DOCSLIB.ORG

Safety Data Sheet

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Safety Data Sheet SAFETY DATA SHEET According to Chinese National Standard GB/T 16483-2008 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product name: Cesium Carbonate, Caesium carbonate Product code: CESCARBDRY CAS No 534-17-8 Synonyms: Cs2CO3 Dicesium carbonate Caesium Carbonate Recommended use: Catalyst, Industrial Products Restrictions on use: Not Applicable Supplier: Asia Pacific Business Service Center and Regional Headquarters Cabot China Ltd 558 Shuangbai Road Minhang District Shanghai 201108, China Tel: +86 21 5175 8800 Fax: +86 216434 5532 E-mail: [email protected] Emergency telephone 24H/7d service China: CHEMTREC 4001 - 204937 International CHEMTREC: +1 703-741-5970 or +1-703-527-3887 US: CHEMTREC: +1-703-527-3887 or 1-800-424-9300 E-mail address: [email protected] 2. HAZARDS IDENTIFICATION GHS - Classification A hazardous substance according to Chinese National Standard GB 13690-2009: General rules for classification and hazard communication of chemicals. Serious eye damage/eye irritation: Category 1 Reproductive toxicity Category 2 Specific target organ toxicity (repeated exposure) Category 2 Label Elements: ___________________________________________________________________________________________ Page 1 / 12 Product code: CESCARBDRY Product name: Cesium Carbonate, Caesium Revision date: 18-Apr-2017 carbonate ___________________________________________________________________________________________ Signal Word: DANGER Hazard statements: H318 - Causes serious eye damage H361f - Suspected of damaging fertility H373 - May cause damage to organs (kidneys, adrenals) through prolonged or repeated exposure Precautionary Statements - • Obtain special instructions before use Prevention • Do not handle until all safety precautions have been read and understood • Do not breathe dust • Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response• IF exposed or concerned: Get medical advice/attention Eyes • IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing • Immediately call a POISON CENTER or doctor/physician Precautionary Statements - Storage • Store locked up Precautionary Statements - Disposal • Dispose of contents/container in accordance with local, regional, national, and international regulations Potential health effects Principle Routes of Exposure: Inhalation, Eye contact, Skin Contact Skin Contact: May cause mechanical irritation. Inhalation: Dust may be irritating to respiratory tract. Ingestion: May be harmful if swallowed. Reproductive Effects: Male Reproductive System. See Section 11. Carcinogenicity: Does not contain any substances listed by IARC (International Agency for Research on Cancer), NTP (National Toxicology Program), OSHA (Occupational Safety and Health Administration), ACGIH (American Conference of Governmental Industrial Hygienists) or EU (European Union). See also Section 11. Target Organ Effects: Respiratory system, Eyes, Skin, Kidney, Adrenal gland ___________________________________________________________________________________________ Page 2 / 12 Product code: CESCARBDRY Product name: Cesium Carbonate, Caesium Revision date: 18-Apr-2017 carbonate ___________________________________________________________________________________________ Medical Conditions Aggravated by Asthma, Respiratory disorder, Kidney disorders, Adrenal gland disorders Exposure: Potential Environmental Effects: None known. See also Section 12. 