DOCSLIB.ORG

Analysis of Carbon Tetrachloride-Extractable Species from Daxing Bituminous Coal

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Analysis of Carbon Tetrachloride-Extractable Species from Daxing Bituminous Coal Supplementary Materials for: Analysis of Carbon Tetrachloride-extractable Species from Daxing Bituminous Coal Cai-Xia Jv1,2 *, Feng-Gang Li2, Peng Yan2, Meng-Meng Fan2, Lin-Lin Jia 2, Hong Zhang 1, Xian-Yong Wei 1*, Zhi-Min Zong 1 Three supporting tables (Table S1-S3) are included in Supplementary Materials. 1 Table S1. Compounds identified by GC-MS for the extract obtained by the SE method. Peak time RC（%） Formula Name 1 3.0815 C2H4BrCl 8.32 ethane,1-bromo-2-chloro- C4Cl6O3 2 3.1613 0.863 acetic acid, trichloro-anhydride 3 3.378 CBrCl3 9.57 methane,bromotrichloro- C2H3Cl3 4 3.4996 29.15 ethane,1,1,2-trichloro- 5 3.6364 C5H8Cl2O 16.64 3-pentanone,1,5-chichloro- C2Cl4 6 4.0089 3.968 tetrachloroethylene 7 4.1952 C6H12O2 2.586 2-ethoxytetrahychofuran C9H18 8 4.4308 3.2 cyclohexane,1,1,3-trimethyl- 9 5.6281 C6H11Cl 2.746 cyclohexane,chloro- 10 12.6672 22.95 C2Cl6 ethane,hexachloro- 2 Table S2. Compounds identified by GC-MS for the extract obtained by the UAE method. Peak time RC（%） Formula Name Trichloroacetic acid, dodecyl 1 5.2437 1.63 C14H25Cl3O2 ester C H O Dodecyl isobutyl carbonate 2 5.4021 1.32 17 34 3 C H O 3 5.6938 0.57 18 34 (Z)-13-Octadecenal 1-butyl-2-propyl- 4 5.8127 1.41 C12H24 Cyclopentane beta.,2,3-trimethyl- 5 6.234 1.65 C10H20O Cyclopentaneethanol C H O Phytol 6 7.3719 0.725 20 40 C H 7 7.5448 3.008 9 12 Mesitylene C HCl Cyclopropane, pentachloro- 8 8.1101 10.58 3 5 C Cl 9 8.8916 10.02 2 6 Ethane, hexachloro- 2-Octen-1-ol, 3,7-dimethyl-, 10 9.583 1.75 C14H26O2 isobutyrate, (Z)- 4-t-Butyl-2-(1-methyl-2- 11 13.1842 1.284 C13H23NO3 nitroethyl) cyclohexanone 1,1,6,6-Tetramethylspiro 12 14.6751 1.12 C13H24 [4.4]nonane 2-Butyloxycarbonyloxy- C H O 13 14.7868 1.06 18 30 5 1,1,10-trimethyl-6,9- epidioxydecalin 1,1,3-trimethyl-3-(2-methyl-2- 14 15.363 4.11 C12H22 propenyl)- Cyclopentane, C H Tetradecane, 2,6,10-trimethyl- 15 15.9644 3.33 17 36 C H 16 16.4001 5.02 16 30 4,12-Hexadecadiene Ethanone, 1-(1a,2,3,5,6a,6b- hexahydro-3,3,6a- 17 17.7218 2.58 C13H18O3 trimethyloxireno[g]benzofuran-5- yl)- 4-(1,5-Dihydroxy-2,6,6- C H O 18 18.2116 1.16 13 20 3 trimethylcyclohex-2-enyl) but-3- en-2-one C H Cl Octadecane, 1-chloro- 19 18.3664 1.84 18 37 C H 20 20.0878 5.39 12 12 1,3-dimethyl-Naphthalene, 5-Heptenoic acid, 6-methyl-4- 21 21.2871 1.453 C15H20O4S [(4-methylphenyl) sulfonyl] C H Cl Octadecane, 1-chloro- 22 22.1838 4.7 18 37 C H 23 23.3542 6.3 13 14 1,4,5-trimethyl-Naphthalene, C H 1,6,7-trimethyl-Naphthalene, 24 23.7755 6.12 13 14 C H 3-(2-Methyl-propenyl)-1H- 25 24.7839 0.239 13 14 indene