DOCSLIB.ORG

Wo 2008/107347 A2

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Wo 2008/107347 A2 (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date PCT (10) International Publication Number 12 September 2008 (12.09.2008) WO 2008/107347 A2 (51) International Patent Classification: (74) Common Representative: CIBA HOLDING INC.; A61K 8/04 (2006.01) A61K 8/42 (2006.01) Patent Department, Klybeckstrasse 141, CH-4057 Basel A61K 8/35 (2006.01) A61K 8/49 (2006.01) (CH). A61K 8/41 (2006.01) A61Q 17/04 (2006.01) (81) Designated States (unless otherwise indicated, for every (21) International Application Number: kind of national protection available): AE, AG, AL, AM, PCT/EP2008/052336 AO, AT,AU, AZ, BA, BB, BG, BH, BR, BW, BY, BZ, CA, CH, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, EE, (22) International Filing Date: EG, ES, FT, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, 27 February 2008 (27.02.2008) IL, IN, IS, JP, KE, KG, KM, KN, KP, KR, KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME, MG, MK, MN, (25) Filing Language: English MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PG, PH, PL, PT, RO, RS, RU, SC, SD, SE, SG, SK, SL, SM, SV, (26) Publication Language: English SY, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, (30) Priority Data: ZA, ZM, ZW 07103670.1 7 March 2007 (07.03.2007) EP (84) Designated States (unless otherwise indicated, for every (71) Applicant (for all designated States except US): CIBA kind of regional protection available): ARIPO (BW, GH, HOLDING INC. [CWCH]; Klybeckstrasse 141, CH-4057 GM, KE, LS, MW, MZ, NA, SD, SL, SZ, TZ, UG, ZM, Basel (CH). ZW), Eurasian (AM, AZ, BY, KG, KZ, MD, RU, TJ, TM), European (AT,BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, (72) Inventors; and FR, GB, GR, HR, HU, IE, IS, IT, LT,LU, LV,MC, MT, NL, (75) Inventors/Applicants (for US only): DESHAYES, NO, PL, PT, RO, SE, SI, SK, TR), OAPI (BF, BJ, CF, CG, Cyrille [FR/FR]; 52, rue de Village-Neuf, F-68128 CI, CM, GA, GN, GQ, GW, ML, MR, NE, SN, TD, TG). Rosenau (FR). EHLIS, Thomas [DE/DE]; Har- riet-Straub-Strasse 23, 79100 Freiburg (DE). GRUME- Published: LARD, Julie [FR/FR]; 2, rue de Mulhouse, F-68330 — without international search report and to be republished Huningue (FR). upon receipt of that report (54) Title: METHOD FOR THE STABILIZATION OF ORGANIC MICRONIZED UV ABSORBERS (57) Abstract: Disclosed is the use of amines and amides for the stabilization of a cosmetic composition comprising: (a) an organic micronized UV absorber selected from a benzophenone derivative and (b) a dibenzoylmethane derivative. The use of the amines and amides results in the stabilization of the end-product formulations. Method for the stabilization of organic micronized UV absorbers The present invention relates to a method of stabilization of organic micronized UV absorb ers, specific cosmetic compositions and the use of these cosmetic composition for preventing the human hair or skin from the harmful effect of UV radiation Cosmetic compositions comprising micronized amino substituted hydroxyphenyl benzophe- none derivatives (as described for example in WO 2004/052837) and Butyl methoxydiben- zoylmethane (Avobenzone) represent very effectual UV absorber compositions. However, mixing together these specific UV actives results in the formation of new and larger scaled crystals and/or particles. This crystallization affects the efficacy of the UV-filter combination and the sensory aspect of the end-product Surprisingly it has been found that the crystallization can be slowed, limited and/or prevented by the use of amines, amides, alkanolamides and more preferably alkanolamines in the m i cronized product or within the end-product formulation. As a result, a stabilization of the end- product formulation is achieved. Therefore, the present invention refers to the use of amines and amides for the stabilization of a cosmetic composition comprising (a) an