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Final Survey Report DME Utilisation Sept 2

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Final Survey Report DME Utilisation Sept 2 TIFAC, DST, GOVT. OF INDIA | SURVEY ON UTILIZATION ISSUES OF METHANOL & DME CONTENTS S.NO DESCRIPTION PAGE Executive Summary 1.0 CHAPTER 1: INTRODUCTION 1.1 1.1 India Energy Outlook 1.1 1.2 India Chemicals Sector 1.3 1.3 India Resource Status 1.3 1.3.1 Crude Oil 1.4 1.3.2 Coal 1.6 1.3.2.1 Coal Reserves 1.6 1.3.2.2 Coal Production 1.6 1.3.3 LPG 1.7 1.3.4 Petrol(Motor Spirit/Gasoline) 1.8 1.3.5 Natural Gas 1.8 1.3.6 Coal Bed Methane 1.10 1.3.7 Gas Hydrate 1.10 1.3.8 Biomass 1.12 1.4 Report Structure 1.13 2.0 CHAPTER-2: STATUS OF METHANOL INDUSTRIES 2.1 2.1 Introduction 2.1 2.1.1 Product Pathways 2.1 2.1.2 Properties 2.2 2.2 Methanol National Status 2.2 2.2.1 Manufacturers of Methanol 2.3 2.2.1.1 GNFC, Bharuch (Gujarat) 2.3 2.2.1.2 Deepak Fertilizers & Petrochemicals, Raigarh 2.4 2.2.1.3 RCF, Mumbai 2.4 2.2.1.4 NFL, Nangal (Punjab) 2.5 2.2.1.5 Assam Petrochemicals Limited 2.5 1 TIFAC, DST, GOVT. OF INDIA | SURVEY ON UTILIZATION ISSUES OF METHANOL & DME S.NO DESCRIPTION PAGE 2.2.1.6 Gujarat State Fertilizer Corporation (GSFC) 2.6 2.2.2 India-Imports and Exports 2.6 2.2.3 Domestic Consumption and End Use Patterns 2.7 2.2.3.1 Consumption 2.7 2.2.3.2 End Use Pattern 2.7 2.2.4 Future Demand Forecast of India 2.8 2.3 International Status 2.9 2.3.1 Production 2.9 2.3.2 Future Methanol Capacity 2.11 2.3.3 Global Imports and Exports 2.12 2.4 Global Supply and Demand 2.14 2.4.1 Historical Trend 2.14 2.4.2 Demand Projection 2.16 2.4.3 Demand and End Use Sector 2.18 2.5 Country Scenario 2.22 2.5.1 China 2.22 2.5.2 USA 2.24 2.5.3 Iran 2.26 2.6 Methanol in the European Union 2.27 2.7 Global DME Market 2.31 2.7.1 DME in China 2.31 2.7.2 Major Players in the World 2.34 3.0 CHAPTER-3:METHANOL AND DME UTILIZATION 3.1 3.1 Chemicals from Methanol 3.1 3.1.1 Methanol Specification 3.3 3.2 Formaldehyde 3.4 3.2.1 Technology 3.5 3.2.2 Indian Scenario 3.5 3.2.3 Projected Demand 3.6 2 TIFAC, DST, GOVT. OF INDIA | SURVEY ON UTILIZATION ISSUES OF METHANOL & DME S.NO DESCRIPTION PAGE 3.2.4 International Scenario 3.7 3.3 Acetic Acid 3.9 3.3.1 Status of Indian Industry 3.9 3.3.2 Current Domestic Demand 3.10 3.3.3 Domestic Projected Demand 3.11 3.3.4 Acetic Acid-International Scenario 3.12 3.4 Methanol to Olefines 3.15 3.5 Methanol as Transportation Fuel 3.16 3.5.1 Fuel Properties 3.17 3.5.2 Methanol as Alternate Fuel 3.17 3.5.3 Salient Feature 3.19 3.5.4 Vehicle Emission 3.23 3.5.5 Phase Stability and Material Compatibility 3.27 3.5.5.1 Phase Stability 3.27 3.5.5.2 Material Compatibility 3.28 3.6 Global Methanol Fuel Blending Regulations 3.29 3.6.1 Global Methanol Transportation Initiatives 3.30 3.6.1.1 Australia 3.30 3.6.1.2 Israel 3.31 3.6.1.3 Central Asia 3.31 3.6.1.4 