Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds

Total Page:16

File Type:pdf, Size:1020Kb

Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds Library Listing – 1,521 spectra Subset of Aldrich FT-IR Library related to organometallic, inorganic, boron and deuterium compounds. The Aldrich Material-Specific FT-IR Library collection represents a wide variety of the Aldrich Handbook of Fine Chemicals' most common chemicals divided by similar functional groups. These spectra were assembled from the Aldrich Collection of FT-IR Spectra and the data has been carefully examined and processed by Thermo. The molecular formula, CAS (Chemical Abstracts Services) registry number, when known, and the location number of the printed spectrum in The Aldrich Library of FT-IR Spectra are available. Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds Index Compound Name Index Compound Name 1066 ((R)-(+)-2,2'- 1062 (1,3- BIS(DIPHENYLPHOSPHINO)-1,1'- BIS(DIPHENYLPHOSPHINO)PROPA BINAPH)(1,5-CYCLOOCTADIENE) NE)DICHLORONICKEL(II) 1068 ((R)-(+)-2,2'- 598 (1,3-DIOXAN-2- BIS(DIPHENYLPHOSPHINO)-1,1'- YLETHYNYL)TRIMETHYLSILANE, BINAPHTHYL)PALLADIUM(II) CH 96% 1067 ((S)-(-)-2,2'- 1063 (1,4- BIS(DIPHENYLPHOSPHINO)-1,1'- BIS(DIPHENYLPHOSPHINO)BUTAN BINAPH)(1,5-CYCLOOCTADIENE) E)(1,5- 1140 (+)-(S)-1-((R)-2- CYCLOOCTADIENE)RHODIUM(I) (DIPHENYLPHOSPHINO)FERROCE TET NYL)ETHYL METHYL ETHER, 98 951 (1,5-CYCLOOCTADIENE)(2,4- 1146 (+)-(S)-N,N-DIMETHYL-1-((R)-1',2- PENTANEDIONATO)RHODIUM(I), BIS(DI- 99% PHENYLPHOSPHINO)FERROCENY 1033 (1,5- L)E CYCLOOCTADIENE)BIS(METHYLD 1142 (+)-(S)-N,N-DIMETHYL-1-((R)-2- IPHENYLPHOSPHINE)IRIDIUM(I) (DIPHENYLPHOSPHINO)FERROCE PF6, 97% NYL)ETHYLAMIN 1050 (1,5- 407 (+)-3',5'-O-(1,1,3,3- CYCLOOCTADIENE)BIS(TRIPHENY TETRAISOPROPYL-1,3- LPHOSPHINE)RHODIUM(I) DISILOXANEDIYL)CYTIDINE, 97% HEXAFLUOROPHOSP 639 (+)-B- 893 (1,5- METHOXYDIISOPINOCAMPHEYLB CYCLOOCTADIENE)DIIODOPLATI ORANE NUM(II), 99.9% 1024 (+)-DI-MU-CHLOROBIS(2-(1- 889 (1,5- (DIMETHYLAMINO)ETHYL)PHENY CYCLOOCTADIENE)DIMETHYLPL L-C,N)DIPALLADIUM, ATINUM(II), 98% 1139 (-)-(R)-1-((S)-2- 244 (1- (DIPHENYLPHOSPHINO)FERROCE BROMOVINYL)TRIMETHYLSILAN NYL)ETHYL METHYL ETHER, 98 E, 97% 1145 (-)-(R)-N,N-DIMETHYL-1-((S)-1',2- 314 (1- BIS(DIPHENYL- HYDROXYALLYL)TRIMETHYLSIL PHOSPHINO)FERROCENYL)ET ANE, 97% 1141 (-)-(R)-N,N-DIMETHYL-1-((S)-2- 378 (1-METHOXY-2- (DIPHENYLPHOSPHINO)FERROCE (TRIMETHYLSILYL)VINYLOXY)TR NYL)ETHYLAMIN IMETHYLSILANE, 98%, MIX OF IS 408 (-)-3',5'-O-(1,1,3,3- 491 (1S,9S)-(-)-1,9-BIS((TERT- TETRAISOPROPYL-1,3- BUTYLDIMETHYLSILYLOXY)MET DISILOXANEDIYL)ADENOSINE, 97 HYL)-5-CYANOSEMICO 640 (-)-B- 1078 (2,2'- METHOXYDIISOPINOCAMPHEYLB BIPYRIDINE)DICHLOROPALLADIU ORANE M(II) 637 (-)-DIP-CHLORIDE 1079 (2,2'- 1055 (1,2- BIPYRIDINE)DICHLOROPLATINUM BIS(DIPHENYLPHOSPHINO)ETHAN (II), 98% E)DICHLOROCOBALT(II) 579 (2- 1054 (1,2- (TRIMETHYLSILYL)ETHOXYMETH BIS(DIPHENYLPHOSPHINO)ETHAN YL)TRIPHENYLPHOSPHONIUM E)DICHLOROIRON(II), 96% CHLORIDE, 98% 1056 (1,2- 331 (2-BROMOETHOXY)-TERT- BIS(DIPHENYLPHOSPHINO)ETHAN BUTYLDIMETHYLSILANE, 99% E)DICHLORONICKEL(II) 245 (2- 1057 (1,2- BROMOVINYL)TRIMETHYLSILAN BIS(DIPHENYLPHOSPHINO)ETHAN E, 98%, PREDOMINANTLY TRANS E)DICHLOROPALLADIUM(II), 98% 596 (2-METHYLENE-1,3- 1193 (1,2- PROPANEDIYL)BIS(TRICHLOROSIL BIS(DIPHENYLPHOSPHINO)ETHAN ANE), 