C H Naphthalene,1-ethyl-2- 26 24.9748 7.73 13 14 methyl- C H 27 27.3444 0.31 14 16 Benzene, (4,5,5-trimethyl-1,3- 3 cyclopentadien-1-yl)- Pentadecane, 2,6,10,14- 28 27.9962 3.19 C19H40 tetramethyl- 1,4,5,8- 29 29.0406 3.19 C14H16 Tetramethylnaphthalene Furan, 2-(9,10-dihydro-9- 30 30.5027 1.75 C18H18O anthracenyl) tetrahydro- C H 31 31.385 0.626 16 18 1,1'-Biphenyl, 3,4-diethyl- Azulene, 1,4-dimethyl-7-(1- 32 32.8363 0.658 C15H18 methylethyl)- C H Heptadecane, 9-hexyl- 33 33.0308 0.704 23 48 C H O 34 33.5386 0.012 15 14 2-benzyl-3-phenyloxirane 1H- C H 35 33.9383 0.287 15 12 Cyclopropa[l]phenanthrene,1a,9b- dihydro- C H 36 34.0824 2.17 15 12 1-Phenylindene C H 37 36.6539 1.002 16 14 9,10-Dimethylanthracene 4 Table S3. Compounds identified by GC-MS for the extract obtained by the MAE method. RC（% Peak time Formula Name ） C Cl 1 8.8863 11.77 2 6 Hexachloroethane C H O 2 13.497 0.35 16 26 2 2,5-Di-tert-amylhydroquinone C H 3 15.3901 1.42 22 44 Cyclooctane, tetradecyl- C H O 4 16.2094 1.754 15 24 2 Limonen-6-ol, pivalate Cyclopentane, 1,1,3-trimethyl-3-(2-methyl- 5 16.4415 5.73 C12H22 2-propenyl)- 1,4-Methanoazulene-9-methanol, C H O 6 17.2859 0.697 15 26 decahydro-4,8,8-trimethyl-, [1S-(1. alpha.,3a. beta.,4.alpha.,8a.beta.,9R*)]- 7 Ethanone, 1-(1a,2,3,5,6a,6b-hexahydro- 17.7977 1.49 C13H18O3 3,3,6a-trimethyloxireno[g]benzofuran-5-yl)- C H O 8 19.3524 1.03 17 32 2 7-Methyl-Z-tetradecen-1-ol acetate 4-(1,5-Dihydroxy-2,6,6-trimethylcyclohex- 9 19.9788 0.46 C13H20O3 2-enyl) but-3-en-2-one C H O 10 21.1141 4.4 20 40 2-Methyl-cis-7,8-epoxynonadecane C H O 11 22.4228 0.355 37 76 1-Heptatriacotanol C H O 12 23.1638 0.074 18 36 4 Erythro-9,10-dihydroxyoctadecanoic acid C H 13 24.0167 3.49 13 14 Naphthalene, 1,4,5-trimethyl- C H 14 25 0.099 13 14 3-(2-Methyl-propenyl)-1H-indene C H 15 25.2303 8.93 13 14 Naphthalene, 1,6,7-trimethyl- C H S 16 26.539 0.682 24 50 2 Disulfide, di-tert-dodecyl (4,5,5-trimethyl-1,3-cyclopentadien-1- 17 27.638 1.051 C14H16 yl)-benzene C H 18 28.0826 6.22 19 40 Pentadecane, 2,6,10,14-tetramethyl- C H 19 29.2878 3.92 14 16 1,4,5,8-Tetramethylnaphthalene 4a,10a-Methanophenanthren-9. beta. -ol, 11- 20 30.658 0.37 C15H17BrO syn-bromo-1,2,3,4,4a,9,10,10a-octahydro- C H O 21 30.8062 0.813 20 40 2-Methyl-cis-7,8-epoxynonadecane 5,8,11,14-Eicosatetraynoic acid, methyl 22 31.2844 0.587 C21H26O2 ester 3-bromo-1, 4-dimethoxy-a-methyl-2- 23 31.6647 0.578 C15H17BrO naphthalene ethanol C H 24 32.2603 0.168 16 18 4-butylbiphenyl C H 25 32.8699 1.39 16 18 1, 2-diphenyl ethane C H 26 33.1663 0.679 16 18 1,2-Bis(4-methylphenyl) ethane; 5H-Dibenzo[a,d]cyclohepten-5-ol, 27 34.0752 0.15 C15H14O 10,11-dihydro- 1H-Indene, 2,3-dihydro-2-methoxy-1- 28 34.3883 1.3 C16H16O phenyl-, cis- 2,5-Cyclohexadien-1-one, 3,5-dihydroxy- 