organic micronized UV absorber selected from a benzophenone derivative and (b) a dibenzoylmethane derivative. The benzophenone UV absorbers preferably correspond to formula ( 1 ) , wherein Ri and R2 independently from each other are; Ci-C 2oalkyl; C2-C2oalkenyl; C3-Ci 0cycloalkyl; C3-Ciocycloalkenyl; or R1 and R2 together with the linking nitrogen atom form a 5- or 6- membered heterocyclic ring; n-i is a number from 1 to 4 ; , R3 is a saturated or unsaturated heterocyclic radical; hydroxy-Ci-C 5alkyl; cyclohexyl option ally substituted with one or more CrC 5alkyl; phenyl optionally substituted with a hetero cyclic radical, aminocarbonyl or d-C 5alkylcarboxy; R3 is an alkylene-, cycloalkylene alkenylene or phenylene radical which is optionally inter rupted by -O-; -NH-; a carbonyl- or carboxy group; a radical of formula *— CH— C≡ C-CH — * or R3 together with A forms a bivalent radical of the formula (1a) ; wherein n2 is a number from 1 to 3 ; R3 is an alkantriyl radical; R3 is an alkanetetrayl radical; A is -O-; Or-N(R 5)-; and R5 is hydrogen; Ci-C 5alkyl; or hydroxy-Ci-C 5alkyl. Ci-C 20alkyl denotes a linear or branched, unsubstituted or substituted alkyl group such as, for example, methyl, ethyl, propyl, isopropyl, n-butyl, n-hexyl, cyclohexyl, n-decyl, n-dodecyl, n- octadecyl, eicosyl, methoxyethyl, ethoxypropyl, 2-ethylhexyl, hydroxyethyl, chloropropyl, N,N- diethylaminopropyl, cyanoethyl, phenethyl, benzyl, p-tert-butylphenethyl, p-tert-octyl- phenoxyethyl, 3-(2,4-di-tert-amylphenoxy)-propyl, ethoxycarbonylmethyl-2-(2-hydroxy- ethoxy)ethyl or 2-furylethyl. C2-C20alkenyl is for example allyl, methallyl, isopropenyl, 2-butenyl, 3-butenyl, isobutenyl, n- penta-2,4-dienyl, 3-methyl-but-2-enyl, n-oct-2-enyl, n-dodec-2-enyl, iso-dodecenyl, n-dodec- 2-enyl or n-octadec-4-enyl. C3-Ci 0cycloalkyl is for example cyclopropyl, cyclobutyl, cyclopentyl, cycloheptyl, cyclooctyl, cyclononyl or cyclodecyl and preferably cyclohexyl. These radicals may be substituted, for example by one or more or equal or different d-C 4alkyl radicals, preferably by methyl, and/or hydroxy. If cycloalkyl radicals are substituted by one or more radicals, they are preferably substituted by one, two or four, preferably by one or two equal or radicals. C3-Ci 0cycloalkenyl is for example cyclopropenyl, cyclobutenyl, cyclopentenyl, cycloheptenyl, cycloocentyl, cyclononenyl or cyclodecenyl and preferably cyclohexenyl. These radicals may be substituted with one or more equal or different Ci-C 4alkyl radical, preferably with methyl, and/or hydroxy. If cycloalkenyl radicals are substituted with one or more radicals they are preferably substituted with one, two, three or four, preferably with one or two equal or differ ent radicals. Hydroxy-substituted Ci-C 5alkyl groups are for example hydroxymehtyl, hydroxyethyl, hy- droxypropyl, hydroxybutyl or hydroxypentyl. An alklyene radical is preferably a CrC^alkylene radical, like for example methylene, ethyl ene, propylene, butylene, hexylene or octylene. The alklyene radicals may optionally be substituted by one or more Ci-C 5alkyl radicals. If R1 and R2 are heterocyclic radicals, these comprise one, two, three or four equal or differ ent ring hetero atoms. Special preference is given to heterocycles which contain one, two or three, especially one or two, identical or different hetero atoms. The heterocycles may be mono- or poly-cyclic, for example mono-, bi- or tri-cyclic. They are preferably mono- or bi- cyclic, especially monocyclic. The rings preferably contain 5, 6 or 7 ring members. Examples of monocyclic and bicyclic heterocyclic systems from which radicals occurring in the com pounds of formula ( 1 ) or (2) may be derived are, for example, pyrrol, furan, thiophene, imida zole, pyrazole, 1,2,3-triazole, 1,2,4-triazole, pyridine, pyridazine, pyrimidine, pyrazine, pyran, thiopyran, 1,4-dioxane, 1,2-oxazine, 1,3-oxazine, 1,4-oxazine, indole, benzothiophene, ben- zofuran, pyrrolidine, piperidine, piperazine, morpholine