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms: Cs2CO3, Dicesium carbonate, Caesium Carbonate CAS No 534-17-8 Chemical name CAS No weight-% Cesium Carbonate 534-17-8 100 4. FIRST AID MEASURES FIRST AID MEASURES Skin Contact Wash thoroughly with soap and water. Seek medical attention if symptoms develop. Eye contact Flush eyes immediately with large amounts of water for 15 minutes. Seek medical attention if redness, swelling, itching, burning or visual disturbances occur. Inhalation If cough, shortness of breath or other breathing problems occur, move to fresh air. Seek medical attention if symptoms persist. If necessary, restore normal breathing through standard first aid measures. Ingestion Do not induce vomiting. If conscious, give several glasses of water. Never give anything by mouth to an unconscious person. Seek medical attention. Self-protection of the first aider: Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in Section 2 and/or in Section 11. Indication of any immediate medical attention and special treatment needed Note to physicians: Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Carbon dioxide (CO2). Foam. Dry chemical. Water. Unsuitable Extinguishing Media: None. Specific hazards arising from the chemical: Thermal decomposition can lead to release of irritating gases and vapors. ___________________________________________________________________________________________ Page 3 / 12 Product code: CESCARBDRY Product name: Cesium Carbonate, Caesium Revision date: 18-Apr-2017 carbonate ___________________________________________________________________________________________ Hazardous combustion products: Oxides of Cesium. Carbon monoxide (CO). Carbon dioxide (CO2). Explosion data Sensitivity to Mechanical Impact: None. Sensitivity to Static Discharge: Avoid dust formation. Take precautionary measures against static discharges. Protective equipment and precautions for firefighters: In the event of fire, wear self-contained breathing apparatus. Wear suitable protective equipment. Risk of Dust Explosion: This material is an inorganic dust and will not create nor support conditions that would result in a dust explosion or fire 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions: Avoid dust formation. Ensure adequate ventilation. Use personal protective equipment. See also Section 8. Environmental Precautions: Environmental Precautions: Contain spilled material on land, if safe to do so. Local authorities should be advised if significant spillages cannot be contained. See also Section 13. Methods and material for containment and cleaning up Methods for containment: Prevent further leakage or spillage if safe to do so. Methods for cleaning up: Do not create a dust cloud by using a brush or compressed air. Clean up promptly by vacuum. Use of a vacuum with high efficiency particulate air (HEPA) filtration is recommended. Pick up and transfer to properly labeled containers. See Section 13. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling: Avoid contact with skin and eyes. Avoid dust formation. Do not breathe dust. Provide appropriate exhaust ventilation at machinery and at places where dust can be generated. Avoid ingestion. Avoid prolonged or repeated exposure. General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Conditions: Hygroscopic material. Will absorb water readily from atmosphere. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in properly labeled containers. Do not store together with strong oxidizing agents. Incompatible materials: Strong oxidizing agents. Strong acids. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION ___________________________________________________________________________________________ Page 4 / 12 Product code: CESCARBDRY Product name: Cesium Carbonate, Caesium Revision date: 18-Apr-2017 carbonate ___________________________________________________________________________________________ Exposure guidelines: There are no exposure limits identified for this product. Exposure limits for dust are stated below. Dust, or Particulates Not Otherwise Austria MAK: 10 mg/m³, STEL 2x30 min, Inhalable dust Specified: 5 mg/m³, TWA, Inhalable dust Belgium: 10 mg/m³, TWA, Inhalable 3 mg/m³ TWA, Respirable France: 10 mg/m³, TWA Inhalable dust 5 mg/m³, TWA Respirable dust Germany - TRGS 900: 10 mg/m³, TWA, Inhalable 3 mg/m³, Respirable fraction Ireland: 10 mg/m³, TWA, Total inhalable 4 mg/m³, TWA, Respirable Italy: 10 mg/m³, TWA, Inhalable 3 mg/m³, TWA, Respirable Spain: 10 mg/m³, VLA, Inhalable 3 mg/m³, VLA, Respirable Sweden: 10 mg/m³, NGV, Total inhalable 5 mg/m³, NGV, Respirable The Netherlands: 10 mg/m³, TGG, Inhalable 5 mg/m³, TGG, Respirable