional infor CN402 mation on the development of the Environmental Hazardous Trenton, New Jersey 08625 Substance List, and a listing of Standard Industrial Classifica (609) 984-6070 tion (SIC) codes.
(CITE 16 N.J.R. 646) NEW JERSEY REGISTER. MONDAY, APRIL 2, 1984 - 2 -
PROPOSALS ENVIRONMENTAL PROTECTION
I. Summary of the Act ronmental Survey or the Department of Health's workplace On August 29, 1983, Governor Thomas H. Kean signed the survey, except for the identity of a special health hazard Worker and Community Right to Know Act (P.L. 1983 substance or information concerning emissions. The Depart c.315). The Act becomes effective on August 29, 1984. It ment of Environmental Protection and the Department of establishes a "comprehensive program for the disclosure of Health intend to jointly propose regulations concerning trade information about hazardous substances in the workplace and secrets in the spring of 1984. Additional regulations may be the community", and provides "a procedure whereby resi proposed concerning trade secret claims for information re dents of the State may gain access to this information." quired to be disclosed on the Emergency Services Information (Section 2 of the Act.) The four departments of State govern (ESI) Survey. ment responsible for administering the Act are the Depart ments of Environmental Protection, Health, Labor, and III. The Environmental Survey Treasury. The Department will conduct the Environmental Survey by The Department of Health is required to develop two haz distributing survey forms to employers. Due to the extensive ardous substance lists: a workplace hazardous substance list nature of the information required, the Department will con and a special health hazardous substance list. The latter list duct the Environmental Survey by way of a short form (Part contains particularly dangerous substances for which no trade I) and a long form (Part II). Part I will ask the employer to secret claims will be allowed. The Department of Health is enter the code for a response to four (4) questions about each further required to develop a workplace survey to assist em Environmental Hazardous Substance present at the facility. ployers in reporting the hazardous substances in use at their Part II will require employers to furnish detailed information facilities. In addition, the Department of Health is required to and data for over 22 questions on each Environmental Haz send employers fact sheets for each hazardous substance iden ardous Substance. All employers will be sent the short form, tified on a completed survey. and selected employers will receive the long form. The Department of Labor is responsible for the distribution While the Act requires the Department to send an Environ of the Workplace Survey to employers, investigation of em mental Survey to employers, it does not require the Depart ployee complaints, and assessment of fees. ment to send a survey to every employer. The Act provides: The Act establishes a Worker and Community Right to "Within five days of the effective date of this act (that is by Know Fund in the Department of Treasury. Fees assessed on September 5, 1984) the Department of Environmental Protec employers will be deposited in the Fund and used for the tion shall transmit an environmental survey to each employer administration of the Act. who(se) business activities, according to criteria developed by The Department of Environmental Protection is required to the department, warrant the reporting of the information develop an Environmental Hazardous Substance List. The required on the environmental survey. Trie department may Act also requires the Department to prepare and distribute an transmit an environmental survey to every employer." (Sec Environmental Survey to those employers it determines tion 6(b) of the Act, Material in parentheses added.) should comply with the Act. The Act applies to employers having a Standard Industrial Part I "short form" The Department proposes to begin a Classification (SIC) code within Major Group Numbers 20- phased distribution of the Environmental Survey. Beginning 39, 46-49, 51, 75, 76, 80, 82 and 84 (hereinafter referred to as September 5, 1984, the "short form" (Part I) Environmental "employer" or "employers"). Survey will be sent to all employers at a rate of approximately 10,000 per month. Since the master file of employers supplied Employers are required to: by the Department of Labor contains approximately 40,000 1) Report to the Department of Health those hazardous employers, the Department anticipates it will complete distri substances present at their places of business; bution of Part I in four months. 2) Maintain a file of basic safety information (supplied by Employers will be required to complete the following infor the Department of Health) about these hazardous substances mation on Part I: the names of the Environmental Hazardous for their employee's use; Substances present at the facility, the range of the maximum 3) Provide their employees with education and training on inventory quantity of each Environmental Hazardous Sub how to handle these substances; stance, the unit of measure, the major method of storage or 4) Label containers containing hazardous substances type of storage container and whether the substance is present within 18 months, and all containers within three years, with in a mixture. the chemical name of their contents; Employers will be required to transmit a copy of the com 5) Disclose to the Department of Environmental Protection pleted Part I form to the Department of Environmental Pro basic information concerning the storage, treatment, and tection and to the county health department (or county clerk emission into the environment of hazardous substances. if there is no health department). The Department of Environ All disclosed information on hazardous substances will be mental Protection intends to supply the employer with the available to employees at the workplace. Members of the appropriate county address. Employer compliance will be re community may obtain this information from county health quired within 90 days of receipt of a form from the Depart departments, and from the State Department of Health and ment. Department of Environmental Protection. Local police and fire departments will also receive information on Hazardous Part II "long form" The Department proposes to select Materials to help them plan for and respond to emergencies employers whose business activities warrant complete report involving hazardous substances. ing after a review of the information provided in Part I, however, the Department will develop a subset of employers II. Trade Secrets to receive the Part II form at an earlier date based on the The Act allows employers to protect Ieg:timate proprietary following considerations: Whether the employer is a major information by allowing them to make a trade secret claim hazardous waste generator, whether the employer is a major regarding any information required to be disclosed in an Envi producer of Environmental Hazardous Substances based on
NEW JERSEY REGISTER. MONDAY, APRIL 2. 1984 (CITE 16 N.J.R. 647) - 3 -
ENVIRONMENTAL PROTECTION PROPOSALS information reported on the Industrial Survey under approximate range of the maximum inventory, the unit of N.J.A.C. 7:1F, Standard Industrial Classification (SIC) code. measure, the major method of storage or type of storage Department enforcement investigations, proximity to envi container, and whether the material is present in a mixture. ronmentally sensitive areas, population density in vicinity of By limiting the requested information on Hazardous Mate facility, facilities which did not respond to the Industrial rials, the Department will be able to fulfill the legislative Survey, areas under public health investigations, number of intent without requiring employers to provide detailed envi employees at a facility, areas with a high incidence of disease, ronmental release information on substances not necessarily and a determination that such information would enable the deemed to be environmental hazards. Department to carry out its responsibilities under federal and Employers will be required to transmit a completed copy of State law. the completed ESI Survey to the local fire department and the In order to enable employers to report the use and environ local police department and to the Department of Environ mental release of Environmental Hazardous Substances at mental Protection. Employer compliance will be required their facilities, the Department will use a printed Part II "long within 90 days of receipt of a form from the Department. form". The Act requires that information on the Environ V. The Hazardous Materials List mental Survey include, but not be limited to twelve categories: One of the major purposes of the Act is to provide local 1. The chemical name and Chemical Abstracts Service health, fire, police, safety, and other government officials number of the environmental hazardous substance; with detailed information about hazardous substances used 2. A description of the use of the environmental hazardous and stored in their communities so that they can respond to substance at the facility; emergencies and enforce compliance with applicable laws and 3. The quantity of the environmental hazardous substance regulations. There are numerous substances with may pose produced at the facility; problems for emergency response personnel, but which are 4. The quantity of the environmental hazardous substance not likely to be environmental health hazards in non-emer brought into the facility; gency situations. 5. The quantity of the environmental hazardous substance In order to gather information on these substances, the consumed at the facility; Department is proposing regulations which establish a list of 6. The quantity of the environmental hazardous substance Hazardous Materials in N.J.A.C. 7:lG-4, as distinct from shipped out of the facility as or in products; Environmental Hazardous Substances in N.J.A.C. 7:lG-2. 7. The maximum inventory of the environmental hazard The Department further proposes a rule to require the report ous substance stored at the facility, the methods of storage, ing of Hazardous Materials on a separate survey form - the and the frequency and methods of transfer; Emergency Services Information (ESI) Survey, N.J.A.C. 8. The total stack or point-source emissions of the environ 7:lG-5. mental hazardous substance; For the purpose of N.J.A.C. 7:lG-4 and -5, the Depart 9. The total estimated fugitive or non point-source emis ment proposes to define Hazardous Materials as those sub sions of the environmental hazardous substance; stances listed by the United States Department of Transporta 10. The total discharge of the environmental hazardous tion (USDOT) on the Optional Materials Table in Title 49 of substance into the surface or groundwater, the treatment the Code of Federal Regulations, Part 172.102, as amended methods, and the raw wastewater volume and loadings; by publication in the Federal Register, 48 Fed. Reg. Vor. 48, 11. The total discharge of the environmental hazardous No. 211, pp. 50234 - 50279 (Oct. 31, 1983). The Department substance into publicly owned treatment works; of Environmental Protection proposes to adopt the USDOT 12. The quantity and methods of disposal, of any wastes list, as amended, by reference. containing an environmental hazardous substance, the Amendments by the USDOT to its above-cited list shall method of on-site storage of these wastes, the location or become amendments to the Department of Environmental locations of the final disposal site for these wastes, and the Protection's Hazardous Materials list upon publication of a identity of the "hauler of the wastes." (Section 3(k) of the notice of such amendment in the New Jersey Register. Any Act.) other amendments to the Department of Environmental Pro Employers will be required to transmit a copy of the com tection Hazardous Materials list will be in accordance with the pleted "long form" to the Department and to the county notice and comment rulemaking requirements of the Admin health department (or county clerk if there is no health de istrative Procedure Act. partment). The Department of Environmental Protection in The Worker and Community Right to Know Act contem tends to supply the employer with the appropriate county plates that there will be a periodic revision to the Environmen address. Employer compliance will be required within 90 days tal Hazardous Substance List. It establishes a Right to Know of receipt of a form from the Department. The Department Advisory Council which shall advise the Department on revi will attempt to provide assistance, as requested. sion to such list. The Department's future determinations on whether to add substances as Environmental Hazardous Sub IV. Emergency Services Information (ESI) Survey stances will be based, in part, on the level of use of substances The Department will require each employer to complete a in the State. As a method of obtaining this use information, separate survey, called an Emergency Services Information the Department will evaluate information reported on the (ESI) Survey, about Hazardous Materials present at his facili Hazardous Materials at facilities throughout the State. ties. Since the extent of the safety risk posed by these mate rials is related to the quantity of the substance and the type of VI. Environmental Hazardous Substances List container, the Department will require the following informa The Act directs the Department of Environmental Protec tion: tion to develop an Environmental Hazardous Substance List The name of the Hazardous Material and its corresponding which: "shall include, but not be limited to, substances used, United Nations (U.N.) number, the United States Department manufactured, stored, packaged, repackaged, or disposed of of Transportation designated hazard class of the material, the or released into the environment of the State which, in the
(CITE 16 N.J.R. 648) NEW JERSEY REGISTER, MONDAY. APRIL :. 1984 - 4 -
PROPOSALS ENVIRONMENTAL PROTECTION department's determination, may be linked to the incidence of 2. Human-Suspect* - Sufficient epidemiological evidence, cancer; genetic mutations; physiological malfunctions, includ which indicates that a causal interpretation is credible, but ing malfunctions in reproduction; and other diseases; or that alternative explanations, such as chance, bias or uncer which, by virtue of their physical properties, may pose a tainty due to multiple influences, could not adequately be threat to the public health and safety. The department shall excluded. base the environmental hazardous substance list on the list of 3. Animal* - Sufficient evidence of carcinogenicity, which substances developed and used by the department for the indicates that there is an increased incidence of malignant purposes of the Industrial Survey Project, established pursu tumors: (a) in multiple species or strains; or (b) in multiple ant to P.L. 1970, c.33 (C.13D-1 et seq.) and P.L. 1977, c.74 experiments (preferably with different dose levels); or (c) to (C.58:10A-1 et seq.), and may include other substances which an unusual degree with regard to incidence, site or type of the department, based on documented scientific evidence de tumor, or age at onset. Additional evidence may be provided termines pose a threat to the public health a.nd safety." (Sec by data on dose-response effects. tion 4(a) of the Act.) 4. Animal-Suspect* - Limited evidence of carcinogenicity, The Department proposes to include 153 substances on the which means that the data suggest a carcinogenic effect but Environmental Hazardous Substance List; 97 were retained are limited because: (a) the studies involve a single species, from the Selected Substances List of the Industrial Survey strain, or experiment; or (b) the experiments are restricted by Project and 56 other substances were add.ed which pose a inadequate dosage levels, inadequate duration of exposure to potential threat to public health and safety. the agent, inadequate period of follow-up, poor survival, too The Department established the following criteria to be few animals, or inadequate reporting; or (c) the neoplasms used in developing the Environmental Hazardous Substance produced often occur spontaneously and, in the past have List and determined that it would include substances which been difficult to classify as malignant based on tissue charac met both criteria. teristics alone. Criteria 1: Evidence of a significant rate of use, produc 5. Animal-Cocarcinogen - A cocarcinogen increases the tion, or importation in New Jersey or the United States, The overall carcinogenic process when administered with the car Department considered 10,000 pounds per year in the State or cinogen. the country to be significant; and 6. Animal-Promoter - A promoter increases the tumori- Criteria 2: Evidence of at least one of the following health genic response when administered after the carcinogen. or environmental effects: carcinogenicity, t>;ratogenicity, mu- * Derived from IARC Monographs of the evaluation of the tagenicity, other chronic toxic effects, acute toxicity, persist Carcinogenic Risk of Chemicals to Humans, Supplement 4, ence, or ability to bioaccumulate. International Agency for Research on Cancer, World Health The Department reviewed documented scientific evidence in Organization, October, 1982. order to determine which substances would meet the above criteria. The Department considered the following to be docu C. Mutagenic Evidence mented scientific evidence: technical information appearing in 1. In vivo - Mammalian - Alteration of the genetic material the available literature, MEDLARS computerized databases, of a live mammal following exposure. the New Jersey Industrial Survey Project, a.nd data submitted 2. In vivo - Other - Alteration of the genetic material of a and collected by other government agencies. live non-mammalian organism following exposure. The Department established standards for use in determin 3. Host-mediated assay - Alteration of the genetic material ing whether a candidate substance met the above criteria. in indicator cells (e.g., bacteria, mammalian, human white These standards were established after reviewing documented blood cells) implanted in a host animal which is treated with scientific evidence. These standards or ''categories" were the test agent and then acts as the source of chemical biotrans- found to be widely accepted in the scientific community. formation. What follows is a summary of categories used in evaluating 4. In vitro - Mammalian cell - Alteration of the genetic candidate substances. The categories (A through L) are not material in cultured mammalian cells. arranged in any order of priority. Within each category, how 5. In vitro - Microorganisms - Alteration of the genetic ever, the Department lists subcategories in order of impor material in cultured microorganisms (e.g. bacteria, yeast). tance. 6. Chromosomal aberrations - Deviations from normal Immediately following the table of "categories", is an ex chromosomal structure, including breaks, gaps, rearrange tensive summary of the Department's basis for proposing ments and fragments, sister chromatid exchange and change Environmental Hazardous Substances. Tie table should be in chromosome number. Only in vivo experiments were con referred to in examining this summary. sidered under this category. D. Teratogenic Evidence - A teratogen is any substance that VII. Environmental Hazardous Substance List - Categories can cause a structural, biochemical, or functional abnormal A. Production, Use, and Imports ity in the developing fetus. 1. Substantial - Greater than or equal to 1 million Ibs/yr. 1. Human - Epidemiological study with statistical valida 2. Moderate - Greater than or equal to 10 thousand Ibs/yr tion. and less than 1 million Ibs/yr. 2. Animal - Teratogenic effects observed in 2 species - 1 3. Minor - Greater than or equal to 1000 Ibs/yr and less rodent and 1 non-rodent than 10 thousand Ibs/yr. 3. Animal - Suspected - Teratogenic effects observed in 1 4. Insignificant - Less than 1000 Ibs/yi. species and/or at high doses. B. Carcinogenic Evidence E. Embryotoxicity - An embryotoxic substance is one which 1. Human* - Sufficient epidemiologkial evidence, which can cross the placenta and exert a damaging effect on the indicates that there is a causal relationship between the sub developing embryo resulting in either stillbirth or reduced stance and human cancer. birth weight.
NE\V JERSEY REGISTER. MONDAY, APRIL 2, 1984 (CITE 16 N.J.R. 649) - 5 -
ENVIRONMENTAL PROTECTION PROPOSALS
F. Fertility and other reproductive effects - Includes steril ity, reduced number of offspring, reduced sperm function and counts, impotence and reduced libido, menstrual effects, spontaneous abortions, absorption of the early embryo by the ^ s. \t ID I'HLi JKIDE " body, premature births, and changes in sex ratio. G. Other Chronic Health Effects - Includes neurotoxicity impairment of hemopoietic system, organ dysfunction, and Rer-JUied-Fsderai behavioral effects. Pn.
1. Frequent - Present in greater than or equal to 10% of all ulrt. samples. mammalian & mKTOorgani-.fi Regulated-Federal 2. Moderate - Present in greater than or equal to l^b and Proaiw:ion-,ubsiami;ii in LS less than 10% of all samples. '_ ,e-modcra!e in \J mammalian i. mn.n)organiMT 3. Infrequent - Present in less than 1% of all samples. Acme ioucii\-jquai[.. biou Rcaulaieil.Fedcral J. Bioaccumulation - Refers to the sorption and storage of Carenoaenn. evidence-animal the unchanged chemical by an organism. Muta^cmc evidence-m MUI inn MuOKenic evidence-in iiro 1. Known - Determined by the direct measurement of an mammalian & mi-.roi.irttjni-.ir organism. ALIPHATIC HVDROCA 2. Potential - Based on physiochemical parameters, such as Bmadiene U06-**-U> log octanol/water partition coefficient. MutagL'nic evidence-in viiro mi RcaulatoU-hcUeral K. Persistence - The tendency of a substance to remain in AMIDES Acci amide" Production A. j-.e-ni.inu m N) the environment and retain its physical, chemical, and func (60-35-5) Car^inogenii: e'-idenw-jnimai , Benzamide" tional characteristics without undergoing degradation or (55-:i-m transformation. It is measured by "half-life" which is the ANHYDRIDES Maleie anri>dndc' time required for a given concentration of a substance to be '108-31-6) Reaulaied-Federai Phthalie anfivdnde ProdUL-non-unkno>*n jmouni ni LS reduced by 50%. (85-44-4, 1. High - A half-life greater than 6 months. AROMATIC AMINES 2. Moderate - A half-life of from 48 hours to 6 months. Aniline- 3. Low - A half-life of less than 48 hours. 162-53-3) Cjrcmoiwnii: evidence-ammdi -u^re.i Regu Idled-Federal L. Regulated o-Anisidme lmpor:l-^ub^taIlC!al in LS (O-Mijthoxvdniiirui C-ircinojenic evidence animal 1. State 2. Federal ,90-04-0) HO R«gulamd-F«deral VIII. Summary of Findings for Candidate Substances 1134-29-2) p-Amsidine ien r Jdij (p-MetnoKwnilintM Regulated-Federal jMon ai Below is a summary of the Department's findings for each (iiM-W-l) HC1 of the candidate chemical substances considered for inclusion (20265-^-8) Bcruidine* Produciion and u^e-nonc in M on the Environmental Hazardous Substance List. The chemi («-r-5t cals reviewed were classified according to their chemical HC1 (14414-63--) Carcinogenic c group. Chemicals within a group, therefore, have similar :HC: Muugemc cvid
structures. These groups are arranged alphabetically, as are H-.SO, Rc-iulatcd-FeJeral chemicals within each group. Common synonyms are listed lfj"t-36-:i when applicable, and for some groups, the salts of certain 2-Bipfienviam chemicals have been included. In addition, the Chemical Ab stract Services (CAS) number is listed. The CAS number is a 4-CJiloro-m-phen^l- unique identifier for each chemical substance. For each candi enediamme date chemical substance, one of four proposed actions is listed. They are: 1. "Retain"- means a candidate is on the Selected Sub Resulaieu-Federal stances List, N.J.A.C. 7:1F, and is proposed as an Environ p-Cresidmc Production & imponi-suDsiannai m US Include mental Hazardous Substance.) i J-Metnyi-o-anisidtne) Carcinogenic evidence-animaJ 1120.71-8) Muiagemc evidence-m vitro 2. "Delete"- means a candidate is on the Selected Sub microoriamsms stances List and is not proposed as an Environmental Hazard ous Substance. 3. "Include"- means a candidate is not on the Selected mammaiian JL mi Substances List and is proposed as an Environmental Hazard Rcau idled-Federal ous Substance. ^,-t-Diammototuene* L--e-moderj:e n 4. Insufficient data for inclusion at this time. Compounds originally on the Selected Substances List are denoted by an asterisk (*).
(CITE 16 N.J.R. 650) NEW JERSEY REGISTER, MONDAY, APRIL 2. 1984 - 6 -
PROPOSALS ENVIRONMENTAL PROTECTION
Chemical iSvnonvmsi Proposed :C\S Numben Basis lor Proposed A;non iCAS Number! Basis for Proposed Acnon Action
Production A use none reported in^iiiciunt Jaia i N'J R«4I Reauiatea-Fcderai or n.-luston Jt Dejection m environmental meaia-frequem Hmh phoiocnemicai rcacnvnv Reauiated-HederaJ i9i-"Mi (one NJ producer liiied) :or inJuiion at Naphthalene" Production & use-substantial in NJ Retain Regulated-Federal 'his ;ime (91.20.3) Other chrome hcuiih effects !,3 -Dichlorobenzidine* Use-substantial m NJ Retam Detection m environmental media-moderate Carcinogenic evidence-animal Bioaccumulation-known :HCI Mmagenic evidence-in vitro Regulated-Federal 1612-83-91 microorganisms Styrene Production i imports-substantial m US Include Regulated-Federal (100-42-5) Carcinogenic evidence-animal suspect 3.3 -Dimethvlbcnzidme Imports-moderate in LS Include Mutagenic evidence-in vivo tmcct (O-Telidme) Carcinogenic evidenve-ammal suspect Mutagenic evidence-in vitro microorganisms 1119-93-") Mutagenic evidence-host mediated asiay Mutagenic evidence-Chromosomal aberra 2HC! Muiagemc evidence-m vitro tions [612-82-81 mammalian & microorganisms Detected in air-frequent Regulated-Federal High photocnemical reactivity 4,4 -Mettnlene Production-substantial in NJ Retain Regulated-Federal Carcinogenic evidence-animal Toluene" Production & use-subfianiial m NJ Retain tMOCA) Muiagentc evidence-in vitro H08-d8-3> Detection in environmental media-frequent (101-14 - 4) mammalian & microorganisms High photochemical reactivity Regulated-Federal Regulated-Federal 4,4 -Methylenebis- Production-substantial m LS Include Xylenes Production & imports-substantial in US Include (N,N-dimethyl) Carcinogenic evidence-animal suspect (1330-20-7) Detected in air-frcquem benzenamine Mutagenic evidence-host mediated as lav High photochemical reactivity ilOl-61-lJ Mutagenic evidence-in vuro Regulated-Federal microorganisms 8. AZO COMPOUNDS Production & imports-moderate m L5 Include SEE DYES-C 1 Solvent Idlow [ Carcinogenic evidence-animal (60-09-3) Mutagenic cvidence-m vuro Diazomethane Lse-no commercial m microorganisms (334-88-3) Carcmogenic evide-nct ammal suspect tor inclusion ai Regulated-Federal Regulated-Federal ihis time 1.5-Napnthalenc
NEW JERSEY REGISTER, MONDAY, APRIL 2, 1984 (CITE 16 N.J.R. 651) - 7 -
ENVIRONMENTAL PROTECTION PROPOSALS
r Proposed Action
intu
Reeulaied-Federa!
Ttfratoaenit ,'vidence-anirnal -.U-.CN;.'! Dele! i ReHulatea-Federal Dimethyl pnihaiato" Pnjdufiion-MiDstann.il in LS (I31-1I-?) L^e-moderate m \J Muuizenic e^idenuc-.n M;-O Teraioaenk svidence-animal suspcc: Regulaied-Federal ReHuiaicd-Feddrat Di-n-octvl phtnalate* Lse-iubMantiat in NJ Proiluciion-unkno^n amount in IS Teratoaemc evidence-ammai suspect uour \J producers listed) Bioaccumulation-Kno*n Cjivinoaenu: evidence-annual Regulated-Federal Mucagenic e\idence-in Mtro Methvlmethacrvlate P^oduclion (N. importvsubManual m L ISO-42-61 Mutagenic evidence-in vtiro nucroorw Production-moderate in \J Reaulated-FeJeral Carcinogenic evidence-animal -.uspect Production-suPsiantiai in LS (108-Of-*) Regulated-Federal Production-moderaie in \J Carcinogenic e\idence-animal suspect 13 ETHERS & LACTONES M EPOMDES Bis <:-chloroc!h>l} Lse-insigmncani m NJ Protiuction-substantui m IS ether* Carcinogenic evidence-animal suspect Mutaaenic e^dence-m vuro (Dichloroethvl ethen Mutagenn: eudencc-m \no insects microorijaniimv Ml l-44~i| Mutagemc eMdc,ii.e-in vitro Hegulatsd-Federai microorganisms P'ouuftion i iiie-noiu :n LS Reeulatea-Federal Production-none m LS Muiagenic evidence-in -.ivo insect Carcinogenic evidence-human Muiayenic <\id«;nce-nost meautea a»-,jv \1uia?enii; evidence-in vitro Mutagemc evidence-in vuro mtcroorganixns microoraanisms Rcguuted-Federal Ksguiated-Fvderal Produt-tion-none m LS Insuiticieni aata 8i>(2-chloro-l- Producuon-signit'k-ant m LS Rtfgulaied- Federal ior inclusion at meth\l«ri>l) other Muiagemc evidence-in vjiro :rm nme lOichloroisopropyl mic Eptcnlorohvdr Lsc-subiiantial m NJ Retain ether) Regulateo-Federal ll-Chloro-2.?- Carcinogenic evidence-animal 108-60-11 Muiawmc e\idence-in -.no insect ;-Cnlorc«tnv| v,n>l Production-unknown amount m LS Insutiiciem data Mutaaemc evidence-in mro ether Regulated-Federal for inclusion at 1110-75-8) Regulaied-Federal & S:ate Chloro-methvl methvi Eihvlene oxide Prjaua-on & i m ports--. ub« an nal rn LS eth«r Carcinogenic evidence-numan VT p nclusion Jt iE-01 (HT-JO-21 Carcinogenic evidence-animal p riis iime Muugenic evidence-m MVO Mutagenic evidence-in vuro mammalian i insect* \tuiauenic e%idence-in vitro Regulated-Federal mammalian i microorganisms Decabromodipnenyl Muugenic ^Mdence-Chromownal aoerra- jiidc' (Decabromobionenyi ether) U163-I9-5) Regulated-Federal 4,4 -Diammodipnenvl Imports-moaerate in LS Glycidaldehyde Production -none in US Insufficient data ether Carcinogenic evidence-animal (2.,3-Epoxypropanal) Carcinogenic evidence-animal suspect Tor inclusion at 1101-80-4) Mutagenic evidence-in Mtro (765-34-4) Muiagenic evidence-m vitro thu time microorganisms microorguiiims f ,4-Dio\anc" Production & use-moderate m LS Regu laced -Federal (123-91-1) Carcinogenic evidence-animal Proauaion-minor m LS Insuiticiem dau Regulated-Federal & Stale Mutagemc evidence-in Miro ior inclusion at beia-Propiolactone* Production-insignificant m LS propane) microorganisms Carcinogenic evidence-animal .5S6-H-S) Regulaied-Federal Mutagenic cvidcnce-m vuro Propvlene o\id<* LNe-subMannal m NJ mammalian & microorganism;. Carcinogenic evidence^animal suspect Regulated-Federal. Muiagenic cv1dence-in ^ivo msect Production 4. impons-suoManiial m L Mutagenic evidenoe-in v»ro Carcinogenic eMi3encc-animai (nicrooraanisms Mutagenic evidence-host mediated ass Rceulaced- Federal Prcducnon-moderate .n LS mammalian & microorgjnivrrn Carcinogenic jvidence-animai , aspect Reauiaied-Federal ^luiagenic evidence-in MVO insect T?irah>droiuran Production-onkno^n amoun; .n LS Murajenic evidence in \itro (THF) Regulated-Federal
Resuiated-Federal imimicieni jaia 14 HALOGENATED ALKANES BromoJorm* L-e-mmor in M Muugenic e\ijenc< Mutagenic svidence-m \itro microoraanums Xsiiuiaied-Federal Detection m environmental media-m Regulated-Federal P---itluc:icin-minor Carbon setracnionJe" Production &. use-moderate ;n NJ Carcmouenu evidence-animal EmDr>otoMciis Detection in environmental meJia-
ReBiiiated-Federal i State
L -e-suossantial .n NJ Care mmai Carcinogenic evidence-jn ,-n Mmagenii. evidence-in ^ivo i Detect-on -n environmental medi T.-raiOKemc jviuenuc-animai Regulated-Federal i State l.:-Dibromo- Prouucnun .* jse-none -nloroprop; IDBCP' R e^uiaied-Federal
(CITE 16 N.J.R. 652) NEW JERSEY REGISTER, MONDAY, APRIL 2, 1984 PROPOSALS ENVIROiNMENTAL PROTECTION
Chemical Chemical iSvnonvms) Proposed iSynonyms) Proposed tCAS Number) Basil p or Proposed Action Vuon iCAS Number) Basi^ for Prooo«ea Action Action
,s"ft8-"°'° Oelcte .E^v'cilej^rom^e) i jrc:nu«nw sv '^^11^1 a/' Carcinogenic ^idcnce-animdi mspeu EDB>
He\ucniorocvdopen- Produtnon A. a-e-nonu reportea
Dctecp.:on in environmental media- Reguuiea-Fedcral noderaie to Irequeni Teirai-hioroetnviene' L^'-iuostannai m NJ Retain Rt;uulaieu-FeUorai & State (Percfilorofinviene) Mutagemc evidence-in mro r<-r-4, Detection m environmenial rneilia mtcroorganitms moderate to frequent Detection in environmental media- Rsauidtcd-K'deral trequert l.i-Dichtoroetrtane Production <& use-none reported lnsu|tic;em Jata Reguiaicd-Fecleral i State l '5-34-3) Detection in environmental media- ror inclusion at Trichloroethvlene* Retain (-9-OL6I Ream at ed- Federal Mutagemc evidence-in vitro 1,; DichUToetnane" Pr^Juc; ton -moderate m NJ Retain microorganism^ n(>--,*-:i Deieuion in envirormental media- ' requent Mutagemc evidence-in MVO Reguiaied-Federal & State :nsects & plants Vmyl bromide* L^e-insisniiieant m NJ Delete Mutagenic evidence-in vitro (593-60-2) Muiagenic evidence-m vitro microorganisms microorganiimi Detection m environmental media- Regulated -Federal moderate to frequent Vinyl chloride" Lse-,ubsian(ial in NJ Retain R emulated- Federal &. State i" 5-0 l-4> Cjrcinogenic evidence-human Dichloromethjne" L-c-ubsiamialm NJ Retain Carcinogenic evtuence-jnimal 'Methviene ;.ilonde) Mutagenic evidence-in vivo msecti Mutaaenic cvidence-m \ivo insects r"-09^l Mutaaeniv evidence-in vitro microorganisms mammalian * microorganisms Detection in environmental media- Mutagenn. jviuence-Chromosonal aOerra- ; requent :ions Regulated- Federal &. State Embrvotoxicitv 1 .^-Dicniorocropane* Production-substantial m US Retain Detection m envronmemal media- l"H-S7-5i Mutagenic evidence-m vitro ("rcquent (airi microorganisms Re2Utatea-Fcdi;rai & State Detection in environmental media- V inylidene chloride* Lse-,niigniricant in NJ Delete infrequent (l.l-Dichioroetnvlencl Carcinogenic evidence-animal suspect Regulated -Federal & State (71-35-4) Mutagemc evidence-m vitro Ethyl chloride Production-substantial in US insufficient data microorganisms iChloroerhanet Detection in environmental media- lor inclusion at Detection in environmental media- (75-00-3) frequent (air) thin time -riodeMie io frequent Regulated-Federal Regulated-Federal i State Hexachloroethane" Uic-moderatc m NJ Retain 16. HAIOGENATED AROMATICS (6---MJ Carcinogenic evidence-animal fuspcct Benzal cMonue Production-subsaniiai in LS Include Regulated-Fed erat ifDichloromethyl). Carcinogenic evidence-animal suspect Methvl bromide' L ie-moderaie in NJ Delete benzene) Mutajjemc SMuence-m vitro (-4-83-9) Regulated-Federal & State (98-87-3) microorjamsms Meihvl chloride" Production 4 use-iubstantia! in NJ Delete Regulated- t-ederal 1 7-M7-1) Detection m environmental media- Benzotnchloride PnDducnon-ufasiantiai m LS Inuude requc-ni (airi ((Trichloromethvl)- Carcinogenic eviden^-e-anima; Regulated -Federal b«nzene) Muiagenic evidence-in vitro Methvl iodide Production- moderate in US Include (98-07-") microorganisms ,"4-)J8-4j Carcinogenic eviaence-ammal suspo:t Regulated- Federal Mutagenic evidence-in vitro Benzyl bromide Production-unknown amount m LS [nsulticient jata microorganisms ((Bromom«hyl)benzcne) Muiagenic evtdencc-m vitro tor inclusion at Regulated -Federal (i 00-39-0) microorganisms this time 1,1,2,2-Tetrachloro- Production-minor in NJ Retain Acute !oxi..!tv-anuatic biota Lse-moderate in NJ Regulated- Federal ("9-34-5) Carcinogenic evidence-animal suspei;t Benzyl chloride include Muiagenic evidence-in vitro ( ( C,h loromet n y 1 ) benzene I Carcinogenic evidence-animal suspect microorganisms (100-44-*) Mutagenic evidence-in vitro Teratogemc evidence-animal 'luspcct mammalian & microorganisms Detetlion in environmental media- Regulated -Federal infrequent to moderate Chlorobcnzenc* Production-moderate m NJ Retain Regulated -Federal & State ( 108-90-7) Lse-subsiannal in NJ 1,1.1-Trichloroethane' L'se-iubstantial in NJ Re;am Detection m environmental media- -Methvl ;hlorolorm) Mutagenic evidence-in vitro moderate :o frequent ri-55-6) nicroorganisms Bioaccumulaiion-poieniial Detection m environmental med:a- Persistence-high rsquem Reguiaieu-Fcderal Reguiated-Feceral & State H-Chloronaphthalene* Production i Use-none m LS Delete 1.1.2-Trichloroethanc* L-,e-moderate m NJ Retain 191-58--) Bioaccumuianon-poiemia! T9-00.5 1 R eg uiated- Federal 1 ,Z-Dichiorobenzene' Lse--.ubstantiai m NJ Retain m requent i 95- 50- II Bioatrcummation-potennal ReEUiateu-Federal Detection m environmental meUia- moderate to fuqucn: "5-69-4) Detection in environmental media- Per^isience-hign ^reauent lain Reuuiated-Feueral Rcguiaied-Feueral 1,3-DichloroBcnzcne" Production & use-none reported Deiete 15 HALOGENATED ALKENES (54l."3-h flioaixumulai ion-potent lal MKl .-hlonde' Lstf-moderatc m NJ Retain Persistence- nigh < t-Oioro-Z-propanei Carcinogenic ;udence-animal susptfi.'i Regulated -Federal 10-4)5-11 Mutagenic sviaence-m -itro 1,-t-Dichlorobenzcne* Rciam (1 06-46-") Detect, on m environmental mcdia- Regulated- Federal & State moderaie to ireauent Chloroorene" Lss-mooerate in NJ Retain Bioaccumuiai ion- ooiemal i I26-'W-^| Mutawenic evidence-in vivo m«c:< Persisience-nien Mu:a«nic evidence-in vitro Regulated-Federal -iicroorHanisms Hexachlorooenzene' Produwiion-moderan: -rt Nj ^srain \luiaaenic yMdcnce-Chromosomai aberra- M18--4-I , .asb'.proauct) -lons Laicmu^enic ivniencs-jnimai
NEW JERSEY REGISTER, MONDAY, APRIL 2, 1984 (CITE 16 N.J.R. 653) - 9 -
ENVIRONMENTAL PROTECTION PROPOSALS
Chemical !-Synonvmsi .Synonymil Proposed •C\& Number) Basis for Proposed Action (CAS ^umD Basis -or Prooosed \c*\a \aion
ProduCtion-none :n LS or NJ Dejection 'u environmental Lse-none m NJ iirequum >o fequcm Carcinogenic evidence-animal suspect Regulated-Federal Chromium & Salts' Use-substantial m NJ Rjauiaied- Federal C 440-47-3) Carcinogenic evidence-human Polvbrommaied Production & Jve-none Carcinogenic evidence-animal bionenvl*;* Tiiraiogcmc evidence- Jin Muiagenic svidcnce-m vivo mammalian iPB8» Mutagenic evidence-in vitro (59536-65-1 Persisience-mgn mammalian <& microorganisms '63S5-OI-3 Mutagenic evidence-Chromosomal abcrr lions Regulated-Federal 1.1654-09-6) Copper & Salts' Use-substantial in NJ Polycti formated Use-moderaie m NJ ,7440-50-8) Acute toxicity-aquatic biota biphenyls* Carcinogenic evidence-a mm, Bioaccumulat ion-known EmhrvoiOMcity Persistence-high Detecnon in environmental Regulated-Federal moderaic Cyanide Ion* Use-substantial Deieciion in marine orgams 15742-5) Acute toxicity-human Potassium cyanide \cute toxicity-animal Persisience-higri (151-50-8) Regulated-Federal Regulated-Federal & State Sodium cyanide Polychlonnatcd Production & use-none (141-33-9) mphcnvls* Lead & Salts & Use-substantial ,n NJ (12642-23-8) or ganomet allies* Carcinogenic evidence-animal 17. HYDRAZINES 1743^-92-1) Teratogcnic evidence-human 1,1-Dimethyl hydrazine* Production it use-none m NJ Fertility effects (57-14-7) Carcinogenic evidence-animal suspect Other chronic health effects Muugenic evidence-in vitro Bioaccumulation-Known mammalian & microorganisms Regulated-Federal Regulated-Federal Manganese & Salts Production-substantial m US Insufficient data 1,2-Dimeihyl hydrazini Production & use-none reported Insufficient data (7439-96-5) Regulated-Federal :or inclusion at 1540-73-8) Carcinogenic evidence-animal for inclusion at this time Mutagenic evidence-in vitro Mercury & Said & Use-moderate m NJ Retain microorganisms organometallics* Embryotoxicity Regulated-Federal 17439-97-6) Other chrome health effects 1,2-Diphenyl hydrazine Production & imports-moderate in US Bioaccumulat ion-known {Hydrazo benzene) Carcinogenic evidence-animal suspect Reguiated-Federal & State (122-66-7) Bioaccum illation-potential Nickel 4 Salts* Use-substantial in NJ Regulated-Federal (74W-02-Q) Carcinogenic evidence-human suspect Hydrazme* Production-minor m NJ Carcinogenic evidence-animal 1302-01-2) Use-moderate in NJ Teratogemc evidence-animal suspect .H,0 Carcinogenic evtdencs-animtl Regulated-Federal (7803-57-8) Mutagenic evidence-in vitro Selenium & Salts* Use-minor in NJ Delete H-,SO4 microorganisms (7^82-49-2) Regulated-Federal U0034-93-2) Regulated-Federal Silver & Salts' L'se-suoscannal in NJ Delete Methyl hydrazine Production-moderate m US (7440-22-4) Regulated-Federal ,60-34-11 Carcinogenic evidence-inimal suspect Thallium & Salts* Production & use-none m NJ Delete Mutagenic evidence-in vivo mammalian (7440-28-0) Bioaccumu lac ion-known Mutagenic evidence-in vitro Regulated-Federal mammalian & microorganisms Zinc & Salts* Use-moderate in NJ Delete Teratogenic evidence-animal suspect < •'440-66-1) Regulated-Federal Regulated-Federal 20. ISOCYANATES Semkarbazide Production-none reported Insufficient data Toluene-2,4- Product ton-substantial in US (Hydrazine carboxamide) Carcinogenic evidence-animal suspect for inclusion at diisocyanate vone producer in NJ) (57-56-7) Mutagenic evidenc<-in vivo insect this time ,584-84-9) Carcinogenic evidence-animal suspect .HCI Mutagenic evidence-in vitro Mutagenic cvidence-m vitro (563-41-7) mammalian & microorganisms microorganisms 18. IM1DES Regulated-Feaeral Etnyleneimme* Production-substantial in US Retain Toluene-2.6- Production-substantial m US (151-56-4) Use-minor m NJ diijocyanaie Carcinogenic evidence-animal suspect Carcinogenic evidence-animal suspect (91-08-7) Regulated-Federal Mutagenic evidence-in vivo 21 KETONES insects & plants [sophorone Production & use-unknown amount in US Insufficient data Mutagenic evidence-in vitro (78-59-1) Regulated-Federal for inclusion a: microorganisms ihis cime Regulated-Federal & State 22. LACTAMS Propyleneimme* Production & use-Unknown amount in US Delete Caprolactam Production-substantial in US Insufficient data (75-55-8) Carcinogenic evidence-animal suspect (105-60-2) Regulated-Federal for inclusion at Mutagentc evidence-host mediated assay :his time Mutagenic evidence-in vitro N-Vinyl-2-oyrrolidinone Imports-substantial m US Insufficient data mammalian & microorganisms 188-12-0) or inclusion at Regulated-Federal :his iime 19. INORGANICS 23. NITRILES Antimony & Sales* Ute-substantial in NJ Retain \crylomtrite* Use-substantial m NJ (7440-36-0) Carcinogenic evidence-human suspect M07M3-1) Carcinogenic evidence-human suspect (salt-Antimony cnoxide) Carcinogenic evidence-animal Regulated-Federal Mutagenic evidence-in vitro Arsenic & Saks* Use-substantial in NJ microorganisms (7440-38-2) Carcinogenic evidence-human Regulated-Federal Teratogenic evidence-animal 24. N1TRO COMPOUNDS Regulated-Federal A State 2.4-Dimtrotoluene* Production-suostantiai in NJ Asbestos' Use-substantial in NJ (121-14-2) Carcinogenic evidence-animal suspect M 332-21-4' Carcinogenic evidence-human Muiagenic evidence-in vivo mammalian Carcinogenic evidence-animal Mutagenic evidece-in vitro Regulated-Federal & State microorganisms Barium & Salts Use-substantial in US insufficient data Detecnon m environmental media- (7440-39-3) Regulated-Federal for inclusion at infrequent :o moderate :his ;ime Regulated-Federal Beryllium & Sails* Use-moderate in NJ Retain :,6-Dinurotoiuene* Production-substantial in NJ {7440-41-7) Carcinogenic evidence-human suspect 1606-20-2) .Muiagenic evidence-m vivo mammalian Carcinogenic evidence-animal Mutagenic evidence-in vuro Muugentc evidence-in vitro mammalian mammalian & microorganisms Regulated-Federal Regulated-Federal Boron & Salts Production-substantial in US Insufficient data Nitrobenzene' Production-moderate m NJ l"44(M2-8) Regulaied-Federal for inclusion ai (98-95-3) Use-substantial in NJ this time Regulated-Feaeral Cadmium & Salts' Lie-moderate in NJ Retain Production-substantial m LS Carcinogenic evidence-human suspect Carcinogenic ;vnlence-ammal Carcinogenic evidence-animal Muiagenic evidence-in vitro Teratogenic evidence-animal microorganisms Reguiated-Federal Regulated-Federal
(CITE 16 N.J.R. 654) NEW JERSEY REGISTER, MONDAY, APRIL 2. 1984 - 10 - PROPOSALS ENVIRONMENTAL PROTECTION
Chemical Chemical (Synonyms! Proposed (Svnonyms) Proposed tCAS Number) Basis for Proposed Act \-tion (C\S Number) Basis for Proposed *
NITROGEN HETEROCYCLICS Chlordecone* Production &. use-none Acndine Production-insignificant m LS Insufficient data (Kcponc) Carcinogenic evidence-animal Mutagenic evidence-in vitro for inclusion at (U3-JO-0) EmbryotoxiCity microorganisms '.Iiis lime Fertility effects Regulated-Federal Bioaccumulation-known Carbazole Imports-moderate m US Insufficient data Persistence-high i86-74-8) for inclusion at Regulated-Federal & State [his time (Prohibited pesticide) M damme Production & imports-substantial j,i US Insufficient data Chlordimeform Imports-moderate in US insufficient data (108-73-!) Regulated-Federal for inclusion at (6164-98-3) Regulated-Federal for inclusion at this time (restricted use-co(ton) this time Pyndine Production-substantial in US Insufficient data Chlorobcnzilate" Imports-mod crate in US Delete U10-86-1) Regulated-Federal for inclusion at (510-15-6) Carcinogenic evidence-am mal suspect this time Persistence-high Qumoline Production & use-unknown amour .t in US Include Regulated-Federal (91-22-5) (one NJ producer listed) (restricted use-citrus) Carcinogenic evidence-animal suspect Chloroptcrin Production-substantial m US Insufficient data Mutagenic evidence-in vitro (Tnchioromtromethane) Regulated-Federal for inclusion at mammalian & microorganisms (76-06-2) this time Regulated -Federal Chiorathalonil* Imports-moderate m US Include 26. N1TROSO COMPOUNDS Carcinogenic evidence-animal suspect N-Niirosoditthylamme" Production & inc-none in US Delete Regulated-Federal (5S-18-S) Carcinogenic evidence-animal Coumaphos Production-moderate m US Insufficient data Mutagenic evidence-in vivo insect <56-72-») Regulated-Federal for inclusion at Mutagenic evidence-host mediated assay this time Mutagenic evidence-in vitro 2.4- D' Production & imports-substantial in US Retain mammalian & microorganisms (94-75-7) Use-minor in NJ Regulated-Federal Teratojenic evidence-animal suspect N-Nitrosodirnethvlamme* Production A use-none m US Delete Regulated-Federal & State (62-75-9) Carcinogenic evidence-animal DOT' Production 4 use-none m NJ Mutagemc evidence-host mediated assay (50-29-3) Carcinogenic evidence-animal Mutagenic evidence-in vitro Acute coxici(y-aquatic biota mammalian & microorganisms Detection in environmental mcdia- Regulated- Federal Bioaccumuiatiori- Ic nown p-Nitrosodimeihytaniline* Production & use-none in NJ Delete Persistence-high (13 8-89-6) Regulated-Federal Regulated-Federal & State N-Niirosodiphenylamine* Production-moderate in NJ Retain (Prohibited pesticide) (86-30-6) Carcinogenic evidence-animal SUSJMCI Diallate Use-moderate in NJ Regulated-Federal (2303-16 Carcinogenic evidence-animal suspect p-NitrOSOdiphenylamme* Production 4 use-none in NJ Delete Mutagenic evidence-in vivo insect (156-ID'5) Muugenic evidence-m vitro 27. ORGANIC PEROXIDES mammalian & microorganisms Benzoyl peroxide Production-substantial in US Regulated-Federal (94-36-0) (one NJ producer listed) Diazinon Production-one NJ producer listed Insufficient dau Carcinogenic evidence-animal promoter (333-41-5) Use-substantial m US for inclusion at Regulated-Federal Regulated-Federal & State this time i-Butyl hydroperoxide Production 4 use-unknown amount m US Insufficient data Dichtorvos Production-substantial in US Include (75-91-2) Mutagenic evidence-in vivo insect for inclusion at (62-73-7) Mutagenic evidence-in vitro Mutagenic evidence-in vitro this time microorganisms microorganisms Acute toxicity-aquauc biota Regulated-Federal Regulated-Federal Cumene tiydroperoxide Production-substantial in US Dicofol' Use-moderate m NJ (30-15-91 (one NJ producer listed) (Ketthane) Carcinogenic evidence-animal suspect Mutagemc evidence-in vitro (115-32-2) Persistence-high microorganisms Regulated-Federal Regulated-Federal Dieldnn- PToduction-none Di-t-butylperoxide Production-substantial in US Insufficient data (60-57-1) Use-none reported in NJ (MQ-QS-4) Regulated-Federal for inclusion at Carcinogenic evidence-animal suspect this Lime Detection m environmental media-inirequem Peracetic acid Production-substantial in US Include Bioaccumulauan*knawn (79-21-0) Mutagemc evidence-m vitro Persistence-high microorganisms Regulated-Federal & State Regulated-Federal Endosuifin* Use-moderate m NJ 28. PESTICIDES Imports-substantial in US Retain (115-29-7) Detection in environmental media- Aldrin' Carcinogenic evidence-animal su!.pect infrequent to moderate (39
NEW JERSEY REGISTER, MONDAY, APRIL 2, 1984 (CITE 16 N.J.R. 655) - 11 - ENVIRONMENTAL PROTECTION PROPOSALS
Chemical (Synonvmsi Basis ror Prooosea (CAS Numberj Sails lor P-ODOsed Aaion
product 10 n-iuQsum i Ji in uS l.-i-Dimitnvlphenoi* P'oauc'.ion-moaera;; in NJ Teracovienie evidence-diurnal suspect im-Xylenol) Lse-substaniial in NJ EmbrvotQiiciiv UOS-67 t) Fertilitv Effects Regulated-Federal :o moderate Meihotychlor' Lie-moderate in NJ Regulated-Federal (72-43,5) Embryotoxicity 4.ft-Oinitro-o-cresoi* Production A use-none reported in NJ Regulated-Federal (2,4-Dmnro-6-meihyl- Mutagenic evidence-in vivo insect Produce ion i use-none phenolj Mutagenic evidence-in vitro Carcinogenic evidence-animal (534-52-t) microorganisms Ttfratogemc evidence-animal Regulated-Federal & State EmoryotoKicity 2.4-Dinuropnenol" Lse-triinor in NJ Bioaccumulation-known (51-26-51 Detection in environmental media- Persistence-known infrequent Regulated-Federal Regulated-Federal (Prohibited pesticide) Hydroquinone Production-substantial in US l-Naphthvlthiourea Imports-minor in US Insufficient data 11.4-Di h yd rot y benzene) Mutagentc evidence-in vitro iANTL'1 Vlutagcnic evidence-in vitro for inclusion at 1123-31-9) mammalian & microorganisms (S6-88-4* microorganisms :his time Reguiated-Federal Regulated-Federal 2-Nitrophenol" Use-moderate m NJ Nitrofen Use-moderate in US (88-75-5) Detection in environmental media- 12,4-Dichlorophenyl' Carcinogenic evidence-animal infrequent 4-nitrophenyl ether) Mutagenic evidence-in vitro Regulated-Federal (1836-73-J) microorganisms 4- Nitro phenol* Use-substantial m NJ Teratogenic evidence-animal suspect (100-02-:j Mutagenic evidence-in vitro Embryotoxicity mammalian & microorganisms Regulated-Federal Detection in environmental media- Parathion' Use-moderate m NJ infrequent (56-38-2) Acute toxicity-birds & aquatic biota Regulated-Federal Regulated-Federal & State Pentachlorophenol* Use-moderate m NJ Propoxur Production-moderate :n US 187-86-5) Embfvotoxicitv i!)4-26-h Mutagenic evidence-in MVO mammalian Mutagemc evidence-in vnro infrequent & moderate microorganisms Bioaccumulation-known Acute toxicjtv-birds Regulated-Federal & State Regulated-Federal & State Phenol* Production-moderate m NJ Quimozene* Production-substantial in U'S (108-95-2) Use-substantial m NJ (Peniachloronitro- Carcinogenic evidence-animal suspect Carcinogenic evidence-animal promotor benzene) Mutagenic evidence-in vitro Mutagenic evidence-in vitro (32-68-8) microorganisms mammalian &. microorganisms Regulated- Federal Regulated-Federal Strobane* Production & use-none 2-Phenylphenol Use-substantial m US (Terpene poly- Carcinogenic evidence-animal suspect (90-45-7) Carcinogenic evidence-animal suspect chlonnated) Regulated-Federal .Na Regulated-Federal (8001-SO-1) (Prohibited pesticide) Sulfallate Production-none reported Insufficient data 2.3,6-Tnchloropnenol Production & use-none reported insufficient data (95-06-7^ Carcinogenic evidence-animal for inclusion at '933-75-5) RL-guiated-Federal for inclusion at Mutagenic evidence-in vitro triis time microorganisms 2.4.5-Tnchloropnenol' Use-moderate m NJ Regulated. Federal (9S-95-41 Regulated-Federal 2.4.5-T" Production-none in IS 2.4.6-Tnchlorophenol" Production & use-none l2.4,J-Tnchloroprien- Lsc-msignificani m NJ 188-06-21 Carcinogenic evidence-animal oxyacetic acid) Mutagenic evidence-m vivo msects Detection m environmental media-moderate 193-76-5) Tcratogenic evidence-animal suspect Bioaccumulation-potential Embryotoxicity Regulated-Federal Regulated-Fcdtirat ?0. PHOSPHORAMIDES Teirachlorvmphos Use-moderate m US Hexamethylphosphoramide Production-unknown amount in US (961-11-5) Carcinogenic evidence-animal suspect (HEM PA) lone NJ manufacturer listed) Regulated-Federal (680-31-9) Carcinogenic evidence-animal suspect Toxaphene' Production-significant m NJ 31. QUINONES & ANTHRA- iPolychlormaied Use-moderate m NJ QUI NONES Carcinogenic evidence-animal 2-Ammoamhraquinone* Use-moderate in NJ (8001-35-2) Mutigenic evidence-m vitro (117-T9-3) Carcinogenic evidence-animal suspect microorganisms Mutagenic evidence-in vitro Mutagentc evidence-Chromosomal aberra microorganisms tions p-Benzoquinone dioxime Production-unknown amount m US Insufficient data Acme toxiciiy-aquaiic biota U05-11O) Carcinogenic evidence-animal suspect Bioaccumulation- k nown Regulated-Federal this time Regulated-Federal & State ;-Methyf-l- Production & use-none in US Insufficient data Tnchlorfon Use-subsiamial in US nitroanthraqumone Carcinogenic evidence-animal for inclusion at [52-68-6) Mutagenic evidence-in vwo mammalian (129-15-7) Muiagenic evidence-in Mtro Mutagenic evidence-m vitro microorganisms mammalian & microorganisms p-Quiitone Producnon A use-unknown amount m L! [nsutfkiem JaU Teraiogenic evidence-animal susp«c: (106-51-41 Regulated-Federal for .ndusion at Regulated-Federal this time Trifturalm L'se-sub«anual m US 32. SULFUR1C ACID ESTERS Product ion-unknown amount m US Insufficient da;a (1582-09-3) Carcinogenic evidence-animal suspect Diethyl ;ulfate Carcinogenic evidence-human suspect t'or .nciusion at Regulated-Federal Carcinogenic evidence-animal Zineb Production-substantial m US Muiagenic evidcnce-m vivo (12122-67-7) Carcinogenic evidence-animal suspect mammaiian, insect, & plants Teratogemc evidence-animal suspect Mutagenic evidence-m vitro Regulated-Federal mammalian & microorganisms 29. PHENOLS Regulated-Federal Catechu! Production-unknown amount in US Production-iubstannal m US (Pyrocatechol) Imports-moderate Carcinogenic evidence-animal (1,2-Dihydroxybenz Carcinogenic evidence-animal promoter Mutagenic evidence-m MVO- (120-80-9) Muiagenic evidence-in vitro mammalian, rish. insects, £ plants mammalian & microorganisms Mmagemc evidence-m vuro i-Chloro-m-cresoi Production & use-none reported Insufficient data mammalian &. microorganisms O-Methvl-4- Bioaccumulation -potential for inclusion ai Regulated-Federal chiorophenoll Regulated-Federal this nme 33. THIOUREAS (59-50-7) Ethvlene :hiourca Production-unknown amount m US ^ Chloropncnoi* Use-minor m NJ Delete lone NJ manufacturer listed) Carcinogenic evidcnce-ammal promotor Carcmozemc evidence-animal Detection m environmental media-mt'requeni Teraiogenic evidence-animal Regulated-Federal Regulated-Federal 2.4-Dichlorophcnol" Use-minor in NJ Delete Thiourea" Use-Moderate m NJ (120-83-21 Carcinogenic evidence-animal promotor 102-56-6) Carcinogenic evidence-animal suspect Detection in environmental media-moderate Mutagenic evtdence-nost mediated assa\ Regulated-Federal Mutagenic evidence-in vitro mammalian & microorganisms Regulated-Federal
(CITE 16 N.J.R. 656) NEW JERSEY REGISTER, MONDAY, APRIL 2. 1984 - 12 - PROPOSALS ENVIRONMENTAL PROTECTION
Social Impact "Common name" means any designation or identification Adoption of the Environmental Hazardous Substance List such as a code name, code number, trade name, brand name will give New Jersey citizens access to information on the or generic name used to identify a chemical other than by its types and amounts of hazardous substances to which they are chemical name. exposed in their communities. This information can be used "Container" means a receptacle used to hold a liquid, by physicians to aid in medical diagnoses, when necessary. solid, or gaseous substance, including, but not limited to, The data generated from the Environmental Survey can also bottles, pipelines, bags, barrels, boxes, cans, cylinders, be used by epidemiologists to analyze the effects of Environ drums, cartons, vessels, vats, and stationary or mobile storage mental Hazardous Substances on public health. In case of an tanks. "Container" shall not include process containers. emergency, such as a fire or spill, emergency response person "Department" means the New Jersey Department of Envi nel will be able to use the information on Hazardous Mate ronmental Protection unless the context clearly indicates oth rials, gathered under the Emergency Services Information erwise. Survey, to take measures to protect public safety and health. "Emergency Services Information Survey" or "ESI Sur vey" means a written form prepared by the Department and Economic Impact transmitted to an employer, on which the employer shall Those companies which must complete [he survey forms provide certain information concerning each of the Hazard will have additional time and personnel requirements. The ous Materials at his facility, including, but not limited to, the extent of the cost of compliance will depend on the number of following: the name of the Hazardous Material and its United substances a company is reporting, since detailed information Nation (U.N.) number, the United States Department of will be requried on the amount of each substance produced, Transportation designated hazard class, the approximate used, shipped out, disposed by, and emitted from the facility. range of the maximum inventory quantity, the unit of mea The Department intends to conduct the Environmental Sur sure, and the major method of storage or type of container, vey in a two phased process (short and long forms). By fol and whether the substance is present in a mixture. lowing this approach, many employers may not need to com "Employer" means any person or corporation in the State plete lengthy questionnaires, thereby limiting the expense of engaged in business operations having a Standard Industrial" the program for industry and the Department. Classification, as designated in the Standard Industrial Classi fication Manual prepared by the Federal Office of Manage Environmental Impact ment and Budget, within Major Group numbers 20 through The Environmental Hazardous Substance List will aid the 39 inclusive (manufacturing industries), numbers 46 through Department in formulating a database on the types and 49 inclusive (pipelines, transportation services, communica amounts of hazardous substances to which the public is ex tions, and electric, gas, and sanitary services), number 51 posed in the community. The information gathered will also (wholesale trade, nondurable goods), number ^5 (automotive aid the Department in selecting toxic substances to monitor in repair, services, and garages), number 76 (miscellaneous re the environment and will provide informar.ion necessary for pair services), number 80 (health services), number 82 (educa the development of regulations to control the emission of tional services), and number 84 (museums, art galleries, bo toxic substances. By requiring employers to identify hazard tanical and zoological gardens). For the purposes of N.J.A.C. ous substances in their waste streams, the Environmental Sur 7:1G "employer" means the State and local governments, or vey will encourage companies to use proper disposal methods. any agency, authority, department, bureau, or instrumental ity thereof. Full text of the proposed new rule follov/s. "Environmental Hazardous Substance" means any sub stance designated by the Department in N.J.A.C. 7:lG-2. CHAPTER 1G "Environmental Hazardous Substance List" means the list WORKER AND COMMUNITY RIGHT TO KNOW of Environmental Hazardous Substances in N.J.A.C. 7:lG-2. REGULATIONS "Environmental Survey" means a written form prepared by the Department of Environmental Protection and trans SUBCHAPTER 1. GENERAL PROVISIONS mitted to an employer, on which the employer shall provide certain information concerning each of the environmental 7:1G-1.1 Scope hazardous substances at the facility, including, but not limited Unless otherwise provided by rule or statute, this chapter to, the following: shall constitute the rules of the Departmenr. implementing the 1. The chemical name and Chemical Abstracts Service Worker and Community Right to Know Act, P.L. 1983 c.315, number of the environmental hazardous substance; N.J.S.A. 34-.5A-1 et seq. 2. A description of the use of the environmental hazardous substance at the facility; 7:1G-1.2 Definitions 3. The quantity of the environmental hazardous substance The following words and terms, when u:;ed in this chapter, produced at the facility; shall have the following meanings unless the context clearly 4. The quantity of the environmental hazardous substance indicates otherwise. brought into the facility; "Act" means the Worker and Community Right to Know 5. The quantity of the environmental hazardous substance Act, P.L. 1983 c.315, N.J.S.A. 34:5A-1 ei: seq. consumed at the facility; "Chemical Abstracts Service number" or "C.A.S. num 6. The quantity of the environmental hazardous substance ber" means the unique identification nuimer assigned by the shipped out of the facility, as or in, products; Chemical Abstracts Service to chemicals. 7. The maximum inventory of the environmental hazard "Chemical name" means the scientific designation of a ous substance stored at the facility, the methods of storage, chemical in accordance with the nomenclature system devel and the frequency and methods of transfer; oped by the International Union of Pure and Applied Chemis 8. The total stack or point-source emissions of the environ try or the Chemical Abstracts Service rules of nomenclature. mental hazardous substance;
NEW JERSEY REGISTER, MONDAY, APRIL 2, 1984 (CITE 16 N.J.R. 657) - 13 - ENVIRONMENTAL PROTECTION PROPOSALS
9. The total estimated fugitive or non point-source emis Chemical CAS Number Group Number sions of the environmental hazardous substance; 10. The total discharge of the environmental hazardous BUTYL BENZYLPHTHALATE 35-63-7 12 substance into the surface or groundwater, the treatment 1,2-BUTYLENE OXIDE 106-88-- 11 methods, and the raw svastewater volume and loadings; C.I. ACID BLUE 9 2650-18-2 10 C.I. ACID GREEN 3 4680-78-8 10 11. The total discharge of the enviromental hazardous sub C.I. BASIC GREEN 4 569-64-2 10 stance into publicly owned treatment works; and C.I. BASIC RED 1 989-38-3 10 12. The quantity and methods of disposal, of any wastes C.I. DIRECT BLACK 38 1937-37-7 10 containing an environmental hazardous substance, the meth C.I. DIRECT BLUE 6 2602-46-2 10 ods of on-site storage of these wastes, the location or loca C.I. DIRECT BROWN 95 16071-86-6 10 tions of the final disposal site for these wastes, and the iden C.I. DISPERSE YELLOW 3 2832-40-8 10 tity of the hauler of the wastes. C.I. FOOD RED 5 3761-53-3 10 "Facility" means the building, equipment and contiguous C.I. FOOD RED 15 81-88-9 10 area at a single location used for the conduct of business. For C.I. SOLVENT ORANGE 7 3118-97-6 10 C.I. SOLVENT YELLOW 1 60-09-3 10 the purpose of this chapter, "Facility" shall not include a C.I. SOLVENT YELLOW 3 97-56-3 10 research and development laboratory. C.I. SOLVENT YELLOW 14 842-07-9 10 "Hazardous Material" means any substance designated by C.I. VAT YELLOW 4 128-66-5 10 the Department in N.J.A.C. 7:1G-4. CADMIUM AND SALTS 7440-43-9 19 "Hazardous Materials List" means the list of Hazardous CAPTAN 133-06-2 28 Materials designated by the Department in N.J.A.C. 7:lG-4. CARBARYL 63-25-2 28 "Mixture" means a combination of two or more substances CARBON TETRACHLORIDE 56-23-5 14 not involving a chemical reaction. CATECHOL 120-80-9 29 "Research and development laboratory" means a specially CHLORAMBEN 133-90-4 28 CHLORDANE 57-74-9 28 designated area used primarily for research, development, CHLOROBENZENE 108-90-7 16 and testing activity, and not primarily involved in the produc CHLOROFORM 67-66-3 14 tion of goods for commercial sale, in which environmental CHLOROPRENE 126-99-8 15 hazardous substances are used by or under the direct supervi CHLOROTHALONIL 1897-45-6 28 sion of a technically qualified person. CHROMIUM AND SALTS 7440-47-3 19 COPPER AND SALTS 7440-50-8 19 SUBCHAPTER 2. ENVIRONMENTAL HAZARDOUS P-CRESIDINE 120-71-8 06 SUBSTANCE LIST CUMENE 98-82-8 07 CUMENE HYDROPEROXIDE 80-15-9 27 CYANIDE ION 57-12-5 19 7:1G-2.1 Designation of Substances 2,4-D 94-75-7 28 The following substances and corresponding Chemical Ab DECABROMODIPHENYL OXIDE 1163-19-5 13 stract Services (C.A.S.) numbers are designated as Environ DIALLATE 2303-16-4 28 mental Hazardous Substances pursuant to the Act. Each sub 2,4-DIAMINOANISOLE 615-05-4 06 stance has further been identified according to the 4,4'-DIAMINODIPHENYL ETHER 101-80-4 13 classifications in N.J.A.C. 7:lG-2.2. Substances may have 2,4-DIAMINOTOLUENE 95-80-7 06 ' numerous synonyms which are not included herein. 1,2-DIBROMOETHANE 106-93-4 14 DI-N-BUTYL PHTHALATE 84-74-2 12 95-50-1 Chemical CAS Number Group Number 1,2-DICHLOROBENZENE 16 1,2-DICHLOROETHANE 107-06-2 14 ACETALDEHYDE 75-07-0 02 1,4-DICHLOROBENZENE 106-46-7 16 ACROLEIN 107-02-8 02 3,3' -DICHLOROBENZIDINE 91-94-1 06 ACRYLIC ACID 79-10-7 01 DICHLOROMETHANE 75-09-2 14 ACRYLONITRILE 107-13-1 23 1.2-DICHLOROPROPANE ' 78-87-5 14 ALDRIN 309-00-2 28 1.3-DICHLOROPROPYL£NE 542-75-6 15 ALLYL CHLORIDE 107-05-1 15 DICHLORVOS 62-73-7 2-AMINOANTHRAQUINQNE 117-79-3 31 DICOFOL 115-32-2 ANILINE 62-53-3 06 DIETHYL PHTHALATE 84-66-2 12 0-ANISIDINE 90-04-0 06 DIMETHYL PHTHALATE 131-11-3 12 ANTHRACENE 120-12-7 07 DIMETHYL SULFATE 77-78-1 32 ANTIMONY AND SALTS 7440-36-0 19 3,3' -DIMETHYLBENZIDINE 119-93-7 06 ARSENIC AND SALTS 7440-38-2 19 2,4-DIMETHYLPHENOL 105-67-9 29 ASBESTOS 1332-21-4 19 2,4-DINITROTOLUENE 121-14-2 24 BENZAL CHLORIDE 98-87-3 16 2,6-DINITROTOLUENE 606-20-2 24 BENZENE 71-43-2 07 DI-N-OCTYL PHTHALATE 117-84-0 12 BENZOTRICHLORIDE 98-07-7 16 1.4-DIOXANE 123-91-1 13 BENZOYL CHLORIDE 98-88-4 01 1,2-DIPHENYL HYDRAZINE 122-66-7 17 BENZOYL PEROXIDE 94-36-0 27 EPICHLOROHYDRIN 106-89-3 11 BENZYL CHLORIDE 100-44-7 16 ETHYLBENZENE 100-41-4 07 BERYLLIUM AND SALTS 7440-41-7 19 ETHYLENE OXIDE 75-21-8 11 BIPHENYL 92-52-4 07 ETHYLENE THIOUREA 96-45-7 33 BIS(2-CHLORO-1-METHYLETHYL) ETHYLENEIMINE 151-56-4 IS ETHER 108-60-1 13 FLUOMETURON 2164-17-2 28 BIS(2-ETHYLHEXYL)ADIPATE 103-23-1 12 FORMALDEHYDE 50-00-0 02 BIS(2-ETHYLHEXYL)PHTHALATE 117-81-7 12 HEPTACHLOR "6-44-8 28 BUTADIENE 106-99-0 03 HEXACHLOROBENZENE 118-74-1 !6
(CITE 16 N.J.R. 658) NEW JERSEY REGISTER, MONDAY, APRIL 2, 1984 - 14 -
PROPOSALS ENVIRONMENTAL PROTECTION
Chemical CAS Number Group Number GROUP NO. CHEMICAL GROLP GROLPNO. CHEMICAL GROl P HEXACHLOROETHANE 67--2-I 14 01 Acids & acid chlorides 18 Imides HEXAMETHYLPHOSPHORAMiDE 680-31-9 30 02 Aldehydes 19 Inorganics HYDRAZINE 302-01-2 r 03 Aliphatic hydrocarbons 20 Isocyanates HYDROQUINONE 123-31-9 29 04 Amides 21 Ketones LEAD AND SALTS AND ORGANO- 05 Anhydrides 22 Lactams METALLICS 7439-92-1 19 06 Aromatic amines 23 Nitriles LINDANE 58-89-9 28 j 1j1*7 TO -J -*q 07 Aromatic hydrocarbons 24 Nitro compounds MANEB ii.4i /-jo-i .,0 08 Azo compounds 25 Nitrogen MERCURY AND SALTS AND heterocycles 7439-97-6 19 ORGANOMETALUCS 09 Carbamates 26 Nitroso METHOXYCHLOR 72-43-5 28 compounds METHYL HYDRAZINE 60-34-4 17 10 Dyes 27 Organic METHYL IODIDE 74-88-4 14 peroxides METHYLMETHACRYLATE 80-62-6 12 11 Epoxides 28 Pesticides 4,4'-METHYLENE BIS(2- 12 Esters 29 Phenols CHLOROANILINE) 101-14-4 06 13 Ethers & Lactones 30 Phosphoramides 4,4'-METHYLENEBIS(N,N- j-lj£ 14 Halogenated alkanes 31 Quinones DIMETHYL) BENZENAMINE 101-61-1 Uu & Anthraqui- 4,4'-METHYLENEDIANlLINE 101-77-9 06 nones NAPHTHALENE 91-20-3 07 15 Halogenated alkenes 32 Sulfuric 1-NAPHTHYLAMINE 134-32-7 06 acid esters NICKEL AND SALTS T.j.tn/*r+U-U^-U ( ) } n 19 f\f 16 Halogenated aromatics 33 ' Thioureas 5-NITRO-O-ANISIDINE QQ77-J7-4 SO "7 uo 17 Hydrazines NITROFEN 1836-75-5 28 4-NTTROPHENOL 100-02-7 29 2-NITROPROPANE ->9-46-9 24 SUBCHAPTER 3. ENVIRONMENTAL SURVEY N-NITROSODIPHENYLAMINE 86-30-6 26 PARATHION 56-38-2 28 7-.1G-3.1 Completion of Environmental Survey PENTACHLOROPHENOL 87-86-5 29 Within 90 days of receipt of Pan I or Part II of the Envi PERACETIC ACID 79-21-0 27 ronmental Survey, an employer shall complete the survey PHENOL 108-95-2 29 concerning each of the Environmental Hazardous Substances 2-PHENYLPHENOL 90-43-7 29 at his facility, and transmit a copy of the completed survey to PHOSGENE 75-44-5 01 the Department of Environmental Protection and the health POLYCHLORINATED BIPHENYLS 1336-36-3 16 114-26-1 department of the county in which the employer's facility is PROPOXUR 28 located (or county clerk if there is no county health depart PROPYLENE OXIDE 75-56-9 11 QUINOLINE 91-22-5 25 ment). This deadline shall be extended for an additional pe QUINTOZENE 82-68-8 28 riod not to exceed 30 days, at the discretion of the Depart SAFROLE 94-59-7 13 ment for good cause shown by the employer. STYRENE 100-42-5 07 STYRENE OXIDE 96-09-3 11 7:lG-3.2 Clarification of completed Environmental Survey 1,1,2,2-TETRACHLOROETHANE 79-34-5 14 The Department may require an employer to submit infor TETRACHLOROETHYLENE 127-18-4 15 mation clarifying any statement made on Part I and Part II of TETRACHLORVINPHOS 961-11-5 28 139-65-1 f\A the Environmental Survey. The Department shall transmit 4,4'-THIODIANILINE UO this clarifying information to the county health department THIOL'REA 62-56-6 33 TOLUENE 108-88-3 07 (or county clerk if there is no county health department), as it TOLUENE-2.4-DIISOCYANATE 584-84-9 20 deems necessary. TOLUENE-2.6-D11SOCYANATE 91-08-7 20 0-TOLUIDINE 95-53-4 06 7:lG-3.3 Updating of Environmental Survey TOXAPHENE 8001-35-2 28 (a) Every employer shall update a completed' Part I and TRICHLORFON 52-68-6 28 Part II of the Environmental Survey for his facility every 1,2,4-TRICHLOROBENZENE 120-82-1 16 other year. If there is any significant change during a nonre- 1,1,1 -TRICHLOROETHANE 71-55-6 14 porting year in the information reported on his Environmen 70JTfl'7-m/*j S 1,1,2-TRICHLOROETHANE 14 tal Survey, the employer shall inform the Department of the TR1CHLOROETHYLENE 79-01-6 15 TRIFLURAHN 1582-09-3 28 change. URETHANE 51-79-6 09 (b) The Department may require an employer to update the VINYL CHLORIDE »5-01-4 15 Environmental Survey for his facility every year. XYLENES 1330-20-7 07 2,6-XYLIDINE 87-62-7 06 SUBCHAPTER 4. HAZARDOUS MATERIALS LIST ZINEB 12122-67-7 28 7:1G-4.1 Designation of Hazardous Materials The substances contained in the Optional Materials Table 7:10-2.2 Chemical Group and Group Numbers in Title 49 of the Code of Federal Regulations, Pan 172.102, The groups, and their designated group numbers, to which as amended by publication in the Federal Register, 48 Fed. Environmental Hazardous Substances listed in N.J.A.C. Reg. Vol. 48, No. 211, pp. 50234-50279 (October 31, 1983) 7:1G-2.1 belong, are designated herein, to reflect similarity in are designated, by reference, as Hazardous Materials pursu chemical structure, with the exception of Pesticides (Number ant to the Worker and Community Right to Know Act, P.L. 28) and Dyes (Number 10), which reflect commercial use: 1983, c.315, N.J.S.A. 34:5A-1 et seq. ,
NEW JERSEY REGISTER. MONDAY, APRIL 2. 1984 (CITE 16 N.J.R. 659) - 15 -
ENVIRONMENTAL PROTECTION PROPOSALS
7:lG-4.2 Amendments to Hazardous Materials List (a) The Department intends to establish a procedure for annually receiving information, advice, testimony, and rec ommendations from the Right to Know Advisory Council established pursuant to the Act, the public, and any other interested party, concerning the implementation of the Act. This procedure shall include a mechanism for revising the Hazardous Materials List. (b) The Department will publish in the New Jersey Regis ter, any revisions by the United States Department of Trans portation (USDOT) to the Optional Materials Table in Title 49 of the Code of Federal Regulations, as amended. Effective upon such publication in the Register, such amendments by the USDOT shall be incorporated into N.J.A.C. 7:1G-4.1. (c) Amendments to N.J.A.C. 7:10-4.1, other than in ac cordance with (a) above, shall be made pursuant to the provi sions of the "Administrative Procedure Act", 1968, c.410, N.J.S.A. 52:148-1 et seq. SUBCHAPTER 5. EMERGENCY SERVICES INFORMA TION (ESI) SURVEY 7:1G-5.1 Completion of ESI Survey Within 90 days of receipt of an Emergency Services Infor mation Survey, an employer shall complete the survey con cerning each of the Hazardous Materials at his facility, and transmit a copy of the completed survey to the Department of Environmental Protection, the local fire department and the local police department. This deadline shall be extended for an additional period not to exceed 30 days, at the discretion of the Department for good cause shown by the employer. 7:lG-5.2 Clarification of completed ESI Survey The Department may require an employer to submit infor mation clarifying any statement made on the Emergency Serv ices Information Survey. The Department shall transmit this clarifying information to the local fire department and local police department as it deems necessary. 7:lG-5.3 Updating of ESI Survey (a) Every employer shall update the Emergency Services Information (ESI) Survey for his facility every other year. If there is any significant change during a nonreporting year in the information reported on his ESI Survey, the employer shall inform the Department of the change. (b) The Department may require an employer to update the ESI Survey for his facility every year.
