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DGP/23-WP/27 国 际 民 用 航 空 组 织 15/8/11 工 作 文 件 危险物品专家组（DGP） 第二十三次会议 2011年10月11日至21日，蒙特利尔 议程项目3: 拟定对《危险物品安全航空运输技术细则补篇》（Doc 9284SU号文件）的修订建 议，以便纳入2013年—2014年版 对第3类至第9类危险物品信息的修改 (由 J. McLaughlin提交) 概要 本文件建议修改技术细则补篇中关于第3类至第9类危险物品的规定。 危险物品专家组的行动：请危险物品专家组考虑召集一个工作组，在危 险物品专家组第23次会议期间开会。工作组的目的是向危险物品专家组提供 一份关于处理补篇中第3类至第9类危险物品事项的最后提案，供其通过。危 险物品专家组第23次会议期间所作修改将可纳入下一版补篇当中。 1. INTRODUCTION 1.1 The DGP Working Group of the Whole Meeting in Abu Dhabi (DGP-WG/10, 7 to 11 November 2010) began efforts to review and update Classes 3-9 dangerous goods in the Supplement to the Technical Instructions during this bienniuum (DGP/23-WP/2, paragraph 3.3.3 refers). This work involved a systematic review of how similar materials and articles are applied in the Supplement. The time and input of those panel members who participated in the numerous emails and discussions on this issue has been greatly appreciated. 1.2 In order to complete this effort, it is proposed that a working group meeting take place during DGP/23. This working paper offers the following material intended to facilitate discussion: Appendix A ⎯ Classes 3-9 Dangerous Goods List: Sorted by division for discussion purposes only, the information within this table has been reviewed for consistency with the UN Model Regulations. Appendix B ⎯ General Packing Requirements: Taken from the Technical Instructions, applicable to Classes 3-9 dangerous goods. （24 页） C1102602 - 2 - Appendix C ⎯ Summary Sheet: For Classes 3-9 dangerous goods, an outline by classes and divisions of quantities limits assigned. This can assist the working group in discussions and in arriving at final determinations. This information is not proposed for inclusion in the Supplement, however, the DGP may wish to consider information similar to the comprehensive summary offered in DGP/23-WP/73 as a basis for information presented in the guiding principles. 1.3 Where there were multiple packing instructions applicable to a substance or material, the most restrictive option was chosen. The DGP may also choose to consider other approaches. — — — — — — — — DGP/23-WP/27 附录 A APPENDIX A CLASSES 3-9 DANGEROUS GOODS LIST Passenger Aircraft Cargo Aircraft Class State Special Excepte UN or div- Sub. P varia- provi- d Name No. ision risk G Labels tions sions Quantity Forbidden P Q Forbidden C Q Forbidden Forbidden 362 1-Chloropropane 1278 3 II A1 (352) (1 L ) Forbidden Forbidden 360 2.5 L Acetaldehyde 1089 3 I A1 (350) (0.5 L) Acrylonitrile, stabilized 1093 3 6.1 I None Forbidden Forbidden 361 30 L Aircraft hydraulic power unit fuel tank (containing a mixture 6.1, A1, Forbidden Forbidden 3165 3 I 373 42 L of anhydrous 8 A48 (350) (0.5 L) hydrazine and methyl hydrazine) (M86 fuel) Alcohols, flammable, 1986 3 6.1 I A3 Forbidden Forbidden 361 30 L toxic, n.o.s. * Aldehydes, flammable, 1988 3 6.1 I A3 Forbidden Forbidden 361 30 L toxic, n.o.s. * Allyl bromide 1099 3 6.1 I None Forbidden Forbidden 361 30 L Allyl chloride 1100 3 6.1 I None Forbidden Forbidden 361 30 L Allyl formate 2336 3 6.1 I None Forbidden Forbidden 361 30 L Arsenical pesticide, liquid, flammable, 2760 3 6.1 I A40 Forbidden Forbidden Forbidden Forbidden toxic, * Bipyridilium pesticide, liquid, flammable, 2782 3 6.1 I A4 Forbidden Forbidden 361 30 L toxic, * Carbamate pesticide, liquid, flammable, 2758 3 6.1 I A4 Forbidden Forbidden 361 30 L toxic* Carbon disulphide 1131 3 6.1 I None Forbidden Forbidden Forbidden Forbidden Chloroprene, stabilized 1991 3 6.1 I None Forbidden Forbidden 361 30 L Copper based pesticide, liquid, 2776 3 6.1 I A4 Forbidden Forbidden 361 30 L flammable, toxic, * Coumarin derivative A48, pesticide, liquid, 