Abstract Shape Synthesis from Linear Combinations of Clelia Curves
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Final Poster
Associating Finite Groups with Dessins d’Enfants Luis Baeza, Edwin Baeza, Conner Lawrence, and Chenkai Wang Abstract Platonic Solids Rotation Group Dn: Regular Convex Polygon Approach Each finite, connected planar graph has an automorphism group G;such Following Magot and Zvonkin, reduce to easier cases using “hypermaps” permutations can be extended to automorphisms of the Riemann sphere φ : P1(C) P1(C), then composing β = φ f where S 2(R) P1(C). In 1984, Alexander Grothendieck, inspired by a result of f : 1( ) ! 1( )isaBely˘ımapasafunctionofeither◦ zn or ' P C P C Gennadi˘ıBely˘ıfrom 1979, constructed a finite, connected planar graph 4 zn/(zn +1)! 2 such that Aut(f ) Z or Aut(f ) D ,respectively. ' n ' n ∆β via certain rational functions β(z)=p(z)/q(z)bylookingatthe inverse image of the interval from 0 to 1. The automorphisms of such a Hypermaps: Rotation Group Zn graph can be identified with the Galois group Aut(β)oftheassociated 1 1 rational function β : P (C) P (C). In this project, we investigate how Rigid Rotations of the Platonic Solids I Wheel/Pyramids (J1, J2) ! w 3 (w +8) restrictive Grothendieck’s concept of a Dessin d’Enfant is in generating all n 2 I φ(w)= 1 1 z +1 64 (w 1) automorphisms of planar graphs. We discuss the rigid rotations of the We have an action : PSL2(C) P (C) P (C). β(z)= : v = n + n, e =2 n, f =2 − n ◦ ⇥ 2 !n 2 4 zn · Platonic solids (the tetrahedron, cube, octahedron, icosahedron, and I Zn = r r =1 and Dn = r, s s = r =(sr) =1 are the rigid I Cupola (J3, J4, J5) dodecahedron), the Archimedean solids, the Catalan solids, and the rotations of the regular convex polygons,with 4w 4(w 2 20w +105)3 I φ(w)= − ⌦ ↵ ⌦ 1 ↵ Rotation Group A4: Tetrahedron 3 2 Johnson solids via explicit Bely˘ımaps. -
Abstract Shape Synthesis from Linear Combinations of Clelia Curves’
Putnam, Lance; Todd, Stephen and Latham, William. 2019. ’Abstract Shape Synthesis From Linear Combinations of Clelia Curves’. In: ACM/EG Expressive Symposium 2019. Genoa, Italy 5-6 May 2019. [Conference or Workshop Item] https://research.gold.ac.uk/id/eprint/27622/ The version presented here may differ from the published, performed or presented work. Please go to the persistent GRO record above for more information. If you believe that any material held in the repository infringes copyright law, please contact the Repository Team at Goldsmiths, University of London via the following email address: [email protected]. The item will be removed from the repository while any claim is being investigated. For more information, please contact the GRO team: [email protected] The 8th ACM/EG Expressive Symposium EXPRESSIVE 2019 C. Kaplan, A. Forbes, and S. DiVerdi (Editors) Abstract Shape Synthesis From Linear Combinations of Clelia Curves L. Putnam, S. Todd and W. Latham Computing, Goldsmiths, University of London, United Kingdom Abstract This article outlines several families of shapes that can be produced from a linear combination of Clelia curves. We present parameters required to generate a single curve that traces out a large variety of shapes with controllable axial symmetries. Several families of shapes emerge from the equation that provide a productive means by which to explore the parameter space. The mathematics involves only arithmetic and trigonometry making it accessible to those with only the most basic mathematical background. We outline formulas for producing basic shapes, such as cones, cylinders, and tori, as well as more complex fami- lies of shapes having non-trivial symmetries. -
Abbott's Flatland, 61 Accidental Symmetry, 26 Acetanilide, 62Ff
