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Safety Data Sheet 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier

Code: ZZSHA81606 Product name MXSHA00240 MILKSUBLIME SHAMPOO 1000 MLNOOK BEAUTY FAMILY

1.2. Relevant identified uses of the substance or mixture and uses advised against

Intended use cosmetic use

1.3. Details of the supplier of the safety data sheet

Name MAXIMA srl Full address Via Staffali, 7 District and Country 37062 Villafranca di Verona (VR) ITALIA Tel. +39(0) 458601074 Fax +39(0) 458618400 e-mail address of the competent person responsible for the Safety Data Sheet [email protected]

Product distribution by MAXIMA srl

1.4. Emergency telephone number

For urgent inquiries refer to +39 0458601074

2. Hazards identification.

2.1. Classification of the substance or mixture.

The product is classified as hazardous pursuant to the provisions set forth in Directives 67/548/EEC and 1999/45/EC and/or EC Regulation 1272/2008 (CLP) (and subsequent amendments and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulationn 1907/2006 and subsequent amendments. Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet.

Danger Symbols: Xi

R phrases: 41

The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet.

2.2. Label elements.

Hazard labelling pursuant to Directives 67/548/EEC and 1999/45/EC and subsequent amendments and supplements.

Xi

IRRITANT

R41 RISK OF SERIOUS DAMAGE TO EYES.

S25 AVOID CONTACT WITH EYES. S26 IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. S39 WEAR EYE/FACE PROTECTION.

2.3. Other hazards.

Information not available.

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3. Composition/information on ingredients. 3.1. Substances.

Information not relevant.

3.2. Mixtures.

Contains:

Identification. Conc. %. Classification 67/548/EEC. Classification 1272/2008 (CLP).

Ammonium Lauryl Sulfate CAS. 2235-54-3 1 - 5 Xi R38, Xi R41 Eye Dam. 1 H318, Skin Irrit. 2 H315 EC. 2187399 INDEX. - Myreth Sulfate CAS. 68891-38-3 1 - 5 Xi R36/38 Eye Irrit. 2 H319, Skin Irrit. 2 H315 EC. - INDEX. - Sodium Cocoamphoacetate CAS. 68608-65-1 1 - 5 Xi R41 Eye Dam. 1 H318 EC. 271-793-0 INDEX. - Guar Hydroxypropyltrimonium Chloride CAS. 65497-29-2 0,1 - 1 Xi R36/38 EC. - INDEX. - ISOCAMPHENYL CYCLOHEXANOL MIXD ISOMERS CAS. 66068-84-6 0 - 0,1 Xi R38 EC. 266-100-3 INDEX. - BUTYL ISOBUTYRATE CAS. 97-87-0 0 - 0,1 Xi R36/38 EC. 202-614-6 INDEX. -

T+ = Very Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Oxidizing(O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F), N = Dangerous for the Environment(N)

The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet.

4. First aid measures. 4.1. Description of first aid measures. No harm to the staff authorised to use has been reported. However, in case of contact, inhalation or ingestion, the following general measures provided for a first aid shall be taken. INHALATION: remove to open air. If respiration is difficult, administer artificial respiration and seek medical advice. INGESTION: seek medical attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious person. EYES and SKIN: wash with plenty of water; if the irritation persists, seek medical advice.

4.2. Most important symptoms and effects, both acute and delayed. No episodes of damage to health ascribable to the product have been reported.

4.3. Indication of any immediate medical attention and special treatment needed. Follow doctor's orders.

5. Firefighting measures.

5.1. Extinguishing media. SUITABLE EXTINGUISHING MEDIA The extinction equipment should be of the conventional kind: dioxide, foam, powder and nebulised water. EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONS None in particular.

5.2. Special hazards arising from the substance or mixture. HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE Do not breathe combustion products (carbon oxide, toxic pyrolysis products, etc).

5.3. Advice for firefighters. GENERAL INFORMATION

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Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS Hardhat with visor, fireproof clothing (fireproof jacket and trousers with straps around arms, legs and waist), work gloves (fireproof, cut proof and dielectric), a depressurised mask with facemask covering the whole of the operator`s face or a self-respirator (self-protector) in the event of large quantities of fume.

6. Accidental release measures. 6.1. Personal precautions, protective equipment and emergency procedures. If there are no contraindications, spray powder with water to prevent the formation of dust. Use breathing equipment if powders are released into the air.

6.2. Environmental precautions. The product must not penetrate the sewer system, surface water, ground water and neighbouring areas.

6.3. Methods and material for containment and cleaning up. Use mechanical tools to collect leaked product and eliminate the remainder using jets of water. Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13.

6.4. Reference to other sections. Any information on personal protection and disposal is given in sections 8 and 13.

7. Handling and storage. 7.1. Precautions for safe handling. Store in closed, labelled containers.

7.2. Conditions for safe storage, including any incompatibilities. Normal storage conditions without particular incompatibilities.