98% E)TUNGSTEN TETRACARBONYL, 691 (2-METHYLPROPYL)BORONIC 97% ACID, 98% (c) 2007 Thermo Fisher Scientific Inc. All rights reserved. Page 1 of 26 Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds Index Compound Name Index Compound Name 429 (3- 1051 (BICYCLO(2.2.1)HEPTA-2,5- (DIETHYLAMINO)PROPYL)TRIMET DIENE)(BIS(TRIPHENYLPHOSPHIN HOXYSILANE, 96% E))RHODIUM(I) HE 308 (3- 899 (BICYCLO(2.2.1)HEPTA-2,5- (HEPTAFLUOROISOPROPOXY)PRO DIENE)CHLORORHODIUM(I) PYL)TRICHLOROSILANE, 97% DIMER 483 (3- 900 (BICYCLO(2.2.1)HEPTA-2,5- (TRI(ETHOXY/METHOXY)SILYL)PR DIENE)DICHLOROPALLADIUM(II) OPYL)UREA, 50 WT. % SOLUTION 897 (BICYCLO(2.2.1)HEPTA-2,5- IN METHYL DIENE)DICHLORORUTHENIUM(II) 332 (3-BROMOPROPOXY)-TERT- POLYMER BUTYLDIMETHYLSILANE, 97% 1158 (BICYCLO(2.2.1)HEPTA-2,5- 360 (3- DIENE)MOLYBDENUM CHLOROPROPYL)TRIETHOXYSILA TETRACARBONYL, 95% NE, 95% 273 (BROMOMETHYL)CHLORODIMET 358 (3- HYLSILANE, 97% CHLOROPROPYL)TRIMETHOXYSIL 523 (CHLOROMETHYL)DIMETHYLPHE ANE, 97% NYLSILANE, 98% 413 (3- 524 (CHLOROMETHYL)METHYLBIS(PE MERCAPTOPROPYL)TRIMETHOXY NTAFLUOROPHENYL)SILANE, 95% SILANE, 95% 302 (CHLOROMETHYL)TRICHLOROSIL 605 (3-TRIMETHYLSILYL-2- ANE, 95% PROPYNYL)TRIPHENYLPHOSPHO 1117 (CUMENE)CYCLOPENTADIENYLIR NIUM BROMIDE ON(II) HEXAFLUOROPHOSPHATE, 548 (4-BROMOPHENOXY)-TERT- 98% BUTYLDIMETHYLSILANE, 97% 239 (DICHLOROMETHYL)TRIMETHYLS 547 (4- ILANE, 97% BROMOPHENOXY)TRIMETHYLSIL 822 (DIMETHYLAMINO)TRIMETHYLTI ANE, 98% N, 96% 1225 (5,6)-FULLERENE-C70 1122 (DIMETHYLAMINOMETHYL)FERR 852 (9,10-DIHYDRO-9,10- OCENE, 96% ANTHRACENEDIYL)TRIS(TETRAH 242 (HEPTAFLUOROPROPYL)TRIMETH YDROFURAN)MAGNESIUM YLSILANE, 97% 518 (9,10-DIHYDRO-9- 238 (IODOMETHYL)TRIMETHYLSILAN ANTHRACENYL)TRIMETHYLSILA E, 99% NE, 99% 60 (METHYL SULFIDE)-1,1,1-D3, 99.5+ 108 (ACETIC ANHYDRIDE)-D6, 99+ ATOM % D ATOM % D 61 (METHYL SULFIDE)-D6, 99.9 1162 (ACETYLACETONATO)DICARBON ATOM % D YLRHODIUM(I), 98% 119 (METHYL SULFOXIDE)-D6, 100.0 64 (AMMONIUM SULFATE)-D8, 98+ ATOM % D ATOM % D 186 (METHYL-D3)- 1061 (BICYCLO(2.2.1)HEPTA-2,5- TRIPHENYLPHOSPHONIUM DIENE)((2S,3S)- BROMIDE, 99 ATOM % D BIS(DIPHENYLPHOSPHINO)BUTAN 185 (METHYL- E D3)TRIPHENYLPHOSPHONIUM 1151 (BICYCLO(2.2.1)HEPTA-2,5- IODIDE, 99 ATOM % D DIENE)(1,1'-BIS- 1172 (METHYLCYCLOPENTADIENYL)M (DIPHENYLPHOSPHINO)FERROCE ANGANESE TRICARBONYL, 97% N 411 (METHYLTHIO)TRIMETHYLSILAN 1064 (BICYCLO(2.2.1)HEPTA-2,5- E, 95% DIENE)(1,4-BIS- 1060 (N3-ALLYL)((2S,3S)-(+)- (DIPHENYLPHOS)BUTANE)RHODI BIS(DIPHENYLPHOSPHINO)BUTAN UM E)PALLADIUM(II) PER 952 (BICYCLO(2.2.1)HEPTA-2,5- 562 (PHENYLTHIOMETHYL)TRIMETHY DIENE)(2,4- LSILANE, 99% PENTANEDIONATO)RHODIUM(I), 1123 (R)-(+)-N,N-DIMETHYL-1- 97% FERROCENYLETHYLAMINE, 97% (c) 2007 Thermo Fisher Scientific Inc. All rights reserved. Page 2 of 26 Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds Index Compound Name Index Compound Name 1091 (R,R)-(-)-N,N'-BIS(3,5-DI-TERT- 391 1,1,3,3,5,5- BUTYLSALICYLIDENE)-1,2- HEXAMETHYLTRISILOXANE, 95% CYCLOHEXANEDIAM 385 1,1,3,3- 657 (S)-(+)-PINANEDIOL TETRAISOPROPYLDISILOXANE, (DICHLOROMETHYL)BORONATE, 95% 97% 384 1,1,3,3- 1124 (S)-(-)-N,N-DIMETHYL-1- TETRAMETHYLDISILOXANE, 97% FERROCENYLETHYLAMINE, 95+% 1178 1,2,3,4- 1092 (S,S)-(+)-N,N'-BIS(3,5-DI-TERT- TETRAHYDRONAPHTHALENE BUTYLSALICYLIDENE)-1,2- CHROMIUM TRICARBONYL, 98% CYCLOHEXANEDIAM 130 1,2,3,4- 589 (TERT- TETRAHYDRONAPHTHALENE- BUTYLDIMETHYLSILYL)ACETYLE D12, 98+ ATOM % D NE, 99% 183 1,2,4,5-BENZENE-D2- 588 (TRIETHYLSILYL)ACETYLENE, TETRACARBOXYLIC 97% DIANHYDRIDE, 98 ATOM % D 590 (TRIISOPROPYLSILYL)ACETYLEN 141 1,2-BENZANTHRACENE-D12, 98 E, 98% ATOM % D 445 (TRIMETHYLSILYL)ACETIC ACID, 255 1,2- 99% BIS(CHLORODIMETHYLSILYL)ETH 485 (TRIMETHYLSILYL)ACETONITRIL ANE, 96% E, 99% 256 1,2- 587 (TRIMETHYLSILYL)ACETYLENE, BIS(DICHLOROMETHYLSILYL)ETH 98% ANE, 98% 310 (TRIMETHYLSILYL)METHANOL, 511 1,2- 98% BIS(DIMETHYLSILYL)BENZENE, 1032 (TRIS(DIMETHYLPHENYLPHOSPHI 98% NE))(2,5- 304 1,2- NORBORNADIENE)RHODIUM(I)PF6 BIS(TRICHLOROSILYL)ETHANE, , 97% 97% 1132 1,1''-((4,4'-BIPIPERIDINE)-1,1'- 356 1,2- DIYLDICARBONYL)BIS(1'- BIS(TRIMETHOXYSILYL)ETHANE, (METHOXYCARBONY 96% 1137 1,1'- 379 1,2- BIS(DIPHENYLPHOSPHINO)FERRO BIS(TRIMETHYLSILYLOXY)CYCLO CENE, 97% BUTENE, 95+% 1149 1,1'-BIS- 373 1,2- (CHLOROMERCURI)FERROCENE BIS(TRIMETHYLSILYLOXY)ETHAN 1127 1,1'-DIACETYLFERROCENE, 97% E, 98% 1135 1,1'-DIBENZOYLFERROCENE 21 1,2-DICHLOROETHANE-D4, 99 1111 1,1'-DIMETHYLFERROCENE, 97% ATOM % D 430 1,1'-ETHYLENEBIS(N,N,1,1- 253 1,2- TETRAMETHYLSILANAMINE), 96% DICHLOROTETRAMETHYLDISILA 1130 1,1'-FERROCENEDICARBOXYLIC NE, 98% ACID, 96% 1113 1,2-DIFERROCENYLETHANE, 98% 47 1,1,1,3,3,3-HEXAFLUORO-2- 227 1,2-DIMETHYLDISILANE, 97% PROPAN(OL-D), 98 ATOM % D 730 1,2- 436 1,1,1,3,3,3- PHENYLENEBISDIMETHYLARSINE HEXAMETHYLDISILAZANE, 98% 737 1,2-PHENYLENEDIARSONIC ACID, 392 1,1,1,3,5,5,5- 95% HEPTAMETHYLTRISILOXANE, 98% 670 1,3,5,7- 565 1,1,1-TRIPHENYLSILYLAMINE, 97% TETRAMETHYLPYRAZABOLE, 98% 275 1,1,2,2-TETRACHLORO-1,2- 154 1,3,5-TRICHLOROBENZENE-D3, 98 DIMETHYLDISILANE, 98% ATOM % D 24 1,1,2,2-TETRACHLOROETHANE-D2, 489 1,3-BIS(3- 99.5+ ATOM % D CYANOPROPYL)TETRAMETHYLDI 229 1,1,2,2- SILOXANE, 97% TETRAISOPROPYLDISILANE, 97% 439 1,3-BIS(CHLOROMETHYL)-1,1,3,3- 228 1,1,2,2-TETRAMETHYLDISILANE, TETRAMETHYLDISILAZANE, 95% 98% (c) 2007 Thermo Fisher Scientific Inc. All rights reserved. Page 3 of 26 Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds Index Compound Name Index Compound Name 389 1,3- 583 1-(TERT- BIS(CHLOROMETHYL)TETRAMET BUTYLDIMETHYLSILYL)IMIDAZO HYLDISILOXANE, 99% LE, 97% 551 1,3- 592 1-(TRIISOPROPYLSILYL)-1- BIS(CHLOROMETHYLDIMETHYLSI PROPYNE, 98% LYLOXY)BENZENE, 95% 591 1-(TRIMETHYLSILYL)-1-PROPYNE, 494 1,3- 99% BIS(TRIMETHYLSILYL)CARBODII 564 1- MIDE, 98% (TRIMETHYLSILYL)CYCLOPROPY 481 1,3-BIS(TRIMETHYLSILYL)UREA, L PHENYL SULFIDE, 98% 95% 311 1-(TRIMETHYLSILYL)ETHANOL, 829 1,3-DIACETOXY-1,1,3,3- 98% TETRABUTYLDISTANNOXANE, 582 1-(TRIMETHYLSILYL)IMIDAZOLE, 97% 97% 390 1,3-DICHLORO-1,1,3,3- 480 1- TETRAISOPROPYLDISILOXANE, (TRIMETHYLSILYLMETHYL)UREA 97% , 97% 560 1,3- 327 1-(TRIMETHYLSILYLOXY)-1,3- DICHLOROTETRAPHENYLDISILOX BUTADIENE, 98%, MIXTURE OF ANE, 90% ISOMERS 388 1,3- 31 1-BUTAN(OL-D), 98+ ATOM % D DIMETHYLTETRAVINYLDISILOXA 32 1-BUTANOL-D10, 99+ ATOM % D NE, 97% 328 1- 168 1,3-DINITROBENZENE-D4, 99 CYCLOHEXENYLOXYTRIMETHYL ATOM % D SILANE, 99% 567 1,3-DIPHENYL-1,1,3,3-
Recommended publications
  • Aldrich FT-IR Collection Edition I Library