29 35.1378 1.313 C13H18O4 4,4-dimethyl-2-(1-oxopentyl)- 5 2α,3α,19,24-Tetrahydroxyurs-12-en-28- 30 35.5684 0.383 C31H50O6 oic acid methyl ester 2,5-Cyclohexadien-1-one, 3,5-dihydroxy- 31 35.876 0.306 C13H18O4 4,4-dimethyl-2-(1-oxopentyl)- C H O 32 36.2563 0.615 22 42 3 Oxiranedodecanoic acid, 3-octyl-, cis- C H 33 37.0169 0.406 16 14 1,3-Diphenyl-3-methylcyclopropene C H 34 37.3385 0.604 16 14 9,10-Dimethylanthracene Hexadecane, 1,1'-[1,2-ethanediylbis(oxy)] 35 37.8391 0.205 C34H70O2 bis- Benz[e]azulene-3,8-dione, 3a,4,6a,7,9,10,10a,10b-octahydro-3a,10a- dihydroxy-5-(hydroxymethyl)-2,10- 36 38.5215 0.152 C17H22O5 dimethyl-, (3a.alpha.,6a.alpha.,10.beta.,10a.beta.,10b.b eta.)-(+)- N-[diethoxy-cyanomethyl]- 37 38.9829 0.15 C23H24N2O4 Dibenzo[a,d]bicyclo[3,2,1]-8-azaoctane C H N O 38 39.4024 0.591 23 24 2 4 Desmethylcarvedilol Benzo[b]dihydropyran, 6-hydroxy-4,4,5,7,8- 39 40.0233 2.302 C14H20O2 pentamethyl- C H 40 40.8846 0.01 18 18 Retene C H O 41 41.4663 0.025 22 30 7 Trichoranin C H O 42 42.1291 0.016 22 30 7 13-O-Acetylphorbol; 3,5-dihydroxy-1-(4'-hydroxy-3',5'- C H O 43 42.8506 0.146 22 30 7 dimethoxyphenyl)-7-(4''-hydroxy-3''- methoxyphenyl) heptane C H 44 44.1538 1.186 26 54 hexacosane 5H-Benzo [5,6] cyclohepta[1,2-b] C H N 45 44.6125 0.35 20 22 2 pyridine, 6,11-dihydro-11-(1-methyl- 4-piperidinylidene)- C H O 46 44.7551 0.843 24 40 4 Hyodeoxycholic acid C H Cl O 47 45.2138 0.137 10 12 2 4 3,6-Dichloro-1,2,4,5-benzenetetramethanol Butanoic acid, 1a,2,5,5a,6,9,10,10a- octahydro-5a-hydroxy-4- (hydroxymethyl)-1,1,7,9-tetramethyl- 6,11-dioxo-1H-2,8a- 48 46.1171 0.591 C24H32O6 methanocyclopenta[a]cyclopropa[e]cy clodecen-5-yl ester, [1aR- (1a.alpha.,2.alpha.,5.beta.,5a.beta.,8a.a lpha.,9.alpha.,10a.alpha.)]- 2,3,23-tri(acetyloxy)- C H O 49 47.1798 0.392 35 54 8 (2alpha,3beta,4alpha)-urs-12-en-28-oic acid C H O 50 47.9796 0.798 24 32 6 Methylprednisolone acetate 3-[(1R,2R,3R,5S)-3,5-Diacetoxy-2-((E)-(S)- C H O 51 48.6032 0.155 25 38 10 3,7-diacetoxy-oct-1-enyl)-cyclopentyl]- propionic acid methyl ester C H O 52 49.0227 0.693 25 38 10 methyl (E), (E)-2,7,7-tricarbomethoxy-13- 6 <(tetrahydro-2H-pyran-2-yl) oxy>-4,11- tridecadienoate 17-Hydroxy-3,11,20-trioxopregn-4-en-21-yl 53 49.8058 0.83 C24H32O6 propionate (1R,3aS,4E,6R,8S,8aR,9S,12aS,13S,13aS)- 5-(Chlormethyl)-13a-hydroxy-1,8a- dimethyl-12-methylen-2-oxo- 54 50.8462 0.2 C28H37ClO11 1,2,3a,6,7,8,8a,9,10,11,12,12a,13,13a- tetradecahydrobenzo[4,5]cyclodeca[1,2- b]furan-6,8,9,13-tetrayl- tetraacetat (11β,16α)-17,21-Dihydroxy-16-methyl- 55 51.5482 0.736 C24H32O6 3,20-dioxopregna-1,4-dien-11-yl acetate (6aR,10aR)-9-Carboxy-6a,7,8,10a- tetrahydro-6,6-dimethyl-3-pentyl-6H- 56 51.8475 0.137 C27H36O10 dibenzo[b,d]pyran-1-yl-D- Glucopyranosiduronic Acid Ergost-22-en-3-ol, (3.
