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ELECTROCHEMISTRY ACCESSORIES CATALOG

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BATTERY HOLDERS

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MEMBRANE FOR FUEL CELL

CONNECTION ACCESSORIES CONTENTS

Bio-Logic SAS (founded in 1983) is located near Grenoble in the French Alps. We design and manufacture high performance, research laboratory instruments for electrochemistry and fuel cell testing. Bio-Logic’s product range is based on a modular and ﬂexible design. We offer potentiostat workstations from single channel up to 16 channel systems, integrating EIS capability and high current boosters.

2 ELECTROCHEMISTRY ACCESSORIES CONTENTS BioLogic Analytical cell kit Small volume cells 4 Large volume cells 6 Flow cells 7 Interdigitated array (IDA) electrodes 8 modular Ring disk type electrodes 8 Screen printed electrodes 9 Corrosion cell kit Standard corrosion cells 10 Avesta cell 11 Flat cells, 1 to 10 cm² sample area 12 Galvanic cells, 1 to 10 cm² sample area 13 potentio Plate material evaluating cell, up to 1 cm² sample area 13 Glassware Small volume cell vials, 1 to 100 mL 14 Big volume cell vials, 100 to 2.000 mL 14 galvano Small size bridge tubes 16 Bridge tubes for corrosion cells 16 Purge tubes for corrosion cells 16 Bridge tubes for analytical cells 17 Purge tubes for analytical cells 17 Bridge tubes with ceramic junction 17 Electrodes Working electrodes 18 stats Reference electrodes 20 Counter electrodes 24 Rotating ring disk electrode Rotating ring disk electrode RRDE-3A 26 Working electrode tips 27 Spectroelectrochemistry current Three utilization modes & two spectrometers 28 Static experiment 30 Flow experiment 31 Quartz Crystal Analyzer EQCM 32 biosensor QCM 34 Battery accessories Battery holder 36 Coin cell holder 36 Sense adapter module SAM-50 36 Faraday cages 37 Fuel cell Soft Membrane electrode assemblies (MEA) 38 Semi-automatic ﬁlling kit 39 Educational kit 39 Connection accessories Multi-electrode investigations cables 40 Speciﬁc cables 41 Test boxes 42 External device connection 42 Connectors 43 Miscellaneous 43

3 ANALYTICAL CELL KIT AnalyticalAnalytical

Small volume cells

Each voltammetry cell is designed for a specific application (specific working electrode, volume of solution, oxygen free condition...). For example, for voltammetry investigations using standard working electrode with an outer diameter (OD) of 6 mm the fixed configuration of SVC-3 kit is recommended. For application requiring other working electrode shape, SVC-2 is more suitable. If only a small amount of the electroactive compound is available, SVC-2 in the microvolume mode is recommended. SVC-2 modularity: microvolume mode oxygen free mode

Small amount of solution For electrode For electrode For microelectrode (200 µL in the sample holder) with OD of 10 mm with OD of 6 mm with OD of 4 mm

Platinum cyclic voltammetry

4 ELECTROCHEMISTRY ACCESSORIES cell kit

SVC-2 SVC-3 VC-4 Bulk electrolysis cell Modular For a volume For a volume For a volume of 100 mL. of 5 to 20 mL, only of 1 to 3 mL, only for working electrode for working electrode with OD of 6 mm. with OD of 6 mm.

Catalog No. Catalog No. Catalog No. Catalog No. A-012668 A-012669 A-011224 A-001197

Contents Sample vial A-001056 20 mL, qty 7 A-001056 20 mL, qty 7 A-011504 5 mL, qty 7 A-012632 100 mL, qty 1 Counter electrode A-002222 5.7 cm A-002233 5 cm A-002222 5.7 cm A-002234 23 cm Teﬂon cap A-012670 A-012671 A-011226 A-012551 Purge tube (ETFE), 1 m A-010537 A-010537 A-010537 A-010537 Additional items adapter 10 to 6 A-011227 cell holder A-010530 porous carbon electrode A-001198 Lid for CE A-001196 chamber for CE A-001236 O-ring A-009131 port plug A-000178 stirrer bar

Optional Sample holder A-012177 9.0 mm, qty 2 A-012176 6.0 mm, qty 2 Cell holder A-001209 for 20 mL Working electrode see page 14 see page 14 see page 14 Reference electrode see page 16 see page 16 see page 16 see page 16 Teﬂon cap 10.2 mm 6.2 mm 1.65 mm 1.6 mm 1.6 mm 6.3 mm 6.2 mm 1.6 mm

Note that a complete analytical special kit SK-2 (A-012763) is also proposed, but the reference electrode has to be Cell geometry purchased separately. The geometry of the cell should be This kit includes: optimized to reduce the ohmic drop. SVC-3 kit (A-012669), Working and reference electrodes PK-3 polishing kit (A-011975), have to be close to each other. one glassy carbon electrode, OD 6.0 mm, ID 3.0 mm (A-002012), The surface area of the counter one platinum electrode, OD 6.0 mm, ID 1.6 mm (A-002013). electrode has to be higher than the surface area of the working electrode.

OD: outer diameter ID: inner diameter 5 ANALYTICAL CELL KIT AnalyticalAnalytical

Large volume cells

This analytical cell with volumes from 50-200 mL is well adapted for macro electrochemistry applications. Two packages are offered: the standard analytical cell kit the complete analytical cell kit (which allows temperature control and gas purging).

Standard analytical Complete analytical Catalog No. cell kit (80 mL) cell kit (80 mL) EL-ELECTRO-1 EL-ELECTRO-2 Glass cell 80 mL EL-A-001 Double jacketed glass cell 80 mL EL-A-002 Teﬂon cap 5 holes EL-A-003 Teﬂon ring (silicon encapsulated, OD 10.2 cm) EL-A-004 Cell collar with clamp EL-A-005 EL-A-005 Double purge tube EL-A-006 Bridge tube for reference electrode with OD of 6 mm EL-A-008 EL-A-003 Pt counter electrode EL-A-009 Purge tube EL-A-016 Reference electrode A-002056 Double nut 25 mm and 12 mm diameter EL-A-011 Telescopic cell stand EL-A-012

EL-A-002 EL-A-004 Options Electrode bridge extension for electroanalytical cell EL-A-022 Bridge tube for reference electrode of OD 8 mm EL-A-017 PT100 probe (indicate connector type) EL-C-014 EL-A-009 Magnetic stirrer & heater, 220 V EL-C-015A without PT100 probe 110 V EL-C-015B Aluminum base holder for magnetic stirrer EL-C-018 Other volumes are available on request.

EL-A-012 EL-A-008

EL-A-022

6 ELECTROCHEMISTRY ACCESSORIES cell kit

Flow cells Cross flow cell Radial flow cell Catalog No. Catalog No. Cross flow cell A-012798 Radial flow cell A-012799 Gasket, working and reference electrodes are sold separately Gasket, working and reference electrodes are sold separately

Schematic diagram Schematic diagram

OUTLET ﬂow channel INLET OUTLET OUTLET INLET

gasket detector gasket detector

Catalog No. Item Description Cross flow A-001000 glassy carbon electrode Ø 3 mm x 2 (dual type), size 25 x 25 mm A-001002 gold electrode Ø 3 mm x 2 (dual type), size 25 x 25 mm A-001012 platinum electrode Ø 3 mm x 2 (dual type), size 25 x 25 mm Single/radial flow A-001008 silver electrode Ø 3 mm x 2 (dual type), size 25 x 25 mm A-001004 carbon paste electrode Ø 3 mm x 2 (dual type), size 25 x 25 mm A-001009 nickel electrode Ø 3 mm x 2 (dual type), size 25 x 25 mm A-001006 glassy carbon/gold electrode Ø 3 mm x 2 (dual type), size 25 x 25 mm A-012583 glassy carbon/platinum electrode Ø 3 mm x 2 (dual type), size 25 x 25 mm A-001046 TG-2M teflon gasket (4 pieces) film thickness 12 µm A-001047 TG-5M teflon gasket (4 pieces) film thickness 25 µm Dual, series/cross flow A-001048 TG-6M teflon gasket (4 pieces) film thickness 50 µm A-001049 TG-8M teflon gasket (4 pieces) film thickness 100 µm A-001092 TG-11M silicon gasket (4 pieces) film thickness 500 µm A-001093 TG-12M silicon gasket (4 pieces) film thickness 1 000 µm A-001032 cross flow cell block material PEEK Radial flow A-001016 glassy carbon electrode Ø 6 mm (single type), size 25 x 25 mm Dual, parallel/cross flow A-012124 glassy carbon electrode Ø 3 mm (single type), size 25 x 25 mm A-009908 platinum electrode Ø 3 mm (single type), size 25 x 25 mm A-011155 gold electrode Ø 3 mm (single type), size 25 x 25 mm A-000999 PFCE carbon electrode Ø 3 mm (single type), size 25 x 25 mm A-010251 carbon paste electrode Ø 3 mm (single type), size 25 x 25 mm A-001146 TG-2MR teflon gasket (4 pieces) film thickness 12 µm A-001147 TG-5MR teflon gasket (4 pieces) film thickness 25 µm A-001148 TG-6MR teflon gasket (4 pieces) film thickness 50 µm A-012802 TG-8MR teflon gasket (4 pieces) film thickness 100 µm A-001192 TG-11MR teflon gasket (4 pieces) film thickness 500 µm A-001193 TG-12MR teflon gasket (4 pieces) film thickness 1 000 µm A-001031 radial flow cell block material PEEK Cross/radial A-012169 RE-3V Ag/AgCl reference electrode screw type size Ø 10 x 48 mm A-001531 1/16" PEEK tube ID 0.25 mm, length 3.0 m A-004130 dynaseal PEEK fingertight (10 pieces) screw for pipe connecting integrated 1/16"