(CITE 16 N.J.R. 660) NEW JERSEY REGISTER, MONDAY, APRIL 2. 1984 APPENDIX I
SUMMARY OF THE ACT
On August 29, 1983, Governor Thomas H. Kean signed the "Worker and Community Right to Know Act" which becomes effective August 29, 1984. The Act establishes a comprehensive system for the disclosure and dissemination of information about hazardous substances in the workplace and in the environment. This law guarantees New Jersey citizens access to the exact chemical identity of hazardous substances to which they may be exposed at their workplaces or in their communities, and will also provide them with information concerning the short and long term effects of exposure to these hazardous substances. The act will also enable the Department of Environmental Protection and the Department of Health to establish a data base concerning the presence and use of hazardous substances throughout the State, which will aid both departments in carrying out their responsibilities to protect the environment and the public health.
The Act applies to employers having a Standard Industrial Classification, as designated in the Standard Industrial Classification Manual prepared by the Federal Office of Management and Budget, within Major Group Numbers 20-39 (manufacturing industries), 46-49 (pipelines, transportation services, communications, and electric, gas, and sanitary services), 51 (wholesale trade, nondurable goods), 75 (automotive repair services, and garages), 76 (miscellaneous repair services), 80 (health services), 82 (educational services), 84 (museums, art galleries, botanical and zoological gardens). State and local governments are also covered under the Act.
Employers covered under the New Jersey "Worker and Community Right to Know Act" are required to:
1) Report to the Department of Health those hazardous substances present at their places of business;
2) Maintain a file of basic safety information (supplied by the Department of Health) about these hazardous substances for their employee's use;
3) Provide their employees with education and training on how to handle these substances;
4) Label containers containing hazardous substances within 18 months, and all containers within three years, with the chemical name of their contents;
5) Disclose to the Department of Environmental Protection basic information concerning the storage, treatment, and emission into the environment of hazardous substances. All disclosed information on Environmental Hazardous Substances will be available to employees at the workplace, and to members of the community at the county health department and from the State Departments of Health (DOH) and Environmental Protection (DEP). Local Police and Fire Departments will also receive this informe.tion to help them plan for emergencies involving hazardous substances.
The Act allows employers to protect legitimate proprietary information by permitting them to make a trade secret claim regarding any information required to be disclosed under the Act, except for the identity of a special health hazard substance or information concerning emissions. Trade secret claims would be subject to review by either the DEP or the DOH, and would be the subject of an administrative hearing conducted by an administrative law judge. Information for which a trade secret claim is pending would not be released to the public by the departments.
The New Jersey "Worker and Community Right to Know Act" will be jointly implemented by the DOH and the DEP. The DOH will enforce those parts of the law dealing with hazardous substances in the workplace, and the DEP will oversee those parts dealing with hazardous substances in the general environment. In particular, the DOH will develop a workplace hazardous substance list, a special health hazard substance list for which no trade secret claims are alloweid, and a workplace survey. It will also send employers hazardous substance fact sheets for each hazardous substance reported on a workplace survey and will adopt joint regulations with DEP regarding trade secrets.
The DEP is required to adopt a list of Environmental Hazardous Substances and develop an Environmental Survey to enable employers to provide detailed information on their, use, emission and disposal of these substances.
The Department of Labor is directed to mediate and resolve employee-employer disagreements related to the interpretation of the act. The departments will be aided and advised by a Right To Know Advisory Council, composed of 11 citizen members appointed by the governor, representing a broad range of groups interested in workplace and environmental safety.
The implementation of the Act will be funded by a fee levied on employers at the rate of $2.00 per employee, or a minimum of $50.00 per employer. The revenues generated by the fee will be deposited in a special fund in the Treasury;, and will be disbursed to the departments responsible for implementing the Act. APPENDIX II
Description of Standard Industrial Classifications (SIC) Codes Covered by the Act
Titles and Description of Industries
Division: Manufacturing
Major Group 20. Food and kindred products Major Group 21. Tobacco manufacturers Major Group 22. Textile mill products Major Group 23. Apparel and other finished products made from fabrics and similar materials Major Group 24. Lumber and wood products, except furniture Major Group 25. Furniture and fixtures Major Group 26. Paper and allied products Major Group 27. Printing, publishing, and allied industries Major Group 28. Chemicals and allied products Major Group 29. Petroleum refining and related industries Major Group 30. Rubber and miscellaneous plastics products Major Group 31. Leather and leather products Major Group 32. Stone, clay, glass, and concrete products Major Group 33. Primary metal industries Major Group 34. Fabricated metal products, except machinery and transportation equipment Major Group 35. Machinery, except electrical Major Group 36. Electrical and electronic machinery, equipment, and supplies Major Group 37. Transportation equipment Major Group 38. Measuring, analyzing, and controlling instruments; photographic, medical and optical goods; watches and clocks Major Group 39. Miscellaneous manufacturing industries
Division: Transportation; communications; electric, gas, and sanitary services
Major Group 46. Pipe lines, except natural gas Major Group 47. Transportation services Major Group 48. Communication Major Group 49. Electric, gas, and sanitary services
Division: Wholesale trade
Major Group 51. Wholesale trade - nondurable goods APPENDIX II (Continued)
Titles and Description of Industries
Division: Services
Major Group 75. Automative repair, services, and garages Major Group 76. Miscellaneous repair services Major Group 80. Health services Major Group 82. Education services Major Group 84. Museums, art galleries, botanical and 2;oological gardens PRIVATE SECTOR EMPLOYERS COVERED UNDER THE NEW JERSEY
"WORKER AND COMMUNITY RIGHT TO KNOW ACT"
LISTED BY
STANDARD INDUSTRIAL CLASSIFICATION
Code fhorf TUlt C»4i tktrt Title 20 FOOD AND KINDRED PRODUCTS 2063 B*«t sugar 201 Meat Products 2065 Confectionery products 2011 Meat- packing plants 2066 Chocolate nnd cocoa products 2013 Sausages and otber prepared meats 2067 Chewing gum 2016 Poultry dressing plants 207 Fats and Oils 2017 Poultry and esc processing 2074 Cottonseed oil mills 202 Dairy Products 2075 Soybeau oil mills 2021 Creamery butter 2076 Vegetable oil mills, nee 2022 Cheese, natural and processed 2077 Animal and marine fats and oils 2023 Condensed and evaporated milk 2079 Shortening and cooking oils 2024 Ice cream nnd frozen desserts 208 Beverages 2026 Fluid milk 2052 Malt beverages 203 Preserved Fruits and Vegetables 2053 Malt 2032 Canned specialties 2054 TVines, brandy, and brandy spirits 2033 Canned fruits and vegetables 2055 Distilled liquor, except brandy 2034 Dehydrated fruits, vegetables, soups 2056 Bottled and canned soft drinks 2035 Pickles, sauces, and salad dressings 2087 Flavoring extracts and sirups, nee 2037 Frozen fruits and vegetables 20S Misc. Foods and Kindred Products 2038 Frozen specialties 2091 Canned and cured seafoods 204 Grain Mill Products 2092 Fresh or frozen packaged fish 2041 Flour and otber grain mill products 2095 Roasted coffee 2043 Cereal breakfast foods 2097 Manufactured ice 2044 Rice milling 209S Macaroni nnd spaghetti 2045 Blended and prepared flour 2099 Food preparations, nee 2046 Wet corn milling 2047 Dog, cat, and other pet food 21 TOBACCO MANUFACTURES 2048 Prepared feeds, nee 211 Cigarettes 205 Bakery Products 2111 Cigarettes 212 Cigars 2051 Bread, cake, and related products 2121 Cigars 2052 CookJes and crackers 213 Chewing and Smoking Tobacco 206 Sugar and Confectionery Products 2131 Chewing and smoking tobacco 2061 Raw cane sugar 214 Tobacco Stemming and Redrying 2062 Cane ngar refining 2141 Tobacco stemming and redrring Coilt Short T 26 PAPER AND ALLIED PRODUCTS 28 CHEMICALS AND ALLIED PROD- 261 Pulp Mills UCTS 2611 Pulp mills 281 Industrial Inorganic Chemicals 262 Paper Mills, Except Building Paper 2812 Alkalies and chlorine 2621 Paper mills, except building paper 2813 Industrial gases 263 Paperboard Mills 2816 Inorganic pigments 2631 Paperboard mills 2819 Industrial inorganic chemicals, nee 264 Misc. Converted Paper Products 282 Plastics Materials and Synthetics 2641 Paper coating and glazing 2821 Plastics materials and resins 2642 Envelopes 2822 Synthetic rubber 2643 Bags, except textile bags 2523 Cellulosic man-made fibers 2645 Die-cut paper and board 2524 Organic fibers, noncellnlosic 2646 Pressed and molded pulp goods 283 Drugs 2647 Sanitary paper products 2831 Biological products 2648 Stationery products 2S33 Medicinal* and botanicals 2649 Converted paper products, nee 2834 Pharmaceutical preparations 265 Paperboard Containers and Boxes 284 Soap, Cleaners, and Toilet Goods 2651 Folding paperboard boxes 2S41 Soap and other detergents 2652 Set-up paperboard boxes 2842 Polishes and sanitation goods 2653 Corrugated and solid fiber boxes 2843 Surface active agents 2654 Sanitary food containers 2844 Toilet preparations 2655 Fiber cans, drums & similar products 255 Paints and Allied Products 266 Building Paper and Board Mills 2851 Paints and allied products 2661 Building paper and board mills 286 Industrial Organic Chemicals Code Sfiort Title Corlt Sliort Title 2S61 Gum and wood chemicals 316 Luggage 2S65 Cyclic crudes :ind intermediates 3161 Luggage 2569 Industrial organic cheiaicals, nee 317 Handbags and Personal Leather Goods 287 Agricultural Chemicals 3171 Women's hnndbags nnd purses 2S73 Nitrogenous fertilizers 3172 Personal leather goods, uec 2874 PUosphatic fertilizers 319 Leather Goods, nee 2875 Fertilizers, mixing only 3199 Leather goods, nee 2S79 Agricultural chemicals, nee 289 Miscellaneous Chemical Products 32 STONE, CLAY, AND GLASS PROD- 2891 Adhesives and sealants UCTS 2592 Explosives 321 Flat Glass 2593 Printing ink 3211 Flat glass 2S95 Carbon black 322 Glass and Glassware, Pressed or Blown 2S99 Chemical preparations, nee 3221 Glass containers 3229 Pressed and blown glass, nee 29 PETROLEUM AND COAL PRODUCTS 323 Products of Purchased Glass. 291 Petroleum Refining 3231 Products of purchased glass 2911 Petroleum refining 324 Cement, Hydraulic 295 Paring and Roofing Materials 3241 Cement, hydraulic 2951 Paring mixtures a nd blocks 325 Structural Clay Products 2952 Asphalt felts and coating.) 3251 Brick and structural clay tile 299 Misc. Petroleum and C>al Products 3253 Ceramic wall and floor tile 2992 Lubricating oils end greases 3255 Clay refractories 2999 Petroleum and coal products, nee 3259 Structural clay products, nee 326 Pottery and Related Products SO RUBBER AND MISC. PLASTICS 3261 Vitreous plumbing fixtures PRODUCTS 3262 Vitreous china food utensils 301 Tires and Inner Tubes 3263 Fine earthenware food utensils 3011 Tires and inner tubes 3264 Porcelain electrical supplies 302 Rubber and Plastics Footwear 3269 Pottery products, nee 3021 Rubber and plastics foolrwear 327 Concrete, Gypsum, and Plaster Products. 303 Reclaimed Rubber 3271 Concrete block and brick 3031 Reclaimed rubber 3272 Concrete products, nee 304 Rubber and Plastics Ho»f and Belting 3273 Ready-mixed concrete 3041 Rubber nnd plastics bosc and belting 3274 Lime 306 Fabricated Rubber Products, nee 3275 Gypsum products 3069 Fabricated rubber products, nee 328 Cat Stone and Stone Products 307 Miscellaneous Plastics Ftoducts 3281 Cut stone and stone products 3079 Miscellaneous plastics products 329 Misc. Nonmetallic Mineral Products 3291 Abrasive products 31 LEATHER AND LEATHER PRODUCTS 3292 Asbestos products 311 Leather Tanning and Finishing 3293 Gaskets, packing and sealing devices 3111 Leather tanning and finishing 3295 Minerals, ground or treated - , 313 Boot and Shoe Cut Stock and Findings 3296 Mineral wool 3131 Boot and shoe cut stock and findings 3297 Nonclay refractories 314 Footwear, Except Rabbir 3299 Nonmetallic mineral products, nee 3142 House slippers 3143 Men's footwear, except athletic 33 PRIMARY METAL INDUSTRIES 31*4 Women's footwear, except athletic 331 Blast Furnace and Basic Steel Products 3149 Footwear, except rubber,, nee 3312 Blast furnaces and steel mills 315 I/esther Gloves and Mittsns 3313 E1cetroroornllurglc»l products 3151 Ltttb*r gloves and mitteas 3312 Stefl wire and related products Cinlc S),ort Title Code Short Title 331G Cokl finishing of steel shapes 343 Screw Machine Products, Bolts, etc. 3317 Steel pipe and tubes 3451 Screw macbiue products 332 Iron and Steel Foundries 3452 Bolts, nuts, rivets, and washers 3321 GMT iron foundries 346 Metal Forcings and Stampings 3322 Malleable Iron foundries 3462 Iron and steel forcings 3324 Steel investment foundries 3463 Xonferrous forging* 3325 Steel foundries, nee 3465 Automotive stampings 333 Primary Nonferrous Metals 3466 Crowns and closures 3331 Primary copper 3469 Metal stampings, nee 3332 Primary lead 347 Metal Services, nee 3333 Primary zinc 3471 Plating and polishing 3334 Primary aluminum 3479 Metal coating and allied services 3339 Primary nonferrous metals, nee 348 Ordnance and Accessories, nee 334 Secondary Nonferrous Metals 34S2 Small arms ammunition 3341 Secondary nonferrous metals 3483 Ammunition, exc. for small arms, nee 335 Nonferrous Rolling and Drawing 3484 Small arms 3351 Copper rolling and drawing 3489 Ordnance and Accessories, nee 3353 Aluminum sheet, plate, and foil 349 Misc. Fabricated Metal Products . 3354 Aluminum extruded products 3493 Steel springs, except wire 3355 Aluminum rolling and drawing, nee 3494 Valves and pipe fittings 3356 Konferrous rolling and drawing, nee 3495 Wire springs 3357 Xonferrous wire drawing & insulating 3496 Misc. fabricated wire products 336 Nonferrous Foundries 3497 Metal foil and leaf 3361 Aluminum foundries 3498 Fabricated pipe and fittings 3362 Brass, bronze, and copper foundries 34S9 Fabricated metal products, nee 3369 Nonferrous foundries, nee 339 Miscellaneous Primary Metal Products 35 MACHINERY, EXCEPT ELECTRICAL 339S Metal beat treating 351 Engines and Turbines 3399 Primary metal products, nee 3511 Turbines and turbine generator sets 3519 Internal combustion engines, nee 34 FABRICATED METAL PRODUCTS 352 Farm and Garden Machinery 341 Metal Cans and Shipping Containers 3523 Farm machinery and equipment 3411 Metal cans 3524 Lawn and garden equipment 3412 Metal barrels, drams, and pails 353 Construction and Related Machinery 342 Cutlery, Hand Tools, and Hardware 3531 Construction machinery 3421 Cutlery 3532 Mining machinery 3423 Hand and edge tools, nee 3533 Oil field machinery 3425 .Hand saws and saw blades 3534 Elevators and moving stairways 3429 Hardware, nee 3535 Conveyors and conveying equipment 343 Plumbing and Heating, Except Electric 3536 Hoists, cranes, and monorails 3431 Metal sanitary ware 3537 Industrial tracks and tractors 3432 Plumbing fittings and brass goods 354 Metalworking Machinery 3433 Heating equipment, except electric 3541 Machine tools, metal cutting types 344 Fabricated Structural Metal Products 3542 Machine tools, metal forming types 3441 Fabricated structural metal 3544 Special dies, tools, jigs & fixtures 3442 Metal doors, sash, and trim 3545 Machine tool accessories 3443 Fabricated plate work (boiler shops) 3546 Power driven band tools 3444 Sheet metal work 3547 Boiling mill machinery 3446 Architectural metal work 3549 Metal working machinery, nee 34-18 Prefabricated metal buildings 355 Special Industry Machinery 3449 Miscellaneous metal work ' 3551 Food product* machinery Cadi Short Title Code Short THIt 3352 Textile machinery 364 Electric Lighting and Wiring Equipment 3553 Woodworking machinery 3641 Electric lamps 3554 Paper industries machinery 3643 Current-carrying wiring devices 3355 Printing trades machinery 3644 Xoncurrent-carrying wiring devices 3559 Special industry machinery, nee 3645 Residential lighting fixtures 356 General Industrial Machinery 3C46 Cwnmercial lighting fixtures 3361 Pumps and pumping equipment 3647 Vehicular lighting equipment 3562 Ball and roller bearings 3643 Lighting equipment, nee 3563 Air and gas compressors 365 Radio and TV Receiving Equipment 3564 Blowers and fans 3651 Radio and TV receiving sets 3565 Industrial patterns 3652 Phonograph records 3566 Speed changers, drives, and gears 366 Communication Equipment 3367 Industrial furnaces and ovens 3661 Telephone and telegraph apparatus 336S Power transmission equipment, nee 3662 Radio and TV communication equipment 3569 General Industrial machinery, nee 367 Electronic Components and Accessories 357 Office and Computing Machines 3671 Electron tubes, receiving type 3572 Typewriters 3672 Cathode ray television picture tubes 3573 Electronic computing equipment 3673 Electron tubes, transmitting 3574 Calculating and accounting machines 3674 Semiconductors and related devices 3576 Scales and balances, esc laboratory 3675 Electronic capacitors 3579 Office machines, oec 3676 Electronic resistors 358 Refrigeration and Service Machinery 3677 Electronic coils and transformers 3581 Automatic merchandising machines 3678 Electronic connectors 35S2 Commercial laundry equipment 3679 Electronic components, nee 3555 Refrigeration and heating equipment 369 Misc. Electrical Equipment & Supplies 3556 Measuring and dispensing pumps 3691 Storage batteries 3589 Serrice industry machinery, nee 3692 Primary batteries, dry and wet 359 Misc. Machinery, Except Electrical 3693 X-ray apparatus and tubes 3592 Carburetors, pistons, rings, valves 3694 Engine electrical equipment 3599 Machinery, except electrical, nee 3699 Electrical equipment & supplies, nee 36 ELECTRIC AND ELECTRONIC 37 TRANSPORTATION EQUIPMENT EQUIPMENT 371 Motor Vehicles and Equipment 361 Electric Distributing Equipment 3711 Motor vehicles and car bodies 3612 Transformers 3713 Truck and bus bodies 3613 Switchgear and switchboard apparatus 3714 Motor vehicle parts and accessories 362 Electrical Industrial Apparatus 3715 Truck trailers 3621 Motors and generators 372 Aircraft and Parts 3622 Industrial controls 3721 Aircraft 3623 Welding apparatus, elecdlc 3724 Aircraft engines and engine parts 3624 Carbon and graphite products 3728 Aircraft equipment, neo 3629 Electrical industrial appnmtus, nee 373 Ship and Boat Building and Repairing 363 Household Appliances 3731 Ship building and repairing 3631 Household cooking equipment 3732 Boatbuilding and repairing - . 3632 Household refrigerators and freezers 374 Railroad Equipment 3633 Household laundry equipment 3743 Railroad equipment 3634 Electric housewares and fans 375 Motorcycles, Bicycles, and Parts 3635 Household vacuum cleaners 3751 Motorcycles, bicycles, and parts 3636 Sewing machines ' 376 Guided Missiles, Space Vehicles, Parts 3S39 Household appliances, nee 3761 Guided missiles nnd space vehicles Code Short Title Code Short Title 3764 Spae* propulsion unit* and ports 39 MISCELLANEOUS MANUFACTURING 3769 Space vehicle equipment, nee INDUSTRIES 379 Miscellaneous Transportation Equip 391 Jewelry, Silverware, and Plated Ware ment 3911 Jewelry, precious metal 5792 Travel trailers and campers 39H Silverware and plated ware 87S5 Tanks and tank components 3915 Jeweltrs' materials & lapidary work SitS Transportation equipment, nee. 393 Musicai Instruments 3931 Musical instruments 3S INSTRUMENTS AND RELATED 394 Toys and Sporting Goods PRODUCTS 3942 Dolls 281 Engineering £ Scientific Instruments 3944 Games, toys, and children's vehicles 3811 Engineering & scientific instruments 3949 Sporting and athletic goods, nee 382 Measuring and Controlling Devices 395 Pens, Pencils, Office and Art Supplies 3822 Environmental controls 3951 Pens and mechanical pencils 3823 Process control instruments 3824 Fluid meters and counting devices 3952 Lead jj*ncils and art goods 3825 Instruments to measure electricity 3953 Mark-lag devices 3839 Measuring i- controlling devices, aec 3955 Carbon paper and inked ribbons 383 Optical Instrument* and Lenses 396 Costume Jewelry and Notions 3832 Optical instruments and lenses 3961 Costume jewelry 384 Medical Instruments and Supplies 3962 Artificial flowers 3341 Surgical and medical instruments 3963 Buttons 3842 Surgical appliances and supplies 39C4 Keedl<;$, pins, and fasteners 3843 Dental equipment and supplies 399 Miscellaneous Manufactures 385 Ophthalmic Goods 3991 Broom.; and brushes 3851 Ophthalmic goods 38S Photographic Equipment and Supplies 3993 Signs and advertising displays 3861 Photographic equipment and supplies 3995 Burial caskets 387 Watches, Gocks, and Watchcases 3995 Hard surface floor coverings 3873 Watches, clocks, and watchctsei 3999 Manufacturing industries, nee 48 COMMUNICATION 46 PIPE LINES, EXCEPT NATURAL GAS 481 Telephone Communication 461 Pipe Lines, Except Natural Gas 4811 Telephone communication 4612 Crcde petroleum pipe lines 482 Telegraph Communication 4613 Refined petroleum pipe lines 4821 Telegraph communication 4619 Pipe lines, nee 483 Radio and Television Broadcasting 4832 Radio broadcasting 47 TRANSPORTATION SERVICES 4833 Television broadcasting 489 Communication Services, nee 471 Freight Forwarding 4899 Communication services, nee 4712 Freight forwarding 472 Arrangement of Transportation 49 ELECTRIC, GAS, AND SANITARY 4722 Passenger transportation arrangement 4723 Freight transportation .irraniemcnt 491 Electric Services 474 Rental of Railroad Cars 4911 Electric services 4742 Railroad car rental with service 492 Gas Production and Distribution 4743 Railroad car rental without service 4922 Natural ffns transmission 478 Miscellaneous Transportation Services 4923 Gas transmission and distribution 4782 Inspection n.nd weighing services 4924 Natural gas distribution 4783 Packing nnd crating 4925 Gas production and/or distribution 4784 Fixed facilities for vehicles, nee 493 Combination Utility Services 4788 Transportation services, nee 4931 Electric and other services combined 4932 Gas and otbsr Miriccs combined 10 4939 Combination utility services, nee 494 Water Supply 75 AUTO REPAIR, SERVICES, AND 4941 Water supply GARAGES 495 Sanitary Services 4952 Sewerage systems 751 Automotive Rentals, Without Drivers 4953 Refuse system* 7512 Passenger car rental and leasing 4959 Sanitary services, oec 7513 Truck rental and leasing 4% Steam Supply 7519 Utility trailer rental 4961 Steam supply 752 Automobile Parking 497 Irrigation Systemn 753 Parking lota 4971 Irrigation systems 7525 Parking structures 751 Automotive Repair Shops 51 WHOLESALE TRADE NONDURABLE 7531 Top and body repair shops GOODS 7534 Tire retreading and repair shops 511 Paper and Paper 'Products 7535 Paint shops 5111 Printing and writing paper 5112 Stationery supplies 7531 General automotive repair shops 5113 Industrial & personal service paper 7539 Automotive repair shops, nee 512 Drugs, Proprietaries, and Sundries 754 Automotive Services, Except Repair 5122 Drugs, proprietaries, and sundries 7542 Oar washes 513 Apparel, Piece Goods, and Notions 7549 Automotive services, n«c 5133 Piece goods 5134 Notions and other dry goods 5136 Men's clothing and furnishings 76 MISCELLANEOUS REPAIR SERVICES 5137 Women's and children's clothing 762 Electrical Repair Shops 5139 Footwear 7622 Radio and television repair 514 Groceries and Related Products 7623 Refrip.'r.ition service nnU repair 5141 Groceries, general line 7629 Electrical repair shops, nee 5142 Frozen foods 76S Watch, Clock, and Jewelry Repair 5148 Dairy products 7631 Watch, clock, and jewelry repair 5144 .Poultry and poultiT products 764 Reupholstery and Furniture Repair 5145 Confectionery 7641 Beupholstery and furniture repair 5146 Fish and seafoods 769 Miscellaneous Repair Shops 5147 Meats and meat products 7692 Welding repair 5148 Fresh fruits and vegetables 7694 Armature rewinding shops 5149 Groceries and related products, nee 7699 Repair services, nee 515 Farm-Product Ran1 Materials 5152 Cotton 5153 Grain 80 HEALTH SERVICES 5154 Livestock 801 Offices of Physicians 5159 Farm-product raw materials, nee 8011 Offices of physicians 516 Chemicals and Allied Products 802 Offices of Dentists 5161 Chemicals and allied products 8021 Offices of dentists 517 Petroleum and Petroleum Products 5171 Petroleum bulk stations & terminals ?03 Offices of Osteopathic Physicians 5172 Petroleum products, nee S031 Offices of ostenpathic physicians 804 Offices of Other Health Practitioners 518 Beer, Wine, and Distilled Beverage* 8041 Offices of chiropractors 5181 Beer and ale 3042 Offices of optometrists 5182 Wines and distilled beverages 8049 Offices of healih practitioner?, nee 519 Miscellaneous Nondurable Goods SOS Nursing and Personal Care Facilities 5191 Farm supplies 8051 Skilled nursing care facilities 5194 Tobacco and tob*e:o products S059 Xursins find personal care, nee 5198 Paints, varnishes, and supplies 806 Hospitals 5199 Nondurable foods, nee 11 8062 General medical k surreal hospital* 8063 Psychiatric hospitals 8069 Specialty hospitals, e«. psychiatric 807 Medical and Dental Laboratories 8071 Medical laboratories 8072 Dental laboratories 808 Outpatient Care Facilities 8081 Outpatient care facilities 809 Health and Allied Services, nee 8091 Health and allied services, nee 82 EDUCATIONAL SERVICES 821 Elementary and Secondary Schools 8211 Elementary and secondary schools 822 Colleges and Universities S221 Colleges and universities, nee 8222 Junior colleges 823 Libraries and Information Centers S231 Libraries and information centers 824 Correspondence and Vocational Schools 8241 Correspondence schools 8243 Data processing schools 8244 Business and secretarial schools S249 Vocational schools, nee 829 Schools & Educational Service*, nee 8299 Schools & educational services, n«c 84 MUSEUMS, BOTANICAL, ZOOLOG ICAL GARDENS 841 Museums and Art Galleries 8411 Museums and nrt galleries 842 Botanical and Zoological Gardens 8421 BotanicAl and ecological gardens APPENDIX III Development of the Environmental Hazardous Substance List In 1978, the New Jersey Department of Environmental Protection Industrial Survey Project under N.J.A.C. 7:IF, it developed a Selected Substance List of 155 chemicals with the advice of the Department of Health. Three major criteria were used to evaluate candidate substances for inclusion on the Selected Substances List, N.J.A.C. 7: IF - Appendix A: evidence of a chronic health effect such as carcinogenicity, mutagenicity and/or teratogenicity; evidence of production in commercial quantities in the United States; and the presence on the United States Environmental Protection Agency (EPA) Priority Pollutant List. The Selected Substance List included several compounds that were no longer commercially produced (e.g., Kepone, DDT, PCBs) since the Department was also surveying past disposal practices. In order to determine which substances from the Industrial Survey should be included for purposes of the Community and Worker Right to Know Act on the Environmental Hazardous Substance List and which others should be added, the Department conducted a search of the scientific literature, using sources such as the National Toxicology Program status reports, the International Agency for Research on Cancer monograph series, and Fishbein's Potential Industrial Carcinogens and Mutagens and also considered structural analogues of known carcinogens. The Department sought information about candiate chemicals in the following areas: 1. The amount of the chemical commercially produced in the United States, as well as the amount imported and exported; 2. The major commercial uses for the chemical; 3. The possible health effects resulting from exposure to the chemical based on epidemiological data on humans and data collected from animal assays, with particular attention to chronic health effects such as carcinogenicity, teratogenicity and mutagenicity; 4. The environmental fate of the chemical such as its ability to bioaccumulate in animals and fish, its solubility in water, its vapor pressure, and its persistence in environmental media (air, water and soil); 5. The regulation of the chemical by federal agencies (Occupational Safety and Health Administration, EPA, Department of Transportation) and the New Jersey Department of Environmental Protection; and 6. The number of companies in New Jersey reporting production or use of the chemical, as well as the amounts reported in New Jersey's Industrial Survey. After searching the literature, the Department reviewed the data to determine whether substances on the Selected Substances List should be retained or deleted from the Environmental Hazardous Substance List, whether new substances should be added, or whether they should be omitted because of insufficient data. Decisions were based on the requirement that every substance chosen must meet two criteria. Criteria 1: Evidence of a significant rate of use, production, or importation in the United States and, in particular, New Jersey. The Department considered 10,000 Ibs., or more, a year to be significant. Criteria 2: Evidence of at least one of the following health or environmental effects: carcinogenicity, teratogenicity, mutagenicity, acute toxicity, persistence, or ability to bioaccumulate. Fifty-eight substances on the Selected Substance List did not meet both criteria and were, therefore, not included in the Environmental Hazardous Substance List. Ninety-seven substances were retained. The Department also developed a list of 51 additional substances which met both criteria out of 113 candidates. The proposed Environmental Hazardous Substance List, therefore, totals 148 substances. The detailed information compiled for each of the substances on the proposed list is contained in Appendix IV: "The Environmental Hazardous Substance List - a Breakdown by Chemical Category of Usage, Health Effects, Environmental Parameters and Regulations." Appendix V illustrates the process used in selecting the substances. APPENDIX IV The Environmental Hazardous Substance List: A Breakdown by Chemical Category of Usage, Health Effects, Environmental Parameters, and Regulations GLOSSARY ACGIH - American Conference of Governmental Industrial Hygienists adenoma - A benign tumor originating in a secretory gland. allergen - A substance capable of inducing an allergy or specific hypersensitivity. bioaccumulation - The sorption and storage of the unchanged subject chemical by an organism. carcinogen - A substance capable of producing cancer. CL - Ceiling Limit cocarcinogen - A substance which induces a synergistic effect in the carcinogenesis process. DOT - United States Department of Transportation edema - The effusion of serous fluid into the interstices of cells in tissue spaces or into body cavities. embryolethal - A substance which is transplacental and lethal to the embryo. embryotoxic - A substance which is transplacental and toxic to the embryo. EPA - United States Environmental Protection Agency equivocal - Some evidence of tumorigenic activity present but all tumorigenie necessary criteria not fulfilled. agent PDA - United States Food and Drug Administration fetotoxic A substance which is transplacental and toxic to the fetus. G.I. Gastrointestinal half-life Time required for a given substance to be reduced by 50%. hemangiosarcoma A malignant tumor formed by proliferation of endothelial and fibroblastic tissue. hemolytic Capable of breaking down red blood cells with the liberation of hemoglobin. hepatoma - A tumor of the liver. hydrolyzed - Hydrolysis is a chemical reaction in which water reacts with another substance to form two or more new substances, I ARC - International Agency for Research on Cancer in vitro - Within an artificial environment, such as a test tube. in vivo - Within a living organism. LC50 - Lethal Concentration, 50% (that quantity of a substance administered by inhalation that is necessary to kill 50% of the test animals exposed to it within a specified time.) LDLO - Lethal Dose Low (lowest dose, other than LD50, to cause death in humans or animals). LD50 - Lethal Dose, 50% (that quantity of a substance at which 50% of the test animals are killed.) leukemogen - An agent (e.g. chemical, virus) capable of inducing leukemia. lymphoma - A tumor arising from any of the cellular elements of the lymph nodes. methemoglobine- - A blood disorder resulting in cyanosis. mia mutagen A substance capable of inducing a mutation. NCI National Cancer Institute NIOSH National Institute of Occupational Safety and Health NTP National Toxicology Program ORM - A Other Regulated Material, Class A ORM - E Other Regulated Material, Class E OSHA Occupational Safety and Health Administration PEL Permissible Exposure Limit photoallergic A photoallergy is an allergic-type sensitivity to light. photochemical A chemical capable of absorbing radiant energy (light) which induces or modifies the chemical's structure, reactivity, stability, or other properties. 11 photolysis - Decomposition of a compound into simpler units as a result of absorbing light. photosensitizer - A substance capable of inducing an abnormal reactivity to sunlight. POTW - Publicly Owned Treatment Works priority - The 126 toxic chemicals for which EPA is required to pollutants promulgate discharge control standards. promoter - A chemical which acts in conjunction with another chemical to enhance or promote the carcinogenic action of the other chemical. RCRA - Resource Conservation and Recovery Act RPAR - Rebuttable Presumption Against Registration s arcoma - Any of various malignant tumors originating in the connective tissue and attacking especially the bones. SCE - Sister chromatid exchange SDWA - Safe Drinking Water Act STEL - Short-term Exposure Limit TCLO - Toxic Concentration Low (inhalation only) TDLO - Toxic Dose Low (all exposure routes except inhalation) teratogen - A substance that can cause a morphologic, biochemical, or functional abnormality in the developing fetus. TLV - Threshold Limit Value tumorigen - A substance capable of producing tumors. TWA - Time Weighted Average TXF : IRR - Toxic effect - irritant TXF : CNS - Toxic effect - central nervous system TXF : SYS - Toxic effect - systemic 111 ACIDS AND ACID CHLORIDES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Acrylic Acid 1976 - Production Approximately 83% is used Acute: Aquatic Toxicity Rating: ACGIH Recommendation: 79-10-7 2.57 x 10 by three captively as a precursor of Eye, skin, and LC50 :100-10 ppm (43) 10 ppm (7) Liquid companies (28) acrylates; the remaining 17% was respiratory irritant used for miscellaneous in humans (43) Solubility in water: EPA: applications, including the Rat Miscible (28) Hazardous Waste (54) production of water-soluble resins LD -340 mg/kg (oral) Reportable (« Benzoyl 1975 - Production In 1974, 57% was used as a Acute: Aquatic Toxicity Rating: EPA: chloride 1.6 x 10 (est.) chemical intermediate in the Irritant to skin, LC 96:1000 100 ppm (7) Hazardous Waste (80) 98-88-4 by two (43) synthesis of benzoyl peroxide; eyes, and mucous Reportable Liquid companies 39% in synthesis of herbicides membranes (43) Solubility in water: quantities (89) (chloramben); 3% in synthesis of Moderately toxic Decomposes to benzoic acid Hazardous water 1980 - Imports , dyes (Vat Yellow 3); and 1% in by ingestion or and HCl (3a) pollutant designa 8.8 x 10 (38) the synthesis of plasticizers inhalation (43) tion S harmful and drugs. (38) Vapor pressure at 20°C: quantities (80) Chroni c: 0.4 mm (38) Limited evidence that DOT: employment in the Generates toxic fumes: Corrosive (7) product, ion of benzoyl (phosgene) when heated (43) chloride is a carcinogenic risk to humans (30) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physi_ca 1 State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ____Regulations Phosgene 1975 - Production In 1973, 62% is used to produce Acute: Solubility in water: OS HA: -j n in" 11.i\ Mildly irritating TUA * fl" 1^ rrr,r,m (-!\v j dirhloride) used to produce polymethylene to mucous membranes CO and HCI, (4c) 75-44-5 N.J. Industrial Survey polyphenyliisocyanate; 4% is in concentrations NIOSH Recommendation: Gas (1978-79): used to make polycarbonate below 10 ppm. Very Vapor pressure at 20°C: CL0.02 ppm/15 min (7) Produced - 1-5 x 10 tyr resins; 10% for miscellaneous irritating to the 1215 mm (43) Purchased - 1-5 x 10 /yr applications in the synthesis of entire respiratory EPA: (84) methyl isocyanate, tract in considerably Hazardous Waste (54) diphenylmethane-4,4' higher concentrations Reportable -diisocyanates, chloroformate Brief exposure to 50 quantities (89) esters, and dimethyl carbamoyl ppm can be rapidly Hazardous water chloride. (43) fatal (64c). pollutant designa tion & harmful Chronic: quantities (80) Pulmonary edema (64c) DOT: Poison A (54) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations Dimethyl - One producer less than Only known use is as a chemical Acute: EPA: carbamoylchloride 100/yr. (21) intermediate in the production of Rats Hazardous Waste (54) 79-44-7 drugs and pesticides. (21) LD :1170 mg/kg (oral) Reportable Liquid (217 quantities (89) LC :180 ppm (inhalation) (7) DOT: Hazardous Materials Chronic: table (80) Carcinogen in mice by skin application or by subcutaneous or interperi toneal injection (21) Mutagen in bacteria (21) ALDEHYDES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronraental Physical^ _State_ _in the U.S. (Ibs./yr.)______Uses______Effects Parameters __Regulations__ Acetaldehyde 1975 - Production In 1973, 50% was used to Acute: Solubility in water: OSIIA: 75-07-0 8.8 x 10 synthesize acetic acid and acetic Eye irritant and to a Miscible (43) Air: Liquid anhydride; 14% was used to lesser extent nose TWA 200 ppm (7) - Imports synthesize n-butanol; 11% was and throat irritant Vapor pressure at 20°C: 9,000 (43) used to synthesize 2-ethylhexanol; (64a) 740 mm (43) ACG1H Recommendation: 25% for miscellaneous uses TLV-TWA 100 ppm including the synthesis of Chronic: Atmospheric Residence time: STEL 150 ppm (7) pentaerythritol, pyridenes, Equivocal tumorigenic 0.03-0.7 days (44) peracetic acid and crotonalde- agent in hamsters (7) EPA: hyde (43) Mutagen in bacterial Persistence in water: Hazardous Waste (54) and mammalian Biodegrades (43) Reportable cell assays (43) quantities (89) Chromosome aberrations Photolysis in air: National Oil & produced in vitro; Probable (44) Hazardous Substances chromatid exchanges Contingency Plan produced in vivo. (43) (80) Pesticide residue tolerance (80) Hazardous water pollutant designa tion & harmful quantities (80) DOT: Flammable liquid (54) FDA: Food contact component (80) Synthetic Food ! 'layering (80) DOT: Cargo of particular hazard (80) Dangerous cargo (80) Toxic cargo (80) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses______Effects Parameters __Regulation s_ Acrolein 1974 - Production 6.1 x 10 70% as an intermediate in Acute: Aquatic toxicity rating: OSHA: (2-Propenal) Additional production synthesis of acrylic acids and A powerful irritant, LC 96 .-under 1 ppm (7) Air 107-02-8 of 9.92-15.0 x 10 as esters; 17% in synthesis of and highly toxic to TLV-TWA-100 ppb Liquid transitory unisolated methionine; 5% for misc. uses man via inhalation. Bioaccumulation: STEL-300 ppb (7) intermediate (28) including as an aquatic herbicide, Humans: Log octanol/water biocide, slimicide (43) LD :153 ppm/10 min. Partition coefficient EPA: N.J. Industrial Survey Moderately toxic via -0.09 (8) Priority Pollutant (1978-79): skin exposure (2d) (8) Produced - 0 Solubility in water at 20°C: Reportable Purchased - 1-5 x 10 (84) Chronic: 20.8% soluble in water (8) quantities (89) Mutagen in bacteria Hazardous waste (54) (7) Persistence: Hazardous water Mutagen in In aqueous environments pollutant designa mammalian cell half-life is less than 1 tion & harmful assays (7) day (8) quantities (80) Vapor pressure at 20°C: FDA: 215-220 mm (8) Food starch modifier (80) Atmospheric residence time: 0.2 days (44) DOT: Detection in environmental Hazardous materials media: table (80) Industrial wastewaters and intakes. USEPA - 0.9% (78) NJDEP (OSR) - Not detected (82) Potable water, raw and treated: NJDEP (OSR) - 0/492 (86) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Formaldehyde 1979 - Production 60% for plastics and resin Acute: Aquatic toxicity rating: OSHA: 50-00-0 5.36 x 10 manufacture ^urea -forma luehyue Highly irritating Lu LC _9o : iGG-iG ppiii ^7 } t\L L I Gas (37% by weight soln.) resins, phenolic resins , skin, eyes and mucous TWA-3 ppm (38) polyacetal resins and melamine membrane (2d) Solubility in water: CL-5 ppm resins); 22% for the production Woman Miscible (38) Peak- 10 ppm/30 rain./ 1975 - Imports of intermediates (in manufacture LD -36 mg/kg (oral) 8 hr. (7) 1 x 10 of acetylenic chemicals, or Vapor pressure at -33°C: (37% by weight soln.) pentaerythritol, 400 mm (38) N10SH Recommendation: hexaraethylenetetramine, and Chronic: CL-1 ppm (54) urea-formaldehyde concentrations); Prolonged exposure Atmospheric residence time: 1975 - Exports 18% for misc. uses such as the can cause hypersensi- 0.1-1.2 days (44) EPA: 2.8 x 10' production of tivity leading to Hazardous waste (54) (37% by weight soln.) diphenyImethanediamine and 4,4'- contact dermatitis. Reportable methylenediphenyl diisocyanate An allergen (2d) quantities (89) chelating agents and National Oil & N.J. Industrial Survey Trimethylolpropane. (38) Sufficient Hazardous Substances (1978-79): . evidence that it is a Contingency Plan Produced - 1-5 x 10 carcinogen in animals (80) Purchased - 1-5 x 10 (84) (42) Pesticide residue tolerance (80) Mutagen in viruses, Hazardous water bacteria, vascular pollutant designa plants, fungi, and tion & harmful insects (42) quantities (80) Mutagen in mammalian PDA: cell assays (7) Food contact component (80) Feed additive (80) CPSC: Sensitizer (80) DOT: Hazardous materials table (80) ALIPHATIC HYDROCARBONS Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phyj5iral State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters __ Regulations 1,3-Butadiene 1972 - Production As polymer component in the Acute: Solubility in water: OSHA: 106-99-0 3.53x10 manufacture of synthetic rubber Irritating to skin Insoluble (64b) TLV-TWA 1,000 ppm (7a) - Imports (5) and mucous membranes. 4.3x10 (43) In acrylonitrile - butadiene - (64b) Vapor Pressure at 21°C: DOT: styrene resins (43) 1840 mm (43) Cargo of particular Humans hazard (80) TC :8,000 ppm Flammable cargo (80) (inhalation) (7b) Hazardous materials table (80) Chronic: Mutagenic in bacteria (7b) Carcinogenic in mice via inhalation (91) AMIDES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses______Effects Parameters _Re_guJ a tjL ons Acetamide N.J. Industrial Survey Used as a solvent for many Acute: Solubility in water at 25°C: 60-35-5 (1978-1979): organic and inorganic compounds; Rat 1 gm/0.5 mg water (16) Solid Produced - 0 as a wetting agent and LD :7000 rag/kg Purchased - 0 penetration accelerator for dyes (oral) (7b) Vapor Pressure at 105°C: Max. Inventory - 0 (84) in the textile industry; in area 10 mm (43) molding compounds; as a Chronic: plasticizer in leather, cloth, Carcinogenic in rat and coatings; and an antiacid in via oral route causing the lacquer, explosives and liver tumors. (16) cosmetics industries; as a humecant for paper; as a chemical Positive in cell intermediate in the synthesis of transformation assay. methylamine, thioacetamide, (7) acetoacetamide, various plastics, pesticides, and medicinals; and as an activator in bleach liquors. (1) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _Rfijgu Ijit i qns Benzarai de N.J. Industrial Survey Organic synthesis (6) Acute: Solubility in water: 55-21-0 (1978-1979): Mouse 1 gm/74 ml water (5) Solid Produced - 0 LD :1160 mg/kg 50 Purchased - 0 (oral) (7b) Max. Inventory - 0 (84) 10 ANHYDRIDES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regu 1_al ions______ Maleic anhydride 1975 - Production 44% as an intermediate in Acute: Solubility in water: OSHA: 108-31-6 2.00 x 10 synthesis of unsaturated Irritating to skin, Forms maleic acid (3c) Air: Solid polyester resins; 13% in eyes and mucous TLV-TWA-250 ppb (7) 1975 - Imports , synthesis of fumaric acid; 11% membrane. Vapor pressure at 440°C: 5.01 x 10 in synthesis of argicultural Inhalation of vapor 1 mm (3c) EPA: chemicals (nialeic hydrazide and can cause pulmonary Hazardous Waste (54) 1975 - Exports malathion); 8% for synthesis of edema. (3c) Atmospheric residence time: Reportable 9.26 x 10 (43) lubricating oil additives; 6% 0.1 days (44) quantities (89) for synthesis of copolymers; 4% Chronic: Pesticiide residue N.J. Industrial Survey for synthesis of maleic acid; 3% Repeated exposure to tolerance (80) (1978-79): for synthesis of alkyd resins; 2% concentrations above Hazardous water Produced - 1-5 x 10 /,yr for synthesis of chlorendic 1.25 ppm has caused pollutant designa Purchased - 1-5 x 10 /yr anhydride; 4% for misc. asthmatic responses tion & harmful (84) application including synthesis in workers. (54) quantities (80) of succinic acid and surface-active agents. (43) DOT: ORM - A (54) FDA: Food contact component (80) 11 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr. )______Uses______Effects Parameters __Reguljat ions Phthaiic Used in the manufacture of Acute: Aquatic Toxicity Rating OSHA: anhydride phthaleins, benzoic acid, alkyd Potent irritant of LC5Q96:100-10 ppm (7) Air 85-44-9 and polyester resins, synthetic the eyes, skin, and TWA 2 ppm (7) indigo, and phthalic acid. respiratory tract (54) Solubility in water: 1/162 parts water (43) ACG1H Recommendation: Also used in the production of Chronic: TWA 1 ppm alizarin dye, anthranilic acid, Repeated exposure STEL 4 ppm (7) anthraquinone, diethyl phthalate, may result in dimethyl phthalate, erythrosin, bronchitis, emphysema, EPA: isophthalic acid, methylaniline, allergic asthma, Hazardous Waste (54) phenolphthalein, phthalamide, urticoria and chronic National Oil & sulfathalidine, and terephthalic eye irritation. (54) Hazardous Substances acid. Contingency Plan (80) It is also used as a pesticide Reportable intermediate (54) quantities (89) FDA: Food contact component (80) DOT: Hazardous Materials Table (80) 12 AROMATIC AMINES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phy s i ca 1 _S ta te_ _in the U.S. (Ibs./yr.) Uses_____ Effects Parameters Regulations Ani1ine 1979 - Production In 1979, 50% was used for the Acute: Aquatic Toxicity Rating: OSHA: 62-53-3 6.9 x 10B production of 4,4'-methylenediphenyl Absorbed readily LC5()96: 100-10 ppm (7) Ai r oily liquid - Imports . diisocyanate (MDI) and polymethylene through skin and TI.V-TWA 5ppm (7) 4.3 x 10 (36) polyphenyl isocyanate; 27% for G.I. tract (43) Solubility in water at 25°C: production of rubber chemicals; 6% 3.5% (36) ACGIH Recommendation: Two N.J. manufacturers for synthesis of dyes and Human TWA 2ppm (7) in 1979 (43) intermediates; 5% for hydroquinone LD:50mg/hg (oral) Vapor pressure at 25°C: production, 3% for production of (43) 0.67 mm (43) EPA: N.J. Industrial Survey drugs; and 9% for miscellaneous Rat Hazardous Waste (1978-79): , applications, including production LD50:440mg/kg (oral) (54) Produced - 1-5 x 10 fi of herbicides and fibers. (36) LCLO:250ppm/4hr. Purchased - 5-10 x 10 (Inhalation) (43) National Oil & (84) Few dyes based on aniline are Hazardous Substances produced in commercial quantities Chronic: Contingency Plan (36). Limited evidence of (80) animal carcinogenicity in rats (36) Reportable quantities (89) Not mutagenic in bacterial and yeast Hazardous water assays. (36) pollutant designa tion & harmful Conflicting results quant i t ies (80) in mammalian cell assays. (36, 7) DOT: Hazardous material (54) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental SLate in the U.J3. (Ibs./yr.) Uses______Effects Parameters ___ Regulations ______o-Ani sidine Three companies Mainly used in the manufacture of Acute: Solubility in water: OSHA: (2-aminoanisole) reported production dyes (43) Moderately toxic. Slightly miscible (36) TLV-TWA 0.1ppm (2-methoxyaniline) in 1977, two companies A mild sensitizer, (43) 90-04-0 in 1978, and one in Also used as an intermediate in the on local contact Vapor pressure at 132°C: liquid 1979. (36) manufacture of synthetic guaiacol can cause a contact 40mm (36) (This standard is (36) dermatitis and can for the mixed Not thought to be be absorbed ortho and para made in the U.S. A total of 45 dyes and pigments can systemically via isomers) (43) in 1982 (36) be made from this chemical, only skin. (2e) nine were produced commercially in DOT: 1979 - Imports , U.S. in 1979 (36) Rat LD -2000 mg/kg Hazardous materials 2.6 x 10 (oral) 77) table (80) (36) Mouse LD : 1400 mg/kg (oral) (71 Chroni c: Sufficient evidence of carcinogenicity in mice and rats. (36) Mutagenic in bacteria (36) 14 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State_ in the U.S. (Ibs./yr.) Uses______Effects Parameters Re g u Lj t ion s_ p-Arii s i dine Not currently An intermediate in the manufacture Acute: Solubility in water: OSHA: Q (p-net Doxy am line) produced in the ot dyes (36) Moderately toxic soluble (36) Air:TWA 500ug/nf 104-94-9 U.S. (36) via oral route. (7) Seven dyes and pigments can be A mild sensitizer 1979 - Imports prepared from it. Two were Local contact may ACG11I Recommendation: 4 x 10 (36) produced commercially in U.S. in cause a contact TLV-TWA 0. Ippm 1979: Azoic Coupling Component 11 dermatitis (2e) (skin) (43) Previously and Pigment Red 190. (36) produced in N.J. Rats LD : I400mg/kg (43) (oral) t ) Mouse LD : 810mg/kg (36) Chronic: Not mutagenic in bacteria (36) Negative in cell transformation assay (36) Positive in mammalian cell assay (7) NCI Carcinogenesis bioassay was negative in mice, indefinite in rats (7) 15 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phys u:a 1 __State_ in the U.S. (Ibs./yr.) Uses_____ Effects Parameters ___Regulations Benzicline Last commercial Principal commercial use is for the Acute: Aquatic Toxicity Rating: OSHA: 92-87-5 production of production of direct azo dyes; the Rats LD50:309mg/kg LC5096:10-lppm (7) Carcinogen (7) sol id benzidine in U.S. quantities of benzidine-based dyes (oral) was in 1976 by one produced have been decreasing Mice LD50:214mg/kg Solubility in water at 12°C: EPA: company. steadily. In 1979, only 16 out of (oral) (43) 400 mg/1 (38) Priority Pollutant 232 benzidine-based dyes were produced (8) Currently, benzidine or imported in U.S. (38) Chronic: Bioaccumulation: Hazardous Waste dihydrochloride is A human carcinogen log octanol/water (54) the only form Minor uses include detection of blood, causing bladder partition coefficient commercially produced, in rubber industry, in adhesives and cancer (42) 1.81 (8) Not Reportable quantities and this was as an plastics industry (38). bioaccumulated. (8) (89) imisolated intermediate Animal carcinogen by one U.S. Company. Free benzidine is present in benzidine in mice, rats, Persistence: Effluent standards (38) derived azo dyes in concentrations hamsters and dogs. water-rapidly (80) usually below lOppm. (54) (38) oxidized by 1980 - Imports naturally occurring DOT: 9 x 10 (38) Mutagen in bacteria cations. (8) Poison B (54) fungus, and mammalian N.J. Industrial Survey cell culture. Some Detection in environmental OSHA: (1978-79): reports of in v^ivo media: Manufacturing & Production - 0 mutagenicity (42,38) Industrial Wastewater handling (80) Purchased - 0 and influents (84) USEPA - 0.21% (78) DOT: NJDEP (OSR) - 0/28 (82) Hazardous materials table (80) Potable Water NJDEP (OSR) - 1/245 (86) POTWS NJDEP (OSR) influents - 0/9 effluents - 0/9 sludge - 0/9 (RR) Substance Name (Synonym) Amount Produced Ma jor CAS Number Imported, Exported Commercial Health Environmental Phys i fa \_ State_ _ in the U.S. (Ibs./yr.) Uses Effects Parameters _Jtegulatiqns__ 2-Bipheriylamine 1971 - Production A chemical intermediate for Acute: Solubility in water: Probably carbazole, resins, and Kat i'l>, n :: 2340 mg/kg Insoluble (43) (o-aminodiphenyl) i ~\ ^ V " 90-41-5 greater than synthetic resins (43) ( oral-} \ i'a) sol id 1000 (43) Chronic: NCI bioassay - induced hemangiosarcomas at various sites in mice (7b) Mutagen in bacteria (7) Positive in cell transformation assay (7) 17 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State_____in the U.S. (Ibs./yr.) Uses______Effects______Parameters______I*?gulat.ions______ 4-Chloro-m- Production - one Used as a dye intermediate and Acute: Solubility in water: phenylenediamine U.S. Company rubber-processing agent. (36) slightly soluble (43) 5131-60-2 presently produces undisclosed amounts There is no evidence that it is Chronic: (36) used commercially in the U.S. as Data is a dye or dye intermediate (36) inadequate to 1970 - Imports evaluate 10 (36) Used in chemical research (43) carcinogenicity (36) Mntageii in bacterial assay (74) 18 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters _Regulations 4-Chloro-o- Presently produced Has been used as a dye intermediate Acute: Solubility in water: phenylenediamine by one U.S. Company No evidence that it is presently Slightly soluble (36) (4-Chloro-l ,2 (36) employed commercially as a dye or benzenediamine) as a dye intermediate (36) Chronic: 95-83-0 1977 - Production Sufficient evidence solid 1-10 x 10 of carcinogenicity (53) in animals (36) Reported to be Mutagen in bacterial produced in New assays. (36) Jersey (43) 19 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State _i!!Li!i? U.S. (Ibs./yr.) Uses_____ Effects Parameters ____ _Regulations _ p-Cresidine 1979 - Production Intermediate for dyes (FD&C Red 40 Acute: Solubility in water: (5-methyl- 1-10 x 10 and Direct Violet) (43) Rat LD :1450 mg/kg Sparingly soluble in o-anisidine) (orairt36) hot water (43) 120-71-8 1979 - Imports An intermediate for azo dyes and so] i (1 5.9 x 10 (43) pigments including 11 dyes produced Chronic: commercially in U.S. (9) Sufficient evidence of carcinogenicity in mice and rats. (36) Mutagen in bacterial assays (36) Positive in cell transformation assay (7) 20 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Physical State _iii_the U.S. (Ibs./yr.).) Uses Effects Parameters _ Regulations___ 2 ,4-Diamino- No production data Used as a component of hair dyes; Acute: FDA: anisole is available (base) as an intermediate in the Kat 1,1) :460mg/kg Cosmetic labeling 615-05-4 manufacture of one commercially (80) sol id 1979 - Imports significant dye, C.I. Basic Brown (base) (compound & salt) .11 S04 2 x 10 (36) 2. (36) 39T56-41-7 (base) U) :4000mg/kg May also serve as an oxidation base (oral) (36) 1977 - Consumption in fur dyeing (36) (Salt) 3 x 10 (est.) (36) Chronic: (base) Sufficient evidence for carcinogenicity (H2S04 Salt) - Believed in mice and rats to be produced in (salt) (36) commercial quantities by one company (36) Mutagenic in yeast, mammalian cell assays, and Urosophila (36) Hair dye formulation of which this was a component caused skeletal changes in rats (36) 21 Substanre Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses_____ Effects Parameters __Regul_a_tionis______ 2,4-Diamirio- 1980 - Production More than 99% is used captively Acute: Solubility in water: EPA: toluene 2.16 x 10b (9) to produce toluene diisocyanate Rat LD :500mg/kg very soluble in hot Hazardous waste (80) 95-80-7 (9). (oral)'T43) water (43) Reportable sol i(1 - Imports quantities (89) 4 x 10J (9) Also used as an intermediate for Chronic: Vapor pressure at 106.5°C: dyes and as a photographic Carcinogenic in 1mm (43) FDA: N.J. Industrial developer (43). mice and rats via Food-contact Survey (1978-79): oral route (37,25,7) Persistence: component (80) Produced - 0 Easily decomposed in Purchased - 1-5 Mutagenic in wastewater activated DOT: x 10 (84) bacterial assay. sludge treatment Hazardous materials (43) systems. (43) table (80) A weak mutagen in insects. (43) 22 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phys i ca I State e Effects Parameters Regulations 2,5-Dichloro- Dye intermediate (43) Acute: Solubility in water: ani i me Kat Lt> :2900 mg/kg Slightly soluble (43) (C.I. Azoic d i a 7.0 component) (l-Amino-2,5- di chlorobenzene) 95-82-9 sol id 23 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Envi ronmental Physical _Sta_Le___ in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations _. 