    Aldrich FT-IR Collection Edition I Library Library Listing – 10,505 spectra This library is the original FT-IR spectral collection from Aldrich. It includes a wide variety of pure chemical compounds found in the Aldrich Handbook of Fine Chemicals. The Aldrich Collection of FT-IR Spectra Edition I library contains spectra of 10,505 pure compounds and is a subset of the Aldrich Collection of FT-IR Spectra Edition II library. All spectra were acquired by Sigma-Aldrich Co. and were processed by Thermo Fisher Scientific. Eight smaller Aldrich Material Specific Sub-Libraries are also available. Aldrich FT-IR Collection Edition I Index Compound Name Index Compound Name 3515 ((1R)-(ENDO,ANTI))-(+)-3- 928 (+)-LIMONENE OXIDE, 97%, BROMOCAMPHOR-8- SULFONIC MIXTURE OF CIS AND TRANS ACID, AMMONIUM SALT 209 (+)-LONGIFOLENE, 98+% 1708 ((1R)-ENDO)-(+)-3- 2283 (+)-MURAMIC ACID HYDRATE, BROMOCAMPHOR, 98% 98% 3516 ((1S)-(ENDO,ANTI))-(-)-3- 2966 (+)-N,N'- BROMOCAMPHOR-8- SULFONIC DIALLYLTARTARDIAMIDE, 99+% ACID, AMMONIUM SALT 2976 (+)-N-ACETYLMURAMIC ACID, 644 ((1S)-ENDO)-(-)-BORNEOL, 99% 97% 9587 (+)-11ALPHA-HYDROXY-17ALPHA- 965 (+)-NOE-LACTOL DIMER, 99+% METHYLTESTOSTERONE 5127 (+)-P-BROMOTETRAMISOLE 9590 (+)-11ALPHA- OXALATE, 99% HYDROXYPROGESTERONE, 95% 661 (+)-P-MENTH-1-EN-9-OL, 97%, 9588 (+)-17-METHYLTESTOSTERONE, MIXTURE OF ISOMERS 99% 730 (+)-PERSEITOL 8681 (+)-2'-DEOXYURIDINE, 99+% 7913 (+)-PILOCARPINE 7591 (+)-2,3-O-ISOPROPYLIDENE-2,3- HYDROCHLORIDE, 99% DIHYDROXY- 1,4- 5844 (+)-RUTIN HYDRATE, 95% BIS(DIPHENYLPHOSPHINO)BUT 9571 (+)-STIGMASTANOL
    [Show full text]
  • EPA Handbook: Optical and Remote Sensing for Measurement and Monitoring of Emissions Flux of Gases and Particulate Matter
    EPA Handbook: Optical and Remote Sensing for Measurement and Monitoring of Emissions Flux of Gases and Particulate Matter EPA 454/B-18-008 August 2018 EPA Handbook: Optical and Remote Sensing for Measurement and Monitoring of Emissions Flux of Gases and Particulate Matter U.S. Environmental Protection Agency Office of Air Quality Planning and Standards Air Quality Assessment Division Research Triangle Park, NC EPA Handbook: Optical and Remote Sensing for Measurement and Monitoring of Emissions Flux of Gases and Particulate Matter 9/1/2018 Informational Document This informational document describes the emerging technologies that can measure and/or identify pollutants using state of the science techniques Forward Optical Remote Sensing (ORS) technologies have been available since the late 1980s. In the early days of this technology, there were many who saw the potential of these new instruments for environmental measurements and how this technology could be integrated into emissions and ambient air monitoring for the measurement of flux. However, the monitoring community did not embrace ORS as quickly as anticipated. Several factors contributing to delayed ORS use were: • Cost: The cost of these instruments made it prohibitive to purchase, operate and maintain. • Utility: Since these instruments were perceived as “black boxes.” Many instrument specialists were wary of how they worked and how the instruments generated the values. • Ease of use: Many of the early instruments required a well-trained spectroscopist who would have to spend a large amount of time to setup, operate, collect, validate and verify the data. • Data Utilization: Results from path integrated units were different from point source data which presented challenges for data use and interpretation.