7 ANALYTICAL CELL KIT AnalyticalAnalytical

Interdigitated array (IDA) electrodes

2 3 µm

Counter electrode Passivation membrane 20 Reference electrode 10 µm Working electrode #1 Working electrode #2 Quartz plate, thickness = 0.5 mm 12 Catalog No. Width Interval Length Number of feet Film thickness IDA electrode Au A-012257 2 µm 2 µm 2 mm 65 pairs 90 nm Pt A-012258 2 µm 2 µm 2 mm 65 pairs 90 nm Au without passivation membrane A-012261 2 µm 2 µm 2 mm 65 pairs 90 nm Pt without passivation membrane A-012264 2 µm 2 µm 2 mm 65 pairs 90 nm Au A-012129 3 µm 3 µm 2 mm 65 pairs 90 nm Pt A-012130 3 µm 3 µm 2 mm 65 pairs 90 nm Au without passivation membrane A-012260 3 µm 3 µm 2 mm 65 pairs 90 nm Pt without passivation membrane A-012263 3 µm 3 µm 2 mm 65 pairs 90 nm Au A-012125 10 µm 5 µm 2 mm 65 pairs 90 nm Pt A-012126 10 µm 5 µm 2 mm 65 pairs 90 nm ITO A-012128 10 µm 5 µm 2 mm 65 pairs 100 ± 20 nm carbon A-012127 10 µm 5 µm 2 mm 65 pairs 1200 ± 100 nm Au without passivation membrane A-012259 10 µm 5 µm 2 mm 65 pairs 90 nm Pt without passivation membrane A-012262 10 µm 5 µm 2 mm 65 pairs 90 nm ITO without passivation membrane A-012265 10 µm 5 µm 2 mm 65 pairs 100 ± 200 nm carbon without passivation membrane A-012266 10 µm 5 µm 2 mm 65 pairs 1200 ± 100 nm

Options Cable kit for IDA electrode A-011066 Ag/AgCl ink for reference electrode (2.0 mL) A-011464

Ring disk type electrodes Catalog No. Ring OD Ring ID Disk Gold ring disk electrode (3 pieces) A-002081 6 mm 4 mm 3 mm Platinum ring disk electrode (3 pieces) A-002082 6 mm 4 mm 3 mm Carbon ring disk electrode (3 pieces) A-002083 6 mm 4 mm 3 mm

8 ELECTROCHEMISTRY ACCESSORIES cell kit

Screen Printed Electrodes

Screen Printed Electrode (SPE) are low cost and disposable. They include one reference electrode, one counter electrode and one or several working electrodes according to the design needed. The working electrode can be made of glassy carbon, platinum, gold… The SPE allows user to work with a small amount of solution (25-100 µL). A two–electrodes set-up is used for multi working electrode Counter electrode SPE with one shared reference electrode and one shared Reference electrode counter electrode. Working electrode

Note with BioLogic’s multichannel potentiostats, it is possible to run simultaneously investigation on each Three-electrode sensor Array of 16 working electrodes working electrode of the array (up to 16).

Catalog No. Working electrode Counter electrode Reference electrode Substrat 3-electrode Ø of WE: 2 mm G-GGA graphite graphite Ag/AgCl alumina size of RE: 0.5 x 1 mm G-GGP graphite graphite Ag/AgCl PVC ratio CE/WE surface area: 4/1 G-PTGA Pt graphite Ag/AgCl alumina overall dimension: 50 x 10 mm G-PTGP Pt graphite Ag/AgCl PVC 50 pieces G-AUGA Au graphite Ag/AgCl alumina G-AUGP Au graphite Ag/AgCl PVC Array of 16 WE Ø of WE: 0.8 mm G-A-GA graphite Ag/AgCl alumina size of pseudo-RE: 20 x 1 mm G-A-GP graphite Ag/AgCl PVC overall dimension: 45 x 19 mm G-A-PTA Pt Ag/AgCl alumina 5 pieces G-A-PTP Pt Ag/AgCl PVC G-A-AUA Au Ag/AgCl alumina G-A-AUP Au Ag/AgCl PVC

Dimensions in mm 9 CORROSION CELL KIT CorrosionCorrosion

Standard corrosion cells

For corrosion applications, two packages for large volume i.e. ~1 L are available: basic corrosion cell kit, complete corrosion cell kit (allows temperature control and includes sample holder and cell stand).

EL-C-005 Basic corrosion cell kit Complete corrosion Catalog No. EL-CORR-1 cell kit EL-CORR-2 EL-C-003 Glass cell 1L EL-C-001 Double jacketed glass cell 1L EL-C-002 Teﬂon cap EL-C-003 Teﬂon ring (silicon encapsulated), OD 10.2 cm EL-C-004 Cell Collar with clamp EL-C-005 Double purge tube EL-C-006 Graphite counter electrode rod (2 pieces) EL-C-009 EL-C-002 EL-C-004 Double nut 25 mm and 12 mm diameter EL-C-011 Telescopic cell stand EL-C-012 Sample holder 1 cm2 092-C-013 Purge tube EL-C-016 Bridge tube for 8 mm diameter reference electrode EL-C-017 Calomel reference electrode R-XR110 EL-C-013 length 80 mm, OD 8 mm screw cap Cable connection for screw cap 10 cm, 2 mm banana plug R-A94L111 12 mm OD conical rings for reference electrode of 8 mm R-X31M012

Options Bridge tube for 6 mm diameter reference electrode EL-C-008 PT100 probe (indicate connector type) EL-C-014 Magnetic stirrer & heater, without PT100 probe EL-C-015A (220 V) EL-C-015B (110 V) Aluminum base holder for magnetic stirrer EL-C-018

EL-C-017 EL-C-009 Other volumes are available on request.

10 ELECTROCHEMISTRY ACCESSORIES cell kit

Avesta cell

Avesta cell is an electrochemical cell developed for pitting corrosion testing (ASTM G150). It is designed to avoid microcrevice corrosion formed between the working electrode and the gasket at the bottom aperture of the cell. A filter paper ring placed between the sample and the gasket is flooded by distilled water in order to eliminate crevice corrosion. The water flow is controlled by a peristaltic pump (EL-AV-008) which delivers 0.5 to 5 mL/h.

Filter paper ring External gasket Internal gasket

INLET Sample Copper connector

Principle of Avesta cell

Catalog No. Avesta cell kit EL-AV-001

Contents Double jacketed cell glass 250 mL EL-AV-002 Teﬂon cap 5 holes EL-AV-003 O-ring PTFE silcone encapsulated El-AV-004 Cell collar with clamp EL-C-005 Double purge tube EL-AV-006 Filter paper ring (100 units) EL-AV-007 Graphite counter electrode rods (2 pieces) EL-C-009 Bridge tube for RE 6 mm EL-C-010 Double nut EL-C-011 Telescopic cell stand EL-AV-012 Skeleton EL-AV-015

Options Peristaltic pump for low ﬂow EL-AV-008 Bridge tube for reference electrode EL-AV-013 with OD of 8 mm Single purge tube EL-AV-014 Temperature probe PT 100 EL-C-014

11 CORROSION CELL KIT CorrosionCorrosion

Flat cells, 1 to 10 cm² sample area

This cell with a volume of 250 mL is adapted to perform AC or DC experiments on flat specimen of 1 cm2 or 10 cm2 area. This cell has a double jacket for temperature control and three holes for reference electrode, purge tube and temperature probe with inner diameter of 17.6 mm and the 2 others of 8.3 mm. Thanks to its design, any sample with a thickness Flat cell 1 cm2 Flat cell 10 cm2 Catalog No. inferior to 1 cm fits in the holder. EL-FLAT EL-FLAT-2 Complete cell for flat sample 1 cm2 EL-FLAT-3 Complete cell for flat sample 10 cm2 EL-FLAT-4 Bridge tube EL-F-004 Platinum gauze counter electrode A-702439 SCE reference electrode A-002056

Investigation in agressive medias If the experiment is performed in more agressive medias such as ﬂuorhydric acid media, it is possible to get a body of the ﬂat cell in PVDF instead of glass.