3,4-DirhIoro- 1975 - Production A chemical intermediate used in the Acute: Solubility in water: aniline greater than production of dyes and herbicides Rat LD -648 mg/kg Practically insoluble 95-76-1 3000 (43) (Diuron and Propanil) (43) (orairt7) (43) sol id Reported to be Mouse LD :740 mg/kg Persistence: produced in N.J. (oral) Slow degradation in (43) agricultural soils. Chronic: May lead to Mutagen in yeast accumulation (43) (7) 24 Substances Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses_____ Effects Parameters Regulations ____ 3 ,3' -Dichloro- 1977 - Production Curing agent for isocyanate - Acute: Solubility in water: OS1IA: benzniine i-iu x 10 by containing polymers; a rubber and nay cause allergic Pure compound is Carcinogen (/b) 91-94-1 two companies plastic compounding ingredient; and skin reactions. (36) almost insoluble (43) sol i d (38) a chemical intermediate for dyes and Rat LD -4740 mg/kg salt - 4mg/l at 22°C (43) EPA: and pigments (43) (oral) Lt43) Priority Pollutant 1980 - Imports Bioaccumulation: (54) 3.2 x 10^ (38) The principal use is as an Chronic: log octanol/water Hazardous Waste intermediate for organic pigments. Sufficient evidence partition coefficient (54) N.J. Industrial The production of these pigments that it is an 3.02 (4b) Survey (1978-79): has remained steady or increased animal carcinogen Reportable quantities Produced - 0 slightly through the 1970s. (38) in mice, rats, Persi stence: (89) Purchased -0.5- hamsters and dogs water-rapidly 1 x 10 (84) via oral administra photodegrades in FDA: tion (38) aqueous solution to Carcinogen (43) give monochloro- Positive in mammalian benzidine (43) OSHA: cell transformation Manufacturing & assay. (43) Detection in environmental handling (80) media. Mutagen in bacteria Industrial wastewater DOT : (42) and intakes Hazardous materials USEPA - 0.12% (78) table (80) NJDEI" (OSR) - 0 (82) Potable water NJBEP (OSR) influents - 0/9 effluents - 0/9 sludge - 0/9 (88) 25 Substances Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical _State_ _in_the U.S. (Ibs./yr.) Uses______E_ffects_ Parameters __ Regulat ions 3,3'-Dimethyl- 1975 - Production A dye intermediate for the Acute: Solubility in water: N10SH Recommendation: benzidinp probably greater production of dyes and pigments; Rat LD r :404 mg/kg Slightly soluble in a i r (o-Tolidine) than 1000. a curing agent for urethane resins; water (10) CL 20ug/m 3 /lhr (7) 119-93-7 and a laboratory reagent for solid Imports detection of blood and gold. (43) Chronic: EPA: 3 x 10 (A3) A carcinogen in rats Hazardous waste (80) via subcutaneous Reportable route. (10) quantities (89) Positive in cell DOT: transformation assay Hazardous materials (7) table (80) Mutagen in bacteria and mammalian cell assays (7) Positive in host mediated assay in rats (7). 26 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses_____ Effects Parameters _____ Regulations__ 4,4'-Methylene 1977 - Production In 1973, 99% was used as a curing Acute: Solubility in water: OS HA: bis (2- greater than agent for isocyanate-containing Can be absorbed almost insoluble (43) Carcinogen (7) cliloroani line) 2 x 10 (43) polymers, 1% is used as a curing through the skin (MOCA) agent for epoxy - urethane resin ACG1H Recommendation: 101-14-4 1976 - Imports blends. (43) Chronic: TWA 0.02 ppm (54) 1 x 10 (43) animal carcinogen in mice and rats EI'A: N.J. Industrial via oral route (13) Hazardous Waste Survey (1978-79): , (54) Produced - 1-5 x 10 r Mutagen in bacteria Reportable Purchased - 1-5 x 10 and mammalian cells. quantities (89) (84) (7) FDA: Food-contact component (80) DOT: Hazardous materials table (80) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental J3t_ate in the U.S. (Ibs./yr.) Uses Effects Parameters _ _Regulations ______ 4,4-Methylene- 1977 - Three Used primarily as a dye intermediate Acute: Solubility in water: bis (N,N-dimethyl) companies produced (36) Mouse LD 3l60mg/kg Insoluble (36) benzenamine 1 x 10 (36) (oral) (36) 101-61-1 Only one dye was produced sol id 1979 - Produced commercially from this substance Chronic : by two in 1979. (36) Limited evidence companies of carcinogenicity (36) in mice and rats. (36) Mutagen in bacteria (36) Caused morphological transformation of hamster embryo cells (36) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phy_siral_ State _in the U.S. (Ibs./yr.) Uses______Effects Parameters ReguVa^t ions 4,4' -Methylene Production is A chemical intermediate in the Acute: ,i, ,.,,; i in* 3.T;2-3.96 x in6 /,, 101-77-9 (92) isocynates and polyisocyanates. (oril) (92) ° These are used extensively in the manufacture of rigid polyurethane Chronic: foams for thermal insulation and NCI Bioassay- in the production of semi flexible carcinogenic polyurethane foams. Also a curing in rats and agent for epoxy resins and urethane mice. (92) elastomers, a dye intermediate, and a cor'rosion inhibitor (92) 29 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmenta1 Physical State__ in the U.S. (Ibs./yr.) Uses_____ Effects Parameters Regu_latiqns__ 1,5-Naphthalene- No evidence that Used almost exclusively as an Acute: Solubility in water: diamine it has ever been intermediate for the manufacture Sparingly soluble in 2243-62-1 produced in of 1,5-naphthalene diisocyanate cold water, soluble sol i 1-Naphthylamine 1975 - Production Used as an intermediate in the Acute: Aquatic Toxicity Rating: OSHA: (Alpha-Naplithylamine) Probably greater manufacture of N-l-naphthylamine-4- Highly toxic to LC5Q96: 10-1 ppm (43) Carcinogen (54) 134-32-7 than 100 (43) su (.phonic acid in coupling agent for humans via ingestion, sol id azo dyes. (1) inhalation, or skin Solubility in water at 25°C: EPA: - Imports . absorption (43) 0.16% (13) Hazardous waste (80) 5.5 x 10 (43) Used in the production of the Keportable herbicide N-1-naphthylaraine - Rat U> :779 mg/kg Vapor pressure at 104.3°C: quantities (89) N.J. Industrial phthalaraic acid. (!) (oral) (43) 1mm (43) Survey (1978-79): , DOT: Produced - 1-5 x 10 Also used to produce the rubber Chronic: Toxic to activated sludge Hazardous materials Purchased - 0 (84) oxidants n-phenyl-1-napthylaraine Inadequate treatment system. (43) table (80) and the aldol-1-naphthylamine evidence of condensate (1) carcinogen!city in animals (42) Also used in the production of 1-naphthal and in the production Mutagen in bacterial ot the herbicide ANTU. (31) and mammalian cell assays. (42) 31 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses_____ Effects Parameters Regulations 2-Napthylami tie No commercial Present use is limited to Acute: Aquatic Toxicity Rating: OSHA : 91-59-8 production or research purposes. (43) Rat U> :727 ing/kg LC 96:10-1 ppm (43) Carcinogen (54) sol i d importation since January 1975 (9) Solubility in water at 25°C: EPA: Chronic: 0.16% (13) Hazardous Waste N.J. Industrial A human carcinogen (54) Survey (1978-79): causing bladder Vapor pressure at 108°C: Produced - 0 cancer (42) 1mm (43) Reportable quantities Purchased - 1-5 (89) x 10 (as an impurity) An animal carcinogen (84) causing bladder cancer DOT: in dogs, hamsters Poison (54) and non-human primates- Causes hepatomas in mice (42) Mutagen in bacterial, fungus, insect and mammalian cell assays. (42). 32 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical^ State__ in the U.S. (Ibs./yr.) Uses_____ Effects Parameters _ _Regulations 5-Nitro-o- In 1979, two U.S. Used almost exclusively as an Acute: Solubility in water: dll 1 a I U i lie ....D-.fr ^ ""eg"in .7n/. ' "-"••&'m n/l,« "f> Soluble ^ n ho* WG*" (Azoicdiazo commercial production. of organic dyes and pigments. (36) (orairi[36) (43) component 13, In 1977, one of these base) companies reported Chronic: 99-59-2 production of Limited evidence sol id 10-10 (43) of carcinogenicity in rats (36) 1979 - Imports . 8.7 x 10 Mutagen in bacteria (36) (36) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physic.il Slate in the U.S. (Ibs./yr.) Uses Effects Parameters 2,2'5,5'-Tetra- Not produced in Used almost exclusively as an Acute: ch 1 o robenz i <] i ne commercial quantities intermediate in the manufacture 15721-02-5 in the U.S. (36) of organic pigments. There is sol id no evidence that the two compounds 1978 - Imports which can be prepared from it have Chronic: 1500 (36) ever been produced commercially in Avai lab the U.S. (36) were in an evaluation of carcinogeniri ty (36) Mutagen in bacteria (36) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phys i ca1_State__ in the U.S. (Ibs./yr.) Uses Effects Parameters 4,4'-Thiodianllinee Believed to be Used almost exclusively as a dye Acute : Solubility in water: 139-65- I prouuceu by one inLermeu ia Le . Only one tiye has Rat LI) :iiGOmg/kg Slight iy soluble in sol id company. (36) been produced commercially in U.S. (oral) (36) hot water (36) from this substance (36) Reported to be Chronic: produced in N.J. (43) Sufficient evidence of carcinogenicity in mice and rats. (36) Mutagen in bacteria (36) Oral administration to pregnant mice reduced fetal implantation and prevented implantation (36) 35 Substance Name (Synonym) Amount Produced Major CAS Numhpr Imported, Exported Commercial Health Environmental Physical State _ in the U.S. (Ibs./yr.) Uses_____ Effects Parameters ______Regulat i_ons_ o-ToLiiidine (Free base) A chemical intermediate used in Acute: Solubility in water: OSHA: (2-arainotoluene) 1979-Production the production of dyes and ion Allergen (3a) Slightly soluble (43) TWA 5ppm (7) 95-53-4 greater than exchange resins. (43) Moderately toxic 1iquid 2000 (36) by all routes (3a) Vapor pressure at 44°C: EPA: An antioxidant in rubber Rat LD :900 mg/kg 1mm (43) (HCL Salt) 1979 - Imports manufacturing (43) (43) Hazardous Waste 2205 (36) Chronic: (9) Used in preparation of Long term exposure (HCL Salt) pharmaceuticals and pesticides may lead to Reportable quantities 1977 - Production (36) methemoglobinemia (89) 1000 (9) (3a) DOT: 1976 - Imports . (HCL Salt) animal llazardous materials 2.5 x 10 (9) carcinogen in rats, table (80) mice via oral route (36) Mutagen in E.co1i UNA-repair and pbage-induction assays. (36) Induced SCE in mammalian cells (42) 36 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical _Stale_ in the U.S. (Ibs./yr.) Uses_____ Effects Parameters _Regulations ___ 2,4,5-Trimethyl- Commercial production Used to produce Ponceau 3R Acute: Solubility in water: aniIine was last reported (C.I. Food Red 6), a dye Highly Soiuole (36) 137-17-7 by one U.S. which has not been produced company in 1968. commercially in the U.S. since Chronic: Vapor pressure at 68.4°C: (36) I960. (36) Limited 1mm (36) evidence of careinogenicity in mice and rats. (36) Mutagen in bacteria (36) 37 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical Sj^atj- in the U.S. (Ibs./yr.) Uses_____ Effects Parameters __ Regulations^ 2,4,6-Trimeth.yl- No evidence that Acute: ani 1 itie i t has ever been Toxic effects include 88-05-1 produced in anemia and commercial quantities methemoglobinemia (36) in the U.S. (36) Chronic: Available evidence inadequate to as.sess carcinogenicity (36) Not Mutagenic in bacteria (36) 38 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Phjrs i£a I State_____.in__t.huL U.S. (llis./yr.) Uses _____ Effects Parameters __ Regulati_pns ______ 2,6-Xylidine 1975 - Production Chemical intermediate for dyes Acute: Solubility in water: OSHA: (l-amino-2,6- greater than 143) Highly toxic by Insoluble (43) TWA 2ppm dimethylbenzene 1000 (43) ingestion, skin STEL lOppm (7) 87-62-7 absorption, or so] id 1975 - Imports . inhalation (43) FDA: 1.8 x 10 (43) Pesticide tolerances Rat LD :840 mg/kg in feed (80) (oral) 50 Mouse LD -707 mg/kg (oral) (43) 39 AROMATIC HYDROCARBONS Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phys^caj^State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ___ Regulations Anthracene 1975 - Produced-over 1,000 Used essentially 100% as Acute: Bioaccumulation: EPA: 120-12-7 - Imported 6.9 x 10 an intermediate in the It exerts photo- log octanol/water Priority Solid (43) manufacture of anthraquinone toxic and photo- partition coefficient: Pollutant (8) and other dye derivatives allergic action on 4.45 (8) Hazardous waste (80) such as alizarin dyes (43), the human skin (64b) Reportable and fluorescent dyes (64b) Solubility in water at 25°C: quantities (89) Chronic: 0.045-0.073 mg/1. (8) Mutagen in bacteria DOT: and in mammalian Vapor Pressure at 20°C: Hazardous materials cell assays (7) 1.95 x 10 mm (8) table (80) N.J. Industrial Survey (1978-1979): Positive in host- Detection in environmental Produced - 0 mediated assay (7) media: Purchased - 1-5 x 10 /yr Industrial Effluents and (84) Influents USEPA - 9% (78) NJDEP (OSR) - 0/28 (82) Potable Water, raw and treated: NJDEP (OSR) - 0/245 (86) POTWs : NJDEP (OSR) - influent - 0/9 effluent - 1/9 sludge - 2/10 (88) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmenta 1 Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Benzene 1979 - Production 12 x 10 In 1978, over 50% was used Acute: Aquatic Toxicity Rating: OSHA: Air, 71-43-2 - Imports 1.6 x 10 to manufacture eLhylbenzene Humans LC_ 096:100-10 ppm. (7) TWA 10 ppm, CL 25 ppn Liquid - Exports 1.3 x 10 (9) and styrene; 20% to LC :20,000 ppm/ PK 50 ppm/ 10 min/8 I synthesize cumene and phenol; 5 mm. (inhalation) Solubility in water at 25°C Emergency Standard 15-16% to synthesize (7a) 1,800 mg/liter (38) overturned by Supreme N.J. Industrial Survey nitrobenzene and aniline; Chronic: Court (54) (1978-1979): 4-5% to synthesize maleic Carcinogenic to Produced - , anhydride, chlorobenzenes, humans (38) Vapor Pressure at 26.1°C EPA: Priority 100-500 x 10 /yr. detergent alkalate; 2.5-3% 100 mm (38) Pollutant (8) Purchased - , each for other uses. (38) Reportable 100-500 x 10 /yr. (8A) Caused chromosomal Atmospheric Residence Time: Quantities (89) It is used as a constituent aberrations in animals 100 mm (38) Hazardous Waste (54) in motor fuels. (54) and humans (64b) Voluntary Cancellatior Detection in the environment of its use as a Industrial Effluents pesticice (75) Associated with bone and influents. marrow depression and USEPA - 25.9% (78) DOT: blood dyscrasias (47a) NJDEP (OSR) - 5/28 (82) Flammable Liquid (54) Causes aplastic anemia Potable water, raw and NJDEP: (64b) Treated: NJDEP (OSR) - 30/498 Toxic Volatile (86) Organic substance Ambient Air (81) NJDEP (OSR) - 100% (83) POTWs NJ0EP (OSR) - influent - 15/18 effluent - 11/18 sludge - 10/10 (88) 41 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmenta1 Physical_S tale in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ___ Regulations Biphenyl 1975 - Production An intermediate in the synthesis Acute: Solubility in water: OSIIA: (Diphenyl) 4.8 x 10 (43) of PCB; an intermediate in the A powerful irritant Insoluble (43) Air - TWA 200 ppb (7) 92-52-4 manufacture of benzidine; A heat to humans when inhaled (2a) Solid transfer agent; a fungistat in Vapor Pressure at 71°C: ACGIH Recommendation: the packaging of citrus fruit; a Chronic: 1 mm (43) STEL 600 ppm. (7) dyeing assistant for polyesters. Produced SCE in vitro. (43) (7) EPA: N.J. Industrial Survey Pesticide residue (1978-1979): tolerance (80) Produced - 0 , Purchased - 0.5-1x10 /yr (84) 42 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Cumene 1975 - Producti?^ 65% as an intermediate in Acute: Aquatic Toxicity Rating: OSHA: 1.9 x 10*" ( i sop ropy 1 benzene ) synthesis of phenol; 34% as an An eye and skin LC5Q96: 100-10 ppm (7) Air 98-82-8 - Imports intermediate in synthesis of irritant. TWA 50 ppm (skin) liquid 2.1 x 10 acetone; 1% for the synthesis of A CNS depressant Solubility in water: (7) - Exports alpha-methylstyrene; the remainder and narcotic (64b) insoluble (43) 4.4 x 10 (31) is used as a high-octane gasoline ACGIH Recommendation: component, and as a thinner for Vapor Pressure at 20°C: STEL 75 ppm (54) paints and lacquers. (43) 8 mm (43) EPA: Persistence: Hazardous Waste (80) High photochemical Pesticide residue reactivity (79) tolerance (80) Reportable Detection in the environment: quantities (89) Ambient Air: National Oil & NJDEP (OSR) - all pro- Hazardous Substance pylbenzenes were detected Contingency Plan (80) in over 70% of samples (83) DOT: POTWS: Hazardous materials NJDEP (OSR) - table (80) influents - 11/18 effluents - 10/18 sludge - 9/10 (88) 43 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses______Effects Parameters Dibenzofuran Not produced Commercially Solubility in water: 132-64-9 in the U.S. (43) Slightly Soluble (43) 44 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmenta1 cal State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations Ethylbenzene 1975 - Production Used as a chemical intermediate Acute: Aquatic Toxicity Rating: OSHA: Air, 100-41-4 5.56 x 10' in the production of styrene, Moderately toxic via LC5Q96:100-10 ppm (la) TWA 100 ppm (skin) (7) Liquid - Imports cellulose acetate, and synthetic all routes of exposure 8.95 x 10 rubber. Also used as a solvent (3f) Bioaccumulation: ACGIH Recommendation: - Exports or diluent and as a component of Irritant to eyes and log octanol/water STEL 124 ppm (7) 8.42 x 10' (43) automobile and aviation gasoline. mucous membranes (64b) partition coefficient: (54) 3.15 (8) EPA: N.J. Industrial Survey Chronic: Priority Pollutant (1978-79): CNS effects (7a) Solubility in water at 20°C: (8) 8, Produced - 1-5 x 1 152 mg/1 (8) Hazardous Waste (80) Purchased 1-5 x 10 /yr. (84) National Oil & Vapor Pressure at 20°C: Hazardous Substances 7 mm (8) Contingency Plan (80) Reportable Atmospheric Residence Time: quantities (89) 1.4 days (8) Hazardous water pol lutant designa Persistence: tion & harmful High photochemical quantities (80) reactivity (79) DOT: Detection in environmental Flammable Liquid (54) media: Industrial effluents and intakes: EPA - 15.4% (78) NJDEP (ORS) - 6/28 (82) Potable Water, raw and treated: NJDEP (OSR) - 4/498 (86) Ambient Air: NJDEP (OSR)- in over 70% of samples (83) POTWS: NJDEP (OSR) - influents - 12/18 effluents - 6/18 sludge - 8/10 (88) 45 ( Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental l State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regu1ations____ Naphthalene 1975 - Production Used as a chemical intermediate Acute: Aquatic Toxicity Rating: OS1IA: 91-20-3 2.3 x 10 for the synthesis of phthalic, A primary irritant LC 96:10-1 ppm (7) Ai r Solid - Imports anthranilic, hydroxyl (napbthols), and can cause dermatitis TWA 10 ppm (7) 1 x 10 (43) amino (naphtylamines), and sulfonic on contact. Bioaccumulation: compounds which are used in the An allergen (54) log octanol/water ACGIH Recommendation: manufacture of various dyes. partition coeffient: STEL 15 ppm (7) N.J. Industrial Survey Also, used in the manufacture of Chronic: 3.37 (8) (1978-79) of hydronaphthalenes, synthetic Hemolytic effects in EPA: Produced - 1 - 5 x 10 /yr. resins, lampblack, smokeless susceptible Solubility in water at 25°C: Priority Pollutant Purchased - 5 - 10 x 10 / powder, and celluloid. A moth populations (G6PD 32-34 mg/1 (8) (8) yr. (84) repellant. (54) deficiency) (54) Hazardous Waste (54) Vapor Pressure at 20°C: National Oi1 & 0.0492 mm (8) Hazardous Substances Contingency Plan (80) Detection in the environment: Reportable Industrial effluents and quantities (89) influents: Hazardous water USEPA 10% (78) pollutant designa NJDEP (OSR) 3/31 (82) tion & harmful Potable water, raw and quantities (80) treated: NJDEP (OSR) - 0.245 (86) DOT: POTWs: ORH - A (54) NJDEP (OSR) - influents - 1/9 effluents - 1/9 sludge - 1/10 (88) Ambient Air; NJDEP (OSR) - 35 to 70% (83) 46 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Physical State in the U.S. (Ibs./yr. ) Uses Effects Parameters Regulations Stymie 1975 - Production 87% is used in the production Acute: Aquatic Toxicity Rating: OSHA: ( vinyl benzene ) 4.6 x 10 ot polystyrene resins, An eye and skin LC-_96: 100-10 ppm (6) Air 100-42-5 - Imports , acrylonitrile-butadiene-styrene irritant. (2h) TWA 100 ppm 1 iquid 6.6 x 10 terpolymers, and styrene- Solubility in Water: CL 200 ppm - Exports acrylonitrile copolymer resins, Chronic: Insoluble Pk 600 ppm/5 min/ 5.7 x 10 (43) and unsaturated polyesters. Caused lung tumors 3 min. (8) About 11% was used to make in mice, negative Vapor Pressure at 35°C: styrene-butadiene rubber. (28) in rats. Limited 10 mm (28) ACGIH Recomm. : evidence of TWA 50 ppm carcinogenicity (42) Persistence: STEL 100 ppm (7) High photochemical Mutagenic in bacteria reactivity (79) EPA: and insects (42 Hazardous Waste (80) Detection in the environment: National Oi1 & Positive in host- Ambient Air: Hazardous Substances mediated assay (42) NJDEP (OSR) - Contingency Plan (80) over 70% of samples (83) Reportable Produced SCE in quantities (89) mammalian cells and Hazardous water in mice (42) pollutant designa tion & harmful quantities (80) FDA: Food-contact component (80) Synthetic food flavoring (80) DOT: Hazardous materials table (80) 47 Substances Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State___ in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _ Regulations Toluene 1975 - Production Used in the manufacture of Acute: Aquatic Toxicity Rating: OSHA: 108-88-3 4.6 x 10y benzene, phenol, toluene Eye irritant LC 96:100-10 ppm (7) Air: Liquid - Imports diisocyanate, benzyl and benzoyl exposure results in TWA 200 ppm 1.5 x 10 derivatives, benzoic acid, toluene CNS depression and Bioaccumulation: CL 300 ppm - Exports _ sulfonates, nitrotoluenes, behavioral disorders log/octanol/water Pk 500/10 min. (7) 8.6 x 10 (43) vinyltoluenes, and saccharin; As (7a) partition coefficient a solvent for paints and Chronic: 2.69 (8) ACGIH Recommendation: N.J. Industrial Survey coating; and as a component TLV-TWA 100 ppm (1978-79): of automobile and aviation fuels. Vapor Pressure at 25°C: STEL 150 ppm (skin) Produced - 0.5 - 1 x - (54) 28.7 mm (8) (7) Purchased - 0.5 - 1 x 10 /yr. EPA: (84) Atmospheric Residence Time Priority Pollutant 1.9 days (45) (8) Hazardous Waste (80) Persistence: Reportable High Photochemical quantities (89) reactivity (79) National Oil & Hazardous Substances Detection in the environment Contingency Plan (80) Industrial wastewaters Hazardous water an intakes: pollutant designa USEPA 27.8% (78) tion & harmful NJDEP (OSR) 20/28 (82) quantities (80) Potable water, raw and Pesticide residue treated: tolerance (80) NJDEP (OSR) - 133/498 (86) Ambient Air: FDA: NJDEP (OSR) - 100% (83) Food-contact POTWS: component (80) NJDEP (OSR) influents - 16/18 CPSC: effluents 11/18 Containers & pack sludge - 10/10 (88) aging (80) Labeling (80) DOT: Flammable Liquid (54) 48 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Xylenes Ortho - No data Ortho - 51% of the synthesis of Acute: Aquatic Toxicity Rating: OSHA : mixed neta - jy 75-Produced phchalic anhydride, 49% exported. Skin and eye LC 36; 100-10 ppm (7) ftl I 1330-20-7 1.84 x 10 (43) (43) irritant (47e) TWA 100 ppm (7) Ortho - Meta - 98% for synthesis of Inhalation can Solubility in water: 95-47-6 Para - 1975-Produced isophthalic acid, 2% for misc. produce irritation insoluble (43) NIOSH Recomm. : Meta - 2.51 x 10 applications such as for the of the upper CL 200 ppm/ 10 min. 108-38-3 - Exported synthesis of meta-toluic acid. (43) respiratory tract Vapor Pressure: STEL 150 ppm (7) Para - 2.49 x 10 (43) (46) Ortho 106-42-3 Para - 61% for synthesis of dimethyl 10 iran at 32.1°C EPA: Mixed - No data terephthalate, 18% for teraphthalic Narcotic effect Meta Hazardous Waste (8 acid, 21% exported (43) on the nervous 10 mm at 28.3°C Reportable system (36, 64) Para quantities (89) Mixed 10 mm at 27.31C (43) Pesticide residue tolerance (80) Persistence: National Oil & High photochemical Hazardous Substances reactivity (79) Contingency Plan (80) Hazardous water Detection in the environment: pollutant designa Air tion & harmful NJDEP (OSR) - over 70% of quantities (80) samples. (83) DOT: Flammable Liquid (54) FI)A: Food-contact component (80) CPSC: Containers & pack aging (80) Labeling (80) 49 AZO COMPOUNDS Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phy_sical State _in the U.S. (Ibs./yr.)______Uses____ Effects Parameters Regulations Diazomethane Use limited to application as a Acute: OSHA: 334-88-3 laboratory methylating agent Inhalation by humans Air Gas where it is produced and used i_n caused chest pains, TWA 0.2 ppm (7) situ (16) asthmatic symptons, cough and fever, fulminating pneumonia, moderate cyanosis, shock and death (16) Chronic: Caused lung tumors in rats by inhalation, and lung tumors in mice via skin application (16) 50 CARBAMATES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Urethane 1975 - Production greater Used principally as a chemical Acute: Solubility in water: EPA: (Elhyl carbaraate) than 1000 (43) intermediate for wash-and-wear Soluble (16) Hazardous Waste (80) 51-79-6 textile finishes; also used as a Reportable Solid N.J. producer listed (43) chemical intermediate in the Vapor pressure at 78°C: quantities (89) preparation and modification of 10 mm (43) amino resins; as a solubilizer Chronic: DOT: and co-solvent for pesticides, Carcinogenic in mice, Hazardous materials fumigants, and cosmetics; and rats and hamsters via table (80) as an anaesthetic for laboratory oral, inhalation, sub animals in veterinary medicine. cutaneous or (43). interperitoneal routes (16) An initiator of skin carcinogenesis in mice both orally and topically. (16) Carcinogenic to neonatal and infant mice (16) Mutagen in bacteria, yeast, and mammalian ceils. (7) Mutagen in Drosophila (7) Positive in cell transformation assay (7) Mutagen in_viy<> in mouse (7) Embryotoxic (7) Teratogenic (7) 51 ( DYES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental PJi Vj> j_ca J^ Jita te_ JnJJ^ U.S. (Ibs./yr.)______.Uses_____ Effects Parameters C.I. Acid Blue 1 1975 - Production by Dyeing wood, silk, leather, Acute: Solubility in water at 20°C: (C.I. Food Blue one U.S. Company jute; staining paper; coloring Rat: 50 gm/liter (5) 3) in unknown amounts. phenol formaldehyde resins; LD,50 greater than (Sodium VRS) coloring milled soaps; coloring 10 gm/kg (oral) (25) 129-17-9 1975 - Imports 3,750 (25) inks, case in and methylated Solid spiritwash; as a biological Chronic: N.J. Industrial Survey stain. The heavy metal salt Carcinogen in rats (1978-1979): of the free acid is used as a following its sub Produced - 0 pigment. The aluminum salts are cutaneous or intra Purchased - 0 used to color pharmaceuticals. muscular injection, (25) producting local Max. Inventory - sarcomas at the less than 100. (25) site of injection. (25) 52 Substance Name (Synonym) Amount Produced Major CAS Number imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations C.I. Acid Blue 9 N.J. Industrial Survey Acute: PDA: (C.I. Food U976-i979) : Mice: ijUjui ciuuitivc', Blue 2) Produced - 0 , LD 4600 mg/kg certification (80) (Briltiant Blue Purchased - 1 - 5 x 10 (Subcutaneous) (7a) Provisional listing FCF) (84) (80) 2650-18-2 Chronic: Equivocal tumorigenic agent in rats via parenteral arid sub cutaneous administration (7) Neoplastic in a second study on rats via sub cutaneous administration (7) 53 Substance Name (Synonym) Amount Produced Majoi CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations C.I. Acid Green 3 1973 - Production A dye for leather, paper and Acute: Solubility in water: FDA: (C.I. Food Green 2.06 x 10 by wood stains; a biological stain Rat Soluble (5) Provisional Listing 1) four U.S. companies. and indicator. (25) LD greater than (80) (Guinea Green B) (25) A dye for silk and wool. (5) 2 gm/kg (oral) (25) 4680-78-8 N.J. Industrial Survey Solid (1978-1979): Chronic: Produced - 0 Carcinogen in rats and Purchased mice via oral route 1 - 5 x 10 (84) producing hepatic tumors, via subcutaneous route in rats producing local sarcomas, and via ambient exposure in rats producing benign mammary tumors. (25) A bacterial mutagen (7) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physi_ca 1 State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Re gulations C.I. Acid Green 5 N.J. Industrial Survey Dye for wool, nylon, silk and Acute: Solubility in water: FDA: (C.I. Food (1978-1979): leather; biological stain. (25) Rat Soluble (5) Provisional Listing Green 2) Produced - less than 100. LD,.,, greater than (80) (Light Green Purchased - 1,000-5,000 2 gm/kg (oral) (25) SF) (84) 5141-20-8 Chronic: Solid Tumorigen, local sarcomas were produced after subcutaneous injection (25) Bacterial Mutagen (7) 55 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Fhyiii-aJ State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations C.I. Basic Green 4 1975 - Production Dye for acrylics, silk, wood, Acute: Aquatic Toxicity: (Malachite 3.19 x 10 (43) acetate bast fibers, paper, Mouse Hemopoetic effects on Green) - Imports , leather, inks, oils, waxes, and LD5Q :80 mg/kg (7) catfish at 0.1 ppm (43) (Aniline 6.7 x 10 (43) cellulose nitrate lacquers. (43) Eye irritant, a 1% Green) Veterinary antiseptic, internal solution can cause LC 96:0.25 ppm for 569-64-2 N.J. Industrial Survey and external. (43) blindness in humans. American eels (43) Solid (1978-1979): (43) Produced - 0 Solubility in water: Purchased - 1-5 x 10 (84) Chronic: Very soluble (5) Mutagen in bacteria and mammalian cells (7) Teratogen in chicken embryos. (43) 56 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ations C.I. Basic Red 1 1979 - Production Dye for silk, cotton, leather, Acute: Solubility in water: (Khodamine bG) 1 x 10 wood, bast fibers, and paper. An eye irritant (43) Soluble (25) 989-38-8 - Imports (25) 1.52 x 10 (25) A component of C.I. Solvent Red Chronic: 36; used as a tracing agent for Carcinogenic in rats N.J. Industrial Survey following water pollution; and after subcutaneous (1978-1979): as an indicator (43) injection producing Produced - 0 sarcomas (25) Purchased - 0 5 - 10 x 10 (84) Mutagen in bacterial assays (7,43) Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Envi ronmenta1 Physica 1 S t£ t e_ in the U.S. (Ibs./yr.) Uses Effects Parameters __Regulations C.I. Direct Black 1978 - Production - Dye for cellulose,' wool, silk, Acute: Solubility in water: 38 8.23 x 10 by one bast fibers, leather, hog's Soluble (30) 1937-37-7 company. (38) hair, synthetic ivory, plastics, Solid aqueous inks and wood flour used 1980 - Imports - as a resin filler; A stain for Chronic: 2.09 x 10 biological specimens; (43) and A carcinogen in (38) has been used as a component of rats (38) hair dyes. (38) Hutagen in bacteria (82) N.J. Industrial Survey (1978-1979): Limited evidence of Produced - 1-5 x 10 embryotoxicity in Purchased - 1,000-5,000 (84) rats. (38) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters __Regulations C.I. Direct Blue 1978 - Productiog Dye for cotton, silk, paper, Acute: Solubility in water: b 6. 16 x 10 reported leather, and aqueous inks. (43) Soluble (38) 2602-46-2 by one company (38) Stain for wool, nylon, and Solid biological specimens. (43) - Imports Chronic: 4.4 x 10 (38) Carcinogen in rats via oral route producing N.J. Industrial Survey hepatocelluar carcinomas (1978-1979): , and neoplastic nodules Produced - 5-10 x 10 (38) Purchased - 0 (84) Exposure to benzidine based dyes has been linked to bladder cancer in humans (38,42) Highly teratogenic in rats via subcutaneous injection when injected during the first half of pregnancy (38) Not a mutagenic in Ames assay. (74) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental a atate in the U.S. (Ibs./yr.)______Uses______Effects Parameters Regulations __ C.I. Direct Brown 1978 - Production Dye for cellulose synthetics, Acute: Solubility in water: 95 7.59 x 10 by one silk, cotton, wool, nylon, Soluble (38) 16071-86-6 company (38) leather, paper, and plastics. (43) 1980 - Imports , Heavy metal salts are used as Chronic: 2.4 x 10 (38) pigments. (38) Limited evidence of carcinogenicity in N.J. Industrial Survey rats. Oral administration (1978-1979): , produced hepatocelluar Produced - 5-10 x 10 carcinomas and Purchased - 0 (84) neoplastic nodules (38,42) Exposure to benzidine based dyes has been linked to bladder cancer in humans (38,42) A mutagen in bacteria (7) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Phys^caj State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _ _Regulations C.I. Disperse Last U.S. production was Used almost exclusively as a Acute: dye intermediate. (36) (l-Amino-2- methy]- 1972 - Imports 265 (36) anthraquinone) 82-28-0 No evidence that it has Chronic: ever been produced in Limited evidence of commercial quantities in U.S. carcinogen!city in None of the dyes that can experimental animals be prepared from it are due to the impurities presently produced in in the material used. (36) commercial quantities in U.S. (36) In rats there was an increased incidence of hepatocellular carcinomas via oral route (36) 61 Substance Kame (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _Regula t i ons _ C.I. Disperse 1979 - Production,- Dyeing acrylic fibers, PVC Acute: Solubility in water: Ye I low 3 3.21 x 10 fibers, polystyrene and other Humans can have an Low aqueous (C.I. Solvent - Imports , plastics. (43) allergic reaction Solubility (50) Yellow 77) 2.5 x 10 (43) leading to dermatitis (Acetate Fast (43) Yellow G) K.J. Industrial Survey (2832-40-8) (1978-1979): Chronic: Produced - 1,000-5,000 NCI bioassay - Purchased - 1-5 x 10 (84) carcinogenic in male mice producing neoplasms in the liver via oral route. Carcinogenic in female mice producing hepatocellular adenomas via oral route (50) Caused chromosome aberrations in frogs (43). Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _ Regulations C.I. Food Red 5 1975 - Production - Dyeing textiles and leathers; Acute: Solubility in water: FDA: (Ponceau HA) fur. coloring inks, papers, Soluble (17) L OVI 5 iGiiei 1. 3761-53-3 pigments; and in wood stains. (80) Solid N.J. Industrial Survey (H) (1978-1979): Chronic : Produced - 0 Carcinogenic in Purchased - 0 rats and mice producing Max. Inventory - liver cell tumors 0.5 - 1 x 10 (84) following oral administration (17) Mutagen in bacteria (7) Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (lbs./yr.)______Uses______Effects______Parameters______!*?&"_! at i_ons_ C.I. Food Red 6 No longer used in U.S. Used to dye wool. (5) . Acute: Solubility in water: PDA: (Ponceau 3R) Last produced in 1960 (17) Used as a biological stain. (6) Very soluble (17) Provisional listing 3564-09-8 (80) N.J. Industrial Survey (1978-1979): Chronic: Produced - 0 Carcinogenic in rats Purchased - 0 via oral route producing Max. Inventory - 0 liver-cell tumors. (84) Also produced bladder tumors in mice after bladder implantation (17) Mutagen in bacteria (43) 64 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Physical State in the U.S. (Ibs./yr.)______Uses____ Effects Parameters _Rej> illation s_ C.I. Food Red 15 1973 - Production of general Used as a color additive for Acute: Solubility in water: EPA: drugs and cosmetics. (21) Irritant to the eye Very soluble (6) Pesticide residue Violet 10) companies - As a dye for paper, and as a (43) tolerance (80) (Rhodamine B) 3.15 x 105 (21) dye used on wool and silk for Ingestion causes liver 81-88-9 fluorescent effects. (6) damage and death (21) FDA: Solid 1975 - Production of drug Used as a biological stain and Mouse Provisional listing and cosmetic grade as a laboratory reagent. (5,6) LD,. n :887 mg/kg (oral) (80) dye - 1.2 x 10 (21) 1975 - Imports 7 Chronic: 6.1 x 10 (21) Carcinogenic in rats when injected sub- N.J. Industrial Survey cutaneously producing (1978-1979): , local sarcomas (21) Produced - 1-5 x 10 Purchased - 5-10 x 10 (84) A Mutagen in bacteria which could be due to an impurity (43) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)_____ Uses_____ Effects Parameters ___Regulations______ C.I. Solvent 1975 - Production - Dye for varnishes, oils, waxes Acute: Solubility in water: PDA: Orange 2 greater than 1,000. and fats. (43) Rat Insoluble (43) Provisional Listing (0:1 Orange (43) LDW :5000 rag/kg (7) (80) SS) 2646-17-5 N.J. Industrial Survey Chronic: Solid (1978-1979): Animal carcinogen Produced - 0 in mice via oral and Purchased - less than subcutaneous routes 100. producing intestinal Max. Inventory - less and local tumors. Also than 100 (84) produced carcinomas of the bladder following bladder implantation (17) 66 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations C.I. Solvent 1971 - Production Used for coloring oils, waxes, Acute: Solubility in water: PDA: Orange 7 7 .6 x 10 hydrocarbon solvents for Insoluble (17) provisional listing (Sudan II) In 1973 there were polishes, candles, and (80) (Oil Scarlel) three U.S. producers. polystyrene resins. (17) 3118-97-6 (17) Chronic: Solid Carcinogenic in mice N.J. Industrial Survey producing bladder (1978-1979): , carcinomas following Produced - 1-5 x 10 bladder implantation Purchased - 0 (84) (17) Mutagen in bacteria (7) 67 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters C.I. Solvent Red No data on production amounts, Used to color skins of oranges Acute: Solubility in water: EPA: 80 in 1975 it was produced by not used for processing. (43) Slightly soluble (17) Hazardous Waste (80) (Citrus Red two companies. (17) No. 2) PDA: (6358-53-8) N.J. Industrial Survey Chronic: Color additive, (1978-1979): Carcinogenic in rats certification (80) Produced - 0 and mice producing Purchased - 0 hyperplasia and tumor Max. Inventory - 0 (84) of the bladder. Sub cutaneous ly, it produced adenocarcinomas of the lung and lymphosarcomas in female mice. In mice it produced bladder carcinomas following bladder implantation (17) Mutagen in bacteria (7) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulationsf C.I. Solvent N.J. Industrial Survey A dye used for lacquers, Acute: Solubility in water: y e I i ow i t,iy/5-/yj: , varnisnes, wax products, on ongnciy soiuDie (if) (p-aminoazo- Production - 1-5 x 10. stains, styrene resins; A dye benzene) Purchased - 5-10 x 10 (84) intermediate for the production 60-09-3 of acid yellow, diazo dyes, and Solid as a chemical intermediate in the synthesis of insecticides (43) Chronic: Carcinogenic in rats via oral route producing liver tumors, and by skin painting producing epidermal tumors (17) Mutagen in vitro in bacteria and mammalian cells. (7) Mutagen in host mediated assay (7) Positive in cell transformation assay (7) 69 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations C.I. Solvent 1972 - No production data Used for coloring polishes, Acute: Solubility in water: OS HA: Yellow 2 available, produced polystyrene, gasoline and Humans-highly toxic Insoluble (43) Carcinogen (7) (Butter Yellow) by three U.S. soap (1) via oral and dermal (DAB) companies. (1) A laboratory reagent (5) routes (43) PDA: (p-Dimethyl- Rat Carcinogen (5) aminoazobenzene) N.J. Industrial Survey LD5() :20b mg/kg (oral) 60-11-7 (1978-1979): Mouse EPA: Solid Produced - 0 LD :300 mg/kg (oral) Hazardous Waste (80) Purchased - 0 (43} Max. Inventory - 0 (84) DOT: Chronic: Hazardous materials Carcinogen in rats by table (80) several routes of administration (17) Carcinogenic in dogs via oral route. (17) Mutagen in bacterial and mammalian cell assays and Drosophila (1,7,43) 70 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations C.I. Solvent 1975 - Production - greater A chemical intermediate; and a Acute: Solubility in water: Yelluw 3 Liiaii i , uuu. ynjj uye 1.O1 Oj. i-S, idt iiil (2-Amino-5- reaction follows azotoluene) Four N.J. manufacturers skin contact (31) 97-56-3 listed in 1980. (43) Rat Solid LDrri :1500 rag/kg (oral) LDrri :800 mg/kg (oral) $3) Chronic: Animal carcinogen, carcinogenic in mice rats, hamsters and dogs via oral route producing tumors of liver, gall-bladder", lung and bladder. Also carcinogenic via other routes of exposure (17) Mutagen in bacterial and mammalian cell assays (7) Positive in cell trans formation assays. (7) 71 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations C.I. Solvent 1979 - Production - Dye for hydrocarbon solvents, Acute: Solubility in water: Yellow 14 3.5 x 1CT oils, fats, waxes, shoe and floor Causes dermatitis Insoluble in water (43) (Sudan 1) - Imports 7 polishes, gasoline, soap, colored in humans. (43) 842-07-9 2.5 x 10 (43) smokes, cellulose ether varnishes, Solid and styrene resins. (43) Chronic: N.J. Industrial Survey Carcinogen in mice via (1978-1979): subcutaneous injection Produced - 1-5 x 10 producing liver tumors Purchased - less than and bladder tumors, and 100 (84) bladder implanation producing bladder tumors. (17) Carcinogen in rats via oral route producing neoplastic nodules of the liver (51) 72 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Physical State in the U.S. (Ibs./yr.)______Uses______Effects Parameters __Regulations C.I. Vat Yellow 4 1976 - Productiog - Dye for cotton, silk, wool and Acute: Solubility in water: izB-66-5 1.24 x 10 (52) paper. (43) Insoluble (52) Dye for cellulose synthetics 1979 - Imports such as polyesters and acetates. 7.7 x 10 J (43) (52) Chronic: Carcinogenic in male N.J. Industrial Survey mice via oral route (1978-1979): , producing an increased Produced - 1-5 x 10 incidence of lymphomas Purchased - 1,000-5,000 (84) (52) 73 EPOXIDES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Pbys i ca 1_S ta_t e____ in the U.S. (Lbs./yr.)______Uses_____ Effects Parameters 1,2-Butylene oxide 1974 - Produced For the production of Acute: Solubility in water at 25°C: (1,2-Epoxybutane) 1 x 10 butanediols, glycol esters, and Eye irritant. 82.4 gm/liter (64a) 106-88-7 ethers; in the preparation of Exposure to liquid Liquid 1975 - Imports surface active agents and gasoline causes skin irritation. 5.3 x 10J (43) additives (43). Also as a Unpleasant odor makes corrosion inhibitor, or acid hazard from inhalation scavenger in chlorinated solvents unlikely. Excessive such as trichloroethylene and exposure to vapors methyl chloroform. (1) would be expected to cause irritation of the lung. (64a) Chronic: Mutagen in bacteria (7) Positive in cell transformation assays (7) 74 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmenta1 Physical State in the U.S. (Ifas./yr.) Uses Effects Parameters Regulations Diepoxybutane Not produced commercially Biochemical research (43). Acute: Solubility in water EPA: 1464-53-5 in the U.S. (43) Curing polymers, crossiinking Rat: Hiscible (43) Hazardous waste (80) Liquid textile fibers, and prevention LD n :78 mg/kg Reportable N.J. Industrial Survey of microbial spoilage (1) (oral) (7a) Vapor pressure at 20°C: quantities (89) (1978-1979): LC -.90 ppm/4 hr. 3.9 mm (43) Produced - 0 (inhal.) (7a) DOT: Purchased - 0 (84) Hazardous materials Chronic: table (80) Carcinogenic in mice by skin application producing skin carcinomas (20) Produced local sarcomas in rats via subcutaneous injection (20) Positive in cell trans formation assay (7) Mutagen in bacteria, yeast, and Drosophila (7) Positive in host- mediated assay in mice (7) 75 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phys_jcal_Surte_ in the U.S. (Ibs./yr.)______Uses______Effects Parameters Regulations Diglycidyl Not produced commercially A liquid epoxy resin-E6, for Acute: resorcinol in U.S. (43) castings, adhesives, laminates; Causes severe burns ether a reactive diluent in the and skin sensitization (l,3-Bis(2,3- Was produced by U.S. production of epoxy resin (43) epoxy-propoxy) companies in unknown coatings; and a curing agent for Rats: benzene) amounts (20) polysulfide rubber (43). LD :2570 mg/kg 101-90-6 (oral) (7) Liquid Chronic: 76 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmenta 1 Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Epichlorohydrin 1973 - Production 58% as an intermediate in Acute: Aquatic toxicity rating: OSHA: 1 A£_OO_Q 1 QA « 1A f /. 1\ swnthps-is nf clvrprir;: fr.r Hi phi v tniri ;- via .-,!! l.C. ",(-, • 1f>n-1f! r-.r-.ir. f7> Air: WL 50 synthesis of unmodified resins; routes. Can be TWA-5 ppm (skin) (7) 1975 - Imports , 7% for synthesis of elastomers, absorbed through Bioaccumulation: 1.83 x 10 (43) glycidyl ethers, some modified skin. Irritant and Potential (4c) N10SH Recom.: epoxy resins and misc. other allergen (4c) TLV-TWA-2 ppm 1975 - Exports products; 5% is exported (43). Solubility in water at 20°C: STEL-5 ppm (skin) 1.60 x 10 (43) Rats: 6.4% by weight (20) (7) LD :90 mg/kg (oral) N.J. Industrial Survey LD^":360 ppm/6 hr. Vapor Pressure at 16.6°C: EPA: (1978-1979): (inhalation) (7) 10 mm (2d) Hazardous Waste (54) Produced - 0 Pesticide residue Purchased r 0 Chronic: tolerance (80) 1-5 x 10 /yr. (84) Produced local Hazardous water sarcomas in mice pollutant designation via subcutaneous & harmful quantities injection. (80) Reportable (20) quantities (89) Active as an initiator PDA: in two-stage skin Food starch modifier carcinogenesis in (80) mice (20). DOT: Positive in cell Flammable liquid and transformation poison (54) assay (7) NJ DEP: Mutagen in bacteria, Toxic volatile yeast, drosophila, and organic substance mammalian cells. (7,20) (81) Positive in host- medLaled assay in mice (1) 77 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health E nv i ronment a 1 Phys [ca !_£> tale_ in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters __ Regulations Ethyl ere oxide 1975 - Production Used as a fumigant for foodstuffs Acute: Aquatic Toxicity Rating: OSHA: 75-21-8 4.4 x 10 and textiles; to sterilize Severe irritant to LC5()96:100-10 ppm (7) Air Gas surgical instruments; in organic mucous membranes of TWA 50 ppm (7) 1975 - Imports , synthesis; as an agricultural respiratory tract (43) Solubility in water: 4.0 x 10 fungicide, as a starting material Rats: Miscible (64a) NIOSH Recommendation: for manufacture of arrylonitrile LD -330 mg/kg (oral) CL 75 ppm/15 min. (7) 1972 - Exports and nonionic surfactants (5) LC^":1462 ppm/4 hr. Vapor pressure at 1095°C: 3.5 x 10 (43) (inhalation) (43) 20 mm (43) EPA: Hazardous Waste (54) Chronic: Pesticide residue Limited evidence of tolerance (80) carcinogenicity in Reportable animals subcutaneous quantities (89) injection in female mice produced local DOT: sarcomas (42) Flammable Liquid (54) Mutagen in bacteria, yeast, mammalian cells, insects, rats and mice (42) Increased chromosomal aberrations in exposed workers (42). Fertility effects found in animals (64a) 78 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. Qbs./yr.)______Uses______Effects Parameters Regulations Glyciilaldehyde No evidence that it has A research chemical; a cross- Acute: Solubility in water: EPA: (2,3-epoxy- ever been produced or used linking agent for finishing of Irritating to eyes, Miscible (43) Hazardous Waste (80) propanal) commercially in U.S. (20). oil, for oil-tanning (chamoising) nose and throat (20) ReporLable 765-34-4 and fat-liquoring of leather and Rats: quantities (89) Liquid surgical sutures. LD :50 mg/kg (oral) Ur;;:251 ppm/4 hr. DOT: Has been tested as vapor-phase (inhalation) (43) Hazardous materials disinfectant. (20) table (80) Chronic: Carcinogenic in mice by skin application and subcutaneous injection and in rats by subcutaneous injection. It produced malignant tumors at site of application (20). Mutagen in bacteria and yeast. (20) 79 Substance Kame (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State______in the U.S. (Ibs./yr.)______Uses______E_f fee ts______Parameters______Regulations_ Glycidol 1978 - Production A chemical intermediate for Acute: Solubility in water: OSHA: (1 ,2-Epoxy-3- less than 5000. pharmaceuticals, cosmetics, Irritant to skin (43) Soluble (43) Air hydroxypropane) (43). glycerin, surfactants, and Rats: TWA 50 ppm (43) 556-52-5 polymers. A stabilizer for LD _:420 mg/kg Vapor pressure at 25°C: Liquid natural oils and vinyl polymers, (oral) 0.9 mm (43) NIOSH Recommendation: as dye-leveling agent and LC -.580 ppm/4 hr. TWA 25 ppm (7) demulsifier. (43) (inhalation) (7b) EPA: Chronic: Hazardous Waste (80) Mutagen in bacteria (7b) DOT: Chromosome changes in Hazardous materials human lymphocytes (7b). table (80) 80 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters JRejju 1ji tio ns Propylene Oxide 1975 - Productiog 59% to make polyether polyols Acute: Aquatic toxicity rating: OSHA: 75-56-9 1.52 x 10' for use in production of Rats LC 96:over 1000 ppm (7) Air: Liquid - Imports polyurethane resins; 21% to make LD :930 rag/kg TWA 100 ppm (7) 2.09 x 10 propylene glycols; 7% to make Ur":4000 ppm/4 hr. Solubility in water at 25°C: - Exports polyether polyals for production akV Miscible 59% (20) ACGIH Recom.: 1.10 x 10 (43) of surface active agents such as Chronic: TLV-TWA 20 ppm (54) hydraulic brake fluids, Produced local Vapor pressure at 20°C: N.J. Industrial Survey lubricants for rubber molds and sarcomas in rats 445 mm (43) EPA: (1978-1979): textile fibers, heat transfer via subcutaneous Hazardous waste (80) Produced - 0 fluids, and compression injection (20) Atmospheric residence time: Pesticide residue Purchased - ?0 lubricants; 3% to make 8.9 days (44) tolerance (80) 5-10 x 10 /yr (84) dipropylene glycol; 2% to make Mutagen in bacteria, Hazardous water glycol ethers; 1.8% in synthesis yeast, and drosophila (1) pollutant designa of glycerin; misc. uses include tion & harmful preparation of isopropanol amines, quantities (80) propylene carbonate, hydroxypropyl Reportable cellulose, hydroxypropyl starch, quantities (89) as a stabilizer for nitro-cellulose lacquers, and as a fumigant. (1) DOT: Flammable liquid (54) FDA: Food starch modifier (80) Pesticide residue tolerance (80) 81 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State_____in the U.S. (Ibs./yr. )______Uses______Effects______Parameters______Regulations _____ Styrene oxide 1974 - Production _ Used as a reactive diluent in Acute: Solubility in water at 25°C: PDA: 96-09-3 9.9-19.8 x 10 (28) epoxy resins to reduce the Skin and eye irritant 0.28 w/w (20) Food-contact Liquid viscosity of mixed systems prior (64a) component (80) to curing. It is also used as Rats: LD :4290 mg/kg Vapor Pressure at 20°C: an intermediate in the preparation (oral) (7a) 0.3 mm (20) of agricultural and biological chemicals, cosmetics, surface. Chronic: (28) Limited evidence of carcinogenicity in animals. It induced neoplasms of the forestomach in rats via oral route (42). Mutagen in bacteria, fungi, insects, mammalian cell assays (42). Mutagen in host mediated assays (42) 82 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Vinyl cyclohexene One U.S. producer; no Used in organic synthesis Acute: Solubility in water at 20°C: ACGIH Recommendation „„,}„.--*-„ „!--:„ 10 tof .,/,, fin\ TI.IA in — 1 1. -i \ (1-Epoxyethyl- (20) diluent for diepoxides and for irritant (43) 3,4-epoxycyclo- epoxy resins derived from Rats: Vapor Pressure at 20°C: hexane) bisphenol-A and epichlorohydrin. LD :2.83 gm/kg less than 0.1 mm (43) 3«J, -v 106-87-6 It has also been proposed for use ( oral) Liquid as a chemical intermediate and as LD -.4580 mg/m a monomer. (20) (inhalation) ( oral) (20) Chronic: Produces squamous-cell skin carcinomas in mice via skin painting (20) Mutagen in bacteria (43) 83 ESTERS Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State ___in the U.S. (Ibs./yr.)______Uses______Effects______Parameters______Regulations Allyl Isovalerate 1979 - Produced Fragrance in creams and lotions; Acute: PDA: 2835-39-4 Probably greater and a flavoring agent in foods, Rat Synthetic Food Liquid than 1,000 (43) useful in apple, cherry fruit LD :230 mg/kg Flavoring (80) blends in baked goods. (43) (oral) (7a) Chronic: NCI bioassay - carcinogenic for male rats producing mononuclear cell leukemia, and for female mice producing lymphoma, via oral route. (7) 84 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phyjsical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _Re gulations Bis(2-ethylhexyl) 1979 - Production The major plasticizer used in Acute: Bioaccumulation: OSHA: phlhalate 4.4 x 10 - U.S. accounting tor /6% of Rats HL n :30,600 Log octanol/wacer TLV-TWA 5 rag/m (di-(2-ethylhexyl) by ten companies plasticizer consumption. (43) LD :30?BOO g/kg (oral) paritition coefficient: STEL 10 mg/m (7) phthalate (38) 86% for PCV resins; 4% for (3&7 5.3 (8) (di-sec-octyl 1980 - Imports (all cellulose ester plastics; 3% for Chronic: Bioconcentration factors EPA: phthalate) octyl phthalates) synthetic elastomers; 3% for Carcinogenic in mice from 130 for fish to Priority pollutant (8) 117-81-7 7.8 x 10 (38) other vinyl resins; 1% for other and rats (38) 1.08 x 10 for mosquito Hazardous Waste (54) Oily liquid 1980 - Exports (all polymers; 3% for misc. Probably teratogenic larvae (8) Reportable quantities octyl phthalates) applications (43). and embryolethal to (89) 9.8 x 10 (38) rodents (38) Solubility in water at 25°C: National Oil & 0.4 mg/1 (8) Hazardous Substances N.J. Industrial Survey Mutagenic in dominant Contingency Plan (80) (1978-1979): lethal assay in mice Vapor Pressure at 20°C: Produced - 1-5 x lo"/yr. (38) 2 x 10 mm (8) FDA: Purchase - 1-5 x 10 /yr. Food-contact (84) Causes testicular component (80) damage in rats (38) DOT: Hazardous materials table (80) 85 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Conunercia 1 Health Envi ronmenta1 Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters ______^ Hegu 1 ations___ Bis(2-ethylhexyl) 1979 - Production Used essentially 100% as a Acute: Solubility in water: adipate 4.67 x 10 plasticizer for vinyl plastics Low toxicity to Insoluble (38) 103-23-1 - Imports for low temperature flexibility rats (2d) Liquid 6.37 x 10 (38) in vinyl meat wraps (43) Chronic: Vapor Pressure at 20°C: Limited evidence that less than 0.02 m (38). it is carcinogenic in mice. An increased incidence of liver cell tumors were produced via oral route. (38) Induces dominant lethal mutations in mice. (38) Reduces fertility in mice. (38) Non-mutagenic in bacterial assays. (38) 86 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phyjj_i£a 1 State in the U.S. (tbs./yr.)______Uses_____ Effects Parameters _____Re gulations Butyl benzyl 1979 - Production Used exclusively as a Acute: Aquatic Toxicity Rating: EPA: P Iss t ici ze r j over* £iuli is usccl Rats LD5() :2,300 LC5()96:cvcr 1,000 ppir. ! 1'ric 85-68-7 1.50 x 10 (38) with PCV to make vinyl floor mg/kg (oral) (7a) (8) Oily Liquid 1974 - Imports , tiles; also used in polyvinyl Bioaccumulat ion: Hazardous Waste (38) 1.46 x 10 (38) emulsions as adhesives in package Chronic: Log octanol/water National Oil & 1976 - Exports industry. Also used as a partition coefficient: Hazardous Contingency 1.98 x 10 (38) plasticizer with acrylic resins, 4.8 (8) Plan (80) ethyl cellulose, polyvinyl formal Non-mutagenic in Pesticide residue N.J. Industrial Survey and polyvinyl butyral (38). bacterial assays (38) Solubility in water: tolerance (80) (1978-1979): 2.9 mg/1 (8) Reportable quantities Produced - 5-10 x 10 (89) Purchased - 5-10 x 10 (84) FDA: Food-contact component (80) DOT: Hazardous materials table (80) 87 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations Diallyl Phthalate 1980 - Production Used as a crosslinking monomer Acute: Solubility in water: EPA: 5 x 106 (Dapon 35) for unsaturated polyester resins; Insoluble (43) Pesticide residue (Dapon R) 1979 - Imports monomer for thermosetting tolerance (80) 131-17-9 4 x 10 (43) molding plastics; a peroxide Vapor Pressure at 150°C: Liqu id diluent in polyester spray 2.4 mm (43) systems; as a dye carrier in Chronic: polyester dyeing; as a sealant in NCI bioassay in insulating varnishes and metal progress (7a) castings. (43) 88 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters ____Regulations Di-n-butyl 1975 - Production Plasticizer in plastisols for Acute: Aquatic toxicity rating OSHA: ^ phthaiate i .23 x 10 (43) carpet backcoating, in vinyl Ka t kU,- n -' J^ , uuu LC 96:1,000-100 ppm (/) TLV-TwA - 5 mg/m (7) 84-74-2 polymers for rotomolding or mg/kg X/a) Oily Liquid N.J. Industrial Survey dipping, in polyvinyl acetate Bioaccumulation: ACGIH Recommendation: (1978-1979): , emulsions (43) Chronic : Log octanol/water STEL 10 mg/m (7a) Produced - 5-10 x 10, Mutagenic in hamster paritition coefficient: Purchased - 1-5 x 10 fibroblastc ells. (43) 5.3 (8) Bioconcentration EPA: (84) factors of 5,000 to 6,700 Priority Pollutant (8) Teratogenic and (8) Hazardous Waste (80) emhryotoxic effects Reportable quantities in mice (7) Solubility in water at 25°C: (80) 13 mg/1 (8) National Oil & Hazardous Substances Vapor Pressure at 115°C: Contingency Plan (80) 0.1 mm (8) Hazardous water pollutant designation (80) FDA: Food-contact component (80) 89 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters ______Reg_ul_a_tion_S_____ Diethyl phthalate 1975 - Production As a plasticizer mainly for Acute: Bioaccumulation: ACGIH Recommendation: 84-66-2 1. 17 x 10 (43) cellulose ester plastics (43) Rat LD :9,000 mg/kg Log octano] /water TLV-TWA 5 mgXm Oily Liquid - Imports , Human TC • 1,000 partition coefficient: STEL 10 mg/m (7) . j IjL) 2.75 x 1(T (43) mg/m 3.22 (calc.) (8) TXF:IRR (7a) EPA: N.J. Industrial Survey Solubility in water at 25°C: Priority Pollutant (8J (1978-1979): Chronic: 986 mg/1 (8) Hazardous Waste (80) Produced - 0 , Teratogenicity, National Oil & Purchase - 1-5 x 10 (84) embryotoxicity and Vapor Pressure at 70°C: Hazardous Substances decreased fertility 0.05 mm (8) Contingency Plan (80) in rats (43) Pesticide residue tolerance (80) Reportable quantities (89) FDA: Food-contact component (80) DOT: Hazardous materials table (80) 90 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmentaI Phyjs i^al SUite in the U.S. (Ibs./yr.)______Uses Effects Parameters _ Regulations Dimethyl 1975 - Productiog 70% is used as a plasticizer, Acute: Bioaccumulation: OS HA: ,, Phthulale b.84 x 10 (43) principally in cellulose ester Kate 1,0 : 6, 900 mg/kg Log octanol/water TLV-TWA 5 mg/nT (7) 131-11-3 N.J. Industrial Survey plastics; 30% as an insect (oral) partition coefficient: STEL 10 mg/ra (7) Oily Liquid (1978-1979): repellant (43) 2.12 (calc.) (8) Produced - 0 Chronic : EPA: Purchase - 1-5 x 10s Teratogenic in Solubility in water at 25°C: Priority Pollutant (8) (84) rats (7) 4,320 mg/1 (8) Hazardous Waste (54) Reportable quantities Vapor Pressure at 20°C: (89) greater than 0.01 mm (8) National Oil & Hazardous Substances Contingency Plan (80) FDA: Food-contact component (80) DOT: Hazardous materials table (80) 91 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State_____in the U.S. (Ibs./yr.)______Uses______Effects______Parameters Di-n-octyl 1975 - Production greater Plasticizer for cellulose ester Acute: Bioaccumulation: EPA: phthalate than 1,000 (43) plastics; for polystyrene Mouse LD :6,513 Log octanol/water Priority Pollutant (8) 117-84-0 - Imports plastics; and for vinyl mg/kg (7a) (oral) partition coefficient: Hazardous Waste (36) Oily Liquid 2.2 x 10 (43) plastics (43) 9.2 (calc.) (8) Reportable quantities Chronic: (89) N.J. Industrial Survey Teratogenic in rats Solubility in water at 25°C: (1978-1979): (43) 3 mg/1 (8) FDA: Produced - 0 , Food-contact Purchased - 5-10 x 10 component (80) (84) DOT: Hazardous materials table (80) 92 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported • Commercial Health Environmental Phj^s i^aj^_^taj.e_____in the U.S. (]bs./yr.)