Europe 3.32 3.6.1.5 China 3.32 3.6.2 Indian Initiative on Methanol 3.33 3.6.3 Adaption for existing vehicles 3.34 3.6.4 Advantages & Disadvantages 3.34 3.7 Methanol for Biodiesel 3.36 3.7.1 Specifications 3.36 3.7.2 Indian Scenario 3.38 3.7.3 Global Scenario 3.42 3 TIFAC, DST, GOVT. OF INDIA | SURVEY ON UTILIZATION ISSUES OF METHANOL & DME S.NO DESCRIPTION PAGE 3.7.4 Global Bio-methanol Companies 3.46 3.8 Methanol as Marine Fuel 3.47 3.8.1 Methanol-Past & Current Marine Applications 3.49 3.8.2 Methanol and LNG-Cost Effectiveness 3.54 3.8.3 Technology 3.59 3.8.4 Emission from Methanol as Marine Fuel 3.62 3.9 Methanol Fuel Cell 3.64 3.9.1 Policy in India 3.67 3.9.2 Research and Development 3.67 3.9.3 Global Market 3.70 3.9.4 Applications 3.72 3.9.5 Global Market Share 3.72 3.9.6 Major Players 3.70 3.9.7 Efficiency 3.82 3.9.8 Potential in India 3.80 3.10 Di-Methyl Ether(DME) 3.85 3.10.1 Background 3.85 3.10.2 DME Applications 3.85 3.10.3 DME Historical Development 3.86 3.10.4 Global Commercial Applications 3.87 3.10.5 Comparison on Calorific Value 3.87 3.11 DME as a LPG Substitute 3.87 3.12 DME and Diesel 3.90 3.12.1 Advantages and Disadvantages 3.90 3.12.1.1 Favourable 3.90 3.12.1.2 Challenges 3.91 3.12.2 Driving and Implementation Concern 3.91 3.12.3 DME Vehicle Emissions 3.92 3.13 Research and Development 3.95 4 TIFAC, DST, GOVT. OF INDIA | SURVEY ON UTILIZATION ISSUES OF METHANOL & DME S.NO DESCRIPTION PAGE 3.13.1 Germany 3.95 3.13.2 US 3.95 3.13.3 Japan 3.96 3.13.4 India 3.96 3.14 DME Specifications 3.97 3.14.1 Material Compatibility 3.99 3.15 Methanol Storage and Handling Guidelines 3.101 3.16 DME Storage & Handling 3.104 3.17 DME Filling in Trucks 3.105 3.18 Quality Standards of DME 3.106 4.0 CHAPTER-4: ENVIORNMENT, HEALTH & SAFETY 4.1 4.1 Methanol 4.1 4.1.1 Methanol Fuel Characteristics 4.2 4.1.2 Solubility 4.4 4.1.3 Flammability 4.4 4.1.4 Fire Class 4.6 4.1.5 Static Charge 4.7 4.1.6 Odor 4.8 4.1.7 Occupational Exposure Limits 4.9 4.1.8 Methanol Spills in Surface Water and Soils 4.11 4.1.9 Methanol in Air 4.12 4.1.10 Ground Water Effects 4.12 4.1.11 Methanol Spillage Scenario 4.14 4.1.12 Methanol Safety for Marine applications 4.15 4.1.13 Personal Protective Equipment 4.15 4.1.14 Green House Gas (GHG) Emissions 4.16 4.1.15 Effects on Ozone 4.21 4.2 Dimethyl Ether 4.22 4.2.1 Flammability 4.24 5 TIFAC, DST, GOVT. OF INDIA | SURVEY ON UTILIZATION ISSUES OF METHANOL & DME S.NO DESCRIPTION PAGE 4.2.2 Heat of Combustion 4.24 4.2.3 Solubility 4.25 4.2.4 Reactivity Profile 4.25 4.2.5 GHG Emissions 4.25 5.0 CHAPTER-5: OBSERVATIONS & RECOMMENDATIONS 5.1 5.1 Observations 5.1 5.2 Recommendations 5.3 5.2.1 Methanol 5.3 5.2.2 DME 5.3 5.2.3 General 5.3 6.0 CHAPTER-6: DEMAND & FORECAST 6.1 6.1 Introduction 6.1 6.2 Projected domestic Demand 6.4 6.3 Conversion from Feed 6.5 6 TIFAC, DST, GOVT. OF INDIA | SURVEY ON UTILIZATION ISSUES OF