Fluorhydric Sulfuric Phosphoric Hydrochloric Nitric Perchlorique Sodium Potassium acid acid acid acid acid acid hydroxide hydroxide 48% 98% 85% 35% 70% 50% concentred Temperature 20° C 50° C 20° C 50° C 20° C 50° C 20° C 50° C 20° C 50° C 20° C 50° C 20° C 50° C 20° C 50° C Teﬂon PVDF* Borosilicated glass excellent good Catalog No.

not recommended PVDF* body EL-F-PVDF not compatible EPDM O-ring kit for 1 cm2 EL-SEAL-1 for 10 cm2 EL-SEAL-10 Teﬂon O-ring kit for 1 cm2 EL-SEAL-T1 for 10 cm2 EL-SEAL-T10 The O-ring kits include 4 O-rings for the glassware side * Polyvinylideneﬂuoride and 10 O-rings for the sample side

12 ELECTROCHEMISTRY ACCESSORIES cell kit

Galvanic cells, 1 to 10 cm² sample area

Thanks to the modular design of the ﬂat cell, it is possible to set two different materials at each end of the cell. The surface area may be 1 or 10 cm2.

Catalog No. Galvanic cell 1 cm2 EL-FLAT-3 + 092-FLAT/1 10 cm2 EL-FLAT-4 + 092-FLAT/10

092-FLAT/10

Plate material evaluating cell, up to 1 cm² sample area

This quite handy cell was developed to evaluate a plate material such as a metal, semi-conducting plate... The sample plate is sandwiched between the two cell blocks.

Catalog No. Plate material evaluating cell A-011951 contents: teﬂon cell [body &base] - O-ring - screw 20 mm - purging tube, 1 m - Pt counter electrode A-002222

13 GLASSWARE GlasswareGlassware

To complete a kit, the cell vials are also offered 18 separately. Note that other volumes are available on request. 50

30 Small volume cell vials, 1 to 100 mL ID 15.6 ID 25.6 A-011504 A-011506

Catalog No. Volume OD ID Height Qty Purpose Small sample vial A-011504 5 mL 18 mm 15.6 mm 30 mm 10 VC-4 volume A-001056 20 mL 28 mm 25.6 mm 50 mm 10 SVC-2, SVC-3 cell vials A-012632 100 mL 50 mm 46.4 mm 50 mm 1 RRDE-3A, bulk electrolysis water jacketed-glass vial A-012672 5 mL 40 mm 15.6 mm 40 mm 1 VC-4 A-001051 20 mL 55 mm 25.6 mm 50 mm 1 SVC-2, SVC-3 A-001209 A-012652 100 mL 70 mm 46.4 mm 80 mm 1 RRDE-3A, bulk electrolysis cell holder cell holder for 20 mL vial A-001209 1 SVC-2, SVC-3 for A-011506 Big sample vial EL-A-001 80 mL 90 mm 62 mm 80 mm 1 EL-ELECTRO-1 volume EL-C-001 1 000 mL 120 mm 90 mm 175 mm 1 EL-CORR-1 cell vials Water jacketed-glass vial EL-A-002 80 mL 90 mm 62 mm 85 mm 1 EL-ELECTRO-2 EL-C-002 1 000 mL 120 mm 90 mm 200 mm 1 EL-CORR-2 cell holder for king size vial (1 L) EL-C-019 1 EL-CORR-1

Big volume cell vials, 100 to 2,000 mL 90 62 90 62

85 80

EL-A-001 EL-A-002

14 ELECTROCHEMISTRY ACCESSORIES cell vials

70 28 45

55 25.6 40 15,6

40 50

ID 46.4 A-012672 A-001051 A-012652 A-012632 120 90

120 90

200

175

EL-C-001

EL-C-002

EL-C-019, Dimensions in mm cell holder for EL-C-001

15 GLASSWARE TubesBridge tubes

The tolerance of each dimension is Bridge tubes for Purge tubes for approximately +/- 0.5 mm. corrosion cells corrosion cells The inner diameter is the size at the top side. EL-C-008 EL-C-017 EL-F-004 EL-F-004B EL-C-016 EL-C-006 Small size 10 bridge tubes 200

A-012176 A-012177 100

120

65 65

140 220 6 9 10 250 60

10 60

10 10

16 ELECTROCHEMISTRY ACCESSORIES purge tubes

Bridge tubes for Purge tubes for Bridge tubes with analytical cells analytical cells ceramic junction

160 EL-A-017 EL-A-008 EL-A-016 EL-A-006 R-AL100 R-AL110 R-AL120

138

165 10 200

250

10 100

10 Ref. electrode Catalog No. OD Height Qty Purpose Small size Ø 6 mm A-012176 6 mm 68 mm 2, 22 for A-012306 SVC-2, SVC-3 bridge tube Ø 9 mm A-012177 9 mm 68 mm 2, 22 for A-012307 SVC-2 Bridge tube for Ø 6 mm EL-C-008-C-008 10 mm 250 mm 1 EL-CORR corrosion cells Ø 8 mm EL-C-017 10 mm 250 mm 1 EL-CORR EL-F-004 10 mm 120 mm 1 EL-FLAT EL-F-004B 10 mm 140 mm 1 EL-FLAT Bridge tube for Ø 8 mm EL-A-017 10 mm 165 mm 1 EL-ELECTRO analytical cells Ø 6 mm EL-A-008 10 mm 155 mm 1 EL-ELECTRO Purge tube for single EL-A-016 10 mm 200 mm 1 EL-ELECTRO analytical cells double EL-A-006 10 mm 220 mm 1 EL-ELECTRO Purge tube for single EL-C-016 10 mm 160 mm 1 EL-CORR corrosion cells double EL-C-006 10 mm 200 mm 1 EL-CORR Bridge tube short R-AL100 12 mm 70 mm 1 with ceramic standard R-AL110 8 mm 250 mm 1 junction with reverse sleeve (non aqueous) R-AL210 8 mm 138 mm 1 standard R-AL120 8 mm 138 mm 1 Option: repair kit for vycor-based bridge tubes is also offered (A-012796).

Dimensions in mm 17 ELECTRODES ElectrodesWorking

Working Long type Standard type Small type Micro type Gauze type electrodes 15 15 15

To address every application, a wide range of working 23 electrodes (WE) is offered with a diameter going from 7 µm up to 6 mm and 70 built with different materials. 10 55 55

110

6 4 4 35

Working electrode maintenance To refresh the surface of the electrode we recommend to polish the electrode after 6 each measurement.

Working electrodes maintenance Catalog No. PK-3 electrode polishing kit A-011975 Contents 0.05 µm polishing alumina (20 mL) A-001050 1 µm polishing diamond (10 mL) A-002054 Glass plate (1 piece) A-002249 Alumina polishing pad (10 pieces) Diamond polishing pad (10 pieces) Replacement item Alumina polishing pad (20 pieces) A-001040 Diamond polishing pad (20 pieces) A-001041 Emery paper UF800 (20 pieces) A-012611 Coarse polishing pad (20 pieces) A-001042

18 ELECTROCHEMISTRY ACCESSORIES electrodes Pt pH =0 pH = 7 pH = 14 TBAP/ACN TBAP/DMF C 1 M HCIO4 0.1 M KCI V vs SCE -3 -2 -1 0 1 2 3 Electroactivity window of the working electrodes in different media

