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The Development of the Periodic Table and Its Consequences Citation: J
Firenze University Press www.fupress.com/substantia The Development of the Periodic Table and its Consequences Citation: J. Emsley (2019) The Devel- opment of the Periodic Table and its Consequences. Substantia 3(2) Suppl. 5: 15-27. doi: 10.13128/Substantia-297 John Emsley Copyright: © 2019 J. Emsley. This is Alameda Lodge, 23a Alameda Road, Ampthill, MK45 2LA, UK an open access, peer-reviewed article E-mail: [email protected] published by Firenze University Press (http://www.fupress.com/substantia) and distributed under the terms of the Abstract. Chemistry is fortunate among the sciences in having an icon that is instant- Creative Commons Attribution License, ly recognisable around the world: the periodic table. The United Nations has deemed which permits unrestricted use, distri- 2019 to be the International Year of the Periodic Table, in commemoration of the 150th bution, and reproduction in any medi- anniversary of the first paper in which it appeared. That had been written by a Russian um, provided the original author and chemist, Dmitri Mendeleev, and was published in May 1869. Since then, there have source are credited. been many versions of the table, but one format has come to be the most widely used Data Availability Statement: All rel- and is to be seen everywhere. The route to this preferred form of the table makes an evant data are within the paper and its interesting story. Supporting Information files. Keywords. Periodic table, Mendeleev, Newlands, Deming, Seaborg. Competing Interests: The Author(s) declare(s) no conflict of interest. INTRODUCTION There are hundreds of periodic tables but the one that is widely repro- duced has the approval of the International Union of Pure and Applied Chemistry (IUPAC) and is shown in Fig.1. -
Synthesis of Mollugin and (3S,4R)-Trans-3,4-Dihydroxy-3,4-Dihydromollugin
Accepted Manuscript Asymmetric epoxidation of chromenes mediated by iminium salts: Synthesis of mollugin and (3S,4R)-trans-3,4-dihydroxy-3,4-dihydromollugin Philip C. Bulman Page, Yohan Chan, Abu Hassan Noor Armylisas, Mohammed Alahmdi PII: S0040-4020(16)31129-2 DOI: 10.1016/j.tet.2016.10.070 Reference: TET 28211 To appear in: Tetrahedron Received Date: 30 July 2016 Revised Date: 22 October 2016 Accepted Date: 31 October 2016 Please cite this article as: Page PCB, Chan Y, Noor Armylisas AH, Alahmdi M, Asymmetric epoxidation of chromenes mediated by iminium salts: Synthesis of mollugin and (3S,4R)-trans-3,4-dihydroxy-3,4- dihydromollugin, Tetrahedron (2016), doi: 10.1016/j.tet.2016.10.070. This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. provided by University of East Anglia digital repository View metadata, citation and similar papers at core.ac.uk CORE brought to you by ACCEPTED MANUSCRIPT Graphical Abstract MANUSCRIPT ACCEPTED Asymmetric Epoxidation of Chromenes Mediated by Iminium Salts: Synthesis of Mollugin and (3 S,4 R)- ACCEPTED MANUSCRIPT trans -3,4-Dihydroxy-3,4-Dihydromollugin Philip C. Bulman Page, a* Yohan Chan, a Abu Hassan Noor Armylisas, b Mohammed Alahmdi c a School of Chemistry, University of East Anglia, Norwich Research Park, Norwich, Norfolk NR4 7TJ, U.K. -
High-Temperature Structural Evolution of Caesium and Rubidium Triiodoplumbates D.M
High-temperature structural evolution of caesium and rubidium triiodoplumbates D.M. Trots, S.V. Myagkota To cite this version: D.M. Trots, S.V. Myagkota. High-temperature structural evolution of caesium and rubidium tri- iodoplumbates. Journal of Physics and Chemistry of Solids, Elsevier, 2009, 69 (10), pp.2520. 10.1016/j.jpcs.2008.05.007. hal-00565442 HAL Id: hal-00565442 https://hal.archives-ouvertes.fr/hal-00565442 Submitted on 13 Feb 2011 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Author’s Accepted Manuscript High-temperature structural evolution of caesium and rubidium triiodoplumbates D.M. Trots, S.V. Myagkota PII: S0022-3697(08)00173-X DOI: doi:10.1016/j.jpcs.2008.05.007 Reference: PCS 5491 To appear in: Journal of Physics and www.elsevier.com/locate/jpcs Chemistry of Solids Received date: 31 January 2008 Revised date: 2 April 2008 Accepted date: 14 May 2008 Cite this article as: D.M. Trots and S.V. Myagkota, High-temperature structural evolution of caesium and rubidium triiodoplumbates, Journal of Physics and Chemistry of Solids, doi:10.1016/j.jpcs.2008.05.007 This is a PDF file of an unedited manuscript that has been accepted for publication. -