    [Show full text]
  • Influence of Additives and Storage Temperature on Physicochemical and Microbiological Properties of Eye Drops Containing Cefazolin
    Acta Poloniae Pharmaceutica ñ Drug Research, Vol. 63 No. 3 pp. 225ñ234, 2006 ISSN 0001-6837 Polish Pharmaceutical Society PHARMACEUTICAL TECHNOLOGY INFLUENCE OF ADDITIVES AND STORAGE TEMPERATURE ON PHYSICOCHEMICAL AND MICROBIOLOGICAL PROPERTIES OF EYE DROPS CONTAINING CEFAZOLIN. ANNA KODYM 1, TOMASZ ZAWISZA 2, KAMILA BUèKA 2 and HELENA KUKU£A 3 1 Department of Drug Form Technology, Nicolaus Copernicus University Collegium Medicum in Bydgoszcz, 2 Department of Drug Form Technology, 3 Department of Pharmaceutical Bacteriology; K. Marcinkowski University of Medical Sciences in PoznaÒ Abstract: The purpose of the studies was to choose additives for eye drops containing cefazolin and the assess- ment of the influence of used additives and the storage temperature on the physicochemical properties and the stability of the eye drops. The drops were 1% sterile solutions of cefazolin in citrate buffer of pH 6.15-6.20. The drops were preserved with 0.002% thiomersal or 0.001% phenylmercuric borate mixed with 0.4% β- phenylethyl alcohol. Viscosity of the eye drops was increased using polyvinyl alcohol (PVAL). The pharma- ceutical compatibility test of selected additives with cefazolin showed the pharmaceutical interaction of 1% solution of cefazolin with higher than 0.003% concentration of thiomersal, 0.005% benzalkonium chloride and 0.01% chlorhexidine diacetate. The drops, protected from light, were stored at the temperature of 4∞C and 20∞C. As the criteria of the qualitative assessment of freshly prepared drops and during their storage, the following properties were considered: organoleptic analysis, sterility, pH, osmotic pressure, density, viscosity, antimicro- bial activity of cefazolin and preservation efficiency of thiomersal and phenylmercuric borate in the eye drops.
    [Show full text]
  • Safety Data Sheet Acc
    Product Distributed by Rio Grande SDS access on web: www.riogrande.com Page 1 of 13 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 03/20/2015 Reviewed on 03/20/2015 1 Identification · Product identifier · Trade name: Midas® 24K Gold Cyanide-Based Concentrate Plating Solution · Article number: 335-082 · Recommended use and restriction on use · Recommended use: Electroplating material · Restrictions on use: No further relevant information available. · Details of the supplier of the Safety Data Sheet · Manufacturer/Supplier: RIO GRANDE 7500 Bluewater Rd. NW Alburquerque NM 87121-1962 1-800-545-6566 [email protected] · Emergency telephone number: ChemTel Inc. (800)255-3924, +1 (813)248-0585 2 Hazard(s) identification · Classification of the substance or mixture GHS06 Skull and crossbones Acute Tox. 2 H300 Fatal if swallowed. Acute Tox. 2 H310 Fatal in contact with skin. Acute Tox. 3 H331 Toxic if inhaled. GHS07 Skin Sens. 1 H317 May cause an allergic skin reaction. · Additional information: There are no other hazards not otherwise classified that have been identified. 0 percent of the mixture consists of ingredient(s) of unknown toxicity. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms GHS06 · Signal word Danger · Hazard-determining components of labeling: potassium cyanide (Contd. on page 2) 40.1.3 Page 2 of 13 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 03/20/2015 Reviewed on 03/20/2015 Trade name: Midas® 24K Gold Cyanide-Based Concentrate Plating Solution (Contd.
