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Energy Analysis and Carbon Saving Potential of a Complex Heating
European Journal of Sustainable Development Research 2019, 3(1), em0067 ISSN: 2542-4742 Energy Analysis and Carbon Saving Potential of a Complex Heating System with Solar Assisted Heat Pump and Phase Change Material (PCM) Thermal Storage in Different Climatic Conditions Uroš Stritih 1*, Eva Zavrl 1, Halime Omur Paksoy 2 1 University of Ljubljana, SLOVENIA 2 Çukurova Üniversitesi, TURKEY *Corresponding Author: [email protected] Citation: Stritih, U., Zavrl, E. and Paksoy, H. O. (2019). Energy Analysis and Carbon Saving Potential of a Complex Heating System with Solar Assisted Heat Pump and Phase Change Material (PCM) Thermal Storage in Different Climatic Conditions. European Journal of Sustainable Development Research, 3(1), em0067. https://doi.org/10.20897/ejosdr/3930 Published: February 6, 2019 ABSTRACT Building sector still consumes 40% of total energy consumption. Therefore, an improved heating system with Solar Assisted Heat Pump (SAHP) was introduced in order to minimse the energy consumption of the fossil fuels and to lower the carbon dioxide emissions occurring from combustion. An energy analysis of the complex heating system for heating of buildings, consisting of solar collectors (SC), latent heat storage tank (LHS) and heat pump (HP) was performed. The analysis was made for the heating season within the time from October to March for different climatic conditions. These climatic conditions were defined using test reference years (TRY) for cities: Adana, Ljubljana, Rome and Stockholm. The energy analysis was performed using a mathematical model which allowed hourly dynamics calculation of losses and gains for a given system. In Adana, Rome and Ljubljana, it was found that the system could cover 80% of energy from the sun and the heat pump coefficient of performance (COP) reached 5.7. -
Chapter 8 and 9 – Energy Balances
CBE2124, Levicky Chapter 8 and 9 – Energy Balances Reference States . Recall that enthalpy and internal energy are always defined relative to a reference state (Chapter 7). When solving energy balance problems, it is therefore necessary to define a reference state for each chemical species in the energy balance (the reference state may be predefined if a tabulated set of data is used such as the steam tables). Example . Suppose water vapor at 300 oC and 5 bar is chosen as a reference state at which Hˆ is defined to be zero. Relative to this state, what is the specific enthalpy of liquid water at 75 oC and 1 bar? What is the specific internal energy of liquid water at 75 oC and 1 bar? (Use Table B. 7). Calculating changes in enthalpy and internal energy. Hˆ and Uˆ are state functions , meaning that their values only depend on the state of the system, and not on the path taken to arrive at that state. IMPORTANT : Given a state A (as characterized by a set of variables such as pressure, temperature, composition) and a state B, the change in enthalpy of the system as it passes from A to B can be calculated along any path that leads from A to B, whether or not the path is the one actually followed. Example . 18 g of liquid water freezes to 18 g of ice while the temperature is held constant at 0 oC and the pressure is held constant at 1 atm. The enthalpy change for the process is measured to be ∆ Hˆ = - 6.01 kJ. -
HEAT and TEMPERATURE Heat Is a Type of ENERGY. When Absorbed
HEAT AND TEMPERATURE Heat is a type of ENERGY. When absorbed by a substance, heat causes inter-particle bonds to weaken and break which leads to a change of state (solid to liquid for example). Heat causing a phase change is NOT sufficient to cause an increase in temperature. Heat also causes an increase of kinetic energy (motion, friction) of the particles in a substance. This WILL cause an increase in TEMPERATURE. Temperature is NOT energy, only a measure of KINETIC ENERGY The reason why there is no change in temperature at a phase change is because the substance is using the heat only to change the way the particles interact (“stick together”). There is no increase in the particle motion and hence no rise in temperature. THERMAL ENERGY is one type of INTERNAL ENERGY possessed by an object. It is the KINETIC ENERGY component of the object’s internal energy. When thermal energy is transferred from a hot to a cold body, the term HEAT is used to describe the transferred energy. The hot body will decrease in temperature and hence in thermal energy. The cold body will increase in temperature and hence in thermal energy. Temperature Scales: The K scale is the absolute temperature scale. The lowest K temperature, 0 K, is absolute zero, the temperature at which an object possesses no thermal energy. The Celsius scale is based upon the melting point and boiling point of water at 1 atm pressure (0, 100o C) K = oC + 273.13 UNITS OF HEAT ENERGY The unit of heat energy we will use in this lesson is called the JOULE (J). -
A Comprehensive Review of Thermal Energy Storage
