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LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, and COBALT ARSENIDE and SULFIDE ORE FORMATION Nicholas Allin
Montana Tech Library Digital Commons @ Montana Tech Graduate Theses & Non-Theses Student Scholarship Spring 2019 EXPERIMENTAL INVESTIGATION OF THE THERMOCHEMICAL REDUCTION OF ARSENITE AND SULFATE: LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, AND COBALT ARSENIDE AND SULFIDE ORE FORMATION Nicholas Allin Follow this and additional works at: https://digitalcommons.mtech.edu/grad_rsch Part of the Geotechnical Engineering Commons EXPERIMENTAL INVESTIGATION OF THE THERMOCHEMICAL REDUCTION OF ARSENITE AND SULFATE: LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, AND COBALT ARSENIDE AND SULFIDE ORE FORMATION by Nicholas C. Allin A thesis submitted in partial fulfillment of the requirements for the degree of Masters in Geoscience: Geology Option Montana Technological University 2019 ii Abstract Experiments were conducted to determine the relative rates of reduction of aqueous sulfate and aqueous arsenite (As(OH)3,aq) using foils of copper, nickel, or cobalt as the reductant, at temperatures of 150ºC to 300ºC. At the highest temperature of 300°C, very limited sulfate reduction was observed with cobalt foil, but sulfate was reduced to sulfide by copper foil (precipitation of Cu2S (chalcocite)) and partly reduced by nickel foil (precipitation of NiS2 (vaesite) + NiSO4·xH2O). In the 300ºC arsenite reduction experiments, Cu3As (domeykite), Ni5As2, or CoAs (langisite) formed. In experiments where both sulfate and arsenite were present, some produced minerals were sulfarsenides, which contained both sulfide and arsenide, i.e. cobaltite (CoAsS). These experiments also produced large (~10 µm along longest axis) euhedral crystals of metal-sulfide that were either imbedded or grown upon a matrix of fine-grained metal-arsenides, or, in the case of cobalt, metal-sulfarsenide. Some experimental results did not show clear mineral formation, but instead demonstrated metal-arsenic alloying at the foil edges. -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Synthesis, Properties and Uses of Chromium-Based Pigments from The
Synthesis, properties and uses of chromium-based pigments from the Manufacture de Sèvres Louisiane Verger, Olivier Dargaud, Mathieu Chassé, Nicolas Trcera, Gwenaëlle Rousse, Laurent Cormier To cite this version: Louisiane Verger, Olivier Dargaud, Mathieu Chassé, Nicolas Trcera, Gwenaëlle Rousse, et al.. Syn- thesis, properties and uses of chromium-based pigments from the Manufacture de Sèvres. Journal of Cultural Heritage, Elsevier, 2018, 30, pp.26 - 33. 10.1016/j.culher.2017.09.012. hal-01777923 HAL Id: hal-01777923 https://hal.sorbonne-universite.fr/hal-01777923 Submitted on 25 Apr 2018 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Synthesis, Properties and Uses of Chromium-Based Pigments from the Manufacture de Sèvres Louisiane Verger1,2, Olivier Dargaud2, Mathieu Chassé1, Nicolas Trcera3, Gwenaëlle Rousse4,5, Laurent Cormier1 1. Institut de minéralogie, de physique des matériaux et de cosmochimie (IMPMC), Sorbonne Universités, UPMC Univ Paris 06, CNRS UMR 7590, Muséum national d'Histoire naturelle, IRD UMR 206, 4 place Jussieu, F-75005 Paris, France 2. Cité de la céramique - Sèvres et Limoges, 2 Place de la Manufacture, 92310 Sèvres, France 3. Synchrotron Soleil, 91190 Saint-Aubin 4 .Collège de France, Chimie du Solide et de l’Energie, UMR 8260, 11 place Marcelin Berthelot, 75231 Paris Cedex 05, France. -
Liroconite Cu2al(Aso4)(OH)4 • 4H2O C 2001-2005 Mineral Data Publishing, Version 1