and thiomorpholine. Preference is given to compounds of formula ( 1 ), wherein - A- Ri and R2 independently from each other are hydrogen; d-C 2oalkyl; C2-C2oalkenyl; C3- Ciocycloalkyl; C3-Ciocycloalkenyl; or R1 and R2 together with the linking nitrogen atom form a 5- or 6-membered heterocyclic ring; n-i is a number from 1 to 4 ; , R3 is a saturated or unsaturated heterocyclic radical; hydroxy-Ci-C 5alkyl; Cyclohexyl substi tuted with one or more CrC 5alkyl; R is an alkylene-, cycloalkylene- or alkenylene radical which is optionally interrupted by a carbonyl- or carboxy group; R3 is an alkantriyl radical; R3 is an alkanetetrayl radical; A is -O-; Or-N(R 5)-; and R5 is hydrogen; Ci-C 5alkyl; or hydroxy-Ci-C 5alkyl. Of preferred interest are compounds of formula (1), wherein Ri and R2 are CrC 20alkyl, preferably Ci-C 5alkyl; and most preferably ethyl. Preferably Ri and R2 in formula (1) have the same definition. If in formula ( 1 ) n-i is 1, compounds are preferred, wherein R3 is a saturated or unsaturated heterocyclic radical, most preferably a saturated hetero- cyclic radical. Among these compounds are those preferred, wherein R3 is a monocyclic radical of 5 , 6 or 7 ring members with one or more heteroatoms, prefera bly wherein R3 is morphonlinyl; piperazinyl; piperidyl; pyrazolidinyl; imadazolidinyl; or pyrrolidinyl. When n-i is 1 further compounds of formula (1) are of interest wherein R3 is an unsaturated heterocyclic radical, preferably a polycyclic radical. Most preferred are compounds of formula (1), wherein R3 is a radical of formula (1a) | —j-R5 , and R5 is polycyclic heteroaromatic radical with one or 2 heteroatoms. Of preferred interest are compounds of formula ( 1), wherein R3 is a radical of formula (1b) <f — J j H-R 6 , wherein R6 is hydrogen; or d-C 5alkyl. R3 is preferably a d-C^alkylene radical, most preferably a C2-C8alkylene radical.
Load more

Recommended publications
  • How Safe Are Children's Shampoos?
    Available online at www.medicinescience.org Medicine Science ORIGINAL ARTICLE International Medical Journal Medicine Science 2021;10(2):334-7 How safe are children's shampoos? Habip Almis1, Ibrahim Hakan Bucak2, Huseyin Tanriverdi2 1Adiyaman University, School of Medicine, Department of Pediatrics, Division of Social Pediatrics, Adiyaman, Turkey 2Adiyaman University, School of Medicine, Department of Pediatrics, Adiyaman, Turkey Received 30 October 2020; Accepted 19 January 2020 Available online 19.03.2021 with doi: 10.5455/medscience.2020.10.231 Copyright@Author(s) - Available online at www.medicinescience.org Content of this journal is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License. Abstract Shampoos are daily care products designed to clean the hair and scalp. The aim of this study was to compare the contents of baby and newborn shampoos sold in supermar- kets and pharmacies, determine the levels of substances reported to be dangerous to babies and newborns’ health in these shampoos. This cross-sectional study included 18 newborn and baby shampoos that families could buy at supermarkets and pharmacies in Turkey. For newborn and baby shampoos, the number of preservative substances have been determined. A total of 68 chemicals was found in these 18 shampoos, with an average of 14.83 ± 2.43 chemicals in each shampoo. Most of these chemicals were not recommended for use in children. Shampoos that contain numerous chemicals and substances confirmed to be harmful or have suspicious effects should not be recommended. It is clear that more studies are needed in this under-researched area. Keywords: Child, chemical, newborn, pediatrician, shampoo Introduction Even low levels of chemicals can have negative effects on growth, and these effects are more pronounced during the early stages Hair and body cleaning and care are important routine parts of of life, especially the fetal and infancy periods [3,4].