United Kingdom - WEL: 10 mg/m³, TWA, Total Inhalable dust 4 mg/m³, TWA, Respirable dust US ACGIH - PNOS: 10 mg/m³, TWA, Inhalable 3 mg/m³, TWA, Respirable US OSHA - PEL: 15 mg/m³, TWA, Total dust 5 mg/m³, TWA, Respirable MAK: Maximale Arbeitsplatzkonzentration (Maximum Workplace Concentration) STEL: Short Term Exposure Limit TWA: Time Weighted Average TRGS: Technische Regeln für Gefahrstoffe (Technical Rule for Hazardous Materials) VLA: Valore Límite Ambientales (Environmental Limit Value) NGV: Nivå Gräns Värde (Level Limit Value) TGG: tijdgewogen gemiddelde (Occupational Exposure Limit) WEL: Workplace Exposure Limit US ACGIH: United States American Conference of Governmental Industrial Hygienists US OSHA: United States Occupational Safety and Health Administration PNOS: Particulate Not Otherwise Specified PEL: Permissible Exposure Limit ___________________________________________________________________________________________
Load more

Recommended publications
  • Synthesis of Mollugin and (3S,4R)-Trans-3,4-Dihydroxy-3,4-Dihydromollugin
    Accepted Manuscript Asymmetric epoxidation of chromenes mediated by iminium salts: Synthesis of mollugin and (3S,4R)-trans-3,4-dihydroxy-3,4-dihydromollugin Philip C. Bulman Page, Yohan Chan, Abu Hassan Noor Armylisas, Mohammed Alahmdi PII: S0040-4020(16)31129-2 DOI: 10.1016/j.tet.2016.10.070 Reference: TET 28211 To appear in: Tetrahedron Received Date: 30 July 2016 Revised Date: 22 October 2016 Accepted Date: 31 October 2016 Please cite this article as: Page PCB, Chan Y, Noor Armylisas AH, Alahmdi M, Asymmetric epoxidation of chromenes mediated by iminium salts: Synthesis of mollugin and (3S,4R)-trans-3,4-dihydroxy-3,4- dihydromollugin, Tetrahedron (2016), doi: 10.1016/j.tet.2016.10.070. This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. provided by University of East Anglia digital repository View metadata, citation and similar papers at core.ac.uk CORE brought to you by ACCEPTED MANUSCRIPT Graphical Abstract MANUSCRIPT ACCEPTED Asymmetric Epoxidation of Chromenes Mediated by Iminium Salts: Synthesis of Mollugin and (3 S,4 R)- ACCEPTED MANUSCRIPT trans -3,4-Dihydroxy-3,4-Dihydromollugin Philip C. Bulman Page, a* Yohan Chan, a Abu Hassan Noor Armylisas, b Mohammed Alahmdi c a School of Chemistry, University of East Anglia, Norwich Research Park, Norwich, Norfolk NR4 7TJ, U.K.
    [Show full text]
  • 100011-1 Cesium (1000Μg/Ml in 1% HNO3)
    100011-1 Cesium (1000μg/mL in 1% HNO3) High-Purity Standards Chemwatch Hazard Alert Code: 3 Catalogue number: 1000-11-1 Issue Date: 03/07/2017 Version No: 3.3 Print Date: 03/07/2017 Safety Data Sheet according to OSHA HazCom Standard (2012) requirements S.GHS.USA.EN SECTION 1 IDENTIFICATION Product Identifier Product name 100011-1 Cesium (1000μg/mL in 1% HNO3) Synonyms 1000μg/mL Cesium in 1% HNO3 Proper shipping name Corrosive liquid, acidic, inorganic, n.o.s. (contains nitric acid) Other means of 1000-11-1 identification Recommended use of the chemical and restrictions on use Relevant identified uses Use according to manufacturer's directions. Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party Registered company name High-Purity Standards Address PO Box 41727 SC 29423 United States Telephone 843-767-7900 Fax 843-767-7906 Website highpuritystandards.com Email Not Available Emergency phone number Association / Organisation INFOTRAC Emergency telephone 1-800-535-5053 numbers Other emergency telephone 1-352-323-3500 numbers SECTION 2 HAZARD(S) IDENTIFICATION Classification of the substance or mixture Classification Metal Corrosion Category 1, Skin Corrosion/Irritation Category 1A, Serious Eye Damage Category 1 Label elements GHS label elements SIGNAL WORD DANGER Hazard statement(s) H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. Hazard(s) not otherwise specified Not Applicable Precautionary statement(s) Prevention Continued... Chemwatch: 9-245281 Page 2 of 10 Issue Date: 03/07/2017 Catalogue number: 1000-11-1 100011-1 Cesium (1000μg/mL in 1% HNO3) Print Date: 03/07/2017 Version No: 3.3 P260 Do not breathe dust/fume/gas/mist/vapours/spray.