Improvement in Retention of Solid Fission Products in HTGR Fuel Particles by Ceramic Kernel Additives
FORMAL REPORT GERHTR-159 UNITED STATES-GERMAN HIGH TEMPERATURE REACTOR RESEARCH EXCHANGE PROGRAM Original report number ______________________ Title Improvement in Retention of Solid Fission Products in HTGR Fuel Particles by Ceramic Kernel Additives Authorial R. Forthmann, E. Groos and H. Grobmeier Originating Installation Kemforschtmgsanlage Juelich, West Germany. Date of original report issuance August 1975_______ Reporting period covered _ _____________________________ In the original English This report, translated wholly or in part from the original language, has been reproduced directly from copy pre pared by the United States Mission to the European Atomic Energy Community THIS REPORT MAY BE GIVEN UNLIMITED DISTRIBUTION ERDA Technical Information Center, Oak Ridge, Tennessee DISCLAIMER Portions of this document may be illegible in electronic image products. Images are produced from the best available original document. GERHTR-159 Distribution Category UC-77 CONTENTS page 1. INTRODUCTION 2 2. FUNDAMENTAL STUDIES 3 3. IRRADIATION EXPERIMENT FRJ2-P17 5 3.1 Results of the Fission Product 8 Release Measurements Improvement in Retention of Solid 3.2 Electron Microprobe Investigations Fission Products in HTGR Fuel Particles 8 by Ceramic Kernel Additives. 4. IRRADIATION EXPERIMENT FRJ2-P18 16 4.1 Release of Solid Fission Products 19 4.2 Electron Microprobe Studies 24 by R. Forthmann, E. Groos, H. GrObmeier 5. SUMMARY AND CONCLUSIONS 27 6. ACKNOWLEDGEMENT 28 7. REFERENCES 29 2 - X. INTRODUCTION Kernforschungs- anlage JUTich JOL - 1226 August 1975 Considerations of the core design of advanced High-Temperature Gas-cooled GmbH IRW Reactors (HTGRs) led to increased demands concerning solid fission product retention in the fuel elements. This would be desirable not only for HTGR power plants with a helium-turbine in the primary circuit (HHT project), but also for the application of HTGRs as a source of nuclear process heat. -
100011-1 Cesium (1000Μg/Ml in 1% HNO3)
100011-1 Cesium (1000μg/mL in 1% HNO3) High-Purity Standards Chemwatch Hazard Alert Code: 3 Catalogue number: 1000-11-1 Issue Date: 03/07/2017 Version No: 3.3 Print Date: 03/07/2017 Safety Data Sheet according to OSHA HazCom Standard (2012) requirements S.GHS.USA.EN SECTION 1 IDENTIFICATION Product Identifier Product name 100011-1 Cesium (1000μg/mL in 1% HNO3) Synonyms 1000μg/mL Cesium in 1% HNO3 Proper shipping name Corrosive liquid, acidic, inorganic, n.o.s. (contains nitric acid) Other means of 1000-11-1 identification Recommended use of the chemical and restrictions on use Relevant identified uses Use according to manufacturer's directions. Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party Registered company name High-Purity Standards Address PO Box 41727 SC 29423 United States Telephone 843-767-7900 Fax 843-767-7906 Website highpuritystandards.com Email Not Available Emergency phone number Association / Organisation INFOTRAC Emergency telephone 1-800-535-5053 numbers Other emergency telephone 1-352-323-3500 numbers SECTION 2 HAZARD(S) IDENTIFICATION Classification of the substance or mixture Classification Metal Corrosion Category 1, Skin Corrosion/Irritation Category 1A, Serious Eye Damage Category 1 Label elements GHS label elements SIGNAL WORD DANGER Hazard statement(s) H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. Hazard(s) not otherwise specified Not Applicable Precautionary statement(s) Prevention Continued... Chemwatch: 9-245281 Page 2 of 10 Issue Date: 03/07/2017 Catalogue number: 1000-11-1 100011-1 Cesium (1000μg/mL in 1% HNO3) Print Date: 03/07/2017 Version No: 3.3 P260 Do not breathe dust/fume/gas/mist/vapours/spray. -
Density Functional Theory Metadynamics of Silver, Caesium and Palladium Diffusion at B-Sic Grain Boundaries ⇑ Jeremy Rabone A, , Eddie López-Honorato B