    [Show full text]
  • Perchloric Acid and Some Organic Perchlorates”
    View Article Online / Journal Homepage / Table of Contents for this issue 4 BURTON AND PRAILL: PERCHLORIC ACID [Vol. 80 Perchloric Acid and Some Organic Perchlorates” BY H. BURTON AND P. F. G. PRAILL (Presented at the W’ngof the Society on Wednesday,July 21st, 1954) The history crf perchlorates is summarised and various methods of pre- paration of the acid are noted. The action of perchloric acid and some organic perchlorates on various types of organic compounds, e.g., anhydrides and ethers, is discussed with particular reference to the formation of, especially, the alkyl perchlorates and related compounds. The simple alkyl esters of Published on 01 January 1955. Downloaded by University of Reading 29/10/2017 13:59:35. perchloric acid have long been known to be highly explosive; in the free state they possess many of the properties of covalent compounds. Con- sequently, when experiments that can lead to their formation are carried out, the risk of serious explosion is always present. GROWINGinterest in the applications of perchloric acid to analytical chemistry makes the recognition of its properties imperative. Perchloric acid and the perchlorates have a notorious reputation; this is due to numerous explosions that have been recorded (Hackl’; Meyer and Spormann2; Kahane3; Zahn4; Balks and Wehrrnann5; Young and Campbell6; and others to be mentioned later) and also to the lack of extensive investigations of their properties. Whilst it is not intended that the hazardous properties of perchloric acid should be belittled, it is thought that a better understanding of its character may dispel some of the fears that have * Much of the chemistry of perchloric acid and perchlorates is summarised in “The Chemical Elements and Their Compounds,” by N.
    [Show full text]
  • European Patent Office of Opposition to That Patent, in Accordance with the Implementing Regulations
    (19) TZZ ¥Z_T (11) EP 2 655 308 B1 (12) EUROPEAN PATENT SPECIFICATION (45) Date of publication and mention (51) Int Cl.: of the grant of the patent: C07C 45/45 (2006.01) C07C 49/84 (2006.01) 07.03.2018 Bulletin 2018/10 (86) International application number: (21) Application number: 11804542.6 PCT/EP2011/073172 (22) Date of filing: 19.12.2011 (87) International publication number: WO 2012/084770 (28.06.2012 Gazette 2012/26) (54) PROCESS FOR THE MANUFACTURE OF DIBENZOYLMETHANE DERIVATIVES VERFAHREN ZUR HERSTELLUNG VON DIBENZOYLMETHANDERIVATEN PROCÉDÉ DE PRODUCTION DE DÉRIVÉS DE DIBENZOYLMÉTHANE (84) Designated Contracting States: • NANDURKAR NITIN S ET AL: "Synthesis of AL AT BE BG CH CY CZ DE DK EE ES FI FR GB sterically hindered 1,3-diketones", SYNTHETIC GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO COMMUNICATIONS, TAYLOR & FRANCIS PL PT RO RS SE SI SK SM TR GROUP, PHILADELPHIA, PA, vol. 37, no. 23, 1 January 2007 (2007-01-01), pages 4111-4115, (30) Priority: 20.12.2010 EP 10195971 XP009144707, ISSN: 0039-7911, DOI: DOI:10.1080/00397910701572803 (43) Date of publication of application: • GUOQING ZHANG ET AL: "Polymorphism and 30.10.2013 Bulletin 2013/44 Reversible Mechanochromic Luminescence for Solid-State Difluoroboron Avobenzone", (73) Proprietor: DSM IP Assets B.V. JOURNAL OF THE AMERICAN CHEMICAL 6411 TE Heerlen (NL) SOCIETY, AMERICAN CHEMICAL SOCIETY, US, vol. 132, 1 January 2010 (2010-01-01), pages (72) Inventor: WEHRLI, Christof 2160-2162, XP007917212, ISSN: 0002-7863, DOI: CH-4002 Basel (CH) DOI:10.1021/JA9097719 [retrieved on 2010-01-28] • FRANEK W: "New Dithio-bis-(diaroylmethanes) (74) Representative: Berg, Katja et al and Acetyl Diaroylchloromethyl Disulfides: DSM Nutritional Products AG Attractive Synthons and Precursors for the Wurmisweg 576 Liberation of Highly Reactive Dithiiranes or CH-4303 Kaiseraugst (CH) Thiosulfines", MONATSHEFTE FUR CHEMIE, SPRINGER VERLAG WIEN, AT, vol.
    [Show full text]
  • Calculation of Properties of Environmental Interest
    1 Journal of Environmental Monitoring 10:435-442, 2008 Solvation parameters for mercury and mercury(II) compounds: calculation of properties of environmental interest Michael H. Abraham, *a Javier Gil-Lostes, a William E. Acree, Jr. b J. Enrique Cometto-Muñiz, c and William S. Cain. c a Department of Chemistry, University College London, 20 Gordon Street, London WC1H OAJ, UK. Email: [email protected] b Department of Chemistry, P. O. Box 305070, University of North Texas, Denton, TX 76203-5070, USA. c Chemosensory Perception Laboratory, Department of Surgery (Otolaryngology), University of California, San Diego, La Jolla, CA 92093-0957, USA 2 Descriptors have been determined for four inorganic mercury(II) species and for seventeen organic mercury(II) species, using experimental literature data. These descriptors can then be used in equations that we have already set out in order to estimate a large number of physicochemical properties. These include the water to octanol partition coefficient and the gas to water partition coefficient. For the organic mercury(II) species, including dimethylmercury and the methylmercury(II) halides, the latter has been estimated over the temperature range 273-373K. Introduction Mercury and mercury(II) compounds are important species; dimethylmercury and methylmercury(II) compounds are known environmental pollutants. Although a number of thermodynamic properties are available especially for mercury 1, 2 and mercury(II) halides, 2 many other properties that are relevant to environmental and health issues are not known. A number of computational methods can be used for the calculation of a range of properties of compounds, but many of these methods such as SPARC,3 Advanced Chemistry Development 4 and PharmaAlgorithms, 5 cannot deal with any compounds that contain mercury atoms.