Catalog No. Isolation Type OD Electrode size Carbon LGCE glassy carbon electrode A-012744 PEEK long 6 mm 3 mm GCE glassy carbon electrode A-002417 PEEK standard 10 mm 5 mm A-002012 PEEK standard 6 mm 3 mm A-012297 PEEK standard 6 mm 1.6 mm A-002411 PEEK standard 6 mm 1 mm SGCE glassy carbon electrode A-012298 PEEK small 3 mm 1.6 mm A-002412 PEEK small 3 mm 1 mm MCE micro carbon ﬁber electrode A-002002 glass micro 4 mm 33 µm A-002007 glass micro 4 mm 7 µm Pyrolytic graphite electrode Basal Plane A-002252 PEEK standard 6 mm 3 mm Edge Plane A-002253 PEEK standard 6 mm 3 mm PFCE carbon electrode A-002408 PEEK standard 6 mm 3 mm A-002409 PEEK standard 6 mm 1 mm SPFCE carbon electrode A-011854 PEEK small 3 mm 1 mm Platinum Platinum gauze electrode A-002250 PEEK gauze 80 mesh 25 x 35 mm LPTE platinum electrode A-012745 PEEK long 6 mm 3 mm PTE platinum electrode A-002420 PEEK standard 10 mm 5 mm A-002422 PEEK standard 6 mm 3 mm A-002013 PEEK standard 6 mm 1.6 mm SPTE platinum electrode A-002313 PEEK small 3 mm 1.6 mm MPTE micro Platinum electrode A-002009 glass micro 4 mm 100 µm A-002003 glass micro 4 mm 25 µm A-002015 glass micro 4 mm 15 µm A-002005 glass micro 4 mm 10 µm Gold Gold gauze electrode A-002251 PEEK gauze 100 mesh 25 x 35 mm LAUE gold electrode A-012746 PEEK long 6 mm 3 mm AUE gold electrode A-002418 PEEK standard 10 mm 5 mm A-002421 PEEK standard 6 mm 3 mm A-002014 PEEK standard 6 mm 1.6 mm SAUE gold electrode A-002314 PEEK small 3 mm 1.6 mm MAUE micro gold electrode A-002010 glass micro 4 mm 100 µm A-002004 glass micro 4 mm 25 µm A-002006 glass micro 4 mm 10 µm Silver AGE silver electrode A-002416 PEEK standard 10 mm 5 mm A-002419 PEEK standard 6 mm 3 mm A-002011 PEEK standard 6 mm 1.6 mm SAGE silver electrode A-002315 PEEK small 3 mm 1.6 mm Palladium PDE palladium electrode A-002019 PEEK standard 6 mm 1.6 mm SPDE palladium electrode A-002319 PEEK small 3 mm 1.6 mm Nickel NIE nickel electrode A-002016 PEEK standard 6 mm 1.5 mm MNIE micro nickel electrode A-002273 glass micro 4 mm 100 µm Copper CUE copper electrode A-002017 PEEK standard 6 mm 1.6 mm CUE copper electrode A-012584 PEEK standard 6 mm 3 mm MCUE copper electrode A-002271 glass micro 4 mm 25 µm Iron FEE iron electrode A-002018 PEEK standard 6 mm 1.5 mm FEE iron electrode A-012585 PEEK standard 6 mm 3 mm Carbon paste CPE carbon paste electrode hole depth 4 mm A-002210 PEEK standard 6 mm 3 mm SCPE carbon paste electrode hole depth 4 mm A-002223 PEEK small 3 mm 1.6 mm CPO carbon paste oil base 1 g A-001010

Dimensions in mm 19 ELECTRODES ElectrodesReference

Reference For aqueous media (Ag/AgCl, Hg) electrodes RE-1B RE-1S RE-1C RE-2B RE-2C RE-3V RE-6H

Reference electrodes are divided into two groups 40,5 50 according to the media 45 in which the electrode is 65 immersed (aqueous or 80 organic media). 11 60

Ag/AgCl ink

Catalog No. Junction Electrolyte Purpose RE-1B silver, silver chloride reference electrode A-012167 vycor glass 3 M NaCl SVC-2, SVC-3, VC-4, bulk electrolysis, RRDE-3A, flat cell RE-1S silver, silver chloride reference electrode A-012168 vycor glass 3 M NaCl SECM RE-1C silver, silver chloride reference electrode A-002058 ceramic saturated KCl SVC-2, SVC-3, VC-4, bulk electrolysis, RRDE-3A, flat cell RE-3V silver, silver chloride reference electrode A-012169 vycor glass 3 M NaCl for flow cell spectroelectrochemcial cell screw type, poly acetal resin SEC-3F RE-3VP Ag/AgCl screw type electrode, A-012170 vycor glass 3 M NaCl for flow cell spectroelectrochemcial cell PEEK resin SEC-3F Ag/AgCl ink, 2 mL A-011464 surface resistance: 0.2 Ω/sq/25.4 µm for micro CV cell, IDA measurment viscosity: 50,000 ±10,000 CP @21.1 °C flash point: 82 °C RE-2B calomel reference electrode A-002056 ceramic saturated KCl SVC-2, SVC-3, VC-4, bulk electrolysis, RRDE-3A, flat cell RE-2C Hg2SO4 reference electrode, A-002057 ceramic saturated K2SO4 free from chloride RE-6H Hg/HgO reference electrode kit A-011503 ceramic 1M NaOH for alkaline media available in alkaline solution (mercury solution is not included)

20 ELECTROCHEMISTRY ACCESSORIES electrodes

For non aqueous media (Ag/Ag+) RE-7 RE-7S RE-7V RE-7VP 5,5 5,5 10 10 20 20 35 35 30 30

23 11 11 68 44

RE-7 - Electrolyte RE-7 - Electrolyte RE-7 - Electrolyte RE-7 - Electrolyte solution (3 mL) solution (3 mL) solution (3 mL) solution (3 mL)

To avoid electrolyte leakage or concentration due to evaporation during storage or transport, the electrolyte is separated from the body. This gives the possibility to fill it regularly. Catalog No. Junction Electrolyte Purpose RE-7 non aqueous reference electrode (Ag/Ag+) A-012171 vycor glass Ag/Ag+/ACN*/TBAP** CV RE-7S non aqueous reference electrode (Ag/Ag+) A-012172 vycor glass Ag/Ag+/ACN*/TBAP** SECM RE-7V non aqueous reference electrode (Ag/Ag+) screw type, poly acetal resin A-012173 vycor glass Ag/Ag+/ACN*/TBAP** flow cell RE-7VP non aqueous reference electrode (Ag/Ag+) screw type, PEEK resin A-012174 vycor glass Ag/Ag+/ACN*/TBAP** flow cell * Acetonitrile ** Tetra Butyl Ammonium Perchlorate

0.930 V Hg/HgO/ NaOH (0.1 M)

0.650 V Hg/Hg2SO4 / K2SO4 (sat) 0.624 V Fc/Fc+ TBAP (0.1M) ACN 0.542 V Ag/Ag+ TBAP (0.1M) ACN

0.241 V Hg/Hg2Cl2 KCl (sat)

0.236 V Hg/Hg2Cl2 NaCl (sat) 0.205 V Ag/AgCl/ KCl (3.5 M) 0.197 V Ag/AgCl/ KCl (sat) 0.194 V Ag/AgCl/ NaCl( sat) 0.000 V NHE Normal Hydrogen Electrode E/V vs NHE at 25°C Potentials of reference electrodes

Dimensions in mm 21 ELECTRODES ElectrodesReference

Reference electrodes

Maintenance of Vycor-based reference electrode Store your reference electrode immersed in the electrolyte When it is not in use, the recommended way to maintain the reference electrode capability and lifetime, is to keep it in a sealed preservative vial with a solution. This storage solution should be identical to the ﬁlling solution ot the reference electrode.

Catalog No. RE-PV preservative vial for reference electrode, 10 mL A- 012108

Contents Teﬂon cap for RE-PV - Screw vial 10 mL -

Option RE-7 electrolyte solution 10 mL A-012549

Replace the vycor when needed Yellowish discoloration indicates contamination. This is caused by the adsorption of organic compounds into their pores.

Catalog No. Repair kit for bridge tube: A-012796 - vycor glass rod, Ø 2.85 x 4.0 mm (10 pieces), - heat shrink teﬂon tubing, 150 mm, (1 piece) Heat shrink teﬂon tubing, 100 mm (1 piece) A-012183

A-012177 Prevent contamination To prevent contamination of the reference electrode, a sample holder can be used.