Journal of Nuclear Materials 458 (2015) 56–63 Contents lists available at ScienceDirect Journal of Nuclear Materials journal homepage: www.elsevier.com/locate/jnucmat Density functional theory metadynamics of silver, caesium and palladium diffusion at b-SiC grain boundaries ⇑ Jeremy Rabone a, , Eddie López-Honorato b a European Commission, Joint Research Centre, Institute for Transuranium Elements, D-76125 Karlsruhe, Germany b Centro de Investigación y de Estudios Avanzados del IPN (CINVESTAV), Unidad Saltillo, Industria Metalúrgica 1062, Parque Industrial, Ramos Arizpe 25900, Coahuila, Mexico highlights DFT metadynamics of diffusion of Pd, Ag and Cs on grain boundaries in b-SiC. The calculated diffusion rates for Pd and Ag tally with experimental release rates. A mechanism of release other than grain boundary diffusion seems likely for Cs. article info abstract Article history: The use of silicon carbide in coated nuclear fuel particles relies on this materials impermeability towards Received 22 May 2014 fission products under normal operating conditions. Determining the underlying factors that control the Accepted 9 November 2014 rate at which radionuclides such as Silver-110m and Caesium-137 can cross the silicon carbide barrier Available online 4 December 2014 layers, and at which fission products such as palladium could compromise or otherwise alter the nature of this layer, are of paramount importance for the safety of this fuel. To this end, DFT-based metadynam- ics simulations are applied to the atomic diffusion of silver, caesium and palladium along a R5 grain boundary and to palladium along a carbon-rich R3 grain boundary in cubic silicon carbide at 1500 K. For silver, the calculated diffusion coefficients lie in a similar range (7.04 Â 10À19–3.69 Â 10À17 m2 sÀ1) as determined experimentally. -
Biologists Struggle with Push to End Use of Caesium Proposed Switch to X-Ray Irradiators Could Affect Results of Research
NEWS IN FOCUS NUCLEAR SECURITY Biologists struggle with push to end use of caesium Proposed switch to X-ray irradiators could affect results of research. BY JEFF TOLLEFSON nybody who wants to conduct experiments on mice in Margaret Goodell’s immunology lab must sub- Amit to a host of security measures, starting JIM R. BOUNDS/AP/PA with a background check by the FBI. That’s because Goodell, a researcher at Baylor College of Medicine in Houston, Texas, uses a caesium-based irradiator to destroy bone marrow in mice that are set to receive stem- cell transplants. The US government fears that the radioactive caesium could be stolen to make a ‘dirty’ bomb. Now the US National Nuclear Security Administration (NNSA) is working with sci- entists to investigate how — or whether — to replace caesium irradiators with less dangerous X-ray technology. Researchers have used the caesium devices for decades, to study every thing from immunotherapy to cancer treat- ment, and some fear that switching to X-ray irradiators will affect their results. Goodell, who has found subtle differences in how the mouse immune system responds Biomedical researchers often use caesium-137 to irradiate cells. to the two types of device, prefers Baylor’s caesium irradiator. Her research has revealed or water; exposure to the substance can cause alternative ways to treat blood is relatively that immune cells called B lymphocytes burns, radiation sickness or death, depend- simple. The NNSA is working with research- recovered more slowly in mice treated with ing on the dose. Caesium irradiators, which ers to pin down the more complicated issue an X-ray irradiator than in those exposed have long been used to eliminate pathogens in of how X-ray irradiators might differ from to caesium. -
US2278550.Pdf
April 7, 1942. D. J. OER E. A. 2,278,550 PREPARATION OF ALKALI METAL ALKOXIDES Filed June 21, 1939 REACTION ------ REGENERATION OFMX FROM M-represents an alkali metal N-represents a number from 2 to 3 R-represents an alkyl group X-represents the anion of a weak acid Donald D. Lee Donald J. Loder NVENTOR BY 232 az - ATTORNEY Patented Apr. 7, 1942 2,278,550 UNITED STATES PATENT OFFICE 2,278,550 PREPARATION OF ALKALI METAL ALKOXDES Donald J. Loder and Donald D. Lee, Wilmington, Del, assignors to E. I. du Pont de Nemours & Company, Wilmington, Del., a corporation of Delaware Application June 21, 1939, Serial No. 280,308 16 Claims. (CI. 260-632) The invention relates to improvements in the and R is an alkyl, or aralkyl