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Safety Data Sheet Material Name: TEB SDS ID: ADC23950 (SINGAPORE)

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Safety Data Sheet Material Name: TEB SDS ID: ADC23950 (SINGAPORE) Safety Data Sheet Material Name: TEB SDS ID: ADC23950 (SINGAPORE) SECTION 1: Identification Product identifier Material Name TEB Synonyms TRIETHYL BORATE; BORIC ACID, TRIETHYL ESTER; BORON ETHOXIDE; BORON TRIETHOXIDE; TRIETHYOXYBORANE; TRIETHOXYBORON Chemical Family esters Product Use semiconductor manufacture Restrictions on Use None known. Details of the supplier of the safety data sheet Entegris, Inc. 129 Concord Road Building 2 Billerica, MA 01821 USA Telephone Number: +1-952-556-4181 Telephone Number: +1-800-394-4083 (toll free within North America) Supplier Entegris Singapore Pte. Ltd. 31 Kaki Bukit Road 3, Techlink, #06-08/11 Singapore 417818 Telephone: +65-6745-2422 Fax: +65-6745-4477 Emergency # 800-101-2201(CHEMTREC) 1-703-527-3887 (International) E-mail: [email protected] SECTION 2: Hazards identification Singapore Standard SS 586-2:2014 Flammable Liquids - Category 2 Acute Toxicity - Oral - Category 4 Serious Eye Damage/Eye Irritation - Category 2 Specific Target Organ Toxicity - Single Exposure - Category 3 ( respiratory system ) Label elements Hazard symbols ____________________________________________________________ Page 1 of 10 Issue date: 2018-07-11 Revision 1.13 Print date: 2018-07-11 Safety Data Sheet Material Name: TEB SDS ID: ADC23950 (SINGAPORE) Signal word Danger Hazard statements H225 Highly flammable liquid and vapor. H302 Harmful if swallowed. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Precautionary statements Prevention P210 Keep away from heat/sparks/open flame/hot surfaces - No smoking. P233 Keep container tightly closed. P240 Ground/Bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting equipment. P243 Take precautionary measures against static discharge. P242 Use only non-sparking tools. P261 Avoid breathing vapor or mist. P264 Wash thoroughly after handling. P280 Wear protective gloves and eye/face protection. P271 Use only outdoors or in a well-ventilated area. P270 Do not eat, drink or smoke when using this product. Response P370+P378 In case of fire: Use appropriate media to extinguish. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330 Rinse mouth. Storage P403+P233 Store in a well-ventilated place. Keep container tightly closed. P235 Keep cool. P405 Store locked up. Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Other Hazards Which Do Not Result in Classification None ____________________________________________________________ Page 2 of 10 Issue date: 2018-07-11 Revision 1.13 Print date: 2018-07-11 Safety Data Sheet Material Name: TEB SDS ID: ADC23950 (SINGAPORE) SECTION 3: Composition / information on ingredients CAS Component Name Percent 150-46-9 TRIETHYL BORATE 100 Impurities and stabilizing additives contributing to the GHS Classification None SECTION 4: First aid measures Inhalation If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. Skin contact Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. Eye contact Flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Then get immediate medical attention. Ingestion If swallowed, get medical attention. Rinse mouth. Most Important Symptoms/Effects Acute Harmful if swallowed, respiratory tract irritation, eye irritation Delayed No information on significant adverse effects. Indication of any immediate medical attention and special treatment needed Treat symptomatically and supportively. SECTION 5: Firefighting measures Flammable Properties Severe fire hazard. Vapor/air mixtures are explosive above flash point. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Suitable extinguishing media regular dry chemical, carbon dioxide, water spray, alcohol-resistant foam. Large fires: water spray or fog, alcohol-resistant foam Unsuitable Extinguishing Media high-pressure water streams Special Hazards Arising from the Chemical Severe fire hazard. Vapor/air mixtures are explosive above flash point. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Hazardous combustion products oxides of boron, oxides of carbon Fire Fighting Measures Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then ____________________________________________________________ Page 3 of 10 Issue date: 2018-07-11 Revision 1.13 Print date: 2018-07-11 Safety Data Sheet Material Name: TEB SDS ID: ADC23950 (SINGAPORE) take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck, evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Flood with fine water spray. Do not scatter spilled material with high-pressure water streams. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. Special Protective Equipment and Precautions for Firefighters Wear full protective fire fighting gear including self contained breathing apparatus (SCBA) for protection against possible exposure. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Wear personal protective clothing and equipment. Environmental precautions Avoid release to the environment. Methods and Materials for Containment and Cleaning Up Avoid heat, flames, sparks and other sources of ignition. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry. SECTION 7: Handling and storage Precautions for safe handling Keep away from heat, sparks, open flame, and hot surfaces - No smoking. Keep container tightly closed. Ground/Bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharges. Avoid breathing vapor or mist. Wear suitable protective gloves and eye/face protection. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Do not eat, drink or smoke when using this product. Conditions for safe storage, including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Store and handle in accordance with all current regulations and standards. Store in a cool, dry place. Store under an inert atmosphere. Avoid contact with water or moisture. Grounding and bonding required. Keep separated from incompatible substances. Incompatible Materials acids, bases, oxidizing materials SECTION 8: Exposure controls/personal protection Exposure Guidelines Component Exposure Limits Singapore and ACGIH have not developed exposure limits for any of this product's components. Biological limit value There are no biological limit values for any of this product's components. Engineering controls ____________________________________________________________ Page 4 of 10 Issue date: 2018-07-11 Revision 1.13 Print date: 2018-07-11 Safety Data Sheet Material Name: TEB SDS ID: ADC23950 (SINGAPORE) Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. PERSONAL PROTECTIVE EQUIPMENT Eye/face protection Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Protective Clothing Wear appropriate chemical resistant clothing. Glove Recommendations Wear appropriate chemical resistant gloves. Protective Materials neoprene, rubber Respiratory Protection Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with organic vapor cartridge(s).
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