Catalog No. Bridge tube Ø 9.0 mm (2 pieces) A-012177 65 Bridge tube Ø 9.0 mm (22 pieces) A-012307

22 ELECTROCHEMISTRY ACCESSORIES electrodes

King size electrodes R-XR300 R-XR820 R-REF921 R-XR110 R-REF621 R-XR200 R-XR400

103 103 120 120

160

Catalog No. Junction Electrolyte Purpose Ag/AgCl reference electrode length 120 mm, OD 8 mm R-XR300 ceramic sat KCl CV length 160 mm, OD 8 mm R-XR820 ceramic sat KCl EIS Calomel reference electrode length 103 mm, OD 7,5 mm R-REF921 ceramic LiCl general (non aqueous) length 80 mm, OD 8 mm R-XR110 ceramic Sat KCl CV Hg/Hg2SO4 reference electrode length 103 mm, OD 8 mm R-REF621 ceramic sat K2SO4 chloride free length 120 mm, OD 8 mm R-XR200 ceramic sat K2SO4 CV Hg/HgO reference electrode length 120 mm, OD 8 mm R-XR400 ceramic 0,1M KOH CV

Options Short connection cable for screw cap electrode length 10 cm with 2 mm male banana plug R-A94L111* Long connection cable for screw cap electrode length 1 m with 4 mm banana plug R-C123A* 12 mm OD conical rings for 8 mm OD electrodes (4 pieces) R-X31M012 Bridge tube with ceramic junction length: 70 mm, OD 12 mm R-AL100 length: 250 mm, OD 8 mm R-AL110 with reverse sleeve (non aqueous) length: 138 mm, OD 8 mm R-AL210 length: 138 mm, OD 8 mm R-AL120 * R-A94L111 or R-C123A connectors are strongly recommended to connect these reference electrodes to the potentiostat

Dimensions in mm 23 ELECTRODES ElectrodesCounter

Counter Small size electrodes A-002222 A-002233 A-002234 A-012638 A-012639 A-012198

Catalog No. Length Wire Ø Surf. area Purpose Pt A-002222 5.7 cm 0.5 mm ~ 0.7 cm2 SVC-2, VC-4, plate material evaluating cell A-002233 5 cm 0.5 mm ~ 0.7 cm2 SVC-3 A-002234 23 cm 0.5 mm ~ 3.6 cm2 RRDE-3A, bulk electrolysis, SVC-3 Au A-012638 23 cm 0.5 mm ~ 3.6 cm2 RRDE-3A, bulk electrolysis, SVC-3 Ni A-012639 23 cm 0.5 mm ~ 3.6 cm2 RRDE-3A, bulk electrolysis, SVC-3 Stainless steel A-012198 5 cm 1.5 mm ~ 2.35 cm2 for ﬂow cell Platinum gauze electrode, PEEK 80 mesh A-002250 25 x 35 mm 0.08 mm ~ 1 cm2 Gold gauze electrode, PEEK 100 mesh A-002251 25 x 35 mm 0.07 mm ~ 1 cm2 55 mesh A-002254 40 x 50 mm 0.12 mm ~ 5.1 cm2 Counter electrode selection The counter should not be the limiting factor for the electron transfer, so the surface area of the counter electrode should be higher than the surface area of the working electrode.

24 ELECTROCHEMISTRY ACCESSORIES electrodes

King size A-002250 A-002254 R-XM110 R-XM120 R-XM140 R-XM150

100

10 120

Catalog No. Length OD Wire dimension Platinum electrode for Voltammetry R-XM110 80 mm 8 mm diameter of 1 mm R-XM120 120 mm 8 mm plate 5 x 5 mm R-XM140 120 mm 8 mm plate 8 x 8 mm R-XM150 120 mm 12 mm disk of 10 mm Glassy electrode for Voltammetry R-M291C 103 mm 8 mm rod diameter of 3 mm

Options Short connection cable for screw cap electrode length 10 cm R-A94L111* with 2 mm male banana plug Long connection cable for screw cap electrode length 1 m R-C123A* with 4 mm banana plug 12 mm OD conical rings for 8 mm OD electrodes (4 pieces) R-X31M012 * R-A94L111 or R-C123A connectors are strongly recommended to connect these counter electrodes to the potentiostat

Dimensions in mm 25 ROTATING RING DISK ELECTRODE Rotating Ring disk electrode

Rotating ring disk electrode RRDE-3A

Speciﬁcations

Rotational range 100 - 8,000 rpm Setting resolution 1 rpm Catalog No. Accuracy ‹ 0.1% RRDE-3A rotating ring disk electrode apparatus A-012180 Rotation control type PLL (phase-locked loop) Bandwidth 60 Hz at 3,500 rpm Contents base and 1,000 rpm RRDE-3A glass cell vial 100 mL A-012632 peak-to-peak modulation Spin coating adapter A-012064 Inlet gas pressure 5 PSI Nipple for purge valve A-012065 Temperature 10-50 deg C TYGON tubing, OD1/4 x ID1/8 (1.3 m) A-010058 Power 100-240 VAC, 50/60 Hz Teﬂon cap for RRDE-3A A-012631 Size (W x D x H) 185 x (base: 230, Instruction manual - body: 120) x 400 mm Power cable - Weight 6 kg Accessory Water-jacketed glass cell (100 mL, OD 70 mm, ID 46.4 mm, H 80 mm) A-012652 DB9 cable to control RRDE-3A 092-22/11 Bipotentiostat cable for two standard channels 092-22/12 Working electrodes (page 27), reference electrodes (page 20) and counter electrodes (page 24) have to be purchased separately.

RDE investigations at different rotation speed

26 ELECTROCHEMISTRY ACCESSORIES ring disk electrode

Working electrode tips

A-012614 A-012613 A-012616 A-012615 A-011170 A-011171 A-011169

Catalog No. Tips length Tips OD Ring ID Ring OD Disk Ø RRDE Pt ring/Pt disk A-011172 25 mm 12 mm 5.0 mm 7.0 mm 4.0 mm Pt ring/GC disk A-011162 25 mm 12 mm 5.0 mm 7.0 mm 4.0 mm Au ring/GC disk A-011163 25 mm 12 mm 5.0 mm 7.0 mm 4.0 mm Disk electrode Ø 4 mm Pt ring/Au disk A-011164 25 mm 12 mm 5.0 mm 7.0 mm 4.0 mm Ring electrode Ø 7 mm Au ring/Pt disk A-012617 25 mm 12 mm 5.0 mm 7.0 mm 4.0 mm RRDE Ø 12 mm GC ring/GC disk A-012618 25 mm 12 mm 5.0 mm 7.0 mm 4.0 mm RDE GCE glassy carbon disk A-011169 25 mm 12 mm - - 3.0 mm PTE platinum disk A-011170 25 mm 12 mm - - 3.0 mm AUE gold disk A-011171 25 mm 12 mm - - 3.0 mm ALE aluminum disk A-011966 25 mm 12 mm - - 3.0 mm AGE silver disk A-011967 25 mm 12 mm - - 3.0 mm Disk electrode Ø 3 mm CUE copper disk A-011968 25 mm 12 mm - - 3.0 mm RDE Ø 12 mm NIE nickel disk A-011969 25 mm 12 mm - - 3.0 mm TAE tantalum disk A-011970 25 mm 12 mm - - 3.0 mm TIE titanium disk A-011971 25 mm 12 mm - - 3.0 mm WE tungsten disk A-011972 25 mm 12 mm - - 3.0 mm CPE carbon paste disk hole depth 4 mm A-011973 25 mm 12 mm - - 3.0 mm

Options PK-3 polishing kit A-011975

Working electrode maintenance

To refresh the surface Working electrodes maintenance Catalog No. of the electrode we PK-3 electrode polishing kit A-011975 recommend to polish Contents the electrode after 0.05 µm polishing alumina (20 mL) A-001050 each measurement. 1 µm polishing diamond (10 mL) A-002054 Glass plate (1 piece) A-002249 Alumina polishing pad (10 pieces) Diamond polishing pad (10 pieces) Replacement item Alumina polishing pad (20 pieces) A-001040 Diamond polishing pad (20 pieces) A-001041 Emery paper UF800 (20 pieces) A-012611 Coarse polishing pad (20 pieces) A-001042

27 SPECTRO- ELECTROCHEMISTRY SpectroSpectro

Spectroelectrochemistry (SEC) can be useful to elucidate electrochemical reaction mechanisms. The spectroelectrochemical kit is composed of three parts (spectrometer, light source and cuvette holder).

Three utilization modes & two spectrometers

Transmittance Fluorescence IrradianceIrradiance

SEC2000-UV/VIS SEC2000-VIS/NIR combo kit combo kit

Catalog No. Catalog No. Spectrometer combo kit type A-012196 SEC2000-UV/VIS A-012598 SEC2000-VIS/NIR

Components Spectrometer A-012191 SEC2000-UV/VIS A-012565 SEC2000-VIS/NIR Light source A-012193 SEC2000-DH UV A-012194 SEC2000-TH Visible Cuvette holder A-012195 SEC2000-CUV A-012244 SEC2000-CUV with diffusion plate Absorbance

Wavelenght (nm)

Absorbance changes for the oxidation of the potassium ferrocyanide.