______Uses______Effects______Parameters______Regulat ions Methyl 1975 - Production 60% is used in the production of Acute: Aquatic Toxicity Rating: OSHA: methacryjate 5.47 x 10 acrylic sheet and arylic moulding An allergen in LC :9b-1000-100 ppm (7) Air: 80-62-6 - Imports and extrusion powders; 22% in humans. (28) TWA 100 ppm (7) Liquid 1.98 x 10 the production of surface coating Solubility in water: - Exports „ resins; 8% in the production of Chronic: Sparingly Soluble (28) ACGTH Recommendation: 1.01 x 10 (28) emulsion polymers; and 10% for TWA 100 ppm (7) all other applications. (28) Vapor Pressure at 25.5°C: 40 mm (28) EPA: Hazardous Waste (54) Mutagen in bacteria Pesticide residue (7) tolerance (89) Hazardous water Caused chromosome pollutant designation aberrations in & harmful quantities rats (7) (80) Reportable quantities Embryotoxicity (89) (28) FDA: Food-contact component (80) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Vinyl acetate 1976 - Production In polymerized form for plastic Acute: Aquatic Toxicity Rating: ACGIH Recommendation: 108-05-4 1.48 x 10 masses, films, and lacquers (5) Human skin and eye LC 96:100-10 ppm (7) TLV-TWA 10 ppm Liquid (6 companies) Intermediate in synthesis of irritant. (43) STEL 20 ppm (7) polyvinyl acetate emulsions, Respi ratory Solubility in water at 20°C: - Exports „ resins, and polyvinyl alcohol. irritant. (67) 20 gm/liter (43) N10SH Recommendation: 3.28 x 10 (28) (43) CI, 15 mg/m /15 min. (7) Used in the production of Chronic: Vapor pressure at 25.5°C: emulsion paint substances, 115 mm (43) EPA: finishing and impregnation Hazardous Waste (80) materials and glue. (67) Hazardous water pollutant designation ft harmful quantities (80) Reportable quantities (89) FDA: Food-contact component (80) DOT: Flammable Liquid (54) 94 ETHERS AND LACTONES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Bis(2-chloroethyl)- 1976 Production probably Used as soil fumigant, as an Acute: Aquatic toxicity rating: OS HA: ether greater than 5000 insecticide, and as an acaricide; Highly toxic via LC5Q96:1000-100 ppm (7) Air: (dichloroether) (43) No longer as a solvent for fats, waxes, oral and inhalation CL 15 ppm (7) 111-44-4 produced for sale greases and cellulose esters; as a routes, moderately Bioaccumulation: Liquid in commercial scouring agent for textiles, in toxic via dermal Log octanol/water ACGIH Recommendation: quantities. Two US paints varnishes and lacquers; as route (2f) partition coefficient: TLV-TWA 5 ppm companies produced a paint remover; in dry cleaning; Rat: 1.58 (8) STEL 10 ppm (skin)(7) it for use within as an intermediate in the LD,...:75 rag/kg (oral) their own plants and synthesis of morpholine compounds Rat: Solubility in water: EPA: subsidiaries. (18) and of divinyl ether (18) LDLO : 1000 ppm/45 rain 10,200 mg/1 (8) Priority pollutant (8) (7a) N.J. Industrial Survey Chronic: Vapor Pressure at 20°C: Hazardous Waste (80) (1978-79): Carcinogenic in mice 0.71 mm (8) National Oil & Produced - 0 producing liver - cell Hazardous Substances Purchased - less than tumors via oral route, Contingency Plan 1000/yr. and local sarcomas via (80) Reportable Max. Inventory. - 100-500/yr. subcutaneous injection quantities (89) (84) (18) DOT: Mutagenic in bacteria Flammable liquid, and Drosophila (1,7) poison (54) 95 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmenta1 Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations______ Bis(2-chloromethyl) No evidence that it is An unisolated component of Acute: Bioaccumulation: OSHA: ether produced on a commercial chloromethylating reaction Humans Log octanol/water partition Carcinogen (7) 542-88-1 scaJe for sale to others mixtures in organic synthesis LC •. 100 ppm/3 rain. coefficient: 0.38 (8) ACGIH Recommendation: Volatile Liquid (13) for a) preparation of anion- Carcinogen (54) exchange resins; b) formation Solubility in water at 25°C: N.J. Industrial Survey of water repel]ants arid other Chronic : 22,000 mg/1 (calc.) (8) EPA: (1978-79): textile-treating agents; c) Carcinogenic in mice Removal from Produced - 0 manufacture of polymers and d^ and rats (42) Vapor pressure at 22°C: priority pollutant Purchased - 0 as solvents for polymerization 30 min. (8) list in 1981. Max Inventory - 0 reactions (1) Human carcinogen (42) Hazardous Waste (54) (84) Atmospheric residence time: National Oil & Mutagen in bacteria 0.02-2.9 days (44) Hazardous Substances (42) Contingency Plan Detection in environmenal (80) media : USEPA-0.16% (78) DOT: Poison (54) Potable water, raw and treated: NJDEP (OSR)-0/245 (86) 96 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State J.IL_tJ»e_ U.S. (Ibs./yr.) Uses Effects Parameters Re guj_ a t_ip n s^ Bis(2-Chloro-l- 1975 - Production greater Solvent for fats, waxes and Acute: Bioaccumulation: OSHA: methy J elliyl jether than a x 10 (1) greases; extractant in paint and Minimally irritating log octanol/water No standard (Dichloroisopropyl varnish removers; a component of to skin and eyes. Partition coefficient: recommended ether) spotting and cleaning solutions; Absorbed through the 2.58 (8) Provisiona1 level 108-60-1 Used in textile processing. (1) skin and can be lethal is 15 ppm. (54) Liquid at high doses. (64a) Solubility in water at room temperature: EPA: Chronic: 1,700 mg/1 (8) Priority Pollutant NCI carcinogenesis (8) bioassay with rats Vapor pressure at 20°C: Hazardous Waste (54) was negative. (7) 0.71-0.85 mm (43) Mutagenic in bacteria DOT: (1) Detection in environmental Corrosive Material May cause damage to media: (54 ) liver and kidney (64a) Industrial effluents and intakes: USEPA - 1.3% (78) Potable water raw and treated: NJDEP (OSR) - 0/245 (86) POTWs NJDEP (OSR) influents - 0/9 effluents - 0/9 (88) 97 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr. )______Uses_____ Effects Parameters _Regulations 2-Chloroethyl 1975 - Production probably Used in the manufacture of Acute: Bioacciunulation: EPA: vinyl ether greater than 1000 anesthetics, sedatives, and Rat: log octanol/water Priority Pollutant(S) 110-75-8 (43) cellulose ethers. (43) LD :250 mg/kg (oral) Partition coefficient: Hazardous Waste (54) Liquid LCjT":250 ppm/4 hr. 1.28 (8) Reportable (inhalation) (7a) quantities (89) Moderately toxic via Solubility in water at 25°C: ingestion or 15,000 mg/1 (8) DOT : inhalation. (6) Hazardous materials Vapor pressure at 20°C: Table (80) 26.75 min. (8) Detection in the environmental media: Industrial wastewater and intakes: U.S.EPA - 1.1% (78) 98 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phys^ca1 State in the U.S. (Ibs./yr.)______Uses______Effects Parameters Chloromethyl Four U.S. companies produced Intermediate in preparation of Acute: Aquatic Toxicity Rating: OSHA methyl ether an unknown amount in 1961.(9) exchange resins and numerous Kat: LC 96:1000-100 ppm (la) Carcinogen (7a) (CMME) May be produced as a chemical chloromethylated compounds (13) LD :817 mg/kg (oral) 107-30-2 intermediate (13) Used in the formation of water In Humans the Solubility in water: EPA: Liquid Commercial CMME contains repellants; the manufacture of principal effect is Soluble (9), but is Hazardous Waste (54) from 1 to 7% BCME, a known polymers; and as a solvent for irritation of the readily hydrolyzed (13) Reportable carcinogen. (54) polymerization reactions (1). skin and eyes. (43) quantities (89) Vapor pressure: Chronic: Highly Volatile (43) DOT: Increased risk of Flammable liquid lung cancer in CMME Atmospheric residence time: and poison (54) workers. May be due 0.004-3.9 days (44) to BCME contamination (13) Technical grade produces local sarcomas after subcutaneous injection. Also, an initiator of skin tumors (42) Mutagen in bacteria (42) 99 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations Decabromodiphenyl 1975 - Production greater Flame retardant for epoxy resins, Acute: oxide than 1,000. (43) nitrile resins, polyester, Low toxicity in rats (Decabromobiphenyl polystyrene, polyethylene, (43) ether) N.J. Industrial Survey polypropylene, polyvinyl acetate, 1163-19-5 (1978-79): , and PVC. (43) Chronic: Produced - 1-5 x 10 /yr Teratogenic in rats Purchased - 1-5 x 10 /yr (43) (84) 100 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental _Physical_State_ in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations 4,4'-Diaminophenyl 1978 - Production probably One of the few aromatic diamines Acute: Solubility in water: ether greater Lhait 2000. LiiaL produces outstanding high- Causes liver and Insoluble (38) (4-Aminophenyl Two U.S. companies temperature resistance in straight kidney damage in mice ether) produced it in 1982. polyimide resins. It is believed treated orally or 101-80-4 (38) to be widely used. Such resins Subcutaneously. (38) Solid are used in a variety of products 1980 - Imports , designed to resist high Chronic: 4.8 x 10 (38) temperatures, such as wire Sufficient evidence that enamels, coatings, films, it is carcinogenic in adhesives, insulating varnishes, mice and rats. (38) coated fabrics and machine parts. Mutagenic in bacteria. It can also be used as an (7) intermediate in the manufacture of epoxy resins and adhesives. But there is no evidence that it is used this way commercially. (38) 101 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmenta1 PhysicaL State_ in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ? ?-£u Nations 1,4-Dioxane 1973 - Production Mainly used as a stabilizer Acute: Aquatic toxicity rating: OSHA: (p-Dioxane) 1.63 x 10 in chlorinated solvents; as a Humans LC5Q96:1000-100 ppm (7) Air: 123-91-1 by 4 companies. (20) solvent for cellulose acetate, LC :470 ppm/3 days TWA 100 ppm (skin) Liquid ethyl cellulose, benzyl cellulose, (inhalation) (7a) Solubility in water: (7) N.J. Industrial Survey resins, oils, waxes, and Miscible (20) (1978-79): some dyes; as a solvent for Chronic: ACGIH Recommendation: Produced - 5-10 x 10^/yr electrical, agricultural and Carcinogenic in rats Vapor pressure at 20°C: TLV-TWA 25 ppm Purchased - 1-5 x 10 /yr biochemical intermediates and and guinea pigs (20) 27 mm (20) STEL 100 ppm (7) (84) for adhesives, sealants, A promoter in a cosmetics, pharmaceuticals, rubber two-stage Atmospheric residence time: EPA: chemicals and surface coatings carcinogenesis study 3.9 days (44) Hazardous waste (54) (20) in mice (20) Pesticide residue Detection in environmental tolerance (80) media: Reportable Ambient air: quantities (89) NJDEP (OSR)- infrequently (83) DOT: Flammable liquid (54) N.J. : Toxic volatile organic substance (81) 102 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi r onme nt a 1 LhY.5i£?l State in the U.S. (Ibs./yr. )______Uses_____ Effects Parameters Regulations Beta-Propiolactone 1975 - Production less than Over 85% is used in captive Acute: Aquatic toxicity rating: OS1IA: 57-57-8 1000 (43) consumption tor synthesis of A powerful irritant LC:1000-100 ppm (7) Carcinogen (7) Liquid acrylates; less than 15% is used (2f) N.J. Industrial Survey as a sterilant (43) Rat: Solubility in water at 25° (1978-79): LC :25 ppm/6 hr. 37% V/V (43) Produced - 0 (inhalation) (7a) Purchased - 0 Vapor pressure at 25°C: Max Inventory - 0 Chronic: 2.4 mm (43) (84) Animal carcinogen (13) Mutagen in bacteria (1 , 7a) and yeast. (1) Mutagen in Drosophila (7) Mutagen in mammalian cells (7) 103 Substance Name (Synonym) Amount Produced Major CAS Numher Imported, Exported Commercial Health Environmental Physical State_____in the U.S. (Ibs./yr.)______Uses______Effects______Parameters______Regulations______ Safrole 1977 - Production and In perfumery; denaturing fats in Acute: Solubility: EPA: 94-59-7 importation of in soap manufacturing; topical Rat Insoluble in water (43) Hazardous Waste (36) (4-Allyl-l,2- over 2 million antiseptic; chemical intermediate LD :1950 mg/kg (oral) Cancellation of its methylenedioxy Ibs. by 9 companies. for synthesis of heliotropin and (43) Vapor pressure: use in pesticide benzene) (9) piperonyl butoxide (43) Mice - LD -.2350 1 nun Hg at 63.8°C (43) production 1978 (9) Liquid mg/kg (oral) (43) Reportable quantities (89) Chronic: Animal carcinogen in FDA: mice, induced hepatomas Use as a flavoring via oral route. In agent prohibited rats induced liver (10) adenomas via oral route (10) DOT: Hazardous materials Bacterial mutagen (43) table (80) Positive in host - mediated assay (7) Mutagen in mammalian cells arid yeast (7) KM Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations Tetrahydrofuran 1975 - Production greater Used as a solvent to dissolve Acute: Solubility in water at 25°C: OSIIA: (THF) than 2,000 synthetic resins, particularly Humans - 30% (43) TLV-TWA-200 ppm (7) 109-99-9 polyvinyl chloride and vinylidene proabable lethal dose Liquid - Exports , chloride copolymers; Used to cast via oral route 50-500 Vapor pressure at 15°C: EPA: 7.14 x 10 (43) polyvinyl chloride films; used mg/kg. (43) 114 mini. (43) Hazardous Waste (54) to coat substrates with vinyl and Humans: Reportable and vinylidene chloride; and used TC 25,000 ppm quantities (89) to solubilize adhesives (43) (inhalation) TXF: CNS (43) DOT: Flammable liquid(54) Chronic: Animals - liver and FDA: kidney damage (54) Food contact component (80) Currently being tested by NTP for carcinogenesis (7) 105 HALOGRNATED ALKANES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physic-al State__ in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Bromoform As an intermediate for organic Acute: Bioaccumulation: OSHA: 75-25-2 N.J. Industrial Survey synthesis and pharmaceutical Toxic by ingestion, log octanol/water Air: Liquid (1978-79): manufacture; as a solvent for wax, inhalation and skin Partition coef.: 2.3 (8) TLV-TWA O.Sppm Produced - 0 grease, oil and fat; as a reagent absorption. (3e) (skin) (7) Purchased - 1,000-5,000 for geochemical analysis; as a Animals: Solubility in water at 30°C: (84) sedative and antitussive; as an Mice 3,190 ppm (8) EPA: ingredient in fire retardant LD :1400 mg/kg Priority chemicals. (3e) (oral) (7) Vapor Pressure at 34°C: Pollutant 10 mm (8) Hazardous Wast^ (54) Chronic: National Oil & Mutagen in vitro in Thought to be formed during Hazardous Substances bacteria (7) chlorination of water (8) Contingency Plan (80) Detected in environmental: Reportable quantities (89) Industrial Effluents and Influents: DOT: USEPA - 1.7% (78) Use (X) on label NJDEP (OSR) - 2/28 (82) (54) Potable Water, raw FDA: and treated: Bottled water NJDEP (OSR) - 0/496 (86) quality (80) Ambient Air: NJDEP (OSR) - not detected (83) 106 Substance* Name (Synonym) Amount Produced Major CAS Nunitxsr Imported, Exported Commercial Health Environmental Physical State J_'L.tl'£__ki.S. (Jhs./yr.)__ _ Uses Etfects Parameters Carbon 1979 - , Used in the manufacture of Acute: Aquatic toxicity rating: OS11A: Tetrachloride Production - 730 x £0 FREONS 11 and 12; In indus Humans: IX 96:100-10 ppm (7) Recommended 56-23-5 Imported - 5.4 x 10, trial degreasing operations; LDL[) : 4:img/kg (oral) Air standard: liquid Exported - 8.5 x 10 (9) as a solvent; as a grain LC rfl : 1000 ppm (inhal.) Bioaccumulation: TWA - 5 ppm funiigant. (9) Jog octanol/water STEL - 20 ppm Consumption is partition coeff.: 2.64 (8) (skin) (7) decreasing. (9) Chronic: Animal carcinogen Solubility in Water at 20°C EPA: N.J. Industrial Survey (42) 785 ppm (8) Priority (1978-79): Embryo toxic (29) Pollutant (8) Produced - 1-5 x 10 /yr Vapor Pressure at 20°C: Hazardous Purchased 1-5 x 10 /yr (84) 90 mm (8) Waste (54) Reportable Atmospheric residence time: quantities (89) 11,000 days (44) Pesticide residue tolerance (80) Detection in environmental National Oil & media: Hazardous Substances Contingency Plan (80) Industrial Wastewaters Hazardous Water and intakes: Pollutant Designa USEPA - 6.3% (78) tion & harmful NJOSR - 3/28 (82) quantities (80) Groundwater: DOT: NJOSR - 26.8% (85) ORM - A (54) Potable Water, Raw and FDA: Treated: Use banned in all NJOSR - 3.8% (86) products unless present as an Air: unavoidable by NJOSR - almost 100% (83) product which will not yield ambient levels of 10 ppm (9) CPSC: Use banned except for manufacturing residues (9) N. J. : Restricted Pesticide (81) Toxic Volatile Organic Substance 107 (81) Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Physical StaJ:e_ in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ______Regulations Chloroform 1977 - , As a solvent; in the manu Acute: Aquatic toxicity: OS HA: 67-66-3 Production - 17 x 10 facture of chlorofluorometh- Moderately toxic by IJC5096:100-10ppm (7) Air 1 i quid Imports - 4 x 10 , ane; as a refrigerant and as oral and inhalation TWA - 50 ppm Exports - 20 x 10 an aerosol propellant; as a routes (2d) Bioaccumulation: CL 2 ppm/60 min. (9) raw material in the production Humans: log/octatiol /water (7a) of fluorinated resins; as a LD :140mg/kg (inhal) partition coeff.: 1.97 (8) N.J. Industrial Survey fumigant; as an anesthetic; in Tc''":5000mg/kg/7 min. EPA: (1978-1979): pharmaceuticals. (1) (infial.) Solubility in Water at 20°C: Priority Pollutant Produced - less than TXF: CNS (7) 8,200 ppm (8) (8) 1,000/yr. Hazardous Waste (54) Purchased 1-5 x 10 /yr (84) Chronic: Vapor Pressure at 20°C: Reportable Prolonged exposure 150.5 mm (8) quantities (89) causes liver & kidney Hazardous Water damage (2d) Atmospheric residence time: Pollutant Designa Animal carcinogen. 120 days (44) tion & harmful (42) quantities (80) Pesticide residue Embryotoxic (29) Detected in environmental: tolerance (80) media: National Oil & Hazardous Substances Industrial Wastewaters Cot ingency Plan (80) and intakes: USEPA - 37% (78) DOT: NJOSR - 19/28 (82) ORM - A (54) Groundwater: FDA: NJOSR - 14.5% (85) Use banned in drug, cosmetic, and food Potable water, raw packaging products. and treated: (5) NJOSR - 37.5% (86) N.J. : Ambient. Air: Toxic Volatile NJOSK - over 70% of samples. Organic Substance (83) (81) 108 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical J5tate ___in the U.S. (ibs./yr.)______Uses______Effects Parameters Regulati t>r 1,2-Dibromo- Two major producers Soil fumigant to control Acute: Solubility in Water: OSIIA: 3-Chioropropane discontinued pesticide nemalodes on cotton, tobacco, It is a moderate to 0.1% (w/w) (29) Air (DBCP) production and recalled vegetables, fruits, greenhouses, high toxicity chemical, TWA 1 ppb 96-12-8 supplies in August 1977. (9) nursery crops. (43) irritant via oral and Vapor Pressure at 21°C: CL 10ppm/30 min (7a) inhalation routes (1) 0.8 mm (29) N.J. Industrial Survey EPA: (1978-1979): Chroni c: Hazardous Waste (54) Produced - 0 Carcinogenic in mice On November 9, 1979 Purchased - 0 (84) and rats (29) EPA suspended, unconditionally all Mutagenic in Ames DBCP-containing test (29) products for end uses except for use Observed increase in on pineapples in Sterility in Industrial Hawaii. It further Groups (29) cited an intent to cancel uncondition al ly all remaining end uses of all registered DBCP- containing pesticide products. (9) Hazardous Waste (80) Reportable quantities (89) PDA: Maximum residue levels of 1.5 mg/1 i n raw mi Ik. Maximum residue levels of 0.05 mg/1 in a 11 other raw agri cut tural commodities. (9) DOT: Hazardous Materials Table (80) 109 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Pjiys ica 1 State____iii_the U.S. (Ibs./yr.) Uses- Effects Parameters Regulations ______ 1,2-Dihromoethane 1975 - 275.6 x 10 (1) As a lead scavenger in tetraalkyl Acute: Aquatic toxicity: OSHA: (t'lhylene dibromide) lead gasoline; as a soil and Irritant via oral, LC 96:100-10ppm (7) Air-TWA 2-ppm 106-9:1-4 N.J. Industrial Survey grain fumigant; as an intermediate dermal, and Cl, 30ppm Liquid (1978-1979): in the synthesis of dyes and inhalation routes (2e) Solubility in Water at 30°C: Peak 50/5 Produced - 1-5 x 10 /yr pharmceuticais; as a solvent for Female 4,300 ppm (24) min/day (7) Purchased - 1-5 x 10 /yr resins, gums and waxes. (1) LD : 90mg/kg (7) (84) Vapor Pressure at 25°C: EPA: Chronic: 11 mm (24) Hazardous Waste (54) Prolonged exposure can Reportable cause liver damage; (2e) quantities (89) Pesticide residue Animal carcinogen in Detected in environmental: tolerance (80) mice and rats, media: Hazardous Water (42) Mutagen Pollutant designa- in bacteria, fungi, Groundwat er: t ion & harm!u 1. plants, insects and NJDEP - 3.6% (85) quantities (80) cultured mammalian cells (42) Ambient Air: NJDEP: NJDEP (OSR) 22% (83) Restricted Pesticide (81)) Toxic Volatile Organic Substance (81) FDA: Pesticide residue tolerance (80) no Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State JELAhe IK^_ (lbs./yr. )______Uses ____ Effects Parameters Dirhlorobromo- Not produced commercially Chemical intermediate; solvent; Acute: Bioaccumulation: EPA: rncthane in the U.S. (43) flame retardant. (43) Animals: Log octanol/water Priority 75-27-4 Rat LD :916 mg/kg Partition coefficient is Pollutant (8) Liquid N.J. Industrial Survey (orairX7a) 1.88 (8) Hazardous Waste (1978-79): (80) Produced - 0 Solubility in water: National Oi1 & Purchased - 0 No data (8) Hazardous Substances (84) Contingency Plan Vapor Pressure at 20°C: (80) 50 mm (8) Reportable quantities (89) Thought to be formed during the chlorination process. (8) FDA: Bottled water Detection in environmental quality (80) media. DOT: Industrial effluents and Hazardous Materials intake waters: Table (80) USEPA - 4% (78) NJDEP (OSR) - 5/28 (82) Groundwater: NJDEP (OSR) - 7% (85) Potable water, raw and intakes: NJDEP (OSR) - 73/498 (86) POTWs NJDEP (OSR) influents 14/18 effluents 12/18 (88) 111 ( Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmenta1 Physical State_____ in the U.S. (Ibs./ Uses Effects Parameters _____ Regulat ions 1,1-Dichloroethane Solvent for extraction of heat Acute: Bioaccumulation: OSHA: 75-34-3 sensitive substances, for rubber, Low toxicity (64b) ,log octanol/water Air: silicone grease, dewaxing mineral Partition coefficent: TWA lOOppm (7a) oils. (43) Chronic: 1.48 (8) ACGII1 Recommendation Not teratogenic TWA 200ppm (64b) Solubility in water at 20°C: STEL 250 ppm (7a) Results of NCI 8,690 mg/1 (8) carcinogen bioassay EPA: were indefinite (7) Detection in environmental Priority Pollutant media: (8) Hazardous Waste (54) Industrial wastewaters Report able and intakes: quantities (89) USEPA - 1.9% (78) NJDEP (OSR) - 4/27 (82) DOT : Flammable Liquid Potable water, raw and (54) treated: NJDEP (OSR) - 5/495 (86) Ambient Air: NJDEP (OSR) - Dichloroethanes were detected in 35-70% of samples. (83) 112 Subs lance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Physical State _ _ln_the U.S. (Ibs./yr.)______Uses______Effects Parameters __^ _ _RegulatM)ns 1,2-Dichloroethane 1976 - Producted 7.92 x 10 86% is used as an intermediate Acute: Aquatic Toxicity Rating: OSIIA: (Ethylene (43) tor vinyl chloride; also used as Inhalation causes LC 96:1000-lOOppm (/) TLV-TWA lOppm; Di chloride) N.J. Industrial Survey an intermediate for 1,1,1-tri- damage to CNS STEL - 15ppm (7a) 107-06-2 (1978-79): 5 chloroethane, tetrachloroethane, Moderately toxic via Bioaccumulation: 1 i qn i d Produced - 1-5 x 10 /yr dichloroethane, and trichloro- oral route (2d) Log/octanolwater EPA: Priority Purchased - 1-5* r x- 10'/yr ethylene; used as a lead scavanger Humans: partition coefficient: Pollutant (8) (84) in gas; used as a solvent, and used TC :4000ppm/hr 1.48 (8) Hazardous as a component of fumigants. (1) (i if ha 1 a t i on) Waste (54) TXT: CNS Solubility in water at 20°C: National emission LD :428mg/kg (oral) 8,690 mg/1 (8) standards (80) Reportable Vapor Pressuare at 20°C: quantities (89) Chronic: 61 mm (8) National Oil & Is an experimental Hazardous Substances carcinogen in mice Atmospheric at 20°C: Contingency Plan and rats via oral 53 days (44) (80) route (29) Pesticide residue Detected in environmental tolerance (80) Mutagen in bacteria media: Hazardous Water and Drosophila and Pollutant designa plants (29) Industrial Wastewaters tion & harmlul and intakes: quant i t i es (80) USEPA - 6% (78) NJOSR - 3/28 (82) 1)011: Flammable Liquid (54) Groundwater NJOSR - 5.8% (85) N.J. : Restricted Pesticide Potable Water, raw (81) and treated Toxic Volatile NJOSR - 3/297 (86) Organic Substances (81) Ambient Air: NJOSR - Dichloroethanes FDA: were detected in 'i!i-70% h'ood contact of samples. (8i) component (80) Feed additive (80) Extraction residue tolerance (80) Pesticide residue tolerance (80) 113 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State_ Uses Effects Parameters Regulations^ __ 8 Di chlorometllane 1975 - Produced 4.98 x 10 As a paint remover (32%); As a Acute: Aquatic Toxicity Rating: OSIIA: (Methyleue - Imported 1.21 x lo solvent for degreasing (10%); Inhalation by humans IX 96:1000-100ppm (7) TLV-TWA lOOppm chloride) - Exported 9.69 x 10 Misc. uses are as a solvent in has produced central STE1, - SOOppm (7) 75-09-2 (43) pharmaceutical applications; in nervous system damage Bi oaccumulation: 1iquid the extraction of naturally and blood dyscrasias log octanol/water EPA: Priority N.J. Industrial Survey occurring heat sensitive Humans: partition coefficient: Pollutant (8) (1978-1979): substances; in the manufacture of TL ;500ppm 1.25 (8) Hazardous Produced - 0 photographic film and synthetic TXF: CNS (2b) Waste (.*>4) Purchased - 1-5 x 10 /yr fibers; and as a component of Solubility in Water at 25°C: Reportable (84) five extinguishing compositions. Chronic: 13,200 to 20,000 mg/1 (8) quantities (89) (43) A mutagen in Pesticide residue Drosophila (42) Vapor Pressure at 20°C: tolerance (80) 362.4 mm (8) National Oil & Hazardous Substances Atmospheric Residence Time: Contingency Plan 77 days (44) (80) Detected in environmental: FDA: media: Food contact component (80) Industrial Wastewater Flavor extraction and intakes: residue tolerance USEPA - 36.2% (78) (80) NJDEP (OSR) - 13/28 (82) DOT: Potable Water, Raw ORM - A (54) and Treated: NJDEP (OSR) - 43.1% (86) N . J . : Hestri cted Air: Pesticide (81) NJDEP (OSR) - 100% (83) 114 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical_Stal.e_ in_the U^S_._(Ibs./yr.) Uses______Effects Parameters Regulations______ 1 ,2-Dichloro 1974 - 40.8 x 10ft As a chemical intermediate in the 'Acute: Bioaccumulation: OSIIA: propane 1975 - 84.2 x 10" (43) production of tetrachloroethylene Toxic by inhalation log octanol/water TLV-TWA /bppm 78-87-5 and carbon tetrachloride; As an and ingestion. (6) Partition coefficient: STEL - llOppm Liqu id N.J. Industrial Survey ingredient in fumigant D-D; (1) 2.28 (8) (7) (1978-79): and as a solvent for fats, oils, Chronic: Produced - 0 waxes, gums, and resins. (6) A bacterial mutagen Solubility in water at 20°C: EPA: Purchased - 0 (84) (1) 2,700 mg/1 (8) Priority Pollutant (8) Vapor Pressure at 20°C: Hazardous Waste (54) 42 mm (8) Pesticide Residue Tolerance (80) Detected in environmental Hazardous Water media: Pollutant Designa tion (80) Industrial effluents and Reportable intakes: quantities (89) USEPA - 1.7% (78) NJDKP: NJDEP (OSR) - 1/28 (82) Restricted Pesticide (81) Potable water, raw and treated: NJDEP (OSR) - 0.2% (86) Air NJDEP (OSR) - Not detected (83) 115 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronment a 1 in the U.S. (Ibs./yr.)_____Uses___ Effects Parameters ______Regulations______ Ethyl chloride 1975 - Produced 90% for the synthesis of Acute: Aquatic Toxicity Rating: OSHA: (Chloroethane) 5.7 x 10 tetraethyl lead; 10% for Has anesthetic LC5()96:over 1,000 (7) Air 75-00-3 - Imported such applications as solvent properties. (64b) 1,000 ppm gas, compressable 4.8 x 10 refrigerant, and in the Bioaccumulation: ACGIH Recommendation: - Exported manufacture of ethyl cellulose Possibility of log octanol/water STEL 1 ,250 ppm (7a) 1.1 x 10 (43) plastics, dyes, and potentiation of partition coefficient: pharmaceuticals. (43) adrenalin resulting 1.54 (8) EPA: in cardiac problems. Priori ty (64b) Solubility in water at 20°C: Pollutant (8) 5,740 mg/1 (8) Hazardous Waste (80) Reportable Vapor Pressure at 20°C: quantities (89) 1,000 mm (8) DOT: Detected in environmental Flammable Liquid media: iForms phosgene on combustion] (54) Industrial wastewaters and intakes: USEPA - 0.41% (78) NJDEP (OSR) - 1/28 (82) Potable water, raw and treated: NJDEP (OSR) - 2/496 (86) Ambient Air: NJDEP (OSR) - in 35-70% of samples. (83) 116 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Physical Jvtate in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _Regulat i ons Hexachloroethane No data on production or As a constituent of candles and Acute: Bioaccumulation: OSHA: 67-72-1 exports. grenades to generate smoke and tog; Toxic by ingest ion and; Log octanol/water TWA tor air solid 1978 - Imports a degassing agent for magnesium; inhalation; strong partition coefficient: 1 ppm (7) 1.7 x 10 (43 ) a component of extreme pressure irritant; absorbed by 3.34 (8) lubricants; an ignition in com skin. (6) EPA: N.J. Industrial Survey bustible liquids; a moth repellant; Solubility in water at 22°C: Priority (1978-79): a plasticizer for cellulose Chronic: 50 mg/1 (8) Pollutant Produced - 0 esters; a flukacide in veterinary Suspected animal (8) Purchased - 1-5 x 10 /yr. medicine; an accelerator in rubber; carcinogen (29) Vapor Pressure at 32.7°C: Haza rdous (84) a retardant in fermentation 1 mm (29) Waste (54) processes; a component in submarine National Oil & paint; an additive to fire- Atmospheric Residence Time: harmful Substances extinguisher fluids; and as a 11,600 days (45) Contingency Plan constituent of various fungicidal (80) and insecticida] formulations. (3b) Reportable Detected in environmental: quantities (89) media: DOT: Industrial Wastewaters ORM - A (54) and intakes: USEPA - 0.46% (78) Potable Water, raw and treated: NJDEP (OSR) - 0/245 (86) 117 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Pby.s i ca Instate in the U.S. (Ibs./yr.) Uses Effects Parameters Methyl Bromide 1972 - 2.47 x 10 (43) Soil and space fumigant; Acute: Aquatic Toxicity OSI1A: 74-83-9 insecticide, rodenticide, and Toxic by ingestion, LC 96:over 1000 ppm (7) TLV-TWA 5 ppm (7) gas N.J. Industrial Survey nematocide; as a chemical inhalation and skin STEL - 15 ppm (skin) (1978-79): intermediate. Extraction of oils absorption; strong Bioaccumulation: (Va) from nuts, seeds and flowers; for irritant (6) Log octanol/water Produced - 0 degreasing wool (43) Human: partition coefficient EPA: Purchased - 5-10 x 10 /yr Can cause central 1.1 (8) Priority (84) nervous system de Pollutant (8) pression and kidney Solubility in water at 20°C: Hazardous Waste (54) injury. (6) 900 mg/1 (8) Pesticide residue tolerance (80) Vapor Pressure at 20°C: Pesticide use 1,420 mm (8) classification (80) Reportable Atmospheric Residence Time: quantities (89) 289 days (45) DOT: Detected in environmental Poison gas (54) Media: USDA: Industrial wastewater Pesticide treatment and intakes: (80) USEPA - 0.06% (78) NJDEP (OSR) - 0/28 (82) PDA: Pesticide residue Groundwater: tolerance (80) NJDEP (OSR) - 0.3% (85) Exempted prescription drug Potable water, raw and ingredient (80) treated: NJDF.P (OSR) - 0/496 (86) NJDEP: Ki'Ktricted Ambient Air: I'cs t icide (81) N.JDKP (OSR) - Detected infrequently (83) 118 Substances Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phys i ca 1 State in the U.S. (Ibs./yr.) Uses Effects Parameters jtegulat ions_ Methyl Chloride 1975 - 3.66 x 108 Chemical intermediate in Acute: Aquatic Toxicity Rating: OSHA: 74-87-3 (43) production ot silicones (43%) Toxic in high LC 96:over lOOOppm (7) TI.V-TWA - 50ppm gas tetramethyllead (38%); as a concentrations STEL - lOOppm (skin) N.J. Industrial Survey catalyst solvent for butyl rubber Rat: Bioaccumulation: (7a) (1978-1979): (4%); as an intermediate in the LC :152,000mg/m / log octanol/water Produced - 1-5 x 10 /yr manufacture of methyl cellulose; 30 min (inhal.) (7) partition coefficient: EPA: Purchased - 1-5 x 10 /yr Tripane, methylmercaptan and 0.91 (8) Priority Pollutant (84) pesticides; as an extraction Chronic: (8) solvent; (43) Refrigerant (3d) Can cause damage to Solubility in water at 20°C: Hazardous Waste (54) the central nervous 6,450 tO 7,250 mg/1 (8) National Oil & system and less Hazardous Substances frequently to the Vapor Pressure at 20C: Contingency Plan liver, kidneys, bone is 3,766 mm (8) (80) marrow and Pesticide residue cardiovascular system Atmospheric Residence Time: tolerance (80) (3d) 83 days (44) Reportable quantities (89) Detected in environmental: media: DOT: Flammable gas (54) Industrial Wastewaters and Dangerous cargo (80) intakes: Particular hazard USEPA - 1.7% (78) (80) NJDEP (OSR) - 1/28 (82) Toxic cargo (80) Groundwater: PDA: NJDEP (OSR) - 0.3% (85) Pesticide residue tolerance (80) Potable Water, raw and treated: NJDEP (OSR) - 0/245 (86) Ambient Air: NJDF.P (OSR) - over 70% of samples. (83) 119 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Reguljjt ions______ Methyl Iodide 1973 - Production Used as a chem intermediate Acute: Solubility in water at 15°C: OSHA: 74-88-4 1.9 x 10 in the synthes f Primarily a CNS 1 vol/125 vol water (64b) Air: Liquid by three companies methylmercuric ide and depressant. Also TWA 5 ppm (7a) (24) dimethylmercury, methyl- indications of lung Vapor Pressure at 25°C: lithium. Also a chemical irritations and 400 mm (64b) ACGIH Recommendation: intermediate in the synthesis kidney involvement TWA 2 ppm of methylamines, quaternary acute exposure STEL 5 ppm (skin) ammonium iodides and phosphonium (7a) salts. (43) Chronic: Carcinogenic in rats EPA: inducing local sarcomas Hazardous Waste (54) via subcutaneous Reportable injection. (24) quantities (89) Mutagen in bacteria DOT: (7) Hazardous Materials Table (80) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Physi_caJ_State_ __ in the U.S. (Ibs./yr.)______Uses______Effects Pa rameters ____ Regulat ions______ 1,1,2,2-Tetra- 1976 Production was^probably As an intermediate in the Acute: Bioaccumulation: OS HA: T I \7 Tl IA 1 ,„_ chi oroelhaue greater, than 4 x 30 v.43,j uiaiiuf eiCunic: of 11" LchloLoet-hyleiie Liver poison and log cctanol/water i ij v - i nn ~ i I'^ftu 79-34-5 1975 - Imports 3.7 x 10 (43) from acetylene; Minor use as a narcotic. partition coefficient STEL - 5 ppm 1iquirt solvent and fumigant. (29) » Humans: 2.56 (8) (skin) (7) N.J. Industrial Survey TD :30mg/kg (oral) (1978-79): TXF: CNS Solubility in water at 20°C EPA: Produced - 1,000-5 ,000/yr TCJn :lOOOmg/m /30min. 2,900 mg/1 (8) Priority Pollutant Purchase - 5-10 x 10 /yr tinhal.) (2e) (8) (84) Vapor Pressure at 20°C: Hazardous Waste (54) Chronic: 5 mm (8) Reportable Limited evidence that quantities (89) it is carcinogenic in Atmospheric Residence Time: mice (29) greater than 1,160 days DOT: (44) ORM - A (54) Mutagen in bacteria (29) Detected in environmental: N.J. : Media: Toxic Volatile Teratogen in mice Organic Substance (29) Industrial wastewaters and (81) intakes: USKPA - 3.4% (78) NJDEP (OSR) - 1/28 (82) Groundwater: NJDEP (OSR) - 2.1% (85) Potable water, raw and treated: NJDEP (OSR) - 1/498 (86) Ambient Air: NJDEP (OSR) - 0-25% (83) 121 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses______Effects Parameters ___Regulations 1,1 , 1-Trichloro- 1975 - Production 4 ? 59 x 10 For cold cleaning of metals and Acute: Aquatic Toxicity Rating: OSHA: ethane - Exports 7.01 x 10 (43) other materials (54%), for vapor Produces a significant LC 96:100-10 ppm (7) Air 71-55-6 degreasing (13%), for export toxic effect in the TI.V-TWA - 350ppm L i qu i d N.J. Industrial Survey (13%), for synthesis of vinylidene form of a functional Bioaccumulation: STEL: 450 ppm (7) (1978-1979) chloride (9%), for misc. depression of CNS log octanol/water Produced - 0 applications including use in leading to respiratory partition coefficient EPA: Priority Purchased - 1-5 x 10 (84) aerosols. (43) failure. (3a) 2.17 (8) Pollutant (8) Humans: Hazardous Waste (54) TC :920 ppm/70 min Solubility in Water at 20°C: National Oil & TXF: CNS (3a) 480 to 4,400 mg/1 (8) Hazardous Substances Contingency Plan Chronic: Vapor Pressure at 20°C: (80) A moderate ingestive 96 min. (8) Pesticide residue and inhalation hazard, tolerance (80) and a slight skin Atmospheric Residence Time: Report able absorption hazard 1,160 days (45) quantities (89) from prolonged exposure. (3a) Detection in environmental DOT: media: ORM - A (54) A bacterial mutagen (29) Industrial Wastewater and N.J. : intakes: Toxic Volatile USEPA - 11% (78) Organic Substance NJDEP (OSR) - 6/28 (82) (81) Groundwater: NJDEP (OSR) - 21% (85) Potable Water, Raw and treated: NJDEP (OSR) - 51.7% (86) 122 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physicaj Stale_ _in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations _____ 1 ,1,2-Trichloro- 1975 - probably greater than Intermediate for vinylidene Acute: Aquatic Toxicity Rating: OSHA: ethane 1000 (43) chionde and tetrachloroethylene; irritant L(J_ Qy6: lOU-lUppm (/) Tl.V-TWA - lUppm 79-00- r> solvent for fats, oils, waxes, STEL - 20 ppm (7) Liquid N.J. Industrial Survey resins, alkaloids, polyesters, Chronic: Bioaccumulation: (1978-1979): and chlorinated rubber. (43) Long term exposure log octanol/water EPA: Priority Produced - 0 produces chronic partition coefficient Pol lutant Purchased - 1-5 x 10 (84) gastric symptoms, fat 2.17 (8) (8) deposition in kidney Hazardous and damage to the Solubility in water at 20°C: Waste (54) lung. (29) 4,500 mg/1 (8) National Oil & Hazardous Substances Suspected animal Vapor Pressure at 20°C: Contingency Plan carcinogen. (29) 19 mm (8) (80) Reportable Produced Atmospheric Residence Time: quantities (89) hepatocellular 35 days (45) carcinomas and DOT: adrenal Detection in environmental Hazardous Materials phaeochromocytomes Media: Table (80) in mice via oral route (29) Industrial Wastewaters and intakes USF.PA - 1.8% (78) NJDEP (OSR) - 1/28 (82) Groundwater NJDEP (OSR) - 2% (85) Potable water, raw and treated: NJDEP (OSR) - 1/498 (86) Ambient Air: NJDEP (OSR) - Tri chloroeLhanes are delec-Lrd in 35-70% of the samples. (H3) 123 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters _Regulations Trichlorofluoro- 1975 - 2.69 x 10 (43) Solvent; in fire extinguishers Acute: Bioaccumulation: OSHA methaiie as a chemical intermediate; May be narcotic in log octanol/water Air 75-69-4 N.J. Industrial Survey blowing agent (propellant) (6) high concentrations. Partition coefficient: TWA - lOOOppm (7) Liquid (1978-79): (6) 2.53 (8) Produced - 1-5 x lo'/yr EPA: Purchased 5-10 x 10 /yr Solubility in water at 20° Removed from (84) to 25°C: Priority List 1,100 mg/1 (8) January 8, 1981 Hazardous Waste (80) Vapor Pressure at 20°C: National Oil & 667.4 mm (8) Hazardous Substances Contingency Plan Detected in environmental (80) Media; Pesticide Residue Tolerance (80) Industrial wastewaters Rcportable and intakes: quantities (89) USEPA -6.2% (78) PDA: Potable water, raw Cosmetic labeling and finished: (80) NJDEP (OSR) - 7/496 (86) DOT: Ambient Air: Hazardous Materials NJDEP (OSR) - 100% (83) Table (80) 124 HALOGENATED ALKENES Substance Name (Synonym) Amount Produced Major CAS Number imported, Exported Commercial Health Environmental Phyjs i caj State in the U.S. (lbs./yr.)______Uses_____ Effects Parameters Regulations Allyl chloride 1973 - 300 x 10 As a monomer in the production Acute: Aquatic Toxicity Rating: OSHA: (l-chloro-2- Produced by 2 U.S. of thermosetting resins for Humans: LC5Q 100-10 ppm (2g) Air: TWA 1 ppm propene) companies (1) varnishes, plastics and adhesives; LC, -3000 ppm 107-05-1 in the synthesis of giycerol, Animals: Bioaccumulation: NIOSH Recomm.: N.J. Industrial Survey epichlorohydrin, allyl alcohol; inflammation of lungs probable (2g) CL 3 ppm (1978-1979): In the synthesis of swelling of kidneys, STEL 2 ppm (7) Produced - 0 pharmaceuticals. (2g) skin irritation (2g) Solubility in Water at 25°C: Purchased - 1-5 x 10"/yr. 3,000 ppm (2g) EPA: (84) Chronic: Hazardous Waste (80) An i ma 1s: Vapor Pressure at 20°C: Hazardous water Degenerative changes 294.3 mm (2g) pollutant designation in 1iver and kidney & harmful quantities (2g). Atmospheric Residence Time: (80) NCI bioassay on mice 0.3 days (44) Reportable quantities caused a low incidence (89) of neoplastic and non- neoplastic lesions of DOT: the forestomach (7a) (•'lammable (7) Cargo of particular Mutagen in bacteria hazard (80) (1) N. J. : Restricted Pesticide (81) 125 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ihs./yr.) Uses Effects Parameters Chloroprene 1976 - 3.62 x 10 8 Used almost exclusively, without Acute: Aquatic Toxicity: OSIIA: (2-chloro-t,2- by two plants (28) isolation, in the production Irritant. Toxic to LC5Q96-100-10 ppm (7) TLV-TWA ppm (7a) butadiene) located in Texas and of polychloroprene elastomers. man at 80 ppm (2d) 126-99-8 Louisiana (76j) (28) Solubility in Water: NIOSH Recomm.: Liquid Used as a component of adhesives Chronic: slighlty soluble (28) CL 1 ppm/15 min. (7 in food packaging. (28) Highly toxic with repeated ingestiori Vapor Pressure at 31.8°C: ACGI1I Recomm. : N.J. Industrial Survey or inhalation (2d) 300 mm (28) TWA 10 ppm (7a) (1978-1979): Produced - 0 Carcinogenesis assay Atmospheric residence Time: DOT: Purchase - 5 - 10 x 10 /yr results indefinite (28) 0.2 days (44) Flammable Liquid (84) (54) Mutagen in bacteria insects, arid in rats and mice (28) Embryotoxic in rats (28) Teratogenic in rats (28) 126 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Envi ronmental Physical Sta_Le__ in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations 1,2-Dichloroethy- No data available (43) Gene'ral solvent for organic Acute: Aquatic Toxicity Rating: OSHA: lene materials; dye extraction; Moderately toxic by LC 96:1000-100 ppm (7) TLV-TWA 200 ppm (7) 540-59-0 perfumes; lacquers; thermoplastics ingestion, inhalation Liquid organic synthesis. (6) and skin contact. (6) Bioaccumulation EPA: N.J. Industrial Survey TC (humans): log octanol/water Priority Pollutant (8) (1978-1979): 5800 mg/m /10 min. partition coefficient Hazardous Waste (54) Produced - 0 TXF: CNS. (7) 1.48 (8) National Oil & Purchased - 1 (84) Hazardous Substances Solubility in water at 20°C Contingency Plan (80) 600 mg/1 (8) Reportable quantities (89) Vapor Pressure at 14°C: 200 mm (8) DOT: Flammable liquid (54) Detected in environmental media: Industrial Effluents and intakes. USEPA - 7% (78) NJDEP (OSR) - 4/28 (82) Potable water, raw and treated: NJDEP (OSR) - 28/498 (86) Ambient Air N.IDEP (OSR) Dichloroethylenes were detected in 35-70% of samples. (83) 127 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phy. s_i_ca l__Sta te in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters 1,3-Dichloropropy- 1974 - 2.01 x 10 (43) Nematocide (43) Acute: Aquatic Toxicity: OSHA: lene Strong irritant (6) LC50 96:100-10 ppm (7) TLV-TWA 1 ppm 542-75-6 Rats LD5Q :250 mg/kg (7) STEL - 10 ppm (skin) . Liquid Bioa ccumulat ion: Chronic: log octanol/water EPA: N.J. Industrial Survey Liver and kidney partition coefficient: Priority Pollutant (8) (1978-1979): damage have been 1.98 (8) Hazardous Waste (54) Produced - 0 produced in experi Reportable quantities Purchased - 0 (84) mental animals. (5) Solubility in water at 25°C: (89) 2,700 mg/1 (cis) Hazardous water Bacterial mutagen (7) 2,800 mg/1 (trans) (8) pollutant designation (80) Vapor Pressure at 20°C: 25 mm (8) DOT: Flammable liquid (54) Detected in environmental media: NJDEP: Industrial Effluents and Restricted .Pesticide intakes. (81) USEPA - 1% (78) NJDEP (OSR) - 0/28 (82) Potable Water NJDEP (OSR) - 1/504 (86) Ambient Air NJDEP (OSR) Not Detected. (83) J28 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters _ Regu la tions______ Hexarhlorohlltadiene Amount used commercially Insecticide, herbicide, algi- Acute: Bioaccumulat i on: OSHA: 67-68-3 is imported from w. Germany cide (3); solvent for elastomers; Toxic to experimental Log octanoi/water TLV-TWA 20 ppm Liquid 2 to 5 x 10 (29) transformer and hydraulic fluid. animals by inhalation, partition coefficient is (skin) (7) (43) ingestion, injection 3.74 (8) Also produced as a or absorption through EPA: byproduct in production of skin; affects central Solubility in water at 20°C: Priority Pollutant (8) tetrachloroethylene, tri- Intermediate for fluorinated nervous system and 2 mg/1 (8) Hazardous Waste (54) chloroethylene, carbon tetra- lubricants and rubber compounds causes hepatic National Oil & chloride and chlorine (29) (A3); disorders Vapor Pressure at 20°C: Hazardous Substances Used for recovery of chlorine (29) 0.15 mm (8) Contingency Plan (80) N.J. Industrial Survey containing gases in chlorine (1978-1979) plants (29). Chronic: Detected in environmental DOT: Produced - 0 Produced benign and media: Use (X) on label (54) Purchased - 0 (84) malignant tumors in Industrial effluents kidneys of rats via and intakes: oral route (29) USEPA - 0.24% (78) Embryotoxic in rats Potable water, raw and (29) treated: NJDEP (OSR) - 0/245 (86) POTWs NJDEP (OSR) influents - 0/18 effluents - 0/18 sludge - 0/10 (88) 129 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmerita 1 PhysicaJ State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Hexachlorocyclo- 1977 - Probably greater As an intermediate for resins, Acute: Bioaccumulation: OSHA: pentadiene than 10 (43) dyes, pesticides, fungicides, Highly toxic by Log octanol/water TLV-TWA 10 ppb 77-47-4 pharmaceuticals (6). ingestion, inhalation partition coefficient: STEL - 30 ppb (7) 1iquid N.J. Industrial Survey and skin absorption. 3.99 (8) (1978-1979): LD_ n for rat (oral) Bioaccumulates in all EPA: Produced - 0 113" mg/kg (7) organisms (8) Priority Pollutant (8) Purchased - 0 (84) 0.805 mg/1 (8) Hazardous Waste (54) In animals caused Pesticide residue degenerative changes Solubility in water at 20°C: tolerance (80) in the brain, heart, 0.805 mg/1 (8) Hazardous water liver, adrenals, pollutant designat.ixsv necrosis of the liver Vapor Pressure at 25°C: (j harmful quantities edemia of the lungs. 0.081 mm (8) (80) (54) Reportable quantit Atmospheric Residence Time: (89) A powerful irritant 0.2 days (44) DOT: (54) Corrosive materials Detection in environmental (54) Chronic: media: Industrial wastewater and intakes: USEPA - 0.09% (78) Potable water, raw and treated: NJDEP (OSR) - 0/245 (86) POTWs: NJDEP (OSR) influents - 0/9 effluents - 0/9 sludge - 0/9 (88) 130 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phsica State in tbe U.S. (Ibs./yr.) Uses Effects Parameters Regulations^ Tetrachloroethy- 1976 - Production Dry cleaning, processing and Acute: Aquatic Toxicity Rating: OS HA: iene 67 x 10 by 9 U.S. finishing (56%); exported (1/%); Moderately toxic via LC 96:100-10 ppm (7) Tl.V-TWA - 100 ppm (Perchloroethylene) companies. solvent in metal cleaning (15%); inhalation, ingesLion CL-200 ppm (7) 127-18-4 - Imports intermediate in the synthesis of and skin absorption Bioaccumulation: Li qu i (i 5.1 x 10 (29) Freons (9%). (43) <2b). log octanol/water EPA: Humans: partition coefficient: Priority Pollutant (8) N.J. Industrial Survey TCLO:96 ppm/7 hr 2.88 (8) Hazardous Waste (54) (1978-1979): (inhal.) Pesticide residue Produced - 0 TC L0:600 ppm/10 min. Solubility in water at 20°C: tolerance (80) Purchased 1 - 5 x 10 /yr TXF: CNS (7) 150 to 200 mg/1 (8) Reportable quantities (84) (89) Chronic: Vapor Pressure at 20°C: Suspected animal 14 mm (8) DOT: carcinogen in mice ORM-A (54) (29) Detected in-environmental media: NJDEP: Mutagen in yeast (42) Industrial wastewaters Toxic Volatile and influents: Organic Substance USEPA - 9.9% (78) (81) NJDEP (OSR) - 4/28 (82) CPSC: Groundwater: Labeling (80) NJDEP (OSR) - 22.7% (85) Potable water, raw and NJDEP (OSR) - 67/499 (86) Ambient Air: NJDEP (OSR) - over 70% of samples. (7'i) 131 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses Effects Parameters ____ Regulations Trichloroethylene 1975 - 2.93 x 10 82% used for vapor degreasing Acute : Aquatic Toxicity Rating: OSHA: 79-01-6 produced ,. of fabricated metal parts, 15% Highly toxic by LC 96:10.00-100 ppm (7) TLV-TWA 50 ppm Liquid 1975 - 8.40 x 10 was exported, 3% for misc. uses inhalation. Moderately STEL - 150 ppm (7) imported which include use as a solvent in toxic via all other Bioaccumulation: 1975 - 3.40 x 10 X the textile industry, as a low- routes. Mild irritant. log octanol/water EPA: exported (43) temperature heat transfer fluid, partition coefficient Priority Pollutant and in commercial cleaning 2.29 (8) (80) fluids. (29) Chronic: Hazardous Waste (80) Carcinogenic in mice Solubility in water at 20°C: Hazardous water N.J. Industrial Survey via oral route 1,110 mg/1 (8) pollutant designation (1979-1979) producing liver and & harmful quantities Produced - 0 lung tumors (42) Vapor Pressure at 20°C: (80) Purchase - 5 x 106/yr 57.9 mm (8) (84) Mutagenic in DOT: bacteria, yeast (42) Atmospheric Residence Time: OKM-A (54) 5.2 days (44) PDA : Detected in environmental Prohibits use in media: food, drugs, and Industrial Wastewater cosmetics (6) and intakes: USEPA - 9.9% (78) N.J. : NJDEP (OSR) - 7/28 (82) Toxic Volatile Organic Substance Groundwater: (81) NJDEP (OSR) - 26.4% (85) Potable water, raw and treated: NJDEP (OSR) - 95/499 (86) Ambient Air: NJUEP (OSR) - in over 70% of samples. (8'j) POTWs NJDEP (OSR) influents - 15/18 effluents - 14/18 (88) 132 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Pliys_i_ca_l_Stat_e ______ULJ-1?? Ji-Jl:_Qbs./yr. )______Uses______5.?JL^£t5______Parameters______Regulations Vinyl bromide 1975 - Produced by 2 U.S. It is a reactive fire retardant Acute: Soluble: OSHA: (Bromocthylene) companies in unknwon amounts used as a comonomer with Moderately toxic via Insoluble (64b) TLV-TWA 5 ppm (7a) 593-60-2 (28) acrylonitrile and other vinyl oral route: Highly monomers in modacrylic fibers. toxic via inhalation Vapor Pressure at 20°C: DOT: N.J. Industrial Survey (28) route. (3b) 1033 mm (64b) Flammable gas (54) (1978-1979): Produced - 0 Chronic: Purchased - less than Mutagen in 1000/yr. (84) bacteria (28) 133 ( Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Re g Vinyl Chloride Annual production is Used in the production of Acute: Aquatic Toxicity Rating: OSIIA : 75-01-4 approximately 7 x 10 plastics and in the synthesis Highly irritating via IX 96: over 1000 ppm (7) Air Gas of other chemicals. Vinyl inhalation and oral TWA - 1 ppm Production of vinyl chloride chloride - acetate copolymer routes. (2c) Bioaccumulation: CL - 5 ppm/15 min. homopolymer is reported is used in the production of vinyl log octanol/water (7a) at 5 x 10 asbestos floor tiles. (9) Chronic: partition coefficient Causes liver damage in 0.60 (8) EPA: Imports of vinyl chloride animals; causes Priority Pollutant (8) homopolymer are 55 x 10 circulatory and bone Solubility in water: Hazardous Waste (9) changes in man. 60 mg/1 (at 10°C) Emissions standards Production of vinyl chloride (2c) 1.1 mg/ ] (at 25°C) (8) (80) acetate copolymer is reported Reportable quantities to be 279 x 10 (9) A human carcinogen Vapor Pressure at 25°C: (89) affecting the liver, 2,660 mm (8) N.J. Industrial Survey brain, lung and DOT: (1978-1979): hemopoietic systems. Atmospheric Residence Time: Flammable gas. (7) Produced - 0 (28) 1.8 days (45) Purchased - 5 x 10 /yr. FDA: (84) An animal carcinogen Detected in "environmental Banned use as a (28, 42) media: propellant in Industrial wastewaters aerosols. (9) Mutagen in bacteria, and intakes: Cosmetics (80) yeast, drosophila, USF.PA - 0.31% (78) and in mammalian cell NJDEP (OSR) - 2/28 (82) CPSC: assays (42) Banned use in Potable water, raw and aerosols for house Treated: hold products (9) NJDEP (OSR) - 1/496 (86) NJDKP: Ambient Air: Toxic volatile NJDEP (OSR) - organic substances trace amounts found (81) in 35-70% of samples. (83) 134 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Env i rontnent a 1 Physica_l Stale__ _in_ Uie^U.S. (Ibs./yr.) Uses Effects Parameters Regula tions _ Vinyl idene In 1976 two U.S. companies Major use is in the production Acute: Aquatic Toxicity Rating: OSHA: chloride produced a comDinea total ot ot copojymers; some is used in Moderately toxic via LU__y6:1UUU-1UO ppm (/) TLV-TWA 10 ppm (1,1-Dichloroethy- 1.54 x 10 ; one of these the"-- production----"•-«-•• — of modacrylic inhalation or by STEL - 20 ppm (7) lene) companies produced an fibers; Is an intermediate in absorption. (3f) Bioaccumulation: 75-35-4 additional 1.1 x 10 as an the production of 1,1,1-tri- log octanol/water EPA: liquid unisojated intermediate. (28) chloroethylene. (28) Chronic: partition coefficient Priority Pollutant (8) Limited evidence 1.48 (8) Reportable N.J. Industrial Survey of carcinogencity quantities (89) (1978-1979): (42) Solubility in water at 20°C: Hazardous Waste (54) Produced - 0 400 mg/1 (8) Purchased - less than Mutagen to bacteria 1,000/yr. (84) mammalian cells (42) Vapor Pressure at 25°C: Hazardous water 591 mm (8) pollutant designation & harmful quantities Atmospheric Residence Time: (80) 2.9 days (44) DOT: Detected in environmental Flammable liquid (54) media: Industrial wastewaters NJDEP: arid intakes: Toxic Volatile USEPA - 6.7% (78) organic substance NJDEP (OSR) - 5/28 (82) (81) Potable water, raw and PDA: treated: Food-contact NJDEP (OSR) - 8/496 (86) component (80) Ambient Air: NJDEP (OSR) - in over 70% of samples. (83) 135 HAi,o<;i:NATi;n AROMATICS Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phy s i^eaj^ J>M te_ __in_JLhe U.S. (Ibs./yr.)______Uses_____ Effects Parameters __ 5?gulations Benzal Chloride 1977 - Production 2-20 x 10 Used almost exclusively for the Acute: Solubility in water: EPA: (Dichloromethyl by two companies manufacture of benzaldehyde, which Vapors are Insoluble (38) Hazardous Waste (54) benzene) is used in perfumes, flavors, dyes irritating to the Reportable 98-87-3 Presently only one U.S. and pharmaceuticals. It can also be eyes (43) Persistence in water: quanitites (89) company is believed to used to prepare cinnamic acid and Also irritating Hydrolyzes to benzaldehyde produce commercial benzoyl chloride. However, cinnamic to the skin (54) and HC1 on contract with DOT: quantities of this acid was not commercially produced in Rats: water (38) Hazardous Waste (54) compound. (38) U.S. as of 1982. (38,54) LD :3249 mg/kg {oral) (7) Vapor Pressure at 123.6°C: 1971 - Imports LC :400 mg/kg/2 60 mm (38) 1 x 10 (38) fir. (38). (in(inhal.) Chronic: Limited evidence of carcinogenicity in mice (38) . Limited evidence that employment in the production of benzal chloride (including exposure to benzyal chloride) represents a carcinogenic risk (38) Mutagenic in Bacteria (38) 136 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Benzolrichloride Annual U.S. Production is Over 99% is used to produce benzoyl Acute: Solubility in water: EPA: (t r i ch1o romet hyI believed to be ft x 10 (3B) chloride. Less than 1% is used in the Vapors are highly Insoluble Hazardous Waste (b4) benzene) systhesis of dyes - basic green 4, irritating to skin Reportable 1980 - Imports , solvent green 1, pigement green 4, and mucous Persistence in water: quantities (89) (alpha, alpha, 2.6 x 10 (38) and vat yellow 2. (43) It is also membranes (43) Decomposes in water to alpha - produce hydrohenzophenone, a stabilizer give benzoic acid and HC1 DOT: trichlorotoluene) in a variety of plastics. (38) Chronic: (43) Corrosive material 98-07-7 A carcinogen in (54) Liquid mice in three Vapor pressure at 130°C: studies (38) 60 mm (38) Mutagen in bacteria (43) 137 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental ?Jlv.5i5jL! State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ____Reguljrti ons Benzyl Bromide 1975 - Production greater Used as a chemical intermediate. Acute: Aquatic Toxicity: DOT: (alpha-bromo- than 2,000 Ibs. (43) Used in the manufacture of framing Intense irritant Acutely toxic to fish (3c) Corrosive toluene) and frothing agents. (43) to skin, eyes, Material: (54) 100-39-0 Tear gas (3c). and mucous Solubility in water: Li quid membranes (3c) Insoluble. (43) Large does pdouce CNS Persistence in water: depression (3c). moderate - hydrolyzes When heated it with time producing highly emits highly toxic HBr. (3c). toxic fums - HBr. (43). Chronic: A mutagen in bacteria. (7) 138 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations Benzyl Chloride 1975 - Production In 1978, 62% was used in thehe Acute: Aquatic Toxicity Rating: OSHA: laipha-cnioroniethyi 7.01 x 10 (43) production of benzyl Benzene) 11% in the production of benzylenzyl to the eyes and TWA 1 ppm (7) 100-44-7 1979 - Imports , alcohol; 10% in the' productiontion of respiratory Solubility in water: Liquid 3.97 x 10 (38) benzyl quaternary ammoniumi salts;salts ; tract. Large Insoluble (38) EPA : 8% in the synthesis of doses cause CNS Hazardous Waste (5 pharmaceuticals. (38) depression. (5) Persistent in water: Reportable Hydrolyzes (3b) quanitities (89) Chronic: Hazardous water Limited evidence Vapor pressure at 100.5°C: pollutant designa that it is an 60 mm (38). tion & harmful animal carcinogen quantities (80) (38) Limited evidence DOT: that is a human Corrosive Material carcinogen. (38) (54) Mutagen in bacteria, yeast, and mammalian cells (42) 139 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Chlorohenzene 1976 - Produced 49% for pesticide and degreasing 8 Acute: Aquatic Toxicity Rating: OSHA: 108-90-7 3.29 x 10 (1) operations; 30% as intermediate for Animals: LC5Q96:100-1 ppm (7) Air: TWA 75 ppm (7) Li quid production of chloronitrohenzenes Rat I-Dg 0 : 2910 1975 - Imported , (in dye and pesticide intermediates); mg/kg (oral) (7) Bioaccumulation: EPA: 8.37 x 10 (1) 8% as an intermediate for dipenyloxide Log octanol/water Priority Pollutant synthesis; 7% as an intermediate for Chronic: partition coefficient: (8) N.J. Industrial Survey DOT production; 6% other uses. (1) Animals: Causes 2.84 (8) Hazardous Waste (54) (1978-79): 4 damage to the Reportable Produced - 1-5 x 10 /yr hemopoietic Solubility in water at 25°C: quantities (89). Purchased - 5-10 x 10 /yr system including 488 ppm (3d) Pesticides residue (84) destruction of tolerance (80) lymphocytes and Vapor pressure at 22°C: Hazardous water depression of 10 mm (3d) pollutant designa the bone marrow. tion & harmful Also produced Atmospheric residence time: quanitities (80) fatty liver 28 days (4) degeneration. (3d) FDA: Detection in environmental Food contact media: components (80) Industrial wastewaters and intakes: USEPA - 4.6% (78) NJDEP (OSR) - 4/27 (82) Potable water, raw and treated: NJDEP (OSR) - 4/489 (86) Ambient air: NJDEP (OSR) - found in over 70% of samples. (83) 110 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations 2-Ch 1 oronaphtha- Not produced commercially Solvent (6) Acute : Bioaccumulation: EPA: lene in the U.S. (43) Animals : Log octano] /water Priority Pollutants 91-58-7 Rat LD :2078 partition coefficient: (8) N.J. Industrial Survey mg/kg (oral) 4.12 (8) Hazardous waste (54) (1978-79): Mouse LD :886 Reportable Produced - 0 mg/kg {oral) (7a) Solubility in water at 25°C: quantities (89) Purchased - 0 (84) 6.74 mg/1 (calc.) (8) DOT: Vapor Pressure: Hazardous materials 0.017 mni at 20°C (calc.) table (80) (8) 141 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental in the U.S. (Ibs./yr. )______tJsej,_____ Effects Parameters 1,2-Dichloroben- 1979 - Produced 70% of organic synthesis (mainly Acute: Bioaccumulation: OS HA: zene - 5.73 x 10' for the production of 3 ,4-dichloro- Rat-LD _:500 Log octanol/water Air: CL 50 ppm (7) (o-dichlorobenzene) aniline; 15% as solvent for toluene mg/kg foral) partition coefficient: 95-50-1 - Imports 2014 (38) diisocyanate production; 8% for misc. LD :821 ppm/7Hr. 3.38 (8) EPA: Liquid solvent uses; 4% for dye manufacture; (inhalation) (7a) Priority Pollutant N.J. Industrial Survey 3% for other applications (38) Solubility in water, at 25°C: (8) (1978-79): 145 mg/1 (8) Hazardous Waste (54) Produced - 0 Reportable Purchased - 1-5 x 10 /yr. Vapor pressure at 25°C: quantities (89) (84) 1.5 mm (8) Hazardous water pollutant designa Atmospheric residence time: tion (80) 39 days (44) DOT: Detection in environmental ORM - A (54) media: Industrial wastewater and intakes: USEPA - 5.4% for all DCBs (78) NJDEP (OSR) - 6/31 (82) Groundwater: NJDEP (OSR) - 4.8% for all DCBs (85) Potable water, raw and treated: NJDEP (OSR) - 4/245 (86) POTWS NJDEP (OSR) influents - 6/18 effluents - 6/18 (88) 142 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phyj; ic al State_ in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters 1,3-Dichloroben- N.J. Industrial Survey Present as a byproduct in technical Bioaccumulation: EPA: zene grade i ,2-dichlorobenzene (17%) arid Log octanol/water Priority pollutant (m-dichloroberi- Produced - 0 1,4-dichlorobenzene (0.1%) (43) partition coefficient: (8) zene) Purchased - 1,000-5,000 3.38 (8) Hazardous Waste (54) 541-73-1 (as a byproduct) (84) Reportable Liquid Solubility in water at 25°C: quantities (89) 123 mg/1 (8) DOT: Vapor Pressure at 25°C: ORM - A (54) 2.28 mm (8) Dectection in environmental media: Industrial wastewaters and intakes: NJDEP (OSR) - 1/31 (82) Potable water, raw and treated: NJDEP (OSR) - 0/245 (86) POTWS NJDEP (OSR) influents - 3/18 effluents - 1/18 sludge - 0/9 (88) 143 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. Qbs./yr.)