    [Show full text]
  • (12) STANDARD PATENT (11) Application No. AU 2009243699 B2 (19) AUSTRALIAN PATENT OFFICE
    (12) STANDARD PATENT (11) Application No. AU 2009243699 B2 (19) AUSTRALIAN PATENT OFFICE (54) Title Bleaching agent having cationic acyl pyridinium derivatives, co-bleaching activators, and hydrogen peroxide (51) International Patent Classification(s) A61K8/22 (2006.01) A61K8/86 (2006.01) A61K 8/34 (2006.01) A61Q5/08 (2006.01) A61K 8/44 (2006.01) (21) Application No: 2009243699 (22) Date of Filing: 2009.02 (87) WIPONo: WO09/135700 (30) Priority Data (31) Number (32) Date (33) Country 10 2008 022 710.2 2008.05.07 DE (43) Publication Date: 2009.11.12 (44) Accepted Journal Date: 2014.01.30 (71) Applicant(s) Henkel AG & Co. KGaA (72) Inventor(s) Gross, Wibke;Nemitz, Ralph;Pauli, Kristin;Fuhr, Denise (74) Agent / Attorney Spruson & Ferguson, L 35 St Martins Tower 31 Market St, Sydney, NSW, 2000 (56) Related Art DE19745356 (12) NACH DEM VERTRAG LIBER DIE INTERNATIONALE ZUSAMMENARBEIT AUF DEM GEBIET DES PATENTWESENS (PCT) VEROFFENTLICHTE INTERNATIONALE ANMELDUNG (19) Weltorganisation fur geistiges Eigentum Internationales Biiro (10) Internationale Veroffentlichungsnummer (43) Internationales Veroffentlichungsdatum WO 2009/135700 Al 12. November 2009 (12.11.2009) PCT (51) Internationale Patentklassiflkation: (81) Bestimmungsstaaten (soweit nicht anders angegeben, fur A61K8/22 (2006.01) A61K 8/86 (2006.01) jede verfiigbare rationale Schutzrechtsart): AE, AG, AL, A61K8/34 (2006.01) A61Q 5/08 (2006.01) AM, AO, AT, AU, AZ, BA, BB, BG, BH, BR, BW, BY, A61K8/44 (2006.01) BZ, CA, CH, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (21) Internationales Aktenzeichen: PCT/EP2009/051835 HN, HR, HU, ID, IL, IN, IS, JP, KE, KG, KM, KN, KP, (22) Internationales Anmeldedatum: KR, KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, 17.
    [Show full text]
  • Supplement DEA CIR EXPERT PANEL MEETING JUNE 27-28, 2011
    Supplement DEA CIR EXPERT PANEL MEETING JUNE 27-28, 2011 International journal of Toxicology 29(Supplement 3) 15lS-161S © The Author(s) 2010 Final Report of the Amended Safety Reprints and permission: sagepub.com/journalsPermissions.nav Assessment of Sodium Laureth DOl: 10.1 177/1091581810373151 http://ijt.sagepub.com Sulfate and Related Salts of Sulfated SAGE Ethoxylated Alcohols Valerie C. Robinson’, Wilma F. Bergfeld, MD, FACP2, Donald V. Belsito, , Ronald MD2 2, Curtis A. Hill, PhD D. Klaassen, PhD2, James G. Marks Jr, 2, 2, Shank, PhD MD Ronald C. Thomas 2, J. Slaga, PhD Paul W. Snyder, DVM, 2, and F. Alan PhD Andersen, PhD3 Abstract Sodium Iaureth sulfate is a member of a group of salts of sulfated ethoxylated alcohols, the safety of which was evaluated by the Cosmetic Ingredient Review (CIR) Expert Panel for use in cosmetics. Sodium and ammonium laureth sulfate have not evoked adverse responses in any toxicological testing. Sodium laureth sulfate was demonstrated to be a dermal and ocular irritant but not a sensitizer. The Expert Panel recognized that there are data gaps regarding use and concentration of these ingredients. However, the overall information available on the types of products in which these ingredients are used and at what concentrations indicates a pattern of use. The potential to produce irritation exists with these salts of sulfated ethoxylated alcohols, but in practice they are not regularly seen to be irritating because of the formulations in which they are used. These ingredients should be used only when they can be formulated to be nonirritating. Keywords cosmetics, safety, sodium laureth sulfate, salts of sulfated ethoxylated alcohols The Cosmetic Ingredient Review (CIR) Expert Panel previ acknowledged that although these ingredients can be eye and ously evaluated the safety of sodium myreth sulfate, with the skin irritants, they can be used safely in the practices of use and data myreth sulfate and 2”1 conclusion, based on for sodium concentration reported.