28 ELECTROCHEMISTRY ACCESSORIES electrochemistry

Spectrometer

SEC2000-UV/VIS combo kit SEC2000-VIS/NIR combo kit Detector 2048 pixels CCD array Wave length range 220 - 800 nm 500 - 1000 nm Grating blazed at 400 nm blazed at 750 nm Resolution 1.8 ± 0.2 nm: slit 50 µm x 1000 µm (standard) (1) Accuracy < 1% at a Abs Dark noise < 2 mAbs A/D resolution 14 bit Optical entrance SMA905 Interface USB 2.0 Operating system WindowsTM XP Dimension (W x D x H) 98 x 118 x 35 mm Catalog No. A-012191 A-012565 * 1. Slit could be selected from: 10, 25, 100, 200 µm.

Light source

SEC2000-DH Light source SEC2000-TH Light source (deuterium & tungsten halogen) (tungsten halogen) Spectral range (Halogen + D2) 200 - 1100 nm 360 - 2000 nm D2 lamp spectral range 200 - 400 nm - power consumption (240 nm) < 5 x 10-8 W/nmsr - stability 1 x 10-3 AU - drift < 0.25%/h - bulb life (2) < 1000 h - Halogen lamp bulb life > 2000 h 1,500 h Connector SMA905 included SMA905 not included Dimension (W x D x H) 98 x 118 x 35 mm 98 x 118 x 35 mm Catalog No. A-012193 A-012194 * 2. Value for less than 50% power consumption of 240 nm.

Cuvette holder

SEC2000-UV/VIS combo kit SEC2000-VIS/NIR combo kit Cuvette holder A-012195 A-012244

29 SPECTRO- ELECTROCHEMISTRY SpectroSpectro

Static experiment 13

39 42 40 100

Platinum kit Gold kit Quartz glass spectroelectrochemical cell kit Catalog No. Catalog No.

0.5 mm kit A-012604 A-012605 Components grid metal - Pt - Au 5,5 mm Pt counter electrode A-012609 A-012609 0,5 mm thin layer quartz glass cell A-012608 A-012608 teﬂon cap A-011501 A-011501 5 mm purging tube A-010537 A-010537 gauze working electrode A-012606 80 mesh, height 6 mm A-012607 100 mesh, height 6 mm

1 mm kit A-011240 A-012186 Components grid metal - Pt - Au 6,5 mm Pt counter electrode A-011499 A-011499 1 mm thin layer quartz glass cell A-011500 A-011500 teﬂon cap A-011501 A-011501 6 mm purging tube A-010537 A-010537 gauze working electrode A-011498 80 mesh, height 5 mm A-012017 100 mesh, height 5 mm

Optional items RE-1B Ag/AgCl reference electrode A-012167 RE-7 non aqueous reference electrode A-012171

30 ELECTROCHEMISTRY ACCESSORIES electrochemistry

Flow experiment

Catalog No. Qty Working electrode SEC-2F spectroelectrochemical flow cell A-012660 Silicone gasket 500 µm Counter electrode Contents Collimating Lens SEC-2F flow cell base - 1 Reference electrode cover - 1 block A - 1 block B - 1 Outlet SEC-2F S500 silicone gasket A-012661 2 Stainless tube OD 1/16" (50 mm) A-012198 1 Needle adaptor - 1 Dynaseal PEEK fingertight - 2 Silicon tube (30 cm) - 1 Teflon tube (1 m) - 1

Optional Reference Ø 10 x 55 mm RE-3V aqueous A-012169 Inlet electrode RE-3VP aqueous (PEEK) A-012170 screw type RE-7V non aqueous A-012173 RE-7VP non aqueous (PEEK) A-012174 Working grid 8 x 27 x 1 mm Pt grid electrode (1 piece) A-012655 electrode Au grid electrode (1 piece) A-012656 for flow cell A-012656 carbon grid electrode (1 piece) A-012657 ITO electrode (4 pieces) A-012658 8 x 27 x 0,5 mm ITO electrode (12 pieces) A-011465 10 x 20 x 0,5 mm ITO electrode (10 pieces) A-010887 10 x 10 x 0,5 mm ITO electrode (30 pieces) A-011233 Ø 4 inch x 0,5 mm ITO electrode (1 piece) A-011827 Gasket silicone S500, 500 µmt (4 pieces) A-012661 S250, 250 µmt (4 pieces) A-012662 S100, 100 µmt (4 pieces) A-012663 teflon T500, 500 µmt (4 pieces) A-012664 T250, 250 µmt (4 pieces) A-012665 T100, 100 µmt (4 pieces) A-012666 Fiber and lens 400 m optical fiber SR, 25 cm A-012667 400 µm optical fiber SR, 2 m A-011522 UV/VIS collimating lens, 200-2000 nm A-012234

Dimensions in mm 31 QUARTZ CRYSTAL ANALYZER Quartz crystal Quartz Crystal

EQCM

The instrument monitors both the resonant frequency and the resonant resistance which are also reﬂected on the two analog outputs. It is possible to connect the Quartz Crystal Analyzer (QCA922) to a Biologic potentiostat using a small optional DB9-8BNC cable (ref: 092-22/1).

Catalog No. Speciﬁcations Quartz crystal microbalance 9 MHz kit SE-QCA922B

Frequency range 1 MHz-10 MHz, Contents resolution 0.1 Hz EQCM 9 MHz (or 5 MHz) main unit SE-QCA922-00 Resonant resistance 10-16 Ω, Adapter cable SE-QCA922-10 range resolution 0.1 Ω Male BNC/BNC cable (2 pieces, length 1 m) COR28100 ∆F Output full scale: ± 10 V (12 bit) ± 200 Hz / ± 2 kHz / Options ± 20 kHz / ± 200 kHz Holder is needed to get static and flow QCA cell 092-QCA-FC Resistance Output full scale: 0-10 V (11 bit) a full QCM or EQCM set-up dip cell SE-CL3 1 / 2 / 4 / 8 / 16 kΩ well cell SE-CL4 Gate time variable (0.1, 1.0, 10.0 s) transparent well cell SE-CL5 Display 40 Digits x 2 rows flow cell (90 µL) SE-CL7 is transparent SE-CL6/SE-CL7 Interface IEEE-488, RS-232C Connector from QCA to potentiostat 092-22/1 Size 260 x 88 x 230 mm Low flow peristaltic pump EL-AV-008 Weight 3.3 kg Temperature 0 - 40 °C Power consumption 100-120 V AC, 230-240 V AC, 50-60 Hz, (15 W)

Frequency and resistance measurements

092-QCA-FC SE-CL3

Electropolymerization by voltage scan of pyrrol to polypyrrol

32 ELECTROCHEMISTRY ACCESSORIES analyzer

Catalog No. Resonators 5 MHz gold electrode (25 pieces) SE- 5AU f0 = 5 MHz (calibration at 5 MHz at factory gold electrode separated lead wire (25 pieces) SE- 5AU-S with no charge when purchased) gold electrode mirror finish (25 pieces) SE- 5AU-M gold electrode mirror finish separated lead wire (25 pieces) SE- 5AU-MS Resonators 9 MHz etching finish gold electrode (30 pieces) SE- 9AU-E/1 f0 = 9 MHz gold electrode (100 pieces) SE- 9AU-E/3 polish finish gold electrode (30 pieces) SE- 9AU-P/1 gold electrode (100 pieces) SE- 9AU-P/3 standard finish resonator silver electrode (25 pieces) SE- 9AG and lead wire aluminum electrode (25 pieces) SE- 9AL Gold gold electrode (25 pieces) SE- 9AU electrode graphite electrode (25 pieces) SE- 9C cupper electrode (25 pieces) SE- 9CU molybdenum electrode (25 pieces) SE- 9MO nickel electrode (25 pieces) SE- 9NI platinum electrode (25 pieces) SE- 9PT silicium oxide electrode (25 pieces) SE- 9SO stainless steel (SUS304) electrode (25 pieces) SE- 9SS titanium electrode (25 pieces) SE- 9TI separated silver electrode (25 pieces) SE- 9AG-S lead wire aluminum electrode (25 pieces) SE- 9AL-S gold electrode (25 pieces) SE- 9AU-S Platinum graphite electrode (25 pieces) SE- 9C-S electrode copper electrode (25 pieces) SE- 9CU-S molybdenum electrode (25 pieces) SE- 9MO-S nickel electrode (25 pieces) SE- 9NI-S platinum electrode (25 pieces) SE- 9PT-S silicium electrode (25 pieces) SE- 9SI-S silicium oxide electrode (25 pieces) SE- 9SO-S stainless steel (SUS304) electrode (25 pieces) SE- 9SS-S titanium electrode (25 pieces) SE- 9TI-S mirror finish resonator silver electrode (25 pieces) SE- 9AG-M and lead wire aluminum electrode (25 pieces) SE- 9AL-M stainless gold electrode (25 pieces) SE- 9AU-M steel graphite electrode (25 pieces) SE- 9C-M electrode copper electrode (25 pieces) SE- 9CU-M ITO electrode (25 pieces) SE- 9IT-M molybdenum electrode (25 pieces) SE- 9MO-M nickel electrode (25 pieces) SE- 9NI-M platinum electrode (25 pieces) SE- 9PT-M silicium electrode (25 pieces) SE- 9SI-M silicium oxide electrode (25 pieces) SE- 9SO-M stainless steel (SUS304) electrode (25 pieces) SE- 9SS-M titanium electrode (25 pieces) SE- 9TI-M separated silver electrode (25 pieces) SE- 9AG-MS lead wire aluminum electrode (25 pieces) SE- 9AL-MS gold electrode (25 pieces) SE- 9AU-MS graphite electrode (25 pieces) SE- 9C-MS copper electrode (25 pieces) SE- 9CU-MS ITO electrode (25 pieces) SE- 9IT-MS molybdenum electrode (25 pieces) SE- 9MO-MS nickel electrode (25 pieces) SE- 9NI-MS platinum electrode (25 pieces) SE- 9PT-MS silicium electrode (25 pieces) SE- 9SI-MS silicium oxide electrode (25 pieces) SE- 9SO-MS stainless steel electrode (25 pieces) SE- 9SS-MS titanium electrode (25 pieces) SE- 9TI-MS