Liroconite Cu2Al(AsO4)(OH)4 • 4H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Typically as crystals with a flattened octahedral or lenticular aspect, dominated by {110} and {011} and striated parallel to their intersections, also {001}, {010}, {100}, to 3.6 cm, alone and in sub-parallel groups. May be granular, massive. Physical Properties: Cleavage: On {110}, {011}, indistinct. Fracture: Uneven to conchoidal. Hardness = 2–2.5 D(meas.) = 2.94–3.01 D(calc.) = [3.03] Optical Properties: Transparent to translucent. Color: Sky-blue, bluish green, verdigris-green, emerald-green; pale blue to pale bluish green in transmitted light. Streak: Pale blue to pale green. Luster: Vitreous to resinous. Optical Class: Biaxial (–). Orientation: Y = b; Z ∧ a =25◦. Dispersion: r< v,moderate. α = 1.612(3) β = 1.652(3) γ = 1.675(3) 2V(meas.) = n.d. 2V(calc.) = 72(5)◦ Cell Data: Space Group: I2/a. a = 12.664(2) b = 7.563(2) c = 9.914(3) β =91.32(2)◦ Z=4 X-ray Powder Pattern: Cornwall, England. 6.46 (10), 3.01 (10), 5.95 (9), 2.69 (6), 3.92 (5), 2.79 (5), 2.21 (5) Chemistry: (1) (2) P2O5 3.73 As2O5 23.05 26.54 Al2O3 10.85 11.77 Fe2O3 0.98 CuO 36.38 36.73 H2O 25.01 24.96 Total 100.00 100.00 • (1) Cornwall, England. (2) Cu2Al(AsO4)(OH)4 4H2O. Occurrence: A rare secondary mineral in the oxidized zone of some copper deposits. Association: Olivenite, chalcophyllite, clinoclase, cornwallite, strashimirite, malachite, cuprite, “limonite”. -
Nickeline Nias C 2001-2005 Mineral Data Publishing, Version 1
Nickeline NiAs c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Hexagonal. Point Group: 6/m 2/m 2/m. Commonly in granular aggregates, reniform masses with radial structure, and reticulated and arborescent growths. Rarely as distorted, horizontally striated, {1011} terminated crystals, to 1.5 cm. Twinning: On {1011} producing fourlings; possibly on {3141}. Physical Properties: Fracture: Conchoidal. Tenacity: Brittle. Hardness = 5–5.5 VHN = n.d. D(meas.) = 7.784 D(calc.) = 7.834 Optical Properties: Opaque. Color: Pale copper-red, tarnishes gray to blackish; white with strong yellowish pink hue in reflected light. Streak: Pale brownish black. Luster: Metallic. Pleochroism: Strong; whitish, yellow-pink to pale brownish pink. Anisotropism: Very strong, pale greenish yellow to slate-gray in air. R1–R2: (400) 39.2–45.4, (420) 38.0–44.2, (440) 36.8–43.5, (460) 36.2–43.2, (480) 37.2–44.3, (500) 39.6–46.4, (520) 42.3–48.6, (540) 45.3–50.7, (560) 48.2–52.8, (580) 51.0–54.8, (600) 53.7–56.7, (620) 55.9–58.4, (640) 57.8–59.9, (660) 59.4–61.3, (680) 61.0–62.5, (700) 62.2–63.6 Cell Data: Space Group: P 63/mmc. a = 3.621(1) c = 5.042(1) Z = 2 X-ray Powder Pattern: Unknown locality. 2.66 (100), 1.961 (90), 1.811 (80), 1.071 (40), 1.328 (30), 1.033 (30), 0.821 (30) Chemistry: (1) (2) Ni 43.2 43.93 Co 0.4 Fe 0.2 As 55.9 56.07 Sb 0.1 S 0.1 Total 99.9 100.00 (1) J´achymov, Czech Republic; by electron microprobe, corresponds to (Ni0.98Co0.01 Fe0.01)Σ=1.00As1.00. -
Nickel and Nickel Compounds Were Considered by Previous !AC Working Groups, in 1972, 1975, 1979, 1982 and 1987 (IARC, 1973, 1976, 1979, 1982, 1987)
NICKEL AND NieKEL eOMPOUNDS Nickel and nickel compounds were considered by previous !AC Working Groups, in 1972, 1975, 1979, 1982 and 1987 (IARC, 1973, 1976, 1979, 1982, 1987). Since that time, new data have become available, and these are inc1uded in the pres- ent monograph and have been taken into consideration in the evaluation. 1. ehemical and Physical Data The list of nickel alloys and compounds given in Table 1 is not exhaustive, nor does it necessarily reflect the commercial importance of the various nickel-con tain- ing substances, but it is indicative of the range of nickel alloys and compounds avail- able, including some compounds that are important commercially and those that have been tested in biological systems. A number of intermediary compounds occur in refineries which cannot be characterized and are not listed. 