7.3. Specific end use(s). Information not available.

8. Exposure controls/personal protection.

8.1. Control parameters. Information not available.

8.2. Exposure controls.

As the use of adequate technical equipment must always take priority over personal protection equipment, make sure that the workplace is well aired through effective local aspiration or bad air vent. If such operations do not make it possible to keep the concentration of the product below the permitted workplace exposure thresholds a suitable respiratory tract protection must be used. See product label for hazard details during use. Ask your chemical substance suppliers for advice when choosing personal protection equipment. Personal protection equipment must comply with the rules in force indicated below. HAND PROTECTION Protect hands with category I (ref. Directive 89/686/EEC and standard EN 374) work gloves, such as those in latex, PVC or equivalent. The following should be considered when choosing work glove material: degradation, breakage times and permeation. Work glove resistance to preparations should be checked before use, as it can be unpredictable. Gloves` limit depends on the duration of exposure. EYE PROTECTION Wear hood visor or protective visor together with airtight goggles (ref. standard EN 166). SKIN PROTECTION Wear category I professional long-sleeved overalls and safety footwear (ref. Directive 89/686/CEE and standard EN 344). Wash body with and water after removing overalls. RESPIRATORY PROTECTION If the threshold value for one or more of the substances present in the preparation for daily exposure in the workplace or to a fraction established by the company`s prevention and protection service is exceeded, wear a mask with an A or universal filter, the class (1, 2 or 3) of which must be chosen according to the limit concentration of use (ref. standard EN 141). The use of breathing protection equipment, such as masks with organic vapour and dust/mist cartridges, is necessary in the absence of technical measures limiting worker exposure. The protection provided by masks is in any case limited. If the substance in question is odourless or its olfactory threshold is higher than the relative exposure limit and in the event of an emergency, or when exposure levels are unknown or the concentration of in the workplace is less than 17% volume, wear self-contained, open-circuit compressed air breathing apparatus (ref. standard EN 137) or fresh air hose breathing apparatus for use with full face mask, half mask or mouthpiece (ref. standard EN 138). An emergency eye washing and shower system must be provided.

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9. Physical and chemical properties. 9.1. Information on basic physical and chemical properties. Appearance liquid Colour beige Odour characteristic Odour threshold. Not available. pH. 5,5-6,0 Melting or freezing point. Not available. Boiling point. Not available. Distillation range. Not available. Flash point. Not available. Evaporation Rate Not available. Flammability of solids and gases Not available. Lower inflammability limit. Not available. Upper inflammability limit. Not available. Lower explosive limit. Not available. Upper explosive limit. Not available. Vapour pressure. Not available. Vapour density Not available. Specific gravity. 1,020 Kg/l Solubility soluble in water Partition coefficient: n-octanol/water Not available. Ignition temperature. Not available. Decomposition temperature. Not available. Viscosity 3000-7000 cps Reactive Properties Not available.

9.2. Other information. VOC (Directive 1999/13/EC) : 0,02 % - 0,18 g/litre. VOC (volatile carbon) : < 0.01 % - 0,09 g/litre.

10. Stability and reactivity.

10.1. Reactivity. There are no particular risks of reaction with other substances in normal conditions of use.

10.2. Chemical stability. The product is stable in normal conditions of use and storage.

10.3. Possibility of hazardous reactions. No hazardous reactions are foreseeable in normal conditions of use and storage.

10.4. Conditions to avoid. None in particular, however the usual precautions used for chemical products should be respected.

10.5. Incompatible materials. Information not available.

10.6. Hazardous decomposition products. In the event of thermal decomposition or fire, vapours potentially dangerous to health may be released.

11. Toxicological information.

11.1. Information on toxicological effects. This product may cause serious ocular lesions, cornea opacity, iris lesions, irreversible eye coloration.

SODIUM CHLORIDE LD50 (Oral): 3000 mg/kg Rat

12. Ecological information. Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or sewers or contaminate soil or vegetation.

12.1. Toxicity. Information not available.

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12.2. Persistence and degradability. Information not available.

12.3. Bioaccumulative potential. Information not available.

12.4. Mobility in soil. Information not available.

12.5. Results of PBT and vPvB assessment. Information not available.

12.6. Other adverse effects. Information not available.

13. Disposal considerations. 13.1. Waste treatment methods. Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

14. Transport information. The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations.

15. Regulatory information.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture.

Seveso category. None.

Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006. Product. Point. 3

Substances in Candidate List (Art. 59 REACH). None.

Substances subject to authorisarion (Annex XIV REACH). None.

Healthcare controls. Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks related to the workers' health and safety are modest and that the 98/24/EC directive is respected.

15.2. Chemical safety assessment.

No chemical safety assessment has been processed for the mixture and the substances it contains.

16. Other information. Text of hazard (H) indications mentioned in section 2-3 of the sheet:

Eye Dam. 1 Serious eye damage, category 1 Skin Irrit. 2 Skin irritation, category 2 Eye Irrit. 2 Eye irritation, category 2 H318 Causes serious eye damage. H319 Causes serious eye irritation. H315 Causes skin irritation.

Text of risk (R) phrases mentioned in section 2-3 of the sheet:

R36/38 IRRITATING TO EYES AND SKIN. R38 IRRITATING TO SKIN. R41 RISK OF SERIOUS DAMAGE TO EYES.

GENERAL BIBLIOGRAPHY

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1. Directive 1999/45/EC and following amendments 2. Directive 67/548/EEC and following amendments and adjustments 3. Regulation (EC) 1907/2006 (REACH) of the European Parliament 4. Regulation (EC) 1272/2008 (CLP) of the European Parliament 5. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament 6. Regulation (EC) 453/2010 of the European Parliament 7. The Merck Index. - 10th Edition 8. Handling Chemical Safety 9. Niosh - Registry of Toxic Effects of Chemical Substances 10. INRS - Fiche Toxicologique (toxicological sheet) 11. Patty - Industrial Hygiene and Toxicology 12. N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition

Note for users: The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product . This document must not be regarded as a guarantee on any specific product property. The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses.

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