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IUPAC–NIST Solubility Data Series #. Transition and 12 to 14 Main Group Metals, Lanthanide, Actinide and Ammonium Halates

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IUPAC–NIST Solubility Data Series #. Transition and 12 to 14 Main Group Metals, Lanthanide, Actinide and Ammonium Halates IUPAC–NIST Solubility Data Series #. Transition and 12 to 14 Main Group Metals, Lanthanide, Actinide and Ammonium Halates Hiroshi Miyamoto ∗ Niigata University, Niigata, Japan Ryo Miyamoto y Hirosaki University, Hirosaki, Japan Cezary Guminski University of Warsaw, Warsaw, Poland Mark Salomon Subcommittee on Solubility and Equilibrium Data, Little Silver, NJ, USA With the assistance of compilers: Christo Balarew, E. V. Zagnit'ko, Jitka Eysseltova, and J. J. Counioux (Received ; accepted ) Abstract This paper is the fourth and final volume in the halate solubility series. The sol- ubility data for halates of transition metals, lanthanides, actinides, ammonium and metallic elements of the main groups 12 to 14 are reviewed. Where appropriate binary-, ternary- and multi-component systems are critically evaluated. Most of the solubility results were obtained in water or aqueous solutions of electrolytes. The solubilities in organic solvents and aqueous–organic solvent mixtures are also col- lected in this volume. All these data were critically examined for their reliability. The best values were selected on the basis of critical evaluations and presented in tabular form. Fitting equations and graphical plots are also provided. When nu- merical data were not reported in an original publication, they were read out from figures and digitized by the compilers. The quantities, units and symbols used in this ∗Present address 1-20, Yurigaoka-cho, Mito, 311-1134, Japan yTo whom correspondence should be addressed. i volume are in accord with the IUPAC recommendations. We always reported the original data and, if necessary, transferred them into the IUPAC recommended units and symbols. The literature on the solubility data was researched through 2002. The compilations and critical evaluations have been presented in IUPAC–NIST Solubil- ity Data Series format. The halates of the mentioned metals play a role in industrial processes. For example, some halates are essential as catalysts, heat-stabilizers, and blanching reagents for manufacturing polymer products such as textiles and resins. Some iodates are used in pyrotechnic compounds for weather modification and col- ored smoke generation. The nonlinear halate crystals are important in construction of optical devices. Key words: transition metals; lanthanides; actinides; elements of main groups 12– 14; aqueous solutions; solubility; chlorates; bromates; iodates. Contents I Preface xii II Introduction to the Solubility of Solids in Liquids: Solubility of Solids in Liquids xvii A The Nature of the Project . xvii B Compilations and Evaluations . xvii C Quantities and Units Used in Compilation and Evaluation of Solubility Data . xx D Thermodynamics of Solubility . xxiv Part 1. Compilation and Evaluation of Solubility Data of Transition Metal Halates 1 III Transition Metal Chlorates 1 A Cobalt Chlorate . 1 B Nickel Chlorate . 6 IV Transition Metal Iodates 11 A Titanium Iodate . 11 B Manganese Iodate . 14 C Iron Iodate . 25 D Cobalt Iodate . 27 E Nickel Iodate . 48 F Zirconium Iodate . 67 G Hafnium Iodate . 75 Part 2. Compilation and Evaluation of Solubility Data of Halates of Metals in the Main Groups 12–14, and Ammonium Halates 79 V Chlorates of Elements in the Main Groups 12–14 and Ammonium Chlorate 79 A Zinc Chlorate . 79 B Cadmium Chlorate . 86 C Thallium Chlorate . 88 D Lead Chlorate . 97 ii E Ammonium Chlorate . 99 VI Bromates of Elements in the Main Groups 12–14 111 A Cadmium Bromate . 