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Safety Data Sheet Breaker J481

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Safety Data Sheet Breaker J481 SDS no. J481 Version 2 Revision date 10-Aug-2017 Supersedes date 11-Sep-2015 Safety Data Sheet Breaker J481 1. Identification of the substance/preparation and of the Company/undertaking 1.1 Product identifier Product name Breaker J481 Product code J481 1.2 Relevant identified uses of the substance or mixture and uses advised against Recommended Use Used as a fracturing additive in oilfield applications Uses advised against Consumer use 1.3 Details of the supplier of the safety data sheet Supplier Schlumberger Oilfield Australia Pty Ltd ABN: 74 002 459 225 ACN: 002 459 225 256 St. Georges Terrace, Perth WA 6000 +47 5157 7424 [email protected] 1.4 Emergency Telephone Number Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518 Denmark Poison Control Hotline (DK): +45 82 12 12 12 Germany +49 69 222 25285 Netherlands National Poisons Information Center (NL): +31 30 274 88 88 (NB: this service is only available to health professionals) 2. Hazards Identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Health hazards Acute toxicity - Oral Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Germ cell mutagenicity Category 2 Carcinogenicity Category 1B Specific target organ toxicity - Single exposure Category 3 Environmental hazards Not classified _____________________________________________________________________________________________ Page 1 / 12 Breaker J481 SDS no. J481 Revision date 10-Aug-2017 _____________________________________________________________________________________________ Physical Hazards Oxidizing Solids Category 1 2.2 Label elements Signal word DANGER Hazard statements H302 - Harmful if swallowed H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation H341 - Suspected of causing genetic defects H350 - May cause cancer H271 - May cause fire or explosion; strong oxidizer Precautionary Statements - EU (§28, 1272/2008) P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P220 - Keep/Store away from clothing/ combustible materials P221 - Take any precaution to avoid mixing with combustibles P280 - Wear protective gloves/protective clothing/eye protection/face protection P370 + P378 - In case of fire: use VERY LARGE quantities of water to extinguish P371 + P380 + P375 - In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion Supplementary precautionary statements P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P283 - Wear fire/ flame resistant/ retardant clothing P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P304 + P340 - IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P306 + P360 - IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes P308 + P313 - IF exposed or concerned: Get medical advice/attention P312 - Call a POISON CENTER or doctor/physician if you feel unwell P330 - Rinse mouth P332 + P313 - If skin irritation occurs: Get medical advice/attention P337 + P313 - If eye irritation persists: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P410 - Protect from sunlight P411 - Store at temperatures not exceeding 43 °C/ 110 °F P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable _____________________________________________________________________________________________ Page 2 / 12 Breaker J481 SDS no. J481 Revision date 10-Aug-2017 _____________________________________________________________________________________________ Contains Sodium bromate 2.3 Other hazards Not classified as PBT/vPvB by current EU criteria Australian statement of hazardous/dangerous nature Classified as Hazardous according to the criteria of NOHSC. HAZARDOUS SUBSTANCE. DANGEROUS GOODS. 3. Composition/information on ingredients 3.1 Substances Chemical Name EC No CAS No Weight-% Regulation (EC) No REACH 1272/2008 registration number Sodium bromate 232-160-4 7789-38-0 60 - 100 Skin Irrit. 2 (H315) No data available Eye Irrit. 2 (H319) Acute Tox. 4 (H302) Ox. Sol. 1 (H271) STOT. SE. 3(H335) Muta. 2 (H341) Carc. 1B (H350) 3.2 Mixtures Not applicable 4. First aid measures 4.1 First aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Get medical attention. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention if irritation persists. Eye Contact Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first five minutes, then continue rinsing eye. Get medical attention if irritation persists. 4.2. Most important symptoms and effects, both acute and delayed General advice The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop, the casualty should be transferred to hospital as soon as possible. Symptoms _____________________________________________________________________________________________ Page 3 / 12 Breaker J481 SDS no. J481 Revision date 10-Aug-2017 _____________________________________________________________________________________________ Inhalation Please see Section 11. Toxicological Information for further information. Ingestion Please see Section 11. Toxicological Information for further information. Skin contact Please see Section 11. Toxicological Information for further information. Eye contact Please see Section 11. Toxicological Information for further information. 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician Treat symptomatically. 5. Fire-fighting measures 5.1 Extinguishing media Suitable extinguishing media Deluge with water. Other methods not effective. Extinguishing media which must not be used for safety reasons Dry chemical, carbon dioxide and other gas-filled extinguishers. 5.2. Special hazards arising from the substance or mixture Unusual fire and explosion hazards May intensify fire; oxidizer. Hazardous combustion products Fire or high temperatures create: Oxygen, Bromine, bromine oxides and hydrogen bromide. 5.3 Advice for firefighters Special protective equipment for fire-fighters As in any fire, wear self-contained breathing apparatus and full protective gear. Special Fire-Fighting Procedures Containers close to fire should be removed immediately or cooled with water. Hazchem code ADG 1Y 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Use personal protective equipment. See also section 8. 6.2 Environmental precautions The product should not be allowed to enter drains, water courses or the soil. Environmental exposure controls Avoid release to the environment. Local authorities should be advised if significant spillages cannot be contained. 6.3 Methods and material for containment and cleaning up _____________________________________________________________________________________________ Page 4 / 12 Breaker J481 SDS no. J481 Revision date 10-Aug-2017 _____________________________________________________________________________________________ Methods for containment Prevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading. Methods for cleaning up Take up mechanically and collect in suitable container for disposal. Take precautionary measures against static discharges. Use non-sparking tools and equipment. After cleaning, flush away traces with water. 6.4 Reference to other sections See section 13 for more information. 7. Handling and storage 7.1 Precautions for safe handling Handling Do not handle until all safety precautions have been read and understood. Handle in accordance with good industrial hygiene and safety practice. Follow procedures for safe handling of oxidizers. Keep away from heat, sparks and open flame. No smoking. Avoid contact with skin and eyes. Avoid dust formation. Hygiene Measures Use good work and personal hygiene practices to avoid exposure. Wash hands and face before breaks and immediately after handling the product Remove contaminated clothing. Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities Technical measures/precautions Ensure adequate
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