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2,999,016 ' ii i United States Patent ice lsaten'ted Sept. 5, 1961 1 2 possible to produce duplicate masters from an original 2,999,016 drawing or to make a reproduction from an ordinary DRAWING MATERIAL _ Allan R. A. Beeber, Elizabeth, N.J., and Daniel S. drawing on to the scribing material. The reproduced out~ Spechler, Brooklyn, N.Y., assignors to Keut‘r‘el & Esser line may then be followed by the scribing technique to Company, Hoboken, N .J., a corporation of New Jersey form a master which acts as a' photographic negative to No Drawing. Filed Mar. 24, 1955, Ser. No. 496,602 form further reproductions. The invention also contem; ' 29 ‘Claims. (Cl. 96-75) plates the use of metallic scribing layers which may be applied to the surface of the foil by evaporation in high This invention relates to drawing and highly accurate vacuum or by deposition from chemical solutions instead reproduction processes such as used ‘by draftsmen and for of the organic scribing layers. When the metallic scribing the production of templates suitable for factory operations layers are used, it is also possible to apply a photosensi and the production of precise maps and the like. ' tive resist over the metallic layer and after developing ‘Patent 2,718,476 to Eichorn describes dimensionally the resist image, the unprotected metal may be etched stable‘materials for these purposes which are based on away by means of a suitable chemical solution to form an ‘woven glass cloth material impregnated with a polyester 15 image which is readily photographically reproduced. _ resin. It has now been found that it is possible to obtain These photosensitive resists may also be applied over the same degree of dimensional stability without the need opaque organic layers which may be etched away by an for using glass-cloth by using a base material which is a organic solvent. For example, M. Hepher and E. E. transparent or translucent ?lm of polyester material‘. Leoning (Kodak Ltd., Harrow, England), published a. These ?lms may range in thickness from .001” to .010", 20 method for dissolving away an organic layer through a. but are usualy .003" to .007" thick. This material has photo ‘mechanical resist using polyethylene glycol to, additional advantages because it is more transparent than prevent undercutting. _ the glass cloth material, it is free from ?bers giving it a _ Besides the use in template work as described above,. smoother drawing surface and eliminating the ?ber pat the new materials and processes of the present invention tern from the background on reproductions made through 25 will ?nd considerable use in mapping work. The scribing; the material. It is more ?exible and therefore can be materials in particular will ?nd considerable use in this lhandled morefreely. It has better initial .tear strength ?eld. A high degree of precision is essential in this work. ‘and its cost is lower. because color separation plates are very often made. One of the most important uses for the new material Those portions of a complete compilation map which are: is in the production of templates, particularly for aircraft 30 to be reproduced in- anyone color ‘are scribed on one: construction. This is done bymaking full'scale drawings ‘ sheet of the dimensionally stable material. Each scribed; on the new material for the templates or. patterns and then sheet then becomes a negative from which the correspond- reproducing them on the actual construction materials ing color plate-is made for printing the map. Obviously, such as aluminum, magnesium, etc. .The usual drawing the different color plates must all register when the ?n materials such as tracing ‘paper and tracing cloth do not 35 ished maps are produced so a high degree of dimensional have su?icient dimensional stability for this purpose be stability is essential in the scribing material. The material cause they are hygroscopic and expand or contract with provided with a metallic scribing layer and a photo— changes of atmospheric moisture as well as with tempera, mechanical resist layer thereover is particularly suitable ture changes thus making it impossible to hold the min in this work since the photo-mechanical resist can be used ute tolerances and exact dimensions necessary for preci to print lettering and symbols which can then be produced: sion machining. _ . in negative form by etching away the metallic coating. 