sustainability Review A Comprehensive Review of Thermal Energy Storage Ioan Sarbu * ID and Calin Sebarchievici Department of Building Services Engineering, Polytechnic University of Timisoara, Piata Victoriei, No. 2A, 300006 Timisoara, Romania; [email protected] * Correspondence: [email protected]; Tel.: +40-256-403-991; Fax: +40-256-403-987 Received: 7 December 2017; Accepted: 10 January 2018; Published: 14 January 2018 Abstract: Thermal energy storage (TES) is a technology that stocks thermal energy by heating or cooling a storage medium so that the stored energy can be used at a later time for heating and cooling applications and power generation. TES systems are used particularly in buildings and in industrial processes. This paper is focused on TES technologies that provide a way of valorizing solar heat and reducing the energy demand of buildings. The principles of several energy storage methods and calculation of storage capacities are described. Sensible heat storage technologies, including water tank, underground, and packed-bed storage methods, are briefly reviewed. Additionally, latent-heat storage systems associated with phase-change materials for use in solar heating/cooling of buildings, solar water heating, heat-pump systems, and concentrating solar power plants as well as thermo-chemical storage are discussed. Finally, cool thermal energy storage is also briefly reviewed and outstanding information on the performance and costs of TES systems are included. Keywords: storage system; phase-change materials; chemical storage; cold storage; performance 1. Introduction Recent projections predict that the primary energy consumption will rise by 48% in 2040 [1]. On the other hand, the depletion of fossil resources in addition to their negative impact on the environment has accelerated the shift toward sustainable energy sources. -
IB Questionbank
Topic 3 Past Paper [94 marks] This question is about thermal energy transfer. A hot piece of iron is placed into a container of cold water. After a time the iron and water reach thermal equilibrium. The heat capacity of the container is negligible. specific heat capacity. [2 marks] 1a. Define Markscheme the energy required to change the temperature (of a substance) by 1K/°C/unit degree; of mass 1 kg / per unit mass; [5 marks] 1b. The following data are available. Mass of water = 0.35 kg Mass of iron = 0.58 kg Specific heat capacity of water = 4200 J kg–1K–1 Initial temperature of water = 20°C Final temperature of water = 44°C Initial temperature of iron = 180°C (i) Determine the specific heat capacity of iron. (ii) Explain why the value calculated in (b)(i) is likely to be different from the accepted value. Markscheme (i) use of mcΔT; 0.58×c×[180-44]=0.35×4200×[44-20]; c=447Jkg-1K-1≈450Jkg-1K-1; (ii) energy would be given off to surroundings/environment / energy would be absorbed by container / energy would be given off through vaporization of water; hence final temperature would be less; hence measured value of (specific) heat capacity (of iron) would be higher; This question is in two parts. Part 1 is about ideal gases and specific heat capacity. Part 2 is about simple harmonic motion and waves. Part 1 Ideal gases and specific heat capacity State assumptions of the kinetic model of an ideal gas. [2 marks] 2a. two Markscheme point molecules / negligible volume; no forces between molecules except during contact; motion/distribution is random; elastic collisions / no energy lost; obey Newton’s laws of motion; collision in zero time; gravity is ignored; [4 marks] 2b. -
Psychrometrics Outline
Psychrometrics Outline • What is psychrometrics? • Psychrometrics in daily life and food industry • Psychrometric chart – Dry bulb temperature, wet bulb temperature, absolute humidity, relative humidity, specific volume, enthalpy – Dew point temperature • Mixing two streams of air • Heating of air and using it to dry a product 2 Psychrometrics • Psychrometrics is the study of properties of mixtures of air and water vapor • Water vapor – Superheated steam (unsaturated steam) at low pressure – Superheated steam tables are on page 817 of textbook – Properties of dry air are on page 818 of textbook – Psychrometric charts are on page 819 & 820 of textbook • What are these properties of interest and why do we need to know these properties? 3 Psychrometrics in Daily Life • Sea breeze and land breeze – When and why do we get them? • How do thunderstorms, hurricanes, and tornadoes form? • What are dew, fog, mist, and frost and when do they form? • When and why does the windshield of a car fog up? – How do you de-fog it? Is it better to blow hot air or cold air? Why? • Why do you feel dry in a heated room? – Is the moisture content of hot air lower than that of cold air? • How does a fan provide relief from sweating? • How does an air conditioner provide relief from sweating? • When does a soda can “sweat”? • When and why do we “see” our breath? • Do sailboats perform better at high or low relative humidity? Key factors: Temperature, Pressure, and Moisture Content of Air 4 Do Sailboats Perform Better at low or High RH? • Does dry air or moist air provide more thrust against the sail? • Which is denser – humid air or dry air? – Avogadro’s law: At the same temperature and pressure, the no. -
Cryogenicscryogenics Forfor Particleparticle Acceleratorsaccelerators Ph
