EPA List of Hazardous Waste

Total Page:16

File Type:pdf, Size:1020Kb

EPA List of Hazardous Waste EPA List of Hazardous Waste CHARACTERISTIC WASTES (D001-D003) D001 Ignitable Characteristic Alkalines Ignitable Compressed Gases Other Corrosives Ignitable Liquids D003 Reactive Characteristic Ignitable Reactives Cyanides Oxidizers Explosives D002 Corrosive Characteristic Reactive Sulfides Acids Water Reactives TOXICITY CHARACTERISTICS D004 Arsenic D024 m-Cresol D005 Barium D025 p-Cresol D006 Cadmium D026 mixed Cresols D007 Chromium D027 p-Dichlorobenzene D008 Lead D028 1,2-Dichloroethane D009 Mercury D029 1,1-Dichloroethylene D010 Selenium D030 2,4-Dinitrotoluene D011 Silver D031 Heptachlor (and its epoxide) D012 Endrin D032 Hexachlorobenzene D013 Lindane D033 Hexachlorobutadiene D014 Methoxychlor D034 Hexachloroethane D015 Toxaphene D035 Methyl Ethyl Ketone D016 2,4-D D036 Nitrobenzene D017 2,4,5-TP (Silvex) D037 Pentachlorophenol D018 Benzene D038 Pyridine D019 Carbon Tetrachloride D039 Tetrachloroethylene D020 Chlordane D040 Trichloroethylene D021 Chlorobenzene D041 2,4,5-Trichlorophenol D022 Chloroform D042 2,4,6-Trichlorophenol D023 o-Cresol D043 Vinyl Chloride HAZARDOUS WASTES FROM NON-SPECIFIC SOURCES (F001-F039) F001 Halogenated solvents used for degreasing 1,1,2-Trichloro-1,2,2,-trifluoroethane 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1,2-Trichloro-1,2,2,-trifluoroethane Chlorobenzene Carbon tetrachloride o-Dichlorobenzene Tetrachloroethylene Trichloromonofluoromethane Trichloromonofluoromethane F002 Halogenated solvents F003 Non-Halogenated solvents 1,1,1-Trichloroethane Acetone FLORIDA ATLANTIC UNIVERSITY, CHEMICAL HYGIENE PLAN 38 Cyclohexanone Ethyl Acetate F005 Non-Halogenated solvents Ethyl Benzene 2-Ethoxyethanol Ethyl Ether 2-Nitropropane Methanol Benzene Methyl Isobutyl Ketone Carbon Disulfide n-Butyl Alcohol Isobutanol Xylene Methyl Ethyl Ketone Pyridine F004 Non-Halogenated solvents Toluene Cresol Cresylic acid F006-F039 (See regulations for details 40 Nitrobenzene CFR§261) ACUTE HAZARDOUS WASTE (P001-P123) P001 4-hydroxy-3-(3-oxo-1-phenylbutyl)-2H-1- Chloromethylbenzene Warfarin P029 Copper Cyanide P002 1-Acetyl-2-thiourea P030 Cyanides N-(aminothioxomethyl)-Acetamide P031 Cyanogen P003 Acrolein Ethanedinitrile P004 Aldrin P033 Cyanogen Chloride P005 Allyl Alcohol P034 2-Cyclohexyl-4,6-dinitrophenol P006 Aluminum Phosphide P036 Dichlorophenylarsine P007 5-(Aminomethyl)-3-isoxazolol Phenyl Arsonous Dichloride P008 4-Aminopyridine P037 Dieldrin 4-Pyridinamine P038 Diethyl Arsine P009 Ammonium Picrate Diethylarsine P010 Arsenic Acid P039 Disulfoton P011 Arsenic Oxide As2O5 P040 O,O-Diethyl O-pyrazinyl Arsenic Pentoxide P041 Diethyl-p-nitrophenyl Phosphate P012 Arsenic Oxide As2O3 P042 4-[1-hydroxy-2-(methylamino)ethyl]-1,2- Arsenic Trioxide Epinephrine P013 Barium Cyanide P043 Diisopropylfluorophosphate P014 Benzenethiol P044 Dimethoate Thiophenol P045 2-Butanone, 3,3-dimethyl-1-(methylthio)-, P015 Beryllium O-[(methylamino)carbonyl] oxime P016 Dichloromethyl Ether Thiofanox Oxybischloromethane P046 alpha,alpha-dimethylbenzeneethanamine P017 Bromoacetone alpha,alpha-Dimethylphenethylamine P018 Brucine P047 4,6-Dinitro-o-cresol P020 Dinoseb P048 2,4-Dinitrophenol P021 Calcium Cyanide P049 Dithiobiuret P022 Carbon Disulfide Thiomidodicarbonic diamide P023 Chloroacetaldehyde P050 Endosulfan P024 4-chloro-benzenamine P051 Endrin p-Chloroaniline P054 Aziridine P026 1-(o-Chlorophenyl)thiourea Ethyleneimine P027 3-Chloropropionitrile P056 Fluorine P028 Benzyl Chloride P057 2-Fluoro-Acetamide FLORIDA ATLANTIC UNIVERSITY, CHEMICAL HYGIENE PLAN 39 Fluoroacetamide P094 Phorate P058 Fluoroacetic acid sodium salt P059 Heptachlor P095 Carbonic Dichloride