Integrated Evaluation of Petroleum Impacts to Soil Randy Adams, D. Marín, C. Avila, L. de la Cruz, C. Morales, and V. Domínguez Universidad Juárez Autónoma de Tabasco, Villahermosa, Mexico
[email protected] 1.00 0.90 0.80 0.70 0.60 R2 = 0.9626 0.50 0.40 1-IAFcorr 0.30 0.20 0.10 0.00 0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000 Conc. hidrocarburos (mg/Kg) Actual Modelo BACKGROUND U J A T •Clean-up criteria for petroleum contaminated soils developed in US in 60’s and 70’s on drilling cuttings •1% considered OK – no or only slight damage to crops, only lasts one growing season •Bioassays confirmed low toxicity of residual oil •Subsequenty used as a basis for clean-up criteria for hydrocarbons in soils in many countries does not consider kind of hydrocarbons does not consider kind of soil SISTEMATIC EVALUATION U J A T •Selection of light, medium, heavy and extra-heavy crudes •Selection of 5 soil types common in petroleum producing region of SE Mexico •Contamination of soil at different concentrations •Measurement of acute toxicity (Microtox), and subchronic toxicity (28 d earthworm) •Measurement of impacts to soil fertility: water repellency, soil moisure, compaction, complemented with in situ weathering experiments •Measurement of plant growth: pasture, black beans Crude Petroleum Used in Study U J A T 100% 80% 60% Aliphatics Aromatics 40% Polars + Resins Asphaltenes 20% 0% Light Crude Medium Crude Heavy Crude Extra-heavy Crude 37 ºAPI 27 ºAPI 15 ºAPI 3 ºAPI U J A T FAO: FLUVISOL VERTISOL GLEYSOL ARENOSOL ACRISOL USDA: FLUVENT