7 ' Prior to the development of the glass cloth material The polyester ?lm used in the present invention is: mentioned above, countless hours were expended in scrib formed from a dibasic acid and a glycol. In particular, ing production drawings on metal templates such as sheet the polyester resin formed from terephthalic acid and aluminum. Many attempts were made to drawn on some ethylene glycol forms a ?lm of excellent dimensional sta-v more stable material or to directly attach a less stable bility, particularly when the molecules are properly. sheet of paper or the like to the metal template. Thus orientated. This ?lm is marketed by the E. I. du Pont de" drawings have been made on metal foil, or ‘paper drawings Nemours Co. under the name of “Mylar.” The linear. made to scale have been attached to metal or other back polymers formed by the reaction of the‘ terephthalic a, d‘, ing by use of various plastic or adhesive compositions. and ethylene glycol are oriented along the ?ber axis in‘, Numerous attempts have also been made to transfer such the production of the ?lm in order to obtain the desired‘ drawings to templates by means of photosensitive mate characteristics. This type of ?lm , will be referred to rial, but because of the opaque nature of the backing hereinafter as a ?lm of oriented, polyester resins formed. material, these processes have generally relied on a re?ex principally from tere'phthalic acid and ethylene glycol. photographic process. The transparent nature of the present material offers a wide variety of reproduction Thisand dimensionalpolyester ?lm stability. has good Both light surfaces transmission, may be ?exibilit smooth processes for transferring the image drawn on the stable or one or the other surface may be provided with a dull polyester ?lm to the metal template. ' " " ' or matte ?nish formed in the polyester ?lm itself. The‘ In its simplest form, the polyester ‘?lm, is provided with matte surface may provide slightly better adhesion, for. a pencil and ink receptive surface suitable for‘ drawings 60 some of the coatings which are used although it is not made in the usual manner as on, tracing paper and tracing ~ essential for adhesion of these coatings. It'has been.‘ cloth. These drawings can be readily‘reproduced on to found that coatings including a substantialproportion metal templates or any other base where a high degree of of an alkyd resinhaveygood adhesion to the polyester dimensional stability is‘ essential. In another form, the ?lm. ‘However, the alkyd resin may be modi?ed'by the; 65 addition of other resins including nitro-cellulose, urea polyester foil is provided with a scribing layer which is formaldehyde ‘and melamine formaldehyderesins. As" opaque to actinic light. When using this‘ material, the ‘ examples of alkyd resins which may be used in these coat original drawing is made by scribing techniques which are ings, the “Rezyl” resins of the American Cyanarnide Co.‘ preferred in‘many cases where the highest accuracy is particularly numbers 387-5, 330-5, 435-1 and the “Glypt desired. The invention also contemplates photo-sensitive 70 a1” resins particularly No. 2522, of the General Electric, coatings applied over the pencil and ink receptive (surfaces . Co. may be used. vThese are basically glycerol phthalate, or over the scribing surface. These materials make it ' which is oil modi?ed for examP to with cast'or oil or so Y a 2,999,016 3 oil. Rezyl resin 387~5 is described in the National done by applying a thin coat of alkyd resin followed by Paint, Varnish and Lacquer Association, supplement 2 a thin coat of an emulsion of vinyl acetate and Ethocel to circular 738, dated September 1952 at page 61a and containing a small amount of pigment and then applying according to the above publication the solids content of two coats of the diazotype formulae of Example III. Rezyl 387-5 is 41% phthalic anhydride, 33% soy bean 01 A brownprint composition containing the usual light oil, and the resin has an acid number maximum of 12. sensitive ferric salt, silver nitrate and keeping salts in a In order to make these coatings receptive to pencil gelatin carrier may be applied on the pencil and ink and ink lines, considerable pigment is incorporated. Par receptive coating. ticularly, siliceous pigment materials may be used includ The scribe coatings which may be applied to the poly ing pure silica and silicates such as diatomaceous talc. 10 ester ?lm generally also require an alkyd or polyester However, the pigment should be transparent in order to resin in substantial proportion. The coating is loaded transmit light for photographic purposes and for this with pigments and/ or dyes to give it the required degree reason, pure silica is usually preferred as the pigment. of visual or actinic opacity as required. The addition Some typical examples of suitable coatings for pencil of nitrocellulose can be incorporated provided the other and ink acceptance are given below: ingredients are properly balanced and this may be desira ble in order to give the coatings suf?cient hardness. The Example I usual opaque pigments such as titanium dioxide are suita 10 lbs of pigment (SiO;) ble particularly for light colors. A high proportion of 5 lbs.
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