Others Resonators lead wire no sputter (50 pieces) SE- LEAD/2 Resonators 9 MHz, no sputter no lead wire (50 pieces) SE- 9Q/2 mirror ﬁnish no lead wire (50 pieces) SE- 9Q-M/2 Surface ﬁnishing

Roughness/µm Electrode materials deposition Standard finish 0.6 µm sputtered Etching finish 0.6 µm vacuum deposition Mirror finish 0.06 µm sputtered Polish finish 0.06 µm vacuum deposition 33 QUARTZ CRYSTAL ANALYZER Quartz crystal Quartz Crystal

Biosensor QCM

The specification (27 MHz) of the Quartz Crystal Microbalance (QCM934) allows user to measure a small mass change. So QCM934 is especially suitable in the bio-sensing field. Excellent sensitivity and resolution. Four configurations are available Specially designed oscillation circuit for added stability. Simultaneous measurement of resonant frequency,

Oscillator & Temperature resonant resistance and temperature. Control Module

Osc.Status

Temp.Status

Power

QCM934 Expandable up to 4 channels. Quartz Crystal Microbalance Works with ﬂows cell, well cell, dip cell. Computer control and data collection via USB interface. "Flow cell-based system of QCM934", Resonators of 9 MHz are compatible with QCM934 and the cell. "perista pump" and "notebook computer"

Speciﬁcations

Oscillator & Temperature Control Module

Osc.Status

Temp.Status

Frequency range 25 MHz-27 MHz, Power QCM934 resolution 0.01 Hz Quartz Crystal Microbalance Resonant resistance 2 Ω, resolution 0.1 Ω range Max channel 4 "Micro ﬂow cell-based system of QCM934", Gate time variable (0.1, 1.0, 10.0 s) "perista pump" and "notebook computer" Display 20 Digits x 2 rows Interface USB 2.0 Size 320 x 280 x 133 mm Dip Cell Weight 5.5 kg QA - CL3

Oscillator & Temperature Control Module

Osc.Status Temperature 10 - 40 °C Temp.Status

Power Transparent Well Cell QCM934 Power consumption 100-120 V AC, 230-240 V Quartz Crystal Microbalance QA -CL5 AC, 50-60 Hz, (60 W)

"Batch cell-based system of QCM934", "transparent well / dip cell" and "notebook computer"

Potentiostat With Analog Out

Oscillator & Temperature Control Module

Osc.Status

Temp.Status

Power QCM934 Quartz Crystal Microbalance

"EQCM-based system of QCM934" and "notebook computer"

34 ELECTROCHEMISTRY ACCESSORIES microbalance

Measurement chamber Oscillation circuit Flow cell (90 µL)L) Micro ﬂow cell (1 µL)L)

Flow cell Micro ﬂow cell Batch cell Catalog No. Catalog No. Catalog No. Product SE-QCM934-F SE-QCM934-MF SE-QCM934-B Main unit SE-QCM934-000 WinQCM software SE-WQCM Oscillator & temperature control module SE-QCM934-200 Cable for oscillator & temperature control module SE-QCM934-200A Measurement chamber SE-QCM934-500 Cable for OSC module connection SE-QCM934-300 Flow cell (90 µL) SE-QCM934-510 Micro ﬂow cell (1 µlL) SE-QCM934-600 Additional channel SE-QCM934-1CHF SE-QCM934-1CHMF SE-QCM934-1CHB

Option Low ﬂow peristaltic pump EL-AV-008

35 BATTERY ACCESSORIES BatteryBattery accessories

Battery holder

4-point measurement 4 A maximum current Adaptable to a wide variety of battery sizes (coin cells, 18 650 or 26 650 cells) Ability to link together many battery holders Catalog No. Battery holder 092-22/10

Coin cell holder Sense adapter module SAM-50

The coin cell holder is To be added to a multichannel directly plugged to system to perform stack the potentiostat measurements up to 50 V connectors. for 5 channel boards and No cable is required. 10 elements measurement. 4 coin cells can be investigated simultaneously.

Catalog No. Catalog No. Coin cell holder, 62 x 82 x 83 mm 092-22/14 Sense adaptor module SAM-50 092-26

36 ELECTROCHEMISTRY ACCESSORIES FARADAY CAGES Faraday cages

Standard Faraday cage

NS-FAR600

Advanced Faraday cage Speciﬁcations

Temperature 0 - 50 °C Power supply 100 VAC-240 VAC, 50/60 Hz Fuse 1 A Gas pressure ‹ 34 kPa max. Size (W x D x H) 286 x 230 x 320 mm Panel open Interface IEEE-488, RS-232C Weight 3.8 kg

Catalog No. Dimensions

Standard Faraday cage for standard channel N-FAR600 600 x 400 x 200 mm Inside the cage for low current channel NS-FAR600 600 x 400 x 200 mm Advanced Faraday cage A-012033 286 x 230 x 320 mm External disturbance To avoid any external perturbations, specially for low current application, we recommend to use the Faraday cage.

Please note that to activate this protection, Rear panel Faraday cage has to be connected to the ground of the instrument (green plug on the rear panel of the instrument).

37 FUEL CELL Fuel cellFuel

Membrane electrode assemblies (MEA)

These MEAs are based on a 50 µm-thick perfluoronated membrane, and a platinum loading of 0.5 mg/cm² (± 0.05), obtained with the standard catalyst concentration, 70% Pt/C. 3 layers MEA corresponds to a catalyst covered membrane (CCM): the proton exchanged membrane is covered with an ink containing the catalyst on the electroactive area. Platinum and Platinum-Ruthenium alloys are available for hydrogen and reformate operations respectively. 5 layers MEA corresponds to a CCM with gas diffusion layers Catalog No. Single cell fixture 5 cm² 095- 08/1 (GDL) completing the electrodes on the electroactive area (without MEA's) 16 cm² 095- 08/2 on both sides of the membrane. 25 cm² 095- 07 7 layers MEA corresponds to a 5-layer MEA with a flat gasket 50 cm² 095- 08 (fiberglass reinforced silicon) around both electrodes. 100 cm² 095- 08/3 Membrane MEA S5, 5 cm² 3 layers 095-09/13 A subgasket, protecting the membrane and the edges of Electrode 5 layers 095-09/14 the active layer can be added to 5 and 7-layer MEAs. Assemblies 7 layers 095-09/15 MEA S16, 16 cm² 3 layers 095-09/16 5 layers 095-09/17 7 layers 095-09/18 MEA S25, 25 cm² 3 layers 095-09/1 5 layers 095-09/2 7 layers 095-09/3 MEA S50, 50 cm² 3 layers 095-09/4 5 layers 095-09/5 7 layers 095-09/6 MEA S100, 100 cm² 3 layers 095-09/7 5 layers 095-09/8 7 layers 095-09/9 MEA S225, 225 cm² 3 layers 095-09/10 5 layers 095-09/11 7 layers 095-09/12