1.1 Synonyms, trade names and molecular formulae of nickel and selected nickel-containing compounds Table 1. Synonyms (Chemical Abstracts Service names are given in bold), trade names and atomic or molecular formulae or compositions of nickel, nickel alloys and selected nickel compounds Chemical Chem. Abstr. SYDoDyms and trade Dames Formula Dame Seiv. Reg. Oxda- Numbera tion stateb Metallc nickel and nickel alloys Nickel 7440-02-0 c.I. 77775; NI; Ni 233; Ni 270; Nickel 270; Ni o (8049-31-8; Nickel element; NP 2 17375-04-1; 39303-46-3; 53527-81-4; 112084-17-0) -- 257 - NICKEL AND NICKEL COMPOUNDS 259 Table i (contd) Chemical Chem. Abstr. Synonym and trade names Formula name Seiv. Reg. Ox- Number4 dation stateb -
Joteite, Ca2cual[Aso4][Aso3(OH)]2(OH)2·5H2O, a New Arsenate with a Sheet Structure and Unconnected Acid Arsenate Groups
Mineralogical Magazine, August 2013, Vol. 77(6), pp. 2811–2823 Joteite, Ca2CuAl[AsO4][AsO3(OH)]2(OH)2·5H2O, a new arsenate with a sheet structure and unconnected acid arsenate groups 1, 2 3 3 4 5 6 A. R. KAMPF *, S. J. MILLS ,R.M.HOUSLEY ,G.R.ROSSMAN ,B.P.NASH ,M.DINI AND R. A. JENKINS 1 Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA 2 Geosciences, Museum Victoria, GPO Box 666, Melbourne 3001, Australia 3 Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125, USA 4 Department of Geology and Geophysics, University of Utah, Salt Lake City, UT 84112, USA 5 Pasaje San Agustin 4045, La Serena, Chile 6 4521 N Via Madre, Tucson, AZ 85749, USA [Received 18 Mary 2013; Accepted 11 July 2013; Associate Editor: F. Ca´mara] ABSTRACT Joteite (IMA2012-091), Ca2CuAl[AsO4][AsO3(OH)]2(OH)2·5H2O, is a new mineral from the Jote mine, Tierra Amarilla, Copiapo´ Province, Atacama, Chile. The mineral is a late-stage, low- temperature, secondary mineral occurring with conichalcite, mansfieldite, pharmacoalumite, pharmacosiderite and scorodite in narrow seams and vughs in the oxidized upper portion of a hydrothermal sulfide vein hosted by volcanoclastic rocks. Crystals occur as sky-blue to greenish-blue thin blades, flattened and twinned on {001}, up to ~300 mm in length, and exhibiting the forms {001}, {010}, {11¯0}, {21¯0} and {111}. The blades are commonly intergrown in wheat-sheaf-like bundles, less commonly in sprays, and sometimes aggregated as dense crusts and cavity linings. -
B Clifford Frondel
CATALOGUE OF. MINERAL PSEUDOMORPHS IN THE AMERICAN MUSEUM -B CLIFFORD FRONDEL BU.LLETIN OF THEAMRICANMUSEUM' OF NA.TURAL HISTORY. VOLUME LXVII, 1935- -ARTIC-LE IX- NEW YORK Tebruary 26, 1935 4 2 <~~~~~~~~~~~~~7 - A~~~~~~~~~~~~~~~, 4~~~~~~~~~~~~~~~~~~~~~~~~~~~~~4 4 4 A .~~~~~~~~~~~~~~~~~~~~~~~~~~4- -> " -~~~~~~~~~4~~. v-~~~~~~~~~~~~~~~~~~t V-~ ~~~~~~~~~~~~~~~~ 'W. - /7~~~~~~~~~~~~~~~~~~~~~~~~~~7 7-r ~~~~~~~~~-A~~~~ ~ ~ ~ ~ ~ ~ ~ ~ ~ -'c~ ~ ~ ' -7L~ ~ ~ ~ ~ 7 54.9:07 (74.71) Article IX.-CATALOGUE OF MINERAL PSEUDOMORPHS IN THE AMERICAN MUSEUM OF NATURAL HISTORY' BY CLIFFORD FRONDEL CONTENTS PAGE INTRODUCTION .................. 389 Definition.389 Literature.390 New Pseudomorphse .393 METHOD OF DESCRIPTION.393 ORIGIN OF SUBSTITUTION AND INCRUSTATION PSEUDOMORPHS.396 Colloidal Origin: Adsorption and Peptization.396 Conditions Controlling Peptization.401 Volume Relations.403 DESCRIPTION OF SPECIMENS.403 INTRODUCTION DEFINITION.