Load more

Recommended publications
  • Annex XV Report
    Annex XV report PROPOSAL FOR IDENTIFICATION OF A SUBSTANCE OF VERY HIGH CONCERN ON THE BASIS OF THE CRITERIA SET OUT IN REACH ARTICLE 57 Substance Name(s): 1,6,7,8,9,14,15,16,17,17,18,18- Dodecachloropentacyclo[12.2.1.16,9.02,13.05,10]octadeca-7,15-diene (“Dechlorane Plus”TM) [covering any of its individual anti- and syn-isomers or any combination thereof] EC Number(s): 236-948-9; -; - CAS Number(s): 13560-89-9; 135821-74-8; 135821-03-3 Submitted by: United Kingdom Date: 29 August 2017 ANNEX XV – IDENTIFICATION OF DECHLORANE PLUS AS SVHC CONTENTS PROPOSAL FOR IDENTIFICATION OF A SUBSTANCE OF VERY HIGH CONCERN ON THE BASIS OF THE CRITERIA SET OUT IN REACH ARTICLE 57..........................................................................................IV PART I ...............................................................................................................................................1 JUSTIFICATION ..................................................................................................................................1 1. IDENTITY OF THE SUBSTANCE AND PHYSICAL AND CHEMICAL PROPERTIES ...................................2 1.1 Name and other identifiers of the substance................................................................................2 1.2 Composition of the substance ........................................................................................................2 1.3 Identity and composition of degradation products/metabolites relevant for the SVHC assessment ....................................................................................................................................3
    [Show full text]
  • SAFETY DATA SHEET Cyclopentane
    SAFETY DATA SHEET Cyclopentane Section 1. Identification GHS product identifier : Cyclopentane Chemical name : cyclopentane Other means of : cyclopentane (dot); pentamethylene identification Product use : Synthetic/Analytical chemistry. Synonym : cyclopentane (dot); pentamethylene SDS # : 001124 Supplier's details : Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 24-hour telephone : 1-866-734-3438 Section 2. Hazards identification OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the : FLAMMABLE LIQUIDS - Category 2 substance or mixture AQUATIC HAZARD (ACUTE) - Category 3 AQUATIC HAZARD (LONG-TERM) - Category 3 GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : Highly flammable liquid and vapor. May form explosive mixtures in Air. Harmful to aquatic life with long lasting effects. Precautionary statements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Prevention : Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion- proof electrical, ventilating, lighting and all material-handling equipment. Use only non- sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Avoid release to the environment. Response : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Storage : Store in a well-ventilated place. Keep cool. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise : None known.
    [Show full text]
  • Classification of Chemicals
    Classification of Chemicals Flame & Detonation Arrester Specifications PROTECTOSEAL ® The Protectoseal Company recommends that the National Butadiene would qualify as a Group D material. In each of Electric Code (NEC) Article 500, rankings of various chemi - these cases, the chemicals were primarly listed in a higher cals be used, whenever possible, to determine the suitability category (Group B), because of relatively high pressure read - of a detonation arrester for use with a particular chemical. ings noted in one phase of the standard test procedure con - When no NEC rating of the particular chemical is available, ducted by Underwriters Laboratories. These pressures were the International Electrotechnical Commission (IEC) classifica - of concern when categorizing the chemicals because these tion (Groups IIA, IIB and IIC) is recommended as a secondary NEC groupings are also used as standard indicators for the source of information for determining the suitability of an ar - design strength requirements of electrical boxes, apparatus, rester for its intended service. In general, the IEC Group IIA is etc. that must withstand the pressures generated by an igni - equivalent to the NEC Group D; the IEC Group IIB is equiva - tion within the container. It should be noted that, in each of lent to the NEC Group C; and the IEC Group IIC includes these cases, the test pressures recorded were significantly chemicals in the NEC Groups A and B. In the event of a dis - lower than those commonly encountered when testing a deto - crepancy between the NEC and the IEC ratings, Protectoseal nation arrester for its ability to withstand stable and over - recommends that the NEC groups be referenced.