______Uses____ Effects Parameters ____Regulations 1,4-Dichloroben- 1979 - Production 8.36 x 10 55% as a space deodorant; 35% for moth Acute: Bioaccumulation: OSHA: zene (38) control; 10% for other applications Animals: Log octano.l/water TLV-TWA 75 ppm (p-dichlorobenzen) (38) Rats: LD"50r :50 partition coefficient: STEL HO ppm (7) 106-46-7 1978 - Imports 2.40 x 10 4 Used for chemical intermediate for mg/kg 3.39 (8) Sftblimable (38) for dyes (2,5-dichloroaniline), Humans EPA: crystals N.J. Industrial Survey insectidices, pharmaceuticals, resins TO -.30 mg/kg Solubility in water at 25°C: Priority Pollutant (1978-79): (polyphenylene sulphide resins), and TXT: SYS effects 79 mg/1 (7) (8) Produced - 0 and other organic chemicals (38) (7a) Hazardous Waste (54) Purchased - 1-5 x 10 (84) Vapor pressure at 20°C: National Oil & 0.6 mm (8) Hazardous Substances Contingency Plan Atmospheric residence time: (80) 39 days (44) Reportable quantities (89) Detection in environmental Hazardous water media: pollutant designa Industrial wastewaters and tion (80) intakes: USEPA - 5.4% for all DOT: DCBs (78) ORM - A (36) NJDEP (OSR) - 3/31 (82) Groundwater: NJDEP (OSR) - 4.8% for all DCBs (85) Potable water, raw and treated: NJDEP (OSR) - 0/245 (86) POTWS NJDEP (OSR) influents - 7/18 effluents - 4/18 (88) 144 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters __Regulations______ Hexach 1 orobenzene Commercial production in As a preemergents fungicide applied Acute: Bioaccumulation: EPA: . 1 - t r r \ Priority Pollutant Crystals 1976. (55) mg/kg (unknown) partition coefficient: (8) An additive for polymers and a (7a) 6.18 (8) Hazardous Waste (80) Occurs as a byproduct in raw material for synthetic rubber (29) Reportable petrochemical industry Chronic: Solubility in water at 25°C: quanitities (89) waste and as a contaminant Carcinogenic in 6 ug/1 (8) National Oil & in pesticides. (29) mice and hamsters. Hazardous Substances (29) Vapor pressure at 20°C: Contingency Plan N.J. Industrial Survey 1.09 x 10 " mm (8) (80) (1978-79): , Embryotoxic (29) Produced - 1-5 x 10 /yr Detected in environmental DOT: as by product media: Hazardous waste Purchased - 0 (84) Industrial wastewates and table (80) intakes: USEPA - 0.89% (78) Potable water, raw and treated: N.JDKP (OSR) - 0/244 (86) POTWS NJDEP (OSR) influents - 0/9 effluents - 0/9 sludge - 0/9 (88) 145 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental £ in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _Regu_l at i ons_ 1,2,3-Trichloro- 1979 - Production estimated Chemical intermediate in the synthesis Acute: Solubility in water: benzene to be between of such chemicals as 2,3-dichloro- Moderately Insoluble (43) 87-61-6 1-10 x 10 phenol; A constituent of trichloro- toxicity via Solid benzene mixture used for termite ingestion and 1979 - Imports of both control; a constituent of trichloro- inhalation (6) l,2,3-and,l,2,4- were benzene mixture used as a transformer 3.09 x 10 (43) fluid; and a dye carrier and solvent. (43) 146 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulat ions 1,2,4-Trichloro- 1973 - Production As an intermediate in industrial Acute: Aquatic toxicity rating: ACGIH Recomm. benzene 2.82 x 10' synthesis, as a solvent, insecticide Animals : LD5096:10-1 ppm (7) TWA : 5 ppm (7) 120-82-1 dielectric fluid and heat transfer Rats LD__756: Liquid 1975 - Imports , medium (1) mg/kg (oral) (7a) Bioaccumulation: EPA: 1.94 x 10 (43) Mice: LD fl :300 Log octanol/water Priority Pollutant mg/kg (oral) (7a) partition coefficient: (8) N.J. Industrial Survey 4.26 (8) Hazardous waste (80) (1978-79): Reportable Produced - 0 , Solubility in water at 25°C: quanitities (89) Purchased - 1-5 x 10 (84) 30 mg/1 (8) DOT: Vapor pressure at 25°C: Should have (x) on 0.42 mm (calc.) (8) label (54) Detected in environmental media: Industrial waterwaters and intakes: USEPA - 0.92% (78) NJDEP (OSR) - 2/31 (82) Potable water, raw and treated: NJDEP (OSR) - 0/245 (86) Ambient air: NJDEP (OSR) - all TCBs were detected infrequently (83) POTWS NJDEP (OSR) influents - 6/18 effluents - 3/18 sludge - 2/10 (88) 147 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phy s _ica1 State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations Polybrominated The sole U.S. producer of Hexabromobiphenyl was used as a fire Chronic: Solubility in water: biphenyl (PBB) hexabromobiphenyl ceased retardant in 1) acrylonitrile-buta- Animals: May Hexa - :11 ug/kg production in November, 1974 diene-styrene plastics; 2) coatings interfere with Octa-:20-30 ug/kg (27) (Hexabromobiphenyl (27) and lacquers; and 3) polyurethane reproduction and pure) Two companies produced octa- foams (27) liver functions Vapor pressure: 36355-01-8 and/or decabromobiphenyl promote nervous Hexa-:7.6-10 mm at 90°C: up to 1976 when production d i sorders. (27) (Hexabromobiphenyl ceased (27) Reacts as a technical) teratogenic Persistent (27) (Firemaster BP-6) N.J. Industrial Survey agent. (27) 59536-65-1 (1978-79): Produced - 0 (Octabromobiphenyl) Purchase - 0 27858-07-7 Max Inventory - 0 (84) (Decabromobiphenyl) 13654-09-6 148 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Polychlorinated No commercial production Before 1972, PCBs were used in Acute: Bioaccumulation: OSHA: Biphenyls in U.S. (9) transformer cooling liquids, heat Humans: an Log octanol/water i'KL: 1 mg/'m (PCBs, Aroclors, transfer and hydraulic fluids, vacuum irritant via partition coefficient: 8 hr. TWA (42% 3 Kanechors) No import or export has pump fluids, lubricants plasticizers, inhalation, can 2.8-7.1 (8) chlorine); 0.5 mg/m 1336-36-3 been permitted since July, fillers in investment coating waxes, cause severe 8 hr. TWA (54% oil to white solid 1979 (9) surface coatings and sealants, liver damage Solubility in water: chlorine) (9) pesticide extenders and for copy causes chloro- 0.003-15 mg/1 (8) N.J. Industrial Survey systems. By 1974, all domestic uses acne. (27) EPA: (1978-79): of PCBs were confined to closed Vapor pressure at 25°C: Ban on manufacture Produced - 0 , systems (9) Chronic: 4 x 10 to 8 x 10 mm (8) processing and dis Purchased - 1-5 x 10 Teratogenic in tribution in Maximum Inventory - the monkey (2c). Detection in environmental commerce (9) 1-5 x 10 (84) Carcinogenic in media: Priority Pollutant mice and rats Industrial wastewaters and (8) (42) intakes: Ban as active or USEPA - 0.7% (78) inert ingredient in Embryotoxic in Groundwater: pesticides (9) animals (27) NJDEP (OSR) - 2 to 7% Hazardous Material (82) (54) Potable water, raw and Hazardous Waste treated: constituent (54) NJDEP (OSR) - 14/494 (86) FDA: POTWS Food contact NJDEP (OSR) component (80) influents - 2/9 effluents - 2/9 DOT: sludge - 2/10 (88) ORM - E (54) Biota NJDEP (OSR) NJDEP: Finfish - 75% Hazardous Waste (81) Shellfish - 50% (87) 149 ( Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmenta1 Physical J5tate_ in the U.S. (Ibs./yr.)______Uses______Effects Parameters _ __Regulations Polychlorinated Produced by one plant Triphenyls (PCTs) in the U.S. up to 1971 (1) (Aroclor 5442) 12642-23-8 K.J. Industrial Survey (1978-79): (Aroclor 6090) Produced - 0 Purchased - 0 (84) 150 HYDRAZINES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations 1,1 -Dimethyl Believed that current Major use is as a storable, high Acute : Solubility in water: OSHA: Hydra zine production is less than energy propellant for liquid- Eye and skin irritant Miscible (13) Air 57-14-7 1 .1 x 10 (13) fuelled rockets. Also used in (54) TWA Img/m (skin) Liquid the manufacture of Rats Vapor pressure at 22°C: (7a) N-dimethylaminosuccinamic acid, LC5() :252 ppm/4 hr. 10 mm (43) a plant growth regulator. A final Mice ACGIH Recommendation: significant use is in the LC : 172 ppm/4 hr. TLV-TWA 500 ppb manufacture of aminimides (13) linhalation) (7a) Suspected carcinogen STKL Ippm (skin) Chronic: (7a) Carcinogenic in mice (13) EPA: Hazardous Waste (80) Mutagen in host- Reportable quantities medicated assay. (7a) (89) Mutagen in mammalian DOT: cells, bacteria and Hazardous materials yeast. (7a) table (80) 151 ( Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phyj;ica 1. S_tate in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters __Regulations 1,2-Dimethyl- Manufactured in laboratory No known commercial uses. It Acute: Solubility in water: EPA: hydrazine quantities only. (13) has been evaluated experimentally Rat Miscible in water (13) Hazardous waste (80) 540-73-8 as a high-energy rocket fuel (13) LD :100mg/kg (oral) Reportable quantities Liquid LC^":280 ppm/4 hr. Vapor pressure 28°C: (89) 100 mm (13) DOT: Chronic: Hazardous materials Carcinogenic in mice, table (80) rats and hampsters via oral and subcutaneous routes. (13) Mutagen in bacteria (7) 152 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters ___ Regulations 1,2-Diphenyl- There are seven producers A chemical intermediate. Acute: Bioaccumulation: EPA: hydrazine and importers ot this Major use is as a starting Rat log octanol/water Priority Pollutant (Hydrazohenzene) chemical. (9) material in the manufacture of LD_:301mg/kg (oral) partition coefficient: (54) 122-66-7 benzidine for use in dyes. (3e) (43f 3.03 (8) Hazardous Waste (54) Produced - 3.73 x 105 /yr. (9) Also used in the synthesis of Rpportable quantities Imports - 1.35 x 10 /yr. (9) phenylbutazone which is a drug Chronic: (89) used for rheumatoid arthritis NCI carcinogenesis Addition unknown amounts are (43) bioassay - Positive DOT: produced on site at dye for mice and rats (7) Hazardous materials manufacturing facilities. (9) table (80) 153 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations Hydrazine 1966 - Production capacity Used as a rocket fuel, in the Acute: Solubility in water: OSHA: 302-01-2 2.21 x 10' (13) synthesis of organic chemicals, A very powerful acute Miscible (13) Air Liquid in the synthesis of plastics. poison, a systemic TWA 1 ppm (skin) (7) °H 0 N.J. Industrial Survey The hydrate is used as a reducing poison and a powerful Vapor pressure at 20°C: T0034-93-2 (1978-79): agent and inorganic solvent (5) irritant. It may 10.4 mm (13) NIOSH Recommendation: °H SO Produced - 100 The sulfate is also used as a cause skin sensitiza- TLV-TWA lOOppb T0034-93-2 Purchased - 1-5 x 10 (84) fungicide and germicide. (2a) tion, may cause damage Persistence: (skin) (54) In 1966, 70% for rocket fuel, 7% to liver and destruc Low, it is rapidly oxidized in the manufacture of maleic tion of red blood (2a) EPA: hydrazine, 5.7% in the manufacture cells (2a) Hazardous Waste (54) of azobisformamide blowing agent, Rat Bioaccumulation: Reportable quantities 2.9% in boiler water treatment, LD :129mg/hg (oral) Negative (2a) (89) (71° 2.9% in synthesis of amitrol (13) LC :570 ppm/4 hr. DOT: (inhalation) (7) Flammable liquid and Poison (54) Chronic: Sufficient evidence of carcinogenicity in animals (42) Mutagen in bacteria and fungi (42) Considered a reproductive hazard in the workplace (2a) 154 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters __Regul 2t*2 Methylhydrazine 1977 - Production 105 -10 Used in missile propellants, as Acute: Solubility in water: OSHA: 60-34-4 (43) a chemical intermediate, and as Vapors are very toxic Soluble (3e) Air Liquid a solvent (43) attacking eyes and CL 250ug/m (skin) respiratory system.,, > Vapor pressure at 25°C: (7a) Rats ( 6) 49.6 mm (3e) LD :33mg/kg (oral) ACGIH Recommendation: LC":74 ppm/4 hr. TLV-CL 200 ppb (inhalation) (7) (skin) Suspected carcinogen Chronic: (7a) Carcinogenic in hamsters via oral NIOSH Recommendation: route (43) Air CL 0.08 mg/ni /2 hr. Mutagen in vitro in (7a) bacteria and mammalian cells. EPA: (7, 43) Hazardous waste (80) Reportable Positive in dominant quantities (89) lethal assay in rats. (43) DOT: Teratogen in toads. Flammable liquid (43) and poison (54) Mutated sperm in mice (43) 155 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State_____in the U.S. (Ibs./yr.)______Uses______Effects______Parameters______Regulations Scmicarbazide In 1974, one manufacturer Used as a reagent in the Acute: Solubility in water: (hyUr.-izine reported production (21) determination of aldehydes and Produces convulsions Soluble (21) carboxamiile) ketones and in the isolation of (21) 57-56-7 hormones and certain fractions °HCL from essential oils. (21) Chronic: 563-41-7 Carcinogen in mice via oral route (21). Mutagen in bacteria, mammalian cells and insects (7) 156 IMINES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations__ ___ Ethy leneimine One U.S. producers, About 50% Acute: Solubility in water: OSHA: 151-56-4 estimated, production is polyethyle Strongly irritating Miscible (18) Carcinogen Liquid 2.87 x 10 (1) an adhesio omoter in coating to eyes, skin, and Air: „ applications; the remainder is mucous membranes (5) Vapor Pressure at 20°C: TWA 1 mg/m (skin) N.J. Industrial Survey used as a chemical intermediate Can be an allergic 160 mm (18) (7a) (1978-1979): in drug, cosmetic, and dye sensitizer of skin Produced - 0 manufacture; in the production (2b) ACGIH Recommendation: Purchased - 0 of N-2-hydroxyethyleneimine and Rat TWA 500 ug/m (skin) Max. Inventory - less of triethylenemelamine; and as LD :15 mg/kg (oral) (7) than 1000 (84) an intermediate and monmer for LD^:25 ppm/8 hr. EPA: oil additive compounds; ion (inhalation) (7a) Hazardous Waste (36) exchange resins; coating resins; Reportable quantities adhesives, polymer stabilizers Chronic: (89) and surfactants (18) Carcinogenic in mice by several routes of DOT: exposure (18, 42) Flammable liquid and poison (54) Mutagen in bacteria, plants, insects, N . J. : mammalian cells (42) Toxic volatile organic substance Positive in cell (81) transformation assay (42) Active as an initator of carcinogenesis in skin (42) Positive in host- mediated assay (42) 157 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical_State_ in the U.S. (Ibs./yr.)______Uses______Effects______Parameters______Regulations Propyleneimine 1972 - Production - at Chemical intermediate in Acute: Solubility in water: OSHA: 75-55-8 least 1,000. (43) modification of latex surface Miscible (18) TLV-TWA 2 ppm (skin) Liquid coating resins and textile (7) N.J. Industrial Survey industry; chemical intermediate Vapor Pressuare at 20°C: (1978-1979): in modification of polymers in 112 mm (18) EPA: Produced - 0 paper industry, dyes; chemical Chronic Hazardous waste (80) Purchased - 0 intermediate in photography, Carcinogenic in rats Reportable quantities Max. Inventory - 0 (84) gelatins (43) via oral route (18) (89) Mutagen in mammalian DOT: cells (7) Flammable liquid (54) Positive in cell transformation assay (7) Positive in host- mediated assay (7) 158 INORGANICS Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physics! State in the U.S. Hbs./vr.) Uses Effects Parameters Antimony N.J. Industrial Survey Widely used in the production of Acute: Aquatic Toxicity Rating: OS HA: (Sb) (1978-1979): , alloys. Used as abrasives, Primary skin irritant LC 96:100-10 ppm for TWA 500 ug/m 7440-36-0 Purchased - 5-10 x 10 of pigments, flameproofing compounds, (Sb and compounds.) 0 (2h) expressed as Sb antimony and salts. (84) plasticizers, and as a catalyst (54) except for SbH_ Salts: in organic synthesis. Also used Dust and fumes are Bioaccumulation: which has a TWS 100 SbH in the manufacture of tartar irritants to eyes, Bioconcentraiton factor ug/m (54) SbBr emetic, paints, lacquers, glass, nose, and throat, (54) 40 for freshwater and SbCK pottery, enamels, glazes, Sb2°3 causes a marine fish; 16,000 for ACGIH Recommendation: SbF pharmaceuticals, pyrotechnics, dermatitis called freshwater and marine Sb 0 processing Sb 6 matches, and explosives. Also "antimony salts". (54) invertebrates (8) is a suspected SbV used in dyeing, for blueing Rats: carcinogen (54) Sbci;: steel, and in coloring aluminum, LD:0.1-3.25 gm/kg Detection in Environmental Sb ° pewter, and zinc. (54) (intraperitonial) Media: EPA: SbH is a highly Industrial wastewaters Priority Pollutant toxic gas (64a) and intakes (54) USEPA - 18% (78) Reportable quantities Chronic: SbCl , SbKC.H.O Sb 0 is a suspected SbCH, SbBr!*, SbF , human carcinogen (64a) and Sb203 - {89) Hazardous Waste SbKC.H.O, is not rnnst iIuent (54) k 4 7 . carcinogenic in mice (64a) DOT: Poison - Use (X) on Evidence that female label. (54) workers in processing Forbidden transport plants had late, (80) spontaneous abortions and premature births (64a) FDA: Poison (80) 159 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Erivi ronmental Physical State hi the U.S. (Ibs./yr.)__ Uses Effects Parameters Regu 1 at i ons Arsenic Production - Arsenic and its compounds are Acute: Aquatic Toxicity Hating: OSIIA: (As) 70 x 10 /yr. of arsenic used in pesticides, glass, Trivalent arsenic LC 96: 10-1 ppm for Air „ 7440-38-2 and its inorganic ceramics, paints, dyes, and the compounds are As 0 AsBr , As 0 TWA 500 ug/m for compounds. (9) preservation of hides. (9) corrosive to skin LC 96:100-10 ppm tor organic As X54) Salts: (54) H^AsO Ca (AsO ) TWA 10 ug/m for AsH Imports - 13.5 x 10 /yr As 0 and As 0 (2,3,3,5) Na 3As04 , , inorganic As (54) primarily as As_0 (9) produce skin ' As 0 sensitization and Bioaccumulation: N10SH Recommendation: A V contact dermatitis Limited for aquatic life. 01 2 ug/m /15 min. AS 2°5 N.J. Industrial Survey (54) Cumulative poison in (54) (1978-1979): Rodents: mammals (3c) Produced - 0 , !D, n 10 mg/kg (oral) ACG1H Recommendation: Purchased - 1-5 x 10 TAs(Iil)) Persistence: TWA 200 mg/m for As (As and salts) (84) LD :100 mg/kg May recycle due to and soluble As salts. toral) (As(IV)) methylation of arsenic (3c) Listed As«0 (32) production as suspected carcinogen Chronic : (7a) Sufficient evidence that inorganic EPA: arsenic compounds Priority Pollutant are carcinogens for (8) skin and lungs in Reportable quantities humans (39) As S As 0 Asfil^, As^ (89) Hazardous Waste Caused chromosome constituent (54) aberrations in RPAR has been issued humans. (39) for cacodylic acid, Ca (AsO ) DSMA, Some evidence that PbHAsO HSMA, and exposure causes blood Na AsO (54) dyscrasias and liver Pesticide labeling tumors (39) (80) Pesticide residue tolerance (80) DOT: Poison B (54) FDA: Bottled water standards (80) Poison (80) Residue tolerances (80) 160 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Physical Stale _!I! the U.S. (Ibs./yr.) Uses Effects Parameters___ Re g u 1 a t iuii s__ Asbestos 1979 - Production Used in over 5,000 products, Acute: Persistence: OSIIA: 1332-21-4 2 x 10 (9) such as roofing, thermal and It is mineralogically Air: Solid 1975 - Imports electrical insulation, cement, stable and not prone lo TWA 2 fibers/cc 1.1 x 10 pipe and sheet, flooring, significant chemical or CL 10 fibers/cc (7a) - Exports gaskets, friction materials, biological degradation in 7.3 x 108 (43) coatings, plastics, textiles, the aquatic environment. ACGIH Recommendation: and paper products (9) Chronic: (8) TLV-TWA 0.2 N.J. Industrial Survey Chronic exposure can fibers/cc (7a) (1978-1979): lead to asbestosis (64a) Produced - 0 EPA: Purchased - 1-5 x 10' (84) Sufficient evidence Priority Pollutant that it is a human and (8) animal carcinogen (42) Hazardous Waste (54) Commercial industrial uses (8Q) Manufacturing (80) National emission standards (80) Keportable quantities (89) DOT: ORM-C (54)' FDA: Food-contact component (80) CPSC: Respirable free- form (80) 161 Substance Name (Synonym) Amount Produced Major CAS Number imported, Exported Commercial Hea1th Envi ronmental Physical Slate Uses Effects Parameters Humiliations Barium 1973 - Production Metallic barium is used for Acute: OS11A: (Ba) 2.2 x 10 removal of residual gas in Alkaline barium Air: 7440-39-3 - Imports vacuum tubes and in alloys with compounds, such TWA 0.5 rog/m for Salts 1.4 x 10y nickel, lead, calcium, magnesium, as the hydroxide soluble Barium BaCO - Exports sodium, and lithium (54). and carbonate, may compounds (7a) BaSCT 1.4 x 10 (43) Barium compounds are used in cause local irritation Ba(CN) the manufacture of white pigments to the eyes, nose, EPA: BaO in paints, chlorine, sodium throat and skin. (54) Keportable quantities Bad hydroxide, valves, and green Soluble barium (Ba(CN) 2 only) (54) BaO flares; in synthetic rubber compounds are Hazardous Waste BaliPO vulcanization, x-ray diagnostic poisonous. (64a) Constituent (54) BaCrO; work, glassmaking, papermaking, Hazardous water beet-sugar purification, animal Chronic: pollutant & harmful and vegetable oil refining. Used Inhalation of quantities (80) in the brick and tile, BaSO, dust may lead pyrotechnics, and electronic to "baritosis", a DOT: industries. Found in lubricants, benign pneumoconiosis. Poison. (X) required pesticides, glazes, textiles dyes (54) on label (54) and finishes, pharmaceuticals, and in cement which will be FDA: exposed to saltwater. (54) Bottled water standards (80) Health hazard labeling (80) Poison (80) 162 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr. ) Uses Effects Parameters Beryl lium 1977 - Production Beryllium is used in the atomic Acute: Aquatic Toxicity Rating: OSIIA: (Be) 7.4 x 10 energy field as as moderate for The soluble salts LC 96:100-10 ppm (7a) Air: , 7440-41-7 1978 - Imports fission reactions, as a reflector are cutaneous (Be and BeCl^ TWA 2 ug las Be/m Salts 1.4 x 10 to reduce leakage of neutrons sensitizers as well CL 5 ug/m BeF 1978 - Exports from the reactor core, and, in a as primary irritants. Solubility in water: PK 25 ug/30 min./8 ht BeCt 1,600 (9) mixture with uranium as a neutron The acid salts cause Soluble Be salts are (7a) Be (NO ) source; Used in x-ray tubes; contact dermatitis. hydrolyzed to form EPA: BeO J ^ N.J. Industrial Survey alloyed with several metals to (54) insoluble Be(OH) 2 - (8) Priority Pollutants (1978-1979): increase hardness. Beryllium (54) Produced - 0 , compounds are used in the manu Chronic: Bioaccumulation: Keportable quantities Purchased - 1-5 x 10 facture of ceramics and Limited evidence of Concentration factor (BeF BeCl (Be and compounds) (84) refractories, as chemical carcinogenicity in for marine and freshwater (Be(SO,} ) ) T89) reagents and gas mantle hardners, humans; workers fish, invertebrates, and Hazardous Waste (Be and in atomic energy reactions. in refining and plants is 100 (8) dust) (54) (54) smelting plants (42) Hazardous Waste constituent (54) Sufficient evidence that National emission beryllium compounds are standards (80) carcinogenic in animals National Oil & (42) Hazardous Substance Contingency Plan (80) DOT: Poison (B) (54) 163 Substances Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Physical State J_B. >-he U.S. (Ibs./yr Uses Effects Parameters Boron 1980 - Production Boron is used in metallurgy as Acute: OSIIA: (B) 5 x 10 (64a) a degasifyiug agent and is Produce irritation Air: 7440-42-8 alloyed with aluminum, iron, and of the nasal mucous Salts steel to increase hardness. Also membranes, the (BK ) H..BCL a neutron absorber in nuclear respiratory tract, and Cl 15 mg/m reactors. Boric acid is a tire- eyes. (54) (BO) proofing agent for wood, a pre TWA O.I mg/m servative, and an antiseptic. Chronic: It is used in the manutacture of 6.01 mg/m glass, pottery, enamels, glazes, 3 cosmetics, cements, porcelain, mg/m B 10 14 borates, leathers, carpets, hats ) (64a) soaps, and artificial gems and in tanning, printing, dyeing, painting DOT: and photography. It is a Corrosive material constituent in powders, ointments, (BBr ) (36) nickeling baths, electrical Nonflammable gas and condensers and is used for poison (BF ) (54) impregnating wicks and hardening steel. Borax is used as a EPA: soldering flux, preservative Hazardous waste (80) against wood fungus, and as an antiseptic. It is used in the manufacture of enamels and glazes and in tanning, cleaning compounds, for fireproofing fabrics and wood and in artifical aging of wood. (54) 164 Substances Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Euvi roiunental Physical State in the U.S. (Ibs./yr.) _Uses______Effects Parameters Cadmium 1980 - Production Major use is in electroplating, Acute: Persistence: OSHA: (Cd) 1.7 x 10 (including used in alloys, used in Cd is an irritant to Relatively mobile in the TWA 0.05 mg/(Cd)/m 7440-43-9 Cd compounds) soldering, and in Cd-Ni the respiratory tract. aquatic environment. (8) for CdO production Sails 1980 - Imports , batteries. (64a) Cd compounds are suspected carcinogen CdBr 2.0 x 10 (including relatively well Bioaccumulation: (64) CdCfC Cd compounds (9) absorbed by Strongly accumlated by CL 0.05 mg(Cd)/m for Cd(C^H 0 ) inhalation (54) all organisms. (8) CdO fiuiie (64a) CdO J ^ N.J. Industrial Survey (1978-1979): , Chronic: Detection in environmental N10S1I Recommendation Produced - 1-5 x 10 Chronic cadmium media: TWA 40 ug(Cd)/m Purchased - 1-5 x 10' poisoning has been Industrial wastewaters CL 200 ug/(Cd)/m / (Cd and compounds) (84) reported after pro and intakes: 15 min. (64a) longed exposure to USEPA 30.7% (78) CdO fumes, CdO dust, NJDEP (OSR) 42% (82) EPA: CdS and Cd stearates firoumlwat pr: Priority Pu! lutant (54) NJDEP (OSR) 2.4% (85) .(«) Potable Water: Reportable quantities Limited evidence of NJDEP (OSR) 0/12 (86) (Cd acetate, carcinogenic!ty in POTWS bromide and humans (42) NJDEP (OSR) chloride) (89) Influents 7/9 Hazardous Waste CdCl 2 , CdO, CdSO, and Effluents 8/9 constituent (54) CdS are animal Sludge 7/9 (88) Ocean dumping (80) carcinogens (42) Ambient Air: Solid waste NJDEP (OSR) 79% (83) facilities (80) Cd(C H302 ) 2 was positive in cell DOT : transformation Label should read (X) assay (42) (54) Teratogenic in FDA: chickens, hamsters Bottled water and rats. (90) standard (80) 165 Substance Name (Synonym) Amount Produced Ma jor CAS Number Imported, Exported Conmiercia 1 Health Envi ronmental Physical State _i«_yi? JL_S • (Ibs./yr.) _ Uses Effects Pa rameters Regulat ions __ Calcium Not produced commercially Fertilizer, defoliant, herbicide Acute: Solubility in water: ACGIH Recommendation: cyanimide in U.S. (43) arid pesticide. Used in the manu Rats: Insoluble (43) TLV-TWA 500 ug/m 156-62-7 facturer of calcium cyanide, LD :1400 mg/kg STKL 1 mg/m" (7a) Solid 1975 - Consumption melamine and docyatidiamide (3f) (oral) 2.9 x l Mutagen in bacteria (7) 166 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Physical State in the U.S. (Ibs./yr.) __ Uses Effects Parameters Chromium 1980 - Production Used in chrome plating, copper Acute: Persistence: OS1IA: (Cr) 7.5 x 10 of Cr stripping, aluminum anodizing, Chromium compounds CR (VI) is soluble but Air: 7440-47-3 and ten important as a catalyst, refractories, may act as allergens reacts with reducing TWA 1.0 mg/m for Cr Salts compounds (9) in organic synthesis, and which cause dermatitis materials to form Cr(III). Cr and water CaCrO, 1980 - Imports photography (54) to exposed skin. May (8) insoluble Cr (54) CrO 1.02 x 10 (9) also produce pulmonary Cr(III) reacts with aqueous TWA 0.5 mg/m for CrCI sensitization. hydroxide ion to form Cr(Ill) and water CrF 5 N.J. Industrial Survey Soluble chromates are insoluble Cr(OH) 3 - (8) soluble Cr(VI) (54) CrSO, (1978-1979): of very low toxicity CrK(SO Produced - 1-5 x 10 by mouth (1500 mg/kg) Bioaccumulation: ACGI11 Recommendation: CrOHSC Purchased - 1-5 x 10 (84) intermediate by Is bioaccumulated by Ai r: CrCI (of Cr and Cr compounds) cutaneous application aquatic organisms and TWA 0.5 mg/m for K Cr6 (200-350 mg/kg) but passage of chromium Cr, Cr(Il), Cr(III) Na Cr,0 Y highly toxic by sub through the food chain TWA 0.05 mg/m for CrPO /• 1 cutaneous, intra- has been demonstrated. (8) Cr(Vl) PbCrO, peritoneal, or intra TWA 0.15 mg/m3 for muscular injection Bioconcentration factors chromyl chloride (10-50 mg/kg) (64a) are 70-4,000 (8) (54) Chronic: N10SH Recommendation: Increased incidence of TWA 0.001 mg/m for lung cancer among workers carcinogenic in the chromate-producing compounds (54) industry, and possibly also among chromium EPA: platers and chromium Priority Pollutant alloy workers (42) (8) Reportable quantities Calcium chromate is (Cr(C 0 H ), H CrO,, carcinogenic to rats by Cr(SO ) ), CrCI . (89) * J several routes chromium chromate, strontium Hazardous Waste chromate and zinc constituent (54) chromate produce local Hazardous water sarcomas in rats at site pollutant & harmful of application (42) quantities (80) Muuufdctuting paint Cr(Vl) is mutagenic in source (80) bacteria, fungi, mammalian cell assays, and mice (42) Positive in cell DOT: transformation Oxidizer (H assay, (42) (54) i FDA: Bottled water standard (80) Poison (80) 167 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported CommerciaI Health Environmental Physical State Jn the U.S. (Ibs./yr.) Uses Effects Parameters Regula t ions Copper 1975 - Production of Cu Widely used in the electrical Acute: Bioaccumulation OSI1A: 7440-50-8 4.85 x 10 industry in all guages of wire High concentrations Copper is strongly Air , Salts 1975 - Imports of refined for circulry, coil, and armature of Cu(II) are toxic bioaccumulated and TWA 0.1 mg/m Cu(C 11 0 ) Cu 2.9 x 10 windings, high conductivity tubes, aquatic organisms (8) is an essential trace for couper fume CuClf J 1975 - Exports of refined commutator bars, etc. made into element. (8) 1 mg/m for copper Cu(NO ) Cu 2.2 x 10 (43) castings, sheets, rods, tubing, Chronic: mists (54) and wire, and is used in water Copper poisoning N.J. Industrial Survey and gas piping, roofing materials, in animals leads to ACGIH Recommendation: (1978-1979): cooking untensils, chemical and injury of the liver, TWA 0.2 mg/m for Produced - 1-5 x 10 pharmaceutical equipment and kidney and spleen (64a) copper fume (54) Purchased - 1-5 x 10 coinage. Forms many important (Cu and salts) (84) a]loys. EPA: Copper compounds are used as Priority Pollutant insecticides, algicides, (8) malluscicides, plant fungicides, Reportable quantities mortants, pigments, catalysts. (54) (Cu(C2H 302 ) , cupric acetoareanate, cupric chloride, cupric nitrate, cupric oxalate, cupric sulfate, cupric sulfate ammoniated, cupric tartrate) (80) Hazardous Waste (Copper cyanide) (54), CAA, industrial pollutant (80) Manufacturing paint source (80) National emission standard (80) Pesticide residue tolerance (80) FDA: Bottled water Standard (80) Color additive (80) Poison (80) DOT: Hazardous materials table (80) 168 Substance Name (Synonym) Amount Produced Ma jar CAS Number Imported, Exported Commercial Health Environmenta I Physical State -in-Jtil?. U-S. (Ibs./yr.) Uses Effects Parameters Cyanides N.J. Industrial Survey Primarily used in the extraction Acute: Aquatic Toxicity Hating OSIIA: 57-12-5 (1978-1979): of ores, electroplating, metal Lethal to freshwater LC5Q96: under I ppm (7a) Air KCN Produced - 0 , treatment, and various fishes at concentra TWA ,r> mg/m (7a) NaCN Purchased - 1-5 x 10 manufacturing processes (54) tions as low as Persistence: Ca(CN) (all cyanides) (84) 50 ug/1. Adversely Eiodegrades and N10SII Recommendations: affects invertebrates volatilizes (8) Cl 5 mg/m /15 mill. HCN and fishes at 10 ug/1 (90) EPA: Humans: Priority Pollutant LD :570 ug/kg (oral) (8) LC r ;::120 mg/m /I hr. Reportable quantities (2 ft (89) Hazardous Waste Chronic: Constituent (54) Degraded by humau water pollution, liver to less toxic toxic pollutant (80) thiocyanate and are not known to be DOT: chronically toxic Poison B to humans. (90) (NaCN and KCN) (54) CPSC: Banned, interstate commerce (80) 169 Substance Name (Synonym) Amount Produced Major CAS Number imported, Exported Commercial Health Environmental Physical State _JL'I the U.S. (Ibs./yr.)^ Uses Effects Parameters Lead Consumption.! s about About 50% is used for the Acute: Solubility in water: OS1IA: ; U'b) 2.87 x 10 (90) manufacture of storage batteries, Toxic to aquatic Tends to form complexes Air ., 7439-92-1 20% is used for the manufacture invertebrates at of low solubility TWA 200 mg/ni (Pb and N.J. Industrial Survey of gasoline antiknock additives 450 ug/1. Toxic with the major anions of its inorganic salts) (1978-1979): (tetraethyl and tetramethyl lead): to aquatic vertebrates natural environmental TWA 75 ug/m Produced - 1-5 x 10 6% is used in pigments and at 900 ug/1 (90) systems. (8) (tetraethyl lead) Purchased - 1-5 x 10 ceramics; other major uses are (54) (Pb and its salts and for metallic lead products or Chronic: Bioaccumulation: organoroetallics) (84) tor lead-containing alloys. (90) Chronically toxic to Bioconcentration factors ACGIII Recommendation: aquatic invertebrates lend to decreases &s the TWA 0.15 mg/m ,as Pb at 100 ug/1, and to trophic level increases. STEL 0.45 mg/m as aquatic vertebrates (8) Pb. (54) at 7.6 ug/1. (90) EPA: Lead disturbs the Priority Pollutant blood chemistry, causes (8) neurological disorders, Reportable quantities kidney damage and adverse Pb(C 2H 02 ) , Pb cardiovascular effects. Arsenate, PbCl , (90) Pb(BF ) PbF , Pbl , PB(NO ) Pb Lead acetate, lead stea rate, PBSO^, PbS, subacetate, and lead tricyanate, phosphate are carcino tetraethyllead) (89) genic to rats and mice. Hazardous Waste (42) (Tetraethyl lead) (54) Hazardous Waste Embryotoxic (64a) Constituent (54) Motor fuel specifications (80) National emission standard (80) DOT: Poison B (Tetraethyl lead) (54) FDA: Bottled water standard (80) Poison (80) CPSC: Banned, interstate commerce (80) Poisoning from paint (80) 170 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _ _Regulations Manganese 1974 - Production of Used in the iron and steel Detection in environmental OSHA: (Hn) of ferruginous magnesium industry in steel alloys and nn is /.:> to j +3 Media: Air: 7439-96-5 ore was 6.96 x 10 (64a) as an agent to reduce oxygen and times as toxic as Mn Ambient Air Cl 5 mg/m 1 of Mn sulfur content of molten steel. (64a) NJDEP (OSR) - 233/234 (54) Mn and its compounds are utilized Minor irritant to the (83) in the manufacture of dry cell eyes and mucous ACG11I Recommendation: batteries, paints, varnishes, membranes of the TWA 1.0 mg/m for inks, dyes, matches, and fireworks, respiratory tract. manganese tetroxide as a fertilizer, disinfectant, (68) and manganese fume. bleaching agent, laboratory (54) reagent, drier for oils, an Chronic: STEL 3.0 mg/m for oxidizing agent in the chemical Chronic manganese manganese fume. (54) industry particularly in the poisoning is not fatal TWA 0.2 mg/m' for synthesis of potassium permangan but disabling (68) manganese ate, and as a decolorizer and me.thy Icyclopenta- coloring agent in the glass and dienyl tricarbonyl ceramics industry. (54) STEI, 0.6 mg/m (54) EPA: Hazardous waste (80) Ground water quality (80) FDA: Bottled water standard (80) 171 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State _?!> the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations______ Mercury Consumption of Ha is Mercury is used as a liquid Acute: Bioaccumulation: OSHA: 7439-97-6 almost 4.56 x 10 (64a) cathode in cells for the Humans Methyl mercury is the Air , electrolytic production of LD :29 mg/kg form of Hg present in Cl 0.1 mg/m (7a) N.J. Industrial Survey caustic and chlorine. It is (orXl) (HgCl ) (64a) most fish tissue, and is (1978-1979): used in electrical apparatus and LD :357 mg/fcg the most readily NIOSH Recommendation: Produced - 0 in control instruments (54) (oral) (HgI 2 ) (64a) accumulated and retained TLV-TWA 50 ug/m Purchased - 1-5 x 10 Inorganic mercury is used in form of mercury in aquatic STEL 150 ug/m (7a) (Hg and other compounds) gold, silver, bronze, and tin- Chronic: biota. (84) plating, tanning and dyeing, Hg vapor effects the Bioconcentration factors EPA: feltmaking, taxidermy, textile brain. In severe are 10 - 105 (8) Priority Pollutants manufacturing photography arid cases it can cause (8) photoengraving, in extracting degeneration of the Persistence: Reportable quantities gold and silver from ores, in brain. (64a) Any mercurial compound (Hg(CN) Hg(N02 ) 2 paints and pigments, in the pre may be microbially HgSO,, Hg thiocyanate paration of drugs and disinfectant Hg(II) effects the converted to methyl HgNo ) (89) in the pharmaceutical industry kidney. (64a) mercury. (8) Hazardous Waste (80) and as a chemical reagent. (54) National emission Organomercury compounds are used Standards (80) in treating seeds for fungi and seedborne diseases, as timber DOT: preservatives and disinfectants. (54) Poison B HgCl , alkyl and aryl mercury ORM-B (Hg) (54) FDA: Bottled water standard (80) Cosmetics (80) Poison (80) 172 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Nickel 1973 - Consumption Nickel alloys with copper, Acute: Solubility in water: OSHA: 7440-02-0 5.18 x 10" (36) manganese, zinc, chromium, iron, Skin sensitization. Under aerobic condition, Air molybdenum. Stainless steel and Irritant to eyes and the hydroxide, carbonate, TWA 1.0 mg/m of Ni N.J. Industrial Survey Monel nickel are important alloys. mucous membranes.,_,.. sulfate, and halide and its soluble (1978-1979): Ni is used in electroplating, compounds are soluble compounds (54) Produced - 5-10 x 10^ anodizing aluminum, casting Chronic: enough to allow toxic Purchased - 1-5 x 10 operations for machine parts, Limited evidence of concentrations to persist NIOSH Recommendation: (Ni and compounds) (84) and in coinage; in the manufacture carcinogenicity in in solution (8) TWA 15 ug/m (54) of acid-resisting and magnetic humans for Nickel and alloys, magnetic tapes, surgical some nickel compounds. Bioaccumulation: ACGIH Recommendation: and dental instruments, Ci-Cd Sufficient evidence Bioaccumulated by some TWA 1 mg/m for Ni batteries, nickel soaps in crank- that nickel refining aquatic organisms. Bio- TWA 0.1 mg/m for case oils, and ground-coat is a carcinogen in concentrations are less soluble Ni salts. enamels, colored ceramics, and humans. (42) than 10J (8) STEL 0.3 mg/m for glass. It is used as a catalyst soluble Ni salts. in the hydrogenation of fats, Sufficient evidence NiS-human carcinogen oils and other chemicals, in that nickel and certain synthetic coal oil production, nickel compounds are EPA: and as an intermediate in the carcinogenic in animals. Priority Pollutant (8) synthesis of acrylic esters for (42) Reportable quantities plastics (54) Ni(NH )(SO ) , NiCl Ci(OHi,,, Ni(Ko )„. NI(SO j (89) * Hazardous Waste constituent (54) DOT: flammable solid (Ni powder) (54) USDA: Food additive (80) 173 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Physi cal _§tate_ in the U.S. (Ibs./yr.) Uses_____ Effects Parameters _ ___Re girl at^ons Selenium N.J. Industrial Survey Mainly used in the manufacture of Acute: Bioaccumulation: OKHA: (Se) (1978-1979): selenium rectifiers; also used as Some Se compounds Bioconcentration factors Air 7782-49-2 Produced - 0 a pigment for ruby glass, paints, (SeO and SeOCL ) 400 to 800 (8) TWA 0.2 mg/m ScO Purchased - 1-5 x 10 (84) and dyes, as a vulcanizing agent are strong irritants (as Se) (54) SeOCL (Se and compounds) for rubber, a decolorizing agent to the upper respiratory SeS, for green glass, a chemical tract and eyes, and may EPA: catalyst in the Kjeldahl test, and cause irritation of the Priority Pollutant an insecticide; in the manufacture mucous membrane of the (8) of electrodes, selenium photocells, stomach. Selenium Hazardous Waste and semiconductor fusion mixtures compounds may also cause (Se02 ) (54) in photographic toning baths; and dermatitis (54) Hazardous Waste for dehydrogenation of organic Constituent (54) compounds (54) Chronic: Reportable quantities SeO inhaled in large (Se.SeO, SeS2 ) (89) quantities may produce pulmonary edema (54) DOT: Poison B (SeO ) (54) FDA: Bottled water standard (80) Food additive (80) 174 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phy s ical_SLate_ in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ___Regulations Silver N.J. Industrial Survey Principal uses are in photo- Bioaccumulation: OSHA: («s) v. 1978-I979./; , gLaplnu ma i-ei ia l S , eiecuiuplatiug, Aii „ 7440-22-4 Produced - 1-5 x 10 , as a conductor, in dental alloys, of 200-3330 (8) TWA 0.01 mg/m Salts Purchased - 5-10 x 10 solder and brazing alloys, paints, (as Ag) (54) AgNo (Ag and compounds) (84) jewelry, silverware, coinage, and AgCNJ mirror production (90) ACGIH Recommendation: AgC H 0 TWA 0.1 mg/m for Ag (54) EPA: Priority Pollutant (8) Reportable quantities (89) (AgNo 3 ) Hazardous Waste (AgCri) (54) Hazardous Waste Constituent (54) DOT: Oxidizer (AgNO ) Poison B (AgCN) (54) FDA: Hottled water standard (80) Color additive (80) Poison (80) 175 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phjrsical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Re gulations Thallium 1976 - Production and use Manufacture of alloys, electronic Acute: Aquatic Toxicity: OSHA: (Tl ) 1500 (90) devices, and special glass. Many Thallium salts may Chronically toxic to Air 7440-28-0' thallium-containing catalysts have be skin irritants fish at 20 ug/1 (91) TWA 0.1 mg/m (as TL) Salts N.J. Industrial Survey been patented for industrial and sensitizers (54) (54) Tl 0 (1978-1979): organic reactions (90) Bioaccunm]ation: T1 2°3 Produced - 0 Chronic: Bioconcentration factors EPA: TIBr Purchased - 0 Extremely toxic and of 10 to 10 (8)' Priority Pollutant T1,,SO, (TL and compounds) (84) cumulative poison (54) (8) Reportable quantities TJ.SO, (89) Hazardous Waste (54) DOT: Poison B (54) 176 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Zinc 1975 - Product of Zn Principal uses of Zn include Bioaccumulation: OSHA: 9.9 x 10 7440-66-6 1975 - Imports of Zn of alloys. (90) of 400 to 100,000 (8) TWA 5 mg/nu for ZnO Salts 7.6 x 10 TWA 1 mg/m for ZnCl 1975 - Exports of Zn ZNO is used in the rubber industry ZriCl 2 (54) ZnO 1.4 x 10 (43) as a pigment and as an aid in Zn(C H 0 ) vulcanizing. (64a) EPA: Zn(CN);j N.J. Industrial Survey Priority Pollutant ZnF (1978-1979): (80) ZnSO Produced - l-5xlOJ Hazardous Waste (80) X National emission (Zn and compounds) (84) standards (80) National Oil & Hazardous Substance Contingency Plan (80) Reportable quantities (89) (Zn and salts) FDA: Bottled water standard (80) Food-contact component (80) Poison (80) DOT: Hazardous materials table (80) 177 1SOCYANATES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Toluene - In 1976, two companies A chemical intermediate; 56% Acute: Aquatic Toxicity Rating: OSHA: 2,4-Diisocyanate reported the production of is used in the synthesis of Skin irritant, causes LC 96:10-1 ppm (7) AfR: (2,4-TCI) 2,4-TCl; two companies flexible and semiflexible allergic eczema (43) CL 20 ppb (43) 584-84-9 produced the 65/35 mixture polyurethane foams; 29% is E'roduces allergic Reactivity with water: L i qu i (1 of 2,4-TCI/2,6-TCI; and exported:7% is used to make sensitization of Reacts violently with ACGIH Recommendation: eight companies make the rigid polyurethane foams; 4% respiratory tract water (28) TLV-TWA 5 ppb 80/20 mixture of 2,4-TCI/ for urethane surface coatings; (43) STEl, 20 ppb (7a) 2,6-TCI. (28) 3% for polyurethane elastomers; Vapor Pressure at 80°C: 1% for miscellaneous Chronic: 1 mm (43) DOT: 1975 - Produced. applications, including spandex NCI carcinogenesis Poison B (54) 4.8 x 10 (43) fibers, adhesives, sealants. (43) bioassay was positive in rats and mice. (7) 1976 - Exports 1.34 x 10 (28) Mutagenic in bacteria (7) Produced in New Jersey (43) 178 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations ___ _ Toluene - 2,6- 1976 - Two companies In 1975, the mixture was used (All experiments were Di isocyanate produced 65/35 in the production of polyurethane done with unspecified (2,6-TCI) (2,4-/2,6-) mixture flexible foam (90-92%); poly toluene diisocyanate 91-08-7 Eight companies urethane coatings (4%); mixtures.) produce 80/20 polyurethane elastomers (3%); (2,4-2/6) mixture - and miscellaneous applications Acute: 5.61 x 10 (28) (1%). (28) Skin irritant (43) Produces allergic 1976 - Exports sensitization of 1.34 x 10 respiratory tract. (isomer ratio (43) unspecified) (28) Chronic: NC1 carcinogenesis bioassay was positive in rats and mice. (7) 179 KETONES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters ____Regulations Isophorone 1976 - Production Solvent for lacquers and Acute: Bioaccumulation: OSHA: (3,5,5-Trimethyl- plastics; solvent for many oils, Irritant of eyes, nose log octanol/water Air: 2-Cyclohexen-1-one) - greater than 5000 (43) fats, gums and resins, and throat. CNS Partition coefficient: TWA 25 ppm (7) 78-59-1 nitrocellulose and vinyl-resin; effects may also 1-7 (8) Liquid and as a chemical intermediate occur (64c) ACGIH Recommendations: in the synthesis of Solubility in water CL 5 ppm (7) 3,5,5-trimethyl-cyclohexano] Chronic: 12,000 mg/1 (8) and 3,5-xylenol. (43) Negative in Ames NIOSII Recommendation: mutagenicity test Vapor pressure at 20°C: TWA 4 ppm (64c) (74) 0.38 mm (8) EPA: Detection in environmental Priority Pollutant media: (8) Industrial wastewaters Hazarodus Waste (80) and intakes National Oil & USEPA - 1.6% (78) Hazardous Substances NJOSR - Not detected (82) Contingency Plan (80) Pesticide residue tolerance (80) Reportable quantities (89) DOT: Hazardous Materials table (80) 180 LACTAMS Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. Qbs./yr.)______Uses_____ Effects Parameters Caprolactam 1976 - Production Used almost exclusively to Acute: Solubility in water: ACGIH Recommendation: 105-60-2 7.8 x 10 produced polycaprolactam, which An irritant of the Soluble (28) TXV-TWA 5 ppm Solid - Imports , is commonly known as nylon 6. eyes, skin, and nasal STEL 10 ppm (vapor) 2.25 x 10 (28) passages. (28) Vapor Pressure at 120°C: (7a) - Exports In 1963, 93% was used to make 6 mm (43) 2.89 x 10 (43) nylon 6 fibers; 7% was used for Rat EPA: nylon 6 plastics and films. (43) :2140 mg/kg National Oil & 50 (oral) (43) Hazardous Substances Contingency Plan (80) Chronic: 181 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental i'hysical State_____in the U.S. (Ibs./yr.)______Uses______Effects______Parameters N-Vinyl-2- One company reported Used to manufacture polyvinyl Acute: Solubility in water: pyrrolidinone production in 1976 of an pyrrolidone; to make copolymers Rat Miscible (28) 88-12-0 undisclosed amount. (28) with other monomers; and as a LD :1470 mg/kg Liquid chemical intermediate. (28) (oral) 1976 - Imports , LC :3200 mg/m 1.59 x 10 of (inhalation) (7) monomer and polymer. (28) 182 NITRILES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State_ in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters lations Acrylonitrile 1976 - Production 48% for the manufacture of Acute: Aquatic Toxicity Rating: OSHA: 107-13-1 1.52 x 10 acrylic and modacrylic fibers; Inhibits the LC 96:100-10 ppm (7) Cancer hazard Liquid 21% for manufacture of respiratory enzymes for Air - Imports acrylonitrile - butadiene - absorbing 0 . Bioaccumulation: TWA 2 ppm 1.35 x 10' styrene and styrene - A powerful, acute log octanol/water Cl 10 ppm/15 min (7) acrylonitrile resins; 12% for syn poison via oral and partition coefficient: - Exports _ thesis of adiponitrile; 19% for dermal routes (2b) - 0.14 (calc.) (8) EPA: 2.34 x 10 (28) other applications mainly for Rats Priority the production of butadiene - LD -82 mg/kg (oral) Solubility in water at 20°C: Pollutant (8) . acrylontrile copolymers (28) LC :500 ppm (inhal.) 73,500 mg/1 (8) Hazardous Waste (54) Pesticide use (7a) Chronic: Vapor pressure at 22.8°C: Classification (80) Limited evidence of 100 mm (8) Hazarodus Water carcinogenicity in Pollutant designa- humans (42) Atmospheric Residence Time: & harmful 5.6 days (44) quantities (80) Sufficient evidence Reportable of carcinogenicity in. quantities (89) rats via oral and inhalation routes. DOT: T _ ___ _ I F IdllUlldl le Liquid (54) Mutagen in bacteria (42) FDA: Prior sanctioned Chromosome aberrations food packaging in rats (42) component (80) Positive in cell N.J.: transformation Restricted Pesticide assay (42) (81) Teratogenic in rats (28) Embryotoxic in rats (28) 183 NITRO COMPOUNDS Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters _ Regulations 2,4-Dinitro- 1975 - Production Used ae a chemical intermediate. Acute: Aquatic Toxicity Rating: OSHA: toluene 3 x 10H (43) A component of explosives. (43) Highly toxic by IX 96:100-10 ppm (7) TWA 1.5 mg/m (54) 121-14-2 absorption, ingestion Solid N.J. Industrial Survey and inhalation. (43) Bioaccumulation: EPA: (1978-1979): log octanol/water Priority Pollutant (8) Produced - 5-10 x 10 partition coefficient: Hazardous Waste (54) Purchased - 0 (84) 2.01 (8) Reportable quantities (89) Solubility in water: Chronic: 270 mg/1 (8) DOT: NCI bioassay ORM-E (54) carcinogenic in Vapor Pressure at 59°C: rats, negative in 1.3 x 10 mm (8) mice. (7) Detection in environmental Mutagen in media: bacteria and Industrial wastewater in mice (7) and intakes: USEPA - 1% (78) NJDEP (OSR) - 1/29 (82) Potable water, raw and treated: NJDEP (OSR) - 1/240 (86) POTWs NJDEP (OSR) influents - 1/9 effluents - 1/9 sludge - 1/10 (88) 184 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State _ in_the U.S. (Ibs./yr.)______Uses_____ Effects Parameters __Regulations 2,6-Dinitro- 1975 - Production Used as a chemical intermediate Acute: Aquatic Toxicity Rating: OSHA: ^ toluene 2.1 x 10 (43) A component ol explosives. (43) Highly toxic by LC 96:100-10 ppm (7) TWA 1.5 mg/nT (54) 606-20-2 inhalation, ingestion N.J. Industrial Survey and absorption (54) Bioaccumulation: EPA: (1978-1979): log octanol/water Priority Pollutant(8) Produced - 1-5 x 10 Chronic: partition coefficient Hazardous Waste (54) Purchase - 0 (84) Prolonged exposure 2.05 (8) Reportable quantities may cause anemia (54) (89) Solubility in water: Mutagen in bacteria about 300 ppm (8) DOT: mammalian cells, ORM-E (54) and in rats (7) Vapor Pressure: Probably low (8) Detection in environmental media: Industrial wastewaters and intakes: USEPA - 1.4% (78) NJDEP (OSR) 0/28 (82) Potable water, raw, and treated: NJDEP (OSR) - 0/244 (86) 185 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phy^si ca 1 _St aj.e_ -JJL-tJli. U-S. (Ibs./yr.)______Uses_____ Effects Parameters ____Re gu lai t^o ti s ___ Nitrobenzene Chemical intermediate, solvent, Acute: Aquatic Toxicity Rating: OSI1A: 98-95-3 in soaps, shoe polish, refining Toxic by absorption, LC 96:100-10 ppm (7) TWA 1 ppm (7) Liquid N.J. Industrial Survey lubricating oils, preservative in inhalation, ingestion (1978-1979): in paints, floor polish, (54) Bioaccumulation: EPA: Produced - 1-5 x 10 £yr. substitute for almond essence. Humans: Log octanol/water Priority Pollutant Purchased - 1-5 x 10 /yr. (31) LD :5 mg/kg (oral) partition coefficient: (8) (84) 1.85 (8) Hazardous Waste (54) Reportable quantities Chronic: Solubility in water at 20°C: (89) 1,900 mg/1 (8) DOT: Detection in environmental Poison B (54) media: Industrial wastewater and intakes: USEPA - 1.7% (78) NJDEP (OSR) - 0/28 (82) Potable water, raw and treated: NJDEP (OSR) - 1/245 (86) POTWs NJDEP (OSR) effluents - 1/9 (88) 186 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters __Regulations 2-Ni tropropaiie 1977 - Production Solvent, component of explosives, Acute: Aquatic Toxicity Rating: OSHA: 79-46-9 3 x iO (20) smoke reducing component of Human: LC5Q 96: 100-10 ppm (7) TWA 25 ppm (7a) Liquid diesel fuel, rocket propel lant, TC :20 ppm N.J. Industrial Survey gasoline additive (43) (inhalation) (43) Solubility in water: EPA: (1978-1979): 1.7 ml/100 ml (43) Hazardous Waste (54) Produced - 0 Reportable quantities Purchased - 0 (84) Vapor Pressure at 25°C: (89) 20 am (43) Chronic: DOT: Carcinogenic in two Flammable liquid inhalation studies in (89) rats (20) Mutagenic in bacteria (20) 187 NITROGEN HETEROCYCLES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phyjuca_[ Stat.e_____in the U.S. (Ibs./yr.)______Uses______ETfects______Parameters______Rpgulat ions_____ Acridine 1975 - probably less than Used in manufacture of dyes and Acute: Solubility in water: DOT: 260-94-6 1,000 (43) intermediates. Some dyes Irritant to the skin Slightly soluble (43) Hazardous materials Solid derived are used for antiseptics. and mucous membranes (4f) table (80) The hydrochloride is a reagent Vapor Pressure at 129.4°C: for cobalt, iron and zinc Chronic: 1 mm (4f) analysis. (4f) Mutagen in bacteria (7) 188 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental _in_the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ___ __ Kegu 1 a _• L°'l? ______ Carbazole 1974 - Greater than 1,000 A chemical intermediate for Acute: Solubility in water: EPA: (9-azafluorene) the synthesis of vat blue 43, Rats Insoluble (5) One of six chemicals 86-74-8 1975 - Imports 1.9 x 10 S (43) for azonic coupling component 15, LD -500 mg/kg (oral) that will be added Solid for pigment violet 23; for (7V' Vapor Pressure are 323°C: to EPA's pretreat- preparation of the explosive 400 mm (43) ment standards for tetranitrocarbazole; and for the specific industries. synthesis of the monomer n- vinylcarbazole. (43) 189 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State_ in the U.S. (Ibs./yr.) Uses Effects Parameters Melaroine 1974 - Produced.. Used as a comonomer with Acute: Solubility in water: 108-78-1 1.2 x 10 (est.) formaldehyde in the synthesis A skin and eye Slightly soluble (5) Solid of amino resin products. (43) irritant (6) 1975 - Imports , Vapor pressure at 315°C: 6.6 x 10b (43) Moderately toxic 50 mm (43) by ingestion (6) Chronic: Not metabolized by mammals. (Pers. Comm.) 190 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phjrsiral State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ___Regulat ions Pyridine 1975 - Production Approximately 33% is used as a Acute: Aquatic Toxicity Rating: OSHA: liu-86-i 1.5 x 10 (est. ) solvent in drug manufacturing, In humans the effects LC 36:1000-100 ppm (7a) Air Liquid and as a reagent (including use are transient, and TWA 5 ppm (7a) 1973 - Imports as a scavenger for acids); 17- center on the central Solubility in water: 9.9 x 10 33% is used as an intermediate in nervous system and Miscible (43) ACG1H Recommendation: synthesis of antihistamines gastrointestinal STF.L 10 ppm (skin) (7) 1975 - Exports , (including cetypyridinum tract. (64a) Vapor pressure at 25°C: 7.5 x 10 (43) chloride); 8-17% is used as an 20 mm (64a) EPA: intermediate in the preparation Reported to be a Hazardous Waste (36) of pipeline; 8-17% as an photosensitizer (64a) Detection in environmental Roportable quantities intermediate in the preparation media: (89) of waterproofing agents in the Chronic: Ambient Air: textile industry; and 8-17% is NJDEP (OSR) DOT: used for miscellaneous infrequently (83) Flammable liquid applications. (43) (7a) 191 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Phy sicaI State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _Re gulations Quinoline 1975 - Production A chemical intermediate for the Acute: Aquatic Toxicity: EPA: 91-22-5 greater than synthesis of local anesthetics, Moderately toxic by LC :5-50 ppm (64a) Hazardous Waste (80) Liquid 3,000. pesticides, and other most routes of Hazardous water pharmaceuticals. A solvent for exposure. (64a) Solubility in water: Pol lutaat designation - Imports - anthraquinone dyes. (43) 60,000 mg/liter (64a) & harmful quantities greater than An eye and skin (89) 3,000. (43) irritant (64a) Vapor Pressure at 59.7°C: 1 mm (64a) DOT: Hazardous materials Chronic: table (80) Carcinogenic in rats and mice (64a) Mutagen in bacteria and mammalian cell assays. (64a) 192 NITROSO COMPOUNDS Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State___ in the U.S. (lb./y Uses .._._. _ Effects Parameters______Regulations N-Nitrosodiethyl- Not produced commercially Predominantly used as a research Acute: Solubility in water: EPA: amine in U.S. (43) chemical; minor applications Guinea pig Soluble (about 10%) (26) Hazardous Waste (80) 55-18-5 include its use in plastics, as U) :250 mg/kg Reportable quantities Liquid a lubricant additive, and as (oral) (7a) (89) an antioxidant (9) Chronic: DOT: Sufficient Hazardous materials evidence that it is table (80) an animal carcinogen (26) Mutagen in host mediated assay. (26) Mutagen in Drosophila, mammalian cells and bacteria (26) 193 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental ical State _in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ___ Regulat ions N-Nitrosodimethyl- Not currently produced in Prior to 1976, it was used as a Acute: Solubility in water: OSHA: amine commercial quantities (9) intermediate in the production Rats Soluble (26) Carcinogen (7) 62-75-9 1,1-dimethylhydrazine, a rocket : 26 mg/kg (oral) Liquid fuel. Also used as a solvent in Vapor Pressure at 67.1°C: EPA: the fiber and plastics industry; 40 mm (3f) Priority Pollutant (8) as an antioxidant; as a softener Chronic: Hazardous Waste (36) of copolymers; and as an additive Sufficient evidence Bioaccumulation: Reportable quantities for lubricants. Present use is carcinogenicity in Little potential (8) (89) limited to research. (9) animals. (26) Persistence: DOT: Resistant to biodegradation Hazardous materials Mutagen in host in surface water (8) table (80) mediated assay (26) Degrades slowly in sewage Mutagen in and sludge (8) drosophila, mammalian cells and bacteria (26) Embryotoxic in rats (26) 194 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters __Regulations p-Nitrosodimethyl- 1975 - Production Used as an accelerator for Acute: Solubility in water: DOT: aniiine Probably greater than rubber vulcanization; in printing Highly irritating to Insoluble (43) Hazardous materials 138-89-6 1000 (43) fabrics; as an intermediate in skin both as primary table (80) Solid the synthesis of dyes; and as a irritant and sensitizing N.J. Industrial Survey chemical intermediate in the agent (43) (1978-1979): synthesis of organic chemicals. Produced - 0 (43) Rat Purchased - 0 LD -.65 mg/kg (oral) Max. Inventory - 0 (84) Chronic: 195 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physica 1 State_____in the U.S. (Ibs./yr.)