-A pseudomorph is defined as a mineral which has the outward form proper to another species of mineral whose place it has taken through the action of some agency.2 This precise use of the term excludes the regular cavities left by the removal of a crystal from its matrix (molds), since these are voids and not solids,3 and would also exclude those cases in which organic material has been replaced by quartz or some other mineral because the original substance is here not a mineral. The general usage of the term is to include as pseudomorphs both petrifactions and molds, and also: (1) Any mineral change in which the outlines of the original mineral are preserved, whether this surface be a euhedral crystal form or the irregular bounding surface of an embedded grain or of an aggregate. (2) Any mineral change which has been accomplished without change of volume, as evidenced by the undistorted preservation of an original texture or structure, whether this be the equal volume replacement of a single crystal or of a rock mass on a geologic scale. -
Journal of the Russell Society, Vol 4 No 2
JOURNAL OF THE RUSSELL SOCIETY The journal of British Isles topographical mineralogy EDITOR: George Ryba.:k. 42 Bell Road. Sitlingbourn.:. Kent ME 10 4EB. L.K. JOURNAL MANAGER: Rex Cook. '13 Halifax Road . Nelson, Lancashire BB9 OEQ , U.K. EDITORrAL BOARD: F.B. Atkins. Oxford, U. K. R.J. King, Tewkesbury. U.K. R.E. Bevins. Cardiff, U. K. A. Livingstone, Edinburgh, U.K. R.S.W. Brai thwaite. Manchester. U.K. I.R. Plimer, Parkvill.:. Australia T.F. Bridges. Ovington. U.K. R.E. Starkey, Brom,grove, U.K S.c. Chamberlain. Syracuse. U. S.A. R.F. Symes. London, U.K. N.J. Forley. Keyworth. U.K. P.A. Williams. Kingswood. Australia R.A. Howie. Matlock. U.K. B. Young. Newcastle, U.K. Aims and Scope: The lournal publishes articles and reviews by both amateur and profe,sional mineralogists dealing with all a,pecI, of mineralogy. Contributions concerning the topographical mineralogy of the British Isles arc particularly welcome. Not~s for contributors can be found at the back of the Journal. Subscription rates: The Journal is free to members of the Russell Society. Subsc ription rates for two issues tiS. Enquiries should be made to the Journal Manager at the above address. Back copies of the Journal may also be ordered through the Journal Ma nager. Advertising: Details of advertising rates may be obtained from the Journal Manager. Published by The Russell Society. Registered charity No. 803308. Copyright The Russell Society 1993 . ISSN 0263 7839 FRONT COVER: Strontianite, Strontian mines, Highland Region, Scotland. 100 mm x 55 mm. -
Zeunerite Cu(UO2)2(Aso4)2·12H2O
Zeunerite Cu(UO2)2(AsO4)2·12H2O Crystal Data: Tetragonal. Point Group: 4/m 2/m 2/m. Crystals, to 4 cm, flat tabular on {001}, commonly in subparallel growths. Physical Properties: Cleavage: On {001}, perfect; on {100}, distinct. Hardness = 2.5 D(meas.) = 3.47 D(calc.) = 3.391 for 16H2O. Radioactive; commonly dehydrates to metazeunerite. Optical Properties: Transparent, becoming translucent on dehydration. Color: Green to emerald-green. Luster: Vitreous. Optical Class: Uniaxial (–). ω = 1.610-1.613 ε = 1.582-1.585 Pleochroism: O = blue-green; E = pale blue-green. Cell Data: Space Group: P4/nnc. a = 7.1797(3) c = 20.857(1) Z = 2 X-ray Powder Pattern: Synthetic Cu(UO2)2(AsO4)2∙16H2O. 10.65 (10), 3.59 (9), 5.04 (8), 3.39 (7), 1.926 (6), 6.86 (5), 2.08 (5) Chemistry: (1) Identification rests on comparison of the X-ray powder pattern and optical data with those of synthetic Cu(UO2)2(AsO4)2∙16H2O. Mineral Group: Autunite group. Occurrence: An uncommon secondary mineral in the oxidized zone of arsenic-bearing hydrothermal uranium deposits. Association: Olivenite, mansfieldite, scorodite, azurite, malachite. Distribution: Material which is fully hydrated at the time of study is relatively rare, although most meta-zeunerite is a dehydration product of pre-existing zeunerite. In Germany, from the Walpurgis vein, Weisser Hirsch mine, Neustädtel-Schneeberg, Saxony; at Sailauf, northeast of Aschaffenburg, Bavaria; in the Anton mine, Heubachtal, near Schiltach, from Menzenschwand, and elsewhere in the Black Forest. In England, at a number of places in Cornwall, as at Wheals Gorland and Maid, Gwennap; in the South Terras mine, St. -