    [Show full text]
  • MSDS Cyclopentane (1).Pdf
    MATERIAL SAFETY DATA SHEET (MSDS) CYCLOPENTANE 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION SUBSTANCE OR PREPATION TRADE NAME Cyclopentane CHEMICAL CLASSIFICATION Cycloparaffin, Naphthene COMPANY/ UNDERTAKING NAME AND Haldia Petrochemicals Limited, ADDRESS PO Box No 12, Haldia Plant PO Durgachak, Dist Midnapore West Bengal, India PIN 721 602 TELEPHONE 091-3224-274384 / 274400 EMERGENCY TELEPHONE NUMBER 091-3224-275916 2. COMPOSTION AND INFORMATION ON INGREDIENTS CHEMICAL CHEMICLAL CONTENT CAS EXPOSURE LIMITS IN AIR NAME FORMULA NUMBER (ppm) ACGIH ACGIH IDLH TLV- TLV- TWA STEL Cyclopentane C5H10 98.20 wt% 287-92-3 600 NA NA 2,2 Dimethyl (CH3)3CCH2CH3 0.28 wt% 75-83-2 500 1000 NA butane n- pentane n- C5H12 1.47 wt% 109-66-0 600 750 NA i- Pentane i- C5H12 0.05 wt% 78-78-4 600 750 NA Total Sulpher S < 1.0 wt. ppm 7704-34-9 NA NA NA 3. HAZARD CLASSIFICATION Highly flammable liquid and vapour. Vapour EMERGENCY OVERVIEW may cause flash fire. Harmful or Fatal is enter lungs and cause damage POTENTIAL HEALTH HAZARDS EYE SKIN INHALATION INGESTION OTHERS ACUTE To cause Not expected Dizziness, Abdominal prolonged or to be harmful headache, pain, significant to internal nausea, diarrhoea, eye irritation organs if Unconsciousness, dizziness, absorbed weakness nausea, sore through the throat skin. CHRONIC Repeated or prolonged contact with skin may cause dermatitis NFPA HAZARD HEALTH FLAMMABILITY REACTIVITY SPECIAL SIGNALS 2 3 0 - HAZCHEM CODE 3YE GHS-Classification Flammable liquids Category 2 Aspiration hazard Category 1 Chronic aquatic toxicity, Category 3 Acute aquatic toxicity, Category 3 Target Organ Systemic Toxicant - Single exposure, Category 3, Inhalation, Central nervous system Document Compiled By Approved By Issue No Rev.
    [Show full text]
  • Cycloalkanes, Cycloalkenes, and Cycloalkynes
    CYCLOALKANES, CYCLOALKENES, AND CYCLOALKYNES any important hydrocarbons, known as cycloalkanes, contain rings of carbon atoms linked together by single bonds. The simple cycloalkanes of formula (CH,), make up a particularly important homologous series in which the chemical properties change in a much more dramatic way with increasing n than do those of the acyclic hydrocarbons CH,(CH,),,-,H. The cyclo- alkanes with small rings (n = 3-6) are of special interest in exhibiting chemical properties intermediate between those of alkanes and alkenes. In this chapter we will show how this behavior can be explained in terms of angle strain and steric hindrance, concepts that have been introduced previously and will be used with increasing frequency as we proceed further. We also discuss the conformations of cycloalkanes, especially cyclo- hexane, in detail because of their importance to the chemistry of many kinds of naturally occurring organic compounds. Some attention also will be paid to polycyclic compounds, substances with more than one ring, and to cyclo- alkenes and cycloalkynes. 12-1 NOMENCLATURE AND PHYSICAL PROPERTIES OF CYCLOALKANES The IUPAC system for naming cycloalkanes and cycloalkenes was presented in some detail in Sections 3-2 and 3-3, and you may wish to review that ma- terial before proceeding further. Additional procedures are required for naming 446 12 Cycloalkanes, Cycloalkenes, and Cycloalkynes Table 12-1 Physical Properties of Alkanes and Cycloalkanes Density, Compounds Bp, "C Mp, "C diO,g ml-' propane cyclopropane butane cyclobutane pentane cyclopentane hexane cyclohexane heptane cycloheptane octane cyclooctane nonane cyclononane "At -40". bUnder pressure. polycyclic compounds, which have rings with common carbons, and these will be discussed later in this chapter.