radical which may be manufacture of metal alkoxides and more particu Saturated, unsaturated, substituted or unsub larly to the preparation of alkali metal alkoxides stituted. by the interaction of alcohols with alkali metal In Reactions 1 and 2, an alkali metal salt of a salts of weak acids. weak acid is digested with an alcohol at an ap Alkali metal alkoxides have been prepared by propriate temperature, the digestion being Con. direct reaction of the alkali metal as such with tinued until equilibrium has been substantially an alcohol. or by action of an alkali metal hy reached. The equilibrium mixture is filtered for. droxide. upon an alcohol. The higher cost of the the separation of any undissolved (MX or M3X) first of these methods has limited somewhat the O salt and the resulting solution (or filtrate) is industrial use of the alkoxide thus prepared and found to contain an alkali metal alkoxide, or much effort has been expended in endeavors to aralkoxide, (MOR) hereinafter called 'al make the second more commercially practicable. -
NEW at ROTH June 2014 NEW Products and Programme Extensions in Chemicals
NEW at ROTH June 2014 NEW Products and Programme Extensions in Chemicals Content NEW Products Chemicals .................................... 2-14 NEW at ROTH | NEW at ROTH | NEW at ROTH | NEW at ROTH | NEW at ROTH | NEW at ROTH | NEW at ROTH | NEW at ROTH | NEW at ROTH | NEW at RO NEW Chemicals June 2014 Acids Nitric acid 40 % Biochemicals ® Nitric acid 40 % Cellpure Nitr Hydrochloric acid 37 % 40 %, pure HNO3 M 63,0 g/mol L-Alanyl-L-glutamine Hydrochloric acid 37 % D 1,25 Hydr 37 %, techn. [7697-37-2] O O Hydrogen chloride EC No 231-714-2 · UN No. 2031 HCl ADR 8 II · WGK 1 H2N OH M 36,46 g/mol h Danger H290-H314 HN O D ~1,19 Type analysis: [7647-01-0] Assay. ...................................................... 39,0-41,0 % H2N CH3 EC No 231-595-7 · UN No. 1789 Chloride (Cl). ................................................ b0,001 % ADR 8 II · WGK 1 Iron (Fe)...................................................... 0,0005 % L-Alanyl-L-glutamine Alan Danger H290-H314-H335 Heavy metals (as Pb). ................................ 0,0001 % 99 %, CELLPURE® h g Ash............................................................... b0,001 % Type analysis: C8H15N3O4 Assay..............................................................36,5 % 6748.1 1 l glass 17,10 € M 217,22 g/mol Density (20 °C). ........................................1,183-1,187 Original pack 6 x 1 l 16,25/1 l mp 209 °C (dec.) Lead (Pb)....................................................0,0001 % 6748.2 5 l plastic 42,90 € Solubility: 450 g/l (H2O, 20 °C) 7476.1 1 l glass 13,85 € Original pack 2 x 5 l 40,76/5 l [39537-23-0] 6748.3 10 l plastic 53,65 € WGK 1 Original pack 6 x 1 l 13,16/1 l 7476.2 2,5 l glass 19,25 € 6748.4 25 l plastic 103,20 € Type analysis: Original pack 4 x 2,5 l 18,29/2,5 l Appearance. -
Enzyme and Lateral Flow Monoclonal Antibody-Based Immunoassays To
www.nature.com/scientificreports OPEN Enzyme and lateral fow monoclonal antibody‑based immunoassays to simultaneously determine spirotetramat and spirotetramat‑enol in foodstufs Ramón E. Cevallos‑Cedeño1,3, Consuelo Agulló2, Antonio Abad‑Fuentes1, Antonio Abad‑Somovilla2 & Josep V. Mercader1* Spirotetramat is employed worldwide to fght insect pests due to its high efciency. This chemical is quickly metabolized by plants into spirotetramat‑enol, so current regulations establish that both compounds must be determined in foodstufs for monitoring purposes. Nowadays, immunochemical methods constitute rapid and cost‑efective strategies for chemical contaminant analysis at trace levels. However, high‑afnity binders and suitable bioconjugates are required. In this study, haptens with opposite functionalisation sites were synthesized in order to generate high‑afnity monoclonal antibodies. A direct competitive enzyme‑linked immunosorbent assay with an IC50 value for the sum of spirotetramat and spirotetramat‑enol of 0.1 μg/L was developed using selected antibodies and a novel heterologous bioconjugate carrying a rationally‑designed hapten. Studies with fortifed grape, grape juice, and wine samples showed good precision and accuracy values, with limits of quantifcation well below the maximum residue limits. Excellent correlation of results was observed with a standard reference chromatographic method. As a step forward, a lateral fow immunoassay was developed for onsite screening analysis of spirotetramat in wine. This assay was successfully validated according to Regulation 519/2014/EU for semi‑quantitative methods at concentrations in line with the legal levels of spirotetramat and spirotetramat‑enol in grapes, with a satisfactory false suspect rate below 2%. Spirotetramat (SP), also known as BYI08330, was developed by Bayer CropScience a few years ago, and it was approved as a pesticide in the European Union and in the USA in 20141,2. -