Index Abbott's Flatland, 61 Antisymmetry (cont.) Accidental symmetry, 26 operations, 190ff Acetanilide, 62ff Archimedean/semiregular polyhedra, 87ff Acetic acid, 96 Architecture, 41, 42, 60, 87, 106, 373 Acetylene, 130 Aromaticity, 322 Adamantane, 129, 131 Artistic expressions, 16, 18, 27, 30, 31, 34, Adamantanes, joint, 131 35, 37, 42, 44, 65, 66, 67, 69, 83, 87, Aesthetic appeal/Beauty/Harmony/Perfection, 90, 99, 150, 191, 194, 240, 324, 349, 1, 13, 16 355,356, 369, 382, 384, 405,457 Alkali halide crystals, 423 Asparagine, 75 Alkali sulfate molecules, 136-137 Asymmetry, 70 Alkanes, 356 Atomic sizes, 420ff Aluminum trichloride, 441ff Aulonia hexagona, 5 Aluminosilicates, 89 Aurelia insulinda, 35 Amino acids, 65, 67, 72ff Average structures, 151-152 Ammonia, 143, 254ff Avogadro's law, 3, 4 Ammonia-aluminum trichloride, 117 Amorphous materials, 456 Bach, J. S., 65 Analogies, 5, 7-8, 60, 67, 74-75, 98-99, Bader, R. E W., 289, 301 114, 139ff, 150, 240, 326, 344, 348, Bands 360ff, 428 one-sided, 342ff Animals, 22ff, 33, 72, 106, 357, 358 scheme to establish the symmetry of, 345 double-headed, 31 seven symmetry classes of, 343 Anisole, 429-430 two-sided bands, 346ff Antarafacial approach, 312, 322 Barlow, W., 405, 422 Antimirror symmetry, 189ff Bart6k, B., 1, 25, 29 Antiprisms, 89, 91, 128 Basic laws of crystals, 385ff Antisymmetry, 70, 189ff, 204 Basis for a representation, 176, 205, 210 elements, 190ff Belousov, B. P, 355 463 464 Index Belousov-Zhabotinsky reactions, 355-356 Character (cont.) Belov, N. V., 81 tables (cont.) Bentley, W. A., 46, 50, 53 C2~, 201,211,249 Benzene, 260ff C3, 259 Benzene derivatives 63, ll5ff, 443 C3v, 186, 202,256 Bernal, J. -
Novel Magnetic Materials Based on Macrocyclic Ligands: Towards High Relaxivity Contrast Agents and Mononuclear Single-Molecule Magnets
Novel Magnetic Materials Based on Macrocyclic Ligands: Towards High Relaxivity Contrast Agents and Mononuclear Single-Molecule Magnets Emma Stares A thesis submitted to the Department of Chemistry in partial fulfillment of the requirements for the Degree of Doctor of Philosophy Supervised by Professor Melanie Pilkington Brock University St. Catharines Ontario, Canada August 2015 © Emma Stares, 2015 Abstract The preparation and characterization of coordination complexes of Schiff-base and crown ether macrocycles is presented, for application as contrast agents for magnetic resonance imaging, Project 1; and single-molecule magnets (SMMs), Projects 2 and 3. II III In Project 1, a family of eight Mn and Gd complexes of N3X2 (X = NH, O) and N3O3 Schiff-base macrocycles were synthesized, characterized, and evaluated as potential contrast agents for MRI. In vitro and in vivo (rodent) studies indicate that the studied complexes display efficient contrast behaviour, negligible toxicity, and rapid excretion. III In Project 2, Dy complexes of Schiff-base macrocycles were prepared with a view to developing a new family of mononuclear Ln-SMMs with pseudo-D5h geometries. Each complex displayed slow relaxation of magnetization, with magnetically-derived energy barriers in the range Ueff = 4 – 24 K. In Project 3, coordination complexes of selected later lanthanides with various crown ether ligands were synthesized. Two families of complexes were structurally and magnetically analyzed: ‘axial’ or sandwich-type complexes based on 12-crown-4 and 15- crown-5; and ‘equatorial’ complexes based on 18-crown-6. Magnetic data are supported by ab initio calculations and luminescence measurements. Significantly, the first mononuclear Ln-SMM prepared from a crown ether ligand is described. -
Chloranilate Frameworks Katherine Bondaruk and Carol Hua* School of Chemistry, the University of Melbourne, Parkville, Victoria, 3010, Australia
Electronic Supplementary Information for: The Effect of Counterions on the Formation and Structures of Ce(III) and Er(III) Chloranilate Frameworks Katherine Bondaruk and Carol Hua* School of Chemistry, The University of Melbourne, Parkville, Victoria, 3010, Australia. *E-mail: [email protected] Table of Contents Table S1. Crystallographic parameters for the 2D (6,3) honeycomb frameworks obtained in this study..S2 Table S2. Crystallographic parameters for the 3D diamond frameworks obtained in this study ...............S3 + Table S3. Crystallographic parameters for frameworks containing PPh3Me obtained in this study.........S4 Table S4. Analysis of the possible coordination geometries using the SHAPE program for the 9- coordinate Ce(III) containing structures, compounds 1, 3 and 5.................................................................S5 Table S5. Analysis of the