METHANOL & DME LIST OF FIGURES S.NO DESCRIPTION PAGE 1.1 Global Energy Consumption 1.2 1.2 Crude oil Production in India 1.5 1.3 Natural Gas Production 1.9 2.1 Pathways for Methanol 2.1 2.2 Global Methanol Production by Region 2.9 2.3 Top Producers Share in Global Production of Methanol 2.10 2.4 Country Exports of Methanol (2014) by percentage 2.12 2.5 Country Imports of Methanol (2014) by percentage 2.13 2.6 Asian Country Imports of Methanol (2014) 2.13 2.7 Asian country Exports of Methanol (2014) 2.14 2.8 Global Methanol Demand by Argus Media 2.16 2.9 Projected Methanol Global Production and Demand by MMSA 2.16 2.10 IHS, Methanol Demand by end use, 2015 2.17 2.11 Global Methanol Demand by IHS 2.17 2.12 Global Methanol Demand by End Use Application 2.19 2.13 Methanol consumption by end use segment, 2015 2.19 2.14 World Methanol Demand by end use (million tonnes) 2.20 2.15 Demand by end use, 2020, Lurgi 2.21 2.16 China Methanol Capacity and Production 2.22 2.17 Demand of Methanol in China 2.24 2.18 US Methanol Plants, 2015 2.25 2.19 North America Methanol Status 2.26 2.20 USA methanol production & trade 2.26 2.21 Methanol, Ethanol costs comparison, Denmark 2.29 2.22 China DME Capacity and Production 2.32 2.23 DME as a fuel blend, global position 3.33 3.1 End use share for Formaldehyde, 2015 3.5 3.2 Formaldehyde Demand by Major Region (2015) 3.8 7 TIFAC, DST, GOVT. OF INDIA | SURVEY ON UTILIZATION ISSUES OF METHANOL & DME S.NO DESCRIPTION PAGE 3.3 Global Share of Formaldehyde(Region- wise), 2014 3.8 3.4 Methanol to Olefins Route 3.15 3.5 Biodiesel Global Production 3.43 3.6 Biodiesel production share by country in 2014 and 2024 3.43 3.7 Timeline for Methanol based Marine Projects 3.51 3.8 SUMMETH Schematic 3.53 3.9 Schematic Diagram of Wartsila Methanol Marine Engine 3.58 3.9a Engine Piping of Wartsila Methanol Marine Engine 3.58 3.9c Small Ship powered by Methanol 3.62 3.10 Emissions from Marine Fuels 3.63 3.11 DMFC 3.67 3.12 Overview of the Reformed Methanol Fuel Cell (RMFC System 3.78 3.13 DME Development Timeline 3.86 3.14 Emissions from DME 3.93 3.15 VOLVO DME Engine 3.97 3.16 SAIC DME Engine 3.98 3.17 MAC Truck DME Engine 3.98 3.18 Volvo DME Truck 3.100 3.19 DME Fuelling in Truck 3.106 4.1 Flash point variation with methanol concentration 4.6 4.2 Methanol NFPA Classification 4.7 4.3 NFPA Rating Guide 4.7 4.4 GHG emissions of methanol relative to gasoline 4.16 4.5 Methanol GHG emissions by feedstocks and country 4.17 4.6 GHG Emissions of Methanol, LNG and Ethanol from feedstocks 4.18 4.7 WTT GHG emissions for different methanol pathways 4.18 4.8 Weighted GHG emissions for methanol and DME from various feed stocks 4.19 4.9 GHG emissions from various fuels 4.20 4.10 GHG emissions from different type of vehicles, 4.21 4.11 Ozone yields for Fuels 4.21 8 TIFAC, DST, GOVT.
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