Malayaite Casnsio5 C 2001 Mineral Data Publishing, Version 1.2 ° Crystal Data: Monoclinic
Malayaite CaSnSiO5 c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Monoclinic. Point Group: 2=m: Crystals wedge-shaped, up to 3 cm; massive, as a coating on cassiterite. Physical Properties: Hardness = 3.5{4 D(meas.) = 4.3(2) D(calc.) = [4.55] Fluoresces pale to bright yellow or yellow-green under UV. Optical Properties: Translucent. Color: Very pale creamy yellow to deep yellow-orange, colorless. Luster: Resinous. Optical Class: Biaxial ({). ® = 1.764{1.765 ¯ = 1.783{1.786 ° = 1.798{1.801 2V(meas.) = 84±{86± Cell Data: Space Group: A2=a: a = 7.156(6) b = 8.895(9) c = 6.668(4) ¯ = 113:4(1)± Z = 4 X-ray Powder Pattern: Synthetic. 3.28 (100), 5.05 (50), 2.639 (45), 3.06 (35), 2.665 (30), 2.412 (20), 2.099 (20) Chemistry: (1) (2) SiO2 21.26 22.49 SnO2 58.48 56.38 FeO 0.15 CaO 19.14 20.94 LOI 0.50 Total 99.38 99.96 (1) Sungei Lah Valley, Malaya; corresponds to Ca0:95Sn1:07Si0:98O5: (2) Gumble, Australia; by electron microprobe, corresponding to Ca1:00Sn1:00Fe0:01Si1:00O5: Occurrence: In tin-rich contact metamorphic skarn deposits, probably a hydrothermal alteration product of cassiterite or other tin-bearing minerals. Association: Cassiterite, quartz, calcite, wollastonite, pyroxene, garnet. Distribution: In the Sungei Lah Valley, Chenderiang, Perak State, and other locations in Malaya, Malaysia. From Piniok, Thailand. In the Toroku and Mitate mines, Miyazaki Prefecture; the Sampo mine, Okayama Prefecture; the Hoei mine, Oita Prefecture; and the Kuga mine, Yamaguchi Prefecture, Japan. -
O, a New Mineral of the Titanite Group from the Piława Górna Pegmatite, the Góry Sowie Block, Southwestern Poland
Mineralogical Magazine, June 2017, Vol. 81(3), pp. 591–610 Żabińskiite, ideally Ca(Al0.5Ta 0.5)(SiO4)O, a new mineral of the titanite group from the Piława Górna pegmatite, the Góry Sowie Block, southwestern Poland 1,* 2 3 3 4 ADAM PIECZKA ,FRANK C. HAWTHORNE ,CHI MA ,GEORGE R. ROSSMAN ,ELIGIUSZ SZEŁĘG , 5 5 6 6 7 ADAM SZUSZKIEWICZ ,KRZYSZTOF TURNIAK ,KRZYSZTOF NEJBERT ,SŁAWOMIR S. ILNICKI ,PHILIPPE BUFFAT AND 7 BOGDAN RUTKOWSKI 1 AGH University of Science and Technology, Department of Mineralogy, Petrography and Geochemistry, 30-059 Kraków, Mickiewicza 30, Poland 2 Department of Geological Sciences, University of Manitoba, Winnipeg, Manitoba R3T 2N2, Canada 3 Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, 91125-2500, California, USA 4 University of Silesia, Faculty of Earth Sciences, Department of Geochemistry, Mineralogy and Petrography, 41-200 Sosnowiec, Bedzin̨ ská 60, Poland 5 University of Wrocław, Institute of Geological Sciences, 50-204 Wrocław, M. Borna 9, Poland 6 University of Warsaw, Faculty of Geology, Institute of Geochemistry, Mineralogy and Petrology, 02-089 Warszawa, Żwirki and Wigury 93, Poland 7 AGH University of Science and Technology, International Centre of Electron Microscopy for Materials Science, Department of Physical and Powder Metallurgy, 30-059 Kraków, Mickiewicza 30, Poland [Received 7 January 2016; Accepted 21 April 2016; Associate Editor: Ed Grew] ABSTRACT Ż ́ ł abinskiite, ideally Ca(Al0.5Ta0.5)(SiO4)O, was found in a Variscan granitic pegmatite at Pi awa Górna, Lower Silesia, SW Poland. The mineral occurs along with (Al,Ta,Nb)- and (Al,F)-bearing titanites, a pyrochlore-supergroup mineral and a K-mica in compositionally inhomogeneous aggregates, ∼120 μm× 70 μm in size, in a fractured crystal of zircon intergrown with polycrase-(Y) and euxenite-(Y).