    [Show full text]
  • Cyclopentane Cyp
    CYCLOPENTANE CYP CAUTIONARY RESPONSE INFORMATION 4. FIRE HAZARDS 7. SHIPPING INFORMATION 4.1 Flash Point: 7.1 Grades of Purity: Commercial; 60% (remainder Common Synonyms Watery liquid Colorless Mild, sweet odor < 20°F C.C. consists of hydrocarbons of similar boiling Pentamethylene 4.2 Flammable Limits in Air: (approx.) 1.1%- point); Research: 99+% 8.7% 7.2 Storage Temperature: Ambient Floats on water. Flammable, irritating vapor is produced. 4.3 Fire Extinguishing Agents: Dry 7.3 Inert Atmosphere: No requirement chemical, foam, carbon dioxide Keep people away. 7.4 Venting: Pressure-vacuum Avoid inhalation. 4.4 Fire Extinguishing Agents Not to Be Shut off ingition sources. Call fire department. Used: Water may be ineffective. 7.5 IMO Pollution Category: (C) Evacuate area in case of large discharge. 4.5 Special Hazards of Combustion 7.6 Ship Type: 3 Notify local health and pollution control agencies. Products: Not pertinent 7.7 Barge Hull Type: Currently not available Protect water intakes. 4.6 Behavior in Fire: Containers may explode. FLAMMABLE. 8. HAZARD CLASSIFICATIONS Fire 4.7 Auto Ignition Temperature: 682°F Containers may explode in fire. 8.1 49 CFR Category: Flammable liquid Flashback along vapor trail may occur. 4.8 Electrical Hazards: Not pertinent 8.2 49 CFR Class: 3 Vapor may explode if ignited in an enclosed area. 4.9 Burning Rate: 7.9 mm/min. 8.3 49 CFR Package Group: II Extinguish with dry chemicals, foam or carbon dioxide. 4.10 Adiabatic Flame Temperature: Currently Water may be ineffective on fire. not available 8.4 Marine Pollutant: No Cool exposed containers with water.
    [Show full text]
  • Section 2. Hazards Identification OSHA/HCS Status : This Material Is Considered Hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200)
    SAFETY DATA SHEET Flammable Liquefied Gas Mixture: 2-Methylpentane / 2-Methylhexane / 2, 3-Dimethylheptane / Benzene / Cyclohexane / Cyclopentane / Dodecane / Ethyl Benzene / Ethyl Cyclohexane / Hexane / Isobutane / Isobutyl Cyclohexane / Isooctane / Isopentane / Isopropylcyclohexane / Methyl Cyclohexane / N-Butane / N-Butyl Benzene / N-Decane / N-Heptane / N-Nonane / N-Octane / N-Pentane / N-Propyl Benzene / Toluene Section 1. Identification GHS product identifier : Flammable Liquefied Gas Mixture: 2-Methylpentane / 2-Methylhexane / 2, 3-Dimethylheptane / Benzene / Cyclohexane / Cyclopentane / Dodecane / Ethyl Benzene / Ethyl Cyclohexane / Hexane / Isobutane / Isobutyl Cyclohexane / Isooctane / Isopentane / Isopropylcyclohexane / Methyl Cyclohexane / N-Butane / N-Butyl Benzene / N-Decane / N-Heptane / N-Nonane / N-Octane / N-Pentane / N-Propyl Benzene / Toluene Other means of : Not available. identification Product type : Liquefied gas Product use : Synthetic/Analytical chemistry. SDS # : 021986 Supplier's details : Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 24-hour telephone : 1-866-734-3438 Section 2. Hazards identification OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the : FLAMMABLE GASES - Category 1 substance or mixture GASES UNDER PRESSURE - Liquefied gas SKIN IRRITATION - Category 2 GERM CELL MUTAGENICITY - Category 1 CARCINOGENICITY - Category 1 TOXIC TO REPRODUCTION (Fertility) - Category 2 TOXIC TO REPRODUCTION (Unborn child) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 AQUATIC HAZARD (ACUTE) - Category 2 AQUATIC HAZARD (LONG-TERM) - Category 2 GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : Extremely flammable gas. May form explosive mixtures with air.