    [Show full text]
  • US2278550.Pdf
    April 7, 1942. D. J. OER E. A. 2,278,550 PREPARATION OF ALKALI METAL ALKOXIDES Filed June 21, 1939 REACTION ------ REGENERATION OFMX FROM M-represents an alkali metal N-represents a number from 2 to 3 R-represents an alkyl group X-represents the anion of a weak acid Donald D. Lee Donald J. Loder NVENTOR BY 232 az - ATTORNEY Patented Apr. 7, 1942 2,278,550 UNITED STATES PATENT OFFICE 2,278,550 PREPARATION OF ALKALI METAL ALKOXDES Donald J. Loder and Donald D. Lee, Wilmington, Del, assignors to E. I. du Pont de Nemours & Company, Wilmington, Del., a corporation of Delaware Application June 21, 1939, Serial No. 280,308 16 Claims. (CI. 260-632) The invention relates to improvements in the and R is an alkyl, or aralkyl radical which may be manufacture of metal alkoxides and more particu Saturated, unsaturated, substituted or unsub larly to the preparation of alkali metal alkoxides stituted. by the interaction of alcohols with alkali metal In Reactions 1 and 2, an alkali metal salt of a salts of weak acids. weak acid is digested with an alcohol at an ap Alkali metal alkoxides have been prepared by propriate temperature, the digestion being Con. direct reaction of the alkali metal as such with tinued until equilibrium has been substantially an alcohol. or by action of an alkali metal hy reached. The equilibrium mixture is filtered for. droxide. upon an alcohol. The higher cost of the the separation of any undissolved (MX or M3X) first of these methods has limited somewhat the O salt and the resulting solution (or filtrate) is industrial use of the alkoxide thus prepared and found to contain an alkali metal alkoxide, or much effort has been expended in endeavors to aralkoxide, (MOR) hereinafter called 'al make the second more commercially practicable.
    [Show full text]
  • NEW at ROTH June 2014 NEW Products and Programme Extensions in Chemicals
    NEW at ROTH June 2014 NEW Products and Programme Extensions in Chemicals Content NEW Products Chemicals .................................... 2-14 NEW at ROTH | NEW at ROTH | NEW at ROTH | NEW at ROTH | NEW at ROTH | NEW at ROTH | NEW at ROTH | NEW at ROTH | NEW at ROTH | NEW at RO NEW Chemicals June 2014 Acids Nitric acid 40 % Biochemicals ® Nitric acid 40 % Cellpure Nitr Hydrochloric acid 37 % 40 %, pure HNO3 M 63,0 g/mol L-Alanyl-L-glutamine Hydrochloric acid 37 % D 1,25 Hydr 37 %, techn. [7697-37-2] O O Hydrogen chloride EC No 231-714-2 · UN No. 2031 HCl ADR 8 II · WGK 1 H2N OH M 36,46 g/mol h Danger H290-H314 HN O D ~1,19 Type analysis: [7647-01-0] Assay. ...................................................... 39,0-41,0 % H2N CH3 EC No 231-595-7 · UN No. 1789 Chloride (Cl). ................................................ b0,001 % ADR 8 II · WGK 1 Iron (Fe)...................................................... 0,0005 % L-Alanyl-L-glutamine Alan Danger H290-H314-H335 Heavy metals (as Pb). ................................ 0,0001 % 99 %, CELLPURE® h g Ash............................................................... b0,001 % Type analysis: C8H15N3O4 Assay..............................................................36,5 % 6748.1 1 l glass 17,10 € M 217,22 g/mol Density (20 °C). ........................................1,183-1,187 Original pack 6 x 1 l 16,25/1 l mp 209 °C (dec.) Lead (Pb)....................................................0,0001 % 6748.2 5 l plastic 42,90 € Solubility: 450 g/l (H2O, 20 °C) 7476.1 1 l glass 13,85 € Original pack 2 x 5 l 40,76/5 l [39537-23-0] 6748.3 10 l plastic 53,65 € WGK 1 Original pack 6 x 1 l 13,16/1 l 7476.2 2,5 l glass 19,25 € 6748.4 25 l plastic 103,20 € Type analysis: Original pack 4 x 2,5 l 18,29/2,5 l Appearance.