    [Show full text]
  • United States Patent (19) (11) 4,161,571 Yasui Et Al
    United States Patent (19) (11) 4,161,571 Yasui et al. 45 Jul. 17, 1979 (54) PROCESS FOR PRODUCTION OF THE 4,080,493 3/1978 Yasui et al. .......................... 260/879 MALE CANHYDRDE ADDUCT OF A 4,082,817 4/1978 Imaizumi et al. ...................... 526/46 LIQUID POLYMER 4,091,198 5/1978 Smith ..................................... 526/56 75 Inventors: Seimei Yasui, Takarazuka; Takao FOREIGN PATENT DOCUMENTS Oshima, Sonehigashi, both of Japan 2262677 2/1975 France ....................................... 526/56 73) Assignee: Sumitomo Chemical Company, 44-1989 1/1969 Japan ......................................... 526/56 Limited, Osaka, Japan Primary Examiner-William F. Hamrock Attorney, Agent, or Firm-Birch, Stewart, Kolasch and 21 Appl. No.: 843,311 Birch 22 Filed: Oct. 18, 1977 57 ABSTRACT Related U.S. Application Data A process for production of the maleic anhydride ad duct of a liquid polymer having a maleic anhydride 62 Division of Ser. No. 733,914, Oct. 19, 1976, Pat, No. addition amount of 2 to 70% by weight, which com 4,080,493. prises reacting a liquid polymer having a molecular 51 Int. C.’................................................ CO8F 8/46 weight of 150 to 5,000 and a viscosity of 2 to 50,000 cp (52) U.S. C. ...................................... 526/90; 526/192; at 30 C. in the presence of at least one compound, as a 526/209; 526/213; 526/193; 526/195; 526/226; gelation inhibitor, selected from the group consisting of 526/233; 526/237; 526/238; 526/272; 525/285; imidazoles, thiazoles, metallic salts of mercapto 525/249; 525/251; 525/255; 525/245; 525/248 thiazoles, urea derivatives, naphthylamines, nitrosa (58) Field of Search ................
    [Show full text]
  • Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds
    Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds Library Listing – 1,523 spectra Subset of Aldrich FT-IR Library related to organometallic, inorganic, boron and deueterium compounds. The Aldrich Material-Specific FT-IR Library collection represents a wide variety of the Aldrich Handbook of Fine Chemicals' most common chemicals divided by similar functional groups. These spectra were assembled from the Aldrich Collections of FT-IR Spectra Editions I or II, and the data has been carefully examined and processed by Thermo Fisher Scientific. Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds Index Compound Name Index Compound Name 1066 ((R)-(+)-2,2'- 1193 (1,2- BIS(DIPHENYLPHOSPHINO)-1,1'- BIS(DIPHENYLPHOSPHINO)ETHAN BINAPH)(1,5-CYCLOOCTADIENE) E)TUNGSTEN TETRACARBONYL, 1068 ((R)-(+)-2,2'- 97% BIS(DIPHENYLPHOSPHINO)-1,1'- 1062 (1,3- BINAPHTHYL)PALLADIUM(II) CH BIS(DIPHENYLPHOSPHINO)PROPA 1067 ((S)-(-)-2,2'- NE)DICHLORONICKEL(II) BIS(DIPHENYLPHOSPHINO)-1,1'- 598 (1,3-DIOXAN-2- BINAPH)(1,5-CYCLOOCTADIENE) YLETHYNYL)TRIMETHYLSILANE, 1140 (+)-(S)-1-((R)-2- 96% (DIPHENYLPHOSPHINO)FERROCE 1063 (1,4- NYL)ETHYL METHYL ETHER, 98 BIS(DIPHENYLPHOSPHINO)BUTAN 1146 (+)-(S)-N,N-DIMETHYL-1-((R)-1',2- E)(1,5- BIS(DI- CYCLOOCTADIENE)RHODIUM(I) PHENYLPHOSPHINO)FERROCENY TET L)E 951 (1,5-CYCLOOCTADIENE)(2,4- 1142 (+)-(S)-N,N-DIMETHYL-1-((R)-2- PENTANEDIONATO)RHODIUM(I), (DIPHENYLPHOSPHINO)FERROCE 99% NYL)ETHYLAMIN 1033 (1,5- 407 (+)-3',5'-O-(1,1,3,3- CYCLOOCTADIENE)BIS(METHYLD TETRAISOPROPYL-1,3- IPHENYLPHOSPHINE)IRIDIUM(I)
    [Show full text]
  • Ep 2508506 A1
    (19) & (11) EP 2 508 506 A1 (12) EUROPEAN PATENT APPLICATION (43) Date of publication: (51) Int Cl.: 10.10.2012 Bulletin 2012/41 C07C 67/343 (2006.01) C07C 227/08 (2006.01) C07F 5/02 (2006.01) C07C 229/34 (2006.01) (21) Application number: 11161611.6 (22) Date of filing: 08.04.2011 (84) Designated Contracting States: (72) Inventor: The designation of the inventor has not AL AT BE BG CH CY CZ DE DK EE ES FI FR GB yet been filed GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR (74) Representative: Kunic Tesovic, Barbara Designated Extension States: Lek Pharmaceuticals d.d. BA ME Sandoz Development Center Slovenia - Patents Verovskova 57 (71) Applicant: LEK Pharmaceuticals d.d. 1526 Ljubljana (SI) 1526 Ljubljana (SI) (54) Preparation of sitagliptin intermediates (57) The invention relates to the preparation of chiral compounds, in particular to the preparation of chiral compounds which may be used as intermediates for the preparation of anti-diabetic agents, preferably sitagliptin. EP 2 508 506 A1 Printed by Jouve, 75001 PARIS (FR) EP 2 508 506 A1 Description Field of the Intention 5 [0001] The present invention relates to the preparation of chiral compounds, in particular to the preparation of chiral compounds which may be used as intermediates for the preparation of anti-diabetic agents, preferably sitagliptin. Background prior art 10 [0002] Type II diabetes mellitus (T2DM) is a global epidemic. Therefore, the research is oriented in the development of selective inhibitors of the enzyme DPP-IV as a promising new treatment for the type II diabetes.