______Uses______Effects______Parameters______Regulations N-Nitrosodiphenyl- 1979 - Produced Used almost exclusively as an Acute: Soluble in water: EPA: amine 6.31 x 10 intermediate in the manufacture Rats Insoluble (36) Priority Pollutant (8) 86-30-6 by four companies. of p-nitrosodiphenylamine and LD :1650 mg/kg Hazardous Waste (80) Solid 1977 - Imports , as a rubber processing chemical. (oral) (43) Bioaccumulation: Reportable quantities 5.2 x 10 (36) (36) log octanol/water (89) Chronic: partition coefficient N.J. Industrial Survey Limited 2.57 (8) DOT: (1978-1979): , evidence that it is Hazardous materials Produced - 5-10 x 10 a carcinogen in table (80) Purchased - 0 (84) animals (36) Not a mutagenic in several assays in prokaryotes or eukaryotes. (36) 196 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations p-Nitrosodiphenyl- 1978 - Produced by two Used as a chemical intermediate Acute: Solubility in water: amine companies. One for dyes and pharmaceuticals, Rats Slightly Soluble (36) 156-10-5 company's production and as a polymerization inhibitor LD_ :2410 mg/kg (oral) Solid in 1977 was during the manufacture of vinyl (36) 1-100 x 10 (36) monomers such as styrene. Also reported to have been used as an accelerator in the vulcanization of rubber. (36) 197 ORGANIC PEROXIDES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Benzoyl 1975 - Production - A polymerization initator used Acute: Solubility in water: OSHA: Peroxide 7.94 x 10 (43) principally for vinyl chloride May cause local Sparingly soluble (3a) AIR (Dibenzoyl polymerizations; a curing agent irritation to the TWA 5 mg/m (7a) peroxide) Produced in New Jersey (43) for thermoset polyesters, and eyes, skin, and Vapor Pressure at 20°C: 94-36-0 silicone rubbers. (43) mucous membranes 1 mm (43) DOT: Solid (43) Organic Peroxide (54) An allergen (43) FDA: Chronic: Food-contact A cocarcinogen in component (80) mice (43) Flour bleaching (80) 198 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations t-Butyl- 1975 - Production An initiator for vinyl monomer Acute: Solubility in Water: PDA: hydroperoxide Probably greater than polymerizations and co- Kye and skin Soluble (43) Food-contact 75-91-2 500 (43) polymerizations with styrene, irritant (43) component (80) Liquid vinyl acetate, acrylics, acrylamide, unsaturated Chronic: DOT: polyesters; and as a curing agent A bacterial mutagen (1) Hazardous materials for thermoset plastics (1) table (80) Mayor use is as an intermediate A mutagen in for the production of propylene dominant lethal oxide and t-butyl alochol. (43) assay in mice (7) 199 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations Cumene 1976 - Production Used as an initiator for vinyl Acute: Solubility in Water: DOT: hydroperoxide 3.18 x 10 (43) monomer polymerizations and Skin irritant (43) Slightly soluble (43) Organic Peroxide 80-15-0 (captive consumption) copolymerizations with styrene, (7a) Liquid acrylics, butadiene-styrene, Chronic: Reported to be produced cross-linked foamed polyesters; A bacterial mutagen EPA: in N.J. (43) as a curing agent for thermoset (1) Hazardous Waste (80) polyesters, styrenated alkyds monomers; and as a promotor for FDA: oxidation of hydrocarbons. (1) Food-contact component (80) 200 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Envi ronmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Di-t-butylperoxide 1976 - Production Used extensively in organic Acute: Solubility in water: FDA: £iyrii~iiCSis ss s J.ITGG 110-05-4 catatyst, as a source of reactive irritant (7a) component (80) Liquid methyl radicals; as a initiator Vapor pressure at 20°C: for vinyl monomer polymerizations Chronic: 19.51 mm (43) DOT: and copolymerizations of ethylene, Hazardous materials styrene, vinyl acetate, and table (80) acrylics and as a curing agent for thermoset polyesters, styrenated alkyds and oils, and silicone rubbers, as a vulcanization agent for rubber, in lubricating oil manufacture, for crosslinking of fire-resistant polybutadiene molding and for cross-linking of high density polyethylene (1) 201 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations Peracetic acid 1974 - Production Primarily employed as a bleaching Acute: Solubility in water: DOT: (peroxyacetic greater than and epoxicizing agent. The range Severe skin and eye Very soluble (43) Organic Peroxide (7a) acid) 2.38 x 10 (43) of utility of peracetic acid irritant. (43) 79-21-0 includes: the bleaching of textiles and paper-pulp; as a Chronic: FDA: catalyst for polymerization of Mutagenic in bacterial Food starch bleaching aminopropionitrile; as a co- assays (1) agent (80) catalyst for a stereospecific polymerization of aldehydes; as a fungicide; as a disinfectant for rooms and medical machines; sterilizing agent for blood serum for tissue culture; as an oxidizing and hydroxylating reagent in organic synthesis; and as a bactericide in food industries. (1) 202 PESTICIDES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Env i ronmenta 1 Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Aldrin Not produced in U.S. (43) An insecticide used in Soil Acute: Bioaccumu] ation : OSIIA: 390-00-2 treatment for termites (43) Highly toxic Shown to occur in mollusks, Air , Solid 1981 - Imports , ingestion, inhalation clams and oysters (2e) TWA 250ug/m (7) 1.2 x 10 and skin absorption (6) (pers. comm. Solubility in water at 25°C: EPA: Scallop Corp. ) Chronic: 180 ppb (8) Priority Limited evidence of Pollutant (8) N.J. Industrial Survey carcinogenicity in Vapor Pressure at 20°C: Hazardous Waste (54) (1978-79): mice. (56) 2.31 x 10 mm (8) National Oil & Produced - 0 Hazardous Substances Purchased - 0 Not a mutagen (56) Persistence: Contingency Plan (80) Maximum Inventory - 0 Oxidized to Dieldrin by Reportable (84) Possible teratogen microbial activity (2e) quantities (89) (56) Pesticide residue Detected in environmental tolerance (80) media: Hazardous Water Industrial wastewater and Pollutant designa and intakes: tion and harmful USEPA - 0.45% (78) quantities (80) Groundwater NJDEP (OSR) - 2.9% (85) DOT: Potable water, raw and Poison B (7) treated: NJDEP (OSR) - 3/254 (86) NJDEP: POTWS Restricted NJDEP (OSR) Pesticides (81) sludge - 1/9 (88) 203 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Phy_sical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations______ Amitrole Current U.S. production is In 1975, 85% was used as a Acute: Solubility in water at 25°C: F.PA: (3-Amino-l,2,4- limited to 4000/yr. (9) herbicide for industrial or Rats 28,000 mg/1 (43) Cancelled for use triazoJe) commercial areas; and 15% was LD :14,700 mg/kg on croplands in 61-82-5 used as an aquatic herbicide. (oral) (43) Vapor pressure: 1971. (9) (43) low volatility (43) Hazardous waste (80) Chronic: Reportable Limited to non-crop uses. (9) Animal carcinogen (9) Persistence: quantities (89) Has been found to persist Mutagen in microbial in water for more than 200 DOT: assay (7) days. (16) Hazardous materials table (80) Positive in cell Rapidly degraded in soil. transformation assay (43) (7) Mutagen in host - mediated assay. (7) Suspected occupational carcinogen (64b) 204 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phy si ca1 State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters __ Re gut a t ion s_ BHCs No reported production in A persistent contact insecticide Acute: Aquatic Toxicity Rating: OSHA: (Benzene U.S. since 1976. (34) with fumigant action. (4a) Rat LC 96: under 1 ppm (7a) Air hexachloride) LD :600-1250 mg/kg TWA 500 ug/m (Hexachloro- (oral) Bioaccumulation: (skin) (7a) cyclohexane) Mouse log octanol/water 608-73-1 LD :700 mg/kg partition coefficient: EPA: Solid (oral) (29) 3.8-4.1 (8) Priority Pollutant (36) Chronic: Concentration factors vary Hazardous Waste (54) IARC - limited from 10 to 500. (8) In 1978, EPA evidence of voluntarily carcinogenicity in Solubility in water at 25°C: cancelled all uses animals. (42) 0.13-31.4 ppm (8) of technical grade BHC. Nongamma BHC Alpha, beta, gamma Vapor Pressure at 20°C: may not be sold, isomers produced 1.7-2.8x10 (8) manufactured, or liver tumors in distributed for use mice (42) Persistence: in U.S. (55) Does not photolyze, Pesticide residue Reduction of fertility oxidize or hydrolyze tolerance (80) in female rats. (29) readily (5). Reportable quantities (89) DOT: ORM - A (7a) NJDEP: Prohibited Pesticide (81) FDA: IVsticide residue tolerance (80) USDA: Food addition (80) 205 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _____Regulations Captan 1975 - Production 62% as a fungicide in agricultural Acute: Solubility in water: ACGIH Recommendation: 133-06-2 9.9 x 10 applications (for apples, peaches, Moderately toxic to Practically insoluble (43) TLV-TWA 5ing/m Solid and other deciduous fruits, humans via oral route) STEL 15 mg/m (7a) - Imports strawberries, grapes, citrus Persistence in water: 2.3 x 104 (43) fruits, vegetable crops, and in Humans: Slowly decomposes in water EPA: seed protection) 38% as a IDr _:1071mg/kg (oral) to yield tetrahydrophtha- Hazardous waste (80) N.J. Industrial Survey fungicide for home gardens ffi limide, thiophosgene and Repo rtable (1978-79): (43). HC1. (43) quantities (89) Produced - 0 Chronic: Pesticide residue Purchased - 5-10 x 10 /yr Mutagenic in bacteria, tolerance (80) (84) and yeast (64a) and Hazardous water mammalian cell assays pollutant designa (7) tion and harmful quantities (80) Teratogenic studies are inconclusive (64a) FDA: Food contact component (80) Pest icide residue tolerance (80) DOT: Hazardous materials table (80) 206 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Physical State _in_ the U.S. (Ibs./yr.)__ Effects Parameters Regulations_____ Carbaryl 1974 - Production A contact insecticide; 19% was Acute: Aquatic Toxicity Rating: OSHA: (Sevin) 2.6 x 10' (43) used on peanuts; 17% on assorted 1C 96:10-1 ppm (7) Air „ (63-25-2) vegetables; 16% for home and TWA 5mg/m (7) N.J. Industrial Survey gardens; 8% on corn; 7% on fruits Solubility in water at 25°C: (1978-79): such as citrus and apples anil Slightly soluble (43) EPA: Produced - 0 nuts; 7% on tobacco; 6% on Hazardous Waste (80) Purchased - 0 soybeans; 6% on cotton; 6% on Vapor pressure at 26°C: Reportable 1-5 x 10 (84) livestock (poultry); 6% on Chronic: less than 0.005 mm (21) quantities (89) grains and wheat; and 2% for It can react with Pesticide residue miscellaneous uses. (43) nitrite to produce tolerance (80) N-nitroso-carbaryl Hazardous water which is carcinogenic pollutant designa in rats (21) tion and harmful quantities (80) Teratogen in guinea pigs (43) 207 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Physical State _ll the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Chloramben 1975 - Production Herbicide; used 98% as a Acute: Solubility in water at 25°C: EPA: (Amiberi) 1 x 10 (43) herbicide for grasses and Slightly toxic (55) 700 mg/1 (43) Pesticide residue (3-Amiiio-2,5- broadleaf weeds on soybeans; 2% tolerance (80) dichlorobenzo ic as a herbicide for grass and Chronic: Vapor pressure at 100°C: acid) broadleaf weeds on other crops Carcinogenic in mice 7 x 10~J (43) 133-90-4 such as dry beans, lima beans, (7, 43) seedling asparagus, pumpkins, squash, corn, tomatoes, peppers, Not mutagenic in sweet potatoes (43) bacteria (7) 208 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmenta1 Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _ Kegirlat ions Chlordane 1974 - Production Insecticide used in soil Acute: Bioaccumulation: OSHA: 57-74-9 2.1 x 10 (43) treatment for termite control Moderately toxic (64fa) log octanol/water Air: Liquid Partition coefficient 2.78 (8)TWA 500 ug/m (7a) N.J. Industrial Survey Chronic: Bioconcentration factors - (1978-79): Carcinogenic in mice 10 to 10 (8) ACGIH Recommendation: Produced - 0 (56) Solubility in water at 25°C: STEL 2.0 mg/m (7a) Purchased - 5-10 xlO (84) 0.056-1.85 ppm (8) Not teratogenic in EPA: mice (56) Vapor pressure at 20°C: Priority 1 x 10 mm (8) Pollutant (8) Technical grade Hazardous Waste (54) chlordane is mutagenic Persistence: National Oil & in bacteria (56) Persistent in the Hazardous Substances environment because Contingency Plan (80) it is resistent to chemical Pesticide residue and microbial decomposition tolerance (80) (43) Reportable quantities (89) Detection in environmental Hazardous water med i a: pollutant designa Industrial wastewater and tion and harmful intakes: quantities (80) USEPA - 0.12% (78) Groundwater: DOT: NJDEP (OSR) - 6.5% (85) Flammable liquid Potable water, raw and (54) treated: NJDEP (OSR) - 0/254 (86) N.JDEP: POTWs Hestriced NJDEP (OSR) Pesticide (81) influents - 3/9 effluent - 2/9 sludge - 3/9 (88) Fish NJDEP (OSR) (87) 209 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _Re gu 1 at_i ons_ Chloriiecone Not manufactured in the Insecticide (29) Acute: Solubility in water at EPA: (Kepone) U.S. (9) Rat 100°C: Hazadrous Waste 143-50-0 LD :95 mg/kg (oral) 0.4% (29) (54) N.J. Industrial Survey (2d? In 1977, EPA (1978-1979): Neurotoxic in fish, Vapor Pressure at 25°C: cancelled all uses Produced - 0 quail, and chicks less than 3 x 10 mm (29) of this pesticide Purchased - 0 (29) (55) Max. Inventory - 1-5000 Persistence: Reportable (84) Chronic: Persistent for long quantities (89) Sufficient periods in soils and Hazardous water evidence of carcino- water (2d) pollutant design genicity in mire and ation & harmful rats. (29) Bioaccumulation: quantities (80) Occurs mainly through Impairs fertility uptake from water. Blue DOT: (29) crabs and avian predators Hazardous materials are major species at table (80) Embryotoxic (29) risk. (2d) NJDF.P: Negative in dominant Prohibited Pesticide lethal assay in rats (81) (29) 210 36 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters _Reji>u 1 a t i ons Chlordimef orm Not believed to be produced An insecticide/acaricide/ Acute: Solubility in water at 20°C: EPA: 6164-98-3 in the U.S. currently ovicide for the control of Mice 250 ppm (3f) Pesticide residue Solid insects in agricultural LD :160 mg/kg tolerance (80) 1980 - Imports applications. The only (oral) (3f) Vapor pressure at 20°C: Restricted use- 4.37 x 10 use of this pesticide is on Rats 3.6 x 10 mm (39) cotton (54) cotton to control birdworm LD :170 mg/kg 1980 - Usage and bollworm. (39) (oral) (3f) PDA: Pesticide residue Chronic: tolerance (80) Sufficient evidence that a metabolite p-chloro- o-toluidine is carcinogenic in mice. (39) Two metabolites (4-chloro-o- toluidine and n-formyl-4-chloro- o-toluidine) were negative in dominant lethal assay in mice. (3f) The metabolite (4-chloro-o-toluidine) is mulagenic in bacteria. (3f) 211 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters __Regulations Chlorobenzilate 1975 - Production probably A pre-harvest contact acaricide Acute: Solubility in water: EPA: 510-15-6 greater than 1000. (14) Rat slightly soluble (43) In 1979, EPA issued LD : 3100-4850 mg/kg a notice of - Imports 1.4 x 105 (43) (oral) (7) Vapor Pressure at 20°C: cancellation and 2.2 x 10 mm (43) denial of registra N.J. Industrial Survey Chronic: tions for uses other (1978-1979): Carcinogenic in two Persistence: than citrus, uses in Produced - 0 studies in male mice Residues of this material Florida, Texas, Purchased - 0 producing hepatomas are known to be persistant California and Max. Inventory - 0 (84) in the field (43). Arizonia. Pesticide residue NCI carcinogenesis tolerance (80) bioassay, positive in Hazardous Waste (80) mice, indefinite in rats (7a) DOT: Hazardous materials table (80) 212 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters RegulationsI Chloropicrin 1975 - Productiog As a fumigant for stored grain Acute: Aquatic Toxicity Rating: OSHA: (Trichloronitro- 5.73 x 10 (43) and other commodities; as a Produces severe LC 96:iO-i ppm (7a) Air methane) fungicide for most soilborne irritation in upper TWA 100 ppb (7a) 76-06-2 pathogenic fungi in crops; as a respiratory passages. Solubility in water at 25°C: Liquid soil insecticide; as a Has strong lacrimatory 1,621 mg/liter (43) ACGIH Recommendation: nematocide; also kills grass properties, produces STE1 300 ppb (7a) seeds in soils. increased sensitivity Vapor pressure at 0°C: after frequent 5.7 mm (43) DOT: In 1975 59% was used on exposures. Potent Poison B (7a) strawberries; 15% on vegetables; skin irritant (5) 15% on stored grain; 10% on EPA: ornamentals; and 1% in Chronic: Pesticide residue forestry applications (43) NCI Carcinogenicity tolerance (80) bioassay was Pesticide use indefinite in mice classification (80) and rats. (7) 213 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _ Regulations_____ Chlorothalonil Only one U.S. company A fungicide. In 1975, Acute: Solubility in water: EPA: (Tetrachloroiso produces it. Amount approximately 63% was used Mouse 0.6 mg/kg (43) Pesticide residue ph thai onit rile) produced is unknown, on peanuts, 17% on vegetable LD :6000 mg/kg tolerance (80) 1897-45-6 but the capacity of crops other than potatoes, Vapor Pressure at 40°C: Solid the plant is 1.10 x 10 9% was used in paints; 6% was Rat less than 0.01 mm (39) FDA: (39) used on potatoes, and 6% was LI) : 10,000 mg/kg Pesticide residue used on lawns and turf. (41) (oral) (39) tolerance (80) 1980 - Imports 3.86 x 10b (39) Chronic: Limited evidence that it is carcinogenic in rats (39). Not a mutagen in bacteria, yeast, fungus and silk worms. (39) 214 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State_____in the U.S. (Ibs./yr.)______Uses______Effects______Parameters______Regulations Coumaphos 1974 - Production Used as a livestock insecticide Acute: Solubility in water: EPA: 56-72-4 3.97 x 10" (43) for cattle grubs, ticks, tlies, Kat insoluble (43) Pesticide residue Solid lice, ectoparasites on sheep, LD : 13 mg/kg (oral) tolerance (80) goats, horses, swine, and poultry, LC :303 mg/m Vapor Pressure at 20°C: Hazardous water and for livestock screwworms. (43) (inhalation) (7a) 1 x 10 nun (43) pollutant design ation & harmful Chronic: quantities (80) Negative in NCI bioassay (7) FDA: Feed premix (80) Positive in cell transformation assay. DOT: (7) Hazardous materials table (80) 215 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations 2,4-D 1975 - Production 75% is used as a selective Acute: Aquatic toxicity rating: OSHA: 94-75-7 5.95 x 10' herbicide for broadleaf weeds Very toxic (43) LC5()96:10-1 ppm (7a) Air „ grains, corn, TWA lOmg/m (7a) - Imports . sorghum, rice, and grazing land; Chronic: Solubility in water at 25°C: 2.95 x 10 13% is used for industrial and A possible teratogen 540 ppm (43) ACGIH Recommendation: commercial use on non-cropland; (24) STEL 20mg/m (7a) - Exports 6% by government agencies on Vapor pressure at 160°C: 1.26 x 10 (43) non-cropland; 6% for home and Passes the placental 0.4 mm (43) EPA: garden use on turf. (43) barrier in pigs (43) Hazardous Waste (54) N.J. Industrial Survey Persistence in soil: Reportable quantites (1978-79): Hydrolyzes by soil (89) Produced - 0 bacteria to acetic acid Pesticide residue Purchased - 1000-5000 and dichlorophenol, both tolerance (80) (84) of which degrade readily Hazardous water (43) pollutant designa tion and harmful quantities (80) DOT: ORM - A (54) NJDEP: Restricted Pesticide (81) FDA: Pesticide residue tolerance (80) Bottled water standard (80) 216 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations DOT 1975 - Production Contact insecticide Acute: Aquatic Toxicity Rating: OSHA: 50-29-3 9.4H x 10 (est.) (43) Rat LC 96: under i ppm (7a) Ai r - Imports I,D -115 mg/kg TWA 1 mg/m (skin) (7) none (oral) (55) Bioaccumulation: - Exports log octanol/water ACGIH Recommendation: 4.88 x 10 (43) Chronic: partition coefficient STEL 3 mg/m (7) IARC - sufficient 3.98-6.19 (8) N.J. Industrial Survey evidence of EPA: Priority (1978-1979): carcinogenicity in Bioconcentration factors Pollutant (54) Produced - 0 mice and rats (42) for DDT range up to 10 Hazardous Waste Purchased - 0 in aquatic systems (8) (54) Max. Inventory - 0 $4 ) No evidence of In 1972, EPA mutagenicity (42) Solubility in water at 25°C: cancelled all uses 1.2-85 ppb (8) of DDT except by the U.S Public Health Vapor Pressure at 25°C: Service, the USDA or 1.9 x 10 mm (8) The military. It's use as a prescrip Persistence: tion drug for Decomposes in soil at a control of body lice rate of 5% per year. (2c) is also permitted Subject to some hydrolysis (55). and/or decomposition in Reportable sunlight (2c). quantities (89) DOT: ORM - A (54) N.IDEP: Prohibited Pesticide (81) 217 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations Diallate Commercial production A pre-emergent herbicide used Acute: Solubility in water at 2 r>°C: EPA: 2303-16-4 in the U.S. has not been principally for the control of High oral toxicity, 14 mg/1 (39) RPAR issued in 1977. Liquid reported since 1975. (39) weeds, like wild oats. The moderate dermal Use currently major uses in U.S. agriculture toxicity. The Vapor Pressure at 25°C: restricted to use by Consumption in U.S. in from 1976-1978 wet'e on sugar toxicity is mainly 1.5 x 10 mm (39) certified applicators 1976-1978 - 3.89 x 10 /yr. beets (71%), flax (10%), lentils to the nervous system wearing protective (39) (11%), and peas (7.8%). (39) (5) clothing. (75) A minor use is as a sprout Reportable inhibitor on potatoes (5). Rat quantities (80) W -.393-1000 mg/kg Hazardous waste (80) (oral) (39) Pesticide residue tolerance (80) Chronic: Limi ted DOT: evidence of carcino- Hazardous materials genicity in mice. (39) table (80) Mutagenic in bacteria and yeast. (7a) Mutagenic in mammalian cell assays. (7a) Mutagenic in Drosophila. (7a) 218 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters __Regulations Diazinon 1975 - Production An insecticide. In 1982, 43% Acute: Solubility in water at 20°C: ACGTH Recommendation: 333-41-5 7.06 x 10" based on was used on tield crops including Kats U.0u4% (43) TLV-TwA 100 ug/m consumption. (43) corn, forage crops including LD :300-850 mg/kg STEL 200 ug/m alfalfa, vegetables, fruit (oral) (7a) Vapor pressure at 20°C: (skin) (7a) Reported to be produced crops, nuts and on livestock; A cholinesterase 4.1 x 1+0 mm (43) in New Jersey (43). 17% was used in industrial and inhibitor (5) EPA: commercial applications to Persistence: Hazardous waste (80) control indoor pests; 11% is used Chronic: Relatively non-persistent Reportable in various applications by NCI carcinogenesis in soils degraded by quantities (89) government agencies; 29% is used bioassay was chemical and biological Pesticide residue for Home and Garden,use on lawns, negative (7) action within two months tolerance (80) turf, ornamentals in homes. (43) of application (43) Hazardous water Positive in cell pollutant design transformation ation & harmful assay. (7) quantities (80) Caused chromosome aberrations in mammalian cell culture (7) 219 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Dichlorvos 1974 - Production Insecticide and anthelminthic for Acute: Aquatic Toxicity Rating: OSHA: 62-73-7 2 x 10 (est.) (29) swine and dogs. It is used in Highly toxic to all LC 96:less than 1 ppm (2c) TWA 100 ppm (skin) Liquid flea collars for pets; in the animals and man via (7a) control of external parasites all routes. (2c) Solubility in water: on livestock; insects in 10 gm/1 (29) EPA: buildings and outdoor areas; In humans inhalation Hazardous Waste (54) insects affecting certain of 1 mg/m caused Vapor pressure at 20°C: Pesticide residue greenhouse crops and insects blood dyscrasis (2c) 1.2 x 10 mm (29) tolerance (80) on harvested tomatoes; and Hazardous water on mushrooms in mushroom Chronic: Persistence: pollutant designa houses. It is also used for Mutagen in bacteria Non-persistent in soils, tion and harmful mosquito and fly control (29). (29) water and biota. (2c) quantities (80) Reportable Mutagen in yeast quantities (89) assays (29) FDA: Caused chromosome Feed premix (80) aberrations in plants Pesticide residue (29) tolerance (80) An experimental teratogen in rats (29) 220 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physicaj_ State_ in the U.S. (Ibs./yr.)______Uses_____ Parameters Regulations , Dicofol 1974 - Productign 55% as an acaricide on cotton; Acute: Solubility in water: EPA: (Kelthane) 2.6 x 10" 20% as an acaricide on citrus Practically insoluble (43) Hazardous Waste (80) 115-32-2 fruits; 20% as an acaricide on Reportable quantites 1976 - Imports , apples and other fruits and nuts; Persistence in soils: (89) 1,0 x 10 (43) 5% as an acaricide on corn and Residues may remain for Pesticide residue on nursery and greenhouse crops. a year or more (43) tolerance (80) N.J. Industrial Survey (43) Chronic: Hazardous water (1978-79): Carcinogenic in mice pollutant designa Produced - 0 , in NCI bioassay (7) tion and harmful Purchased - 1-5 x 10 (84) quantities (80) FDA: Pesticide residue tolerance (80) DOT: Hazardous materials table (80) 221 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Dieldrin Insecticide. Used for soil Acute: Bioaccumulation: OS HA: 60-57-1 treatment for termites. (56) Rat Bioconcentrdtion factors Ai r _ Solid LD :60 mg/kg in various organisms range TWA 250 mg/m (7a) ACGIH Recommendation: Absorbed through the Solubility in water at 25°C: STEL 750 ug/m (7a) skin (90) acts as a 195-200 ppb (8) stimulant of the EPA: central nervous Vapor Pressure at 2p°C: Priority Pollutant system (90) 1.78 to 2.8 x 10 mm (8) (8) Hazardous Waste (54) Chronic: Persistence: Carcinogenic in mice 100% remained in river Use restricted to causing a dose-related water after 8 weeks (2d) subsurface ground increase in liver insertion for tumors (40) 75% was left in soil after termite control (55) 1 year, 40% after 3 years Reportable (2d) quantities (89) National Oil & Hazardous Substances Contingency Plan (80) Pesticide residue tolerance (80) Hazardous water pollutant design ation & harmful quantities (80) 222 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Pliy s i cal__S 1 ate_ _in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ______Regulations Endosulfan 1974 - Production An insecticide; 34% is used on Acute: Bioaccumulation: ACG1H Recommendation: 115-29-7 vegetables other than Irish log ocLanoi/wattfr TWA mg/'ni „ potatoes; 21% is used on Irish Partition STEL 300ug/m (7a) N.J. Industrial Survey potatoes; 15% on apples; 14% on coefficient: (1978-79): tobacco; 9% on other fruits and 3.6 (8) EPA: Produced - 0 nuts; 5% on field crops and other Priority Purchased - 1-5 x 10 (84) crops and other grains; 2% on Chronic: Solubility in water at 20°C: Pollutant (8) soybeans; and less than 1% on and pH 5.5: Hazardous Waste (54) grains; nursery crops and 0.1-0.3 ppm (8) ReporLable quantities greenhouse crops. (43) (89) Vapor pressure at 25°C: Pesticide residue 1 x 10 mm. (8) tolerance (80) Hazardous water Detection in environmental pollutant designa media: tion and harmful Industrial wastewater and quantities.(80) intakes: USEPA - 0.3% (78) DOT: Potable water, raw and Poison B (54) treated: NJDEP (OSR)-A-25/254 NJDEP: B-6/254 (86) Restricted POTWs Pesticide (81) NJDEP (OSR) influent - 1/9 FDA: effluent - 2/9 Pesticide residue sludge - 1/9 (88) tolerance (80) 223 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmenta1 Physical J>ta_te_ _iP._th.e U-S. (Ibs./yr.)______Uses_____ Effects Parameters ____ Reguljj t ions_ Endrin 1975 - Production Insecticide, rodenticide Acute: Aquatic Toxicity Rating: OS1IA: 72-20-8 3 x 10 (43) avicide (43) A skin irritant LC 96:under 1 ppm (7a) Air highly toxic to 100 mg/m (7a) N.J. Industrial Survey birds, fish and man. Bioaccumulation: (1978-1979): log octanol/water EPA: Produced - 0 Rat partition coefficient Priority Pollutant Purchased - 0 •:ll mg/kg (oral) 5.6 (calc.) (8) (8) Max. Inventory - 0 (84) Hazardous Waste (54) Chronic: Concentration factors of Restricted use as a 3 4 Teratogenic in mice 10 and 10 have been pesticide (55) and hamsters (43) measured. (8) Reportable quantities (89) Solubility in water at 25°C: National Oil & 0.25-0.26 ppm (8) Hazardous Substances Contingency Plan (80) Vapor Pressure at 25°C: Pesticide residue 2 x 10 mm (8) tolerance (80) Hazardous water pollutant design ation & harmful quantities (80) Worker protection for agricultural pesticides (80) DOT: Poison B (54) NJDEP: Prohibited Pesticide (81) USDA: Pesticide restricted use (80) FI)A: Bottled water 224 standard (80) Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters lat ioris_ Fenthion 1974 - Productiog In 1974, about 40% was applied Acute: Solubility in water at room ACGIH Recommendation: 55-38-9 2.01 x 1 225 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ______Regulations Fluometuron One company is believed A herbicide, which is used to Acute: Solubility in water at 25°C: EPA: 2164-17-2 to be producing it currently control broadleaf weeds and Rat 80 ppm (43) Pesticide residue Solid in unknown amounts. grasses in cotton. The area of LD -.8900 nig/kg tolerance (80) largest use in the U.S. is the (oral) Vapor Pressure at 20DC: 1980 - Imports 1103 (39) Mississippi delta. (39) Mouse, male 5 x 10 mm (43) FDA: LD -.900 mg/kg Pesticide residue 1978 - Total useage (oral) (39) tolerance (80) 2.87 x 10 (39) Chronic: Data inadequate to evaluate carcinogenicity (39) NCI carcinogenesis bioassay was positive in mice, negative in rats. (7) Commercial formulation was mutagenic in bacteria. (39) Mutagenic in plants (39) Experiment with Pesticide of unknown purity caused inhibition of DNA synthesis in mice (39) 226 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Heptachlor 1975 - Productign Insecticide used in soil Acute: Aquatic Toxicity Rating: OS HA: (/b-44-B) 2.0 x 10 (43) treatment for termites (56) Toxic by ingestion, LC, :96-under 1 ppm (7a) Air Solid inhalation and skin TWA 500ug/m (7a) absorption (6) Bioaccumulation : Positive potential for ACGIH Recommendation: Chronic: accumulation (2b) STEL 2 mg/m (7a) Carcinogenic in mice (29) Solubility in water at 25°C: EPA: 0.056 - 0.180 ppm (8) Priori ty Pollutant (8) Vapor pressure at 25°C: Hazardous Waste (54) 3 x 10" mm (8) Reportable quantities (89) Persistent: National Oil & Persistent in soils (2b) Hazardous Substances Contingency Plan Detection in environmental (80) media: Pesticide residue Industrial wastewaters and tolerance (80) intakes: Hazardous water USEPA - 0.24% (78) pollutant designa Groundwater: tion and harmful NJDEP (OSR) - 8.5% (85) quantities (54) Potable water, raw and treated: DOT: NJDEP (OSR) - 9/259 (86) ORM - E (54) POTWs NJDEP (OSR) NJDEP: influents - 0/9 Hetricted effluents - 1/9 Pesticide (81) sludge - 1/9 (88) 227 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Lindane No reported production since Insecticide is used for seed Acute: Aquatic Toxicity Rating: OS HA: (gamma -BUG) 1976 in U.S. (56) treatment and to control various Skin irritant and LC 96:under 1 ppm (7a) Air „ 58-89-9 wood-inhabiting insects (56) allergen (4a) TWA 500 mg/m (7a) Solid Imports - 106 (56) Bioaccumulation: Highly toxic (6) log octanol/water ACGIH Recommendation: N.J. Industrial Survey partition coefficient: STE1. 1500ug/m (skin) (1978-79): Chroni c: 3.72 (8) (7a) Produced - 0 , Carcinogenic in mice Slightly bioaccumulated Purchased - 5-10 x 10 (84) (29) in organisms (8) EPA: Priority Induces chromosome Solubility in water at 25°C: Pollutant (8) aberrations, 6.8 - 7.8 (8) Hazardous Waste (54) polyploidy and mitotic National Oil and arrest in various Vapor pressure at 20°C: Hazardous Substances plant systems (43) 3.3-,„._„,__ to 2.1 x ,„-*10 (8)^^ Contingency Plan (80) Reportable quantities Induces chromatid Detection in environmental (89) breaks in human media: Pe s t i c i de re s i due lympliocyctes iji Potable water, raw and tolerance (80) vitro (29) treated: Hazardous Water NJDEP (OSR) - 11/254 (86) pollutant designa POTWs tion and harmful NJDEP (OSR) quantities (80) influents - 2/9 effluents - 3/9 DOT: sludge - 1/9 (88) ORM - A (54) NJDEP: Restricted Pesticide (81) FDA: Bottled water standard (80) 228 17 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Env i ronmenta1 Phy s ica I State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations Maneb 1972 - Production Agricultural fungicide (31). Acute: Solubility in water: EPA: 12427-38-2 1.2 x 10' Used to control early and late Moderately (43) RPAR issued in Solid blight of potato and tomato, 1977. (55) 1972 - Exports downy mildew and anthracnose on a Pesticide residue 4.4 x 10 (21) number of vegetables and so called tolerance (80) "rot" diseases of such fruits as Chronic: apricots, peaches, and grapes. Embryotoxic in rats. DOT: It is also used for seed (7) Hazardous materials treatment of small grains, such table (80) as wheat (21). Teratogenic in rats. (21) Decline in ferlitity in rats (21) 229 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr. )______Uses_____ Effects Parameters ______Regulations Methoxychlor 1975 - Production An insecticide: Used 34% as an Acute: Solubility in water: OSHA: 72-43-5 5.5 x 10 (43) insecticide on beef cattle, 29% Practically insoluble (14) TWA 15 mg/m (7a) as an insecticide on dairy cattle; N.J. Industrial Survey 16% on alfalfa; 3% on corn; 3% on Chemical Reactivity: ACGIH Recommendation: (1978-79): peanuts; 2% on assorted fruits Resistant to heat and TWA lOmg/m (7a) Produced - 0 and nuts; 4% on other field oxidation (29) Purchased - 1-5 x 10 (84) crops; 3% on other livestock; Chronic: EPA: 3% for non-crop, non-livestock Positive in cell Hazardous Waste (80) uses; 3% for miscellaneous transformation assay Pesticide residue uses. (43) (43) tolerance (80) Reportable quantities Non-mutagenic in (89) bacterial assay (43) Hazardous water pollutant designa Embryotoxic in rats tion and harmful (7, 29) quantities (80) DOT: OEM - E (54) FDA: Bottled water standard (80) 230 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Mirex No current production in Insecticide used to control Acute: Solubility in water: EPA: 11QC „ QC ,-C 11 C //. Q\ western harvest ants, yellow Rats Insoluble (2 jackets, and imported fire ants. LD: 600-740 mg/kg registered products N.J. Industrial Survey (43) (oral) (29) Vapor Pressure at 25°C: containing mirex (1978-1979): were effectively Produced - 0 Chronic: cancelled. All Purchased - 0 Sufficient evidence Bioaccumulation: existing stock in Max. Inventory - 0 (84) of carcinogenicity High lipid to water U.S. will not be in mice and rats parition coefficient sold, distributed (29) Bioconcentrates or used after June several thousand fold 1978 (55) Embryotoxic (29) in food chains (43) Teratogenic (29) Persistent: Highly persistent in Negative in dominant air, water, and soil. lethal assay in mice (43) (29) Degrades to chlordecone (Kepone) (43) 231 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental i cal State in the U.S. (Ibs./yr.)______Uses______Effects Parameters kl°!L?_ l-Naphthyl-2- Production has not been Rodenticide for the control of Acute: Aquatic Toxicity Rating: OSIIA: thiourea reported in the U.S. since adult Norway rats. It was widely Rat LC 96:10-1 ppm (7a) Ai r „ (ANTU) 1953. (39) used in the 1940s, but has sub LD -6-8 mg/kg TWA 300 ug/m (7a) 86-88-4 sequently been replaced by other (oral) (7a) Solubility in water Solid 1975 - Imports compounds in most countries. (39) 600 mg/1 for technical ACGTH Recommendation: 1987 (39) Chronic: grade (43) STEL 900 ug/m The available (skin) (7a) carcinogen!city experiments were EPA: inadequate (39) Hazardous Waste (39) Reportable Mutagen in quantities (89) bacteria (39) DOT: Positive in cell Hazardous materials transformation (39) assay (39) NJDEP: Restricted Pesticide (81) 232 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Nitrofen Produced by one U.S. company Used as a pre-and postemergence Acute: Solubility in water at 25°C: EPA: (2,4-Dichloro- in unknown amount. herbicide in agricultural Rats 0.7-1.2 mg/1 (39) Pesticide residue phenyl- Estimated usage in 1978. applications. In 1978, 90% was LD :740 mg/kg (oral) tolerance (80) 4-nitrophenyl 9.04 x 1(T (39) used on vegetables and the Mice: Vapor pressure at 40°C: ether) remainder on sugar beets (39) LD50:450 mg/kg 8 x 10" 6 mm (39) 1836-75-5 1968 - Imports , Solid 2.2 x 10 (39) Irritant to eyes, skin and respiratory tract 1980 - No exports (39) (43) Chronic: Animal carcinogen (39) Teratogenic to mice and rats when given at very high doses. (39) Decreased neonatal and postnatal viability in three-generation reproductive study in rats (39) Mutagenic in bacteria (7) Positive in cell trans formation assay (7) 233 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regul ations Parathion 1974 - Production ' An insecticide and an acaricide. Acute: Aquatic Toxicity Rating: OSI1A: 56-38-2 1.04 x 10 99% for agriculture products; 27% Highly toxic to LC 96:under 1 ppm (7a) Air on cotton, 27% on grains; 16% on mammals TWA 100 ug/m (7a) 1975 - Imports - 0 fruits and nuts; 14% corn; 16% Rats Solubility in water at 25°C: for other crops (43) LD -13mg/kg (oral) 24 ppm (43) ACGIH Recommendation: 1975 - Exports , ar STEL 300 ug/m (7a) 6.39 x 10 Persistence: (including methyl Very toxic to birds Persists in river water N10SH Recommendation: parathion) (43) Wild Birds for four weeks (43) Air LD5Q 2mg/kg (oral) (7) TWA 50 ug/m (7a) N.J. Industrial Survey Bioaccumulation: (1978-79): Chronic: Unlikely that it will EPA: Produced - 0 NCI Carcinogenesis Bioaccumulate or Hazardous Waste (54) Purchased - 1-5 x 10 (84) bioassay was Biomagnify (43) National Oil and indefintie in rats, Hazardous Substances negative in mice (7) Contingency Plan (80) Pesticide residue tolerance (80) Pesticide use classification (80) Reportable quantities (89) Hazardous water pollutant designa tion and harmful quantities (80) Worker protection for agricultural pesticides (80) DOT: Poison B (54) NJDEP: Restricted Pesticide (81) 234 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phys i ca 1 State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations______ Propoxur 1974 - Productiofi In 1974, over 50% as an Acute: Solubility in water at 20°C: ACGIH Recommendatiqn: i14-26-i 3.09 x 10 (est.) insecticide tor mosquitoes in Rat 2000 mg/1 (5) TI,V-TWA 500 us/nT" Solid (43) outdoor areas. The rest is used LD 1300mg/hg (oral) STEL 2000ug/m (7a) as an Insecticide for flies on (551° Vapor pressure at 120°C: agricultural premises, for fleas Wild Birds 1 x 10 mm (43) N.1DEP: and ticks on pets, as an LD :4 mg/kg (7a) Rest ricted insecticide on lawns and turf, Cholinesterase Pesticide (81) for ants on flowering plants, inhibiter (43) and an insecticide in dwellings and public facilities. (43) Chronic: Mutagen in bacteria and yeast (7) Mutagen in dominant lethal assay in rats via oral route (7) 235 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Quintozene 1971 - Production A fungicide used for seed and Acute: Solubility in water: EPA: (PCNB) 2.09 x 10 soil treatment. (14) Practically insoluble (14) Hazardous Waste (54) (Peritachloro- Pesticide residue ni trobenzene) 1969 - Imports Vapor pressure at 25°C: tolerance (80) 82-68-8 1.32 x 10 (14) Chronic: 1.33 x 10 mm (14) Reportable Carcinogenic in mice quantities (89) N.J. Industrial Survey (14) Persistence: (1978-79): Highly stable in soil. DOT: Production - 0 Mutagen in bacteria Hazardous materials Purchased - 0 and yeast (7) Stable in Sunlight (43) table (80) Maximum Inventory - 0 (84) 236 Substance Name (Synonym) Amount Produced Ma j o r CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations Strobane N.J. Industrial Survey Agricultural insecticide and a Acute: Vapor pressure: EPA: (Terpene (1978-1979): mothproofing agent. (14) Rat 3 x 10"' mm (14) In 1976, all polychlorinates) Produced - 0 LD:200-250 mg/kg products containing 8001-50-1 Purchased - 0 (oral) (90) strobane were Max. Inventory - 0 (84) subject to voluntary Chronic: cancellation. (55) Produced hepatomas Pesticide residue in mice via oral tolerance (80) route (14) NJDEP: Prohibited Pesticide (81) 237 41 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _ Regulations Sulfallate Only one U.S. Company has Used as a herbicide in Acute: Solubility in water at 25°C: EFA: 95-06-7 produced it, that company agricultural applications. Rat 92 mg/1 (39) Pesticide residue Oil is believed to have stopped (39) LD :850 mg/kg tolerance (80) 50 production in 1981. (39) Used essentially 100% for (oral) (39) Vapor Pressure at 20° C: vegetables (43) 2.2 x 10 mm (39) Chronic: Sufficient evidence of carcinogenic!ty in rats and mice (39) Mutagenic in bacteria and fungus. (39) 238 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses______Effects Parameters Regulations 2,4,5-T October 1983 - Sole U.S. A herbicide. In 1979, EPA Acute: Aquatic Toxicity Rating: OSHA: (2,4,5-JTrichloro- producer ceased production. suspended the registration for Highly toxic, readily LC5()96:10-1 ppm (7a) Air phenoxy] acetic all products containing 2,4,5-T absorbed via inhal TWA lOmg/m (7a) acid) N.J. Industrial Survey except on rice, rangeland and ation and ingestion, Solubility in water at 26°C: 93-76-5 (1978-79): non-crop uses. slowly via skin 280 mg/1 (43) ACGIH Recommendation: Produced - 0 absorption (2d) STEL 20 mg/m (7a) Purchased - less than 1000 Non-crop uses include uses at Max. Inventory - less airports; fences; hedgerows; Chronic: EPA: than 1000. (84) lumber yards, refineries, Inadequately tested Hazardous Waste (54) non-food crop areas; storage for carciriogenicity Hazardous water areas; wastelands; vacant lots, (24) pollutant designa tank farms; industrial sites. tion and harmful (55) Teratogen in rats via quantities (80) oral route; in mice via Reportable oral and subcutaneous quantities (89) route, and in hamsters via oral route (24) DOT: Hazardous materials Embryotoxic (24) table (80) 239 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations Tetraclllorvinphos 1978 - Production An insecticide, used to control Acute: Solubility in water at 20°C: EPA: 961-11-5 9.92 x 10 insects on livestock and poultry. Cholinesterase 11 mg/1 (39) Pesticide residue Solid by one company (39) It is believed to be used to inhibitor (5) tolerance (80) control adult flies and as a Rats larvacide (39). Male FDA: LD5() :400mg/kg (oral) Pesticide residue Females tolerance (80) LD :9100 mg/kg (oral) Chronic: Limited evidence of carcinogenicity in animals (39) Not mutagenic in bacteria (39) A weak inducer of chromosomal aberrations in mammalian cell cultures. (39) 240 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Toxaphene 1975 - Productiqn An insecticide, used 76% on Acute: Aquatic Toxicology Rating: OSHA: (8001-35-2) 3.7 x 10' (43) cotton; 4% on soy beans; 3% on Skin irritant in LC: under 1 ppm (7a) TWA 500 ug/ (skin) (7a) N.J. Industrial Survey potatoes, and other vegetables; Highly toxic, via Bioaccumulation: (1978-1979) , 2% on wheat, alfalfa, other oral and inter- log octanol/water ACGIH Recommendation: Produced - 5-10 x 10 grains and field crops, fruits, peri tonal route, partition coefficient STEL 1 mg/m (skin) Purchased - 5-10 x 10 (84) nuts and ornamentals; 12% to moderately toxic 3.3 (8) (7a) control miscellaneous livestock via skin and pests. (43) inhalation (3b) Tends to accumulate in EPA: biological as well as Priority Pollutant Humans non-biological material. (8) LD :40 mg/kg (3b) Hazardous Waste (54) (oral) (3b) Pesticide residue Solubility in water at 25°C: tolerance (80) Chronic: 0.5-0.74 ppm (8) Reportable Animal carcinogen quantities (89) in mice and rats (29) Vapor Pressure at 25°C: Hazardous water 0.2-0.4 mm (8) pollutant designa Suspected human tion and harmful carcinogen (29) Detection in environmental quantities (80) media: Mutagen in Industrial wastewater and DOT: bacteria (29) intakes: IIRM - A (54) USEPA - 0.15% (78) Chromsome aberrations Potable water, raw and NJDEP: observed in exposed treated: Restricted workers (29) NJDEP (OSR) - 0/254 (86) Pesticide (81) FDA: Bottled water standard (80) Pesticide residue tolerance (80) USDA: Pesticide restricted use (80) 241 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physi c al State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ____ Regulations Tri chlorf on It is not produced An insecticide. In 1978, 40% Acute: Solubility in water at 25' C: EPA: 52-68-6 commercially in U.S., on miscellaneous field crops, Allergic dematitis 154,000 mg/1 (43) RPAR issued in 1979. Solid but is believed to be 20% on forests, 10% on cotton, (39) (54) imported. (39) and 10% on vegetables. The Rats Vapor Pressure at 20° Hazardous Waste (80) forestry usage included LD :400-650 rag/kg 7.8 x 10 irai i (43) Reportable 3*J -I \ 1978 - Useage , applications to control outbreaks ( oral) quantities (89) 1.00 x 10 (39) of gypsy moth and eastern spruce Mouse Pesticide residue budworm. It is also used to LI) :630-800 mg/kg tolerance (80) control botfly larvae and worms (oral) (39) Hazardous water in horses and ectoparasites in pollutant design beef cattle. (39) Chronic: ation & harmful Available data is inade quantities (80) quate evaluate carcino- genicity (39). FDA: Pesticide residue NCI carcinogenesis tolerance (80) bioassay in progress (7) Trichlorfon or its degradation product is mutagenic in bacteria, mammalian cells and mice. (39) Teratogenic in mice, rats, and hamsters at doses which reduced maternal body weight. (39) 242 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters __ Regulations Trifluralin 1975 - Production In 1972, it was used as a Acute: Solubility in water: EPA: 1582-09-8 2.17 x 10' selective herbicide for grasses Mouse 24 mg/1 (43) Determined that it based on and broadleaf weeds, of which LD :5000 mg/kg can be contaminated consumption (43) 52% is used on soybeans, 40% on (oral) (7a) Vapor Pressure at 29.5°C: with the carcinogenic cotton, 8% on other field crops, 1.99 x 10 mm (43) contaminant N-Nitroso 1972 - Exports , vegetables, fruit, nuts, Chronic: di-N-propylamine 4.01 x 10 (43) nursery, crops, alfalfa, pasture Positive in NCI (NDPA). land, and summer fallow; and 2% carcinogenesis Level of NDPA should as a selective herbicide in other bioassay in mice; be less than 1 ppm applications. (43) negative in rats (7) (43) PDA: Pesticide residue tolerance (80) 243 34 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental PhysjlcaJ_ State in the U.S. (Ibs./yr.)______Uses______Effects Parameters Zineb 1975 - Production In 1975, it was used as a Acute: Solubility in water at room EPA: 12122-67-7 3.5 x 10 b (43) fungicide for apples (55%), as Irritant to eyes, temperature: RPAR issued (55) Solid by two U.S. a fungicide for home and garden, skin and mucous insoluble (21) Pesticide residue companies (21) lawn and turf (17%), and as a membranes (64b) tolerance (80) fungicide for vegetables (14%) Vapor Pressure at 25°C: (43) Rat negligible (21) LD :52 mg/kg (oral) (64K) Chronic: Suspected animal carcinogen (64b) Caused chromosome aberrations in animals. (43) Teratogenic in mice and rats at very high concentrations (64b) 244 PHENOLS Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters _ Regulations Catechol 1977 - One company reported Major use is the synthesis of Acute: Solubility in water: ACGIH Recommendation: (pyrocatechol) production of this chemical 4-t-butylcatecho] which is a Skin contact causes Soluble in 2.3 parts of TWA 5 ppm (54) (1,2-dihydroxy- for captive use, a second polymerization inhibitor in eczematous dermatitis water. (43) benzetie) company reportedly produces styrene. It is also used as an (64a) More toxic than 120-80-9 it on demand. (24) antioxidant, in electrosensitive phenol except by Vapor pressure at 118.3°C: Solid copying papers, in the synthesis inhalation (64a) 10 mm (43). 1975 - Imports . of pharmaceuticals and pesticides, An eye and skin 3.4 x 10 (43) in photography and in rubber irritant (64a) compounding aids. Other important 1970 - Use in the U.S. was uses are as a photographic Chronic: greater than and in rubber compounding aids. A mutagen in 1.2 x 10 (24) Other important uses are as a bacterial and photographic developing agent, as mammalian eel 1 as an oxidation base in fur and assays. (7) a chemical intermediate for a A cocarcinogen rubber accelerator, the in mice (1,24) di-ortho-tolylquanidine salt of dicatechol borate. (24) 245 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Env i ronmenta1 Pliysjj^aJ_State in the U.S. (Ibs./yr.)______Uses______Effects Parameters ___ Regulations _ 4-Chloro-m-cresol Used as an external germicide Acute: Bioaccuraulation: EPA: (p-chloro-m-cresol) and as a preservative for glues, Rat: log octanol/water Priority Pollutant (3-methyl-4- paints, inks, textiles and leather LD 500 rag/kg partition coefficient: (8) chlorophenol) goods. It is used as a toral) (7a) 2.95 (8) Hazardous Waste (8) 59-50-7 preservative in cosmetics. (54) Reportable Solid Solubility in water at 20°C: quantities (89) 3,850 mg/1 (8) Can be formed during the FDA: chlorination of effluents Kood-contact from electric power component (80) generating plants and domestic sewage treatment DOT: facilities (54). Hazardous materials table (80) Detection in environmental media: Industrial wastewaters and intakes: USEPA - 1.8% (78) 246 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations 2-Chlorophenol Probably greater than Solvent for polyester fibers; Acute: Bioaccumulation: EPA: (o-chlorophenol) 1,000 (43) component of disinfectant Strong irritant Log octanol/wate.r Priority Pollutant 95-57-8 formulations; antiseptic; soil to skin. Toxic by partition coefficient: (8) Liquid N.J. Industrial Survey sterilant, a chemical skin absorption, 2.17 (8) Hazardous Waste (54) (1978-79): intermediate in manufacture of inhalation, or Reportable Produced - 0 dyes. (43) ingestion. (6) Solubility in water at 20°C: quantities (89) Purchase - 1,000-5,000/yr. 28,500 rag/liter (8) (84) Chronic: DOT: Cocarcinogen in Vapor pressure at 20°C: Label should bear mice. (64a) 2.2 mm (8) (X). (54) Detection in environmental media : industrial wastewater and intakes: USEPA - 2.1% (78) Potable water NJ (OSR) - 5/500 (82) POTWS NJDEP (OSR) influents - 0/9 effluents - 0/9 sludge - 0/9 (88) 247 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phys ica1 State iS_lh?. U-S. (Xbs./yr.)______Uses_____ Effects Parameters __ Regulations______ 2,4-Dichlorophenol 1975 - Production Chemical intermediate in the Acute: Bioaccumulation: EPA: (DCP) - greater than 1,000 manufacture of herbicides, Strong irritant to Log octanol/water Priority Pollutant 120-83-2 fungicides, bactericide and tissue; moderately partition coefficient: (8) Solid - Imports , germicides. (43) toxic by ingestion (6) 2.75 (8) Hazardous Waste (54) 6.7 x 10 (43) Plant regulator Chronic: Solubility in water at 20°C: residue tolerances N.J. Industrial Survey Cocarcinogen in 4,500 mg/liter (8) (80) (1978-79): mice. (43) Reportable Produced - 0 Vapor pressure at 20°C: quantities (89) Purchased - 1000-5000 (84) 0.12 mm (8) DOT: Detection in environmental Hazardous materials media: table (80) Industrial wastewater and intakes: USEPA - 3.0% (78) NJDEP (OSR) - 1/29 (82) Potable water, raw and treated: NJUEP (OSR) - 14/240 (86) POTWS NJDEP (OSR) influents - 0/9 effluents - 0/9 sludge - 0/9 (88) 248 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State _LS_the U.S. (Ibs./yr. )______Uses______Effects Parameters Re gulations 2,4-Dimethylphenol 1979 - Production As a disinfectant; in the Acute: Bioaccumulation: EPA: (m-xylenol) 14.5 x 10' manufacture of phenolic resins; Toxic by ingestion Log octanol/water Priority Pollutant 105-67-9 as a solvent; as a chemical and skin absorption partition coefficient: (8) Solid - Imports ^ intermediate in synthesis of (6) 2.50 (8) Reportable 4.1 x 10 (43) phosphate esters, and phenolic quantities (89) antioxidants. (43) Chronic: Solubility in water: Hazardous Waste (54) N.J. Industrial Survey Appears to be a slightly soluble (6) (1978-79): cocarcinogen, but its DOT: Produced - 5-10 x 10^ role as a primary Vapor pressure at 20°C: Hazardous materials Purchased - 1-5 x 10 cancer-producing agent 0.06 mm (8) table (80) (84) is uncertain. (43) Detection in environmental media: Industrial wastewaters and intakes: USEPA - 5.0% (78) NJDEP (OSR) - 2/29 (82) Potable water, raw and treated: NJDEP (OSR) - 2/240 (86) POTWS NJDEP (OSR) influent - 1/9 effluent - 0/9 sludge - 0/9 (88) 249 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phjrsical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ons 4,6-Di nitro-o- N.J. Industrial Survey Dormant ovicidal spray for Acute: Aquatic Toxicity Rating: OSHA: rresol (1978-79): fruit trees; herbicide; Extremely toxic via LC5Q96:10-1 ppm (7) T1.V-TWA 200 ug/m (DNOC, Elgetol, Produced - 0 insecticide. (6) inhalation, oral and STEL 600 ug/m Sinox) Purchased - 0 (84) dermal exposure (3e) Bioaccumulation: (skin) (7) 534-52-1 Humans: Log octanol/water Solid TC :1 mg/m- partition coefficient: EPA: TXFTCNS (7) 2.85 (8) Priority Pollutant (8) Chronic: Solubility in water at 20°C: Hazardous Waste (54) A cumulative poison (5) 100 ppm (8) Pesticide residue tolerance (80) Mutagen in bacteria Vapor pressure at 25°C: Reportable and Drosophila (7) 1.05 x 10 mm (43) quantities (89) Detection in environmental DOT: media: Poison (54) Industrial wastewates and intakes: NJDEP: USEPA -1.1% (78) Restricted NJDEP (OSR) - 0/29 (82) Pesticide (81) Potable water, raw and treated: NJDEP (OSR) - 6/241 (86) POTWS influents - 0/9 effluents - 0/9 sludge - 0/9 (88) 250 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (ibs./yr.) Uses Effects Parameters 2 ,4-Uinitroplieriol 1975 - Probably greater Manufacture of diaminophenol; Acute: Aquatic Toxicity Rating: EPA: 51-28-5 than 1,000. (43) preserving timber; manufacture An experimental skin i,C^_96:IO-l ppm (7) Priority Pollutant Solid of dyes (C.I. sulfur black 1 and and eye irritant. (8) N.J. Industrial Survey 2); manufacture of photochemicals Orally it is highly Bioaccumulation: Hazardous Waste (54) (1978-79): and explosives', as an acid-base toxic to rats, mice, Log octanol/water Reportable Produced - 0 indicator (84) . guinea pigs and wild partition coefficient: quantities (89) Purchased - 0 birds. (3b) 1.53 (8) Hazardous water Maximum Inventory - Is phytotoxic and pollutant design 1000-5000 (84) an allergen. (3b) Solubility in water at 18°C: ation (80) 5,600 mg/liter (8) Chronic: DOT: Detection in environmental Dry - explosive, media: poison Industrial wastewater and Solution - Poison B intakes: (54) USF.PA - 1.7% (78) NJDEP (OSR) - 1/29 (82) Potable water, raw and treated: NJOSR - 1/500 (86) POTWS NJDEP (OSR) influents - 0/9 effluents - 0/9 sludge - 0/9 (88) 251 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmenta1 Physical StaJ.e _in_the U-S. (Ibs./yr.)______Uses______Effects Parameters _ Regulations Hydroquinone 1975 - Production 1.65 x 10' Used as a developer in black Acute: Solubility in water at 25°C: OSHA: (1 ,4-dihydroxy- of technical grade by and white photography; used as It is highly toxic to 7% (64a) TWA 2 mg/m (7a) benzene) three companies. (24) an antioxidant and polymerization humans via oral route. 123-31-9 inhibitor; used as a chemical It is a powerful Persistence: ACUIH Recommendation: 1974 - Imports 1103 (24) intermediate and as a laboratory allergen and a strong Biodegrades at moderate STEL 4 mg/m (7a) reagent. (24) irritant. (3b) rate once bacteria becomes acclimated (3b) NIOSH Recommendation: Chronic: CL 2 mg/m /15 min Data insufficient to Vapor pressure at 132.4°C: (7a) assess carcinogenicity 1 mm (3b) (24). Currently being FDA: tested in NCI Food-contact carcinogenesis bioassay component (80) (7). Mutagenic in bacterial and mammalian DOT: cell assays (7). Hazardous materials table (80) 252 Substance Name (Synonym) Amount Produced Major CAS Number. Imported, Exported Commercial Health Environmental Physical SJtate in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters __ Regulations 2-Nitrophenol 1975 - Production Chemical intermediate for o- Acute: Bioaccumulation: EPA: (o-nitrophenol) Probably greater than aminophenol and o-nitroanisole Toxic by Log octanol/water Priority Pollutant 88-75-5 1,000 dye stuffs; indicator in chemical ingestion (6) partition coefficient: (8) Solid analysis. (43) 1.76 (8) Hazardous Waste (54) - Imports greater than Reportable 4.87 x 10 (43) Solubility in water at 20°C: quantities (89) 2,100 ppm (8) Hazardous water N.J. Industrial Survey pollutant design (1978-79): Vapor pressure at 49.3°C: ation (80) Produced - 0 1.0 mm (8) Purchased - 0 DOT: Maximum inventory Detection in environmental ORM - E (54) 1-5 x 10 (84) media: Industrial wastewaters and intakes: USEPA - 2.2% (78) NJDEP - (OSR) - 1/29 (82) Potable water: NJDEP (OSR) - 4/240 (86) POTWs NJDEP (OSR) influents - 0/9 effluents - 0/9 sludge - 0/9 (88) 253 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phys^ij:al_State _ in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ____Regulations 4-Nitrophenol 1975 - Production 87% as a chemical intermediate Acute: Bioaccumulation; EPA: (p-nitrophenol ) Probably greater than for methyl and ethyl parathion; Toxic by ingestion Log octanol/water Priority Pollutant 100-02-7 2,000. as an intermediate for azo and Rats: LD •350 mg/kg partition coeffici 1.91 (8) Solid sulfur dyes, for N-acetyl-p- (oral) Hazardous Waste - Imports , aminophenol, for leather Mice: LD :467 mg/kg Solubility in water at 20°C: (54) 3.18 x 10 (43) preservative, as an indicator. 