    [Show full text]
  • Natural Standard for Personal Care
    NPA Standard and Certification for Personal Care Products In order to protect the consumer and best equip her to maximize her well-being, we have developed Natural Products Association Standard and Certification for Personal Care Products. It is a set of guidelines that dictates whether a product can be deemed truly “natural.” It encompasses all cosmetic personal care products regulated and defined by the FDA. All products that are labeled or branded “Natural” must: – Be made with at least 95% natural ingredients – excluding water – Contain only synthetic ingredients specifically allowed under this standard and environmentally-friendly products that are nurturing to us and as harmless as possible to the earth (see Appendix I) What is “Natural”: – Ingredients that come or are made from a renewable resource found in nature (Flora, Fauna, Mineral), with absolutely no petroleum compounds. (See Appendix IV for allowed processes) A synthetic non-natural ingredient can be used: – Only when there is not a readily available natural alternative ingredient (See Appendix II for a list of allowed synthetics) – Only when there are no suspected human health risks as indicated by peer- reviewed third-party scientific literature Ingredients that are prohibited: – Ingredients that have suspected human health risks as indicated by peer- reviewed third-party scientific literature – Ingredients that incorporate synthetic silicone or petroleum compounds – The following is an illustrative list of ingredient classes that are prohibited (see Appendix III for a longer list of prohibited ingredients): . Parabens — Synthetic preservatives that are potential endocrine disrupters (1-8) . Sodium Lauryl Sulfate — Harsh cleansing agent that can potentially damage the lipid layer of your skin and cause irritation (9-12) .
    [Show full text]
  • DTR06 Standard for Environmental Friendly Cosmetics Ed01 Fabian
    document Techincal Istituto per la Certificazione Reference Standard Etica e Ambientale DTR.06 Ed 01 Rev.00 Title: TECHNICAL REFERENCE STANDARD FOR THE CERTIFICATION OF “ENVIRONMENTAL FRIENDLY COSMETICS ” INDEX 1. INTRODUCTION…………………………………………………………………………………………2 2. GOALS……………………………………………………………………………….……........................2 3.CONCEPTS......................................................................................................................................3 4. APPLICATION FIELD………………………………………………………………….………………...3 5. STANDARD REFERENCES……………………………………………………………………………3 6. RAW MATERIAL……………………………………………………………………….…………………4 6.1 SUBSTANCES……………………………………………………………………………………………………4 6.2 RAW MATERIAL OF PLANT ORIGIN…………………………………………………………………………..4 6.3 RAW MATERIAL OF ANIMAL ORIGIN………………………………………………………………………...4 6.4 INORGANIC RAW MATERIAL………………………………………………………………………………….5 6.5 CHEMICAL RAW MATERIAL…………………………………………………………………………………...5 6.6 GMO…………………………………………………………………………………………...............................5 6.7 IRRADIATION…………………………………………………………………………………………………….5 7. PACKAGING……………………………………………………………………….………………………5 8. LABELLING……………………………………………………………………..…………...……………..6 9. MARK………………………………………………………………………………………….……………6 10. ENCLOSURES……………………………………………………………………………….………….6 ANN.1- LIST OF THE SUBSTANCES NOT ALLOWED IN ORDER TO OBTAIN ICEA’S CERTIFICATION ON ICEA ENVIRONMENT-FRIENDLY COSMETICS STANDARD……………………………………7 ANN. 2 – PACKAGING NOT ALLOWED MATERIAL………………………………………………….211 Written Check Check Approval Type of Date Page(s) Ed. Rev. RCV RAQ CNC CDA
    [Show full text]
  • Properties of Sodium Laureth Sulfate
    Properties Of Sodium Laureth Sulfate Frank suntans thinkingly? Elvin remains folded after Kirby plebeianises spontaneously or achieve any protein. Bradley remains bridgeless after Kristos jellify anticlockwise or brings any disinterments. Sodium Lauryl Sulfate Exemption From the Federal Register. SDS can be converted by ethoxylation to sodium laureth sulfate also called sodium lauryl ether sulfate SLES which is judicial harsh on gender skin. Should cause toxicity of raw material, her local exhaust or. Sodium Laureth Sulfate SLES is at liquid surfactant used in high foaming cleaners Foam stability in the presence of bicycle is much improved over other anionics. This section identifies changes in? Sodium dodecyl sulfate wikidoc. As preservatives for how strong antibacterial and antifungal properties. For safety of coatings of adsorption equilibrium more. There dangers of delfen contraceptive properties. Chemical of one month Sodium Laureth Sulfate & Sodium. Pour soap were found safe and tailoring the properties of sodium laureth sulfate. The lathering solid surface aggregate phase after feel free energy for discontinuous, such circumstances of. Crystal SLES & SLS Free Stephenson. Sls is easier to its previously established a paralegal certification as described. What elements are in sodium laureth sulfate? The safety data on this site constitutes a potential health impacts caused by modifying characteristics, are particularly with hot water. She was used as a unique properties, whereas an article written by our skin? Primary foam cleaning and spirit good tolerance and emulsifying properties. In most body care products: may be blended with sls, is designed for? Registration is included in skin irritation properties of sodium laureth sulphate. Sodium Lauryl Sulfate ChemicalSafetyFactsorg.