A Review of Rare-Element (Li-Cs-Ta) Pegmatite Exploration Techniques for the Superior Province, Canada, and Large Worldwide Tantalum Deposits
Exploration and Mining Geology, Vol. 14, Nos. 1-4, pp. 1-30, 2005 © 2006 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved. Printed in Canada. 0964-1823/00 $17.00 + .00 A Review of Rare-Element (Li-Cs-Ta) Pegmatite Exploration Techniques for the Superior Province, Canada, and Large Worldwide Tantalum Deposits JULIE B. SELWAY, FREDERICK W. BREAKS Precambrian Geoscience Section, Ontario Geological Survey 933 Ramsey Lake Road, Sudbury, ON P3E 6B5 ANDREW G. TINDLE Department of Earch Sciences, Open University Milton Keynes, Buckinghamshire, UK MK7 6AA (Received February 16, 2004; accepted September 20, 2004) Abstract — Rare-element pegmatites may host several economic commodities, such as tantalum (Ta- oxide minerals), tin (cassiterite), lithium (ceramic-grade spodumene and petalite), and cesium (pollucite). Key geological features that are common to pegmatites in the Superior province of Ontario and Manitoba, Canada, and in other large tantalum deposits worldwide, can be used in exploration. An exploration project for rare-element pegmatites should begin with an examination of a regional geology map. Rare-element pegmatites occur along large regional-scale faults in greenschist and amphibolite facies metamorphic terranes. They are typically hosted by mafic metavolcanic or metasedimentary rocks, and are located near peraluminous granite plutons (A/CNK > 1.0). Once a peraluminous granite pluton has been identified, then the next step is to determine if the pluton is barren or fertile. Fertile granites have elevated rare element contents, Mg/Li ratio < 10, and Nb/Ta ratio < 8. They commonly contain blocky K-feldspar and green muscovite. Key fractionation indicators can be plotted on a map of the fertile granite pluton to determine the fractionation direction: presence of tourmaline, beryl, and ferrocolumbite; Mn content in garnet; Rb content in bulk K-feldspar; and Mg/Li and Nb/Ta ratios in bulk granite samples. -
Unit 6 the Periodic Table How to Group Elements Together? Elements of Similar Properties Would Be Group Together for Convenience
Unit 6 The periodic table How to group elements together? Elements of similar properties would be group together for convenience. The periodic table Chemists group elements with similar chemical properties together. This gives rise to the periodic table. In the periodic table, elements are arranged according to the following criteria: 1. in increasing order of atomic numbers and 2. according to the electronic arrangement The diagram below shows a simplified periodic table with the first 36 elements listed. Groups The vertical columns in the periodic table are called groups . Groups are numbered from I to VII, followed by Group 0 (formerly called Group VIII). [Some groups are without group numbers.] The table below shows the electronic arrangements of some elements in some groups. Group I Group II Group VII Group 0 He (2) Li (2,1) Be (2,2) F (2,7) Ne (2,8) Na (2,8,1) Mg (2,8,2) Cl (2,8,7) Ar (2,8,8) K (2,8,8,1) Ca (2,8,8,2) Br (2,8,18,7) Kr (2,8,18,8) What is the relationship between the group numbers and the electronic arrangements of the elements? Group number = the number of outermost shell electrons in an atom of the element The chemical properties of an element depend mainly on the number of outermost shell electrons in its atoms. Therefore, elements within the same group would have similar chemical properties and would react in a similar way. However, there would be a gradual change of reactivity of the elements as we move down the group.