possible coordination geometries using the SHAPE program for the 8- coordinate Er(III) containing structures, compounds 2, 4 and 7. Where more than one unique Er(III) exists, the analysis is shown for each of the Er(III) centres. .......................................................................S6 Table S6. Analysis of the possible coordination geometries using the SHAPE program for the 9- coordinate Ce(III) centres in compound 6...................................................................................................S7 1-2 Figure S1. The (6,3) [Ce2(can)3(H2O)6] network in [Ce2(can)3(H2O)6]·12H2O ......................................S8 Figure S2. The 3D anionic framework, (DPMP)[Er(can)2] (4) with dia topology. ...................................S8 + + Figure S3. The calculated and experimental powder XRD patterns of 1 with Bu4N and Me4N cations. S9 + + Figure S4. The calculated and experimental powder XRD patterns of 2 with Bu4N and Me4N cations S9 Figure S5. The experimental and calculated powder XRD patterns of 3 .................................................S10 Figure S6. -
Aeronautics and Space Report of the President
Aeronautics and Space Report of the President 1 9 75 Activities NOTE TO READERS: ALL PRINTED PAGES ARE INCLUDED, UNNUMBERED BLANK PAGES DURING SCANNING AND QUALITY CONTROL CHECK HAVE BEEN DELETED Aeronautics and Space Report of the President I975 Activities National Aeronautics and Space Administration Washington, D.C. 20546 President’s Message of Transmittal To the Congress of the United States: We continued to probe the unknown in space. Pioneer 10 will be the first Inan-made object to I am pleased to transmit this report on the Nation‘s venture beyond our solar system. Pioneer 11 will progress in space and aeronautics during 1975. This make the first flyby of Saturn in 1979. In passing report is provided in accordance with Section 206 of Jupiter these vehicles sent back pictures that added the National Aeronautics and Space Act of 1958 as greatly to our knowledge of the largest planet. Last amended (42 U.S.C. 2476). August and September we launched two Viking was another year of continued progress in 1975 spacecraft toward Mars. They will arrive at the the Nation’s space and aeronautics activities. It height of our Bicentennial celebration and may marked significant accomplishments in many areas. provide information on the existence of life in some Earth-orbiting satellites continued to bring new form on our neighboring planet. and increased benefits in a variety of applications. In aeronautics, research focused on the technologies Two additional international communications satel- needed to reduce fuel requirements, noise, and pollu- lites were launched, expanding the already impressive tion. Also emphasized was improved reliability, international satellite communications capability. -
Volume 75 (2019)
Acta Cryst. (2019). B75, doi:10.1107/S2052520619010047 Supporting information Volume 75 (2019) Supporting information for article: Lanthanide coordination polymers based on designed bifunctional 2-(2,2′:6′,2″-terpyridin-4′-yl)benzenesulfonate ligand: syntheses, structural diversity and highly tunable emission Yi-Chen Hu, Chao Bai, Huai-Ming Hu, Chuan-Ti Li, Tian-Hua Zhang and Weisheng Liu Acta Cryst. (2019). B75, doi:10.1107/S2052520619010047 Supporting information, sup-1 Table S1 Continuous Shape Measures (CShMs) of the coordination geometry for Eu3+ ions in 1- Eu. Label Symmetry Shape 1-Eu EP-9 D9h Enneagon 33.439 OPY-9 C8v Octagonal pyramid 22.561 HBPY-9 D7h Heptagonal bipyramid 15.666 JTC-9 C3v Johnson triangular cupola J3 15.263 JCCU-9 C4v Capped cube J8 10.053 CCU-9 C4v Spherical-relaxed capped cube 9.010 JCSAPR-9 C4v Capped square antiprism J10 2.787 CSAPR-9 C4v Spherical capped square antiprism 1.930 JTCTPR-9 D3h Tricapped trigonal prism J51 3.621 TCTPR-9 D3h Spherical tricapped trigonal prism 2.612 JTDIC-9 C3v Tridiminished icosahedron J63 12.541 HH-9 C2v Hula-hoop 9.076 MFF-9 Cs Muffin 1.659 Acta Cryst. (2019). B75, doi:10.1107/S2052520619010047 Supporting information, sup-2 Table S2 Continuous Shape Measures (CShMs) of the coordination geometry for Ln3+ ions in 2- Er, 4-Tb, and 6-Eu. Label Symmetry Shape 2-Er 4-Tb 6-Eu Er1 Er2 OP-8 D8h Octagon 31.606 31.785 32.793 31.386 HPY-8 C7v Heptagonal pyramid 23.708 24.442 23.407 23.932 HBPY-8 D6h Hexagonal bipyramid 17.013 13.083 12.757 15.881 CU-8 Oh Cube 11.278 11.664 8.749 11.848 -