    [Show full text]
  • INDUSTRIAL SURFACTANTS Second Edition
    INDUSTRIAL SURFACTANTS Second Edition by Ernest W. Flick NOYES PUBLICATIONS Park Ridge, New Jersey, U.S.A. Copyright 0 1993 by Ernest W. Flick No part of this book may be reproduced 01 utilized in any form or by any means, electronic 01 mechanical, including photocopying, recording 01 by any infoma- tion storage and retrieval system, without permission in writing from the Publisher. Library of Congress Catalog Card Number 93-11138 ISBN 0-8155-1332-1 Printed in the United States Published in the United States of America by Noyes Publications Mill Road, Park Ridge, New Jersey 07656 10 9 8 7 6 5 4 3 2 1 Library of Congress Cataloging-in-Publication Data Flick, Ernest W. Industrial surfactants / Ernest W. Flick. -- 2nd ed. p. an. Includes index. ISBN 0-8155-1332-1 1. Surface active agents. I. Title. Tp994.F58 1993 668’.1--dc20 93-11138 m To Raymonde and Charles Amsellem and Alain Amsellem (1948 - 1983) and Patricia, Joël, Alexia and Audrey Horny Preface The Second edition of this useful book describes almost 2900 surfactants which are currently available for industrial use. The book will be of value to technical and managerial personnel involved in the specification and use of these products. It has been compiled directly from information received from 46 surfactant suppliers. Industrial surfactants find uses in almost every industry, from asphalt manufacturing to carpet fibers, from pulp and paper production to leather processing. Examples of the types of chemicals used as surfactants are fatty alcohol sulfates, akanolamides, akoxylates, sulfosuccinates, amines, quaternaries, phosphate esters, acid esters, block copolymers, betaines, imidazolines, alkyl sulfonates, etc.
    [Show full text]
  • (12) United States Patent (10) Patent No.: US 7,851,423 B2 Ruppert Et Al
    US007851423B2 (12) United States Patent (10) Patent No.: US 7,851,423 B2 Ruppert et al. (45) Date of Patent: Dec. 14, 2010 (54) POST-FOAMING CLEANSING PRODUCT (58) Field of Classification Search ................. 510/120, WITH MOLECULAR OXYGEN 510/135, 140, 155, 158,475,505; 424/401, 424/70.11, 70.21, 70.22, 70.31 (75) Inventors: Stephan Ruppert, Hamburg (DE); See application file for complete search history. Thomas Blatt, Wedel (DE); (56) References Cited Christopher Mummert, Bienenbiettel (DE); Ludger Kolbe, Dohren (DE); U.S. PATENT DOCUMENTS Anja Aechtner, Mannheim (DE) 4.405489 A 9, 1983 Sisbarro 4,772,427 A 9, 1988 Dawson et al. (73) Assignee: Beiersdorf AG, Hamburg (DE) 2004/0022839 A1 2/2004 Barnikol 2004/0241105 A1 12/2004 Riedel et al. (*) Notice: Subject to any disclaimer, the term of this 2005/OO74471 A1 4/2005 Bleckmann et al. patent is extended or adjusted under 35 2007/0031348 A1 2/2007 Staeb et al. ................... 424/47 U.S.C. 154(b) by 0 days. FOREIGN PATENT DOCUMENTS (21) Appl. No.: 12/373,980 DE 101 13 048 A1 9, 2002 WO O2/O5754 A2 1, 2002 (22) PCT Filed: Jun. 25, 2007 WO 03/022238 A1 3, 2003 WO 2005/027869 A1 3, 2005 (86). PCT No.: PCT/EP2007/056314 WO WO 2005/027869 * 3/2005 OTHER PUBLICATIONS S371 (c)(1), (2), (4) Date: Apr. 8, 2009 Stanzl K. et al., “The effectiveness of molecular oxygen in cosmetic formulations'. International Journal of Cosmetic Science, 18, pp. (87) PCT Pub. No.: WO2008/009539 137-150 (1996).
