Process for Preparing 2,2,6,6-Tetramethyl-4-Oxopiperidine
Europaisches Patentamt J>) European Patent Office @ Publication number: 0152 935 A1 Office europeen des brevets ^ 1 ® EUROPEAN PATENT APPLICATION © Application number: 85101710.3 ® ln* CI.*: C 07 D 211/74 @ Date of filing : 15.02.85 © Priority: 16.02.84 JP 27711/84 © Applicant: ADEKA ARGUS CHEMICAL CO., Ltd., 5-2-13 Shirahata, Urawa City, Saitama Prefecture (JP) @ Inventor: Haruna, Tohru, 969-4 Shimohideya, Okegawa Saitama (JP) Inventor: Nishimura, Atsushf, 2750-49 Washinomiya, @ Date of publication of application :28.08.85 Washinomiya (JP) Bulletind.. 85/35oc/m Inventor: Sugibuchi, Kazuo, 3-25-10 Nakagawa, Adachi-ku Tokyo (JP) @ Representative: Schmied-Kowarzik, Volker, Dr. et al, Patentanwalte Dr. V. Schmied-Kowarzik Dipl.-lng. G. Dannenberg Dr. P. Weinhold Dr. D. Gudel Dipl.-lng. S. Schubert Dr. P. Barz Siegf riedstrasse 8, @ Designated Contracting States : BE CH DE FR GB LI NL D-8000 MQnchen 40 (DE) @ Process for preparing 2,2,6,6-tetramethyl-4-oxopiperidine. A process is provided for the preparation of 2,2,6,6-te- tramethyl-4-oxopiperidine, reacting acetone with 2,2,4,4,6- pentamethyl-2,3,4,5-tetrahydropyrimidine in the presence of a catalytically effective amount of an organic carboxylic acid halide. 2, 2, 6, 6-tetramethyl-4-oxopiperidine, triacetone amine, is prepared by reacting acetone with 2, 2,4,4, 6-pentamethyl- 2, 3, 4, 5-tetrahydropyrimidine (acetonine). Triacetone amine has been recognized as a key intermediate in the preparation of 2, 2, 6, 6-tetramethyl piperidyl and related light stabilizers for polymer materials. Several procedures for reacting acetone with acetonine are described in the patents and literature.
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