Supporting Information
Supporting Information Exploring the Slow Magnetic Relaxation of a Family of Photoluminescent 3D Lanthanide-Organic Frameworks Based on Dicarboxylate Ligands Itziar Oyarzabal, Sara Rojas, Ana D. Parejo, Alfonso Salinas-Castillo, José Ángel García, José M. Seco, Javier Cepeda and Antonio Rodríguez-Diéguez Index: 1. Powder X-ray Diffraction 2. Additional structural data 3. Interpretation of void content from SQUEEZE analysis 4. Continuous Shape Measures Calculations 5. Magnetic Properties 6. Luminescence Properties 1 S1. Powder X-ray Diffraction Table S1. Data of pattern-matching refinement of compound 2. Space group P-1 a (Å) 10.87(2) b(Å) 11.11(2) c(Å) 13.26(3) α (°) 105.28(2) β (°) 94.22(3) γ (°) 93.65(2) V/ Å3 1534(3) Figure S1. Pattern-matching analysis and crystalline parameters of the polycrystalline sample of compound 2. Table S2. Data of pattern-matching refinement of compound 3. Space group P-1 a (Å) 10.85(2) b(Å) 11.04(4) c(Å) 13.21(2) α (°) 105.01(2) β (°) 94.90(4) γ (°) 93.90(4) V/ Å3 1516(5) Figure S2. Pattern-matching analysis and crystalline parameters of the polycrystalline sample of compound 3. 2 Table S3. Data of pattern-matching refinement of compound 4. Space group P-1 a (Å) 10.86(2) b(Å) 11.03(4) c(Å) 13.20(2) α (°) 105.20(2) β (°) 94.38(4) γ (°) 93.75(4) V/ Å3 1515(5) Figure S3. Pattern-matching analysis and crystalline parameters of the polycrystalline sample of compound 4. 3 S2. -
Acoustic Vibrations of Au Nano-Bipyramids and Their
Acoustic Vibrations of Au Nano-Bipyramids and their Modification under Ag Deposition: a Perspective for the Development of Nanobalances Benoît Dacosta Fernandes, Miguel Spuch-Calvar, Hatim Baida, Mona Tréguer-Delapierre, Jean Oberlé, Pierre Langot, Julien Burgin To cite this version: Benoît Dacosta Fernandes, Miguel Spuch-Calvar, Hatim Baida, Mona Tréguer-Delapierre, Jean Oberlé, et al.. Acoustic Vibrations of Au Nano-Bipyramids and their Modification under Ag Depo- sition: a Perspective for the Development of Nanobalances. ACS Nano, American Chemical Society, 2013, 7 (9), pp.7630-7639. 10.1021/nn402076m. hal-00874407 HAL Id: hal-00874407 https://hal.archives-ouvertes.fr/hal-00874407 Submitted on 1 Mar 2018 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Distributed under a Creative Commons Attribution - NonCommercial| 4.0 International License Acoustic Vibrations of Au Nano- Bipyramids and their Modification under Ag Deposition: a Perspective for the Development of Nanobalances Benoıˆt Dacosta Fernandes,† Miguel Spuch-Calvar,‡ Hatim Baida,† Mona Tre´guer-Delapierre,‡ Jean Oberle´,† Pierre Langot,† and Julien Burgin†,* †Univ. Bordeaux, LOMA, UMR 5798, F-33400 Talence, France and ‡CNRS, Univ. Bordeaux, ICMCB, UPR 9048, F-33600 Pessac, France ABSTRACT We investigated the acoustic vibrations of gold nanobipyramids and bimetallic gold silver core shell bipyramids, synthesized by wet chemistry techniques, using a high-sensitivity pump probe femtosecond setup. -
Metallaheteroboranes Containing Group 16 Elements: an Experimental and Theoretical Study
Journal of Organometallic Chemistry 883 (2019) 71e77 Contents lists available at ScienceDirect Journal of Organometallic Chemistry journal homepage: www.elsevier.com/locate/jorganchem Metallaheteroboranes containing group 16 elements: An experimental and theoretical study * Moulika Bhattacharyya, Rini Prakash, R. Jagan, Sundargopal Ghosh Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India article info abstract Article history: Thermolysis of diphenyl dichalcogenides, Ph2E2 (E ¼ S, Se and Te) with an insitu generated intermediate, Received 19 November 2018 5 obtained from the reaction of [Cp*WCl4] (Cp* ¼ h -C5Me5) with [LiBH4$THF], yielded new tung- Received in revised form staheteroboranes, [(Cp*W)2(m-EPh)(m3-E)(m-H)(B3H2EPh)], 1 and 2 (1:E¼ S; 2:E¼ Se), and [(Cp*W)2(m- 9 January 2019 TePh)B H (m-H) ], 4. Formation of