    [Show full text]
  • (12) United States Patent (10) Patent No.: US 6,858,216 B2 Schulze Zur Wiesche Et Al
    USOO6858216B2 (12) United States Patent (10) Patent No.: US 6,858,216 B2 Schulze Zur Wiesche et al. (45) Date of Patent: Feb. 22, 2005 (54) COSMETICAGENT CONTAINING DE 44 13 686 C2 10/1996 2-FURANONE DERVATIVES DE 19738 866 A1 3/1999 DE 19756 454 C1 6/1999 (75) Inventors: Erik Schulze zur Wiesche, Hamburg EP O O47 714 B1 10/1985 (DE); Detlef Hollenberg, Erkrath (DE); E. s 2. g A2 3. Britta Bossmann, Erkrath (DE) EP O 283 817 B1 12/1990 (73) ASSignee: Henkel Kommanditgesellschaft auf E. s R is: Aktien, Duesseldorf (DE) EP O 561 999 B1 1/1996 EP O 612 759 B1 10/1996 (*) Notice: Subject to any disclaimer, the term of this EP O 740 741 B2 11/1996 patent is extended or adjusted under 35 GB 2104 O91 A 3/1983 U.S.C. 154(b) by 0 days. GB 2 235 451 A 3/1991 JP 04-091084 3/1992 JP O7-1261.48 5/1995 (21) Appl. No.: 10/289,061 JP O7-242526 9/1995 (22) Filed: Nov. 6, 2002 JP 08-026942 1/1996 JP 11-292753 10/1999 (65) Prior Publication Data WO WO 92/13829 A1 8/1992 WO WO 94/0897O A1 4/1994 US 2003/0206933 A1 Nov. 6, 2003 OTHER PUBLICATIONS Related U.S. Application Data Database accession No. 131:303228 CA XP002185854 (JP (63) Continuation of application No. PCT/EP01/04822, filed on 11292753 Oct. 26, 1999). Apr. 28, 2001. Database accession No. 124:269960 CA XP002185855 (JP (30) Foreign Application Priority Data 08 026942 Jan.
    [Show full text]
  • Natural Certification Standard – Home Care Products
    Natural Products Association Standard and Certification for Natural Home Care Products In order to protect the consumer and best equip the consumer and to maximize the consumer’s well- being, we have developed Natural Products Association Standard and Certification for Home Care Products. It is a set of guidelines that will dictate whether a product can be deemed truly “natural.” It encompasses select home care products including but not limited to laundry, dish, concentrated and ready-to-use hard surface cleaners, and wipes. The following is the standard as of April 1, 2017: • All products that are labeled or branded “Natural” must: – Be made with at least 95% all natural ingredients (not counting water) with the remainder of ingredients limited to “allowed synthetics” (see Appendix II) • What is “Natural”? – Ingredients that come or are made from a renewable resource found in nature (Flora, Fauna, Mineral), with absolutely no petroleum compounds. These natural ingredients are made with the following illustrative list of allowed processes: Amination of Alcohols and Fatty Acids Reagents: Ammonia, Alkyl Amine Catalysts: Nickel, Palladium, various known other reducing agents Agricultural Inputs: Alcohols, Acids, Aldehydes, Ketones Description: The process of introducing an amine into an alcohol or fatty acid. Distillation of Essential Oils Reagents: Water (high-pressure steam) NHC Natural Standard 040517 Page 1 of 12 Natural Products Association · 440 1st Street NW, Ste. 520, Washington, DC 20009 · ph: (202) 223-0101 · fax: (202) 223-0250 [email protected] · www.NPAinfo.org Catalysts: None Agricultural Inputs: plant material (flowers, herbs, spices, etc.) Description: The physical process to acquire essential oils from plant material.