    [Show full text]
  • Enzyme and Lateral Flow Monoclonal Antibody-Based Immunoassays To
    www.nature.com/scientificreports OPEN Enzyme and lateral fow monoclonal antibody‑based immunoassays to simultaneously determine spirotetramat and spirotetramat‑enol in foodstufs Ramón E. Cevallos‑Cedeño1,3, Consuelo Agulló2, Antonio Abad‑Fuentes1, Antonio Abad‑Somovilla2 & Josep V. Mercader1* Spirotetramat is employed worldwide to fght insect pests due to its high efciency. This chemical is quickly metabolized by plants into spirotetramat‑enol, so current regulations establish that both compounds must be determined in foodstufs for monitoring purposes. Nowadays, immunochemical methods constitute rapid and cost‑efective strategies for chemical contaminant analysis at trace levels. However, high‑afnity binders and suitable bioconjugates are required. In this study, haptens with opposite functionalisation sites were synthesized in order to generate high‑afnity monoclonal antibodies. A direct competitive enzyme‑linked immunosorbent assay with an IC50 value for the sum of spirotetramat and spirotetramat‑enol of 0.1 μg/L was developed using selected antibodies and a novel heterologous bioconjugate carrying a rationally‑designed hapten. Studies with fortifed grape, grape juice, and wine samples showed good precision and accuracy values, with limits of quantifcation well below the maximum residue limits. Excellent correlation of results was observed with a standard reference chromatographic method. As a step forward, a lateral fow immunoassay was developed for onsite screening analysis of spirotetramat in wine. This assay was successfully validated according to Regulation 519/2014/EU for semi‑quantitative methods at concentrations in line with the legal levels of spirotetramat and spirotetramat‑enol in grapes, with a satisfactory false suspect rate below 2%. Spirotetramat (SP), also known as BYI08330, was developed by Bayer CropScience a few years ago, and it was approved as a pesticide in the European Union and in the USA in 20141,2.
    [Show full text]
  • Chemical Names and CAS Numbers Final
    Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number C3H8O 1‐propanol C4H7BrO2 2‐bromobutyric acid 80‐58‐0 GeH3COOH 2‐germaacetic acid C4H10 2‐methylpropane 75‐28‐5 C3H8O 2‐propanol 67‐63‐0 C6H10O3 4‐acetylbutyric acid 448671 C4H7BrO2 4‐bromobutyric acid 2623‐87‐2 CH3CHO acetaldehyde CH3CONH2 acetamide C8H9NO2 acetaminophen 103‐90‐2 − C2H3O2 acetate ion − CH3COO acetate ion C2H4O2 acetic acid 64‐19‐7 CH3COOH acetic acid (CH3)2CO acetone CH3COCl acetyl chloride C2H2 acetylene 74‐86‐2 HCCH acetylene C9H8O4 acetylsalicylic acid 50‐78‐2 H2C(CH)CN acrylonitrile C3H7NO2 Ala C3H7NO2 alanine 56‐41‐7 NaAlSi3O3 albite AlSb aluminium antimonide 25152‐52‐7 AlAs aluminium arsenide 22831‐42‐1 AlBO2 aluminium borate 61279‐70‐7 AlBO aluminium boron oxide 12041‐48‐4 AlBr3 aluminium bromide 7727‐15‐3 AlBr3•6H2O aluminium bromide hexahydrate 2149397 AlCl4Cs aluminium caesium tetrachloride 17992‐03‐9 AlCl3 aluminium chloride (anhydrous) 7446‐70‐0 AlCl3•6H2O aluminium chloride hexahydrate 7784‐13‐6 AlClO aluminium chloride oxide 13596‐11‐7 AlB2 aluminium diboride 12041‐50‐8 AlF2 aluminium difluoride 13569‐23‐8 AlF2O aluminium difluoride oxide 38344‐66‐0 AlB12 aluminium dodecaboride 12041‐54‐2 Al2F6 aluminium fluoride 17949‐86‐9 AlF3 aluminium fluoride 7784‐18‐1 Al(CHO2)3 aluminium formate 7360‐53‐4 1 of 75 Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number Al(OH)3 aluminium hydroxide 21645‐51‐2 Al2I6 aluminium iodide 18898‐35‐6 AlI3 aluminium iodide 7784‐23‐8 AlBr aluminium monobromide 22359‐97‐3 AlCl aluminium monochloride
    [Show full text]
  • WO 2014/060464 Al 24 April 2014 (24.04.2014) P O P C T
    (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2014/060464 Al 24 April 2014 (24.04.2014) P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C07D 213/75 (2006.01) C07D 209/48 (2006.01) kind of national protection available): AE, AG, AL, AM, C07D 233/60 (2006.01) C07D 295/104 (2006.01) AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, C07D 249/08 (2006.01) A61K 31/44 (2006.01) BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, C07D 207/408 (2006.01) A61P 11/06 (2006.01) DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, (21) International Application Number: KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME, PCT/EP20 13/07 1607 MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, (22) International Filing Date: OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, 16 October 2013 (16.10.201 3) SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, (25) Filing Language: English ZW. (26) Publication Language: English (84) Designated States (unless otherwise indicated, for every (30) Priority Data: kind of regional protection available): ARIPO (BW, GH, P20 123 1598 17 October 2012 (17.