compounds 1 and 2 substantiate the evidence of [(Cp*W) B H ], Accepted 11 January 2019 5 5 3 2 4 10 which supports our previous studies. Compound 4 has a capped octahedral geometry that is unique due Available online 17 January 2019 to the presence of three W-H-B bridging hydrogens in a closo cluster. Alternatively, the shape of cluster 4 can be defined as oblatoarachno that can be derived from a heptagonal bipyramid. All the compounds Keywords: 1 11 1 13 1 Oblatoarachno have been characterized by mass spectrometry, H, B{ H}, IR and C{ H} NMR spectroscopy in solution Metallaheteroboranes and the structural architectures of 1 and 4 were unequivocally established by X-ray crystallographic Tungsten analysis. The density functional theory calculations also yielded geometries in close agreement with the Diphenyl dichalcogenide observed structures. -
Biomimetics Scrivener Publishing 100 Cummings Center, Suite 541J Beverly, MA 01915-6106
Biomimetics Scrivener Publishing 100 Cummings Center, Suite 541J Beverly, MA 01915-6106 Biomedical Science, Engineering, and Technology The book series seeks to compile all the aspects of biomedi- cal science, engineering and technology from fundamental principles to current advances in translational medicine. It covers a wide range of the most important topics including, but not limited to, biomedical materials, biodevices and biosys- tems, bioengineering, micro and nanotechnology, biotechnology, biomolecules, bioimaging, cell technology, stem cell engineering and biology, gene therapy, drug delivery, tissue engineering and regeneration, and clinical medicine. Series Editor: Murugan Ramalingam, Centre for Stem Cell Research Christian Medical College Bagayam Campus Vellore-632002, Tamilnadu, India E-mail: [email protected] Publishers at Scrivener Martin Scrivener ([email protected]) Phillip Carmical ([email protected]) Biomimetics Advancing Nanobiomaterials and Tissue Engineering Edited by Murugan Ramalingam, Xiumei Wang, Guoping Chen, Peter Ma, and Fu-Zhai Cui Copyright © 2013 by Scrivener Publishing LLC. All rights reserved. Co-published by John Wiley & Sons, Inc. Hoboken, New Jersey, and Scrivener Publishing LLC, Salem, Massachusetts. Published simultaneously in Canada. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning, or other - wise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4470, or on the web at www.copyright.com. -
Quaternionic Kleinian Modular Groups and Arithmetic Hyperbolic Orbifolds Over the Quaternions
Università degli Studi di Trieste ar Ts Archivio della ricerca – postprint Quaternionic Kleinian modular groups and arithmetic hyperbolic orbifolds over the quaternions 1 1 Juan Pablo Díaz · Alberto Verjovsky · 2 Fabio Vlacci Abstract Using the rings of Lipschitz and Hurwitz integers H(Z) and Hur(Z) in the quater- nion division algebra H, we define several Kleinian discrete subgroups of PSL(2, H).We define first a Kleinian subgroup PSL(2, L) of PSL(2, H(Z)). This group is a general- ization of the modular group PSL(2, Z). Next we define a discrete subgroup PSL(2, H) of PSL(2, H) which is obtained by using Hurwitz integers. It contains as a subgroup PSL(2, L). In analogy with the classical modular case, these groups act properly and discontinuously on the hyperbolic quaternionic half space. We exhibit fundamental domains of the actions of these groups and determine the isotropy groups of the fixed points and 1 1 describe the orb-ifold quotients HH/PSL(2, L) and HH/PSL(2, H) which are quaternionic versions of the classical modular orbifold and they are of finite volume. Finally we give a thorough study of their descriptions by Lorentz transformations in the Lorentz–Minkowski model of hyperbolic 4-space. Keywords Modular groups · Arithmetic hyperbolic 4-manifolds · 4-Orbifolds · Quaternionic hyperbolic geometry Mathematics Subject Classification (2000) Primary 20H10 · 57S30 · 11F06; Secondary 30G35 · 30F45 Dedicated to Bill Goldman on occasion of his 60th birthday. B Alberto Verjovsky [email protected] Juan Pablo Díaz [email protected] Fabio Vlacci [email protected]fi.it 1 Instituto de Matemáticas, Unidad Cuernavaca, Universidad Nacional Autónoma de México, Av.