    [Show full text]
  • Disciplinare Per I Cosmetici Eco Bio Cosmesi
    B.C.I NA.0201 DISCIPLINARE PER I COSMETICI ECO BIO Ed. 01 Rev.01 COSMESI GENNAIO 2019 ALLEGATO 1 - LISTA DELLE SOSTANZE VIETATE NOME INCI NOME CHIMICO / IUPAC n° CAS FUNZIONE 1,2,3,4-TETRAHYDRO-6- NITROQUINOXALINE Quinoxaline, 1,2,3,4-tetrahydro-6-nitro- additivi 1,2,4-BENZENETRIACETAT E Benzene-1,2,4-triyl triacetate. 613-03-6 coloranti per capelli 1,2,4-TRIHYDROXYBENZENE Benzene-1,2,4-triol. 533-73-3 coloranti per capelli 4,4'-[1,3-propanediylbis(oxy)]bisbenzene-1,3- 1,3-BIS-(2,4-DIAMINOPHENOXY)PROPANE diamine. 81892-72-0 coloranti per capelli 1,5-NAPHTHALENEDIOL Naphthalene-1,5-diol (CI 76625). 83-56-7 coloranti per capelli 1-ACETOXY-2-METHYLNAPHTHALENE 1-Naphthalenol, 2-methyl-, acetate 1386868 coloranti per capelli 1-NAPHTHOL 1-naphthol (CI 76605). 90-15-3 coloranti per capelli 2- HEPTYLCYCLOPENT ANONE 2-heptylcyclopentanone. 137-03-1 solventi 2- METHYLRESORCINOL 1,3-Benzenediol, 2-methyl- 608-25-3 coloranti per capelli 2,2'-THIOBIS(4-CHLOROPHENOL) Phenol, 2,2'-thiobis[4-chloro- 97-24-5 antimicrobici 2,3-NAPHTHALENEDIOL Naphthalene-2,3-diol. 92-44-4 coloranti per capelli 113715-25- 2,4-DIAMINO-5-METHYLPHENETOL HCl 1,3-benzenediamine, 4-ethoxy-6-methyl- 6 coloranti per capelli 2,4-DIAMINO-5-METHYLPHENOXYET Ethanol, 2-(2,4-diamino-5-methylphenoxy)-, 113715-27- HANOL HCl dihydrochloride 8 coloranti per capelli 2,4-DIAMINODIPHENYLA MINE 1,2,4-benzenetriamine, N-phenyl- 136-17-4 coloranti per capelli 2,4-DIAMINOPHENOL 2,4-diaminophenol. 95-86-3 coloranti per capelli 2,4-DIAMINOPHENOL DIHYDROCHLORIDE 2,4-Diaminophenol dihydrochloride 137-09-7 coloranti per capelli 2,4-DIAMINOPHENOL HCl 4-hydroxy-m-phenylenediammonium dichloride.
    [Show full text]
  • Whole Foods Market
    INTRODUCING PREMIUM BODY CARE oor WFM Body Care Quality Standards Already the HIGHEST IN THE INDUSTRY. We CAREFULLY EVALUATE each and every product we sell. All personal care products must meet our CURRENT BODY CARE QS LIST. With the growing interest in natural personal care, WE DECIDED TO SET THE BAR HIGHER. The Result: PREMIUM BODY CARE, a top tier standard that recognizes the highest quality personal care products we sell Premium Body Care: The Process We worked MORE THAN 3 YEARS with the most recent scientific data and research to examine EACH AND EVERY BODY CARE INGREDIENT ON OUR SHELVES in four areas: Results Source Environmental Impact Safety PREMIUM BODY CARE GOES BEYOND NATURAL! Over Unacceptable Ingredients Including 300 ACETAMIDE MEA CARBOMER ISOPROPYL MYRISTATE PABA SODIUM LAURETH SULFATE ACRYLATES COPOLYMER CETEARETH 2 – 100 KOJIC ACID PARABENS SODIUM LAURYL SULFATE ALKYL BENZOATE CETRIMONIUM BROMIDE LAURAMIDE MEA PENTYLENE GLYCOL SODIUM MYRETH SULFATE ALPHA HYDROXY ACIDS CETRIMONIUM CHLORIDE LAURETH-7 PETROLATUM SODIUM POLYACRYLATE ALUMINUM HYDROXIDE CHLORPHENESIN LAURETHSULFOSUCCINATE PHTHALATE SOYAMIDE DEA ALUMINUM OXIDE COCAMIDE DEA METHOXYCINNAMATE POLAXAMER 335 STEARDIMONIUM CHLORIDE ALUMINUM POWDER COCAMIDE MEA METHYL GLYCETH-20 POLYACRYLAMIDE SYNTHETIC FRAGRANCE AMMONIUM LAURETH SULFATE COCAMIDE MIPA METHYL GLYCOL POLYBUTENE TALC AMMONIUM LAURYL SULFATE CYCLOMETHICONE METHYL PROPANEDIOL POLYETHYLENE GLYCOL (PEG) TEA-LAURYL SULFATE AMMONIUM POLACRYLATE CYCLOPENTASILOXANE METHYLPARABEN POLYISOBUTENE TETRASODIUM EDTA ARTIFICIAL
    [Show full text]