    [Show full text]
  • Towards More Sustainable Synthesis of Diketopyrrolopyrroles
    View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Repository@Nottingham Towards more sustainable synthesis of diketopyrrolopyrroles By Flavia Pop,* a,b Joshua Humphreys,a,b Jesper Schwarz,a,b Liam Brown,a,b Ashmiani van den Berg,a David B. Amabilino* a,b a. School of Chemistry, The University of Nottingham, NG7 2RD Nottingham, UK. b. GSK Carbon Neutral Laboratories for Sustainable Chemistry, The University of Nottingham, Jubilee Campus, Triumph Road, Nottingham, NG7 2TU, UK. ABSTTRACT The alkylation of 1,4-diketo-3,6-arylpyrrolo[3,4-c]pyrroles (ArDPP) is one of the most important steps in the synthesis of soluble materials based on these molecules and the polymers derived from them (that are employed widely in putative organic solar cells). Here we report an improvement in their method of synthesis replacing habitual solvent and base. Compared with more usual conditions, we employed acetonitrile as solvent to give higher or similar yields, with less toxic and hazardous waste, lower reaction time and temperature, and allows recycling of unreacted starting materials. Unlike dimethylformamide and N-methylpyrrolidone, which are the most commonly employed solvents. Our reaction conditions have been tested on three different ArDPPs (Ar = thiophene, phenyl and 4-methoxyphenyl) with a variety of linear and branched alkyl reagents. The results show similar and improved results in comparison with the published reports while reducing the waste and hazard of the reaction, as well as simplifying the purification of the products in many cases. Overall this method has lower environmental impact, is more cost effective and requires neither the use of dry solvent nor inert atmosphere.
    [Show full text]
  • Controlling and Exploiting the Caesium Effect in Palladium Catalysed Coupling Reactions
    Controlling and exploiting the caesium effect in palladium catalysed coupling reactions Thomas J. Dent Submitted in accordance with the requirements for the degree of Doctor of Philosophy The University of Leeds School of Chemistry May 2019 i The candidate confirms that the work submitted is his own and that appropriate credit has been given where reference has been made to the work of others. This copy has been supplied on the understanding that it is copyright material and that no quotation from the report may be published without proper acknowledgement The right of Thomas Dent to be identified as Author of this work has been asserted by him in accordance with the Copyright, Designs and Patents Act 1988. © 2019 The University of Leeds and Thomas J. Dent ii Acknowledgements This project could not have been completed without the help of several individuals who’ve helped guide the project into the finished article. First and foremost I’d like to thank Dr. Bao Nguyen his support, useful discussions and the ability to sift through hundreds of experiments of kinetic data to put together a coherent figure. My writing has come a long way from my transfer report, so all the comments and suggestions seem to have mostly not been in vain. To Paddy, the discussions relating to the NMR studies and anything vaguely inorganic were incredibly useful, and provided me with data that supported our hypothesis with more direct evidence than just the reaction monitoring experiments. Rob, I really enjoyed my time at AZ and your support during my time there was incredibly useful so I could maximise my short secondment when I was getting more results than I knew what to do with.