111 B Mercury(II) Bromate . 114 C Mercury(II) Bromate Hydroxide . 116 D Thallium Bromate . 118 E Lead Bromate . 136 VII Iodates of Elements in the Main Groups 12–14 and Ammonium Iodate 147 A Aluminum Iodate . 147 B Zinc Iodate . 163 C Gallium Iodate . 177 D Cadmium Iodate . 187 E Indium Iodate . 198 F Mercury(I) Iodate . 205 G Mercury(II) Iodate . 212 H Thallium Iodate . 213 I Lead Iodate . 263 J Ammonium Iodate . 299 Part 3. Compilation and Evaluation of Solubility Data of Scandium, Yttrium, Lan- thanum and Lanthanide Halates, and Actinide Iodates 301 VIII Yttrium, Lanthanum and Lanthanide Bromates 301 A Yttrium Bromate . 301 B Lanthanum Bromate . 306 C Praseodymium Bromate . 318 D Neodymium Bromate . 327 E Samarium Bromate . 338 F Europium Bromate . 344 G Gadolinium Bromate . 345 H Terbium Bromate . 348 I Dysprosium Bromate . 353 J Erbium Bromate . 354 K Ytterbium Bromate . 355 L Lutetium Bromate . 357 IX Scandium, Yttrium, Lanthanum and Lanthanide Iodates 358 A Scandium Iodate . 358 B Yttrium Iodate . 359 C Lanthanum Iodate . 366 D Cerium(III) Iodate . 393 E Cerium(IV) Iodate . 403 F Praseodymium Iodate . 410 G Neodymium Iodate . 420 iii H Samarium Iodate . 434 I Europium Iodate . 443 J Gadolinium Iodate . 453 K Terbium Iodate . 462 L Dysprosium Iodate . 470 M Holmium Iodate . 481 N Erbium Iodate . 489 O Thulium Iodate . 498 P Ytterbium Iodate . 508 Q Lutetium Iodate . 519 X Actinide Iodates 527 A Thorium Iodate . 527 B Uranyl Iodate . 530 System Index 535 Registry Number Index 536 Author Index 537 List of Figures 1 Partial phase diagram of the Co(ClO3)2–H2O system . 4 2 Partial phase diagram of the Ni(ClO3)2–H2O system . 9 3 Temperature dependence of solubility of Mn(IO3)2 in water . 16 4 Solubility of cobalt(II) iodate hydrates in water (The dihydrate is a cryltalline form, and the tetrahydrate and the anhydrate are metastable. *: rejected data, see footnote of Table 15) . 32 5 Solubility of nickel(II) iodate hydrates in water (The tetrahydrate form is an in- termediate metastable. The dihydrate indicated by (am.) is the amorphous form. Solubilities of anhydrate were doubtful (see text).) . 52 6 Partial phase diagram of the Zn(ClO3)2–H2O system . 82 7 Temperature dependence of solubility of TlClO3 in water . 89 8 Partial phase diagram of the NH4ClO3–H2O system. 101 9 Temperature dependence of solubility of TlBrO3 in water . 120 10 Temperature dependence of solubility of Zn(IO3)2 in water . 164 11 Temperature dependence of solubility of TlIO3 in water . 215 12 Temperature dependence of solubility of Pb(IO3)2 in water . 267 13 Temperature dependence of solubility of La(BrO3)3 in water . 308 14 Temperature dependence of solubility of Pr(BrO3)3 in water . 320 15 Temperature dependence of solubility of Nd(BrO3)3 in water . 329 16 Temperature dependence of solubility of Sm(BrO3)3 in water . 340 17 Temperature dependence of solubility of Gd(BrO3)3 in water . 347 18 Temperature dependence of solubility of Tb(BrO3)3 in water . 349 iv List of Tables 1 Interconversions between Quantities Used as Measures of Solubilities c- component Systems Containing c 1 Solutes i and Single Solvent c. xxvi − 2 Experimental solubility of Co(ClO3)2 in water . 1 3 Tentative solubility of Co(ClO3)2 in water . 4 4 Experimental solubility of Ni(ClO3)2 in water . 6 5 Tentative solubility of Ni(ClO3)2 in water . 9 6 Composition of saturated solutions in the ternary Ti(IO3)4–CsIO3–H2O system at 25 ◦C . 12 7 Summary for solubility studies of Mn(IO3)2 in water at various temperatures . 14 8 Doubtful solubility of Mn(IO3)2 in water . 15 9 Solubility of Mn(IO3)2 in aqueous solution of NaCl and KIO3 at various temper- atures . 18 10 Solubility of Mn(IO3)2 in aqueous solutions of Mn(ClO4)2 containing HClO4 at 25 ◦C . ..
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