P060 Isodrin Phosgene P062 Hexaethyl Tetraphosphate P096 Hydrogen Phosphide P063 Hydrocyanic Acid Phosphine Hydrogen Cyanide P097 Famphur P064 Isocyanatomethane P098 Potassium Cyanide Methyl Isocyanate P099 Argenate (1-), bis(cyano-C)-, potassium P065 Fulminic Acid, mercury salt Potassium Silver Cyanide Mercury Fulminate P101 Ethyl Cyanide P066 Methomyl Propanenitrile P067 1,2-Propylenimine P102 Propargyl alcohol 2-methyl-Aziridine P103 Selenourea P068 Methyl Hydrazine P104 Silver Cyanide P069 2-Methyllactonitrile P105 Sodium Azide P070 Aldicarb P106 Sodium Cyanide P071 Methyl Parathion P108 Strychnidin-10-one P072 alpha-Naphthylthiourea Strychnine P073 Nickel Carbonyl P109 Tetraethyldithiopyrophosphate P074 Nickel Cyanide P110 Tetraethyl Lead P075 Nicotine Tetraethyl Plumbane P076 Nitric Oxide P111 Tetraethyl Ester Diphosphoric Acid Nitrogen Oxide NO Tetraethyl Pyrophosphate P077 4-nitro-benzenamine P112 Tetranitromethane p-Nitroaniline P113 Thallic Oxide P078 Nitrogen Dioxide Thallium Oxide Nitrogen Oxide NO2 P114 Selenious Acid, dithallium salt P081 Nitroglycerine Thallium Selenite N-methyl-N-nitroso-methanamine P115 Sulfuric Acid, dithallium salt P082 N-Nitrosodimethylamine Thallium Sulfate P084 N-Nitrosomethylvinylamine P116 Hydrazinecarbothioamide Vinylamine, N-methyl-N-nitroso Thiosemicarbazide P085 Octamethyl Diphosphoramide P118 Trichloromethanethiol Octamethylpyrophosphoramide P119 Ammonium Vanadate P087 Osmium Tetroxide Vanadic Acid, ammonium salt P088 Endothall P120 Vanadium oxide P089 Parathion Vanadium Pentoxide P121 Zinc Cyanide P092 (Acetato-O)phenyl-mercury P122 Zinc Phosphide Phenylmercury Acetate P123 Toxaphene P093 Phenylthiourea OFF-SPECIFICATION HAZARDOUS WASTE (U001-U249) U001 Acetaldehyde U006 Acetyl Chloride U002 Acetone U007 Acrylamide U003 Acetonitrile U008 Acrylic Acid U004 Acetophenone U009 Acrylonitrile U005 2-Acetylaminofluorene U010 Mitomycin C FLORIDA ATLANTIC UNIVERSITY, CHEMICAL HYGIENE PLAN 40 U011 Amitrole U058 Cyclophosphamide U012 Aniline U059 Daunomycin U014 Auramine U060 DDD U015 Azaserine U061 DDT U016 Benz(c)acridine U062 Diallate U017 Benzal Chloride U063 Dibenz(a,h)anthracene U018 Benz(a)anthracene U064 1,2,7,8-Dibenzopyrene U019 Benzene U066 1,2-Dibromo-3-chloropropane U020 Benzenesulfonyl Chloride U067 Ethylene Dibromide Fluoranthene U068 Dibromomethane U021 Benzidine U069 Di-n-butyl Phthalate U022 Benzo(a)pyrene U070 o-Dichlorobenzene U023 Benzotrichloride U071 m-Dichlorobenzene U024 bis(2-Chloroethoxy)methane U072 p-Dichlorobenzene U025 bis(2-chloroethyl)ether U073 3,3'-Dichlorobenzidine U026 Chlornaphazin U074 1,4--Dichloro-2-butylene U027 bis(2-chloroisopropyl)ether U075 Dichlorodifluoromethane U028 bis(2-ethylhexyl)phthalate U076 1,1-Dichloroethane U029 Methyl Bromide U077 1,2-Dichloroethane U030 4-Bromophenyl Phenyl Ether U078 1,1-Dichloroethylene U031 n-Butyl Alcohol U079 1,2-Dichloroethylene U032 Calcium Chromate U080 Methylene Chloride U033 Carbon Oxyfluoride U081 2,4-Dichlorophenol Carbonyl Fluoride U082 2,6-Dichlorophenol U034 Trichloroacetaldehyde U083 1,2-Dichloropropane U035 Chlorambucil U084 1,3-Dichloropropylene U036 Chlordane U085 1,2,3,4-Diepoxybutane U037 Chlorobenzene U086 N,N-Diethylhydrazine U038 Chlorobenzilate U087 0,0-Diethyl S-methyldithiophosphate U039 p-Chloro-m-cresol U088 Diethyl Phthalate U041 1-Chloro-2,3-epoxypropane U089 Diethyl Stilbestrol U042 2-Chloroethyl Vinyl Ether U090 Dihydrosafrole U043 Vinyl Chloride U091 3,3'-Dimethoxybenzidine U044 Chloroform U092 Dimethylamine U045 Chloromethane U093 p-Dimethylaminoazo-benzene U046 Chloromethyl Methyl Ether U094 7,12-Dimethylbenz(a)anthracene U047 2-Chloronaphthalene U095 3,3'-Dimethylbenzidine U048 2-Chlorophenol U096 a,a-Dimethyl Benzyl Hydroperoxide U049 4-Chloro-o-toluidine Hydrochloride U097 Dimethylcarbonyl Chloride U050 Chrysene U098 1,1-Dimethylhydrazine U051 Creosote--Lead U099 1,2-Dimethylhydrazine Creosote--Naphthalene U101 2,4-Dimethylphenol Creosote--Pentachlorophenol U102 Dimethyl Phthalate Creosote--Phenanthrene U103 Dimethyl Sulfate Creosote--Pyrene U105 2,4-Dinitrotoluene Creosote--Toluene U106 2,6-Dintirotoluene Creosote--Xylene U107 Di-n-octyl Phthalate U052 Cresols U108 1,4-Dioxane U053 Crotonaldehyde U109 1,2-Diphenylhydrazine U055 Cumene U110 Dipropylamine U056 Cyclohexane U111 Di-n-propylnitrosamine U057 Cyclohexanone U112 Ethyl Acetate FLORIDA ATLANTIC UNIVERSITY, CHEMICAL HYGIENE PLAN 41 U113 Ethyl Acrylate U163 N-Methyl N'-nitro N-Nirosoguanidine U114 Ethylene bis-dithiocarbamic acid U164 Methylthiouracil U115 Ethylene Oxide U165 Naphthalene U116 Ethylene Thiourea U166 1,4-Naphthoquinone U117 Ethyl Ether U167 1-Naphthylamine U118 Ethyl Methacrylate U168 2-Naphthylamine U119 Ethyl Methane Sulfonate U169 Nitrobenzene U121 Trichloromonofluoromethane U170 p-Nitrophenol U122 Formaldehyde U171 2-Nitropropane U123 Formic Acid U172 N-Nitroso-di-n-butylamine U124 Furan U173 N-Nitroso-di-n--ethanolamine U125 Furfural U174 N-Nitrosodiethylamine U126 Glycidaldehyde U176 N-Nitroso-N-ethylurea U127 Hexachlorobenzene U177 N-Nitroso-N-methylurea U128 Hexachlorobutadiene U178 N-Nitroso-N-methylurethane U129 alpha-BHC U179 N-Nitrosopiperidine beta-BHC U180 N-Nitrosopyrrolidine delta-BHC U181 5-Nitro-o-toluidine gamma-BHC (Lindane) U182 Paraldehyde U130 Hexachlorocyclopentadiene U183 Pentachlorobenzene U131 Hexachloroethane U184 Pentachloroethane U132 Hexachlorophene U185 Pentachloronitrobenzene U133 Hydrazine U186 1,3-Pentadiene U134 Hydrogen Fluoride U187 Phenacetin U135 Hydrogen Sulfide U188 Phenol U136 Arsinic Acid, dimethyl U189 Phosphorous Sulfide U137 Indeno (1,2,3-cd)pyrene U190 Phthalic Anhydride U138 Iodomethane U191 2-Picoline U140 Isobutyl Alcohol U192 Pronamide U141 Isosafrole U193 1,3-Propane Sultone U142 Kepone U194 n-Propylamine U143 Lasiocarpine U196 Pyridine U144 Lead Acetate U197 p-Benzoquinone U145 Lead Phosphate U200 Respirine U146 Lead subacetate U201 Resorcinol Lead, bis(acetato-O)tetrahydroxytri- U202
Recommended publications
  • Toxicological Profile for 2-Butanone Released for Public Comment in May 2019
    Toxicological Profile for 2-Butanone October 2020 2-BUTANONE ii DISCLAIMER Use of trade names is for identification only and does not imply endorsement by the Agency for Toxic Substances and Disease Registry, the Public Health Service, or the U.S. Department of Health and Human Services. 2-BUTANONE iii FOREWORD This toxicological profile is prepared in accordance with guidelines* developed by the Agency for Toxic Substances and Disease Registry (ATSDR) and the Environmental Protection Agency (EPA). The original guidelines were published in the Federal Register on April 17, 1987. Each profile will be revised and republished as necessary. The ATSDR toxicological profile succinctly characterizes the toxicologic and adverse health effects information for these toxic substances described therein. Each peer-reviewed profile identifies and reviews the key literature that describes a substance's toxicologic properties. Other pertinent literature is also presented, but is described in less detail than the key studies. The profile is not intended to be an exhaustive document; however, more comprehensive sources of specialty information are referenced. The focus of the profiles is on health and toxicologic information; therefore, each toxicological profile begins with a relevance to public health discussion which would allow a public health professional to make a real-time determination of whether the presence of a particular substance in the environment poses a potential threat to human health. The adequacy of information to determine a substance's
    [Show full text]
  • The Mechanism and Kinetics of Methyl Isobutyl Ketone Synthesis from Acetone Over Ion- Exchanged Hydroxyapatite
    Lawrence Berkeley National Laboratory Recent Work Title The mechanism and kinetics of methyl isobutyl ketone synthesis from acetone over ion- exchanged hydroxyapatite Permalink https://escholarship.org/uc/item/4hq4p42d Authors Ho, CR Zheng, S Shylesh, S et al. Publication Date 2018-09-01 DOI 10.1016/j.jcat.2018.07.005 Peer reviewed eScholarship.org Powered by the California Digital Library University of California Journal of Catalysis 365 (2018) 174–183 Contents lists available at ScienceDirect Journal of Catalysis journal homepage: www.elsevier.com/locate/jcat The mechanism and kinetics of methyl isobutyl ketone synthesis from acetone over ion-exchanged hydroxyapatite ⇑ Christopher R. Ho a,b, Steven Zheng a, Sankaranarayanapillai Shylesh a,b, Alexis T. Bell a,b, a Department of Chemical and Biomolecular Engineering, University of California, Berkeley, CA 94720-1462, United States b Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, United States article info abstract Article history: The synthesis of methyl isobutyl ketone (MIBK) can be carried out by the condensation of acetone in the Received 9 May 2018 presence of hydrogen over a supported metal catalyst. Previous studies have shown that hydroxyapatite Revised 26 June 2018 is an excellent catalyst for condensation reactions. The present investigation was undertaken in order to Accepted 2 July 2018 elucidate the reaction mechanism and site requirements for acetone coupling to MIBK over a physical Available online 18 July 2018 mixture of hydroxyapatite and Pd/SiO2. The reaction is found to proceed by consecutive aldol addition to form diacetone alcohol (DAA), dehydration of DAA to mesityl oxide (MO), and hydrogenation of MO Keywords: to MIBK.
    [Show full text]
  • Methyl Isobutyl Ketone
    Issued: Data Sheet 19-Sep-2005 Product Name Methyl isobutyl ketone Product Code S1215 Asia Pacific Product Category Ketones CAS Registry 108-10-1 Number EINECS Number 203-550-1 Alternate Name 2-methyl-2-pentanone, hexanone, MIBK Description Methyl isobutyl ketone, MIBK, a medium boiling ketone is a stable water-white liquid. Like acetone and MEK, it displays strong solvent power for cellulose esters vinyl polymers and copolymers, and most natural and synthetic resins. MIBK is a medium evaporating solvent with excellent solvency characteristics and with a high tolerance for hydrocarbon diluents. Sales Property Unit Min Max Method Specification Purity % m/m 99.5 ASTM D3329 Water % m/m 0.05 ASTM D1364 Methyl isobutyl carbinol mg/kg 1000 ASTM D3329 Mesityloxide + mg/kg 1000 ASTM D3329 Isomesityloxide Dimethylketone mg/kg 1000 ASTM D3329 Appearance Cl & FFSM ASTM D4176 Color Pt-Co 10 ASTM D1209 Density @20°C g/mL 0.799 0.802 ASTM D4052 (4) Refractive Index @20°C 1.395 1.397 ASTM D1218 (4) Acidity as Acetic acid % m/m 0.005 ASTM D1613 Non Volatile Matter g/100mL 0.002 ASTM D1353 Distillation, IBP °C 114.0 ASTM D1078 (4) Distillation, DP °C 117.0 ASTM D1078 (4) (1) Guaranteed, (2) Typical, (3) Report Only, (4) Guaranteed spec with typical result Product as produced complies with DIN 53247, ASTM D 1153 and ACS 9th edition. Typical Properties Property Unit Method Value Density @20°C kg/L ASTM D4052 0.800 Cubic Expansion Coefficient @20°C (10^-4)/°C - 12 Refractive Index @20°C - ASTM D1218 1.396 Distillation, IBP °C ASTM D1078 114.0 Distillation,
    [Show full text]
  • Characterization of a Crumb Rubber
    Abstract 2415 The National Toxicology Program Synthetic Turf/Recycled Tire Crumb Rubber Research: Characterization of a Crumb Rubber Lot for Use in in Vitro and in Vivo Studies Tim Cristy1, Georgia Roberts2, Brian Burback1, Scott Masten2 and Suramya Waidyanatha2 1Battelle Memorial Institute, Columbus, OH; 2Division of the National Toxicology Program, National Institute of Environmental Health Sciences, Research Triangle Park, NC 27709 ABSTRACT METHODS AND INSTRUMENTATION RESULTS RESULTS ANALYSES OF VOLATILES (PPM) BY HEADSPACE GC-MS Optical Microscopy: An Olympus SZX12 stereo microscope with an Olympus DP-71 camera Artificial turf athletic fields have been growing in popularity due to decreased ANALYSIS FOR INORGANICS a (Tokyo, Japan). Compound Replicate 1 Replicate 2 Average Match Score (%) maintenance required relative to conventional fields. Crumb rubber (CR) used as an Element Replicate 1 Replicate 2 Average Methyl Isobutyl Ketone 3.48 3.21 3.35 98.6 infill in artificial turf has brought public health concerns in recent years. The National Scanning Electron Microscopy (SEM) and Energy Dispersive X-Ray Spectroscopy (EDS): Zinc (%) 1.62 1.74 1.68 Aniline 0.980 1.12 1.05 99.6 JEOL 7600-F (JOEL, Tokyo, Japan) and Apollo X silicon drift detector (EDAX, Mahwah, NJ). Silicon (%) 0.898 0.966 0.932 Benzothiazole 0.753 0.684 0.719 94.0 Toxicology Program (NTP) is conducting research to improve the understanding of Toluene 0.441 0.415 0.428 100.0 Thermogravimetric Analysis: Pyris 1 (Perkin Elmer, Waltham, MA) thermal gravimetric Aluminum (%)
    [Show full text]
  • Chromatographic Separations of Niobium, Tantalum, Molybdenum, and Tungsten Lionel Herbert Dahmer Iowa State University
    Iowa State University Capstones, Theses and Retrospective Theses and Dissertations Dissertations 1966 Chromatographic separations of niobium, tantalum, molybdenum, and tungsten Lionel Herbert Dahmer Iowa State University Follow this and additional works at: https://lib.dr.iastate.edu/rtd Part of the Analytical Chemistry Commons Recommended Citation Dahmer, Lionel Herbert, "Chromatographic separations of niobium, tantalum, molybdenum, and tungsten " (1966). Retrospective Theses and Dissertations. 5355. https://lib.dr.iastate.edu/rtd/5355 This Dissertation is brought to you for free and open access by the Iowa State University Capstones, Theses and Dissertations at Iowa State University Digital Repository. It has been accepted for inclusion in Retrospective Theses and Dissertations by an authorized administrator of Iowa State University Digital Repository. For more information, please contact [email protected]. This dissertation has been microfihned exactly as received 67-5577 DAHMER, Lionel Herbert, 1936- CHROMATOGRAPHIC SEPARATIONS OF NIOBIUM TANTALUM, MOLYBDENUM, AND TUNGSTEN. Iowa State University of Science and Technology, Ph.D., 1966 Chemistry, analytical University Microfilms, Inc., Ann Arbor, Michigan CHROyiATOGRAPHIC SEPARATIONS OP NIOBIUM TANTALUM, MOLYBDENUM, AND TUNGSTEN by Lionel Herbert Dahmer A Dissertation Submitted to the Graduate Faculty in Partial Fulfillment of The Requirements for the Degree of DOCTOR OF PHILOSOPHY Major Subject: Analytical Chemistry Approved : Signature was redacted for privacy. In Cha lor V/ork Signature was redacted for privacy. Heâi of Major Department Signature was redacted for privacy. De^t of Gr&duate College Iowa State University Of Science and Technology Ames, Iowa 1966 ii TABLE OP CONTEXTS Page INTRODUCTION 1 PART I. CATION EXCHANGE SEPARATION OF MOLYBDENUM, 8 TUNGSTEN, NIOBIUM, AND TANTALUM PROM OTHER METAL IONS LITERATURE SURVEY 9 EXPSRIKSITAL 10 Apparatus 10 Reagents 10 Separation Procedure 12 Analysis of Column Effluents 14 Results and Discussion 15 PART II.
    [Show full text]
  • Methyl Isobutyl Ketone
    Shell Chemicals Technical Datasheet Methyl Isobutyl Ketone Product Code S1215 Region Asian Pacific Product Category Ketones CAS Registry Number 108-10-13 Synonym(s) 4-methyl-2-pentanone, MIBK Description Methyl Isobutyl ketone, MIBK, a medium boiling ketone is a stable water-white liquid. Like acetone and MEK, it displays strong solvent power for cellulose esters vinyl polymers and copolymers, and most natural and synthetic resins. MIBK is a medium evaporating solvent with excellent solvency characteristics and with a high tolerance for hydrocarbon diluents. Typical Properties Property Unit Method Value Purity, min. %m/m GC 99.5 Water %m/m ASTM D1364 0.03 Acidity (as Acetic Acid) %m/m ASTM D1613 0.001 Density at 20°C kg/l ASTM D4052 0.800 Specific Gravity at 20°C/20°C - ASTM D4052 0.801 Specific Gravity at 25°C/25°C - ASTM D4052 0.798 Coefficient of Cubic Expansion at 20°C 10-4/°C Calculated 12 Refractive Index at 20°C - ASTM D1218 1.396 Colour Pt-Co ASTM D1209 < 5 Boiling Point °C - 116 Relative Evaporation Rate (nBuAc=1) - ASTM D3539 1.6 Relative Evaporation Rate (Ether=1) - DIN 53170 7.2 Antoine Constant A # kPa. °C - 6.31286 Antoine Constant B # kPa. °C - 1449.92 Antoine Constant C # kPa. °C - 220.093 28 Methyl Isobutyl Ketone April 2016 Temperature Limits for Antoine Equation # °C - -20 to +120 Vapour Pressure at 20°C kPa Calculated 1.9 Vapour Pressure at 50°C kPa Calculated 8.8 Saturated Vapor Concentration at 20°C g/m3 Calculated 77 Volatile Organic Compound (VOC) g/l EU / EPA 800 Flash Point (Abel) °C IP 170 15 Auto Ignition Temperature
    [Show full text]
  • Ketones Acetone, MEK, MIBK, DIBK, and DAA
    KETONES Acetone, MEK, MIBK, DIBK, and DAA Shell Chemicals 2 KETONES ARE STRONG POLAR SOLVENTS AND ARE USed IN A VARIETY OF APPLICATIONS INCLUDING: ■■ Paints and coatings (major end use) ■■ Adhesives ■■ Magnetic tape ■■ Inks ■■ Cleaning ■■ Aerospace ■■ Extraction Ketones IF YOU WANT TO KNOW WHERE WE CAN Take YOU, LOOK AT WHERE WE’VE beeN From the beginning, Shell chemical companies products. We are committed to being leading- have built a reputation for a broad product edge suppliers in today’s global marketplace. range, technical expertise and manufacturing excellence. We are one of the largest Although Shell Chemicals have continued to petrochemical concerns in the world with develop new solvent alternatives, we have manufacturing facilities in 13 countries and maintained our commitment to our core solvent marketing hubs in 3 global regions with products, including hydrocarbon solvents, customer service covering 55 countries. alcohols, glycol ethers and ketone solvents. Shell pioneered the use of ketone solvents, has We draw on more than 80 years of manufacturing sites in Europe, and is a major experience in the solvents business and global supplier. Shell maintains an excellent provide assistance to customers regarding global supply position to satisfy anticipated solvent selection, solvent regulations and demand for the ketone family of solvents. general HSSE support. It is this commitment Figure 1 gives the typical properties for the and customer focus that allow us to remain an ketones available from Shell Chemicals, industry leader. including acetone, methyl ethyl ketone (MEK), methyl isobutyl ketone (MIBK), di-isobutyl We have been producing solvents for ketone (DIBK) and diacetone alcohol (DAA).
    [Show full text]
  • Methyl Isobutyl Ketone
    HEAC 6/5/18 DRAFT Cal/OSHA Draft Substance Summary for the December 12, 2017 HEAC Meeting Substance name: Methyl isobutyl ketone CAS: 108-10-1 MW: 100.16 Synonyms: 4-Methylpentan-2-one, Hexone, 4-Methyl-2-pentanone Molecular formula: C6H12O Structural formula: 1 ppm to 4.1 mg/m3 conversion factors at 25 oC and 760 mm/Hg: GHS Classification GHS Hazards Flammable liquids Category 2 Acute toxicity (Inhalation) Category 4 Eye irritation Category 2A Skin irritation Category 3 Specific target organ toxicity - single exposure Category 3 (Resp. irritation) Carcinogenicity Category 2 Signal Word: Danger GHS Hazard Statements H225 Highly flammable liquid and vapor. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. Physical characteristics at room temp: Colorless liquid with sweet odor Special physical characteristics if any: very low solubility with water but miscible with most organic solvents; can form explosive peroxides upon exposure to air. Page 1 of 14 HEAC 6/5/18 DRAFT Flammability and other hazards: flammable, Vapor pressure 20.2 hPa @ 20 °C Upper Explosive Limit: 8% Lower Explosive Limit: 1.2% Major commercial form(s): liquid Uses/applications: a solvent for nitrocellulose, lacquers, gums, paints, polymers, varnishes, resins and surface coatings. Also used as precursor to N'-phenyl-p-phenylenediamine (6PPD), an anti- oxidant used in rubber and other elastomeric compounds and in manufacturing fungicides, pharmaceuticals, germicides and electroplating solutions. Also found in adhesives, food packaging, denatured alcohol and in synthetic flavorings (it is found naturally in food.) Occupations with Potential Exposure to MIBK Occupational exposures to MIBK occur in such industries as tire manufacturing, spray painting and industrial coating applicators.
    [Show full text]
  • “Inert” Ingredients Used in Organic Production
    “Inert” Ingredients Used in Organic Production Terry Shistar, PhD A Beyond Pesticides Report he relatively few registered pesticides allowed in organic production are contained in product formulations with so-called “inert” ingredients that are not disclosed on the T product label. The “inerts” make up the powder, liquid, granule, or spreader/sticking agents in pesticide formulations. The “inerts” are typically included in products with natural or synthetic active pesticide ingredients recommended by the National Organic Standards Board (NOSB) and listed by the National Organic Program (NOP) on the National List of Allowed and Prohibited Substances. Any of the pesticides that meet the standards of public health and environmental protection and organic compatibility in the Organic Foods Production Act (OFPA) may contain “inert” ingredients. Because the standards of OFPA are different from those used by the U.S. Environmental Protection Agency (EPA) to regulate pesticides and given changes in how the agency categorizes inerts, the NOSB has adopted a series of recommendations since 2010 that established a substance review process as part of the sunset review. NOP has not followed through on the Board’s recommendations and, as a result, there are numerous materials in use that have not been subject to OFPA criteria. This report (i) traces the history of the legal requirements for review by the NOSB, (ii) identifies the universe of toxic and nontoxic materials that make of the category of “inerts” used in products permitted in organic production, and (iii) suggests a path forward to ensure NOSB compliance with OFPA and uphold the integrity of the USDA organic label.
    [Show full text]
  • US EPA, Inert
    Inert Ingredients ordered alphabetically by Chemical Name Updated August 2004 CAS PREFIX NAME 1 (POE) 6 Tridecyl ether phosphate, reaction prod3 68954-84-7 (Poly(oxy-1,2-ethanediyl), alpha-nonylphenyl)-o 3 6798-76-1 Abietic acid, zinc salt 3 14351-66-7 Abietic acids, sodium salts 3 64-19-7 Acetic acid 4B Acetic acid ethenyl ester, polymer with carbon 26337-35-9 monoxide and ethene 4B Acetic acid ethenyl ester, polymer with ethanol and alpha-2-propenyl-omega-hydroxypoly(oxy- 137091-12-4 1,2-ethandiyl) 4B Acetic acid, [(5-chloro-8-quinolinyl)oxy]-, 1- 99607-70-2 methylhexyl ester (9CI) 4B 631-61-8 Acetic acid, ammonium salt 4B 123-86-4 Acetic acid, butyl ester 3 108419-35-8 Acetic acid, C11-14 branched, alkyl ester 3 90438-79-2 Acetic acid, C6-8-branched alkyl esters 3 108419-32-5 Acetic acid, C7-9 branched, alkyl ester C8-rich 3 Acetic acid, C9-11-branched alkyl esters, C10- 108419-34-7 rich 4B 62-54-4 Acetic acid, calcium salt 4A 2016-56-0 Acetic acid, dodecylamine salt 3 110-19-0 Acetic acid, isobutyl ester 3 127-08-2 Acetic acid, potassium salt 4A 127-09-3 Acetic acid, sodium salt 4A 108-24-7 Acetic anhydride 4B 141-97-9 Acetoacetic acid, ethyl ester 3 93-08-3 2'- Acetonaphthone 3 67-64-1 Acetone 3 75-05-8 Acetonitrile 2 98-86-2 Acetophenone 4B 828-00-2 6- Acetoxy-2,4-dimethyl-m-dioxane 3 32388-55-9 Acetyl cedrene 3 77-90-7 Acetyl tributyl citrate 4B 1506-02-1 6- Acetyl-1,1,2,4,4,7-hexamethyl tetralin 3 21145-77-7 Acetyl-1,1,3,4,4,6-hexamethyltetralin 3 61788-48-5 Acetylated lanolin 3 91994-94-4 Acetylated lanolin alcohol 4B 74-86-2
    [Show full text]
  • Epa Hazardous Waste Codes
    EPA HAZARDOUS WASTE CODES Code Waste description Code Waste description D001 Ignitable waste D023 o-Cresol D002 Corrosive waste D024 m-Cresol D003 Reactive waste D025 p-Cresol D004 Arsenic D026 Cresol D005 Barium D027 1,4-Dichlorobenzene D006 Cadmium D028 1,2-Dichloroethane D007 Chromium D029 1,1-Dichloroethylene D008 Lead D030 2,4-Dinitrotoluene D009 Mercury D031 Heptachlor (and its epoxide) D010 Selenium D032 Hexachlorobenzene D011 Silver D033 Hexachlorobutadiene D012 Endrin(1,2,3,4,10,10-hexachloro-1,7-epoxy- D034 Hexachloroethane 1,4,4a,5,6,7,8,8a-octahydro-1,4-endo, endo- 5,8-dimeth-ano-naphthalene) D035 Methyl ethyl ketone D013 Lindane (1,2,3,4,5,6-hexa- D036 Nitrobenzene chlorocyclohexane, gamma isomer) D037 Pentachlorophenol D014 Methoxychlor (1,1,1-trichloro-2,2-bis [p- methoxyphenyl] ethane) D038 Pyridine D015 Toxaphene (C10 H10 Cl8, Technical D039 Tetrachloroethylene chlorinated camphene, 67-69 percent chlorine) D040 Trichlorethylene D016 2,4-D (2,4-Dichlorophenoxyacetic acid) D041 2,4,5-Trichlorophenol D017 2,4,5-TP Silvex (2,4,5- D042 2,4,6-Trichlorophenol Trichlorophenoxypropionic acid) D043 Vinyl chloride D018 Benzene D019 Carbon tetrachloride D020 Chlordane D021 Chlorobenzene D022 Chloroform B-1 EPA HAZARDOUS WASTE CODES (Continued) Code Waste description Code Waste description HAZARDOUS WASTE FROM NONSPECIFIC solvents: cresols, cresylic acid, and SOURCES nitrobenzene; and the still bottoms from the recovery of these solvents; all spent solvent F001 The following spent halogenated solvents mixtures/blends containing, before use, a used in degreasing: Tetrachloroethylene, total of ten percent or more (by volume) of trichlorethylene, methylene chloride, 1,1,1- one or more of the above nonhalogenated trichloroethane, carbon tetrachloride and solvents or those solvents listed in F001, chlorinated fluorocarbons; all spent solvent F002, and F005; and still bottoms from the mixtures/blends used in degreasing recovery of these spent solvents and spent containing, before use, a total of ten solvent mixtures.
    [Show full text]
  • Reductive Condensation of Acetone to Methyl Isobutyl Ketone on a Bifunctional Catalyst*
    Reductive Condensation of Acetone to Methyl Isobutyl Ketone on a Bifunctional Catalyst* aD. BOMBO§, bGr. BOZGA**, aM. BOMBOČJ, aA. §TEFAN, and aL STANCIU a Chemical Research institute ICECHIM, 772 08 Bucharest, Romania b Polytechnical University, Department of Chemical Engineering, 772 06 Bucharest, Romania e-mail: [email protected] Received 14 June 1999 The methyl isobutyl ketone (MIBK) was obtained in vapour phase, from acetone and hydrogen in a single step, using Pd/(Zn) H-ZSM-5 as a catalyst. The chemical transformation occurs in a sequence of two steps, acetone condensation to mesityl oxide on the acidic sites of zeolite, followed by the mesityl oxide hydrogenation to MIBK on the palladium metallic sites. The experiments were performed in a continuous fixed bed reactor at 0.5 MPa, 135—210 °C, hydrogen/acetone mole ratios of 0.5—9, and acetone mass hourly space velocity of 0.15—1 h_1. The experimental data showed that the hydrogenation step occurs very fast compared with the condensation one, the intermediary mesityl oxide not being identified in the reaction mixture. The obtained acetone conversion was up to 55 % and MIBK selectivity between 83 % and 94 %. A kinetic model was also proposed, assuming that the overall process rate is controlled by the acetone condensation step. Methyl isobutyl ketone (MIBK) is used mainly as Industrially, the MIBK synthesis is performed in organic solvent for paints and varnishes, or for the a single stage by direct catalytic reaction of acetone preparation of other chemical products (stabilizers, with hydrogen, on a bifunctional catalyst containing etc.). As a solvent, MIBK is considered environmen­ a metal (usually Pd) supported on solid acids.
    [Show full text]