    [Show full text]
  • Sodium-Bismuthate
    He a lt h 2 0 Fire 0 2 0 Re a c t iv it y 0 Pe rs o n a l Pro t e c t io n J Material Safety Data Sheet Sodium bismuthate MSDS Section 1: Chemical Product and Company Identification Product Name: Sodium bismuthate Contact Information: Catalog Codes: SLS3700, SLS1480 Sciencelab.com, Inc. 14025 Smith Rd. CAS#: 12232-99-4 Houston, Texas 77396 RTECS: VZ1750000 US Sales: 1-800-901-7247 International Sales: 1-281-441-4400 TSCA: TSCA 8(b) inventory: Sodium bismuthate Order Online: ScienceLab.com CI#: Not available. CHEMTREC (24HR Emergency Telephone), call: Synonym: 1-800-424-9300 Chemical Name: Not available. International CHEMTREC, call: 1-703-527-3887 Chemical Formula: NaBiO3 For non-emergency assistance, call: 1-281-441-4400 Section 2: Composition and Information on Ingredients Composition: Name CAS # % by Weight Sodium bismuthate 12232-99-4 100 Toxicological Data on Ingredients: Sodium bismuthate LD50: Not available. LC50: Not available. Section 3: Hazards Identification Potential Acute Health Effects: Hazardous in case of eye contact (irritant), of inhalation. Potential Chronic Health Effects: Hazardous in case of eye contact (irritant), of inhalation. CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, mucous membranes. Repeated or prolonged exposure to the substance can produce target organs damage. Section 4: First Aid Measures Eye Contact: Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention. Skin Contact: No known effect on skin contact, rinse with water for a few minutes.
    [Show full text]
  • 1 Abietic Acid R Abrasive Silica for Polishing DR Acenaphthene M (LC
    1 abietic acid R abrasive silica for polishing DR acenaphthene M (LC) acenaphthene quinone R acenaphthylene R acetal (see 1,1-diethoxyethane) acetaldehyde M (FC) acetaldehyde-d (CH3CDO) R acetaldehyde dimethyl acetal CH acetaldoxime R acetamide M (LC) acetamidinium chloride R acetamidoacrylic acid 2- NB acetamidobenzaldehyde p- R acetamidobenzenesulfonyl chloride 4- R acetamidodeoxythioglucopyranose triacetate 2- -2- -1- -β-D- 3,4,6- AB acetamidomethylthiazole 2- -4- PB acetanilide M (LC) acetazolamide R acetdimethylamide see dimethylacetamide, N,N- acethydrazide R acetic acid M (solv) acetic anhydride M (FC) acetmethylamide see methylacetamide, N- acetoacetamide R acetoacetanilide R acetoacetic acid, lithium salt R acetobromoglucose -α-D- NB acetohydroxamic acid R acetoin R acetol (hydroxyacetone) R acetonaphthalide (α)R acetone M (solv) acetone ,A.R. M (solv) acetone-d6 RM acetone cyanohydrin R acetonedicarboxylic acid ,dimethyl ester R acetonedicarboxylic acid -1,3- R acetone dimethyl acetal see dimethoxypropane 2,2- acetonitrile M (solv) acetonitrile-d3 RM acetonylacetone see hexanedione 2,5- acetonylbenzylhydroxycoumarin (3-(α- -4- R acetophenone M (LC) acetophenone oxime R acetophenone trimethylsilyl enol ether see phenyltrimethylsilyl... acetoxyacetone (oxopropyl acetate 2-) R acetoxybenzoic acid 4- DS acetoxynaphthoic acid 6- -2- R 2 acetylacetaldehyde dimethylacetal R acetylacetone (pentanedione -2,4-) M (C) acetylbenzonitrile p- R acetylbiphenyl 4- see phenylacetophenone, p- acetyl bromide M (FC) acetylbromothiophene 2- -5-
    [Show full text]