    [Show full text]
  • SAFETY DATA SHEET Cyclopentane
    SAFETY DATA SHEET Based upon Regulation (EC) No. 1907/2006, as amended by Regulation (EC) No. 453/2010 cyclopentane SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier: Product name : cyclopentane Synonyms : pentamethylene Registration number REACH : 01-2119463053-47 Product type REACH : Substance/mono-constituent CAS number : 287-92-3 EC index number : 601-030-00-2 EC number : 206-016-6 RTECS number : GY2390000 Molecular mass : 70.14 g/mol Formula : C5H10 1.2 Relevant identified uses of the substance or mixture and uses advised against: 1.2.1 Relevant identified uses Industrial and professional use. Before use: carry out a risk assessment 1.2.2 Uses advised against No uses advised against known 1.3 Details of the supplier of the safety data sheet: Supplier of the safety data sheet Distributor of the product 1.4 Emergency telephone number: 24h/24h (Telephone advice: English, French, German, Dutch): +32 14 58 45 45 (BIG) SECTION 2: Hazards identification 2.1 Classification of the substance or mixture: Classified as dangerous according to the criteria of Regulation (EC) No 1272/2008 Class Category Hazard statements Flam. Liq. category 2 H225: Highly flammable liquid and vapour. Aquatic Chronic category 3 H412: Harmful to aquatic life with long lasting effects. 2.2 Label elements: Signal word Danger H-statements H225 Highly flammable liquid and vapour. H412 Harmful to aquatic life with long lasting effects. P-statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves and eye protection/face protection.
    [Show full text]
  • Estimation of Thermophysical Properties of Athabasca Vacuum Residue Using a Single Molecule Representation 7 1.3
    TABLE OF CONTENTS Page 1. INTRODUCTION 1 1.1. Motivation 1 1.2. Background 2 1.2.1. Athabasca Vacuum Residue and its molecular structure 3 1.2.2. Estimation of thermophysical properties of Athabasca Vacuum Residue using a single molecule representation 7 1.3. Research Objectives 8 2. LITERATURE REVIEW 9 2.1. Phase Equilibrium 10 2.1.1. Basic equations of phase equilibrium 12 2.2. Cubic Equations of State (EOS) 13 2.2.1. Peng-Robinson Equation of State 14 2.3. Group Contribution Concept 15 2.4. Group Contribution Based Equations of State 16 2.4.1. Characteristics of the GC Method 17 2.4.2. Estimation of parameter b 19 2.4.3. Estimation of temperature dependent parameter a 19 2.4.4. Estimation of the shape parameter m 20 2.4.5. Estimation of the parameter a at the boiling point temperature a(Tb) 23 2.4.6. Estimation of the temperature dependent parameter c 24 2.4.7. Estimation of boiling point temperature using the group contribution concept 26 2.4.8. Performance and limitations of the GC Method 29 2.4.9. Simplification of the GC method applicable to mixtures (Crampon et al., 2003) 30 2.5. Application of the GC Method to mixtures 33 2.6. Phase Equilibrium Calculations 35 2.6.1. Equilibrium calculations for single compounds 35 1 2.6.2. Stability Criteria 37 2.6.3. The Tangent Plane Criterion 38 2.6.4. Numerical Solutions in Equilibrium Calculations 40 3. METHODOLOGY 48 3.1. Scope of Project 48 3.2.