CryogenicsCryogenics forfor particleparticle acceleratorsaccelerators Ph. Lebrun CAS Course in General Accelerator Physics Divonne-les-Bains, 23-27 February 2009 Contents • Low temperatures and liquefied gases • Cryogenics in accelerators • Properties of fluids • Heat transfer & thermal insulation • Cryogenic distribution & cooling schemes • Refrigeration & liquefaction Contents • Low temperatures and liquefied gases ••• CryogenicsCryogenicsCryogenics ininin acceleratorsacceleratorsaccelerators ••• PropertiesPropertiesProperties ofofof fluidsfluidsfluids ••• HeatHeatHeat transfertransfertransfer &&& thermalthermalthermal insulationinsulationinsulation ••• CryogenicCryogenicCryogenic distributiondistributiondistribution &&& coolingcoolingcooling schemesschemesschemes ••• RefrigerationRefrigerationRefrigeration &&& liquefactionliquefactionliquefaction • cryogenics, that branch of physics which deals with the production of very low temperatures and their effects on matter Oxford English Dictionary 2nd edition, Oxford University Press (1989) • cryogenics, the science and technology of temperatures below 120 K New International Dictionary of Refrigeration 3rd edition, IIF-IIR Paris (1975) Characteristic temperatures of cryogens Triple point Normal boiling Critical Cryogen [K] point [K] point [K] Methane 90.7 111.6 190.5 Oxygen 54.4 90.2 154.6 Argon 83.8 87.3 150.9 Nitrogen 63.1 77.3 126.2 Neon 24.6 27.1 44.4 Hydrogen 13.8 20.4 33.2 Helium 2.2 (*) 4.2 5.2 (*): λ Point Densification, liquefaction & separation of gases LNG Rocket fuels LIN & LOX 130 000 m3 LNG carrier with double hull Ariane 5 25 t LHY, 130 t LOX Air separation by cryogenic distillation Up to 4500 t/day LOX What is a low temperature? • The entropy of a thermodynamical system in a macrostate corresponding to a multiplicity W of microstates is S = kB ln W • Adding reversibly heat dQ to the system results in a change of its entropy dS with a proportionality factor T T = dQ/dS ⇒ high temperature: heating produces small entropy change ⇒ low temperature: heating produces large entropy change L. -
Quantitation of Hydrocarbons in Vehicle Exhaust and Ambient Air
QUANTITATION OF HYDROCARBONS IN VEHICLE EXHAUST AND AMBIENT AIR by Randall Bramston-Cook Lotus Consulting 5781 Campo Walk, Long Beach, California 90803 Presented at EPA Measurement of Toxic and Related Air Pollutants Conference, Cary, North Caolina, September 1, 1998 Copyright 1998 Lotus Flower, Inc. QUANTITATION OF HYDROCARBONS IN VEHICLE EXHAUST AND AMBIENT AIR Randall Bramston-Cook Lotus Consulting 5781 Campo Walk, Long Beach, California 90803 ABSTRACT Ironically, one of the most complex analyses in gas chromatography involves the simplest computation to generate concentrations. The difficult determination of hydrocarbons in vehicle exhaust and ambient air involves separation of over 200 compounds, requires cryogenic concentration to bring expected concentrations into a detectable range, and mandates usage of multiple columns and intricate valving. Yet, quantitation of these hydrocarbons can be calibrated with only one or two component standards and a simple mathematical operation. Requirements for meeting this goal include: (1) even detector responses for all hydrocarbons from ethane to n-tridecane (including olefins and aromatics), (2) accurate and reproducible measure of the sample injection volumes, (3) maximizing trap, column and detector performances, and (4) minimizing sample carry-over. Importance of these factors and how they can be implemented in routine measurements are presented with examples from vehicle exhaust and ambient air analyses. TEXT Hydrocarbons remain a major pollutant in our atmosphere. Much of the problem generated is from incomplete combustion and unburned fuel in vehicle exhaust. Accurate measure of atmospheric and exhaust levels for hydrocarbons is on-going in many facilities in the world. This analysis is undoubtedly one of the most complex in chromatography due to large number of individual hydrocarbon components found, the low levels required to be measured, and high concentrations of potential inferences to the measuring process. -
Thermal Energy: Using Water to Heat a School
Thermal Energy: Using Water to Heat a School Investigation Notebook NYC Edition © 2018 by The Regents of the University of California. All rights reserved. No part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy, recording, or any information storage or retrieval system, without permission in writing from the publisher. Teachers purchasing this Investigation Notebook as part of a kit may reproduce the book herein in sufficient quantities for classroom use only and not for resale. These materials are based upon work partially supported by the National Science Foundation under grant numbers DRL-1119584, DRL-1417939, ESI-0242733, ESI-0628272, ESI-0822119. The Federal Government has certain rights in this material. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the author(s) and do not necessarily reflect the views of the National Science Foundation. These materials are based upon work partially supported by the Institute of Education Sciences, U.S. Department of Education, through Grant R305A130610 to The Regents of the University of California. The opinions expressed are those of the authors and do not represent views of the Institute or the U.S. Department of Education. Developed by the Learning Design Group at the University of California, Berkeley’s Lawrence Hall of Science. Amplify. 55 Washington Street, Suite 800 Brooklyn, NY 11201 1-800-823-1969 www.amplify.com Thermal Energy: Using Water to Heat a School -