    [Show full text]
  • Safety Data Sheet
    SAFETY DATA SHEET Prepared in accordance with ISO 11014-1/ ANSI standard Z400.1-2004/ JIS Revision date: 18-Apr-2017 Z 7253:2012 . 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product Identifier Product name: Cesium Carbonate, Caesium carbonate Product Code: CESCARBDRY Other means of identification Synonyms: Cs2CO3, Dicesium carbonate, Caesium Carbonate CAS No 534-17-8 Registration number(s) No information available Recommended use of the chemical and restrictions on use Recommended use: Catalyst, Industrial Products Restrictions on use: Not Applicable Details of the supplier of the safety data sheet Sales and Shared Service Center Cabot Specialty Chemicals, Inc. Sumitomo Shiba-Daimon Bldg. 11F 2-5-5 Shiba Daimon, Minato-ku Tokyo 105-0012 JAPAN Tel: 81-3-6820-0255 Fax: 81-3-5425-4500 E-mail: [email protected] Emergency Telephone Number: 24H/7d service JAPAN: CHEMTREC 03-4520-9637 International CHEMTREC: +1 703-741-5970 or +1-703-527-3887 US: CHEMTREC: +1-703-527-3887 or 1-800-424-9300 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Serious eye damage/eye irritation: Category 1 Reproductive toxicity Category 2 Specific target organ toxicity (repeated exposure) Category 2 ___________________________________________________________________________________________ Page 1 / 12 Product code: CESCARBDRY Product name: Cesium Carbonate, Caesium Revision date: 18-Apr-2017 carbonate ___________________________________________________________________________________________ Label
    [Show full text]
  • (PEEK) Composite Materials for Recycling Applications Dandy, Luke; Oliveux, Geraldine; Wood, Joseph; Jenkins, Michael; Leeke, Gary
    Accelerated degradation of Polyetheretherketone (PEEK) composite materials for recycling applications Dandy, Luke; Oliveux, Geraldine; Wood, Joseph; Jenkins, Michael; Leeke, Gary DOI: 10.1016/j.polymdegradstab.2014.12.012 License: Creative Commons: Attribution (CC BY) Document Version Publisher's PDF, also known as Version of record Citation for published version (Harvard): Dandy, L, Oliveux, G, Wood, J, Jenkins, M & Leeke, G 2015, 'Accelerated degradation of Polyetheretherketone (PEEK) composite materials for recycling applications', Polymer Degradation and Stability , vol. 112, pp. 52-62. https://doi.org/10.1016/j.polymdegradstab.2014.12.012 Link to publication on Research at Birmingham portal Publisher Rights Statement: Eligibility for repository: checked 11/02/2015 General rights Unless a licence is specified above, all rights (including copyright and moral rights) in this document are retained by the authors and/or the copyright holders. The express permission of the copyright holder must be obtained for any use of this material other than for purposes permitted by law. •Users may freely distribute the URL that is used to identify this publication. •Users may download and/or print one copy of the publication from the University of Birmingham research portal for the purpose of private study or non-commercial research. •User may use extracts from the document in line with the concept of ‘fair dealing’ under the Copyright, Designs and Patents Act 1988 (?) •Users may not further distribute the material nor use it for the purposes of commercial gain. Where a licence is displayed above, please note the terms and conditions of the licence govern your use of this document.
    [Show full text]
  • Enhanced Power-Conversion Efficiency in Polymer Solar Cells Using an Inverted Device Structure
    LETTERS PUBLISHED ONLINE: 19 AUGUST 2012 | DOI: 10.1038/NPHOTON.2012.190 Enhanced power-conversion efficiency in polymer solar cells using an inverted device structure Zhicai He, Chengmei Zhong, Shijian Su, Miao Xu, Hongbin Wu* and Yong Cao Polymer-fullerene bulk heterojunction solar cells (PSCs) are typically based on n-type metal oxides, our device is solution- currently attracting a great deal of attention and gaining processed at room temperature, enabling easy processibility over a increasing importance, having already shown great promise large area. Accordingly, the approach is fully amenable to high- as renewable, lightweight and low-cost energy sources1–4. throughput roll-to-roll manufacturing techniques, may be used to Recently, the power-conversion efficiency of state-of-the-art fabricate vacuum-deposition-free PSCs of large area, and find PSCs has exceeded 8% in the scientific literature5. However, practical applications in future mass production. Moreover, our to find viable applications for this emerging photovoltaic tech- discovery overturns a well-accepted belief (the inferior performance nology, further enhancements in the efficiency towards 10% of inverted PSCs) and clearly shows that the characteristics of high (the threshold for commercial applications) are urgently performance, improved stability and ease of use can be integrated required6. Here, we demonstrate highly efficient PSCs with a into a single device, as long as the devices are optimized, both opti- certified efficiency of 9.2% using an inverted structure, which cally and electrically, by means of a meticulously designed device simultaneously offers ohmic contact for photogenerated structure. We also anticipate that our findings will catalyse the charge-carrier collection and allows optimum photon harvest development of new device structures and may move the efficiency in the device.
    [Show full text]