    [Show full text]
  • S-SBR Solution Styrene-Butadiene Rubber Copolymers Versalis Proprietary Process Technologies Available for Licensing
    Proprietary process technology S-SBR Solution Styrene-Butadiene Rubber copolymers Versalis proprietary process technologies available for licensing II 1 Our company Our commitment to excellence, in quality of our Versalis – the petrochemical subsidiary of Eni – is products and services, makes our company an active a dynamic player in its industry sector facing the partner for the growth of customers involved in multifold market needs through different skills. petrochemical business. With a history as European manufacturer with more Through engineering services, technical assistance, than 50 years of operating experience, Versalis stands marketing support and continuous innovation, our as a complete, reliable and now global supplier in the knowledge is the key strength to customize any new basic chemicals, intermediates, plastics and elastomers project throughout all phases. market with a widespread sales network. Customers can rely on this strong service-oriented Relying on continuous development in its production outlook and benefit from a product portfolio that plants as well as in its products, strengthening the strikes a perfect balance of processability and management of the knowledge gained through its long mechanical properties, performance and industrial experience, Versalis has become a worldwide eco-friendliness. licensor of its proprietary technologies and proprietary catalysts. The strong integration between R&D, Technology and Engineering departments, as well as a deep market expertise, are the key strengths for finding answers
    [Show full text]
  • 2.5 Cycloalkanes and Skeletal Structures 67
    02_BRCLoudon_pgs4-4.qxd 11/26/08 8:36 AM Page 67 2.5 CYCLOALKANES AND SKELETAL STRUCTURES 67 Likewise, the hydrogens bonded to each type of carbon are called primary, secondary, or ter- tiary hydrogens, respectively. primary hydrogens CH3 CH3 H3C CH2 CH2 "CH "C CH3 L L L LL L "CH primary hydrogens secondary hydrogens 3 tertiary hydrogen PROBLEMS 2.10 In the structure of 4-isopropyl-2,4,5-trimethylheptane (Problem 2.9) (a) Identify the primary, secondary, tertiary, and quaternary carbons. (b) Identify the primary, secondary, and tertiary hydrogens. (c) Circle one example of each of the following groups: a methyl group; an ethyl group; an isopropyl group; a sec-butyl group; an isobutyl group. 2.11 Identify the ethyl groups and the methyl groups in the structure of 4-sec-butyl-5-ethyl-3- methyloctane, the compound discussed in Study Problem 2.5. Note that these groups are not necessarily confined to those specifically mentioned in the name. 2.5 CYCLOALKANES AND SKELETAL STRUCTURES Some alkane contain carbon chains in closed loops, or rings; these are called cycloalkanes. Cycloalkanes are named by adding the prefix cyclo to the name of the alkane. Thus, the six- membered cycloalkane is called cyclohexane. CH2 H C CH 2 M % 2 H2""C CH2 %CHM2 cyclohexane The names and some physical properties of the simple cycloalkanes are given in Table 2.3. The general formula for an alkane containing a single ring has two fewer hydrogens than that of the open-chain alkane with the same number of carbon atoms.
    [Show full text]
  • Section 13. Disposal Considerations Disposal Methods : the Generation of Waste Should Be Avoided Or Minimized Wherever Possible
    SAFETY DATA SHEET Flammable Liquid Mixture: 2-Methylpentane / 2,3-Dimethylbutane / 3-Methylpentane / Benzene / Cyclohexane / Cyclopentane / Hexane / Isopentane / Methyl Cyclopentane / N-Butane / N-Pentane Section 1. Identification GHS product identifier : Flammable Liquid Mixture: 2-Methylpentane / 2,3-Dimethylbutane / 3-Methylpentane / Benzene / Cyclohexane / Cyclopentane / Hexane / Isopentane / Methyl Cyclopentane / N-Butane / N-Pentane Other means of : Not available. identification Product use : Synthetic/Analytical chemistry. SDS # : 019890 Supplier's details : Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 24-hour telephone : 1-866-734-3438 Section 2. Hazards identification OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the : FLAMMABLE LIQUIDS - Category 1 substance or mixture SKIN CORROSION/IRRITATION - Category 2 GERM CELL MUTAGENICITY - Category 1B CARCINOGENICITY - Category 1 TOXIC TO REPRODUCTION (Fertility) - Category 2 TOXIC TO REPRODUCTION (Unborn child) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 AQUATIC HAZARD (ACUTE) - Category 3 AQUATIC HAZARD (LONG-TERM) - Category 2 GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : Extremely flammable liquid and vapor. May form explosive mixtures in Air. Causes skin irritation. May cause genetic defects. May cause cancer. Suspected of damaging fertility or the unborn child. May cause drowsiness and dizziness. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects. Precautionary statements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.
    [Show full text]