16,000 ppm (8) Reportable (43) quantities (89) N.J. Industrial Survey Chronic: Vapor pressure at 146°C: Pesticide residue (1978-79): Mutagen in bacterial 2.2 mm (8) tolerance (80) Produced - 0 , and mammalian cell Hazardous water Purchased - 1-5 x 10 /yr. assays. (7) Detection in environmental pollution design (84) medi a: ation (80) Industrial wastewaters and intakes: DOT: USEPA - 2.1% (78) ORM - E (54) NJDEP (OSR) - 1/29 (82) Potable water, raw and treated: NJUEP (OSR) - 2/240 (86) POTWS NJDEP (OSR) influents - 0/9 effluents - 0/9 sludge - 0/9 (88) 254 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental I'_hY s_i (al State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _ Regulations Pentachlorophenol 1975 - Production 78% as wood preservative; 12% Acute: Bioaccumulation: OSI1A: (PCP) 3.9 x 10 tor pentachlorophenol salt; 6% Highly toxic by Log octanol/water Air: 87-86-5 as waterproofing agent; 3% for ingestion, inhalation partition coefficient TLV-TWA 500 ug/mJ Solid 1974 - Imports , termite treatment; 1% as and skin absorption 5.01 (8) STEI, 1,500 ug/m 11.9 x 10 (43) herbicide. (43) The salt of PCP (5). Bioconcentration of 30 to (skin) (7) is used as a wood preservative; Humans: 1,000 (8) N.J. Industrial Survey as a fungicide in water-based LD -29 rag/kg (oral) EPA: (1978-79): latex points; as a herbicide TD n-196 rag/kg (oral) Solubility in water at 20°C: Priority Pollutant Produced - 0 , and as a slimicide. (29) TXF: CNS (7a) 14 ppm (8) (8) Purchased - 5-10 x 10 Hazardous Waste (54) (84) Chronic: Vapor pressure at 20°C: RPAR Issued in 1978 Not carcinogenic (64a) 1.1 x 10~* (8) (54) Some evidence of Reportable embryotoxicity in Persistence: quantities (89) rats. (64a) Not persistent in aqueous National Oil & medium, but is sorbed by Hazardous Substances organic matter in soils Contingency Plan (80) and sediments (8) Hazardous water pollution design ation & harmful quantities (80) DOT: ORM - E (54) NJDEP: Restricted Pesticide (81) FDA: Wood preservative (80) 255 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Physical State^ in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _ „ „ Regulations______ Phenol 1975 - Production 41% of manufacture of phenolic Acute: Aquatic Toxicity Rating: OSI1A: 108-95-2 17.5 x 10 resins; 17% for prep, of Strong irritant to LC 96:100-10 ppm (7) TLV-TWA 5 ppm Solid caprolactam; 10% for prep, of tissue. Toxic by STEI, 10 ppm (skin) - Imports 2 X 10 bisphenol A; 3% for prep, of ingestion, inhalation Bioaccumati on: (7) adipic acid; 3% for prep, of and skin absorption. Log octanol/water - Exports 5.1 x 10 7 (43) salicylic acid; 2% for prep, of (6) partition coefficient; EPA: plasticizers; 2% for prep, of 1.46 (8) Priority Pollutant N.J. Industrial Survey nonylphenol; 1% for synthesis of Chronic: (8) (1978-79): 5 2,4-D; 1% for synthesis of PCP; Tumorigenic in mice Solubility in water at 25°C: Hazardous Waste (54) Produced - 1-5 x 10 /yr 2% for synthesis of other chloro- (64a) Negative in NCI 93,000 mg/1 (8) Reportable Purchased l-5x 10 /yr (84) phenols; 16% for misc. carcinogenesis bioassay quantities (89) applications including use as a on mice and rats (7) Vapor pressure at 20°C: Oroundwater quality solvent in the petroleum A mutagen in bacterial 0.53 mm (8) (80) industry. (43 ) and mammaliam cell National Oil & assays (7). Atmospheric residence time: Hazardous Substances A promotor in two 0.6 days (44) Contingency Plan (80) stage carcinogensis Pesticide residue assay (64a) tolerance (80) Hazardous water pollutant design ation & harmful quantities (80) DOT: Poison B (54) FDA: Bottled water standard (80) Food contact component (80) Poison (80) Animal use warning statements (80) CPSC: Ubeling (80) 256 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phyjuca \ Stale in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters 2-Phenylphenol Produced by only one U.S. Used as a fungicide and Acute: Solubility in water at 25°C: EPA: (o-Phenylphenol antibacterial agent. T5~ *- -, n,., (2-Biphenylol) Agricultural use is believed to LD50 -.2700 rag/kg tolerance (80) 90-43-7 1979 - Imports be largely in post-harvest (oral) Vapor Pressure at 140°C: Solid 1.50 x 10 treatment of citrus. (43) Mouse 7 mm (39) PDA: Sodium salt Industrially, it is used as a LD :2000 mg/kg Food-contact 132-27-4 1978 - Useage for component of hard-surface (oral) (39) component (80) industrial purposes cleaners, metal-working fluids, in U.S. , automotive gaskets, finished Chronic: 4.85 x 10 of leather, paints and polishes. The current data for compound and It is also used in ceramic the free base was sodium salt. (39) glazes, clay slips, and phenolic inadequate to assess disinfectants used in hospitals, carciiiogenicity. (39) households and industry. (39) Limited evidence that the sodium salt was carcinogenic in rats. (39) A variety of mutagenic tests have not demon strated any unambiguous mutagenic or DNA damaging effect. (39) 257 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters ___Regulations 2,3,6-Trichloro- Acute: EPA: phenol Rat: To be added to the 933-75-5 LD5Q :308 mg/kg (7a) pretreatment standards for specific industries. Hazardous water pollutant design ation (80) 258 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations 2,4,5-Trichloro- N.J. Industrial Survey Used to produce the defoliant Acute: Solubility in water at 25°C: EPA: phenol (1978-79): 2,4,5-T and related products, Dermatoses, including less than 2 g/liter (29) Priority Pollutant 95-95-4 Produced - 0 , (Silvex, Ronnel, and Sodium photoallergic contact (8) Solid Purchased - 1-5 x 10 (43) 2,4,5-trichlorophenate). (29) dermatitis, have been Vapor pressure at 72°C: Hazardous Waste (54) Also used directly as germicide, reported in humans,, * 1 mm (29) Reportable 2,3,7,8-Tetrachloro- bactericide, glue, wood quantities (89) dibenzo-p-dioxin can preservative and antimildew Chronic: Pesticide residue be formed as a biproduct treatment. (54). tolerance (80) from the synthesis of Hazardous water this chemical. (1) pollutant design- nation (80) DOT: ORM - A (54) 259 Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters _ _Regul ?j- i°ns 2,4,6-Trichloro- No longer commercially Bactericide; preservative for Acute: Bioaccumulation: EPA: phenol produced in U.S. (43) wood and glue; anti-mildew May cause skin Log octanol/water Priority Pollutant 88-06-2 treatment for fabric (43) irritation (6) partition coefficient: (8) Solid 1978 - Imports 6 (43) 3.38 (8) Hazardous Waste (54) Chronic: National Oil & N.J. Industrial Survey Sufficient evidence Solubility in water at 25°C: Hazardous Substances (1978-1979) that it is an animal 800 mg/liter (8) Contingency Plan (80) Produced - 0 carcinogen (43) Hazardous water Purchased - 0 Vapor pressure at 76.5°C: pollutant design (84) 1 mm (8) ation (80) Reportable Detection in environmental quantities (89) meida: Industrial wastewater and DOT: influents: ORM - A (54) USEPA - 4.2% (78) NJDEP (OSR) - 2/29 (82) Potable water: NJDEP (OSR) - 18/500 (86) POTWS NJDEP (OSR) influents - 0/9 effluents - 0/9 sludge - 0/9 (88) 260 PHOSPHORAMIDES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physj/:aJ_ State in the U.S. (Ibs./yr.)______Uses______Effects Parameters _ ReguJ ations Hexamethyl- 1976 - Production In the U.S., the major producer Acute: Solubility in water: Phosphoramide - probably greater uses the chemical only as a Male rats Miscible with water (24) (HEMPA) 5,000 (43) processing solvent for aromatic LD -2650 mg/kg (oral) 680-31-9 polyamide fiber. (24) Vapor Pressure at room Liquid Produced in New Jersey (43) Other known uses include: as a temperature: solvent for polymers, as a Chronic: 0.03 mm (24) selective solvent for gases, as Carcinogenic in rats a polymerization catalyst, as a via inhalation (24) stabilizer against thermal degradation in polystyrene, as an additive to polyvinyl and polyolefin resins to protect against degradation by IJ-V light, and as a solvent in organic and organometallic reactions research laboratories. (24) Positive in cell transformation assays (7) 261 QUINONES AND ANTHRAQUINONES Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regujations__ 2-Aminoanthra- Production - believed to Used almost exclusively as a Acute: Solubility in water: qui none be made for captive dye intermediate (36) Insoluble (36) 117-79-3 consumption by one U.S. Solid Company. (36) 1979 - Imports 1 x 104 (36) N.J. Industrial Survey Chronic: (1978-1979) Technical grade was Produced - 0 mutagenic in bacteria Purchased - 0 (36) Max. Inventory 1-5 x 10 (84) Limited evidence of carcinogenicity in animals for the technical grade (36) 262 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters Regulations p-Benzoquinone 1975 - Production probably Used as a chemical intermediate Acute: Solubility in water: FDA: dioxime greater than 1,000. for commercial production of at Soluble in hot water. (38) Approved as (p-Quinone least two chemicals (poly-p- vulcanizing agent dioxime) Believed to be made by dinitrolobenzene and dibenzoyl- Chronic: for rubber articles 105-11-3 two U.S. Companies in p-quinone dioxime), both are used Limited used with food Solid 1982. (43) in the rubber industry. (38) evidence of products. (38) Vulcanizer for rubber, rubber carcinogenicity in 1975 - Imports 150 (43) accelerator, bactericide. (43) rats. (38) NCI carcinogen bioassay was considered positive in rats, indefinite in mice. (7) 263 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.)______Uses______Effects Parameters 2-Methyl-l- Not produced in commercial Used almost exclusively Acute: Solubility in water: nitroanthraquinone quantities in U.S. (36) as a dye intermediate. (36) Insoluble (36) 129-15-7 Solid Chronic: Carcinogenic in animals (36) Mutagenic in bacteria (36) 264 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State_____in the U.S. (Ibs./yr.)______Uses______Effects______Parameters______Regulations______p-Quinone 1975 - Production Probably Used as chemical intermediate Acute: Solubility in water: OSHA: (1,4-Benzo- greater than 1,000 tor the synthesis of hydroquinone, Slightly soluble (43) Air quinone) (43) rubber accelerators, oxidizing TWA 0.1 ppra (7a) 106-51-4 agents; as a polymerization 1974 - Imports 6,000 (43) inhibitor for unsaturated EPA: polyester resins; and as a Hazardous Waste (80) photographic chemical. (43) Chronic: Insufficient PDA: evidence to Food-contact evaluate carcinogencity component (80) (24) DOT: Not mutagenic in Hazardous materials yeast (24) table (80) 265 SULFU1UC ACID ESTERS Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Phys i c-al Sta t.e_ in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters __ Regulations Diethyl sulfate 1975 - Production probably An alkylating agent used for the Acute: Aquatic Toxicity Rating: DOT: 64-67-5 greater than 1000 (43) ethyl derivatives of phenols, Rats LC 96:100-10 ppra (7a) Hazardous Materials Liquid amines, and thiols (43) LD 350 mg/kg Table (80) (subcutaneous) Solubility in water: TDLQ :750 mg/kg (oral) 0.7 gm/100 ml (43) (7) Chronic: Vapor pressure at 45°C: Limited evidence 1 mm (43) of carcinogenicity in humans. Sufficient evidence of carcinogenicity in animals (42) Mutagen in dominant lethal assay in mice (42) Mntagen in insects, yeast, mammalian cells and bacteria (42). 266 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Envi ronmenta1 Physicaj State in the U.S. (Ibs./yr.)______Uses_____ Effects Parameters Regulations Dimethyl Sulfate There are 12 producers and A chemical intermediate in the Acute: Aquatic Toxicity Rating: OSIIA: 77-78-i importers. synthesis of methyl derivatives Eye and skin irritant LC _: 100-10 ppm (7a) Air: Liquid of active hydrogen compounds, in (2e) TWA 1 ppm (skin) (7) Production - 4.8 x 10 /yr. the synthesis of quaternary Rat Solubility in water at 18°C: (9) ammonium methosulfate salts, in LD :440 mg/bg (oral) 28 gm/1 (43) ACGIH Recommendation: the synthesis of some cationic LD^":32 ppm/4 hr. TLV-CL 100 ppb surfactants, and in the (infial.) (43) Vapor pressure at room (skin) synthesis of anticholinergic temperature: 0.1 mm (43) Suspected carcinogen agents. (43) Chronic: (7a) Sufficient evidence of carcinogenicity in EPA: animals. (42) Hazardous Waste (54) Reportable quantities Mutagen in insects, (89) mammalian cells, yeast, and bacteria (42). DOT: Corrosive material arid poison (54) 267 THIOUREAS Substance Name (Synonym) Amount Produced Major GAS Number Imported, Exported Commercial • Health Environmental . Physical State_____in the U.S. (Ibs./yr.)______Uses______Effects______Parameters______Regulations Ethylene 1973 - Production - Used as an accelerator for Acute: Solubility in water at 30°C: EPA: Thiourea probably greater neoprene (polychloroprene) Rats 20 gin/liter (43) Hazardous Waste (80) (2-Imidazoli- 1,000 lb. (43) rubber. It is also recommended LD 1832 rag/kg (oral) Reportable quantities dine-thione) for use as part of a curing (7a) (89) 96-45-7 Produced in New Jersey (43) f or polyacrylate rubbers. (16) Solid Chronic: FDA: Carcinogen in rats Food-contact via oral route in component (80) three studies (16, 42 ) DOT: Hazardous materials Teratogenic in rats table (80) and cats. (16, 43) 268 Substance Name (Synonym) Amount Produced Major CAS Number Imported, Exported Commercial Health Environmental Physical State in the U.S. (Ibs./yr.) Uses Effects Parameters RRegulations Thiourea Not presently manufactured Approximately 50% is used as an Acute: Solubility in water at 25°C: EEPA: (62-56-6) commercially in U.S. (43) anti-yellowing agent for photo I part to 11 parts of Hazardous waste (80) Solid sensitive copy paper; most of the water (16) Reportable quantities 1973 - Imports , remainder is probably used as a (89) 3.75 x 10 (43) chemical intermediate for flame retardants and as a nylon treating FDA: N.J. Industrial Survey agent to prevent running and to Chronic: Food-contact (1978-1979): improve handling properties; the Carcinogen in rats component (80) Purchased - 0 next most important use is via oral and intra- Purchased - 1-5 x 10 (84) probably as an agent in boiler- peritoneal route (16) DOT: water treatment. (43) Hazardous materials Mutagen in bacteria, table (80) yeast and mamalian cell assays. (7) Positive in cell transformation assays. (7) Mutagen in host- mediated assay (43) Teratogen in rats (7) Reduced fertility in rats and mice (7) 269 1 . Fishbein, L Potent ial Industrial Carcinogens and Mutagens. New York: Elsevier Scientific Publishing, 1979. 2. Dangerous Properties of Industrial Materials Report 2a Vol. 1, No . 1 , Sept./Oct . 1980 2b Vol. 1, No . 2 , Nov. /Dec. 1980 2c Vol. 1, No . 3 , Jan. /Feb. 1981 2d Vol. 1, No . 4 , Mar. /Apr. 1981 2e Vol. 1, No . 5 , May/June 1981 2f Vol. 1, No . 6 , July/Aug. 1981 2g Vol. 1, No . 7 , Sept./Oct . 1981 2h Vol. 1, No . 8 , Nov. /Dec. 1981 3. Dangerous Properties of Industrial Materials Report 3a Vol. 2, No . 1 , Jan. /Feb. 1982 3b Vol. 2, NO . 2 , Mar. /Apr. 1982 3c Vol.' 2, NO . 3 , May/June 1982 3d Vol. 2, NO . 4 , July/Aug. 1982 3e Vol. 2, NO . 5 , Sept./Oct . 1982 3f Vol. 2, NO . 6 , Nov. /Dec. 1982 4. Dangerous Properties of Industrial Materials Report 4a Vol. 3, NO . 1 , Jan. /Feb. 1983 4b Vol. 3, No . 2 , Mar. /Apr. 1983 4c Vol. 3, No . 3 , May/June 1983 4d Vol. 3, No . 4 , July/Aug. 1983 4e Vol. 3, No . 5 , Sept./Oct . 1983 4f Vol. 3, No . 6 , Nov. /Dec. 1983 5. The Merck Index, Ninth Edition. Rahway, NJ: Merck and Co. , 1976. 270 6. Hawley, G.G. The Condensed Chemical Dictionary/ Tenth Edition. New York: Van Nostrand Reinhold Co., 1981. 7. USDHHS, NIOSH. Registry of Toxic Effects of Chemical Sub stances . A National Library of Medicine's MEDLARS computer data base. 7a. ______. Registry of Toxic Effects of Chemical Substances, NIOSH Publication No. 81-116. Washington, DC: US Government Printing Office, 1982. 7b. ______. Tumorigenic, Mutagenic, and Reproductive Effects Citations; Subfiles of the Registry of Toxic Effects of Chemical Substances, NIOSH Publication No. 81-136. Washington,, DC: US Government Printing Office, 1981. (microfiche). 8. USEPA, Office of Water Planning and Standards. Water Related Environmental Fate of 129 Priority Pollutants, 2 vols., EPA 440/4-79-029a & b. Washington, DC: US Government Printing Office, 1979. 9. USDHHS, NTP. Second Annual Report on Carcinogens, NTP81-43. Washinton, DC: US Government Printing Office, 1981. 10. WHO, IARC. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man, Volume 1. Lyon, France: Int'l Agency for Research on Cancer, 1972. 11. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man; Some Inorganic and Organo- metallic Compounds, Volume 2. Lyon, France: Int'l Agency for Research on Cancer, 1973. 12. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man: Certain Polcyclic Aromatic 271 Hydrocarbons and Hetercyclic Compounds, Volume 3. Lyon, France: Int'l Agency for Research on Cancer, 1973. 13. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man; Some Aromatic Amines, Hydrazine and Related Substances, N-Nitroso Compounds and Miscel laneous Alkylating Agents, Volume 4. Lyon, France: Int'l Agency for Research on Cancer, 1974. 14. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man; Some Organochlorine Pesticides, Volume 5. Lyon, France: Int'l Agency for Research on Cancer, 1974. 1 5. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man; Sex Hormones, Volume 6. Lyon, France: Int'l Agency for Research on Cancer, 1974. 16. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man: Some Anti-thyroid and Related Substances, Nitrofurans, and Industrial Chemicals, Volume ]_. Lyon, France: Int'l Agency for Research on Cancer, 1974. 17. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man; Some Aromatic Azo Compounds, Volume 8. Lyon, France: Int'l Agency for Research on Cancer, 1975. 18. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man; Some Aziridines, N-, S-, and 0-mustards, and Selenium, Volume 9. Lyon, France: Int'l Agency for Research on Cancer, 1975. 272 19. ______. IARC Monographs on the Evaluation of Carcinogenic R2Lj=k_of_C_h£mjL£_a_l£_t.o_M_arij__Some Naturally Occurring Substances, Volume 10. Lyon, France: Int'l Agency for Research on Cancer, 1976. 20. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man: Cadmium, Nickel, Some Epoxides, Miscellaneous Industrial Chemicals, and General Considera tions on Volatile Anaesthetics, Volume 11. Lyon, France: Int'l Agency for Research on Cancer, 1976. 2 1. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man; Some Carbamates, Thiocarbamates, and Carbazides, Volume 12. Lyon, France: Int'l Agency for Research on Cancer, 1976. 22. ______. IARC Monographs on the Evaluation of Carcinogenic Rj.sk^Ojf Chemicals to Man: Some Miscellaneous Pharma- ceutical Substances, Volume 13. Lyon, France: Int'l Agency for Research on Cancer, 1977. 23. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man; Asbestos, Volume 14. Lyon, France: Int'l Agency for Research on Cancer, 1977. 24. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man; Some Fumigants, the Herbicides 2,4-D_and 2,4, 5-T, Chlorinated Dibenzodioxins, and Miscellaneous Industrial Chemicals, Volume 15. Lyon, France: Int'l Agency for Research on Cancer, 1977. 273 25. ______. IARC Monographs on the Evaluation of Carcinogenic Aromatic Amines and Reflated Compounds — Hai r Dyes, Coloring Agents, and Miscellaneous Industrial Chemicals r Volume 16 . L y o n , France: Int'l Agency for Research on Cancer, 1978. 26. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans; Some N-Nitroso Compounds, Volume 17. Lyon, France: Int'l Agency for Research on Cancer, 1978. 27. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans: Polychlorinated Biphenyls and Polybrominated Biphenyls, Volume 18. Lyon, France: Int'l Agency for Research on Cancer, 1978. 28. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans; Some Monomers, Plastics, and Synthetic Elastomers, and Acrolein, Volume 19. Lyon, France: Int'l Agency for Research on Cancer, 1979. 29. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans; Some Halogenated Hydrocar bons, Volume 20. Lyon, France: Int'l Agency for Research on Cancer, 1979. 30. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans; Sex Hormones (II), Volume 21 . Lyon, France: Int'l Agency for Research on Cancer, 1979. 274 31. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans: Some Non-nutritive Sweet ening Agents, Volume 22. Lyon/ France: Int'l Agency for Research on Cancer, 1980. 32. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans; Some Metals and Metallic Compounds, Volume 23. Lyon, France: Int'l Agency for Research on Cancer, 1980. 33. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans: Some Pharmaceutical Drugs, Volume 24. Lyon, France: Int'l Agency for Research on Cancer, 1980. 34. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans; Wood,_Leather and Some Associated Industries, Volume 25. Lyon, France: Int'l Agency for Research on Cancer, 1981. 35. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans; Some Antineoplastic and Immunosuppressive Agents, Volume 26. Lyon, France: Int'l Agency for Research on Cancer, 1981. 36. ______. IARC Monographs on the Evaluation of the Carcino genic Risk of Chemicals to Humans; Some Aromatic Amines, An_tji_r_ac[_u_i ri£ n ejs_a. n d_N jj:££jS£_C_o_mp_ cnands ,_and Inorganic Flourides Used in Drinking Water and Dental Preparations, Volume 27. Lyone, France: Int'l Agency for Research on Cancer, 1982. 275 37. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans; The Rubber Industry, Volume 28. Lyon, France: Int'l Agency for Research on Cancer, 1982. 38. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans: Some Industrial Chemicals and Dyestuffs, Volume 29. Lyon, France: Int'l Agency for Research on Cancer, 1982. 39. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans; Miscellaneous Pesticides, Volume 30. Lyon, France: Int'l Agency for Research on Cancer, 1983. 40. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans; Some Food Additives, Feed Additives, and Naturally Occurring Substances, Volume 31. Lyon, France: Int'l Agency for Research on Cancer, 1983. 4 1. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans; Chemicals and Industrial Processes Associated with Cancer in Humans, IARC Mono graphs, Volumes 1_to 20. IARC Monographs Supplement 1 . Lyon, France: Int'l Agency for Research on Cancer, 1979. 276 42. ______. IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans; Chemicals and Industrial Processes Associated with Cancer in Humans , IARC Mono graphs, Volumes 1_to 29. IARC Monographs Supplement 4. Lyon, France: Int'l Agency for Research on Cancer, 1982. 43. USDHHS, National Library of Medicine. MEDLARS, Toxicology Data Bank (TDB). Computer data base. 44. USEPA, Environmental Sciences Research Laboratory. Fate of Toxic and Hazardous Materials in the Air Environment. EPA 600/S3-80-084. Washington, DC: U.S. Government Printing Office, 1980. 45. Singh, H. , et al. "Measurement of Some Potentially Hazardous Organic Chemicals in Urban Environments." Atmospheric Environment 15 (1981), pp. 601-612. 46. Journal of Applied Toxicology 46a Vol. 1, No. 1, February 1981 46b Vol. 1, No. 2, April 1981 46c Vol. 1, No. 3, June 1981 46d Vol. 1, No. 4, August 1981 46e Vol. 1, No. 5, October 1981 46f Vol. 1, No. 6, December 1981 47. Journal of Applied Toxicology 47a Vol. 2, No. 1, February 1982 47b Vol. 2, No. 2, April 1982 47c Vol. 2, No. 3, June 1982 47d Vol. 2, No. 4, August 1982 277 47e Vol. 2, No. 5, October 1982 47f Vol. 2, No. 6, December 1982 48. Journal of Applied Toxicology 48a Vol. 3, No. 1, February 1982 48b Vol. 3, No. 2, April 1982 48c Vol. 3, No. 3, June 1982 48d Vol. 3, No. 4, August 1982 48e Vol. 3, No. 5, October 1982 48f Vol. 3, No. 6, December 1982 49. Wolfsie, J.H., et al. "Hydrogen Cyanide." Journal of Occupa tional Medicine, 1 (May 1959), pp. 281-288. 50. USDHHS, National Toxicology Program. NTP Technical Report on the Carcinogenesis Bioassay of C.I. Disperse Yellow 3 (GAS No^L-ilUzMzil_in F344/N Rats and B6C3F1 Mice (Feed Stjudy__)_, NTP-TR-222. NIH Publication No. 82-1778. Washington, DC: U.S. Government Printing Office, 1982. 51. ______. NTP Technical Report on the Carcinogenesis Bioassay of C.I. Solvent Yellow 14 (CAS No. 824-07-9) in F344/N Rats and B6C3F1 Mice (Feed Study), NTP-TR-226. NIH Publication No. 82-1782. Washington, DC: U.S. Govern ment Printing Office, 1982. 52. USDHEW, National Cancer Institute. Bioassay of C.I. Vat Yellow 4 for Possible Carcinogencity, NCI-CG-TR-134. DHEW Publication No. (NIH) 79-1389. Washington, DC: U.S. Government Printing Office, 1979. 278 53. USDHHS, National Toxicology Program. NTP Technical Report on the Carcinogenesis Bioassay of Melamine (GAS No. 108-78-1) in F344/N Rats and B6C3F1 Mice (Feed Study), NTP-TR-245. NIH Publication No. 83-2501. Washington, DC: U.S. Government Printing Office, 1983. 54. Sittig, M. Handbook of Toxic and Hazardous Chemicals. Park Ridge, NJ: Noyes Publication, 1981. 55. Sittig, M., ed. Pesticide Manufacturing and Toxic Materials Control Encyclopedia. Park Ridge, NJ: Noyes Data Corp., 1980. 56. National Research Council, Committee on Toxicology. An Assess- ment_o_f the Health Risks of Seven Pesticides Used for Termite Control. Washington, DC: National Academy Press, 1982,. 57. National Research Council, Safe Drinking Water Committee. Drinking Water and Health, Volume 1, Washington, DC: National Academy Press, 1977. 58. ______. Drinking Water and Health, Volume 3. Washington, DC: National Academy Press, 1980. 59. ______. Drinking Water and Health, Volume 4. Washington, DC: National Academy Press, 1982. 60. Proctor, N.H. and J.P. Hughes. Chemical Hazards of the Work place. New York: J.B. Lippincott Co., 1978. 61. Oehme, F.W., ed. Toxicity of Heavy Metals in the Environment, 2 Vols. New York: Marcel Dekker, C. 1978-1979. 62. Lee, D.H.K., ed. Metallic Contamination and Human Health. New York: Academic Press. 1972. 279 63. Weast, R.C., ed. CRC Handbook of Chemistry and Physics, 61st Edition. Boca Raton, FL: CRC Press, 1980. 64a. Clayton, G.D. and F.E. Clayton, eds. Patty's Industrial Hygiene and Toxicology, Volume 2A; Toxicology. Third Revised Edition. New York: John Wiley and Sons, 1981. 64b. ______. Patty's Industrial Hygiene and Toxicology, Volume 2B: Toxicology. Third Revised Edition. New York: John Wiley and Sons, 1981. 64c. ______. Patty's Industrial Hygiene and Toxicology, Volume 2C; Toxicology with Cumulative Index for Volume 2. Third Revised Edition. New York: John Wiley and Sons, 1982. 65. American Conference of Governmental Industrial Hygienists. Documentation of the Threshold Limit Values. 4th Edition. Cincinnati: AGGIH, 1980. 66. Shepard, T.H. Catalog of Teratogenic Agents. 3rd Edition. Baltimore: Johns Hopkins University Press, 1980. 67. International Labour Office. Encyclopedia of Occupational Health and Safety. 2 Vols. New York: McGraw-Hill Book Co., 1971. 68. USDHEW, National Institute for Occupational Safety and Health. Occupational Diseases; A Guide to Their Recognition. Revised Edition. DHEW (NIOSH) Publication No. 77-181. Washington, DC: U.S. Government Printing Office, 1977. 69. Gosselin, R.E., et al. Clinical Toxicology of Commercial Products; Acute Poisoning. 4th Edition. Baltimore: Williams and Wilkins, 1976. 280 70. Weiss, G., ed. Hazardous Chemicals Data Book. Park Ridge, NJ: Noyes Data Corp., 1980. 71 . Copper, Chemical Fact Sheet prepared by the Bureau of Toxic Substances Assessment, N.Y. Department of Health, July 1982. 72. Mercury, Chemiccil Fact Sheet prepared by the Bureau of Toxic Substances Assessment, N.Y. Department of Health, November 1981 . 73- Z i n c, Chemical Fact Sheet prepared by the Bureau of Toxic Substances Assessment, N.Y. Department of Health, 1982. 74. USDHHS, National Institute of Environmental Health Sciences. "Results of 1311 compounds tested under the Environmental Mutagenesis Testing Development Program." Computer printout, August 1983. 75. USEPA, Registration Support and Emergency Response Branch. • ^P^AP^^tjL^j.de_Regj.str ation Division Status Report on Review Actions, Registration Standards, Data Call-in, June 1983. Reprint from Chemical Regulation Reporter, V. 7, No. 25, September 16, 1983. 76. USEPA, Office of Air Quality Planning and Standards. Organic Chemical Mcinuf acturing. Research Triangle Park, NC : USEPA, 1980,. 76a. Volume 1; Program Report EPA 450/3-80-023 76b. Volume 2; Process Sources EPA 450/3-80-024 7 6 c. Volume 3: Storage, Fugitive, and Secondary Sources EPA 450/3-80-025 7 6 d . Volume 4; Combustion Control Devices EPA 4 5 0/ 3-80-026 281 7 6 e. Volume 5: Adsorption, Condensation, and Absorption Devices EPA 450/3-80-027 76f. Volume 6: Selected Processes EPA 450/3-80-028a 76g. Volume 7; Selected Processes EPA 450/3-80-028b 76h. Volume 8; Selected Processes EPA 450/3-80-028c 76i. Volume 9: Selected Processes EPA 450/3-80-028d 76j. Volume 10; Selected Processes EPA 450/3-80-028e 77. Matsumura, R. Toxicology of Insecticides. New York: Plenum Press, 1975. 78. USEPA, Analytical Programs. "Priority Pollutant Frequency Listing Tabulations and Descriptive Statistics." Memoran dum to Effluent Guidelines Division, January 2, 1980. 79. USEPA, Environmental Criteria and Assessment Office. Air Quality Criteria for Ozone and Other Photochemical Oxi- dants, EPA-600/8-78-004. Research Triangle Park, NC: USEPA, 1978. 80. Chemical Regulation Reporter-Index to Government Regulation. Washington, D.C.: Bureau of National Affairs, 1984. 81 . New Jersey Administrative Code, Title 7-Environmental Pro tection. 82. NJDEP, Office of Science and Research. Results on Priority Pollutant Analyses of Industrial Wastewater Discharges. In draft. 83. ______. Toxic Air Pollutants in New Jersey. Trenton, NJ: NJDEP, 1983. 84. ______. Summary of Industrial Survey Data. 1983. 282 85. ______. Toxics in Groundwater. Trenton, NJ: NJDEP, 1981. 86. ______. Potable water data base, 1978-1980. 87. ______. PCBs in Selected Finfish Caught Within New Jersey Waters, 1981-1982 (With Limited Chlordane Data). Trenton, NJ: NJDEP,, 1983. 88. Rutgers University. Publicly owned treatment works (POTWs) data. 1983. 89. Code of Federal Regulations. Title 40, Section 302. (40 CFR 302) 90. Sittig, M., ed. Priority Toxic Pollutants; Health Impacts and Allowable Limits. Park Ridge, NJ:: Noyes Data Corp., 1980. 91. USDHHS, National Toxicology Program. NTP Technical Report on the Toxicology and Carcinogenesis of 1 , 3-Butadiene (CAS No. 106-99-0.) in B6C3F1 Mice (Inhalation Studies). NTP-TR-288. NIH Publication No. 84-2544. Research Triangle Park, NC: National Toxicology Program, October 1983. [Board draft] . 92. ______. NTP Technical Report on the Carcinogenesis Studies of 4,4'-Methylenediani1ine dihydrochloride (CAS No. 13552-44-8) in F344/N Rats and B6C3F1 Mice (Drinking Water Studies) . NTP-TR-248. NIH Publication No. 83-2504. Washington, DC: U.S. Government Printing Office, 1983. 283 Appendix V Diagram of the Selection Process Used in Developing the Environmental Hazardous Substance List Literature Review Toxicitv Review Evidence of Chroni Data / Health / Effects Production and Commercial Use Environmental Tatc Existing Rcgulat ions Review APPENDIX VI The Environmental Survey - Part I and Instructions SURVEY INSTRUCTIONS The following Tables of Information Codes will be used to complete Part I of the Environmental Survey and also the Emergency Services Information (ESI) Survey: Table "5" - Column 5 "Container" Indicate the major method of storage or type of container for each substance: (the largest bulk vessel) 50 above ground tank 43 fiber drumm 49 below ground tank 42 bag 48 tank inside building 41 box 47 steel drum 40 cylinder 46 pail or can 39 bottles or jugs (glass) 45 carboy 38 bottles or jugs (plastic) 44 silo 37 other (note) Table "4" - Column 4 "Mixture" Is the substance present in a mixture with other substances? 30 Pure state (981 or above) 29 Greater then 50% 28 Unknown 27 Less then 50% 26 Present, but less than II of mixture Table "5" - Column 5 "Inventory" Indicate the approximate range of the maximum inventory quantity: (the most on hand at any time) 20 1 million or more 15 10,000 - 50,000 19 500,000 - 1 million 14 1,000 - 10,000 18 250,000 - 500,000 13 100 - 1,000 17 100,000 - 250,000 12 10 - 100 16 50,000 - 100,000 11 less then 10 Table "6" - Column 6 "Unit of Measure" Use the appropriate units C = Cubic feet for gases P = Pounds for Solids G = Gallons for Liquids A.P.C. ID §tate of 5seui ttersey DEPARTMENT OF ENVIRONMENTAL PROTECTION "WORKER AND COMMUNITY RIGHT TO KNOW ACT" ENVIRONMENTAL SURVEY-PART I (SHORT FORM) ® Does this label accurately show the facility location? Enter changes below: Company Name Division Location ENTER CODES (D DOES THIS FACILITY USE, STORE, OR PRODUCE ANY QUANTITY OF ANY SUBSTANCE LISTED ON THE ATTACHED ENVIRONMENTAL HAZ ARDOUS SUBSTANCE LIST ( ) YES ( ) NO CONTAINER INVENTORY If "no", sign the certification below and return as directed. MIXTURE UNITOF MEASURE If "yes", complete the form using the code numbers provided in the instruc tions. FOR OFFICIAL X ENVIRONMENTAL HAZARDOUS SUBSTANCES © C.A.S. No. (I) ® ® ® USE ONLY t © I, HEREBY CERTIFY THAT ALL STATEMENTS MADE BY ME IN THIS REPORT ARE TRUE, COMPLETE, AND CORRECT. Name (print)______Signature_____:______Title ______Date______NOTE: Make Copies of this form! send a COPY to: return original to: NJDEP SURVEY THE COUNTY H.D. OR CLERK (address provided) CN 405 TRENTON, N.J. 08625 NOTE: You are required to make a copy available to your employees..See complete instructions! DUE DATE:' APPENDIX VII The Emergency Services Information (ESI) Survey Form A.P.C. ID §tate of New Derszy DEPARTMENT OF ENVIRONMENTAL PROTECTION "WORKER AND COMMUNITY RIGHT TO KNOW ACT" EMERGENCY SERVICES INFORMATION SURVEY (ESIS) ® Does this label accurately show the facility location? Enter changes below: Company Name Division Location ENTER CODES ® DOES THIS FACILITY USE, STORE, OR PRODUCE ANY QUANTITY OF ANY SUBSTANCE LISTED ON THE ATTACHED US DOT HAZARDOUS MATERIALS TABLE ( ) YES ( ) NO CONTAINER INVENTORY UNITOF If "no", sign the certification below and return as directed. MIXTURE MEASURE If "yes", complete the form using the code numbers provided in the instruc tions. FOR OFFICIAL ® US DOT HAZARDOUS MATERIALS - © I, HEREBY CERTIFY THAT ALL STATEMENTS MADE BY ME IN THIS REPORT ARE TRUE, COMPLETE, AND CORRECT. Name (print)______Signature—______Title ______Date. NOTE: Make Copies of this form! send a COPY to: return original to: NJDEP SURVEY YOUR LOCAL FIRE AND POLICE DEPARTMENTS CN 405 TRENTON, N.J. 08625 NOTE: You are required to make a copy available, to your employees. See complete instructions! DUE DATE: APPENDIX VIII The Environmental Survey - Part II ID Sl»t« of Ntw J«rs«y CM D«p*rtm«nt of Environment*! Protection Return forms to: NJJ3EP __ |ny i r onmen t al CN405 OFFICE OF THE COMMISSIONER TRENTON. iVJ 08625 RTfiHT TO KNOW PART II _____- General Plant Information (LONG FORM) COMPLETE ONE REPORT FOR EACH PLANT SITE OR FACILITY LOCATION 1. Company Name. 2. Division or Plant Name . 3. Mailing Address (Street). (City/Town)______.County. .State. .Zip Code. 4. Plant Location Address (Street). (If not as above) (City/Town)______.County. .State. .Zip Code. 5. Date Plant Began Operations At This Location, 6. Person to Contact Regarding this Report___ .Title. 7. Phone Number (Area Code)______ 3. SIC Code (Four Digit). Standard Industrial Classification (if available) 9. Nature of Business _ 10. Number of Production Employees at this Plant Site. 11. Does this plant manufacture, process, form, repackage, release, use-, dispose of or store any o< the Environmental^ shown on Table I of the enclosed instructions? (Check One) YES Q NO Q Hazardous If your answer to number 11 is "YES", complete the Entire Report for your facility, sign and return. If your answer to number 11 Is "NO",^ _, sign and return. I, HEREBY, CERTIFY THAT ALL STATEMENTS MADE BY ME IN THIS REPORT ARE TRUE, COMPLETE AND CORRECT TO THE BEST OF MY KNOWLEDGE AND THAT ESTIMATES WHERE USED HAVE BEEN MADE IN GOOD FAITH. NAME (Print). . Signature. Title ———— .Date. 12A. Sketch (On the reverse side of this page) or attach a copy of a map indicating the exact location of the plant site. 123. Supply your Dun i Brad street number if available. ———————————————————————————————————— FOR OFFICIAL USE ONLY *• n state of New Jersey RIGHT TO KNOW New Jersey Department of Environmental Protection PART II ' COMPLETE ONE FORM FOR EACH ENVIRONMENTAL HAZARDOUS SUBSTANCE FOR DEP USE 1. Name and Location of Plant I.D. 2. Environmental Hazardous Substance Name CAS H 3. Briefly Describe its Use On The Site CHECK ONE COMPLETE THE FOLLOW1NO INFORMATION ENTER THE ACTUAL USE THE RE Actual Estimated FOR THE PLANT BASED ON 1983 USAGE OR ESTIMATED AMOUNTS QUESTED UNITS 4. Quantity Produced on Site Ibs/yr. THROUGHPUT QUANTITIES 5. Quantity Brought on Site Ibs/yr. -6. Quantity Consumed on Slta Ibs/yr. 7. Quantity Shipped off Site Ibs/yr. a» (or In) Product 8. Maximum Inventory Ibs. INVENTORY Sa. Methods of Storage 3b. Methods at Transfer 3c. Frequency of Transfer I Ibs/yr. a Totai Stack Emissions of Environmental Hazardous Substance EMISSIONSAIR max Ibs/day Ibs/yr. 10 Total Fugitive Emissions of Environmental Hazardous Substance max Ibs/day Ibs/yr. , 1 Total Discharge of Environmental • Hazardous Substance Into 'Surface Water max Ibs/day IWASTEWATERDISCHARGE Ibs/yr. ., Total Discharge of Environmental • Hazardous Substance Into Publicly Owned Treatment Works max iba/day Total Discharge of Environmental Ibs/yr. 13. Hazardous Substance to Ground Water max Ibs/day 14. Disposal of Waste Containing the Environmental Hazardous Substance: UNITS NAME AND LOCATION OF TABLE NAME AND ADDRESS OF QUANTITY " • Pounds or TABLE TABLE FINAL DISPOSAL SITE A WASTE HAULER SUBSTANCE f .PO D Gallons B C TABLE A TABLES TABLE C DISPOSAL METHODS PHYSICAL STATE METHOD OF ONSITE STORAGE 01 Composting • M-07 Land Bur: al M-13 Surface Water W-01 Solid • 3-01 Drums 02 Evaporation M-08 Land Spreading M-14 Suosurface System WO2 Liquid 3-02 Tank 03 Holding Tank ^9 Neutralization M-15 Pyrolysls W-03 Slurry S-03 Dumpster 04 incinwalion 1^-10 Ocean M- 16 Spray irnaation VIHX Sludge 3-04 Pi t of Lagoon ~,z '- •• " '/xi »,t.:< n,»cyc!in(| M-1 T Stor*^ on Sit» *v-09 Otner (Specify! S-05 Other (Soecifvl APPENDIX IX The United States Department of Transportation Optional Hazardous Materials Table DEPARTMENT OF TRANSPORTATION OPTIONAL HAZARDOUS MATERIALS TABLE (49 CFR 172.102; 48 FR 50234, October 31, 1983) 172.102 Optional Hazardous Materials Table (1) (2) (3) (4) (i) (2) (3) (4) Nous Idenri- Idenu- IMCO Notes IMCO nc»tKm Hatardoias Maternal Deamom and Proper Sfupewg Names CUM txuxm and Hazardous Materials Dejcnpoon and Proper Shipping Names Oats Symbol Number Number Acetal 3.1 UN IOM * Alcohols, tosic. l.o* 3.1 UN 11* Acetaldehyde 3.2 UN 1916 3.1 UN I0» 3.3 UN 191* Acetaldehyde ammonia 9 UN 1*41 Acetaldchydc osime 3.3 UN 2332 Acetic acid, glacial or Acetic acid solution, man inun tV% ant Iff 1 UN 2719 fttgnt * Atdehydea. ao.s. 3.1 UN I9|9 32 UN 1919 Acetic acid solution, mart tnan 23% hut net more Ikon 90% acuL by 1 UN 2790 3.3 UN 1919 »mr« Aldehydes, loaic. BJXS 3.1 UN I9U Acetic anhydride 1 UN17IJ 1.2 UN HU 3.3 UN HU Acetone 3.1 UN 1090 Acetone cyanohytinn. tiaetiiiied 6.1 UN 1541 A Idol 61 UN 2139 Acetone oils .1.1 UN 1091 . Alkali metal alkiyv liquid 43 UN 1421 Acetomtntc* Set Methyl cyanide Alkali melal amalgams. a.c>.s. 43 UN I3S9 Acetyl acetone peroiide, maximum concentration 40% tn tarutian 3.2 I'N 2080 Alkali metal amides, n.o.s. 43 UN 1390 Acetyl benioyl pcrotide. maximum conetntratKm 45% in tolutiun 5.2 UN2C«I Alkali melal dispenwoa, n.o.s. or Alkali earth melal dnpennm. 4.3 UN 1391 Acetyl bromide 1 UN 1716 n.o.&. Alkaline caustic liquidt, n.o.s. See Cauxtic alkali liquidv n.o.s. Acetyl chloride 3.2 UN 1717 Alkaline corrosive liquids, n.o.s. 5re Corrovve liquicH. n o.s. * AILalne amnh maul alloys, n.as. 4.3 UN IMS Acetyl cyclohcune sulpftonyl peniside, maximum rofcrnrWHM 5.2 UN 2082 Alkaline earth Beta! amalivms, n.o s. 13 UN 1)92 Acetyl cycloheiane suiphonyl pero&ide. maximum concentration 5.2 UN 2013 • Alkaloids. R.O.S. or Alkaloid salts, a.o *.. poaonou 6.1 UN 15*4 12% in button 6.1 UN 1S44 Acetylene, dtaolfed 2.1 UN IUOI AlkylamuMa and polyaaninea, flainpani teb* 23 at* C and lolling 3.2 UN 27JJ point afoit 35 aeg C but not more tJian 200 deg C. n.o.s. Acetyl iodide 1 UN IS9I Alkytsjsunea and polyamiisas. flashpoint 23 deg C or above, boiling 1 UN 2734 point atow J5 deg C but mot mart tkan 200 dff C. n.o.s. At«riyl methyl carbtrvol 3.3 UN 2621 Acd>l peroiide. *iaximitm conctntrati&n 2?% in jerfarKm 5.2 UN 20M Alky lamina* and polyamnes, flasnfotni of 23 deg C or above and 1 UN 2735 boiling point abe* 200 Arg C. B.O.S. . Acid Tislures, spent, nitrating 1 UN 1126 Ac>di. liquid, n.o.s. See Corrosive liquid*. n.OA. Acridi.x 41 UN 2713 Alkvl. Arvl or Toluene suilr*honic «cid. hquld. containing mart tnan 1 UN 25M i% free' mlprturu: acH Acruletn dtmer. aabtttzed 3.3 UN 2607 AlkyU Aryl or Toluene ijlphooic acid, liquid, fomenting not mm 1 UN 2516 . Acrolem. inhibited 3.1 UN 10»J tnan J * fret tulpnunc tctd Alkyl. Aryl or Toluene sulphonic SCHJ. solid, containing man ikan 1 UN2JI3 Acr>! amide 6.1 UN 2074 S% fret lulfhuric xid Acrylic acid, inhibited 1 UN 2211 Alkyl. Aryt or Toluene iiulphoaic acid, solid, containing not more 1 UN 2515 Inan 3% free rulpnunc teia * Alkyl phenols. n.o.s. 6.1 UN 2430 Acrylonitrile, inhibited 3.2 UN I09J Allyl acetate 3.2 UN 2333 • Activated carbon. See Carbon, activated Allyl atecM 3.2 UN 1091 * Acln ated charcoal SIT Carbon, activated Adhesive^, containing a jammabte liquid 3.1 UN 1133 Allvlamine 3.1 UN 2334 3.2 UN 1133 3.3 UN 1133 Allyl broniide 32 UN 1099 Adipominle 6.1 UN 2203 Aerosol dispensers. mi* • cjoaaetft below 1400 evbac cm. . Allyl ch!oc«Je 3.1 UN 1100 f'l meet titan IV% by wtignt of tatak contend confuting offlam- 11 UN 1950 AIM i-hlorocarbonate Set AIM chtomlormaie 121 internal prtaure greaur Inan tlO as* al 1 30 dig f. 2.2 UN 1950 Allyl chioroformate 1 UN 1722 Ill mart Inan 4S% bf mt*tnt of total mtentt camming offlam- 31 UN 1950 mablt luruid. Tna Haul m rttjuetm1 to J'3% i/ inert m ant 3.2 I'N 1936 flammable gas pUMnt 33 UN 1950 Allyl ethyl ether 3.2 UN 2333 14) meet tnan 10% bf mngnt oj tax* tuotuanea in tko liquuj 6.1 UN 19» 61 Ailyl formate 3.2 UN 233* (3) mart tnan S% by *ngnl a/ forrcatre niltuanea in tkr liaumj 1 UN 1950 certctnfrnit Allyl glycidyl ellier 3.3 UN 2219 UN 1950 Allyl iodide 3.2 UN 1723 N Aerosol dHpenaen. •Rf* a cmpattrf of 1OOU cubtr. cm. or mart 2 UN 1950 Again. Maxsag. Type B. Set Eiploiivea. bunting. Type 8 AUyl laothiocyaruric, itarMlutJ 6.1 UN 1545 Agents, blasting. Type E. 5W EifHoaixes. blaatirg. Type E Air comumem 2.2 UN 1002 1 UN 1724 Aircraft thrual device far aautea1 taJLe^tff" 4.1 UN 2791 Allyl tnchtonmilaiie. itttMutd Air. rtfngtrutfu1 tufta*1 !J UN 1003 •N Alarm devices. elptoHvt momatH 145 UN 0001 • Aluminium alkyl halides. in solution 4.2 UN 2220 • Aloalnkv B.O.I. 3.1 UV I9t7 • Aluminium alkyl lulido. /«~ 4.2 UN 2221 J-Z UN IW7 3J UN itrr Alumtmwan atkyta. Set M.etal alk>hk n.o i. •An twensk in oohima one of thi> table indicate* an entry thai was added or ctuuifvd it « FR 502J4, October 3], 1963. [S«C. 172.102] OPTIONAL TABLE 172.102 Optional Hazardous Materials Table (Cont'd) (I) m (3) (4) (D (J) (3) (4) Idmu- Identi- IMCO Note, IMCO Hazardow Mauritti Deacriptioi and Proper SMppinf Nana ncation and HaurdoM Matenala Docnpuoa tad Proper Saippint Namet On ficalica and Cla. Number Symbol Number Ahavmv'uBi borohydnde or Aluminium borohydride m devioa 4.2 UN 2170 ' AmmOBMm nitrate, with more thorn &1% ff writ/it of etmoutliole I.I D UN 0222 noaonm wKVueVitf oaf orotuuc mmuomee coJcuMUo' ta cmrwon. fo He orAuiui mfomj other mimai rmoaomce Amnmium mtntt. with not more Ihmm 0.2% of comouaiole moaonce 5.1 UN 1942 1 UN 1725 1 UN23M Ho* of o*r other orH ainmnrr "liiaiiiiiiiii iiiliiili 4.3 UN 1394 Ammoniam Krchkxau 5.1 UN 1442 AlMMiMiiBi cMoridc. aBhydfOM 1 UN 1726 N Ammanium perchlomc, ffermet morHele tar. mm thtn 45 miamea 1.1D UN 0402 AlttmtfMiim chloride totnttcm UN 25«! 1 5.1 UN 1444 AhBBttMim femwhcoB, fo*-wtr 43 UN 13»5 •N Ammomum picrale. o'rr or wmet with lea thn 10% woter, tf weifhi I.ID UN 0004 AJamwum hydntk 4.2 UN 2*43 1 ninnninm picrale. iMtiefl. with not lm thorn 10% woier. ojr weitfil 4.1 UN 1310 Ammimum ntnit 3 1 UN 1431 ". • Ammowim picntc, wetted. MM not lorn that 33 1/3 % woter. of 4.1 UN 1310 Aiwminium phosphide 4.3 UN 1397 weifrii Ammoniym polyMlphide. aglution 1 UN 2111 AlMmUium powder, ooaiad 41 UN IX» 6.1 UN 2161 • Aluminium, powder, pyrophonc Srr Pymphonc metab Ammonium silicofliionde 6.1 UN 2154 1 UN 2613 AlMBomvm, powder. .m^oa!.*.. mam-fyn^t.onc 4.3 UN 1396 Ammonium wlphide, tolution AJommium rooaatc 4.1 UN 2715 Alammium tihcoft, *oWrf. trnooa tW 4.3 UN 13«t Ammunition, illuminaring. with or wilrma turner, rjfellitt chaite or 1.4 G UN 0297 2-Amtiio-i-chlorophei.ol 61 UN 2673 frofelUnf chorft . 61 UN 2*46 N Ammunition. Ulumutalinf, with or without hunter. Oftllint charfe or I.2O UN 0171 N-Ammoettiylpipcrazioe i UN2J15 N Ammunition, Ulummarini. with or without hunter, afellinf choree «r 1.3G UN 02 54 AmtaopaenoB (»-, m~, ^-) 6.1 UN 2512 trope/lint charfe • Ammopyridtaes (». m-. f-) 61 UN 2671 N Ammunition, inomdiKry, Zifvii* or gel. with oitnter. txfetling charge 1.3J UN 0247 Ammonia, tmkrdmti. titfttrfieti or ammonia aointtoiu. denary (specific 2.3 UN 1005 or fraoellint charfr grvttyf /CB rAtM Q.MO «l /J ttmfgrra C « *«wr, OCMUIWIU m«* Ammuiiitioa, nwcnduvy (other than water+ctimueo1 ammunition). 1.4 G UN 0300 mm 30% *v*mo«.a without while phmohai m or mhtofhuies. wah or without ovraer. • Ammonia totubons ttfnaty fjfvct^c frwirrJ fcrn^K-n 0.890 ctiut 0.957 I UN 26?: etfellimi charte or orofeUint chaite ot 15 def C. i* water, wttk man iktm 10% tvut not meet tttan J5% N Ammunition, incendiary (other than water-octiwitee' ammitnitiotil. I.2G UN 0009 •MimOHta. Of aVTaf *J without what mhcofhana or fhoMphidea. with or without hunter. Ammonia solution*, tttnary {tpecific twity) ten rAan AMD at 15 22 UN 2073 ufelliKf charfe or froorllinf charfe affr-fo C i« MITT, «bMiai*t4f men lAa* JJ% ami MM -xvr rAaw N Ammunition, iaceadiary (other than woter-ataiatea ammunition}. 1.3G UN 0010 J0% ammonia. without white phosphorus or phcaphuia. with or without hunter, Ammonium tnaatu 6 1 UN 134« expelling charte orpropelkng charfe Ammonium btfluonde. Stx Ammonium hydrofen fluonde N Ammunition, incendiary, while phoaphomt, with tunur. eiprllinf I.2H UN 0243 Ammoniiun dichramaie 3 1 UN 1439 charfe or prvptllint charte Ammonium dtmmj-o-craoUie 61 UN 1143 N AmmunitiOB. •cendinnr, while phoaphonn, MI* hunter, expelling 1.3H UN 0244 rjiarte or praprJIimt charte Amawntion, practice 1.4G UN 0342 Aaanwaition, proof 1.4G UN03U Ammonium fluonde 6.1 UN 1505 N Ammumtioa, •noke (other than Mairr-tenivW ammunittoHf without I.2G UN 0015 AmmoniwD hydrofen fluonde, idid 1 UN 1777 whrte pfuwpfmut or oharfhr»n> wah or mahout hunter, expelling AmnMMMBB hydrofen fluonde. mtutton 1 UN 2JI7 charge or mropetUmt chart* Ammomua hydrofai aulphnie UN 2506 N Amnumitioe, Mnke (other than MUnvedrMMa1 ommuiirtotl without 1.3G UN 0016 white phaaphona or ohcaphiatt. with or without hunter, ^xpellint 6.1 UN 2»«9 charge or propellint c*»I» • Ammonium artnu feruhzen. e.o L ! 1 UN 20^2 N AmMuaEUOB. nainfcB (other than water^aiwuej ammunition} without 1.4G UN 0303 whae phaaphjonu or amaaphmin with or without hunter, expelling rjuwte or pmpeUimt chart* N AaununiDoa. moke, white phoaphonai (other than water~aclnatad I.2H UN 0245 Ammonium utraie fertduerv of the tome armpautio* at dtfirtrd in 1 1 D i'N(i::3 d-m 5. 1 tm w 5015 «W 5016 of //W IMCOCode tmt er^iammg ammunition/, with hunter, expelling charge or propelling charte fntarr «mow<«a V"VIC «W/*»f ownAiunM' mater!*, titan spm- N Ammunition, amoke, white phoapjtonai (ether than wote^mctiwjtea' 1.3K UN 0246 ammunition), with hunter, expelling charge or propelling emerge • (\ inmnniisai aucnat Cenibxeri, r-w ^ Ammunition, tear producing, aon-eKpiocive, with neither huraer nor 6.1 UN 2017 ^ Unifor'm mom teg •yyaoiy *tuc/tir0 «V •fmMKMium *ttrau .rtttt 3 1 UN 2067 N Antmuniuon. tear producuic. with owner, expelling charte or promt!- 1.2G UNOOH mmmoMm wfrauc (wtMnww AM Jea *AM ft/% «V»im-joii/-m umg I'hmne wrrair jW «M wef* (Aon 5*?% [See. 172.102] OPTIONAL TABLE 172.102 Optional Hazardous Materials Table (Cont'd) (1) (3) (4) ; (l) (J) (3) (4) Uaxi- IdCTO- Ham IMCO Nou. IMCO mi Hu-vdov- M*urruk Deacnpuna tad Fropcf Shipping Name* ClMi nd Hiuntoui Muenilt Dacnpuon md Proper 5h»jpm Nuna Srata* Numbcr Symbol. Nuinbe> 3.2 UN till I.4O UN 0353 ^I^MkL. 3.3 UN 1110 Arucla. eiptaivt. i-o* I.4S UN01*» Aayliilntt 3.3 UN 1112 AMyl write 3.1 UN 1113 N ArocUc ciplcunc. 1.04. 1.IL UN 03 54 tort ABY! Mfni T «fiMlW MTM» ^A £-•/ 5.2 UN 219* N Anideft, apiaww, B-C^I. 12L UN 0355 N ARicka. eiptauive. i^u. I.3L UN 03S6 101-Aajyl perayMdccwnite •*« ll fcut #% fMrfmaatr 5J UN 21*1 N Anfcta. pyrophotic I.2L UN 0310 • UN 2212 * A+mM, MM lerl'AjMjrl perosypivtlafe •uximMm cMcrMiwiM 77% i* aWvriM 5.2 UN 2937 9 UN 23*3 Alfk>h al-biekl. Sir C«-a>ckv f^ltfll tr tmmt* Anyl trickkxotuuM 1 UN 1721 * 2J'-Ajodi<2.*-dinic (1) (3) (4) (1) <2> (4) Idcno- lri«nfi- IMCO Notn MCO and Haurdoui Milcruli De •euoyt peniide, " m tmamaim if mot* i*n 72* aw ten Bronoaortyl bromide 1 UN 2JI3 4.1 UN 1327 Bhuia Brooooeruene 3.3 UN 2514 Bifluondn, a.o.*. 1 UN 1740 * UN 1644 • Bromobmzyl cyarudc* 61 Bipyridilium peHicida, liquid, flammable, toik, B.O.X., ftastifioiiu Ira 3.2 UN27U UN 1339 <*M 21 Jet C l-Bromobuune 32 Bromochtoromethane 0.1 UN 1117 2-Bromorthyl ethyl etfaer 3.2 UN 2340 Bromofora 6 1 UN 2513 Bipyriditium peKicidet, liquid, IOXK, flammable, H.O.S., flashpoint 61 UN 3015 UN 2341 towttn 13 dfi C«W 61 ft? C 1 - Bromc- 3- methyfbutane 32 t.l UN 3015 3.2 UN 2342 Bromomethyrpropaaei 3.3 UN 1342 6.1 UN 3015 2-BroeoopeaUDc 3.2 UN 2343 Broroopropaael 3.2 UN2J44 • Bipyndilium pexticidek, liquid, toxic, o.o.*. 6.1 UN 3016 BromopropaAoi 3.3 UN 1344 t.l UN 3016 3-Bromopropyrie 3.2 UN 2345 6.1 UN 3016 Bromolnfluoroethylene 11 UN 2419 • Bipyridilium pcuicidct, tolid, toiic, B.O.I. t.l UN 1711 Bromotnfluorometaanc 12 UN 100* t.l UN 2711 Bmone 6.1 UN 1570 0.1 UN 2711 N Burucn. otfieant MD UN.OM3 UN 2W3 Buudien*. mkHiuat 11 UN~ 1010 Baunedione 3.2 UN 1344 N Black powder, cooiareeaed I.1D UN 0021 • Buuar or butane mixlurei 11 UN 1011 N Black powder, gmutlmr or m Me«7 MD UN 0017 • lac-Buunol 3J UN 1120 Bleaching powder. Se* Calcium hypochlorite aiixturea, dry, wiVA • tcn-Buiaool A 3.2 UN 1120 man MM 10% tot met man r«0n 39% mwiobtt cftJonn« Bound 3.3 UN 1120 Blue aabcaloi S«f Ajbeiloi. brue Butene. Sn Bulylene N BoajbL conuuuni flannable Hquid. wUk *«mi«j c*»f I.IJ UN03W Butoxyl 3.3 UN 2701 N Bombt, conuiauii flammable bquid, •»* buntutf cAurrf 1.11 UN 0400 Butyl aortaiex 3.2 UN 1123 N Bombx, photo-flaih MD UN 0031 Bulyl aad pboaphau 1 UN 1711 N Boenbt, photo-flaih I.IF UN 0037 N Bombt, photo-flath I.2O UN 0039 Buiylacryuuc mhrbncd 3.3 UN 1341 N Bombx, phou>Haah I.3C UN 0199 rWtyl tlcohoi Str Butanol Bombs, imokc, cpflMMfMf • eorromte HajuU. wtm^xftotna. mlhoitt 1 UN 2021 aac-Bwyl alcokol. Snr MC-Biiua [Stc. 172.102] OPTIONAL TABLE 172.102 Optional Hazardous Materials Table (Cont'd) (I) tt) (3) (1) (2) (J) (4) Noua Identi Noun Meno- IMCO IMCO •ad Haurdou. Mauna* Docnpooo and Proper Sfcf>pin« Namei fication and Hazardoua Materials Deacrictioil aad Proper tnuyyiaf Name* Claai dam fkatxm Symbol Number Symbtb Numter * *0i>Buty1 hydreperoudc, maximum eomcmtnhen tO% in « •myric anhydride 1 UN 2739 Bttrraanrik 3.2 UN 2411 ten-Butyl bydraprruude. maximum concentration 73% witn muter 5.2 UN 209) * N-^Bwtyl mudAiote 61 UN 2690 Butyryl cMonde 3.2 UN 2333 tot-Butyl mttcyttaie UN 24M 3.2 Cacodybcaorf .., UN 1572 UN 2570 mrtofitfmKymu* 3j UN 1415 Cadamm comooiaadi 6.1 61 UN 2570 iutyi nercaptaa 3.2 UN 2347 Caeaium hydroiide. aolid I UN 2612 •-Butyl Mthacrylate 3.3 UN 2227 Oiiiam cydroudc. loliruo. t UN 26*1 Bwyl nethyl ether 3.2 UN 2350 rajimm, mtttl 4.3 UN 1407 • ten- Butyl monopennymaJeiie. maximum contentferion 55% at t 3.2 UN 2101 raraiiim nnralr 5 1 UN 1451 Cafiium, punlttid. Srr Pyrephoric metala • ten -Butyl monoperotyinaleatc. maximum eonctntntic* 55% in jo/u- 3.2 UN 2100 Calcium anenate 6 1 L'N 1513 ftCM Calcium anenate and aramite, totid mutntrtt 6 1 UN 1574 • ten-Butyl monopero^auUeate, terkiucaJ pure 5.2 UN 2099 Calcium boulphiie, aWanon. Stt Calcium hydrogen wlphtte. xWvuot ten- Butyl mooopeixiiyphthalaic. uettnteai pun 5.2 UN 2105 Calcium carbide 43 L'N 1402 Butyl nunie 3.2 UN 2351 ten-Butyl pcroiKk. i*r Dvteri -butyl peroxide Calcium chlorate 5.1 UN 1457 ten-Butyl peroxyKvute, tn a conttntnnon of mart tnan 52% Mr * 5.2 UN 2095 maximum eoncrntretton of 76% t* tolutum Calrinm chlorate, •fttfnu tolunon 3.1 UN 2479 ten-Butyl peroxyaceuic, maximum conctntntnon J,?% in solution 5.2 UN 2096 Calcium chlonte J.I UN 1453 ten-Butyl peroxyfeeiuatte, maximum eonetntrwum 75% « xVttfiM 3.2 UN 2091 ten-Butyl peroivt-tiumie, utfuucol pun or a a eoncfntraaon of 5.2 UN 2097 man ikan 75% IM xdvito* • Calcium cyanamide. n*uinin$ mon Ike* <2/% and %x mon tt»n 43 UN 1403 • ten-Butyl peroiytwruoaie wiiA 01 -KW 50% inert inorganic mid 5.2 UN 2190 O.i% ofcalavm eartWr irn-Butyl peroiycrwooaie, maximum eoncenmnon ?6% in JO/HAM 5.2 UN 2113 • Carniim cyanamide, conMii'Rjt men (Ao^ Q 3% of aJfrum oer^id> 43 UN 1403 o- Butyl peroiydicartonatc, in a eoncmtretuxi of man inan 27% lea 5.2 UN 2169 Calaum cyaude 61 L'N 1575 maximum conceit: *ottoti of $2% in toJuiton Calcium hydnde 43 UN 1404 a-Butyl peroxydicart>onaie, maximum concentration 27% tn solution 5.2 UN 2170 Calrium hydrcaulphile 4.2 UN 1913 • ten- Butyl peroiydtethyumcetate, (in a maxim vm concentration of 5.2 UN 2551 • Calciuai hypcchlorate, hydnuxl or Calciuoj hypochlonie. hydraied 5.1 UN 2MO 33%). with ten-buiy'l peroiyfaeoxaaie. (tn a maximum contemn- mutuna vuA KM Ita ike* 5.3% £•/ nor mort lAoji 10% MVHT non of 33%). and MfA toi^tnt len-Butyl perox>dicthy.acetau. ttfbutccJ purr 5.2 UN 2144 • Calcium hypcchlomt dry or Calcium hypcchlonu miiturea. mk , 1 1 L'N P4I • ten- Butyl peroi*-;-ethy!h«uf>otte, maximum eom^nmnon 30% 5.2 UN 2M6 man c*«4 39% avaifoMr fManm ft.8% fmtlaM* agjf fnl with 2.2-dMiert-butvl peroi^) butane maximum conetntfttton Calcium hypocMorite mutant, dry. MM man titait 10%, t*t lot '. 5 I UN 220* J5% 9*4 wtih AM It&x 15% pnJefmatutr IHVT iA« 39%. •w/lanV ditvint urn-Butyl peroiy-:^thylhc«noate maximum eonttniratiofi 12% 5.2 UN2H7 Calcium maafaneae aUicon 4 j L'N J>44 with 2.2-dHtrn-buivl peroiv ^butane maxim mm c**ct*tranon L'N 1401 }4%. and wi/A Jt ttasi 14% pilffmatutr and 60% inert inofftnie Cakium anrate 5 1 L> 1454 tcn-Buiyl peroty-* 6.1 UN 2991 Butyl tnchtoro.tiuuK 1 UN 1747 • CafbMHac paauodea, linuH. louc, a^)-L 6.1 UN 1992 6 1 L'N !W Butyl vmyl ether. inJubfifd 3.2 UN 2352 61 L'N 2997 * 1 ,4- But yned KM 4.1 UN 2716 Caitamaat ptainrtiu. lolid. louc. a-OJ. 6.1 UN 2757 6.1 L'N 2757 Bmyraldebydc 3.2 UN ll» Caftohc acid. 5«r Ptaeaoav PHe«ol ulucnm tr PtaaoL molten Mryraldoumr J.3 UN 2MO Carton Ktrvwd 4J UN 1362 (S4K. 172.102] OPTIONAL TABLE 172.102 Optional Hazardous Materials Table (Cont'd) (1) (2) (3) (4) (1) (2) ,3, (4, Idertti- Notaa IMCO Idenb- Nous IMCO aad Hazardous Materials Description and Proper Shipping Names ncaoon Haurdoa Materials Deacnpuon and Proper Shipping Names dans ftcaooa and Oass Symbols Number Symbols Number • Carton. awim*/ at wiyseMr enti* 4.2 UN IMI Cernjsa, crude, aleh v infoo 4.1 UN 1333 Caiboa kssiilpl»id«. £rr Carton dssuJphide Charcoal, activated Sn Carbon, activated Carbon dioiide 2.2 UN 1013 • Giawcaai aim ai n paMat of antmal at ttftueit onftn Stt Carbon, of • Caiton dioiide and ctfcyhne oudc mixuara vvfa men IASM d% 2.3 UN 1041 •aiaW or stfisa6^r onr'i tAyttm ttxmV N Charges, doBoktna 1.1D UN (DM • Carton dioxide and ethyfcK oxide niinirel •** MV men <*M i% 2.3 UN 1*32 N Charges, depth 1 ID UN 0056 N Chargat, propelling, for cannon 1 1C UN 0279 Carbon dnude and nnroys oudc mumaa 2-2 UN 1013 •N Cbargo. propeUuig. for cannon 12C UN 0414 Carton dioiide and oiygea. miiiura 2J UN 1014 N Chargo. propelling, for cannon I.JC UN024J Carbon dioiide, refhgentad lnjMid 12 UN 2117 N Charges. pnpeUug, for rocket rnoton 1 1C UN 0271 • Carbon dniide, sobd 9 UN 114) •N Oiargsi. propelling, for rocket amors 1.2C UN 0415 Carbon imulphide 3.1 UN 1131 N Olarfea, propeUiag. for rocket moton 1 JC UN 0272 N Charges, proDdbag. for rocket axxorv nmfastu murirnr 1 1C UN 0273 Carbon monoiide 2.1 UN 1016 •N Charges, propefling, for rocket motorv mnpotitt iwxtuir I.2C UN 0416 N Charges, propribng. for rocket motorv owuxauw <*uxnvr I.JC UN 0274 • Carbon monoxide and hydrogen mixture 2.3 UN 2600 •N Charges, shaped, commercial. MrfcMi dtiaalor 1 ID UN 0059 Carom paptr. Stt Paper, rrteied mtlt awaunttii otU. OKompttuty Charges, shaped, fleiiblc linear, mm/ clad 1.4 D UN 023T Intd N Charges, shaped, fleiible. linear, mtal clad 1 ID UN 02!8 Carbon remover, liqutd 3.2 UN 1132 N Charges, wpplemeniary. explosive 1.ID UN 0060 Carbon sulphide. Sft Carbon daulprude Chloral ««*>rrfro«a. AiAifcttrf 6 1 L'N20?5 Carbon tetrabroaude 6.1 UN 2)16 • Chlorate and bonst*. mixtures S.I UN 1451 Carbon uarachlondc 6.1 UN 1*46 CentenX c/Uonst Stt Phoagene • Chlorate and magnesium chloride, muiure 3 1 UN 1459 Carbonyl flaonde 2.3 UN 2417 * • Caftonyl sulfide 2.3 UN 2204 Chloraies, inorganic, n.o s. 5 U UN 1*61 • 9 Cavtnoav oxatx Stt rsan canridgea Chloric acid solution wrA wx monr inan 10% aad 5.1 UN 2626 N Cartridges, flaih 1.IO UN 004» • Chlorine 13 UN 1017 N Canridga. fash 1 JO UN 0030 Canridgea for weapon, blank 1.4 C UN 0331 Chlorine penufluondc 2.3 UN25*« 'N Cartridges for weapon, blank I.2C UN 0413 N Canridga for weapon, blank I.1C UN 0326 Chlonne tnfluonde 13 UN 1749 N Canndgo for weapons, blank I.JC UN 0327 4 Canridgea for weapon, blank ar Cartridges, safety, blank 1.4 S UN 0014 Chloritek awrganic. n.o.s. 3.1 UN 1*62 Canridgo for weapon. ooWr rAan Mao* 1.4 S UN 0012 Chloroaceuldehvile 6.1 UN 2232 I UN 1730 N Canridgea for weapons. «tt* aa/maf c*sirff LIE UN 0006 Chloroaceuc aad. banjo* N Canndgei for weapon*. •«* mtrmtf C/WT* 1.2E UN 0321 . Chloroaceac acid, solid 1 VN 1751 N Canridgea for weapons, •«* teneiag ckarp I.IF UN 009) Chloroacetonc, mablotd 6.1 UN I6W N Canridgo for weapon, antA awsn'iiy eemrft I.2F UN 0007 Cbloroacctonitrue 6.1 UN 2661 • Canridga for waapoaa, nr> tsmutf eaarp I.4E UN 0412 I N Canridga for « <•!