38 ELECTROCHEMISTRY ACCESSORIES cell

Semi-automatic ﬁlling kit

An external kit (Semi Automatic Water Filling Kit) can be added to an existing FCT. This kit consists of two separate pumps that can be easily added to the front panel of a FCT. Using this external tool, researchers can manually fill the humidifier (anodic and cathodic side separately) without switching off the instrument or disrupting Catalog No. the experiment in progress. Semi-automatic filling kit 095-16

Catalog No. Single cell ﬁxture 5 cm² 095- 08/1 Educational kit (without MEA's) 16 cm² 095- 08/2 25 cm² 095- 07 The educational fuel cell kit is very simple and easy to use: 50 cm² 095- 08 just plug the hydrogen tank into the cell and let the fuel cell 100 cm² 095- 08/3 Membrane MEA S5, 5 cm² 3 layers 095-09/13 use the oxygen in the surrounding air to produce electricity. Electrode 5 layers 095-09/14 1 plastic electrolyser cell (25 cm²) containing a 7-layer Assemblies 7 layers 095-09/15 membrane electrode assembly. At the anode side of the MEA S16, 16 cm² 3 layers 095-09/16 electrolyser cell there is a water reservoir, the hydrogen gas 5 layers 095-09/17 7 layers 095-09/18 produced comes out of the cell via one of the gas exits on MEA S25, 25 cm² 3 layers 095-09/1 the top and bottom side of the cell. 5 layers 095-09/2 A plastic screw is included 7 layers 095-09/3 for closing the unused gas exit. MEA S50, 50 cm² 3 layers 095-09/4 5 layers 095-09/5 1 plastic air-breathing fuel cell (25cm²). The cell has one 7 layers 095-09/6 hydrogen gas input and one exit. A porous material MEA S100, 100 cm² 3 layers 095-09/7 is placed inside the kit for the homogeneous diffusion 5 layers 095-09/8 of hydrogen over the whole surface area of the membrane 7 layers 095-09/9 electrode assembly. MEA S225, 225 cm² 3 layers 095-09/10 Catalog NNo.o. 5 layers 095-09/11 Educational kit 110 V 095-20/A 7 layers 095-09/12 (fuel cell / electrolyzer) 220 V 095-20/B

Contents Kit PAC#1: 25cm² air-breathing cells (MEA S25-7L N50-Pt/C 70%), no possibility to dismantle the cell 095-20/1 PAC#2: 25cm² air-breathing cells (MEA S25-7L N125-Pt/C 70%), no possibility to dismantle the cell 095-20/2 PAC#3: 25cm² air-breathing cells (MEA S25-7L N212-Pt/C 40%), no possibility to dismantle the cell 095-20/3 Electrolyzer kit (including gas line) 095-20/4 Variable resistance 095-20/5 Data acquisition (including connection, data logger, software) 095-20/7 Power supply 220 V 095-20/9 110 V/220 V adapter for 110 V conﬁguration 095-20/10

Optional products 25 cm² air-breathing cell (no MEA) 095-20/6 Power supply by two photovoltaic cells 095-20/8

39 CONNECTION ACCESSORIES ConnectionConnection

Multi- electrode investigations cables

Bipot cable: Dedicated to RRDE applications.

Low current Nstat box

Nstat box (8 channels).

Connection to the cell

Channel Number of channels Length Catalog No. Bipot cable standard 2 1.5 m 092-22/12 (for VSP, 2 3 m 092-22/12A BiStat, VMP3) 2 4 m 092-22/12B Nstat box standard 4 1.5 m 092-16 (for VSP, VMP3) 8 1.5 m 092-22/3 low current 8 1.5 m 092-22/4

Option External power supply for the Nstat box (this option is needed if more than 092-16/1 one Nstat box is connected to VMP3 or if the user uses VSP)

40 ELECTROCHEMISTRY ACCESSORIES accessories

Speciﬁc cables

By default, the potentiostat and the booster are provided with a cell cable of 1.5 m long. The cable connected from the booster to the potentiostat is 80 cm long. For some applications, the user may need cables with different length. That's why, longer cable are offered. Moreover for applications performed in glove box, hermetic cell cables are also offered. Please contact us for other cable length. Longer cable Hermetic cell cable for glove box

Available length Catalog No. Catalog No. SP-50, SP-150, VSP, VMP3, MPG2 2.5 m 092-23/2 SP-50, SP-150, BiStat, VSP, VMP3, MPG2 092-23/5 3 m 092-23/7 SP-200, SP-300 094-101/8 5 m 092-23/3 10 m 092-23/4 Booster 2 A, 4 A, 5 A 2.5 m 092-33/11 3 m 092-33/12 Connection cable 5 m 092-33/13 Booster 8 A, 10 A, 20 A 2.5 m 092-33/21 from booster to potentiostat 3 m 092-33/22 Available length Catalog No. 5 m 092-33/23 All boosters 3 m 092-33/5 5 m 092-33/6 Set-up connection Bad connection could induce some effects on the measurement (effect on the stability of the potentiostat, artifact...). We recommend the user to optimize his set-up by using the accessories offered in this section.

41 CONNECTION ACCESSORIES accessoriesConnection

Test boxes

Catalog No. Contents Purpose Test-Box 1 092-22/5 16 R/C circuits standard check 2 092-22/6 several circuits with high precision resistors calibration and validation 3 092-22/7 3 circuits: linear, exponential, non-linear for teaching and demonstration 4 092-22/9 2 R/C circuits standard check Dummy cell 094-111/1 1 R/C circuit standard check for booster 2 to 5 A 092-32/2 1 power resistor, 50 mOhm standard check for booster 8 to 20 A 092-32/1 1 power resistor, 5 mOhm standard check

External device connection

5 - I monitor E monitor - 9 4 - Trigger out Trigger in - 8 3 - Open in Ground - 7 2 - Analog out Analog in 2 - 6 1 - Analog inl

Catalog No. Catalog No. PT100 temperature probe 092-22/13 BNC-DB9 connector for auxiliary I/O 092-22/1 To be connected to the auxiliary I/O

42 ELECTROCHEMISTRY ACCESSORIES accessories

Connectors

Colour Catalog No. Alligator clips with female connector of 2 mm (pack of 10) black 092-1001/1 red 092-1001/2 white 092-1001/22 blue 092-1001/26 Alligator clips with female connector of 4 mm (pack of 5) black 092-1001/13 red 092-1001/14 blue 092-1001/23 Sockets 2 mm female (pack of 10) black 092-1001/5 red 092-1001/6 blue 092-1001/7 white 092-1001/8 Sockets 4 mm female (pack of 10) black 092-1001/25 red 092-1001/4 blue 092-1001/3 Banana plugs 2 mm (pack of 10) black 092-1001/9 red 092-1001/10 blue 092-1001/11 white 092-1001/12 Banana stackable plugs 4 mm (pack of 5) blue 092-1001/15 red 092-1001/16 yellow 092-1001/17 white 092-1001/24 Banana adapter 2 mm female socket to 4 mm male plug (pack of 5) black 092-1001/18 red 092-1001/19 blue 092-1001/20 white 092-1001/21 Adapter for banana 2 mm female socket to 4 mm male plug (pack of 5) 092-1001/27

Miscellaneous

Catalog No. SP-200 suitcase care 094-082

43 DISTRIBUTION

Bio-Logic Science Instruments is present in most countries through an extensive distribution network

France: Bio-Logic SAS (Corporate Office) Romania: Sc Remed Prodimpex Srl USA: Bio-Logic USA LLC (Affiliate Office) Singapore/Malaysia: Alpha Analytical Ltd. India: Bio-Logic India PVT. Ltd. (Affiliate Office) Bosnia/Croatia/Slovenia/Serbia: Inspirion d.o.o. Japan: Hokuto Denko Corp. Turkey: Entek Electronik Ltd. Sti. South Korea: Neoscience Co. Ltd. South America/Australia : Bio-Logic USA LLC Germany: Gamec AnalysenTechnik Rest of the world: contact us China: Dalian Huayang Scientific Instruments Co. Ltd. Spain: Trallero & Schlee Taiwan: Beam Associates Co. Ltd. UK & Ireland: EC-Lab Ltd. Canada: Snow Hous e Solutions inc. Israel: New Road Agencies 1001003

www.snowhouse.ca

Corporate Ofﬁce USA Customers Bio-Logic, SAS Bio-Logic USA, LLC 1, rue de l’Europe P.O.Box 30009 38640 CLAIX - France Knoxville TN 37930 - USA Tel.: +33 476 98 68 31 Tel.: +1 865 769 3800 Fax: +33 476 98 69 09 Fax: +1 865 769 3801 Brochure released on May 2010 - on May released Brochure www.bio-logic.info www.bio-logic.us www.bio-logic.info