3024 3 6.1 I Forbidden Forbidden 361 30 L A4 flammable, toxic * Desensitized explosives, liquid, 3379 3 I A133 Forbidden Forbidden Forbidden Forbidden n.o.s. Elevated temperature liquid, flammable, n.o.s., with flash point 3256 3 III None Forbidden Forbidden Forbidden Forbidden above 60.5°C, at or above its flash point Ethyl Isocyanate 2481 3 6.1 I None Forbidden Forbidden 361 30 L DGP/23-WP/27 附录 A A-2 Passenger Aircraft Cargo Aircraft Class State Special Excepte UN or div- Sub. P varia- provi- d Name No. ision risk G Labels tions sions Quantity Forbidden P Q Forbidden C Q Forbidden Forbidden Forbidden Forbidden Ethyl mercaptan 2363 3 I A1 (350) (0.5 L) (360) (2.5 L) Forbidden Forbidden Forbidden Forbidden Ethyl Nitrite 1194 3 6.1 I A2 (350) (0.5 L) (360) (2.5 L) Ethylene oxide and propylene oxide 2983 3 6.1 I None Forbidden Forbidden 361 30 L mixture Flammable liquid, 6.1, toxic, corrosive, n.o.s. 3286 3 I None Forbidden Forbidden 360 2.5 L 8 * Flammable liquid, 1992 3 6.1 I A3 Forbidden Forbidden 361 30 L toxic, n.o.s. * Mercaptan mixture, A1, Forbidden Forbidden 374 60.0 L liquid, flammable, 1228 3 6.1 II A3, (352) (1 L) toxic, n.o.s. * A36 Mercury based pesticide, liquid, 2778 3 6.1 I A4 Forbidden Forbidden 361 30 L flammable, toxic, * Methacrylonitrile, 3079 3 6.1 I A223 Forbidden Forbidden Forbidden Forbidden stabalized Methoxymethyl 2605 3 6.1 I A223 Forbidden Forbidden Forbidden Forbidden isocyanate Forbidden Forbidden 360 2.5 L Methyltrichlorosilane 1250 3 8 I A1 (350) (0.5 L) Nitriles, flammable, 3273 3 6.1 I None Forbidden Forbidden 361 30 L toxic, n.o.s. * Nitroglycerin mixture, A17, desensitized with 3343 3 Forbidden Forbidden Forbidden Forbidden A204 <30% nitro by mass Nitroglycerin mixture, desensitized with 3357 3 II A17 Forbidden Forbidden Forbidden Forbidden <30% nitro by mass Nitroglycerin solution Forbidden Forbidden 3064 3 II None 362 5 L in alcohol (352) (1 L) A1, Forbidden Forbidden Nitromethane 1261 3 II No Limit A39 (352) (1 L) Organochlorine Forbidden Forbidden 361 30 L pesticide, liquid, 2762 3 6.1 I A4 (350) (0.5 L) flammable, toxic * Organophosphorus pesticide, liquid, 2784 3 6.1 I A4 Forbidden Forbidden 361 30 L flammable, toxic, * Organotin pesticide, liquid, flammable, toxic 2787 3 6.1 I A4 Forbidden Forbidden 361 30 L * Pesticide, liquid, flammable, toxic, n.o.s. 3021 3 6.1 I A4 Forbidden Forbidden 361 30 L * DGP/23-WP/27 A-3 附录 A Passenger Aircraft Cargo Aircraft Class State Special Excepte UN or div- Sub. P varia- provi- d Name No. ision risk G Labels tions sions Quantity Forbidden P Q Forbidden C Q Phenoxyacetic acid derivative pesticide, liquid, flammable, toxic 3346 3 6.1 I A4 Forbidden Forbidden 361 30 L * flash point less than 23°C Forbidden Forbidden 364 60.0 L Propionitrile 2404 3 6.1 II A1 (352) (1 L) Pyrethroid pesticide, liquid, flammable, toxic 3350 3 6.1 I A4 Forbidden Forbidden 361 30 L * Substituted nitrophenol pesticide, liquid, 2780 3 6.1 I A4 Forbidden Forbidden 361 30 L flammable, toxic, * Forbidden Forbidden 361 5 L Tetramethylsilane 2749 3 I A1 (350) (0.5 L) Thiocarbamate pesticide, liquid, 2772 3 6.1 I A4 Forbidden Forbidden 361 30 L flammable, toxic, * Triazine pesticide, liquid, flammable, 2764 3 6.1 I A4 Forbidden Forbidden 361 30 L toxic, * A1, Zirconium suspended Forbidden Forbidden 1308 3 I A3, 361 5 L in a flammable liquid † (350) (0.5 L) A108 Hydrocarbons, liquid, A3, 3295 3 I 302 1 L 303 30 L n.o.s. A224 Hydrocarbons, liquid, A3, 3295 3 II 305 5 L 307 60 L n.o.s. A224 Hydrocarbons, liquid, A3, 3295 3 III 309 10 L 310 220 L n.o.s. A224 Forbidden Forbidden Forbidden Forbidden Isopropyl isocyanate 2483 3 6.1 I A223 (350) (0.5 L) (360) (2.5 L) Forbidden Forbidden 366 220 L Kerosene 1223 3 III A224 (355) (60 L) 5-tert-Butyl-2,4,6- A20, trinitro-m-xylene (musk 2956 4.1 III A200, xylene) A215 Forbidden Forbidden Forbidden Forbidden Azodicarbonamide 3242 4.1 II A60 (450) (15 KG) (453) (50 KG) Barium azide, wetted 1571 4.1 6.1 I A40 Forbidden Forbidden 456 0.5 KG Forbidden Forbidden 453 50 KG Decaborane 1868 4.1 6.1 II A1 (450) (15 KG) Desensitized 3380 4.1 I A133 Forbidden Forbidden Forbidden Forbidden explosive, solid, n.o.s. Dipicryl sulphide, 2852 4.1 I A40 Forbidden Forbidden 451 0.5 KG wetted Flammable solid,organic, molten, 3176 4.1 II None Forbidden Forbidden Forbidden Forbidden n.o.s. Flammable solid,organic, molten, 3176 4.1 III None Forbidden Forbidden Forbidden Forbidden n.o.s. DGP/23-WP/27 附录 A A-4 Passenger Aircraft Cargo Aircraft Class State Special Excepte UN or div- Sub. P varia- provi- d Name No. ision risk G Labels tions sions Quantity Forbidden P Q Forbidden C Q Flammable 3097 4.1 5.1 II A3 Forbidden Forbidden Forbidden Forbidden solid,oxidizing, n.o.s. Flammable 3097 4.1 5.1 III A3 Forbidden Forbidden Forbidden Forbidden solid,oxidizing, n.o.s. Isosorbide-5- A20, Forbidden Forbidden 3251 4.1 III Forbidden Forbidden mononitrate A110 (454) (100 kg) A2, Forbidden Forbidden Matches, fusee 2254 4.1 III 460 100 KG A125 (451) (25 kg) Matches, strike A2, 1331 4.1 III anywhere A125 musk xylene (5-tert- A20, Butyl-2,4,6-trinitro-m- 2956 4.1 III A200, xylene) A215 Naphthalene, molten 2304 4.1 III None Forbidden Forbidden Forbidden Forbidden Nitroglycerin mixture A1, desensitized, solid, 3319 4.1 Forbidden Forbidden Forbidden Forbidden A68 n.o.s. * Pentaerythrite tetranitrate mixture, 3344 4.1 None Forbidden Forbidden Forbidden Forbidden densensitized, solid, n.o.s.
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  • An Investigation Into the Synthesis and Characterisation of Metal

    An Investigation Into the Synthesis and Characterisation of Metal

    An Investigation into the Synthesis and Characterisation of Metal Borohydrides for Hydrogen Storage by Daniel Thomas Reed A thesis submitted to the University of Birmingham For the degree of Doctor of Philosophy School of Metallurgy and Materials College of Engineering and Physical Sciences University of Birmingham October 2009 University of Birmingham Research Archive e-theses repository This unpublished thesis/dissertation is copyright of the author and/or third parties. The intellectual property rights of the author or third parties in respect of this work are as defined by The Copyright Designs and Patents Act 1988 or as modified by any successor legislation. Any use made of information contained in this thesis/dissertation must be in accordance with that legislation and must be properly acknowledged. Further distribution or reproduction in any format is prohibited without the permission of the copyright holder. SYNOPSIS With relatively high gravimetric and volumetric hydrogen storage capacities, borohydride compounds are being investigated for their potential use as hydrogen storage media. A study has been made into the mechanical milling of metal chlorides with sodium borohydride to try to form homoleptic borohydrides. Various characterisation techniques have been used to characterise the composition and microstructure of the samples, and to monitor in-situ the thermal decomposition processes. It was found that rather than homoleptic borohydrides (such as Zn(BH4)2 or Mg(BH4)2), complex borohydrides of the form AM2(BH4)5 and AM(BH4)3 (where A = Li or Na and M = Zn, Mg or Ca) tend to form. Mechanical milling of zinc chloride with sodium borohydride resulted in the formation of a covalent complex NaZn2(BH4)5.