Thermal Profiling of Residential Energy Consumption
1 Thermal profiling of residential energy consumption Adrian Albert and Ram Rajagopal Abstract—Demand Response (DR) programs aim to dynami- the thermal mass of the premise may act as “thermal bat- cally match consumption on the grid with available supply in tery”. Affecting the thermally-sensitive load may be typically real-time. Understanding the patterns in demand of individuals achieved through direct load control of the HVAC system (e.g., is now being facilitated by granular consumption data collected load curtailment or automatic adjustment of the thermostat via smart meter sensors that power utility companies have rolled setpoint), through adjustable rates (e.g., critical peak pricing), out at scale. In this paper we propose a dynamic model that uses or through incentive schemes [4], [5]. hourly electricity and weather readings to characterize residential users’ thermally-sensitive consumption. From this model we Here we propose a simple model of consumption for a extract useful benchmarks to build profiles of individual users residential premise that is driven by unobserved “occupancy for use with DR programs that focus on temperature-dependent states” that have different responses to ambient weather. These consumption such as air conditioning or heating. We present are consumption regimes of a given household that depend on example profiles generated using our model on real consumers, lifestyle (work schedule, familial composition etc.), premise and show its performance on a large sample of residential characteristics (heating/cooling mass, square footage etc.), users. We then compute metrics that allow us to segment the appliance stock, and weather patterns. It is a daunting task population dynamically for the purpose of a thermally-motivated to disentangle how much energy each of these components DR program. -
Introducing Electric Thermal Energy Storage (ETES) – Putting Gigawatt Hours of Energy at Your Command
Same forces. New rules. Introducing Electric Thermal Energy Storage (ETES) – putting gigawatt hours of energy at your command. Impossible is just another word for never done before. 100% renewables is said to be impossible. As were the first flight, space travel, the internet … Now here is something that makes a complete energy transition possible: Electric Thermal Energy Storage (ETES). A proven energy storage solution that is inexpensive, built with 80% off-the-shelf components, and scalable to several GWh. No need to explain that ETES is a giant step – for SGRE and for the energy industry. While the forces of nature remain the same, Electric Thermal Energy Storage has launched a new era. Find out how it will boost the energy transition and how new players, energy-intensive companies and even conventional power plants will profit from it. Or, in short: time for new rules. Welcome TiteltextRule #1: Power in. Power out. ETES is technology that can be charged with electricity or directly with heat and which then releases heat that, in return, can generate electricity. Unlike other storage technologies, it is made of rocks absorbing heat. This makes ETES very sustainable in design and the first gigawatt-hour scale energy storage that can be built almost anywhere – limiting its size and use only to your imagination. Flexible scalability of charging power, discharging power and storage capacity. Proven, reliable technology – discharging technology used for more than a 100 years. Cost-competitive, GWh scale, multiple revenue streams. ETES technology TiteltextRule #2: If it works for you, it works for all. ETES solutions basically prolong the availability of ETES and all of its components are fully scalable energy that otherwise would be “wasted“. -
Measurements of Higher Alkanes Using NO Chemical Ionization in PTR-Tof-MS
Atmos. Chem. Phys., 20, 14123–14138, 2020 https://doi.org/10.5194/acp-20-14123-2020 © Author(s) 2020. This work is distributed under the Creative Commons Attribution 4.0 License. Measurements of higher alkanes using NOC chemical ionization in PTR-ToF-MS: important contributions of higher alkanes to secondary organic aerosols in China Chaomin Wang1,2, Bin Yuan1,2, Caihong Wu1,2, Sihang Wang1,2, Jipeng Qi1,2, Baolin Wang3, Zelong Wang1,2, Weiwei Hu4, Wei Chen4, Chenshuo Ye5, Wenjie Wang5, Yele Sun6, Chen Wang3, Shan Huang1,2, Wei Song4, Xinming Wang4, Suxia Yang1,2, Shenyang Zhang1,2, Wanyun Xu7, Nan Ma1,2, Zhanyi Zhang1,2, Bin Jiang1,2, Hang Su8, Yafang Cheng8, Xuemei Wang1,2, and Min Shao1,2 1Institute for Environmental and Climate Research, Jinan University, 511443 Guangzhou, China 2Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, 511443 Guangzhou, China 3School of Environmental Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), 250353 Jinan, China 4State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 510640 Guangzhou, China 5State Joint Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, 100871 Beijing, China 6State Key Laboratory of Atmospheric Boundary Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese