DOCSLIB.ORG

Synthetic Studies in Oxygen Heterocycles

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Synthetic Studies in Oxygen Heterocycles A Thesis Entitled SYNTHETIC STUDIES IN OXYGEN HETEROCYCLES Submitted to Goa University for the Award of the Degree of DOCTOR OF PHILOSOPHY In CHEMISTRY By Ms. MAYURI MADHUKER NAIK M. Sc. Under the Guidance of PROF. VIJAYENDRA P. KAMAT Department of Chemistry and PROF. SANTOSH G. TILVE Department of Chemistry GOA UNIVERSITY Taleigao Plateau, Goa 403 206 INDIA APRIL 2018 A Thesis Entitled SYNTHETIC STUDIES IN OXYGEN HETEROCYCLES Submitted to Goa University for the Award of the Degree of DOCTOR OF PHILOSOPHY In CHEMISTRY By Ms. MAYURI MADHUKER NAIK M. Sc. Under the Guidance of PROF. VIJAYENDRA P. KAMAT Department of Chemistry and PROF. SANTOSH G. TILVE Department of Chemistry GOA UNIVERSITY Taleigao Plateau, Goa 403 206 INDIA APRIL 2018 DEPARTMENT OF CHEMISTRY CERTIFICATE This is to certify that the thesis entitled, “ Synthetic Studies in Oxygen Heterocycles ” submitted by Ms. MAYURI MADHUKER NAIK , is a record of research work carried out by the candidate during the period of study under our supervision and that it has not previously formed the basis for the award of any degree or diploma or other similar titles. Goa University Prof. Vijayendra P. Kamat Prof. Santosh G. Tilve April 2018 Research Guide Research Guide Department of Chemistry Department of Chemistry Goa University Goa University DECLARATION I hereby declare that the work embodied in the thesis entitled “ Synthetic Studies in Oxygen Heterocycles ” is the result of investigations carried out by me under the guidance of PROF. VIJAYENDRA P. KAMAT and PROF. SANTOSH G. TILVE at Department of Chemistry, Goa University and that it has not previously formed the basis for the award of any degree or diploma or other similar titles. In keeping with the general practice of reporting scientific observations, due acknowledgement has been made wherever the work described is based on the findings of other investigators. Goa University Ms. Mayuri M. Naik April 2018 Ph. D. Student Department of Chemistry Goa University ACKNOWLEDGEMENT Ph. D. is a degree for which to achieve one has to go through several barriers in life. Also it cannot be complete without the direct or indirect help and support from various people. So, at the final stage of my Ph. D. course I would like to take the opportunity to thank all the people who helped me at different stages and without whom it would have not been possible to complete the thesis. At the outset I would like to express my deep sense of gratitude to both my supervisors Prof. V. P. Kamat (former registrar, Goa University) and Prof. S. G. Tilve (former Head, Department of Chemistry, Goa University) for considering me and giving an opportunity to work as a research student under their valuable guidance. Their constant support, encouragement and useful suggestions helped me to work in right direction and inculcated broad research thinking. I really appreciate their immense knowledge, patience and the freedom given to me to do research work as well as to write research articles which helped me to develop myself throughout this period. I will be always grateful to them. The role played by Prof. S. G. Tilve in my research career cannot be expressed in words. He has always been a supportive guide through his valuable guidance, suggestions, motivation and unique ideas throughout the Ph. D. course. I would like to sincerely thank Prof. Varun Sahni (Vice-chancellor, Goa University), Prof. Y. V. Reddy (Registrar, Goa University), Prof. S. Shetye (former Vice-chancellor, Goa University) and Prof. V. P. Kamat (former Registrar, Goa University) for their valuable support by allowing me to carry out my research work in this institute. I would also like to express my kind gratitude to Prof. B. R. Srinivasan (Head, Department of Chemistry, Goa University), Prof. Gourish M. Naik (Dean, Natural Sciences, Goa University), Prof. J. A. E. Desa and Prof. A. V. Salkar (Former Deans) for providing necessary facilities for my research work. I sincerely acknowledge my subject experts, Dr. Jayant Umarye (Head, R & D, Godrej Agrovet Ltd., Mumbai & former group leader, Syngenta Biosciences Pvt. Ltd., Goa) and Dr. Sandesh Bugde (Assistant Professor in Chemistry, Parvatibai Chowgule college of Arts and Science) for providing the much needed insights into my subject. I also acknowledge Prof. V. S. Nadkarni and Prof. B. R. Srinivasan for their expert advice whenever required. I would like to deeply acknowledge Human Resource Development Group-Council of Scientific and Industrial Research (HRDG -CSIR) , New Delhi for providing me financial assistance through NET - Junior and Senior Research Fellowships for 5 years. I express my sincere gratitude towards all my teachers Prof. K. S. Rane, Prof. J. B. Fernandes, Prof. S. P. Kamat, Prof. S. G. Tilve, Prof. V. P. Kamat, Prof. A. V. Salkar, Prof. B. R. Srinivasan , Prof. V. S. Nadkarni , Dr. V. M. S. Verenkar , Dr. R. N. Shirsat , Dr. S. N. Dhuri and Mrs. Siddhali Rajadhyaksha for their valuable teaching and motivational talks from which I could learn a lot. Also, I thank the present faculty members Dr. Mahesh Majik , Dr. Kanchanmala , Dr. Kashinath , Dr. Pranay , Dr. Bhanudas , Dr. Prachi and Dr. Sonia for their help and goodwill. I also thank former faculty Dr. Gururaja for his helpful discussions on NMR spectra. I also thank Dr. J. K. Kirtany and Dr. Lisette Dsouza for their valuable suggestions during my Ph. D. course. I also express thanks to my B. Sc. Chemistry teachers Dr. Beena Vernekar and Mrs. Jaqueline Fernandes for their teaching method, encouragement and developing interest in chemistry. I am also thankful to Dr. Gopakumar (Librarian, Goa University) for his assistance in the plagiarism check of thesis. I also acknowledge the staff members of Library and administrative members Goa University for being kind and helpful. I also thank all the non- teaching staff, Department of Chemistry, Goa University for helping at numerous times. I am thankful to Prof. Sanjeev Ghadi (Department of Biotechnology, Goa University) and Dr. Surya Nandan Meena for performing anti-diabetic studies of my samples. I acknowledge Indian Institute of Science (IISc) , Bangalore and Syngenta Biosciences Pvt., Ltd. , Goa for providing the HRMS facility. I also thank Sophisticated Analytical Instrument Facility-Indian Institute of Technology (SAIF-IIT) , Bombay for providing ICP-MS data. I immensely thank my seniors Dr. Kashinath , Dr. Sandesh and Dr. Prachi for helping me and providing tremendous support in all the possible ways at difficult times during this course. I also appreciate their funny acts, joyful moments, fruitful research discussions and motivational talks which helped me to enjoy as well as boost up my research work. I also express my sincere thanks to all my group members Dr. Mahesh, Dr. Rupesh, Dr. Prakash, Dr. Reshma, Dr. Sonia, Dr. Prachi, Dr. Chinmay , Dr. Hari , Dr. Sagar , Dr. Prajesh , Durga and Pratibha for their constant help, encouragement, valuable discussions, suggestions and enjoyable moments. I cannot express in words the knowledge I gained and things I learnt from my group members for which I will always be grateful to them. I also acknowledge my junior group members Ketan, Shashank and Lima for pleasing working environment and Dr. Sumit for fruitful discussion. I thank Dr. Santosh Shetgaonkar , Dr. Mahesh Majik , Dr. Amit Vernekar , Dipesh Harmalkar and Dr. Siddhi for providing the required references. Also, I am thankful to Dr. Santosh for helping me in providing LCMS data of some of my samples. I also offer my thanks to Dr. Chinmay , Dr. Kashinath , Dr. Sandesh , Dr. Hari , Dr. Prajesh and Dr. Sagar for providing great help by recording NMR spectra of my samples in the beginning of my research work. I am greatful to Dr. Kashinath , Dr. Prachi , Durga , Dr. Sandesh and Ashwini for helping me in editing my thesis. I would like to extend my thanks to all my senior and present colleagues Dr. Vidhya , Dr. Nitya , Dr. Rajesh , Dr. Shrikant , Dr. Lactina , Dr. Vinod , Dr. Priyanka , Dr. Savia , Dr. Sulaksha , Dr. Jose , Dr. Satish , Dr. Rohan , Dr. Umesh , Dr. Kiran , Dr. Mithil , Rita , Savita , Dr. Diptesh , Dattaprasad , Satu , Shambhu , Dr. Madhavi , Mira , Kedar , Vishal , Abhijeet , Daniel , Dr. Celia , Pratik , Apurva , Prajyoti , Chandan , Sarvesh , Madhavi , Johnross , Vishnu , Sudarshana , Pooja , Neha , Sudesh , Rahul and Amarja for making days enjoyable at university. Also, I thank my friends Roma , Samrudhi , Belinda , Sejal , Bindiya , Harshada , Pratiksha , Poonam , Nitesh , Madhukar , Manjunath , Dr. Dinesh , Anupa , Palmira , Shilpa , Sonam , Neclin , Mahesh , Santosh , Dr. Kiran and Dr. Pradnyesh for their warm friendship. I am also very thankful to Dr. V. J. Pissurlekar (The principal, P. E. S’s. R. S. N. college of arts and science), Dr. Anita S. Tilve (M. Sc. co-ordinator) and all my colleagues of chemistry department for their support during my working period. Also I am very much thankful to Dr. Nandkumar N. Sawant (The principal, Parvatibai Chowgule college of arts and science) and all my senior colleagues of chemistry department from the presently working college for their help and support. I am deeply thankful to my father late Mr. Madhuker M. Naik for raising me with love, affection, good moral values and constant encouragement for higher studies. Also my mother Mrs. Madhavi M. Naik enabled me to study further by her extreme hard work, motivation, freedom and I thank her for always being a pillar of support. I am at loss of words to express their love and support offered to me for which I will be always grateful to them. Without them I would not have been able to reach at this stage of my career. The funny acts of my elder brother Mandar helped me to overcome the tensions and he also encouraged to work hard with his kind words. Also I thank my other family members from the bottom of my heart for constantly encouraging me and providing love, care and support throughout my life.
Load more

Recommended publications
  • Inorganic Selenium and Tellurium Speciation in Aqueous Medium of Biological Samples
    1 INORGANIC SELENIUM AND TELLURIUM SPECIATION IN AQUEOUS MEDIUM OF BIOLOGICAL SAMPLES ________________________ A Thesis Presented to The Faculty of the Department of Chemistry Sam Houston State University ________________________ In Partial fulfillment Of the Requirements for the Degree of Master of Science ________________________ by Rukma S. T. Basnayake December, 2001 2 INORGANIC SELENIUM AND TELLURIUM SPECIATION IN AQUEOUS MEDIUM OF BIOLOGICAL SAMPLES by Rukma S.T. Basnayake _______________________________ APPROVED: ________________________________ Thomas G. Chasteen, Thesis Director ________________________________ Paul A. Loeffler ________________________________ Benny E. Arney Jr. APPROVED: _____________________________ Dr. Brian Chapman, Dean College of Arts and Sciences 3 ABSTRACT Basnayake, Rukma ST, Inorganic Selenium and Tellurium Speciation in Aqueous Medium of Biological Samples, Master of Science (Chemistry), December 2001, Sam Houston State University, Huntsville, Texas, 60 pp. Purpose The purpose of this research was to develop methods to study the ability of bacteria, Pseudomonas fluorescens K27 to detoxify tellurium and selenium salts by biotransformation processes under anaerobic conditions. Another purpose was to make an effort to separate biologically produced Se0 from cells. Methods Pseudomonas fluorescens K27 was grown in TSN3 medium (tryptic soy broth with 0.3% nitrate) under anaerobic conditions and the production of elemental tellurium and elemental selenium was observed when amended with inorganic tellurium salts and selenium salts, respectively. The amount of soluble tellurium species in the culture medium also was determined. Samples from a 2.75 L bioreactor were taken after cultures had reached the stationary growth phase and were centrifuged in order to separate insoluble species (elemental tellurium, elemental selenium) from soluble species (oxyanions of tellurium, oxyanions of selenium).
    [Show full text]
  • Download Download
    Preparation of Telluric Acid from Tellurium Dioxide by Oxidation with Potassium Permanganate Frank C. Mathers, Charles M. Rice, Howard Broderick, and Robert Forney, Indiana University General Statement Tellurium dioxide, Te0 2 , although periodically similar to sulfur dioxide, cannot be oxidized by nitric acid to the valence of six, i.e., to telluric acid, H 2 Te04.2H 2 0. Among the many stronger oxidizing agents that will produce this oxidation, potassium permanganate in a nitric acid solution is quite satisfactory. This paper gives directions and data for the preparation of telluric acid by this reaction. The making of telluric acid is a desirable laboratory experiment because (1) tellurim dioxide is available in large quantities and is easily obtained, (2) the telluric acid is a stable compound, easily purified, easily crystallized, and non-corrosive, and (3) students are interested in experimenting with the rarer elements. The small soluibility of telluric acid and the high solubility of both manganese and potassium nitrates in nitric acidi gives a sufficient differ- ence in properties for successful purification by crystallization of the telluric acid. Methods of Analyses Tellurium dioxide can be volumetrically 2 titrated in a sulfuric acid solution by an excess of standard potassium permanganate, followed by enough standard oxalic acid to decolorize the excess of permanganate. The excess of oxalic acid must then be titrated by more of the perman- ganate. The telluric acid can be titrated, like any ordinary monobasic acid, 3 (1911). with standard sodium hydroxide using phenolphthalein as an indicator, if an equal volume of glycerine is added. If any nitric acid is present, it must be neutralized first with sodium hydroxide, using methyl orange as indicator.
    [Show full text]
  • Developing a Method for Determining the Mass Balance of Selenium and Tellurium Bioprocessed by a Selenium-Resistant Bacterium Grown in The
    Developing a Method for Determining the Mass Balance of Selenium and Tellurium Bioprocessed by a Selenium-Resistant Bacterium Grown in the Presence of Selenite or Tellurite __________________ A Thesis Presented to The Faculty of the Department of Chemistry Sam Houston State University ____________________ In Partial Fulfillment Of the Requirements for the Degree of Master of Science ____________________ by Janet Horton Bius December, 2001 Developing a Method for Determining the Mass Balance of Selenium and Tellurium Bioprocessed by a Selenium-Resistant Bacterium Grown in the Presence of Selenite or Tellurite by Janet Horton Bius ____________________ Approved: _____________________________ Thomas G. Chasteen ____________________________ Mary F. Plishker ____________________________ Rick C. White Approved: ____________________________ Brian Chapman, Dean College of Arts and Sciences II ABSTRACT Bius, Janet Horton, Developing a Method for Determining the Mass Balance of Selenium and Tellurium Bioprocessed by a Selenium-Resistant Bacterium Grown in the Presence of Selenite or Tellurite, Master of Science (Chemistry), December, 2001. Sam Houston State University, Hunts- ville, Texas, 68 pp. Purpose The purpose of this investigation was to determine: (1) the mass balance of selenium or tellurium that was bioreduced when a selenium-resistant facultative anaerobe was amended with either selenium or tellurium; and (2) methods to analyze for these metalloids in biological samples. Methods Analytical methods were developed for the determination of
    [Show full text]
  • PHCOG RES.: Research Article Investigation of the Flavonoidal Constituents and Insecticidal Activity of Teucrium Zanonii
    Pharmacognosy Research [Phcog Res] Vol 1, Issue 6, Nov-Dec, 2009 Page 410-416 (An Official Publication of Pharmacognosy Network Worldwide) Received: 29 09, 2009 Modified: 12 10, 2009 Accepted: 12 00, 2009 PHCOG RES.: Research Article Investigation of the flavonoidal constituents and insecticidal activity of Teucrium zanonii Abdelshafeek Khaled A.1,2,*, Abdelrahem Fahem2, Elwahsh Mohemmed A.1 and Abdelkhalek Ismail A.3 1 Altahadi University, Faculty of Science, Chemistry Department, Sirt, Libya, P.O. 674. 2 National Research Center, phytochemistry Department, Dokki, Cairo, Egypt.3 3 National Research Center, pests and plant protection Department, Dokki, Cairo, Egypt.3 * Corresponding author: e-mail: [email protected] ABSTRACT Teucrium zanonii (Family labiateae) is an endemic Libyan plant growing in many regions around Benghazy city. Investigation of the flavonoidal constituents of plant led to isolation of Cirsiliol, Luteolin, Chrysoeriol and Xanthomicrol from ethyl acetate fraction while Apigenin 6,8-di-O-glucoside and Luteolin-7-O-rutinoside were isolated from the butanol fraction. All compounds were identified by chromatographic and spectroscopic methods (UV, MS, 1H and 13C NMR spectroscopy). The study of insecticidal activity of different extracts of the plant against the adult of Phloeotribus oleae showed the highest effect (86.67% mortality) was observed with the aqueous extract, while the unsaponifiable fraction was the least in this concern which give only 43.33% mortality,. Also, mortalities of 83.33%, 80.00%, 70.00% and 66.67% were obtained by using of alcoholic, butanol, ethyl acetate and chloroform extracts, respectively. Also the filed experiments proved that aqueous, alcoholic and butanol extracts significantly lowered the percentage of infestation to 70.82%, 65.86% and 66.56%, respectively after one week.
    [Show full text]
  • (%.(Zwj-2Mk Date
    The behavior of tellurium during copper ore processing at the American Smelting and Refining Company (Tucson, AZ) Item Type Thesis Authors Josephson, Amy E. Download date 10/10/2021 10:50:30 Link to Item http://hdl.handle.net/11122/6826 THE BEHAVIOR OF TELLURIUM DURING COPPER ORE PROCESSING AT THE AMERICAN SMELTING AND REFINING COMPANY (TUCSON, AZ) By Amy E. Josephson RECOMMENDED: \k/ — Dr. Rainer J. Newberry Dr. Thomas P. Trainor Dr. Sarah M. Hayes Advisory Committee Chair Dr. Thomas K. Green Chair, Department of Chemistry and Biochemistry APPROVED: Dr. Paul W. Layer Dean, College of Nat and Mathematics Dean of the Graduate School ... (%.(ZwJ-2Mk Date / THE BEHAVIOR OF TELLURIUM DURING COPPER ORE PROCESSING AT THE AMERICAN SMELTING AND REFINING COMPANY (TUCSON, AZ) By Amy E. Josephson, B.S. A Thesis Submitted in Partial Fulfillment of the Requirements for the Degree of Master of Science in Environmental Chemistry University of Alaska Fairbanks August 2016 APPROVED: Sarah M. Hayes, Committee Chair Rainer J. Newberry, Committee Member Thomas P. Trainor, Committee Member Thomas K. Green, Chair Department of Chemistry and Biochemistry Paul W. Layer, Dean College of Natural Science and Mathematics Michael A. Castellini, Dean of the Graduate School Abstract Essentially all tellurium (Te), an element used in solar panels and other high technology devices, is recovered as a byproduct of copper mining. Recent increases in demand have sparked questions of long-term supplies of Te (crustal abundance ~3 pg-kg"1). As part of a larger study investigating Te resources, this project examines the behavior of Te during Cu ore mining, smelting, and refining at the American Smelting and Refining Company (Tucson, AZ) as a first step toward optimizing Te recovery.
    [Show full text]
  • List of Lists
    United States Office of Solid Waste EPA 550-B-10-001 Environmental Protection and Emergency Response May 2010 Agency www.epa.gov/emergencies LIST OF LISTS Consolidated List of Chemicals Subject to the Emergency Planning and Community Right- To-Know Act (EPCRA), Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and Section 112(r) of the Clean Air Act • EPCRA Section 302 Extremely Hazardous Substances • CERCLA Hazardous Substances • EPCRA Section 313 Toxic Chemicals • CAA 112(r) Regulated Chemicals For Accidental Release Prevention Office of Emergency Management This page intentionally left blank. TABLE OF CONTENTS Page Introduction................................................................................................................................................ i List of Lists – Conslidated List of Chemicals (by CAS #) Subject to the Emergency Planning and Community Right-to-Know Act (EPCRA), Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and Section 112(r) of the Clean Air Act ................................................. 1 Appendix A: Alphabetical Listing of Consolidated List ..................................................................... A-1 Appendix B: Radionuclides Listed Under CERCLA .......................................................................... B-1 Appendix C: RCRA Waste Streams and Unlisted Hazardous Wastes................................................ C-1 This page intentionally left blank. LIST OF LISTS Consolidated List of Chemicals
    [Show full text]
  • Laboratory and Chemical Storage Areas Must Be Kept Locked When Not in Use
    CHEMICAL HYGIENE PLAN AND HAZARDOUS MATERIALS SAFETY MANUAL FOR LABORATORIES This is the Chemical Hygiene Plan specific to the following areas: Laboratory name or room number(s): ___________________________________ Building: __________________________________________________________ Supervisor: _______________________________________________________ Department: _______________________________________________________ EMERGENCY TELEPHONE NUMBERS: 911 for Emergency and urgent consultation 3-2035 MSU Police; 3-2066 Facilities Management 3-2179 or (606) 207-0629 Eddie Frazier, Director of Risk Management 3-2584 or (606) 207-9425 Holly Niehoff, Environmental Health & Safety Specialist 3-2099 Derek Lewis, Environmental Health & Safety Technician 3-______ Building Supervisor State 24-hour warning point for HAZMAT Spill Notification If you need to report a spill in accordance with SARA Title III Section 304 and KRS 39E.190, please contact the Duty Officer at the Commonwealth Emergency Operations Center at 800.255.2587 which serves as the twenty-four (24) hour warning point and contact for the Commonwealth Emergency Response Commission. Updated 2018 All laboratory chemical use areas must maintain a work-area specific Chemical Hygiene Plan which conforms to the requirements of the OSHA Laboratory Standard 29 CFR 19190.1450. Morehead State UniversityMorehead laboratories State may Chemical use this document Hygiene Plan as a starting point for creating their work area specific Chemical Hygiene Plan (CHP). MSU Laboratory Awareness Certification For CHP of (Professor, Building, Room)________________________ The Occupational Safety and Health Administration (OSHA) requires that laboratory employees be made aware of the Chemical Hygiene Plan at their place of employment (29 CFR 1910.1450). The Morehead State University Chemical Hygiene Plan and Hazardous Materials Safety Manual serves as the written Chemical Hygiene Plan (CHP) for laboratories using chemicals at Morehead State University.
    [Show full text]
  • Metals-10-01176.Pdf
    metals Article Selective Recovery of Tellurium from the Tellurium-Bearing Sodium Carbonate Slag by Sodium Sulfide Leaching Followed by Cyclone Electrowinning Zhipeng Xu 1,2,3, Zoujiang Li 1,2, Dong Li 1,2, Xueyi Guo 1,2,*, Ying Yang 1,2, Qinghua Tian 1,2,* and Jun Li 1,2 1 School of Metallurgy and Environment, Central South University, Changsha 410083, China; [email protected] (Z.X.); [email protected] (Z.L.); [email protected] (D.L.); [email protected] (Y.Y.); [email protected] (J.L.) 2 National & Regional Joint Engineering Research Center of Nonferrous Metal Resource Recycling, Changsha 410083, China 3 First Materials Co., Ltd., Qingyuan 511517, China * Correspondence: [email protected] (X.G.); [email protected] (Q.T.); Tel.: +86-731-8887-6255 (X.G.); +86-731-8887-7863 (Q.T.) Received: 27 July 2020; Accepted: 19 August 2020; Published: 1 September 2020 Abstract: The rigorous environmental requirements promote the development of new processes with short and clean technical routes for recycling tellurium from tellurium-bearing sodium carbonate slag. In this paper, a novel process for selective recovery of tellurium from the sodium carbonate slag by sodium sulfide leaching, followed by cyclone electrowinning, was proposed. 88% of tellurium was selectively extracted in 40 g/L Na2S solution at 50 ◦C for 60 min with a liquid to solid ratio of 8:1 mL/g, while antimony, lead and bismuth were enriched in the leaching residue. Tellurium in the leach liquor was efficiently electrodeposited by cyclone electrowinning without purification. The effects of current density, temperature and flow rate of the electrolyte on current efficiency, tellurium recovery, cell voltage, energy consumption, surface morphology, and crystallographic orientations were systematically investigated.
    [Show full text]
  • Alternative Electrochemical Salt Waste Forms, Summary of FY11-FY12 Results
    CRADA-PROTECTED INFORMATION Alternative Electrochemical Salt Waste Forms, Summary of FY11-FY12 Results Prepared for U.S. Department of Energy B.J. Riley, J.S. McCloy, J.V. Crum, W.C. Lepry, C.P. Rodriguez, C.F. Windisch Jr., J. Matyas, M.P. Westman, B.T. Rieck, J.B. Lang, M.J. Olszta, and D.A. Pierce Pacific Northwest National Laboratory January 17, 2014 FCRD-SWF-2013-000025, Rev.1 PNNL-22034 CRADA-PROTECTED INFORMATION CRADA-PROTECTED INFORMATION DISCLAIMER This information was prepared as an account of work sponsored by an agency of the U.S. Government. Neither the U.S. Government nor any agency thereof, nor any of their employees, makes any warranty, expressed or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness, of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. References herein to any specific commercial product, process, or service by trade name, trade mark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the U.S. Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the U.S. Government or any agency thereof. CRADA-PROTECTED INFORMATION Alternative Electrochemical Salt Waste Forms, Summary of FY11-FY12 Results January 17, 2014 iii SUMMARY The Fuel Cycle Research and Development Program, sponsored by the U.S. Department of Energy Office of Nuclear Energy, is currently investigating alternative waste forms for wastes generated from nuclear fuel processing.
    [Show full text]
  • Chemical Compatibility Storage Group
    CHEMICAL SEGREGATION Chemicals are to be segregated into 11 different categories depending on the compatibility of that chemical with other chemicals The Storage Groups are as follows: Group A – Compatible Organic Acids Group B – Compatible Pyrophoric & Water Reactive Materials Group C – Compatible Inorganic Bases Group D – Compatible Organic Acids Group E – Compatible Oxidizers including Peroxides Group F– Compatible Inorganic Acids not including Oxidizers or Combustible Group G – Not Intrinsically Reactive or Flammable or Combustible Group J* – Poison Compressed Gases Group K* – Compatible Explosive or other highly Unstable Material Group L – Non-Reactive Flammable and Combustible, including solvents Group X* – Incompatible with ALL other storage groups The following is a list of chemicals and their compatibility storage codes. This is not a complete list of chemicals, but is provided to give examples of each storage group: Storage Group A 94‐75‐7 2,4‐D (2,4‐Dichlorophenoxyacetic acid) 94‐82‐6 2,4‐DB 609-99-4 3,5-Dinitrosalicylic acid 64‐19‐7 Acetic acid (Flammable liquid @ 102°F avoid alcohols, Amines, ox agents see SDS) 631-61-8 Acetic acid, Ammonium salt (Ammonium acetate) 108-24-7 Acetic anhydride (Flammable liquid @102°F avoid alcohols see SDS) 79‐10‐7 Acrylic acid Peroxide Former 65‐85‐0 Benzoic acid 98‐07‐7 Benzotrichloride 98‐88‐4 Benzoyl chloride 107-92-6 Butyric Acid 115‐28‐6 Chlorendic acid 79‐11‐8 Chloroacetic acid 627‐11‐2 Chloroethyl chloroformate 77‐92‐9 Citric acid 5949-29-1 Citric acid monohydrate 57-00-1 Creatine 20624-25-3
    [Show full text]
  • Agrilife Hazcom Program
    TEXAS AGRILIFE RESEARCH AND TEXAS AGRILIFE EXTENSION HAZARD COMMUNICATION PROGRAM Revised August 2010 Table of Contents INTRODUCTION: ..................................................................................................................................... 3 PROGRAM EXEMPTIONS AND EXCEPTIONS ................................................................................. 3 RESEARCH LABORATORY EXEMPTIONS ....................................................................................... 4 DUTIES AND RESPONSIBILITIES ........................................................................................................ 4 THE SAFETY COORDINATOR .................................................................................................................. 4 THE CENTER DIRECTOR ......................................................................................................................... 4 THE SAFETY OFFICER ............................................................................................................................. 5 SUPERVISORS ........................................................................................................................................... 5 EMPLOYEES ............................................................................................................................................. 5 CONTRACTED CONSTRUCTION, REPAIR AND MAINTENANCE ............................................................. 5 HAZARDOUS CHEMICAL INVENTORY: ..........................................................................................
    [Show full text]
  • Chemical Compatibility Storage Codes1
    CHEMICAL COMPATIBILITY STORAGE CODES1 Storage Group A: Compatible Organic Bases Identifier Name 100‐46‐9 Benzylamine 100‐85‐6 Benzyltrimethylammonium hydroxide 108‐91‐8 Cyclohexylamine 111‐42‐2 Diethanolamine 109‐89‐7 Diethylamine 75‐04‐7 Ethylamine 107‐15‐3 Ethylenediamine 110‐89‐4 Piperidine 102‐71‐6 Triethanolamine 121‐44‐8 Triethylamine Storage Group B: Compatible Pyrophoric And Water Reactive Materials Identifier Name 7783‐70‐2 Antimony pentafluoride 98‐88‐4 Benzoyl chloride 353‐42‐4 Boron triflouride compound with methyl ether (1:1) 594‐19‐4 Tert‐Butyllithium 156‐62‐7 Calcium cyanamide 16853‐85‐3 Lithium aluminum hydride 4111‐54‐0 Lithium diisopropylamide 7580‐67‐8 Lithium hydride 7439‐93‐2 Lithium metal (e.g., in THF) 124‐63‐0 Methanesulfonyl chloride 917‐54‐4 Methyllithium solution (and other alkyls) 7440‐09‐7 Potassium metal 17242‐52‐3 Potassium amide 16940‐66‐2 Sodium borohydride 7646‐69‐7 Sodium hydride 7440‐66‐6 Zinc (fume or dust) Storage Group C: Compatible Inorganic Bases Identifier Name 1336‐21‐6 Ammonium hydroxide 17194‐00‐2 Barium hydroxide 1305‐62‐0 Calcium hydroxide 21351‐79‐1 Cesium hydroxide 1310‐65‐2 Lithium hydroxide 1 Adapted from Stanford University’s ChemTracker Storage System. Used with permission from Lawrence M. Gibbs, Stanford University. 1310‐58‐3 Potassium hydroxide 1310‐82‐3 Rubidium hydroxide 1310‐73‐2 Sodium hydroxide 18480‐07‐4 Strontium hydroxide Storage Group D: Compatible Organic Acids Identifier Name 64‐19‐7 Acetic acid 79‐10‐7 Acrylic acid 65‐85‐0 Benzoic acid 98‐07‐7 Benzotrichloride 98‐88‐4
    [Show full text]