••. as* aanftg r*a/jr I.4F UN 0341 ( Canndga for weapons, wna BMrt projectile 1.4 C UN03M Chloroaoetophenooe 61 UN IW7 N Canridgo for weapons, waft son projectile I.2C UN 0321 CMoroacetyl cbtoode * 1 UN 1752 •N Canndga for weapons, with men projectile i.x: UN 0417 Oiloroaaibnea, Itruid 6.1 UN 2019 ! Canndgea. oil wefl 1.4 C UN 0271 Chkoroaatbao, >oi*d 6.1 UN 2011 N Cartndgea. oil well IJC UN 0277 p-Chloro-o-aaiaidine 6.1 UN 2233 Cartndgea, power device 1.4 C UN 0276 Chlorobrrucae 3.3 UN 1134 Cartridges, power device 1.4 S UN 0323 ChJorobcsuotnfluonda 3J UN 223* p-Chlorobeuoyl peroxide. Stt Di*<* |S«C. 172.102] OPTIONAL TABLE 172.102 Optional Hazardous Materials Table (Cont'd) (1) (2) (3) (D 0) (3) (4) New Idcnu- Noua lantt- IMCO IMCO Hazardous Materute Docnpttoa and Proper Shipping Name* •ad 5cauon and Oat HuardOM VUteriali Deacripooa aod Proper StiippBf Nana Cbe> Svmbote Number S^mboto Number CUoropemjuftttoro.nlu.ae 2.2 UN 1020 Copper aceuaneoitc UN 131) . £OUoropcroiyteBioic acid, maximum oMrnvrvrkM W* 5.2 UN 2733 Copper anenHe 4.1 UN I5M CWoropheiaie*. bqtud 1 UN2*>4 * Copper band peuicidci. ItiHiid. flea anal ifa, mic, BA>. flitlifoiiu J.I UN 5716 Cakmoncnaio, »ohd 1 UN 2905 ImMmUAtC OUoropheBoax bquid 6.1 UN2O2I OOorophenok. aolid 6.1 UN 2020 CUoropacatyt trichloroail.ne 1 UN I73J * Copper beod pailicidll. **»d, louc, flamBable, B.O.L. fadtfoiiu 6.1 UN 3009 . QtJoropicra 6.1 UN 1310 amwo il *f C «W tl &tC CUoropicria aad aacihyl aw CUoropicria aad metbyt cUoride. mantra 2.J UN 1512 6.1 UN JOOT . . Chloropicnft mixture*, R.O.*. 6.1 UN 1SW • Copper bawd pauicidai. ftqwd. louc. 0.0.1. 6.1 UN 3010 6.1 UN I3U 6.1 UN 3010 ChJoropUiiiuc acid. >olid 1 UN 25O7 61 UN 3010 CMoropreae. inhibited 3.2 UN 1991 • Copper bated panic ide«. wlid. B"c. a-oj. 61 UN 277J 6.1 UN 2773 3 1 UN 2356 2-Chloropropane Copper chlorate 5.1 UN 2721 J-'CUoropropanol") 6 1 UN2M9 2-OUoroprapeac 3 1 UN 2436 Copper cyanide 6.1 UN IJt7 CUotoprap.oajc mod 1 UN 2311 Copra 4.2 UN 1363 • 2-atforopyndine 61 UN 2112 Chteroauipnofuc acid. **/* or vakotti odpkttr triaiJdt 1 UN I7J4 Cor4,delo»iD*f./ki»^ 1.4 D UN 02*9 Chloroieuafluoroethane 2.2 UN MQ1 N Cord. deioa«iia(. fltxMt 1 ID UN 0065 Chtorotohicaea to-, m-. p~) 3.3 UN 12 14 N Cord, doonami. meaW clod 1 ID UN 0290 4-Chloro-o-ioluidinc hydrochtondc 6.1 UN 1579 N Cord, dctoaauaa. Meiat cM 1.2D UN 010! Qiloroioluidtnei 6.1 UN 22J9 Cord, detoulint. nild effect, mml d*f 1.4 D UN 0104 QikxotnfluoroethtiK 2.2 UN 1913 Cord, ifmitt 1.4 O UN 0066 CkionxnflMonttkmm*. See TrifluonxhkM-oeihane • Corroaive bqtadi. flamauble. B.O.I. 1 UN 2920 CUofftr]/Ji**unkjiit*4. SAT Triflnorochk)roethyl«iK QikrromfluororoethuK 2.2 UN IOJ2 • Corrouve tiquidt. B.OX 1 UN 1760 ChkHotnfluoromethaae and irtfluorrnethaae ucotropk mixture w\tk 2.2 UN 2399 I UN 1760 ffftwumaltfy 60% cMomr\fl*ar*metk*»t • Cormive Kquid* pooonoio. B.O.L I UN 2922 • Chronic add, total Set Cbromiwai tnoxide, aahydroui « Corroiive tohdi, OamiMhlr a^^ 1 UN 2921 Chronic acid, niunom 1 UN P55 Chronic aahydndc. S*t Chromua tnoxxle, anhydrous • Corroirve tolidi. «.oj. 1 UN 1759 • Chronic fluoridc, tolid 1 UN 17J6 I UN 1739 Ckroawc Aaocidc, •otvooa 1 UN 1757 • Corroaive wlidv poiaoacm, BJXI. 1 UN 2923 Chromun ahrau 5.1 UN 2720 • Coametici. Stt Perrtonery proiiucu Chromium oiychlonde 1 UN P5t Conoa, dry. Sn nbm. xynMk *r> • COKOB nain, oily trnifrtpml •«* lot itai 1% if vumel or 4.2 UN 1364 * Chromium trioiide, anhydrous 5.1 UN 1463 • Cooon waiu. cdy ^fn^msttd wfA j%. af nwrc, •/ eiufiw/ or 4.2 UN 1364 t**^V*^«* 1 UN 2240 C^ottr,»r«.-.»«rf 4.2 UN 1365 Ouysoal*. Set Atbeuoi, while Crook (IK m-. f-l 6.1 UN 2076 4 1 UN 1M7 Craylicaod 6.1 UN 2022 Ckeuuos compound. Sw FUmnMbte Hqvid prepkruoons. n.o.i. Crocidoliu. Vr Aibeawt, blue * 2.3 UN 102J Coal CM CiDtoaaldeayde, nh*uec! 3.2 UN 1143 Croloaic acid 1 UN 2123 . Coal ur dtsutlcte 32 UN 11M 3J UN 11 J6 CrMoayleac 3.1 UN 1144 Coal ur aaphtha 32 UN 2553 CiuneM hydroperoude. Stt Cumyl hydroperoud* Coal ur od. St* Coal ur dtstilUte Cumyl hydroperoude. iKtuucmt fw* 5.2 UN 2116 rrnriaf aaluaoa 3.2 UN 1139 * Caoiyl peroiyacodeeaaaua, mammiat eaamMnaaaii 77% tn tohtuoa 5.2 UN 2963 3.3 UN 1139 Citmh •nhthrnairi mi rfir 4.1 UN 2OOI « Cumyl pcroiypivBlai*. »iaum«>« caacnowiM 77% Hi minim 3.2 UPI1 IN 4TO4>4riU _ . . ^^— _ rr ^ 4.1 UN 1311 Coccul«.^W 6.1 UN I5»4 Cutftf nwueK. JM* OutiffBl cyanide Cotofar aptnt*. S*r Ethaaol 1 UN 1761 Cohtaataaa apiritt. Str Methaool Cataacta. aaitofc er Hauum 3.2 UN IW9 J.J UN 1999 fVMaipe.«Mi aiay ^ CUiOW< tTUA, 8 O t 14B UN 0313 1.4 S UN 0070 Conpoaana, ciptoanfc torn, a-ai- I.4S UN 03*4 Cunen. cable, eiptoaive Cyanide auuufa. iW CrB-idea. |S*c. 172.102) OPTIONAL TABLE 172.102 Optional Hazardous Materials Table (Cont'd) (I) (2) (3) (4) (1) (2) (3) w Notes Identi Novas IMCO IMCO ftcanoa and Hazardous Materials Description and Proper Shipping Names Ous fication and Hazardous Material! Daachptiaai an4 Proper Sbpamf NaaMa Oaas Jy-toi, Number Symbols Number C^"d ——————— 61 UN 2744 Dtkwyi piKPtyii*CaMTtoB*Kt MaulMst***] cwpMWaaW •/% >Wn UN 214* Mbcfwa* 2.1 UN 1*11 • 1.3,9-CyclododecMriene 1 UN 2511 Cyctohepttne 3.2 UN 2141 DfereaBobauene 3.J UN 2711 CycttKBtairieM 3.2 UN 2603 U-P*romntia»aa 3-one 41 UN 2641 1 ^-DibrasM>34kloropfejt>iM 4.1 UNMT2 CyctokepMat. 3.2 UN 2242 MA \a\ il a UN 1*41 CydoheuM 3.1 UN 1145 Crdobeianone 3.3 UN 1*15 DaVoaaoaseiaeax (.1 UN 26*4 Cydohaanone peniidea, fa • etattnlration of man inan 90% wiln 5.2 UN 2117 T*t (' Vinr'TTui— T 1 UN 2241 la, ilia* 10% mam Cydohexanoae peroxides, maximum eonetmtratum 90%. mitk at baa 5.2 UN 211* *J *> »V! _ L— . .!.-.;_.— (J.-.fc.J 61 UN2J73 10% maltr . 5.2 UN 21*4 Cydohelanone peroxides, maximum coMtntmtori 72% ana contain- 5.2 UN 2111 mm* 42%. *t*Mr auftma* m [Sec. 172.102] OPTIONAL TABLE 172.102 Optional Hazardons Material* Table (Cont'd) (1) 0) (3) <0 m (3) (4) Idexn- Idnn- Nou> IMCO Notea IMCO ficauoa Hazardous Muenak) Deacripooa and Proper Shrppaif Htma Claai ricaoon and Haurdoia Maierah Decnrxion ind Proper Shippuif Narta d— Sya*ob Number Symbol. Number -~ . 1 . . 6.1 UN 2230 2,1-Dihydropyru 3.2 UN 2376 V DMI-kydroiy cycloheiyi) peroude. urlutml f*n 5.2 UN 2141 1 UN 1764 DicHeirVeayl r/iehloroaUaae DiKtMlylawiiic 33 UN 23*1 6.1 UN 2730 Diaobwykoe. (mmtne ranaxuxM 3.2 UN 2030 1.1 UN 2047 DfcWoroprofMM Dnotalyl kctoM 3.3 UN 1157 2.3 UN 2119 Pirilarnalail Diiaoocryt acid phocphate 1 UN 1902 2.2 UN If31 Dumpropylamine V2 UN 1131 DK-* ami*. axtaW^. ~ -» -m-W 3.2 UN 2121 Dnagpropylbevene hydroi^rrotibe. mujtutwm cWKtmrmno* 72% 'ft 32 UN 2171 1 UN 23*5 "£°*^ . 6.1 UN 2617 1 UN 2123 3.1 UN 2151 Dnupreprl ethar J.I UN 1 1 W ••air Dmopropyl pemiy4i*c*fDanau, t4c*mc*l pun 52 UN 2133 5J UN 2132 Dinopropyl peroiydicarctonalc. maximum m*cr*ittxi* 52* te »• 5.2 UN 2134 DicydopeMadiea* 3.3 UN20M /MKM CMecanoyl peronde, itdaiefl fun 3.2 UN 2120 « Dinotndecyl pcroudtcarboaate. *fk*icai purr 5.2 UN 2119 • 2,2-Di-<4,4-dMen-bmTilperoiy cydooayl) propnac, awfnui eo*. 5J UN 2161 Diketrne. inhibiied 3.3 UN 25JI • DiUuroyl pcrotidc "loximwm riMcmtnafKM 42%. uatdr dlipefvo* "i 5 J UN 2I»J Di-2,4*hchk>robauoyt peroiide, MXMUUII axKeamatfai 75* •«* 3.2 UN 2137 •aler 52 UN 2124 Di-2.4Hiichlorobeuoyl peroiide. JHUMKWI eawmimabu 37* at « SJ UN 213t Dilauroy) peroiide. Ittttwel fvrt anv ' I.l-Dtmethoiyelhane 3 1 UN 2V7 I'N 2377 Di-2.44ichlorobeuay1 pcrnidc, mnimm eunamumOm J7% 1* " UN 2139 J2 1.2-Dimethoiyethanc 12 UN 2252 . \ _2-Di- Dwhyl ketoac 3.2 UN 1134 UN 2P4 DtabyhaanetMai 4.2 UN 1347 47% *ati waarr DHMiiyiduuM 3.2 UN 2707 33 UN 2707 DmkyHMMraaoaailiac 4.2 Dinelkyl dawiride ) 2 UN 2311 33 UN 1031 SJ UN 2173 Dimethyl ether 2.1 UN IOJ3 DwtkylMMtic 3.2 UN 2375 N.N-DtMMfrjnaamafc > 3 UN 2263 Dwiethylhydralinc. ifmattrrteml 32 UN JJI2 Dmkyl «%*«r 6.1 UN 1394 1 UN 2751 • Dta-rJiytardnnrH, iwymwraal 32 UN 1163 DKthylmc 4.2 UN 1346 Di-UytaH ———• 42 UN 1341 ,.,.D«——— —— 2.1 UN 1030 U^fi***-**. *, P.N- —————— hyun,^e 2.1 UN t»59 11 UN 2044 MHorm^^^M^-4-1 __ frr f^~-^— —•III __ DLl-a)! tl |nil|liaM»aii '"*" 32 UN 22*6 1 UN 17*1 t 3.] UN 2l7t Oaawtkyl i^lplmi 6.1 UN 1J93 P»-eHryl nlpaiili } 1 UN 11*4 (S*c. 172.102] OPTIONAL TABLE 172.102 Optional Hazardous Materials Table (Cont'd) (1) 0) (3) (4) (1) (2) I3t Noam IMCO Ue*a- Notei IMCO liJcnit •ad Hazardoaa Macro* Deacnption and Proper Skiapma. Name. ffxoaa •nd HaxardcNH Matcrub Deicnpiion and Proper Shipping Niniet Clftu Sy—x* Number Symboto Nufnher ttaaahyl thiontoaahoryl chloride 1 UN 2267 6 1 UN 3006 • nitnJorarhaaaii peancidat. tohd, toxic, n OJ 6 1 UN :?71 DieMtkytoxac 4.2 UN 1370 t 1 UN 2771 • Di-(3.3.5-tniaelky)-U-c1k>ioiuyl-3)peretide. ai « antr MiA •/ Irau 52 UN W> 5.2 UN 2142 SO%fU Epichturohydnn 6 1 I'V 2O23 DiaitrophenoU wetted •«*. IT -»tf/n a> Jaw /J* mlrr 4.1 UN 1320 1.2-Epoxy-3-ethyloxy prooue 3 3 UN 2'5: •N Diaitronaorcmol, dry or «wW WnUexr faea 0% water l.ID UN 0071 Eradicaton, feint or fmuc h?ui4 To ot clauifitd and labrbd at- UN l!50 Dnu'troreaorcmoL, welted wrA, Ay wtaAt. ar few* 75% ««urr 4.1 UN 1322 ardinf, te Inf princtptr Hatafdottt counrumi • Eaaracev Ser Extractx, aromaoc. liqwd N Dmitroaobenzene 1.3C UN 0*06 Ethane, compmstd : i UN 1035 • Duiitrototuenea, molten 6.1 UN 1600 Ethane, ftfitgtivttd lioiuJ 2 1 UN l»t>l • Diaatrotolucnet. loiid 6.1 UN 2031 • EthanoU/mnc or EthanoUmme voluuom t UN 2491 Di-n-nonanoyl peroxide, MrAmea/ an/v 3J UN 2130 Ethaaol ar Elkaaol mlynoei ineJudimf Alcoholic beveraaei 3.2 UN 1170 33 UN \n DM-octanoyl peroxide, ucnnual put* 5.2 UN 2129 Elhcr. Sff Diethyl ether Ethyl acetate 3.2 UN 1173 Dtoxane UN 1163 « Ethyl acetylene, inhibited 2 1 UN 2452 DioioUat 3.2 UN 1166 Ethyl acrylate. intMnd .12 UN 1917 Dipentene 3.3 UN 2052 Ethyl alcohol. S» Elhaaol • " Dtperoxyazelaic acid, maxima** comrurmaa* 21%. "*A not Im 5.2 UN 2931 Ethyl aldehyde. 5ar AcetaMehyde Ethyl alunnwtm dichlonde 4 : UN 1924 Diphenylaaunachloroar*oc 6.1 UN I6M DtphenytcttoroaneK 6.1 UN 1*99 Elhyi ahmnMm ieaquchiande 4 2 UN 192! 1 UN 17*9 • DiphenylmetBaae-«.4'diBocyanau 4.1 UN 24*9 EthyUouae 11 UN 1036 Dipheaylnethyl bromide 1 UN 1770 • Ethytamine loluuon in Mtirr. eoncrfitiuov ua (o 70% J ! UN 2270 •N l.ID UN 0*01 1)1 UN 2270 Dipicryl lulfide. dry or mtntd vv/A fesr aWa /0% walrr, Ajp »nj»A.r l 1 US 2170 Dtpicryl ulphidc. wetted >tl«. Ay a***i « iaor J(X% wmr 4.1 UN 2152 Ethyl amyl ketone 1.3 UN 2271 Dipi'opiofiyl peroude, mtrmum oMcrajnanaa 2f % at jaranbn 3.2 UN 2132 6 1 UN 22'J DipraeyUauiw 3.2 UN 2313 2-ElhylaniliM 4 1 UN i273 Dipropyl ether 3.1 UN 23*4 EthyfeeaztM U | UN IPS • Dnropyftxaoe* 3.3 UN no N-Etbyl-«^benzylaniUae 4 1 UN 2J74 CVivpropyl |.inii.liiiil..ian HnMoWaarf 3.2 UN 217* 41 UN 27S3 Ethyl borate .1 2 UN 1176 • rhaiiifnninll niniaiii mtfml nil 1 UN 1903 Ethyl bramdc 4.1 UN 1191 t Dwarfectaaah •** t aeavaaaft AVvatf or waW aj UN 1*01 Ethyl bfonoacetate LN 1603 6.1 UN 1601 6.1 UN 1*31 2-Elky1b«aaol 3 J UN227S • Danarylperexydicartioaate. >M M* aMar^ afcaaW 5J UN 2)92 Elhylbulyl acetate 3 3 UN 1177 t Duvccmc «od peroude. «i«JUMaiii eaanaaMH* 77*. »»nW a • Dnhkxarbaaaaic peabcideL bond. IOXK. faaBanabk. a^o^ ylaafr- 6.1 UN 3005 Etkft ctJancfrtanaM. far Elhyi cMorofomale ag«> t.r». U der C aW <7 4er C Ethyl chJoroforaaiu 12 UN 1112 6.1 UN 3005 • Ethyl-2-ckaxoprapioaata 33 UN 29J5 6.1 UN 3005 v ...... 1 UN2U» . D^KX-t———. peaoc^a, lur-J. ui_ __ 6.1 UN 300* Ethyl crtMCMle 3) UN llaj 6.1 UN 3006 Ethyl cyaaoacawe 6! UN 2*6* |S«e. 172.102] 10 OPTIONAL TABLE 172.102 Optional Hazardous Materials Table (Cont'd) (1) (2> (3) (0 a) (3) (4) Idera- Notes IMCO Identi- Nolea IMCO and HfturtVwci M*imib Docnptton MK) Proper Shippuic N»m« ficanon ncaoo. CI*M HuaniOM MMemii Docripra tmd fnfn Sfyfu* NM.W Symbol* Number Symtoh ' Eihyl-3.}*dMieri-bvtyiperoiy) butyraie. maximum concrnfuxm 5.2 UN 2113 N ExpfcMivn, WMtinc. Type B I ID UN 0012 77% M ja/nftM N ExphMVA, MMcm*. Type C 1.10 UN 0013 Eihyl-JJ-d^tCTi-buTyHperoiy) hutynue. wr***.*/ pu*e 5.2 UN21M N EJiptotrvai, li •••!•*, Type D 1.ID UN 00*4 E«pto.iv<«,b4MiM.TypcE 1.50 UN 0332 N Expiodva, blMiM. Type E I.1D UN 0241 j 2 • Extract., n nmmw., liqyid UN H«9 Ethy]-3.Mi(iCTi-bWylpefoiy)buiyru«, MI* «/ JNB/ J.HI- m«*t, MM*. 3.2 UN 25« 3.) UN 1169 fvmr jo/W Eitncu, Rawovrinc, bquid 3-2 UN 1197 Ethyl dKhtorOATMne 6. 1 UN in: 3.3 UN 1197 EfhyldKhkj«niUne 32 UN 111) • Fabric, tninul or vcgctabte. 5*« Fibm, Moowl or vcfet»bk Feme aneoaUc a.1 UN 1*06 Ethylene chlorohydna 6 I UN 113) Feme aVTMtuit UN 1*07 Feme chloride, atthydroai 1 UN 1773 Elhylene, compnsud : i UN l»62 Feme chloride, tohukM 1 UN 2312 EihyieAcdiaumne i UN 1«04 Ferric Bitnttc 9.1 UN 14M Ferrocenun 4.1 UN 1)23 61 UN I«3 Ethyiene dferoaide , Ferroulicoa, co*UH*t*t man itAatw 3O% Ki ka /A** 90% tilice* 4.3 UN 1401 EthylcM dtchioode 32 UN IIM Ferrow trkentte 61 UN laOl 3 ) UN 1133 Ethytcne glycol dtetiiyl ether Ferrous awui borinfv ihavirifK, tunua^, «v cutim|« M * form 4.2 UN 279) EJhytene (tlycol monobutyl ether M UN 1349 /MtWr 10 jr// ktmttnf Feniloer knt.noa.«6nf •otuttovu anuatiuitf fr** amntoiu* at cxccfl of 2.2 UN 104) • 4.2 UN 1)72 Ethytene jtycol monoethy! ether 33 UN 1171 Fibres, .wiin..! or vcfcUabk. btirmi. twr tw AMIV Ethykme gly«M monoethyl ether acetate 3.3 UN 1172 • Fibra or Ftbric. iai.n»J or vir^ubk. OMMuunf **** tko* S% of 4.2 UN 1)7) Ethytene flvco) motiometh>l ether 33 UN nil animal or vefetoMe at/ Ethylew flycol raoBomerhyl ether acetate 3.) UN IIW Flbrct. n| bthyliMthutynte UN 23«! FMhmeaJ «r AfjMCnp, A«A A.nwM iwmirrvW MO.VIW c«(ieiic u*- 4.2 UN 1)74 wrrwwrt >( oDfurai u atva of 12% IT *n»At Mfwtefcrf >/ Eihyl nocyAnaie " cmrnu m CXMB of // V Ay i-w^Ai. M nW AST o/ «JiiKuu4arir trwaul fWtmtil •ef&ucnt 3.3 UN 1192 ' Fithme«l or fkhscrxp. •« vuwu4a*i tn&d. mautw* cm**! r*"- 4.2 UN 1)74 Ethyl mcrcapufl 3 1 UN 2.V.3 rr r^M J% OM M( umirfim /7% *f Mnr»U >t amttni not J2 UN 2:-7 Ethyl meilucr>Ulr. inhibited * FlammoMt fai M ^«*cn, SM Lifliten lor cifmn tad cifiretieft, «c Ethyl methy! ether : i UN 1039 MlA JlommaMc gas E'hyl methyl kelone 32 UN 1193 • Fl»mm«tvk bqaid prapcnDMi. ».oj. 3.2 UN 1142 Eihyl methyl kelone prro>Kle(»l, mfjumum nxcnuoimi 60% <'J UN :ir> UN 1142 Ethyl nKl>i^ ketone prrrudeOk muim*m ammimto* SO%. mi- UN 2550 Fl»mm»b*e bqaids, oom»ve, 0^4. ).l UN 2724 Mininf *w meet titan tO% tmtloMf oz>yr« N tthyl methyl ketone peroiideut. maximum rMrMi'rolK^ £>%. cot. 3.2 UN 2924 . 3 1 I'N 1194 nimmarfih h-iiali • n i 3.1 UN l«93 Ethyl tulrnc mlununs UN I99J Elhyl orthotVirmate 3.) UN 2324 13 UN 199) «.! UN 2523 Ethyl oialalr , 3.1 UN1992 EthylphenykiichlriruKiUne * I'N J4)S 3.2 UN 1992 l-Eihvl ptpen^ine 3 2 UN 23U 3.) UN 1992 Ulhyl proptcnate \2 UN 1193 Ethyl propyl rther 1 1 UN 2«I3 Elhyl likcue Sfr Teuarthyi tihcMe t 4.1 UN 2923 1 UN 2"! • PUouMbic toiidm, m-ox 41 UN 1)23 N.hth>hn)uKline» lo.rn.fi r> 1 fNrM 4.1 UN 1323 4.1 UN2T2* 4.1 UN 293* •N 1.10 UN042O Cihyltnchloroulane 32 UN 1194 FUmaaral •N Flana, aerwj 1.10 UND421 N E>pla«iv [S«c. 172.102) 11 OPTIONAL TABLE 172.102 Optional Hazardous Materials Table (Cont'd) (2) (3) (4) (1) (2) (3) (4) Nowa Idenu- Notca Idenu- IMCO IMCO and Hazardous Mtlenah Deacnptttn and Pimni Shipeaaf Naatet Hazardout M«eriait Deicnptton and Proper Snipping Namea Oaa. and Cl—. Syntob Nunber Sy.bc* N umber Flam, aenal I.4S ITNO»04 *_ Owu petcha toUtncMi 3.2 UN 1203 3.3 UN 1203 •N Flam, terrace (akrr lAea •**<-atlnard floral 1.10 UN 0411 rUrniMl metal powder, dry 4J UN 2543 •N Flare, wrfacc (ailur I*M murt-ftntu*' floral UO UN 0419 • HaMM mtltl powder, werud. mdi mat lam nWa U% *»Hr la 4.1 UN 132o N Flam, mrface tailor tmta **nr artiigitt floral I.3O UN 0092 nWar cacao afwttfr mm* at arormlj moemaiueatly ffua'm.td fmru- Ft**, trf. Sit Horn. iiiHaUt, trf car mm km tka* 53 muemu. ar cmemuMlrr ptvtmcaa. particle oat Fluotenc acid' 1 UN 1773 lam <**• HO aaeram Photic >od. Sn Hydrolhaoric acid, aoluiioa Htlojea«larl Jmuunj bqadt. a-O-l. 6.1 UN 1610 Plworae, cMaanBBaa1 JJ UN 1043 Fhionaceuc add 6.1 UN 2*42 6.1 UN 1610 a 4-Fl»raa«utac 6.1 UN 2944 • 2-Fluoroamline 6.1 UN 2941 Fluorobeuene 3.2 UN 2317 Hay 4.1 UN 1327 UN 1776 Fluorophotphonc acid. artkfdrvta 1 UN 1046 Fluorotulphonic acid 1 UN 1777 HeNwi. rerriieraud hqojd 2.2 UN l%3 Fluor otoluenet 3.2 UN23H 3.3 UN 23<1 Hr*<+ trf. Sit Fikm. fttrlafii. trf Fluoulick acid 1 UN 1771 Heptane, artd to domm 3.2 UN 1206 Formaldehyde lolunoni 3.3 UN 1191 a-Hep«ae 3.2 UN 227J Formaldehyde, lolunoni \rtrti ifakfoi*! font SI mtfrtti C 9 UN 2209 Heuchloroacetoae 6.1 UN 2661 Formalin. Set Formaldehyde 6.1 UN 2729 Formic acid 1 UN 1779 6.1 UN 2379 ILjlu kLlMU ul Ini iiilli1i>Mr 6,1 UN 2646 N Fracturing dr. viccx eiptoaive. for oil wttb I.ID UN 0099 HeucMoropheoe 6.1 UN 2175 Fuel, aviation, nirottr tnfftt 3.2 UN IMJ Heuctocyt nckloroailane 1 UN !7«l Fuel, pyrophonc, a.oj. 4.2 UN IJ73 Hiurtirnr 3.1 UN 2451 HeiKlkyl Mtnphoaphau 6.1 UN 1611 6.1 UN 161 1 Fumaryl chloride 1 UN 1710 • Hexaethyl tatrapkocphaie fad coaBprcaacd pa matitrt 2.3 UN 1612 Furu 3.1 UN 2319 HciAfluoroaoekme 2.3 UN 2420 Furfural 3.3 UN 1199 HczairaoroacetDae bydralc 61 UN 2552 Furfuryl alcohol 61 UN 2174 Hriaflnnmclhaot 2.2 UN 2193 Furfurylamine 3.3 UN 2326 Htjui/laaronfcrjarjhoric acid 1 UN 1712 Fuae. igniter, tutelar, mftal dad 1.4 O UN 0103 Hcufiu^HuuJ'7>»~ 2.2 UN 1151 N FUM. instantaneous non-detonarjnf 1 JO UN 0101 HeiafcJefcydr. 3.3 UN 1207 FuMloil 3.2 UN 1201 1 UN 2210 • Fine, lafety 1.4 S UN 0105 1 UN 1713 6.1 UN 2211 1.4S UN 0347 . 3J UN. 2493 Fuzet. detonatuvc 141 UN 0257 5.2 UN 2166 c*uraaai 53% «T"«m '0*0?™° maamam can- N Fuzct, detonaonf I.I! UN 0106 UN 2167 N Furea. detonating I.2B UN 0107 1.M1T.T Hfllmrrlljrl I.T.1.* Irrranini prlnanMni. muimmm ea*- 5.J N Fuzet, detonating. **iM pnMi'tiit framra I.ID UN 0401 1.1 lift T- llnaiailli.l 1.1.1.1 lirn nrii-ji-|i«iri«ai urtitiittl fun 3.2 UN 2165 N Fuzet, detonating, M/A proutnve ftofara 1.2D UN 0409 Heumtne 4.1 UN 1321 N Fuze*. detonating. »u* |iig»tripi protmii 1.40 UN 0410 Heiane. am* la ammrt 3.1 UN 12M Fuzei, ifnitinf 145 UNOJ44 •N I.ID UN 0079 N Fuzet. ifTutui| I.JO UN 0316 N HcuawcatiRMae I.ID UN 0392 N Fuzet. i|mtm4 14O UN 0317 3.3 UN 22S2 GaJlium, mttol 1 UN2M3 N llnalriail rail I.ID UN 0393 Gat dnpa, kydfoca'too* JJ UN 1164 Hei-l-ane 3.1 UN 2370 Guoil 33 UN 1207 Gatolme 3.1 UN 1203 •N Hctonu, try or moat *uk lam m*m li% «wrr. ff wa*jkl I.ID UN 0111 Gemaae 2.3 UN 2192 Hayt ericWorailaK 1 UN 1714 HydraoM. Mkyctroia) ar HvdraziaK ai|y«u«» iDMjaow cavajuaaif 3.) UN 2029 Olycerol^lp*ia-«»»ochJ N Gwyl mi naai ^uaayi>de« kydram*. amaratia; »r •nr*t at I.IA UN 01 13 HydrecMonc acid, aoaaaom 1 UN I7t9 N Guanyl aara^aan luanyl letriHM. mi mmof, *f i«r»*i at laaw MA UN 0114 m [S«c. 172.102] 12 OPTIONAL TABLE 172.102 Optional Hazardoiu Material* Table (Cont'd) (11 (3) (4) (1) (2) (11 Ml Uenli- IdcnM. Notes MCO Notes IMCO and Haurdout MaleruU De*cnpiio*i and Pniper Slitppmg Name* data and Hazardous Matenah Descnpiion and Proper Shipping Nsmes Clau flClltOH Symbols Number Symbols Number Hydrocyanic acid, aqueous solution, mt* not more lltan 20% nydro- 61 UN 1613 IsobMyl acetate 32 UN 1213 eyantc and laotwyl acrytale. inliitaetl .1 3 UN 2527 Hydrofluoric acid and sulphuric acrf mixtures 1 UN 17g6 Isobwyl alcohol See Isobulanol Hydrofluoric acid, solution 1 UN 17*0 laobinyl aldehyde Sre Isobutyraldrhvd* Hydrofluoxilicic acid. Set Fluouucic acid laobwylamme 3.2 UN 1214 • Hydrogen and methane Mixtures, compressed 2.1 UN 2034 • laobwylene 2 1 UN 1055 • Hydrogen bromide, anhydrous L3 UN 1041 Isobutyl rormaw 32 UN 2393 • Hydrogen chlondc. anhydrous 2.2 UN 1030 • IsobMyl isobutyrate 1.1 UN 2521 Isobwyl inocyanale 32 UN 2416 Hydrogen, tnnsjimssf 2.1 UN 1044 Isobwyl nMthacryUle. mkitiud 3.3 UN 22«3 • Hydrogen cyanide, anhydrous, stabilized n.1 UN 1031 inobutyl methyl ketone peroaide. nuuimvm coacrntrviio* 62% in 5.2 UN 2126 nWnflnw • Hydrogen cyanide, anhydrous, tlabilmd. aluortea' in a forom inert 6.1 UN 1614 material Iiobutyl propionate 3.2 UN 2394 • Hydrogen fluoride. anhydrous 13 UN 1032 Isobutyraldehyde 3 1 UN 2045 • Hydrogen iodide, anhydrous 11 UN 21*7 Isobutync acid 3.3 UN 252* Isobuiync aahydnde 33 UN 2530 • Hydrogen iodide, solution. See Hydrude nod total on fx^utyronilnle 32 UN 22*4 * Hydrogen peroxide, aqueous solutions m<» not lea Iton 1% ful lea 51 UN 2914 inan 20% kfdrofeit peruadt laaeilae* a nettaary) Isonmyryl chloride 32 UN 2395 • Hydrogen peroxide, aqueous solution) «m not lea inait 20% but not 5.1 UN 2014 Isobutyryl peroxide, maximum rwtctniraiton 52*k tit salmict 52 UN 2112 mart Inan 6O% nydrcfen peroxide tuaatlued Of netvaary) Isocyanales. n-O.s. or Isocyanale lolunons. n.o.s . boiling po**i tt» 6 1 UN 2201 • Hydrogen peroxide, stabilized, or Hydrogen peroxide, aqueous solu 5.1 UN 2013 lea Ikon MO del C tion*, stabilized. nM more inan tO% nfdrofrn peroxide laocyanatea. n.o.l- or [socyaiialr viluitons. not. /lai*ipontt *>>t tea « 1 UN 2206 tnati 2J «cg C eoiltnf point /» ilun 100 def C Hydrogen, refrigerated /iMitf 2.1 UN 1966 • Hydrogen tckmide. annjfdrota 13 UN 1202 Isocyanates, n.o.s. or Isocyanalc solution*, n o.v ftaiApoutt not leu J2 UN 2478 Ikon -It aeg C fia leu titan li dtf C Hydrogen sulphide 11 UN 1033 Isocyanalcs. a.oJ. or laocyaniste solutions, n o i /Jaiftxnitr tea :*J* • 3 1 UN J47J It deg C Hydroqumonc 4.1 UN Unl • laocyajialobetuotnfluondes 6 1 US 2285 Hydrosilicofluonc and. See PhKMrbac acid UN2M3 Hydroxyuunine sulphate 1 Isoheptene i i UN 2217 • UN 17*1 Hypochlome. solutions «** mart rl>an 3% nilaMt c*Jori»t 1 IlobMcne 3, UN 22M * Uononanoyl peroxide. See Di^3.3.5.irtinelhylKeunovl) perotMk Igniter for aircraft thrust de%ice far aaaut ukr-off 4.1 UN 27*2 laoocune 32 UN 1216 Igniters 1.4 O UN 0323 * N Igniters 1.IO UN 0121 Isopenune. Set Penunes Isopenieaa 3.1 1 UN 2371 N Igniters I.2O UN 03 14 IsonhoronedinmuK 1 UN 2219 N IgMtOT 1.30 UN 0315 boohorone duaocysnau; 6 1 UN'1290 3,3''lminobispropyl*nune 1 UN 226* ' 3 1 ' Inflammable gas in lighten. Set Lighten, for dgaii and ctgarnua. Uopme. mhibned UN 1211 etc vith flammaoie gas Isopropanol 32 UN 1219 Inflammable liquid preparations, a.oj. Sat Flansavibk liquid prep- laopropenyl acetate 3.2 UN 2403 arauons, n.O4. Isopropenylbeuene 33 UN 2303 • Inflammable liquids, corrosive. LOO. Set Flanunacx uquios, corro Isopropyl acetate * 32 UN IJ20 sive. U.O.S. • Isopropyl acid phoaphattc 8 UN P93 . Inflammable hquxis. a.O-1. Sat Flammable liquids. n.o.1. • Uflammable liquids, nononous. n.cu. Set Fuuntuvbte tiqtnc*. po»- laopropyl alcobol See Isopropanot •OOOUS, ILO.S. Lsopropylamine .1 1 ! UN 1221 * IniUmmable souda. corrosive, a oj. Sat Raanmntk solids, corro- laopropylbensene 3 3 ! UN 191! Isopropyl butyrate .1 3 UN 2405 • . lanamnuble souda, poaonous. a.oo. Set Flaaunable souda. po«on- Isopropyl chkxonceuie 3 3 : UN 294T OUS. Q.O.S. Isopropyl chloroformate 32 j UN :4rr • Ink. prmten 3.2 UN 1210 3.3 UN 1110 • lsopropyl-2-chioropropionaie 33 irN2934 • lanu m nil ganes. *o*4oxir. 0.0^ 11 UN 1*61 laoprooyl inobutyratc 32 UN24O6 11 UN 19*1 • laopropyl imcyannir 32 UN24H Insu nrirlr gnaa*. mac. 0,0.1. 13 UN l«*7 Iodine anonochlonde 1 UN 1772 Isopropyl nitrate 32 UN 1223 lcdnw peala/luonde 3.1 UN 24*3 laopropyl pros»osu« 3.2 UN 2409 2-lodobnnne 3.2 UN 23*0 lioaorbide dranraw ouirurr nir* not lea titan oO% lacxme. monacal. 4 1 UN 2907 lodaeaethylpropana 3.1 UNU*t aarck. or ealenun kfdrart* paoteJtair luOutx uunnes 32 UN 13*2 N Jet perforating guns, charged. «/ ~r [S«C. 172.102] 13 OPTIONAL TABLE 172.102 Optional Hazardous Materials Table (Cont'd) (1) (2) (31 (4) (I) (2) (4) ldenl>- Note* IMCX) tdenu. Nota IMCO ficaiton •ud Hazardotts Materials DescnpuuB and Proper Shipping Name* Cl«u TlCltlOR end Haurdoii* MaleruUi OocriplKn ud Proper Stiippmf Name* Clan Symaoh Number Symbol* Number 1 an | Mil Tir raaiii •• MaJomurtrile 61 UN 2647 Lwroyl pcraudc. Stt Dilaatroyl peroudc B Maneb, or Ma*eb pteparauoa [Sec. 172.102] 14 OPTIONAL TABLE 172.102 Optional Hazardous Materials Table (Cont'd) tl) (2) (3) (4) (1) (2) (3) (4) Idenn- Notea Menb- Now MOO IMCO and and Hatardoaa Malenab Deacripuoa and Proper Shippea* Namea a— Acanon Haxardoui Matenak Dwacnption and Proper Shipeaaf Name* CM- ncanoa SrmtoH Number Symbott • Metal aftyk. a.o.4. 4.2 UN 2003 Methyl ethyl ketone perouoa.) Sir Ethyl methyl kdone peroiide Methyl ethyl ketona. Srt Ethyl methyl ketone Mi«a)d»h)di 4.1 UN 13U 2-Mtthyl-5 (Sec. 172.102] OPTIONAL TABLE 172.102 Optional Hazardous Materiala Table (Cont'd) (I) (3) (1) (1) (3) (4) Mao- Nota IMCO Nota IMCO •nd HftZftrdoui Mitenul Docnpoo* uid Piupcr Shipping Nuna ftoux Hid Hiurdow VUurab Dacnpnon uid Proper Shippnf Nunet a— ficatioa Syntob Number Syrniol. Number N***--*** 6.1 UN 1650 3-Nnjo 4 rhlncrHimmnlhiondt 6.1 UN 2307 6.1 UN 16)1 NuracraKh UN 2446 6.1 UN 1632 . NfcfOMlWM 3.3 UN 2142 ,• "^SrrTTTtlr. 4.1 UN 1304 2.2 UN 1066 M.,.,,^ ^— .fcj ... HOIA-Jlf ._, e— Methane latinl 2.3 UN 1067 NaivraJ gaaoUac, S*t CMRfhcad gMoirac . Nm^^ __ l ^Ht 2.2 UN 1977 NwfceuM. &* Dimethyl tautaac Ntmit* wraiide. Stt Niirafa dioiide NKM. mqpHBH/ 2.2 UN 1063 Nkrata influonde 2.3 UN 2451 N«OB. rcfri|em*d bquid M UN 1913 Nickd oarbooy! 61 UN 1254 Nitfofcm thoxidc 2.3 UN 2421 •N N«rot)y<»Ti>t jnmamnt: M* * •N Nttroflyocnuc. ipim o^, MfA mart fka* 1 % but *at mot* (Au 70% I.ID UN 0144 . Nickel caulytt, dry prteiptttted on a earner wnk * tptctei «tSMW 4.2 UN 2111 Ml/Of lyftrvtt M JB/HOM M eJevJtoi • Nnrotlyccna lotmoa. • ikotel wA M mart (Acii 1% nnmitfctr- 3.2 UN 1204 • Nickel catAiyiL, wetted vr'A not tto (A*n 49% wfcr of other Mfabtt 4.2 UN 1371 at &fMj4. to "«f*t /i**/*1 rfmd«L aaiM/Mt or ^nw N N'itroguuudiac dry »f CMMMM^ by vcttkL tta iA«n 20% Mter I ID UN 0212 Nickel cytiude 6.1 UN 1633 NHTOfUAnidiac wcood. wilk. by fftgril, ft letw 20% mattr 4.1 UN 1336 Nickd aiirau 5.1 UN17J3 Nflnaydrocuofic KM 1 UN 1791 Nickd mtnte 5.1 UN17U NimMethi«e 3.3 UN 1261 Nilroanruoc Kid. See Nitrohydrachlonc Kid • Nicotine (and taht oft, bquid 6.1 UN 1654 6.1 UN 1654 Nnmmpikiinr 41 UN233» 6.1 UN I6M Niuophenab If, *-. p-> 6.1 UN 1663 « Nicotine («W talo of}, solid 6.1 UN 1654 Niuoprop^aei 3.3 UN 2601 6.1 UN 1654 p-NitraodinietllyUiiiluK 4.2 UN I3«9 Nicotine compound*, n.o.t [S*e. 172.102] 16 OPTIONAL TABLE 172.1102 Optional Hazardous Material* Table (Cont'dl) (1) (2) (3) (1) 0) (3) (4) Idenli- Identi- MOM IMCO Noua IMCO and Hazardous Materials Description and Proper Shipping Names Clans ficauoa and Hazardous Materials Description and Proper Shipping Names Class Symbols Number Symbols Number ' Dfgaiiijiiiiiisiiliinin LKalii'.'sili I. liquid, toxic. flaaisMJrie. a.o.a., /Loia- 6, UNM17 • Peaoobes. liquid. IOIK, flaaMubk. a j.a. fltitifaaa atttmri 3) a% C 6.1 UN 2*03 faiM MM** U Jit C W ti 4f C 61 UN 3017 6.1 UN 2903 6.1 UN M17 6.1 UN 2903 , OrgasMcAaaphorw poticaaa, Uqnai. toxic. a-o.x. fc| UN Mil , Pesticides, liquid, toxic, a.o.1. 6.) UN 2902 61 UN Mil 61 UN 2902 6.1 UN Mil 6.1 UN 2902 • Orfanopkospkor— panada solid, toxic, a.aj. 6.1 UN 2713 • Poticidct, solid, toxic, n.o.x. 6.1 UN 2511 6.1 UN 2713 6.1 UN 2511 Or BanutMi li 61 UN 27U Piliitaniiti crude oil 3.1 UN 1267 6.1 UN27M 3.2 UN 1267 3.3 UN 1167 ' ' Organotin pesticides, hquid. ftaaimable. louc, a.o.1. /loiV" "*» 3.2 UN 2717 Petroleum distillate*, n.o.s. 3.1 UN I2M 3.2 UN 1261 3.3 UN 1261 Petroleum ether. 5rr Petroleum spirit • Organotin pesticides, nquid. toxic, flammable, n.o .«.. /7ajAp°"" **• 61 UN 3019 • Petroleum gates, liquefied 2.1 UN 107J r»m, 23 dti C erui tl *tf C Pdroleum oil 3.1 UN 1270 6.1 UN 3019 3.2 UN 1270 3.3 UN 1270 6.1 UN MI9 Petroleum spinl 3.1 UN 1271 3.2 UN 1271 3.3 UN 1271 • Organotin pearifidca, liquid. toxic, n.o.a 61 UN 3020 61 UN 3020 Petrol Sft Gasoline 6.1 UN 2645 61 UN 3020 Phenacyl bromide • 6.1 UN 2311 . Organolin pesticides. lOfid. toxic, n.o.s. 61 UN 2716 Phenetidirws (o~, f-) 61 UN 2716 Phenol 6.1 UN 1671 61 UN 23 12 Oxmiuxn letroxide 61 UN 2471 Phenol, molten 6.1 Oialato. **ur aWuMr 61 UN 2449 Phenol solutions UN 2121 1 UN IM3 . Oxidizing subatanm, n oj. 5 1 UN 1479 Phenohulphonic acid, liquid • Phenoxyl paiticidci, solid, toxic, n.o.s. 61 UN 2765 Oift" «•*' niton ataiiot maltm. Stt Carbnn dioxide and 6.1 UN 2765 oxygen muntrta • Phenoxy pesticides, liquid, flammable, toxic. « o.i, /Ia>Aaa« lfa 3.2 UN 2766 Oxygen, compmtd 2.2 UN 1077. >«a« li dtf C Oxygen difluonde 2.3 UN 2190 • Oxygen, nfnp^l^^ 12 UN 1073 Phenoxy nevucidn. Uqiud. IOXK, flammable, n.o.x., JkuhpaiHt aV- 6.1 UN 2999 . Paints, enamels, lacquers, tuba, shellac ID/HOOU, v»rniih. polishes. 32 UN 1263 6.1 UNJ999 fillers /iowfti lacquer base or thinaen 3.3 UN 1263 • Paper, uaaarurated oil treated, meomfintly dnt4 42 UN 1379 6.1 UN-2999 • rValbrnaldekyde 4.1 UK 2213 Phenox> peMicides. liquid, tonic, n.o.s. 61 UN 3000 6.1 UN 3000 Paraldenyde 3.3 UN 1264 6.1 UN 3000 Penlaborane 4.3 UN I3U Phenylacetomlrile. liquid , 6.1 UN 2470 Phenylacetyl chkmde 1 UN2J77 Pentachlorortnane 61 UN 1669 PhenylcarbylBRiinc chloride 6.1 UN 1672 •N Penlaeryihntr irtnnitnte. w«ted *irt fa tea ikan 23% *ttrr. to? 1 ID UN 01 50 Phenylchloroformate 6.1 UN 2746 Phenylenedtamincs (o-, m: p-l 6.1 UN 1673 •N Pesnacrylbnle temniirate. mdt not JEra 'Aa* 7% MU. *y wara; 1 ID UN 0411 Phenylhvdntinc 6.1 UN 2572 3.3 UN 2216 PenLanietkyUiepiane Phenyl nocyarute 6.1 UN 2417 3.3 UN 2310 Pentanet 3.1 UN 1265 l-Penlol 1 UN 2705 Phenyl mercaplan 6.1 UN 2337 •N Penlolile. df *r wtmt wnk lai OaM 11% *mur. *jt •«•;»< 1 ID UN 0151 Phenylmercuric acetate 6.1 UN 1674 * PercJuorato, awrgmnic. SLOJ. M UN 1411 Pnenylaxccunc compounds. 11.00. 6.1 UN 2026 6.1 UN 2026 Perchloric acid. «x cinW» . r^roudea, inurgmnic. a.o.t 5.1 UN 1413 • Peraxyacenc acid, muimum c*x**n*lu* 43% i« ismir aray or in • 52 UN 2131 • Phenyl urea peaucidea, liquid, toxic, flammable, n.o x.. flttkfoaa 61 UN 3001 •mwn 11 itt C aW tl drf C 4% A^nafra armriaV aW awr aaw l*aw /* jit^pflw ana* 6.1 UN 3001 • Pancaia. bo»d. naauubk. nuic. 14-s. flukiMH (rat. ij »ef C 3.2 UN 3031 6.1 UN 3001 • Phcnyl Una inaiiciaix. kqiud. toxjc, • o « 6.1 UN 3002 [S*e. 172.102) 17 OPTIONAL TABLE 172.102 Optional Hazardous Materials Table (Cont'd) (1) (2) (3) (4) (2) (3) (4) Menu, Identi IMCO Notes IMCO and Hazardous Materials Dascnpuoa aad Proper Shrpome. Names fication Oass rtcabon and Hazardous Mslerun Description and Proper Shippuif. Names QMS Symbols Number Syvooa; Number a.1 UN 3002 • Pononoaa liquids, R.O.S. 61 UN 2«IO 6.1 UN 30O2 61 UN 2110 Phaayt ana pcatiddcv solid, luic. B.O.S. 6M UN 1767 PuMonoaa solids, corrosive, a.o.s. 6.1 UN 2921 6.1 UN 1767 • Puamanaa solids, flammable, n.o.s. 6.1 UN 2930 • Phcaaaae il UN 1076 • t 4.2 UN 2*J40 Piisaaaoas solids, a.o.s. 61 UN 2111 6.1 UN 2111 2.3 UN 2199 Pobskcs. Srr Pirns. «c Pohfthtiu) fluid. S*r RammsMe liquid preparauons, n.o.i. • Pbmphoric acid. %.«f 1 UN 1103 Mychlonaalad biphnyb ' UN 2313 * Phoipbooc.cid.JoW 1 UN 1103 * rVmvrae Itratti cjtasaoaMe. imfFegHarrl *Mf A /lemmaolt /levtd Srr Phosphoric athydnde. Sft Phoaptona) pemoude Plasucs aiouldin| mauruus evoivin| flammable vapours 61 UN 1677 Ptootphoroist and. ortho 1 UN 2JM PotaaHuan anenate PotavsiuiB aratnite 61 UN 1671 Phosphorous bromide. 5ft Phosphorus tribroaude • Phosphorous ckloridc. &r Phoaphonai trichloride Pruaaliiiai bifluonde. xld UN I!M Phosphorus, amorphous 4.1 UN 1331 Pol mum bifluonde. jo/anon 1 UN 1111 4 1 UN 1339 Potaawug borohydndc 4.3 UN 1170 UN 1444 Photntana oiybromde. molten 1 UN 2576 Pousanun bromaie 5 1 Phosphorus oiybromidc. solid S UN 1«39 PouatiufB chlorale 5 1 UN I4«5 Phosphorus oiychtondc 1 UN 1110 Phosphorus penubroaudc 1 UN 2641 Potassium chlorate, afwma tolvtio* 5 1 UN 2427 Phosphorus peaucMorioe 1 UN 1(06 Phosphorus portafluonde 2.3 UN 2!9« Pouasuus cuprccyaaidc 6 1 UN \tr> Phosphorus pmttasulphide. fntfmm ftHo* or •*/« pimpliana 4.1 UN 1340 rnlassiiini cyaaidc 6.1 UN I6U Phosphorus peaioude 1 UN IIOT PoUawsB fluoride 6.1 UN U12 Phosphorus sesauiiulphick. frit from j*"°« «* •*•" /*oa>«»nii 4.1 UN 1341 Potaausua fluoraaceute 6.1 UN 2628 Phosphorus tribromide I UN IBM • Pntssaiiiiii kydrotea nuonoe. Str Pouxnum bifluonde Potassium hydrogen sulphate t US :S09 Phosphorus trichloride 1 UN 1109 Potassuw hydroKilptuu 4.2 UN 1929 Phosphorus trtoside 1 UN 2371 • PotassnaB h>-dro>ide. solid 1 UN 1113 Phosphorus insulphide. fru /rw« j#/fcv or w*i« a»iirj»iin» 4.1 UN 1343 • Potsawan hfdroude. solution 1 UN 1114 4.2 UN 2447 Phosphorus, white, molten • "nlaniiiin hvpochlonie. «Wui«xi Srr H»pochJomt solutions, nc 42 Phosphorus. wtHtt Of frlta*. dry 42 ' UN 1311 PotHStum metal UN 1257 43 Phosphorus, wkut of yello*. tit maMr 4.2 UN 1311 PDUSSIUB. Beta! tlloyi UN 1420 6.1 UN 2164 N Photo-flash powder im vrniu 1.1O UN 0094 Potlssiiim aitrate 5 1 UN 144* N Photo-flash powder M njtits I.JO UN 00*6 • Potttsittm tutrale and sodium nitnte, iruirure S.I UN 14«7 N Photo-flash powder M void I.3G UN 0303 Phthahc anhydride, ao/ia1 or mo/*** 1 UN 1214 PotaaBMD aitrate bafi. tinpty- $** Ba£i. *"ipfy s*d mi^iir^iorf /ic PouaHun nitriu: 5.1 UN IMS • Phihaliimde derivaltve peatictdcs. Houid. (UmiMMc. locic LO.L. 3.2 UN2T74 flattfou btln 13 dqC Pouswim oude 1 UN 2033 Pouaaiw perchloraie 5.1 UN 14»« 5 1 U N 1 490 • Phthatunide denvaiive pension, uqttid. IOKIC. nammahk. R.O.I.. 6.1 UN 3007 /lai^ojiu OITMIH 23 dVf C *W 4y oVf C Pinaariiiiii peroiide 5 1 UN 1491 6.1 UN 3007 Potamuai persulphate 5 I L'N 1492 . Potassjum phosphide 4 J UN 2012 6.1 UN 3007 N Praaaiiiini «Uti of mtro-aromatic denvsavta. exfJouw 1JC UN 0158 .* ftthalirntoe denvstrw pgllmdes. hquid, lose. a.o.k 61 UN 3001 PotBSBHim ftlioofluonde 6 1 UN 2655 6.1 UN 300* f-iairnin -rnlnm. illej 43 UN 1422 6.1 UN 300* • Potaiaium tulpmde, anhydrous or Pousvun siUphide MCA Itm (*•* 4.2 UN 1312 • Pathahmide denvauvv paiiindti. lohd. tosic. n.a.1. 6.1 UN 2773 JO* —Jrr e/ crrn.«<»no. 61 UN1TO • Pouasum sulphide, aydnied. M* not lot t*a» JO* MW afrrraaJ 1 UN 1147 Ptcolma J.3 UN 1311 •auaM 3 1 • Ptcnc aad. welled. 5«v ThHstropajMoi. wnied UN 2446 Ptaaayt hydroperoude ajrfcuea/ pv* S.1 UN 1162 •N Powder cake, welted ml» w> feat <*•• JS\ —wr Hy -* |S«C. 172.102] 18 OPTIONAL TABLE 172.102 Optional Hazardous Materials Table (Cont'd) (1) (2) (3) (4) (1) (2) (3) (4) Now. Nous IMCO Idemi- IMCO Uemi- •xd Hazardous Material* Detcnpnon lad Proper Shipping Names ftcttion and Hacardom Mauriah Deacnpnc* t*d Proper Shippinf NUKS ftcauon Sya*ob Number Symbol. Number N Projectile*. wil* bttnur ur ttftliiHf entry* 12D UN 034* RtducaH liquid 5ft FlaaMtaMe liquid prepanoo.. a.o.1. •N Projectjkt, MI* tairarr tr OftUint dkwp UF UN 042* N Refnceraat ntat, a.at. 11 UN 1071 •N Projectika. M*M omivtr tr txprlli*! dWfv 1.4F UN 0427 RefritWMli.Ma.aJu. 2.2 UN 1071 N Projactilea, wir* toutftr t* tuftllmg cnmrft 1.40 UN 0347 2J UN 2137 N Projeclilet. mik Mmniaj f*"f I.ID UNOIM Releaat devioet. eiptoaive 1.4S UN 0173 N Projeculea, milt t*mi*f duijt UN 01*9 N Projeclilet, •** Mi/mar r**ir 1.4D UN 0344 Removtitf hqutd. 5ft Flammbk liquid preparslioea, a.o.s. I.IF UN 01*7 N Projecnks, wuk turm*t fltaf ' Ream toluaoa m flfmmtHr /inurf 32 UN 116* N Projectiles, •*» K/nwt: c*«f 1.2F UN 0324 3.3 UN II** • Pmpadiene. mhibrtrd 11 UN 2200 Rem toluuoB. poauaout 6.1 UN in* • Propane 11 UN 1«7I • PropanethMh 3.1 UN 2402 UN in* Propuol 3J UN 1274 • PropioMldehyde 3.1 UN 1275 3.2 UN 1275 • Propionic Kid. toiuuon containing not lot than iWt tcij 1 UN 1141 Retorcmol 6.1 UN 2176 Riveu, etploiive 1.4 S UN 0174 Road atpoalL fifMrt am 0r oil Srr Cut-backl, upMt or Mrvmm Propionic tnhydride 1 UN 249* N Rocket motors 1.IC UN 02 10 N Rocket motors I.2C UN 0211 Propiomtnk 3.2 UN 2404 N Racket moton I.JC UNOIM N Rocket moton. ewiwininf kytrrgoitc /lawirfr. *ittt or wrfAovf tuftlltnt ML UN 0322 Propionyl chkjnoe 3.2 UN 1115 N Rocket moton, WAMminf Vpl'giWic Afuiall vtlk or wirAoiM txprlling 1.3L UN 02 50 ••Propyl tcetmx 3.2 UN 1276 ctiov tec-Propyl tlconol >» Uopropanol N Racket moion. liquid fueled 1.2J UN03W n-Propyl tlcohol 3rt Propsnol N Racket moton. liquid fueled 1.11 UN 039* Propylaimne Srr Moaoprops lamine N Rockeu. IUK throwwg 1.20 UN 0231 Propyl benzene 3.3 UN 23*4 N Rockeu, Une throwing 1.3O UN 0240 Propyl chlonde 3.1 UN 1271 N Racknt. liquid fueled, •** annMn; r4o>«r I.I) UN 0397 »-Propyl chteroformatt 3.3 UN 2740 N Rockeo, aqwd rudad. •«* tunaaa; ctiftft 1.11 UN 0391 N Rockiu. «M oumut dmrgr 1 IE UN 0111 • Propylene 11 UN 1077 N Rodutta. •*!* KnMf Maarpr 1.2E UNOIC Propylerie chloichydnn 6.1 UN 2611 N Rockau. mi* *oaHKf CMWR I.1P UNOIM • PrQpykned'^vntne 3.2 UN 2251 N Rockett. mill *vntt*t cAafr 1.2F UN 0295 3.3 UNU5J N Rockeu. mill mm knJ 1.3C UN 0113 • Rodcntmdet. LOX, bfM** 6.1 UN 1*11 6,1 UN 1611 Propylene durhlonde 3.2 UN 1279 6.1 UN 1611 Propyleneurune, tnlttoittd 3.2 UN 1921 • Rodewcidat. a.04.. leUt 61 UN 1U1 • Propylene oxide 3.1 UN 1210 61 UN I6JI Propylene letrwner 3.3 UN 2150 * UN 1MI Roam oil 3.2 UN 121* Propyl formalcs 3.2 3.3 UN 121* UN 2412 n-Propyl tucyintte 3.2 * 21 Srr O>lorodilTuoroi«ha«. n-Propyl mtr»(e 3.2 UN 1(65 Rubber ten*. »»«'«««' •• irmumlard 4.1 UN 1345 Propyl tnchlorowltne 1 UN 1116 Rubber thoddy. Srr Rubber termp Rubber tokiooa 3.2 UN 1217 3.3 UN 1217 Pyridine 3.2 UN 1212 Rubidiiia] hydraude. aakd 1 UN 2*71 Rubidium kydroudt. totaooa 1 UN 2*77 Pyrophonc fud. n o.i. Srt Fuel, pyrophoric, nJXt , 4.3 UN 1423 4.2 UN 2*45 Pyrophonc liquMh. A.O.L •N 1 UN 01*0 Pyrophonc mettk. n.o %. [S«c. 172.102] 19 OPTIONAL TABLE 172.102 Optional Hazardou Material* Table (Conf d) (1) (2) (3) (4) (D (2) (3) (4) Identi Identi Nont 1MCO Notes IMCO and Hazardous Materials Description and Proper Shipping Names Claas fication and Hsiardom Material! Dexnptton and Proper Shipping Names Qass fication Symbols Number Symbols Number Signal devKes. hand I.4S UN 0371 Sodium hvdrogen sulphite, solution. Str Bisulphites, inorganic. aqueous solutions, n.o.s. Signal devices, hand 1.4 O UN 0191 Sodms* hydrowlphide. «'* am '*« 11% **ur a/ cryuallaano* 42 UN 2318 N e^-p-u^ dsatraas, afctil rafavr rftttt mmltr acttMtfttJ 1.1Q UN 0194 8 UN 2949 N Signals , dantas, tty titter laavs tMtr-aetimltdl 1.30 UN 0195 Sodwal hydrasulphide. MI* aw Ira titan }}% iwlrr ef cryuadaatn* • Sodium hydraaulphide. mtk not It* lltfn JS% *attr of ojuattwita* 8 UN 2949 N Signals, railway track, expkxive I.IG UN 0192 Sodium hydroaulpluie. Stt Sodium duhnsule N Signals, railway track, explosive 1.4S UN 0193 Sodium hydroxide, solid 8 UN 1123 UN 1824 N Signala, smoke. wra txtlttat totttttt unit I.IC UN 0196 Sodium hydroxide, solution 8 • 43 UN 1428 N Signala, smoke, wf/A txflaiivi jottita' HHH I.JO UN 0313 Sodium, mm/ 43 UN I4J9 Stgnak. amoke. witnattl Hamcmr awW unit 1.4 O UN 0197 Sodium ittttaL maftruo* tit organic fiewMti Sodiua sanhyuue 43 UN 1431 Silane 2.1 UN 2203 Sodnws SBetkylaie, solutions Itt alaoiiot 3.2 UN 1219 33 UN 12<9 Silicofluoric acid. Stt Fluoailicic acid Sodium monoxide 8 UN 1825 StlKofluondes. n.o.s- 6.1 UN 2156 Sodium nitrate N 5.1 UN I49t Stlicon chloride. Stt Silicon tetrachlonde • Sodium nitrate and potash, miiturea 5 1 UN 1418 Silicon powder, amwpnotu 4.1 UN 1346 Sodium nitrate and potassium nitrate, mixturts 51 UN 1499 Silicon tetrachlonde 8 UN lilt Sodium nitrau nags, rmfrf. So Bags, tmpry ana" ««»ai*n£ ric. • Sodium nitrite 5.1 U'N 1500 Silicon tetrafluonde 2.3 UN 18)9 Silver anemic 6.1 UN 1613 Sodium pentachloroprienate 6.1 UN 2561 Silver cyanide 6.1 UN 1614 Sodium percarbonatea 5.1 UN 24*1 Silver nitrate 5.1 UN 1493 / » Sodium perchiorate 5.1 UN 1502 Stiver picrate. wetted MI A. Ay ««if nr. at loan 30% *ater 4.1 UN 1347 Sodium permanganate 5.1 UN 1503 SuaL ttry. Sfr Fibre, itieiabtt. dry 5.1 UN 1504 Sludge acid 1 UN 1906 Sodium peroxide Soda lime 8 UN 1907 Sodium persulphate 5.1 UN 1505 • Sodium aluminate, solution 1 UN 1(19 , Sodium phenolalt. soUd 8 UN 24?7 43 Sodium aluminium hydride UN 2835 , Sodium phosphide 43 UN 1432 Sodium amalgam 43 UN 1424 • Sodium amide 43 UN 1425 •N Sodium picramate, dn or trtntd wirA tta man 20% •v/er. by »vi(Ar 1.3C UN 0235 Sodium ammonium vanadxle 6 I UN 2»63 Sodium picramale, wetted n'x. tr wifAt. 01 lout K% ~eur 4.1 UN 1349 Sodium arsamlaic 61 UN 2473 Sodium arsenal* 6.1 UN IM; Sodium-potassium, alhy Stt Potaasium-aodiuln, alloy Sodium anenite, aqueous solutions 6.1 UN 1686 •N Sodium saltx of nitro-aromatic denvativea, n.o j.. txploart 1.3C UN 020! 6.1 UN I6<6 Sodium stuconuohde 61 UN 2*14 Sodium anenrte, solid 6.1 UN 2027 • Sodium sulphide, anhydrous or Sodium sulphide nit tta r*sn 10% 42 UN 1385 Sodium ante 6.1 UN 16*7 wtjttrof eryttallajattan Sodium sulpnide, hydmect *it* a Ittut 3O% ~tirr 8 UN 1*49 • Sodium bssulphate. solid. Saf Sodium hydrogen sulphate, solid Sodium superoxide S.I l)N 25*7 • Sodium bssulphitt, solution Sir Sodium hydrogen sulphite, solution Sodium boronydriojc 4} UN 1426 LIE UN 0374 Sodium faromate 51 UN 1494 : N Souadmg devicaa, explosive N Sounding devicea. explosive 1.2E UN 0375 Sodium caoodylate 6.1 UN 1611 N Sounding device*, explosive * 1.IF UN 0296 Sodium chlorate 51 UN 1495 N Sounding device*, explosive I.2F UN 0204 Sfnt nsiiW anal Str Acid matures, sfr'i Sodium chlorate, aaveota solution 5 1 UN 2428 Spino of saha.5R Hydrochloric acid Squibs I4S UN 0206 Sodium chlonte 51 UN 1496 , Squibs 148 UN 042: .* Sodium chlonte, solution *ir* mart than 3% amilablt chloniu 1 UN 1901 ' Squib. I.4G UN 0423 Sodium chloroacetale 61 UN 2659 Statm. Str Painla. ear • 6.1 UN2JI6 Suiuue- chloride, anhydrous 8 L'N 1827 Sodsuai dsprocvaaide solution 6! UN2JI7 Stamsic cWoride pesuahydrale , UN 24*0 „ .. . Soasvm cvanade 6.1 UN IM* • SunsK phosptudea 43 UN I4J3 •N I3C UN 0234 Soboc 2.3 UN 2616 Sodium dinitro-o-crcBolaie, wetted MIA, *• atfafAi at ttaa 15% 41 UN I Ml Straw 4.1 UN 1327 SodHssa dsnjtro-o-crcnosate. wetted •if*, of •rajAt. at iaur 70% 4.1 UN 134* Striae anjrwken mascsn. Stt ""'•>—• grlkt awjnJkm sour Strononm. alloys am ijisytaisi 43 UN 14)4 • SodM drJuonise 4.2 UN 1314 StrasnMsn arsesute 6.1 UN 1641 Strontium chiorasc 51 UN 1506 Sodisan flaonde. sohd 6.1 UN 1640 Sodium fluonde. solution 6.1 UN 1640 Strontium same 5.1 UN 1507 Sosknai fssswoacanaia' 6.1 UN26« Stronuum percbionas 5.1 UN 1508 Sodium hydrate. Stt Sodium kvdroiide, sar»ia>a Stronnum peroxide 51 UN 1509 Sooman hyitrna 4.3 UN 14J7 Strasusum phosptode 4.3 UN 201) Sodsisnl hydroft* fhonde 1 UN24M • Sttyckaan* (aW Jato «A JsasaV/ 6.1 UN IMJ Sodioss hvdrogesi stilphau, sobd 8 UN mi 6.1 Sodmm hyarogeat aurptum. sohnson 1 UN 2137 6.1 UN 169! [S»c. 172.102] 20 OPTIONAL TABLE 172.102 Optional Hazardous Materials Table (Cont'd) (3) (4) (I) (2) (3) (4) Idoiu- Identi Now. IMCO Notts IMCO ••d Hazardous Materials Deacnption and Proper Shipping Nsmes Claai ftcauon and Hazardous Materials Description and Proper Shrppmg Names Claai fication Symtoott Number Symbols Number * «.rryrra»s»f (mud *iu ofl. talid 61 UN 1692 Tetraelhyl lead. Set Motor fuel aMi-fcnoct mixtures 6 1 UN 1692 Tetraethyl pyrophosphate and comprraand gas. mizmrt 2.3 UN 1705 Styreae aaoaoitier, inhibiud 3.3 UN 2055 Tetrafthyl'siHoale 3.3 UN 1292 I.IL UN 0337 Tetrafluoroethylene. inhibited 2.1 UN IWI I.2L UN 0358 Tetrafluorohydrazinc 2.3 (UN 1.3L UNOJ59 1955) Suialanui which, a* contact with water, emit flammable gases, 4.3 UN 2813 a.oj. Tetrafluoromethane 2.2 UN 1912 . Substituted Mtrophenol pesticides, liquid, flammabk. toxic. tt-o.s.. 3.2 UN 2710 I,2.3.t-Teinhydrobenzaldehyde 3.3 UN 2498 fluiifani »>*H 2} tr, C Tetrahydrofuran 3.1 UN 2056 • Tetrahydrofurfurylamine 3.3 UN2*t3 Tetrahydrophthalic anhydrides 8 UN 2698 • Substituted ititrapherol pesticides, hquid. toxic, fliunmable, a.o.s., t.l UN 3013 fluttfOHt otl^ten 23 del Cmd tl del C 1 .2,3.6-Tetrahydropyridme 32 UN 2410 61 UN 3013 Tetrahydrotruophene 3.2 UN 2412 Tetralin hydroperoxide, uertnml p*n 5.2 UN 2136 6.1 UN 3013 Tetramethylaaunonium hydroxide 8 UN 18W 1.1.3.3-Tetnmethyl butyl hydroperoxide. recfinieel purt 52 UN 2160 • Substituted nilrophenol pesticides, Uquid. toxic, n.o.l. 6.1 UN 3014 1,1,3,3-Tetramethyl butyl peroxy-2-cthy) hexanoatc, technical pure 5.2 UN 2161 61 UN 3014 6.1 UN 3014 Tetramelhylsilane 31 UN 2749 • Substituted nitrophetiol pesticides, solid, toxic, n o.s. 6.1 UN 2779 N Tetranitro-aniline 1 ID UN 0207 61 UN 2779 • Tetrsmtromethane 5.1 UN 1510 SuccinK acid peroxide See Disuccinic acid peroxide • Tetrspropylortholitanate 3.3 UN 2413 * SulphamK acid 1 UN2"e7 N Tetraxol-1 -acetic acid I.4C UN 0407 Sulphur chlorides « UN 1821 • Textile waste, wet, n.as 4.2 UN 1857 Sulfliur dKklandt. Set Sulphur chlorides Thallium chlorate 5.1 UN 2573 Sulphur dioxide, Afttf/M 2.3 UN 1079 Sulphur hexafluoride 2.2 UN 1010 . Thallium compounds. n.o.s. liquid t.l UN 1707 • Sulphunc acid, fuming 8 UN 1831 UN 1707 61 UN 1707 • Thalhum compounds, n.o.s. nttd 61 UN 1707 t.l UN 1707 • Sulphunc acid, spent 8 UN 1832 Thalbum aitrate 61 UN 2727 4-Thiapemanal t.l UN 2785 • Sulphunc acid, WrA moet tke* 31% acid 1 UN 1830 Thinners. Set Paintt. IK. Thinning liquid. Sx Flanuiuak liquid preparations, a.o.1 ThioacetK; acid 3.2 UN 2436 • Sulphunc acid, wi Sulphur, molten 4.1 UN 2448 Thnphea* 3.1 UN 2414 Thiophoagene 6.1 UN 2474 Sulphurous acid ' I'N K3J Thiophosphoryl chlonde 8 UN 1!37 Sulphur tetnfluonde 2.3 UN !41! Thtourea t.l UNJI77 Sulphur tnoxide. aaeilaed 8 UN 1829 . Tm chlonde, fuming. See Stannic chlonde, anhydrous « Tnciura. medicinal 3.2 UN 1293 Sulphuryl chlonde 8 UN 1834 3.3 UN 1293 *) Tin telrachlonde. Sar Surtnic cbloride, anhydrous Sulphur,! fluondc 2.3 UN 2191 Titanram hydnde 4.1 UN 1871 Tan, JatW Stt Ctt-badu. ttfkali or taunt* ' Titanium mttil powder, dry awcisnam/r/ pnducrd, awfinV x(ar ar- 4.2 UN 2546 Tax gaa caadka. *m-ULpi*<* 61 UN 1700 nwn 1 i~l ij micro** or namsaj/ product*, pamc.li tat *m l*» MO mirmi Tear gas grenadea. «M-e«ffasm Sit Tear gas candles * Tilanura was/ powder, wened •*» nar fco IBM 23% watr (* 4.1 UN 1352 Taar fas. ftmfauaf aaaanrav ofuM1 *• lolidl. a.o s. 6.1 UN It*) miNt ffcra of wtlte mtat mt pftftmt) mtctmructUy product*, puni- t.l UN 1*93 fir OJr »m«ni 1 t*d ij micrau; tr c*ff TetnetAyUaiepelitasnsae 8 UN U20 Tnlis«lia«a /•* «K p-t 61 UN 1701 [Sec. 172.102] 21 OPTIONAL TABLE 172.102 Optional Hazardous Materials Table (Cont'd) CD (2) (3) ID 12) (31 (4) Weno- Notes Idcnti- Now 1MCO 1MCO and Haurdoui Material* Di^nptxm and Prt'fwi Shipping Narno* •ad Hazardous Material* Description Mad Proper Slupptnf Name* Oaai Acaoon Clav Sy»bala Number SymhoK NuinKT 71 Tnl«,lniu1iimiat 6.1 UN 1709 2,4.4-Tnnteihylnenlyl-2-peTOiv phrnox) acelalr, ma^imutt ntwrw- 5.2 UN 2961 IrmltO* S1%. IH UMttlitHt N I OTpOdon, MM M/VMf Cttffft LIE UN 0329 Tnmelhyl pl-osphite 33 UN 232" N Torpedoo, •** taMMff i^hvyr 1.IF UN 03 30 Trucm for •••••iin« 1.4 G UN 0306 N Tonttro-anthne 1 ID UN 0153 1 ID UN 02 11 N Tnccn for Mt.iniinrt.oa I.3O UN 0212 N Tnmiroani»ole •N UN 0214 Trbllybmine 3.3 UN 2610 Trimtroheniene. dry or *rt'td *rnlr lei\ ftai J"1- »airr hy «rvAr 1 ID I.IL UN 03<6 Trial.y. taocitc 61 UN 2609 N rrmitrolienreneiulfanic acid Tnruirubenzene. wetted wirA. by MriyA/. >jt Inifi ltt< nu/»' 4 1 UN 1354 Trinilroheniene. wetted with ma ku (Ajt JOTr »vi;r. hv *ri/tlii 4 1 UN I3M • Tnuiite potictda., liquid. ftwWaWbtc, knic* ao.*.. jf*s*fat*t Mo* 3.2 UN27M 23 def C N Trinttrobcnztnc M:id. dry or rrm'tf'Krne. bv «». n-l.i lr*i ffnitt J'''J 1 ID UN o; ! 5 wottr Trinitrobenzoic aLid. welled »i/A. by »*v'". *" '•'*'' tljC^ <*vrrf 4 1 UN 11J5 • UN 2997 Tnazine pettiodcs. liquid, toiic. fUmmatak, n.OA, /kiApcMfir 6envrm 61 Tnnitroben^oK acid, wetted *»A nor ln\ itun Ii'» »ofr/ hy **ifhi 4 1 UN 1355 JJ d«I C ox* 61 4rf C 6 1 UN 2997 N TnnttrocrilorobenTene I.1O UN 0155 UN (>!«• 6.1 UN 2997 N Trinitron uorenone 1 ID •N Trmitro-m-ciesol 1 ID UN 0216 . Tnuinc pCMtcidev Itqutd, tone, n.o.». 6 1 UN 2998 N Trintlrcmapnthalenc 1 ID UN 0217 6.1 UN 2991 N Tnnitrophenetoie 1 ID I'NOJIS •N 6 1 UN 2991 Tnnitroplienol. rfri or vctltd »-irA A-»i trier, JfM *-jt,r by *v«A? 1 ID UN 0154 • • Tn.utne pesticides solid, touc, a.txs. 61 UN 2763 Triniirunhennl. wetted, wirA IUH Itu {far, Jiff *v/<-' by *-rijthi ^ i UN 1.1*1 6.1 UN 2763 ' Trimmiphemil, wetted wi'/A nut /n* irtuii /0LI *airr r,> wttjht 4 1 UN 13*4 Tnbutylunifw 1 UN 2542 UN H39 TnchloroaceiK acid, »Jid 8 N fumtroririenylmetriylmtramtne 1 ID UN 0208 TnclilottMcclK acid, tolutiots 1 UN 25*4 N Tn-iiimre^orcinol. etinlammg. by *Ytt,-ht. nut /m rljui ?"*^ wulrr nr 1 ID UN 0194 TnchlorotKetyl cWor.de 8 UN2«2 •N rriniirore*orcinol. dry or werrrtf »*rA tm tftutt }<>*$ wvitr. by ^vtfthi 1 ID UN 021" Tncrtlorobcnzeno. liqvui 6 1 UN 2321 (or fitxturr ofattortol and walfrt Tnchlorobuiene 6 1 UN 2322 •N Trmitroi4)luene and neianuroMilbene mixing "* Trinuniiolucnc 1 ID UN 0388 •nd tnnttrnhenzene mixtures 1,1.1,-Tnchtoroeth.uie <* 6 1 UN 2131 • *N 1 r.nitrninluene. drv or wetltfd wtri Itu than Mil -wi.'^ b\ '•VIR'H 1 ID UN 0209 TnchloroethyVene 61 UN 1710 •N rrinitrnuiliiene mixtures crniuming mnnrnben/cm: JHJ ^•namtrc^- I. ID VNU3W • Tnchlorottocyuturic acid, dry 5 1 IN24M tilbene 1 Trinitrotoluene, w-etted w/A. by viiifhi. at /fa*.' If1'' *uitr 4 1 UN 1356 • TnchlorouUfte 43 UN 1295 1 rinitr«lolucne. wetiej »iltt fun Im than jljl- nu/i'. rtv HVJifAr 4.1 UN 1356 Tncraylptwiphtu. **tk man ttm* J% orr^o ttom*r 61 UN 2574 ] npropylaluntmum 4.2 UN 27111 • Triei h y UluminiufB 42 UN 1102 , rnpri'ptlAnmie .1.3 UN 2X1 Tneihyt..mme 3.2 UN 1296 Tncthyrenetctn.m..K 8 UN 2259 TnpropylciK 32 L'N 2057 3.3 UN 2057 Tnvll.^iriainyOprmphine cinide. u>luiinn 6 1 UN 2501 • Tnethyl pho«phiit 33 UN 2323 N Tr:tonal « 1 ID UN 0390 TnfluorcMcetic tod 1 UN 2699 • TunBMen ht-xaOiKinde 2.1 UN 219« Turprnlinc 33 UN I2W r^iMxatoottMMifcA.)..*, JM BraOaOthniMitMiKUune 12 UN 1300 • TnOuorochlofOcthyfeoe, inhibited 2.1 UN IM2 33 UN 1300 TnflttarockioromtttHutt. Stt CUoroinfluort)Q>eth.u.« • C' O M H i.-*- Dimetrnlhydrj/ine. uns\mmctrn.'al TnfluoroctaUnt 2.1 UN 2035 Undecane J.3 UN 2330 ThnuoromethaUK 2.2 UN 19*4 Urea hydrogen peru&.de 5 1 UN 1511 • J-TrinuoroMtfcyl MUliae 61 UN 2441 N Urea nitrate, dry tjr nniotntnf. by HrrfAl, l*i\ t/taf ^0$ *vlrr 1 ID UN 0220 • 2-ThnuorameO.yl MLIK.M 6.1 UN 2»42 • Urea nitrate, wetted wifA HW Itii than ItMr wvtfr. by »t,gr,t 4 1 UN 1357 TniMbMiy, dJvwuuwn 4.2 UN 1930 Urea nitrate, wetted wtti nfn /fn ikan JOf! *ij/.f. *v **iglu 4 1 UN 1357 Vakrilderi>de 3.2 UN 2051 Tnaotwlyieoe 3.3 UN 2324 Valcryl i.hlori Trmopropyl bonce 3.3 UN 2616 Vanadium penloxtde. rmtt-fttKd Jrtrm 6.1 UN 2Ki2 TnanfeylKnyl cfatoridc 1 UN 2431 Vanadium letrachlonde 1 UN 2444 • TnoKtbyUyMiuiia 42 UN 1103 Vanadium trichloride 8 UN 2475 Vanadium inoiide. iion-fiutd form 61 UN 2160 ' T nttdliyWBaM, aAliydrovi 2.1 UN K«U • Vanadyl Milphaie 6 1 UN 2931 TnaMdnliaMni. aimal alaniai raiilriniaj ax aw* nW» J0« •/ 3.2 UN I2»7 rnHMrfaffaMiMe Vamnh 5er Pamtk, ttc. 1.3,5-TriMfcyftenUBe 3.3 UN 2325 Vinyl acetate, irtrtitittfd 12 UN 1301 • TnaiHlyt boralr 32 UN 241* Vinyl bfomidei jnAirwir^ 2 1 UN IMS 3.3 UN 2416 Vinyl bulyrate iahibiled 32 UN 2131 Tliaaila;lialimiailaal 3.2 UN 129C Vinyl chlondc, »A*W 2.1 UN 10M Vinyl chloroacelate 6 1 UN 2519 1 UN23J6 . Tna»ajylhriaMr (Sec. 172.102] 22 OPTIONAL TABLE 172.102 Optional Hazardous Materials Table (Corit'd) (1) (11 (4) Idenn- Nom IMCO and Hd/irdiiu* Material* Devrripnun and Prupei Shipping Names Cliss Symbol* N umber Vmv|>d N Wnrhtadi. rocliei. **'* tmnttr or f.*p?iii*g ckarjft I.4O L'N 0.170 N Warheadv nickel. *»/* tttinitr or riptttmf charff 1 tf UN 0.171 N *'arhetdv. rocket, wtili trurMing charge 1 ID UN (1280 N w«rhe*(K roc ltd. with iwmnx chow 1 2D L'N 02K7 N V-'.frne.idv rocket. wiM b*ntinf Hwy 1 IF L'N OMrH N WVheads. torpedo, twf* burning chant* i in UN D221 *'hne atheMov 5--* Aotx-Mov »hiie *"hiif phosphorus, fl*™. S*v PrM^phttrui. whitr w yc Mow. dry V^'hiic prKWphoru*. »vi S«-r Ph*«ph«ru<, vtiilt or yrtio*. in *»*/lf/ H',vio/ Vr M«lKunol 4 -' W\*a»l *,IMV, *T( UN l.>»7 Xenon 22 I'N 2016 Xem>n. rffrigrr-tlcd lii^utd 22 IN lifl XvlimeN .12 L'S IX)7 .1 } UN' 1.107 X^lemih ft 1 IN 22M .X>|^tn«n 6 1 UN 1711 .Vi-dWi $t* Xvlen-n X>I>1 br.-HTiidc 0 1 L'S 1701 ^ cllou phosphorus, dry if.* Phi>vph<'ru*. ••A«c uf wlto*. J-y Ye Ho* pho*phoruv **(. i»-r l*hitsph ZI^K. chkviie 5 1 UN |}IJ . Zm^ chloride, anhydrom g IN 23J1 • ZI'K v.-hton /..rs rxT,,»»Je 5 1 UN 1516 Zns. prti>sphide /i^s. pemilrr \tr du*t. pvnjpHaric -Vcr CsrophorK metals • /"i^ r"'wder or ir.\\. ilust. n.»»i-/iv'T>p.':t^if 4 1 US 14)6 Zi-. rcsmaic 4 1 L'N 2714 ?!i.iv »ilicofluoritlc 0 1 L'S 2*5} Zirconium hyUririe 4 1 L'N 14.17 • /-.'c-nium. m«o; dry. fmnhrd mrul rtfili imf w ffflW "W 42 UN '(»» .i:rier t'tun ID rnicrvn*: /".-onium. mi-:j/ dry. finf-hed \heeti. itrip of coiled *1T flhinnfr 4 | UN 2»<> , . sjn .T54 mti-rviJ frwr nof thinner than IS mtcrynij • /T., Z<:c.Mnum pK-ramMie. wetted »v;A. *y «*i|f'il at least 20K vtater t 1 UN 1517 Zircs^nium. vrap 4.2 UN I9J2 / '.onium. \utr*-r\ded in flammable llauid .1 1 I'N DCW /••..Kiium telrat htpfule H I'N 2501 23 APPENDIX X Sections of the Community and Worker Right to Know Act Pertaining to the Environmental Hazardous Substance List and the Environmental Survey Section: 2. Findings and Declaration; Legislative Intent 3. Definitions a. Chemical Abstract g. Employee representatives Services Number h. Employer b. Chemical name i. Environmental Hazardous Substance c. Common name j. Environmental Hazardous Substance d. Container List e. Council k. Environmental Survey f. County Health Department 1. Facility 4. Preparation of Material by PEP Development of Environmental Hazardous Substance List by DEP, based on Industrial Survey List; criteria for development of List; development of Environmental Survey; preparation of documents in Spanish; adoption of the list 3 months prior to effective date. 6. Transmission of Surveys to Employers DEP transmits Environmental Survey to employers whose activities, in DEP's determination, warrant reporting of information required on the Environmental Survey. 7. Completion of Surveys by Employer Within 90 days of receipt of surveys, employers transmit completed copies of Environmental Survey to DEP, and to the County Health Department and local police and fire departments. 9. DEP Responsibilities DEPEP maintains environmental surveys for 30 years; DEP to require emmployers to update or clarify survey; DEP to transmit copies of nvironmental surveys to persons requesting them in writing. 11. Availability of Spanish Translation of Materials Employers and County Health Departments, upon request, to provide Spanish translation of materials obtained from DEP. 15. Trade Secret Protection Employer permitted to make a trade secret claim on any information required to be disclosed under the Act, except information concerning emissions or the identity of a special health hazard substance. DOH or DEP makes the first determination on the validity of a trade secret claim, employer may appeal this decision and request an administrative hearing, and may then appeal to the courts. A physician shall have access to information for which a trade secret claim has been made. 21. Procedure for Annual Review of Implementation of Act DEP, DOH, DOL and Right to Know Advisory Council establish procedure for annual review, including revising the Workplace H Hazardous Substance L ist and Environmental Hazardous Substance List. 25. Responsibility of Fire and Police Departments; Special Provision for R & D Labs Fire and police departments prohibited from making material submitted to them by employers available to public. Police department, fire departments and county health departments are allowed to request additional information from employers. Research and development labs required to establish a communications program with local fire department. 31. Right of Entry DEP authorized to enter an employer's facility during normal operating hours to determine compliance with Act. 32. Adoption of Rules and Regulations DEP authorized to adopt rules and regulations to implement the Act. 33. Enforcement; Penalties; Fines DEP, upon determination of a violation, of the Act is authorized to issue order of compliance; levy civil administrative penalties; bring civil action; bring civil action for a civil penalty. Civil administrative penalties authorized up to $25,000.00. Willful violation of Act punishable by penalty of at least $10,000.00. 34. Appropriation $1,700,000.00 is appropriated immediately from the General Fund as a loan to the Right to Know Fund, to be paid back when revenues accrue to the fund; DEP to receive 20%. 35. Effective Date Act becomes effective one year after enactment, except for establishment of "Worker and Community Right to Know Fund" and appropriation. o*atiat>ie iMvyciJ * Ldhiun, mttaJ 43 UN 1413 • Mercury baaed pmicidci, liquid, touc. naotnuble. n.o.v, /laiAaoini 6 I UN 301 1 Lnhntni mime 5.1 UN 2712 trrwM 13 aVf C a«f tl del C Lithium nrtride 41 UN 2106 6.1 L'N 301 1 Lrthtum peroiid> !.l UN 1472 * Uihium silicon 43 UN 1417 6 1 UN 3011 London purple 6 1 UN 1621 Lye See Sodium h>dro»de * Mercury bated peatKtdc*, liquid, tone, n.o.i 6 1 UN 3012 • Magnesium aJummiu/n phobphrde 43 L'N 1419 6.1 UN 3012 t 1 UN 30i: Magnesium anrrutr 6 1 UN 1612 * Mercury baaed peMiodea. lolid. (OIK. n.o.» 6 1 UN 27" Magneuum brrMTuie 5 1 UN i47i 6 1 UN 2TT! Mercury bamaoaw 6 1 L'N 1631 Magnesium chkyaic 5 1 UN mi Mercury huuilplnu 6 1 L'N 163i Mercury bromide* UN 1634 Mafnestufli dum>d« 42 UN 2004 6 1 Mercury compounda, liquid, B.O.I.* 61 UN 2024 6 1 UN 2O24 4} UN JOOJ Mercury compound*, lolid. n o L 6 1 UN 20:? 6 1 UN 202 .< • MuneuuBi granules ^.-oaied nMtwmnf -*w» /^- Xr% *vig<*mm. 43 UN jtM pantcit sar *J» /n? tkam 14$ '^••AMJ Mercury cyanide 6 1 UN 16>e Magmsiuin hydrvjf 43 UN 2010 N Mercun ftummate. foHtamiHg. *y metflu. ar lout X% Muer or 1 IA UN013> Magnesium nitrate 5 1 UN 14-U Huxrmrt e/«Jre*W •ne' mtlrr 6 1 L'N 16."' ' Magnesium